Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
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D<br />
Diisopropylp http://www.maybridge.com<br />
2,6-Diisopropylphenol, 99%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
334820050 Glass bottle 5 g INR 1,900<br />
334820250 Glass bottle 25 g INR 5,810<br />
R22 R34<br />
S26 S36/37/39 S45<br />
Light sensitive<br />
Air sensitive<br />
Store below +4ºC<br />
Diisopropylphosphine<br />
10 wt.% solution in hexanes<br />
C12H18O CAS: 2078-54-8<br />
MFCD00008885<br />
FW: 178.27<br />
mp: 18 °C<br />
bp: 256 °C (764 mmHg)<br />
Fp: >112 °C<br />
d: 0.960<br />
n 20<br />
D : 1.513 -1.515<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
383400025 Glass bottle 2.5 g INR 2,520<br />
383400100 Glass bottle 10 g INR 6,550<br />
383400500 Glass bottle 50 g INR 26,590<br />
R11 R34 R48/20<br />
R51/53 R62 R65 R67<br />
S9 S16 S26 S33 S36/<br />
37/39 S45 S61 S62<br />
Air sensitive<br />
C 6 H 15 P [(CH 3 ) 2 CH] 2 PH<br />
CAS: 20491-53-6<br />
MFCD00233814<br />
FW: 118.16<br />
Fp: -22 °C<br />
Diisopropyl phosphite<br />
APPLICATION GUIDE<br />
Organophosphorous intermediates<br />
* Phosphites Reagent is alkylated to give trisubstituted phosphite. JCS(P1) 2000, 421<br />
* Phosphonates Reagent is used for the synthesis of complex phosphonates. SC 1998, 28, 175<br />
Diisopropyl phosphite, 98%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
115261000 Glass bottle 100 g INR 9,110<br />
R22 R36/37/38<br />
S26 S37/39<br />
Stench<br />
Moisture sensitive<br />
C 6 H 15 O 3 P [(CH 3 ) 2 CHO] 2 P(O)H<br />
CAS: 1809-20-7<br />
MFCD00117905<br />
FW: 166.16<br />
bp: 71 °C (8 mmHg)<br />
Fp: >112 °C<br />
d: 0.997<br />
Diisopropyl phosphorofluoridate , see Diisopropyl fluorophosphate on page 833<br />
(-)-Diisopropyl D-tartrate, 99%<br />
n 20<br />
D : 1.4065 -1.4085<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
211180100 Glass bottle 10 g INR 920<br />
211180500 Glass bottle 50 g INR 3,090<br />
S24/25<br />
Hygroscopic<br />
C10H18O6 CAS: 62961-64-2<br />
MFCD00008876<br />
FW: 234.25<br />
[-CH(OH)CO2CH(CH3 ) 2 ] 2<br />
bp: 275 °C<br />
Fp: 110 °C<br />
[] 20<br />
D : -17.25 (neat)<br />
d: 1.110<br />
n 20<br />
D : 1.438 -1.44<br />
834 Please enquire for bulk quantities<br />
OH<br />
(+)-Diisopropyl L-tartrate<br />
APPLICATION GUIDE<br />
Cyclopropanation<br />
* Simmons-Smith SL 2003, 1075<br />
Oxidation<br />
* Epoxidation Used with titanium isopropoxide and t-butyl hydroperoxide in the Sharpless epoxidation<br />
of allylic alcohols. JACS 1980, 102, 5974<br />
Resolution<br />
* Allylic alcohols Kinetic resolution of racemic allylic alcohols via the Sharpless epoxidation. JOC<br />
1994, 59, 1444<br />
(+)-Diisopropyl L-tartrate, 99%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
212030050 Glass bottle 5 g INR 570<br />
212030250 Glass bottle 25 g INR 830<br />
212031000 Glass bottle 100 g INR 2,420<br />
S24/25<br />
Hygroscopic<br />
C10H18O6 CAS: 2217-15-4<br />
MFCD00064450<br />
FW: 234.25<br />
[-CH(OH)CO2CH(CH3 ) 2 ] 2<br />
bp: 275 °C<br />
Fp: 110 °C<br />
[] 20<br />
D : +17.25 (neat)<br />
d: 1.110<br />
n 20<br />
D : 1.438 -1.44<br />
4,4'-Diisothiocyanostilbene-2,2'-disulfonic acid disodium salt , see DIDS on page 770<br />
Diketene acetone adduct , see 2,2,6-Trimethyl-4H-1,3-dioxin-4-one on page 2094<br />
2,5-Diketopiperazine , see Glycine anhydride on page 1112<br />
Dilauroyl peroxide, 99%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
349741000 Plastic bottle 100 g INR 1,070<br />
349745000 Plastic bottle 500 g INR 2,730<br />
R7<br />
S3/7 S14A S36/37/<br />
39<br />
Store below +4ºC<br />
C24H46O4 CAS: 105-74-8<br />
MFCD00008964<br />
Dilauryl phosphite, 85%<br />
tech.<br />
[CH 3 (CH 2 ) 10 CO] 2 O 2<br />
FW: 398.63<br />
mp: 53-57 °C<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
115290250 Glass bottle 25 g INR 6,740<br />
115291000 Glass bottle 100 g INR 11,060<br />
R36/37/38<br />
S26 S37/39<br />
Moisture sensitive<br />
C 24 H 51 O 3 P [CH 3 (CH 2 ) 11 O] 2 P(O)H<br />
CAS: 21302-90-9<br />
MFCD00015068<br />
FW: 418.64<br />
Dilithium phthalocyanine<br />
mp: 24 °C<br />
bp: 200 °C (2 mmHg)<br />
Fp: >112 °C<br />
d: 0.946<br />
n 20<br />
D : 1.45 -1.453<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
407820050 Glass bottle 5 g INR 13,970<br />
S24/25 C 32 H 16 Li 2 N 8<br />
CAS: 25510-41-2 MFCD00059094 FW: 526.40<br />
Dilithium tetrachlorocuprate, 0.1 M solution in THF<br />
APPLICATION GUIDE<br />
Organometallic Chemistry<br />
* Halogen metal exchange Catalyst for the cross-coupling reaction of Grignard reagent with alkyl<br />
halides. TL 1982, 23, 3115<br />
* Nucleophilic addition Catalyst for opening of epoxides with Grignard reagents from the less hindered<br />
site. TL 1996, 37, 3931<br />
* Nucleophilic addition Efficient catalyst for the conjugate addition reaction. TA 1999, 10, 2739<br />
Reduction<br />
* Epoxide to alcohol When used in excess of stoichiometric quantities it opens epoxides to give a transchlorohydrins.<br />
TL 1986, 27, 3697
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