Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
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1,3-Diiodopropane, 99%<br />
stabilized<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
218600250 Glass bottle 25 ml INR 1,760<br />
218601000 Glass bottle 100 ml INR 5,300<br />
R36/37/38<br />
S26 S37/39<br />
Light sensitive<br />
Diiodosilane<br />
C3H6I2 CAS: 627-31-6<br />
MFCD00001097<br />
FW: 295.88<br />
I(CH 2 ) 3 I<br />
bp: 111-113 °C (31<br />
mmHg)<br />
Fp: >110 °C<br />
d: 2.576<br />
n 20<br />
D : 1.6405 -1.6425<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
388920010 1 g INR 1,550<br />
388920050 5 g INR 3,820<br />
R10 R14 R20/21/22<br />
R34<br />
S8 S16 S26 S36/37/<br />
39 S45<br />
Light sensitive<br />
Moisture sensitive<br />
Air sensitive<br />
Store below +4ºC<br />
H 2 I 2 Si SiH 2 (I) 2<br />
CAS: 13760-02-6<br />
FW: 283.90<br />
2,5-Diiodothiophene, 97%<br />
bp: 53-60 °C (25 mm-<br />
Hg)<br />
Fp: 38 °C<br />
d: 2.834<br />
<strong>Maybridge</strong> Product code Packaging Pack size Price<br />
CD08226EA Glass bottle 10 g INR 6,900<br />
R20/21/22 R36/37/<br />
38<br />
S26 S36/37/39<br />
Light sensitive<br />
Store below +4ºC<br />
C4H2I2S CAS: 625-88-7<br />
MFCD00014525<br />
FW: 335.94<br />
mp: 37-41 °C<br />
bp: 139-140 °C<br />
Fp: 96 °C<br />
3,5-Diiodo-L-tyrosine dihydrate, 99%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
225610100 Glass bottle 10 g INR 2,590<br />
225610500 Glass bottle 50 g INR 7,580<br />
R36/37/38<br />
S26 S37/39<br />
Store below +4ºC<br />
C 9 H 9 I 2 NO 3 .2H 2 O HOC 6 H 2 I 2 CH 2 CH(NH 2 )COOH.2H 2 O<br />
CAS: 300-39-0<br />
MFCD00150275<br />
FW: 469.01<br />
mp: 200 °C (d)<br />
S I<br />
[] 20<br />
D : -20.7 (c=2.5,<br />
0.1N NaOH/H2O)<br />
Diiron nonacarbonyl<br />
APPLICATION GUIDE<br />
Reduction<br />
* Deoxygenation Deoxygenation of fura-aryne adduct. Forms a complex which decomposes gradually<br />
to aromatic hydrocarbon. AJC 1982, 35, 843<br />
I<br />
http://www.acros.com Diiodopropan<br />
Diiron nonacarbonyl, 98%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
209280100 Glass bottle 10 g INR 3,070<br />
209280500 Glass bottle 50 g INR 11,020<br />
R11<br />
S16<br />
Light sensitive<br />
Air sensitive<br />
Store below +4ºC<br />
C9Fe2O9 CAS: 15321-51-4<br />
MFCD00151465<br />
Diisobutylaluminium chloride<br />
0.8M solution in heptane, AcroSeal®<br />
Fe2 (CO) 9<br />
FW: 363.78<br />
mp: 100 °C (d)<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
377561000 AcroSeal 100 ml INR 5,770<br />
377568000 AcroSeal 800 ml INR 20,670<br />
R11 R14/15 R35<br />
R50/53 R65 R67<br />
S6A S16 S26 S29<br />
S36/37/39 S43E S45<br />
S57<br />
Moisture sensitive<br />
Air sensitive<br />
C8H18AlCl CAS: 1779-25-5<br />
MFCD00008927<br />
FW: 176.67<br />
d: 0.726<br />
Diisobutylaluminium hydride, 1.1M solution in cyclohexane<br />
APPLICATION GUIDE<br />
Organometallic Chemistry<br />
* Hydrometallation Alkynes/alkenes to hydroalumination product. JOC 1971, 36, 3520<br />
Reduction<br />
* 1,4-Reduction Reagent of choice for the reduction of ,-unsaturated ketones and ,-unsaturated<br />
esters to allylic alcohols. CC 1970, 213; JOC 1982, 47, 2993<br />
* Acid chloride to alcohol JOC 1985, 50, 2443<br />
* Acid to alcohol JOC 1985, 50, 2444<br />
* Acid to aldehyde Carried out at low temperature -75-70°C. JGU 1967, 37, 525<br />
* Aldehyde to alcohol JOC 1985, 50, 2443<br />
* Amide to aldehyde Keeping the amide in excess gives the aldehyde rather than the amine. Bull.<br />
Acad. Sci. USSR, Div. Chem. Sci 1959, 2046<br />
* Amide to amine When the amide is kept in excess, the aldehyde rather than the amine is produced.<br />
BAU 959, 2046<br />
* Carboxylic ester to alcohol With 2 eq. Of DIBAL. JOC 1985, 50, 2443<br />
* Carboxylic ester to aldehyde With 1 eq. Of DIBAL at low temperatures. JOC 1966, 31, 1447<br />
* Disulfide to thiol JOC 1985, 50, 2443<br />
* Epoxide to alcohol At the more hindered carbon. JACS 1973, 95, 957<br />
* Epoxide to alcohol DIBAL gives attack at the most hindered carbon or SN2 type attack is seen.<br />
JACS 1973, 95, 957<br />
* Imine to amine TL 1982, 23, 1929<br />
* Isocyanate to imine JOC 1985, 50, 2443<br />
* Ketone to alcohol In the presence of methylaluminium bis (2,6-di-t-butyl-4-methyl-phenoxide)<br />
reduces the more sterically hindered ketone. JACS 1988, 110, 2650<br />
* Nitrile to aldehyde Following hydrolysis of intermediate imine. JOC 1970, 35, 858<br />
* Nitrile to imine JOC 1985, 50, 2443<br />
* Nitro to hydroxylamine JOC 1985, 50, 2443<br />
* Oxime to amine Rearranged products can be obtained due to Lewis acidity of DIBAL. TL 1983, 24,<br />
4711<br />
* Sulfone to sulfide At higher temperatures. CJC 1973, 51, 1419<br />
* Tosylate to alkane Recl. Trav. Chim. Pays-BaS 1984, 103, 220<br />
Please enquire for bulk quantities 829<br />
Cl<br />
Al<br />
D
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