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Acros Organics & Maybridge - D

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D<br />

Diiodobenzen http://www.maybridge.com<br />

1,4-Diiodobenzene, 98%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

185970500 Glass bottle 50 g INR 2,270<br />

185972500 Glass bottle 250 g INR 8,990<br />

R36/37/38<br />

S24/25<br />

Light sensitive<br />

C6H4I2 CAS: 624-38-4<br />

MFCD00001054<br />

4,4'-Diiodobiphenyl, 99%<br />

C6H4I2 FW: 329.90<br />

mp: 128-132 °C<br />

bp: 285 °C<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

115120050 Glass bottle 5 g INR 940<br />

115120250 Glass bottle 25 g INR 2,670<br />

115121000 Glass bottle 100 g INR 7,110<br />

R36/37/38<br />

S26 S37/39<br />

Light sensitive<br />

C12H8I2 IC6H4C6H4I CAS: 3001-15-8 FW: 406.00 mp: 201-204 °C<br />

Di--iodobis(p-cymene)iodoruthenium(II), 97%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

382572500 Glass bottle 250 mg INR 1,350<br />

382570010 Glass bottle 1 g INR 3,820<br />

R22 R36 R52/53 R68<br />

S26 S36/37 S61<br />

Moisture sensitive<br />

Air sensitive<br />

Store below +4ºC<br />

C 20 H 28 I 4 Ru 2<br />

CAS: 90614-07-6 MFCD08064027 FW: 978.18<br />

Diiodo(p-cymene)ruthenium(II) dimer , see Di--iodobis(p-cymene)iodoruthenium(II) on page 828<br />

1,4-Diiodo-2,5-dimethylbenzene, 97%<br />

<strong>Maybridge</strong> Product code Packaging Pack size Price<br />

BTB13663DA Glass bottle 1 g INR 12,100<br />

BTB13663EA Glass bottle 10 g INR 40,600<br />

R36/37/38<br />

S26 S37/39<br />

Light sensitive<br />

C 8 H 8 I 2<br />

CAS: 1124-08-9<br />

MFCD00829126<br />

FW: 357.95<br />

mp: 103-104 °C<br />

1,2-Diiodoethane<br />

APPLICATION GUIDE<br />

Cyclopropanation<br />

1,2-Diiodoethane is used in the methylcyclopropanation of alkenes with diethylzinc, ethylzinc iodide,<br />

copper powder, zinc/copper couple, zinc/silver couple, trialkylaluminum reagents or Samarium (0).<br />

JOC 1987, 52, 3942<br />

Halogenation<br />

* Arene to haloarene Used as a source of positive iodine. JOC 1992, 57, 2495<br />

1,2-Diiodoethane, 99%<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

115140250 Glass bottle 25 g INR 1,560<br />

115141000 Glass bottle 100 g INR 5,520<br />

R36/37/38<br />

S26 S37/39<br />

Light sensitive<br />

Store below +4ºC<br />

C2H4I2 CAS: 624-73-7<br />

MFCD00001093<br />

ICH 2 CH 2 I<br />

FW: 281.85<br />

mp: 80-83 °C<br />

d: 2.130<br />

828 Please enquire for bulk quantities<br />

I<br />

I<br />

1,6-Diiodohexane, 97%<br />

stabilized<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

386740050 Glass bottle 5 g INR 600<br />

386740250 Glass bottle 25 g INR 1,530<br />

R36/37/38<br />

S26 S37/39<br />

Light sensitive<br />

C6H12I2 CAS: 629-09-4<br />

MFCD00001103<br />

FW: 337.96<br />

I(CH 2 ) 6 I<br />

mp: 9-10 °C<br />

bp: 141-142 °C (10<br />

mmHg)<br />

Fp: >110 °C<br />

3,5-Diiodo-4-hydroxybenzonitrile, 98%<br />

d: 2.052<br />

n 20<br />

D : 1.5852 -1.5872<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

259180050 Glass bottle 5 g INR 6,620<br />

R21 R23/25 R36<br />

R48/22 R50/53 R63<br />

S36/37 S45 S60 S61<br />

S63<br />

Light sensitive<br />

C7H3I2NO CAS: 1689-83-4<br />

MFCD00016422<br />

FW: 370.90<br />

mp: 200 °C<br />

3,5-Diiodo--(p-hydroxyphenyl)alanine , see 3,5-Diiodo-L-tyrosine dihydrate on page 829<br />

Diiodomethane<br />

APPLICATION GUIDE<br />

Cyclopropanation<br />

* Cyclopropanation Combination with zinc-copper couple generates ICH2ZnI, the reagent for the<br />

classical Simmons-Smith cyclopropanation of alkenes. JACS 1958, 80, 5323<br />

Reduction<br />

* Carbonyl to alkene Useful alternative to Wittig reaction. OR 1972, 20, 1<br />

Diiodomethane, 99+%<br />

stabilized<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

169830250 Glass bottle 25 g INR 1,030<br />

169831000 Glass bottle 100 g INR 3,330<br />

169835000 Glass bottle 500 g INR 13,820<br />

R20/21 R25 R36/37/<br />

38<br />

S26 S36/37/39 S45<br />

Light sensitive<br />

CH2I2 CAS: 75-11-6<br />

MFCD00001079<br />

FW: 267.83<br />

1,5-Diiodopentane, 98%<br />

stabilized<br />

CH2I2 mp: 6 °C<br />

bp: 181 °C<br />

Fp: >110 °C<br />

d: 3.320<br />

n 20<br />

D : 1.737<br />

<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />

249630250 Glass bottle 25 g INR 1,200<br />

249631000 Glass bottle 100 g INR 4,570<br />

249630500 Glass bottle 50 ml INR 2,280<br />

R36/37/38<br />

S26 S37/39<br />

Light sensitive<br />

C5H10I2 CAS: 628-77-3<br />

MFCD00001101<br />

FW: 323.94<br />

I(CH 2 ) 5 I<br />

bp: 101-102 °C (3 mm-<br />

Hg)<br />

Fp: >110 °C<br />

d: 2.177<br />

I<br />

N<br />

OH<br />

I<br />

n 20<br />

D : 1.5992 -1.6012

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