Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
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D<br />
Diethylchlor http://www.maybridge.com<br />
Diethyl chlorothiophosphate, 97%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
114260050 Glass bottle 5 g INR 1,150<br />
114261000 Glass bottle 100 g INR 2,050<br />
114265000 Glass bottle 500 g INR 6,810<br />
R21/22 R26 R29 R34<br />
S8 S26 S28A S36/<br />
37/39 S45<br />
Stench<br />
Moisture sensitive<br />
C 4 H 10 ClO 2 PS (C 2 H 5 O) 2 P(S)Cl<br />
CAS: 2524-04-1<br />
MFCD00009088<br />
FW: 188.61<br />
Diethylcyanamide, 99+%<br />
bp: 96-98 °C (25 mm-<br />
Hg)<br />
Fp: 92 °C<br />
d: 1.200<br />
n 20<br />
D : 1.471 -1.473<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
200220100 Glass bottle 10 g INR 7,510<br />
200220500 Glass bottle 50 g INR 31,950<br />
R23/24/25 R36/37/<br />
38<br />
S26 S36/37/39 S45<br />
Moisture sensitive<br />
C5H10N2 CAS: 617-83-4<br />
MFCD00001769<br />
FW: 98.15<br />
(C 2 H 5 ) 2 NCN<br />
1,1'-Diethyl-2,2'-cyanine iodide, 99%<br />
bp: 186-188 °C<br />
Fp: 69 °C<br />
d: 0.846<br />
n 20<br />
D : 1.421 -1.423<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
407255000 Glass bottle 500 mg INR 5,020<br />
R23/24/25<br />
S45<br />
C 23 H 23 IN 2<br />
CAS: 977-96-8<br />
MFCD00011971<br />
FW: 454.34<br />
mp: 273 °C (d)<br />
Diethyl cyanomethylphosphonate<br />
APPLICATION GUIDE<br />
Organophosphorous intermediates<br />
* Horner-Emmons<br />
Diethyl cyanomethylphosphonate, 96%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
114270100 Glass bottle 10 g INR 830<br />
114270500 Glass bottle 50 g INR 3,220<br />
R20/21/22 R36/37/<br />
38<br />
S23 S26 S36/37/39<br />
C 6 H 12 NO 3 P (C 2 H 5 O) 2 P(O)CH 2 CN<br />
CAS: 2537-48-6<br />
MFCD00001893<br />
FW: 177.14<br />
bp: 101-102 °C (0.4<br />
mmHg)<br />
Fp: >112 °C<br />
d: 1.090<br />
n 20<br />
D : 1.4312 -1.4332<br />
Diethyl cyanophosphonate<br />
APPLICATION GUIDE<br />
Acylation<br />
* C-Acylation C-Acylation of active methylene compounds can be achieved with a carboxylic acid and<br />
DEPC in the presence of a base. CPB 1984, 32, 3323<br />
Interconversion of functional groups<br />
* Arylsulfinic acid salt to aryl thiocyanate Aryl thiocyanates can be prepared from the sodium salt of<br />
the arylsulfinic acid and DEPC. TL 1982, 23, 447<br />
* Carboxylic acid to amide Aromatic and aliphatic acids and amines can be condensed with aliphatic<br />
and aromatic acids. TL 1973, 1595<br />
Peptide chemistry<br />
* Coupling agent Very little racemisation is seen during peptide coupling. CPB 1982, 30, 3147<br />
Reduction<br />
* N-Oxide to amine Reaction of the N-oxide of nitrogen containing heterocycles with DEPC allows acyanation<br />
with loss of the oxide e.g. isoquinoline-1-oxide to 1-cyanoisoquinoline (Reissert reaction).<br />
H 1981, 15, 981<br />
780 Please enquire for bulk quantities<br />
Diethyl cyanophosphonate, 93%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
224290050 Glass bottle 5 g INR 1,110<br />
224290250 Glass bottle 25 g INR 3,490<br />
224291000 Glass bottle 100 g INR 13,990<br />
R26/27/28 R32 R34<br />
S26 S28A S36/37/39<br />
S45 S50A<br />
Stench<br />
Moisture sensitive<br />
Store below +4ºC<br />
C 5 H 10 NO 3 P (C 2 H 5 O) 2 P(O)CN<br />
CAS: 2942-58-7<br />
MFCD00010256<br />
FW: 163.11<br />
bp: 104-105 °C (19<br />
mmHg)<br />
Fp: 80 °C<br />
d: 1.070<br />
Diethyl 1,1-cyclopropanedicarboxylate, 97%<br />
n 20<br />
D : 1.402 -1.404<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
164450250 Glass bottle 25 g INR 26,410<br />
S24/25 C 9 H 14 O 4 C 3 H 4 (CO 2 C 2 H 5 ) 2<br />
CAS: 1559-02-0<br />
MFCD00001283<br />
FW: 186.21<br />
bp: 94-96 °C (10 mm-<br />
Hg)<br />
Fp: 86 °C<br />
d: 1.050<br />
Diethyl trans-1,2-cyclopropanedicarboxylate, 97%<br />
n 20<br />
D : 1.432 -1.434<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
169180050 Glass bottle 5 g INR 6,240<br />
169180250 Glass bottle 25 g INR 19,230<br />
S24/25 C9H14O4 C3H4 (CO2C2H5 ) 2<br />
CAS: 3999-55-1 bp: 70-75 °C (1 mmHg)<br />
MFCD00001286 Fp: 98 °C<br />
FW: 186.21<br />
d: 1.060<br />
Diethyl 2,2-diallylmalonate<br />
Tech.<br />
n 20<br />
D : 1.44 -1.442<br />
<strong>Maybridge</strong> Product code Packaging Pack size Price<br />
SB00826EA Glass bottle 10 g INR 2,700<br />
SB00826EE Glass bottle 50 g INR 11,700<br />
S24/25 C13H20O4 CAS: 3195-24-2<br />
MFCD00009126<br />
FW: 240.30<br />
Fp: >110 °C<br />
d: 0.994<br />
n20 D : 1.446<br />
Diethyl 2,5-dibromohexanedioate, 97%<br />
<strong>Maybridge</strong> Product code Packaging Pack size Price<br />
BTB13063DA Glass bottle 1 g INR 3,900<br />
BTB13063EA Glass bottle 10 g INR 27,500<br />
R34<br />
S26 S36/37/39 S45<br />
Lachrymator<br />
C 10 H 16 Br 2 O 4<br />
CAS: 869-10-3<br />
MFCD00276565<br />
FW: 360.04<br />
mp: 66-68 °C<br />
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O<br />
O<br />
Br<br />
O O<br />
Br<br />
O<br />
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