Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
You also want an ePaper? Increase the reach of your titles
YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.
Diethyl carbonate, 99%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
114221000 Glass bottle 100 ml INR 1,020<br />
114225000 Glass bottle 500 ml INR 3,340<br />
114220010 Glass bottle 1 l INR 4,070<br />
114220025 Glass bottle 2.5 l INR 6,980<br />
R10<br />
S16<br />
Moisture sensitive<br />
C5H10O3 CAS: 105-58-8<br />
MFCD00009107<br />
FW: 118.13<br />
trans-Diethyl caronate, 95%<br />
(C 2 H 5 O) 2 CO<br />
mp: -43 °C<br />
bp: 126-128 °C<br />
Fp: 33 °C<br />
d: 0.975<br />
n 20<br />
D : 1.383 -1.385<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
374260010 Glass bottle 1 g INR 8,560<br />
S24/25 C11H18O4 CAS: 67945-22-6<br />
MFCD00145428<br />
FW: 214.26<br />
n 20<br />
D : 1.4425 -1.4445<br />
N,N,-Diethylchloroacetamide, 98%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
351850050 Glass bottle 5 g INR 870<br />
351850250 Glass bottle 25 g INR 2,720<br />
R21/22 R26 R36/37/<br />
38<br />
S26 S28A S36/37/39<br />
S38 S45<br />
C6H12ClNO CAS: 2315-36-8<br />
MFCD00000928<br />
FW: 149.62<br />
bp: 121-122 °C (12<br />
mmHg)<br />
Fp: >110 °C<br />
d: 1.089<br />
Diethyl (4-chlorobenzyl)phosphonate, 98%<br />
n 20<br />
D : 1.469 -1.471<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
332260050 Glass bottle 5 g INR 5,630<br />
332260250 Glass bottle 25 g INR 16,520<br />
R36/37/38<br />
S26 S37/39<br />
C11H16ClO3P CAS: 39225-17-7<br />
MFCD00051568<br />
FW: 262.67<br />
bp: 153-156 °C (0.6<br />
mmHg)<br />
d: 1.090<br />
n 20<br />
D : 1.508 -1.51<br />
Diethyl (2-chloroethyl)phosphonate, 95%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
310130050 Glass bottle 5 g INR 11,750<br />
R22 R36/37/38<br />
S26 S37/39<br />
C 6 H 14 ClO 3 P ClCH 2 CH 2 P(O)(OC 2 H 5 ) 2<br />
CAS: 10419-79-1<br />
MFCD00010358<br />
FW: 200.62<br />
Cl<br />
O<br />
bp: 92-94 °C (4 mmHg)<br />
Fp: 98 °C<br />
d: 1.150<br />
O O<br />
O<br />
O P O<br />
O<br />
n 20<br />
D : 1.439 -1.442<br />
http://www.acros.com Diethylcarbo<br />
Diethyl (chloromethyl)phosphonate<br />
APPLICATION GUIDE<br />
Organophosphorous intermediates<br />
* Horner-Emmons TL 1985, 26, 4435<br />
Diethyl (chloromethyl)phosphonate, 98%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
330650010 Glass bottle 1 g INR 4,120<br />
330650050 Glass bottle 5 g INR 15,620<br />
R36/37/38<br />
S26 S37/39<br />
C5H12ClO3P CAS: 3167-63-3<br />
MFCD00010189<br />
FW: 186.57<br />
bp: 109-110 °C (10<br />
mmHg)<br />
Fp: 86 °C<br />
d: 1.200<br />
n 20<br />
D : 1.438 -1.44<br />
Diethyl chlorophosphate<br />
APPLICATION GUIDE<br />
Coupling Chemistry<br />
* Coupling agent Used to activate carboxylic acids, the phosphonate ester can be treated with<br />
alcohols, amines and thiols to provide esters, amides and thiol esters respectively. TL 1985, 26,<br />
1341<br />
Interconversion of functional groups<br />
* Phosphorylation Highly electrophilic phosphorylating reagent for phenols, alcohols, anilines and<br />
carbon nucleophiles. S 1991, 691; JOC 1989, 54, 3292; JOC 1993, 58, 3811<br />
Organophosphorous intermediates<br />
* Phosphonates Trapping ketone enolates provides enol phosphates, which rearrange to the bketophosphonates<br />
on further treatment with base. These are useful intermediates in Wadsworth<br />
Horner Emmons chemistry. TL 1986, 27, 4265.<br />
Reduction<br />
* Deoxygenation Phenol phosphates and enol phosphates are readily deoxygenated by reduction with<br />
activated titanium metal. JOC 1978, 43, 2715<br />
Diethyl chlorophosphate, 95%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
407240250 Glass bottle 25 g INR 1,820<br />
407241000 Glass bottle 100 g INR 4,970<br />
R26/27/28 R29 R34<br />
S8 S26 S28A S36/<br />
37/39 S45<br />
Moisture sensitive<br />
C 4 H 10 ClO 3 P (C 2 H 5 O) 2 POCl<br />
CAS: 814-49-3<br />
MFCD00009075<br />
Diethylchlorophosphine , see Chloro(diethyl)phosphine on page 512<br />
Diethyl chlorophosphite, 90%<br />
tech.<br />
FW: 172.55<br />
bp: 81 °C (6 mm Hg)<br />
Diethyl chlorophosphonite , see Diethyl chlorophosphite on page 779<br />
d: 1.190<br />
n 20<br />
D : 1.416 -1.418<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
114250250 Glass bottle 25 ml INR 5,890<br />
114251000 Glass bottle 100 ml INR 14,310<br />
R11 R34<br />
S16 S24/25<br />
C 4 H 10 ClO 2 P (C 2 H 5 O) 2 PCl<br />
CAS: 589-57-1<br />
MFCD00009074<br />
FW: 156.55<br />
bp: 153-155 °C<br />
Fp:
Change language