Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
Acros Organics & Maybridge - D
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Diethyl (3-aminopropyl)phosphonate oxalate<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
332235000 Glass bottle 500 mg INR 25,830<br />
R36/37/38<br />
S26 S37/39<br />
Hygroscopic<br />
C 7 H 18 NO 3 P.C 2 H 2 O 4<br />
CAS: 203192-99-8 MFCD00800257 FW: 285.23<br />
[6-(Diethylamino)-3-pyridinyl]methanol, 97%<br />
<strong>Maybridge</strong> Product code Packaging Pack size Price<br />
MO07117CB Glass bottle 250 mg INR 7,100<br />
MO07117DA Glass bottle 1 g INR 14,000<br />
MO07117DE Glass bottle 5 g INR 39,800<br />
R20/21/22 C10H16N2O CAS: 690632-68-9<br />
MFCD06200887<br />
FW: 180.25<br />
Diethylaminosulfur trifluoride<br />
APPLICATION GUIDE<br />
Fluorination<br />
* 1,1-difluorination Aliphatic aldehydes to 1,1-difluorinated compounds. S 1973, 787<br />
* 1,1-difluorination Aromatic aldehydes to 1,1-difluorinated compounds. JOC 1975, 40, 574<br />
* 1,1-difluorination Heterocyclic aldehydes to 1,1-difluorinated compounds. JHC 1981, 18, 1029<br />
* Alcohol to alkyl fluoride Less likely to cause rearrangements or dehydration than other reagents<br />
sometimes used for this purpose (eg SF4 , HF). OSC 1988, 6, 835<br />
* b-Diketones to a,b-difluoro-a,b-unsaturated ketones Oxidatively fluorinated with DAST at -78°C to<br />
r.t. TL 1986, 27, 3337<br />
* b-keto esters to a,b-difluoro-a,b-unsaturated esters Oxidatively fluorinated with DAST at -78°C to<br />
r.t. TL 1986, 27, 3337<br />
* Carboxylic acid to acyl fluoride JFC 1985, 27, 35<br />
* Dialkyl sulfoxides to a-fluoroalkyl sulfides DAST, chloroform, ambient temp. TL 1988, 29, 5729<br />
* Dialkyl sulfoxides to a-fluoroalkyl sulfides Less reactive sulfoxides by catalysis with certain Lewis<br />
acids. JOC 1990, 55, 4757<br />
* Epoxides to difluoro compounds The reactivity of DAST with epoxides varies with structure. eg<br />
cyclopentene oxide and cyclohexene oxide give a mixture of 1,1-difluoro and bis(a-fluoro) ethers.<br />
JFC 1987, 36, 373<br />
* Interconversion of halide JOC 1975, 40, 574; OR 1988, 513<br />
Diethylaminosulfur trifluoride, 95%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
216110050 Plastic bottle 5 g INR 2,000<br />
216110250 Plastic bottle 25 g INR 7,700<br />
216111000 Plastic bottle 100 g INR 28,530<br />
R5 R10 R14 R35<br />
S16 S26 S36/37/39<br />
Moisture sensitive<br />
Store below -20ºC<br />
C4H10F3NS (C2H5 ) 2NSF3 CAS: 38078-09-0 bp: 30-32 °C (3 mmHg)<br />
MFCD00000363 Fp: 23 °C<br />
FW: 161.18<br />
d: 1.316<br />
N<br />
N<br />
OH<br />
n 20<br />
D : 1.41 -1.416<br />
http://www.acros.com Diethylamino<br />
N,N-Diethylaniline, 99%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
181060050 Glass bottle 5 ml INR 1,200<br />
181062500 Glass bottle 250 ml INR 1,260<br />
181060010 Glass bottle 1 l INR 2,630<br />
181060025 Glass bottle 2.5 l INR 6,260<br />
R23/24/25 R33 R51/<br />
53<br />
S28A S37 S45 S61<br />
C 10 H 15 N C 6 H 5 N(C 2 H 5 ) 2<br />
CAS: 91-66-7<br />
MFCD00009042<br />
FW: 149.24<br />
2,6-Diethylaniline, 98%<br />
mp: -38 °C<br />
bp: 215-217 °C<br />
Fp: 88 °C<br />
N,N-Diethylanilineborane , see Borane-N,N-diethylaniline complex on page 270<br />
d: 0.933<br />
n 20<br />
D : 1.541 -1.543<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
165222500 Glass bottle 250 ml INR 3,060<br />
165220010 Glass bottle 1 l INR 6,810<br />
R22<br />
S23 S24<br />
Light sensitive<br />
Air sensitive<br />
C 10 H 15 N (C 2 H 5 ) 2 C 6 H 3 NH 2<br />
CAS: 579-66-8<br />
MFCD00007753<br />
FW: 149.24<br />
1,4-Diethylbenzene, 98%<br />
mp: 3-4 °C<br />
bp: 243 °C<br />
Fp: 123 °C<br />
d: 0.900<br />
n 20<br />
D : 1.5446 -1.5466<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
114150050 Glass bottle 5 ml INR 1,360<br />
114150250 Glass bottle 25 ml INR 4,530<br />
S24/25 C 10 H 14 C 6 H 4 (C 2 H 5 ) 2<br />
CAS: 105-05-5<br />
MFCD00009264<br />
FW: 134.22<br />
mp: -43 °C<br />
bp: 184 °C<br />
Fp: 56 °C<br />
Diethylbenzene<br />
mixture of o-, m- and p-isomers, sum min. 95%<br />
d: 0.860<br />
n 20<br />
D : 1.4935 -1.4955<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
114162500 Glass bottle 250 ml INR 2,210<br />
114160010 Glass bottle 1 l INR 3,040<br />
114160025 Glass bottle 2.5 l INR 6,670<br />
114160100 Metal drum 10 l INR 17,720<br />
S24/25 C 10 H 14<br />
CAS: 25340-17-4<br />
MFCD00792900<br />
FW: 134.22<br />
bp: 180-182 °C<br />
Fp: 56 °C<br />
d: 0.869<br />
n 20<br />
D : 1.494 -1.496<br />
Diethyl benzylphosphonate<br />
APPLICATION GUIDE<br />
Organophosphorous intermediates<br />
* Horner-Wadsworth-Emmons Reaction with aromatic aldehydes gives stilbenes, exclusively trans.<br />
NaH & 15-crown-5 promotes reaction with aldehydes and ketones at room temperature. JOC 1965,<br />
30, 680; S 1981, 117<br />
Please enquire for bulk quantities 777<br />
D
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