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Al<br />

F i<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

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0<br />

1 2 3 4 5 6 7 8 9 10<br />

Fig.2.: Fluorescence <strong>in</strong>tensity dependence on pH for each complex<br />

pH<br />

The fluorescence <strong>in</strong>tensity can be significantly <strong>in</strong>creased <strong>in</strong> the presence <strong>of</strong> cationic<br />

surfactant and small bathochromic shift <strong>in</strong> excitation spectra is also observed. The<br />

fluorescence is <strong>in</strong>creased <strong>in</strong> one hour (Fig.3) and after it reaches maximum, it’s stable at least<br />

10 hours. The best positive effect was found for Zephyram<strong>in</strong>e (Fig.4.). No positive effect was<br />

observed for anionic and nonionic surfactants.<br />

20<br />

Ga<br />

In<br />

18<br />

a b<br />

Fig.3.: Comparison <strong>of</strong> emission spectra time trace for Al-QSA complex without surfactant (a)<br />

and <strong>in</strong> presence <strong>of</strong> cationic surfactant Zephyram<strong>in</strong>e (b)<br />

Sborník soutěže Studentské tvůrčí č<strong>in</strong>nosti Student 2006 a doktorské soutěže O cenu děkana 2005 a 2006<br />

Sekce DSP 2006, strana 245<br />

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