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2. ENVIRONMENTAL ChEMISTRy & TEChNOLOGy 2.1. Lectures

2. ENVIRONMENTAL ChEMISTRy & TEChNOLOGy 2.1. Lectures

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Chem. Listy, 102, s265–s1311 (2008) Environmental Chemistry & Technology<br />

Fig 3. Comparison of b analysis<br />

Note : w.w. = waste water, MWWT = mechanical waste water<br />

treatment, SWTP = sewage water treatment plant<br />

Fig. 4. boron concentrations<br />

The results are from these samples, because boron could be<br />

component in small particulates of waste water samples.<br />

Boron concentration is low in waster water which is cleaned<br />

in SWTP. The limits are not specified by low for boron concentration<br />

in waste water to the water recipient.<br />

In the Danube, water (Komárno – Bratislava) was<br />

determinate to have a natural concentration on the level of<br />

s524<br />

39 µg dm –3 (ref. 6 ) and for river is the level of 20 µg dm –3 in<br />

the river after the biological waste water treatment plant and<br />

20 µg dm –3 in recipient to pulp mill. Boron concentration was<br />

low in lime sludge too. Boron was accumulation in system<br />

and its output was waste water, but boron concentration was<br />

low.<br />

Conclusions<br />

In this work was studied effect of adding boron compound<br />

to recovery line on the water quality.<br />

• Boron is component in very small particulates in waste<br />

water, therefore boron concentration is better without<br />

filtration of samples for boron determination. Boron<br />

concentration is not total in waste water by filtration.<br />

• Boron concentration is low in output - waste water to<br />

river, what corresponding accumulation of boron compounds<br />

in system of pulp mill.<br />

• There was little decreasing of boron concentration after<br />

trial, but boron compounds were in system.<br />

Open question:<br />

• What about deposits in recovery line and pipeline of<br />

waste water?<br />

This work has been supported by Kraft pulp mill.<br />

REFEREnCES<br />

1. Internet: Referat – prvky p1 a p2<br />

<strong>2.</strong> www.chtf.stuba.sk/kach/support/ACh_prednaska06.pdf<br />

3. Richards T., nohlgren I., Warnqvist B., Theliander H.:<br />

nordic Pulp and Paper Research Journal 17(3), 213<br />

(2002).<br />

4. http://sk.wikipedia.org/wiki/B%C3%B3r<br />

5. Safety data sheet for commercial product [borax]<br />

6. www.gabcikovo.gov.sk/vvb/vr2004/priloha%20D/text.<br />

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