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2. ENVIRONMENTAL ChEMISTRy & TEChNOLOGy 2.1. Lectures

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Chem. Listy, 102, s265–s1311 (2008) Environmental Chemistry & Technology<br />

A<br />

B<br />

C<br />

Fig. <strong>2.</strong> Mophology of surface of the zinc ferrite sorbent, A – primary,<br />

b – pasivated, C – biological and chemical regenerised<br />

Conclusions<br />

The presented results confirm the possibility of utilization<br />

of the biological-chemical method as a new regeneration<br />

method of desulphurization sorbents based on zinc ferrite.<br />

The big advantage of this process in comparison with conventional<br />

regeneration methods is the lowering of the temperature<br />

of leaching from 500°C to 30°C. The period of the<br />

duration of the regeneration seems to be an disadvantage, its<br />

lowering requires the additional research aimed at the con-<br />

s417<br />

Table I<br />

Comparison of the selected fysical and chemical charakteristic<br />

of the zinc ferrite sorbents before and after biological and<br />

chemical regeneration<br />

Specific Surfaces<br />

Average of<br />

Sample surface SA factor f *<br />

particles<br />

[m2 g –1 ] d50 [μm]<br />

primary<br />

sorbent<br />

pasivated<br />

sorbent<br />

regenerised<br />

sorbent<br />

<strong>2.</strong>6 1.022 4.77<br />

<strong>2.</strong>8 1.478 9.10<br />

6.2 1.797 <strong>2.</strong>19<br />

tinual optimalization of conditions for biologico-chemical<br />

regeneration.<br />

This work was supported by the Slovak Research and<br />

Development Agency under the contract No. APVV-51-<br />

027705.<br />

REFEREnCES<br />

1. Grindley T., Steinfeld G.: Proceedings. 4 th Annual<br />

Contractor ´s Meeting on Contaminant Control in Hot<br />

Coal-Derived Gas Streams. U. S. Department of Energy/<br />

METC. Morgantown, WV. DOE/ METC, 85-3, pp. 314-<br />

446. Morgantown 1984.<br />

<strong>2.</strong> Krishan G. n.,Tong G. T., Lamoreaux R. H., Brittain R.<br />

D.: Wood B.J.: Proceedings of Fifth Annual Contractor´s<br />

Meeting on Contaminant Contro in Hot Coal-Derived<br />

Gas Streams. U. S. Department of Energy/METC. Morgantown,<br />

WV. DOE/ METC-85/6025, pp. 6-18. Morgantown<br />

1985.<br />

3. Lamoreaux R.M., Brittain R.D., Zieger J., Leach. S.C.:<br />

Determination of Solid Phase Boundaries in Coal Gas<br />

Desulfurization by Zinc Ferrite., U. S. Department of<br />

Energy/METC. Technical Report DOE/MC 21096-219<strong>2.</strong><br />

Morgantown, WV, 1986.<br />

4. Sasaoka E., Hatori M., Sada n., Uddin A.: Ind. Eng.<br />

Chem. Res. 39, 3844 (2000).<br />

5. Buchanan R. E. and Bigons n. E. Bergy´s Manual of<br />

Determinative Bacteriology., 8 th ed., Baltimore, 1974.<br />

6. Wutzer R., Steinike U., Lorenz P., Rossahl,B.: Brennstoff-Wärme-Kraft<br />

45, 477 (1993).<br />

7. Šepelák V., Rogachev Yu., Steinike U., Uecker D. Ch.,<br />

Krumeich F., Wissmann S., Becker K. D.: Brennstoff-<br />

Wärme-Kraft 48, 1996, 28.<br />

8. Barret J., Hughes M. n., Karavajko G. I., Spencer P. A.:<br />

Metal extraction by bacterial oxidation of minerals. Eôis<br />

Horwood, new York, London, Toronto, Sydney, Tokyo,<br />

Singapore, 1996.<br />

9. Baláž P., Kušnierová M., Varencova V. I., Mišura B.: J.<br />

Miner. Process. 40, 273 (1994).

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