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Rudy Folkersma - Domein Applied Science

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Conferentie Onderzoek in <strong>Applied</strong> <strong>Science</strong><br />

7 november 2012, Hanzehogeschool<br />

www.stendenpre.com


Stenden PRE<br />

Polymore Research & Education<br />

Door <strong>Rudy</strong> <strong>Folkersma</strong><br />

www.stendenpre.com


Province of Drenthe<br />

Community of Emmen<br />

SNN (Samenwerkingsverband Noord Nederland)<br />

API Institute (<strong>Applied</strong> Polymer Innovations)<br />

NUON (Emmtec Services)<br />

Stenden University of <strong>Applied</strong> <strong>Science</strong>s<br />

Stenden PRE is part-financed by the European Union, European Regional Development Fund and the Northern Netherlands Provinces (SNN)


www.stendenpre.com<br />

Research<br />

Recycling / Upcycling<br />

Upcycling is the reuse of plastics for higher use applications. This can be done by<br />

removing plastic parts from discarded products, or by processing plastic waste into a<br />

valuable raw material.<br />

Biopolymers<br />

The term biopolymers has two meanings and in practice they often go together.<br />

Polymers of biological origin are often called biopolymers, however polymers that<br />

are biodegradable are also called biopolymers.<br />

Smart Materials<br />

In this topics research and development is performed for smart or sensory<br />

materials. For instance the use of sensor technology in textile applications.<br />

Examples include protective clothings and seatbealts.<br />

Biocomposites<br />

Materials that are made out of natural fibres like hemp, flax, wood etc. and<br />

(bio)polymers.


www.stendenpre.com<br />

Facilities<br />

Stenden University (polymer technology laboratory)<br />

Injection molding, extruders, compounding and<br />

mechanical test laboratory.<br />

Emmtec Services (analytical laboratory)<br />

Analytical equipment for polymer research (e.g. IR, UV,<br />

GPC and DSC).<br />

<strong>Applied</strong> Polymer Innovations Emmen (laboratory for<br />

applied polymer research)<br />

Equipment for determination of physical properties, rheology<br />

and microscopical research. Test instruments for fibre<br />

spinning.


Curriculum Werktuigbouwkunde en Life <strong>Science</strong><br />

• Doorlopende leerlijnen Werktuigbouwkunde en Life <strong>Science</strong> met het Drenthe College.<br />

• Major: materiaalkunde kunststoffen, ontwerp matrijs, projecten, keuzevak, stage en<br />

afstuderen.<br />

• Minoren (15 ec)<br />

• Master (120 ec)<br />

www.stendenpre.com<br />

algemene minor duurzame kunststoffen<br />

onderzoeksminor duurzame kunststoffen<br />

Samen met Windesheim Zwolle (partners RUG, WUR, UT)<br />

Curriculumontwikkeling samen met bedrijven<br />

• Begeleiding promovendi<br />

Onderwijs Stenden PRE


Cumapol energiehuishouding<br />

PEZY recycling / design for disassembly<br />

Morssinkhof energiehuishouding<br />

Tilmar extrusietechnologie en simulatie<br />

Codin duurzame coatings<br />

API Institute dominostenen<br />

HZW recycling (sorteermachine)<br />

OBS Angelso kunstwerk<br />

www.stendenpre.com<br />

Projecten Stenden PRE


Claudia Cluth FHW Moulds GmbH<br />

Gouke Kuipers Fokker<br />

Matthias Mahlmann Tilmar<br />

Michael de Jong Fokker<br />

Patrick Kaspers Tilmar<br />

Richard Trip API Institute<br />

Thomas Schreuder Fokker<br />

Vincent Rolfes DSM<br />

Waldo Bruinsma Fokker<br />

www.stendenpre.com<br />

Afstuderen Stenden PRE


Biocomposieten Daan van Rooijen<br />

3D Printing Gerard Slot / Jan Jager<br />

Additieven Raymond Gommers<br />

Toepassing biopolymeren Alle medewerkers<br />

Spuitgietoptimalisatie promovendus Werner Timans<br />

www.stendenpre.com<br />

Onderzoek Stenden PRE


BIOCOMPOSITES 2.0: ORIENTATION & BIOBASED


NATURAL FABRIC REINFORCED<br />

THERMOPLASTIC LAMINATES


NATHPRO<br />

NATURAL TEXTILES REINFORCED THERMOSET<br />

PROFILES


NATURAL FIBRE HIGH<br />

PERFORMANCE PROFILES<br />

Goals<br />

● Processing natural fibre<br />

using pultrusion proces.<br />

● Replacement of glass fibre,<br />

hardwood, plastic and metal<br />

profiles.<br />

● 20 % cheaper than glass<br />

fibre profiles<br />

● 40 % lower environmentimpact<br />

than glass fibre profiles.


HET PULTRUSIE PROCES


PROCESS RESEARCH PRINCE


Resultaten<br />

● > 40 Gpa buigstijfheid, Hardwood<br />

= 18,6 Gpa<br />

● > 300 Mpa buigsterkte, Hardwood<br />

= 156 Mpa<br />

● Geschikt voor hoogbelaste en<br />

vuurbestendige<br />

constructietoepassingen<br />

● Ten minste 40% Lagere<br />

milieubelasting dan hout


Resultaten<br />

● 25% stijver en 30% lichter dan<br />

glasvezel versterkte profielen<br />

● Goedkoper dan glasvezel<br />

versterkte profielen<br />

● Brandwerend en extreem<br />

weersbestendig (vocht en UV<br />

licht)


VIDEO BRANDTESTJE


Resultaten<br />

WPC FLAX comp Flax/ PF Glass/EP<br />

Known Known Tested Known<br />

● Buig sterkte: 73 MPa 300 MPa 300 MPa 1050 MPa<br />

● Buig stijfheid : 7,2 Gpa 28 GPa 41 GPa 30 Gpa<br />

● Hitte afgifte


Vergelijk BIOCOMPOSIETEN eigenschapen


GEVERFD VURENHOUT EN STAAL VERSUS NATHPRO<br />

Balk van 15 cm x 5 cm x 2 m met 150 kg belasting<br />

met gelijke doorbuiging<br />

F<br />

Vuren hout Staal NATHPRO<br />

● Hoogte 150 mm 50 mm 100 mm<br />

● Wanddikte - 3,6 mm 4,2 mm<br />

● Volume per m 7.50 dm3 0,72 dm3 1,26 dm3<br />

● Gewicht per m 3,23 kg 5,62 kg 2,39 kg<br />

● Geschatte kosten per m in euro 6 - 10 5 - 7 5 - 9<br />

● Eco-impact per m 5,1 Mpt 6,26 Mpt 2,00 Mpt<br />

● GER per m 106 MJ 98,0 MJ 43,6 MJ<br />

● Max. belasting 86 kg 276 kg 482 kg


Vergelijk Biocomposieten: balken en kokers


BAMBOO CONSTRUCTIES


BLINDERINGEN AND JALOUZIEN


BIOMIMICRY FOR BUILDING MATERIALS<br />

• BIOPREG ® a thermoplastic biocomposite reinforced<br />

with natural fabric<br />

• Fully biodegradable anf 100% recyclble<br />

• As stiff as glasfibre composite but two times greener<br />

• 5 times stronger then soft wood C18<br />

• The first high performance biocomposites for<br />

structural applications<br />

• Suitable for outdoor applications<br />

• Resistant to water, chemicals and sunlight (UV)<br />

• Can be cutted, sawed drilled and painted , printed and<br />

glued


Color samples


DESIGN PROPERTIES<br />

• Textiles can be painted and<br />

printed.<br />

• Textures, sheets and foam can be<br />

pressed within one step.<br />

• Thin sheets can be folded and<br />

cutted


Two processes for BIOPREG: filmstacking and mixed textiles


PROPERTIES<br />

• Different polymers are possible: PP<br />

PLA, PET, PA<br />

• Properties are comparable to High<br />

pressure laminate (TRESPA)<br />

• Very robust and impact resistant.


WOOD WORKING HANDLING<br />

• Thickness between 0,15 mm to 150<br />

mm flat and rolled<br />

• Can be glued and painted as wood<br />

products<br />

• Can be cutted, sawed and drilled with<br />

tools for wood<br />

ZWARTZ BIOPREG


PRESS SPECIFICATIONS<br />

• Production series from 10 to 10 million<br />

• Short pressing times : 1-3 minutes<br />

• Vacuum pressing is possible for low<br />

depth shapes<br />

• Maximum deep drawing ratio = 1: 1<br />

ZWARTZ BIOPREG


FOLDING , WELDING<br />

INSERTS AND<br />

EDGE PRESSING


TOOL TO DESIGN THE PERFORMANCES OF BIOPREG SKIN<br />

ASHBY : STRUCTURELE EFFICIENCY VAN SANDWICHES<br />

Price / stiffness en price / strength indices<br />

stiffness (E ) 1/3 strength ( ƒt ) 2/3<br />

M-Eb sandwich = ________ M-Fb sandwich = _________<br />

Costs * density () Costs * density ()<br />

Eco-impact / stifness en Eco-impact / tensile strength indices<br />

stiffness (E ) 1/3 strength ( ƒt ) 2/3<br />

M-Eb sandwich = _________ M-Fb sandwich = _________<br />

Eco-ind m * density () Eco-ind m * density ()


COMPARISON WEIGHT, COSTS AND ENERGY USE 80 MM SANDWICH PANELS WITH<br />

DIFFERENT SKINS


COMPARISON MATERIAL EFFICIENCY ON EQUAL STIFFNESS<br />

Weight reduction: the higher , the better


COMPARISON MATERIAL EFFICIENCY ON EQUAL STIFFNESS<br />

Cost and eco-impact reduction: the higher , the better<br />

PARISON MATERIAL EFFICIENCY ON EQUAL STIFFNESS


FIBRE BOARD AND STEEL VERSUS BIOPREG<br />

Sandwich 8 cm thickness of 1 x 2 m<br />

Equal deflection<br />

F<br />

Fibre board Steel BIOPREG<br />

● Wall thickness 8,0 mm 0,7 mm 1,5 mm<br />

● Volume per m 16,00 dm3 1,40 dm3 3,00 dm3<br />

● Weight per m 10,24 kg 5,49 kg 2,97 kg<br />

● Costs estimate per m2 in euro 6 - 10 6 - 10 10<br />

-15<br />

● Eco-impact per m 7,68 Mpt 70,7 Mpt 1,20 Mpt<br />

● GER per m 202,7 MJ 810,0 MJ 21,4 MJ<br />

● Max. load 850 kg 5.053 kg 3.213 kg


GLAS/PP AND TRESPA VERSUS BIOPREG<br />

Sandwich 8 cm thickness of 1 x 2 m<br />

Equal deflection<br />

F<br />

Glass/PP Volkern BIOPREG<br />

● Wall thickness 0,8 mm 2,3 mm 1,5 mm<br />

● Volume per m 1,60 dm3 4,60 dm3 3,00 dm3<br />

● Weight per m 3,19 kg 6,58 kg 2,97 kg<br />

● Costs estimate per m2 in euro 10 - 15 6 - 10 10<br />

-15<br />

● Eco-impact per m 8,39 Mpt 64,40 Mpt 1,20 Mpt<br />

● GER per m 129,4 MJ 169,4 MJ 21,4 MJ<br />

● Max. load 6.912 kg 3.543 kg 3.212 kg


SUITABLE CORE MATERIALS<br />

1) Fibre insulations mats:<br />

• Sheep wool<br />

• Celluose-insulation<br />

• Flax or hemp mat


2) Foam plates<br />

• Recycled PET foam<br />

commercially available. Not suited for<br />

insulation but for high performance<br />

construction panels and windmill bladed<br />

• Paper foam


• BIO FOAM<br />

Commercially available. Is a foam produced<br />

from PLA granules that can be produced in<br />

different densities. As a blowing agent, CO2<br />

is used. It is Cradle to Cradle certified.<br />

• PLA honeycomb<br />

Commercially available. Is a foam produced<br />

from PLA granules that can be produced in<br />

different densities. As a blowing agent, CO2<br />

is used. It is Cradle to Cradle certified.


3) Other core plates<br />

• End grain Balsa wood<br />

Balsa has a superior compression strength.<br />

Local forming of the sandwich should take<br />

place by milling the balsa core and<br />

subsequently hot pressing of the facing.<br />

• Paper honeycomb<br />

Paper honeycombs are very common in the<br />

furniture industry, like they are applied in the<br />

doors cabinets and closets.<br />

These honeycombs are cheap and come in<br />

many varieties to fit the requirements.<br />

Forming of the sandwich should take place<br />

by milling or cutting out the honeycomb<br />

locally and subsequently the hot pressing of<br />

the facing.


Suitable top foils to improve weather resistancy and fire resistancy<br />

• Geopolymer as binder for woodfibre or for natural fibres<br />

• BIO PA11<br />

- Biobased<br />

- Waterstable<br />

- Extreem weather resistance<br />

- Extreem fire safety<br />

- Biobased castoroil<br />

- Lightness and Density<br />

- Superior Impact Resistance<br />

- High Scratch Resistance at low T<br />

- High Transparency<br />

- Decorability and Design Versatility


TABLE TOP(1999)<br />

Replacement of Trespa


DESIGN FURNITURE<br />

Design furniture<br />

Jute fabric/ Balsa core

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