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Accepted Papers - 3.pdf - UNESCO

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National Seminar on Rainwater Harvesting and Water Management 11-12 Nov. 2006, Nagpur<br />

72. Physico-Chemical Investigation of Waste Water from Electroplating<br />

Industry at Agra and Technologies for Metal Removal<br />

and Recovery of Water<br />

Introduction<br />

Present era of industrialization and<br />

development also brings some fall backs, which<br />

needs immediate attention to overcome their effects<br />

on living beings and the ecosystems. One of these<br />

is release of toxic metals bearing industrial effluents<br />

which has become a primary challenge for last few<br />

decades(Dahiya et al, 2003).These metals can be<br />

introduced in to aquatic system through effluent<br />

discharges from various industrial operations<br />

including mining, chemical manufacture and<br />

electroplating (Gupta et al., 2001) and their<br />

increased concentration in aqueous environment<br />

is capable of causing phytotoxicity,<br />

*Monika Singh *Susan Verghese<br />

Abstract<br />

Industrialization and urbanization have led to discharge of industrial effluents, which<br />

in turn pollute the ecosystem. The disposal of effluents has become a serious technoeconomic<br />

problem particularly due to rising cost of disposal and growing awareness of<br />

pollution hazards. Out of all waste water discharges, effluents from industries such as<br />

electroplating, textiles, oil paints etc pose a threat as these waste water are usually dumped<br />

into natural water resources like river, lakes and make the same unfit for human, plant and<br />

animal consumption as well as for industrial use.<br />

The present paper focuses on the waste water management of effluents from<br />

electroplating industry which is a great water consumer and as a consequence, one of the<br />

biggest producers of liquid effluent. This industry presents one of the most critical industrial<br />

waste problems. Paper deals with the analysis of waste water quality from electroplating<br />

units of Agra city , by determining parameters such as pH by digital pH meter, BOD by<br />

titration method and COD by dichromate reflux method. Heavy metal analysis was done<br />

on an Atomic Absorption Spectrometer (Perkin- Elmer A. Analyst 100). Analysis was done<br />

for a period of one year and highest BOD (118 ppm), COD(424 ppm), certain toxic metals<br />

Ni (27 ppm ) and (24 ppm) concentrations clearly indicate towards the seriousness and<br />

immediate action towards developing methods for reclaiming metals from plating waste<br />

stream. The paper also discusses different membrane technology for recovery of water<br />

and different natural and cheap adsorbents for removal of toxic heavy metals.<br />

bioconcentration and biomagnification by<br />

organisms (Joshi, 2000).<br />

In India there are over 50,000 large, medium<br />

and small electroplating units mostly scattered in<br />

the urban areas (Upadhyay, et al. 1992). Plating<br />

waste water contains heavy metal, oil, grease and<br />

suspended solids at levels that might be considered<br />

hazardous to the environment and could pose risk<br />

to public health. Because of the high toxicity and<br />

corrosiveness of plating waste streams, plating<br />

facilities are required to pretreat waste water prior<br />

to discharge in accordance with national pollutant<br />

discharge elimination system (NPDES) permits as<br />

required by clean water act (CWA).<br />

*School of Chemical Sciences, Department of Chemistry, St John’s College, Agra, India<br />

397

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