0044513 t.v o ^ 7 1 - Hanford Site

Qzmnrerra Incorporated -
13715 RiderTrailNorth
Earth City, Missouri 63045
314 298-8566 Telephone
314 298-8757 Fax
CERTIITCATE OF ANALYSIS
0044513
t.v o ^ 7
1
niuanfe^'ra
H^nmvAal
Sem^
Bechtel Hanford Incorporated ^12 S46e,
P.O. Box 1970 ^
Richland, Washington 99352 "^ ^
OCT l^
September 19, 1995 RED^yEp
Attention: Joan Kessner LOB In
Project number
Dates Received by Lab
Number of Samples
Sample Type
SDG Number
Data Deliverable
I. Introduction
550.93
August 14, 15, and 16, 1995
Eighteen (18)
Water
W0671
Standalone
`^? C2
Between August 14 and 16, 1995, eighteen (18) water,satnples were received by Quanterra,
Richland and transferred to Quanterra, St. Louis for chemical analysis. Upon receipt, the samples
were given the following laboratory ID numbers to correspond with their specific client ID's:
St Louis ID WHC ID Richland ID Matrix Date of Receint
9116-001 BOGFD3 50824001 Water 08/14/95
9116-002 BOGF83 50824003 Water 08/14/95
9116-003 B0GFD4 50824002 Water 08/14/95
9116-004 B00F84 50824004 Water 08/14/95
9123-001 BOGF85 50825101 Water 08/15/95
9123-002 BOGFB9 50825103 Water 08/15/95
9123-003 BOGF99 50825105 Water 08/15/95 y^e
9123-004 BOGF81 50825107 Water 08/15/95 ^a`
9123-005 BOGF86 50825102 Water 08/15/9 ^
9123-006 BOGFCO 50825104 Water 08/15/
9123-007 BOGFBO 50825106 Water 08/15/
9123-008 B0GF82 50825108 Water 08/15/9 a^
9128-001 BOGFDS 50826801 Water 08/16/95 ^9
9128-002 BOGFC1 50826803 Water 08/16/95 ''^g
Cy
J^t^ ^96^a
L-

Bechtel Hanford Incorporated
September 19, 1995
Project Number: 550.93
SDG: W0671
Page 2
^'irianterra
Environmenbl
Services
St Louis ID WHC ID Richland ID Matrix Date of Receint
9128-003 BOGFC3 50826805 Water 08/16/95
9128-004 BOGFD6 50826802 Water 08/16/95
9128-005 BOGFC2 50826804 Water 08/16/95
9128-006 BOGFC4 50826806 Water 08/16/95
II. Analytical Results/ Methodology
The analytical results for this report are presented by analytical test. Each set of data includes
sample identification information, analytical results and the appropriate detection limits.
Analyses requested: Chloride, Fluoride, Nitrite, Nitrate, Phosphate and Sulfate by EPA method
300.0. ICAP Metals by EPA method 6010. Ammonia by EPA method
350.1. NitratefNitrite by EPA method 353.1. Sulfide by EPA method 9030.
III. Quality Control
A Laboratory Control Sample and Method Blank were analyzed with each preparation batch.
Matrix Spike and Matrix Spike Duplicate or Sample Duplicate analyses were performed per the
ptntocolfor each analyte.
IV. Definitions
The following codes are used to denote laboratory quality control samples and can be found in the
data summary section of this report:
QCBLK- Quality Control Blank, Method Blank
QCLCS- Quality Control Laboratory Control Sample, Blank Spike
A

Bechtel Hanford Incorporated
September 19, 1995
Project Number: 550.93
SDG: W0671
Page 3
V. Comments
'iiuanter'ra
Euviw=mad
s^c^
The Matrix Spike Duplicate recovery for Cadmium (73.4%) was less than 75% therefore all
associated data was flagged with an "N".
The Fluoride analysis on sample 9123-001 was run at a two times dilution because of an
interfering peak, which raised the detection limit.
The Nitrite analysis on sample 9123-003 was run at a five times dilution because of
interference, which raised the detection limit.
The Relative Percent Difference could not be calculated because both values were less than the
detection limit for the Fluoride, Chloride, Sulfate, Phosphate, Nitrite and Nitrate analyses on
sample 9116-001.
On sample 9123-001 a Fluoride peak was integrated as a hit but the peak area is less than the
peak area of the lowest calibration standard, hence, it was reported as less than the detection
limit.
The Relative Percent Difference could not be calculated for the Nitrate/Nitrite and Ammonia
analyses due to the values being below the detection limit for sample 9116-001 and it's
duplicate.
3

Bechtel Hanford Incorporated
September 19, 1995
Project Number. 550.93
SDG: W0671
Page 4
Environmen[a1
ServiCes
I certify that this data package is in compliance with the SOW, both technically and for
completeness, for other than the conditions detailed above. Release of the data contained in
this bard copy data package has been authorized by the Laboratory Manager or a designee, as
verified by the following signature.
waue rL. rnce
Project Manager
e: k%p.iee5%at,bydav6hunv,o671.nar
^

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I B0GFB0
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER La7S Sample ID: D9123-007
Level (low/med): LOW Date Received: 08/15/95
% Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7440-22-4
AuTinum
Antimony_
Barium
Beryllium
Cadmium
Calcium
Chromiua
Cobalt
Copper
Iron
Magnesium
Manganese
Nickel
Potassium
Silver
24.6
45.9
59.3
0.50
3.1
38600
42.2
4.3
4.7
48.0
12400
2.6
14.2
5630
2.2
U
U
U
U
_
U
U
_
-
U
U
7440-23-5 Sodium 12000 _
7440-62-2
7440-66-6
Vanadium
Zinc
15.2
20.5
_
Clarity Before:
Clarity After:
FO I - IN
IUI
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
a'$

, I U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFB9
I
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.; WO 71
Matrix ( soil/water): WATER Lab Sample ID: 9123-002
Level ( low/med): LOW Date Received: 08/15/95
% Solids: 0-7
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A uminum 28.8
7440-36-0 Antimony 45.9 U
7440-39-3 Barium 49.2
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U _N
7440-70-2 Calcium
32500 _
7440-47-3 Chromium_ 42.4
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 9.8
7439-89-6 Iron 993 -
7439-95-4 Magnesi.um 5550 -_
7439-96-5 Manganese 8.6
7440-02-0 Nickel 14.2 t^
7440-09-7 Potassium 3750
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 5140
7440-62-2 Vanadiuu 9.8
7440-66-6 Zinc
Clarity Before:
Clarity After:
FORM I - IN
IM
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
;^q

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
% Solids: 0.-0
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGFCO
Contract: 550.93
SAS No.: SDG No.: WO 71
LaF Sample ID: D9123-00
Date Received: 08/15/95
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A uminum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 42.6
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U
7440-70-2 Calcium
30200 _
7440-47-3 Chromium 11.2
7440-48-4 Cobalt 4.3 U
7440-50-8
7439-89-6
Copper
Iron
12.5
31.0
_
_
7439-95-4 Magnesium 5160 _
7439-96-5 Manganese 3.2
7440-02-0 Nickel 14.2 U
7440-09-7 Potasslum 2080 _
7440-22-4 Silver 3.3 _
7440-23-5 Sodium 4550 _
7440-62-2 Vanadium 11.7 _
7440-66-6 Zinc 11.9
Clarity Before:
Clarity After:
IM
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
3,D

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFCI
I
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER ---La'E Sample ID: 9128-002
Level (low/med): LOW Date Received: 08/16/95
% Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No
7429-90-5
7440-36-0
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7440-22-4
7440-23-5
7440-62-2
7440-66-6
Analyte
A uum
Antimony_
Barium
Berylli.um
Cadmium
Calcium
Chromiua
Cobalt -
Copper
Iron
Magnesium
Manganese
Nickel
Potassium
Silver
Sodium
Vanadium
Zinc
IConcentration
Clarity Before:
Clarity After:
FORM I - IN
29.7
45.9
28.8
0.50
3.1
27300
13.8
4.3
4.7
59.1
10600
2.3
14.2
6020
2.2
19000
15.4
34.4
U
U
Q
I N
IM
P
P
P
P
P
P
P
P
P P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846

' ' U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I B0GFC2
Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
a Solids: 0.0
Contract: 550.93
SAS No.: SDG No.:
La5 Sample ID:
Date Received:
W0671
D9128-005
08/16/95
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 AuTm'inum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 29.9
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U
7440-70-2 Calcium
28100 _
7440-47-3 Chromium 9.6
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 4.7 U
7439-89-6 Iron 29.3 _
7439-95-4 Magnesium 10900 _
7439-96-5 Manganese 2.0
7440-02-0 Nickel 14.2 U
7440-09-7 Potass^.um 5560
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 19600 _
7440-62-2 Vanadium 15.2 _
7440-66-6 Zinc 16.5
Clarity Before:
Clarity After:
FORM I - IN
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
3^'

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
B0GFC3
Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
Contract:
SAS No.:
550.93
SDG No.:
L--aF Sample ID:
Date Received:
W0671
9128-003
08/16/95
% Solids: 0-7
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A uminuu 92.8
7440-36-0
7440-39-3
Antimony_ Barium
45.9
39.1
U
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U
7440-70-2 Calcium
29000 _
7440-47-3 Chromium 24.5 _
7440-48-4 Cobalt 4.8
7440-50-8
7439-89-6
Copper_ Iron
4.7
138
U
_
7439-95-4
7439-96-5
Magnesium
Manganese
9710
5.4
_
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 6790 _
7440-22-4 Silver 4.0 _
7440-23-5 Sodium 17500 _
7440-62-2 Vanadium_ 9.4 _
7440-66-6 Zinc ^9.3
Clarity Before:
Clarity After:
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
I _ I
Texture:
Artifacts:
SW-846
33

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGFC4
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
SAS No.: SDG No.:
Lab Sample ID:
W0671
D9128-006
Level (low/med):
o Solids :
LOW
0 .-0
Date Received: 08/16/95
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 Aluminum 34.4
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 38.6
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U _N
7440-70-2 Calcium-
28300 _
7440-47-3 Chromium 18.1
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 4.7 U
7439-89-6 Iron 60.3 _
7439-95-4 Magnesium 9550
7439-96-5 Manganese 1.7 -
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 5890
7440-22-4 Silver 2.2 U
7440-23-5 Sodium- 17300 _
7440-62-2 Vanadium 7.4 _
7440-66-6 Zinc 43.8
Clarity Before:
Clarity After:
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
3`^

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (1ow/med): LOW
% Solids: 0.-0
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
B0GFD3
Contract: 550.93
SAS No.: SDG No.: W0671
Lab Sample ID: 9116-001
Date Received: 08/14/95
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 Zminum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 3.4
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U _N
7440-70-2 Calcium
1940
7440-47-3 Chromium_ 2.8 U
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 4.7 U
7439-89-6 Iron 33.0 _
7439-95-4 Magnesium 291 _
7439-96-5 Manganese 1.8
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 1470
7440-22-4 Silver 2.2 t^
7440-23-5 Sodium 424
7440-62-2 Vanadium_ 3.8 U
7440-66-6 Zinc 29.8
Clarity Before:
Clarity After:
FORM I
IM
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
35

U.S. EPA - CLP
1
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
B0GFD4
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
SAS No.:
--L-`aF
SDG No.:
Sample ID:
W0671
D9116-003
Level (low/med): LOW Date Received: 08/14/95
a Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A uminum 32.6
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 3.7
7440-41-7
7440-43-9
Beryllium
Cadmium
0.50
3.1
U
U _N
7440-70-2 Calcium
2280 _
7440-47-3 Chromium 5.0 _
7440-48-4 Cobalt 4.8
7440-50-8 Copper 4.7 U
7439-89-6 Iron 26.9 _
7439-95-4 Magnesium 420 _
7439-96-5 Manganese 2.1
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 2010
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 501
7440-62-2
7440-66-6
Vanadiuu
Zinc
3.8
24.8
U
Clarity Before:
Clarity After:
FORM I - IN
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
3^

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix ( soil/water): WATER
Level ( low/med): LOW
a Solids: 0-7
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFD5 I
Contract: 550.93
SAS No.: SDG No.: WO 71
Lab Sample ID: 9128-001
Date Received: 08/16/95
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q M
7429-90-5 Aluminum 24.6 U P
7440-36-0
7440-39-3
Antimony_
Barium
45.9
3.5
U P
P
7440-41-7
7440-43-9
7440-70-2
7440-47-3
Berylllum 0.50
Cadmium
3.1
Calcium ---------f330
Chromiua_ 2.8
U P
U _N_ P
P
U P
7440-48-4 Cobalt 4.3 U P
7440-50-8
7439-89-6
Copper_
Iron
4.7
23.5
U
_
P
P
7439-95-4
7439-96-5
Magnesium
Manganese
309
1.4 U
P
P
7440-02-0 Nickel 14.2 U P
7440-09-7 Potasslum 1060 U P
7440-22-4
7440-23-5
Silver
Sodium
2.2
495
U P
P
7440-62-2 Vanadium 3.8 U P
7440-66-6 Zinc 19.4 P
Clarity Before:
Clarity After:
FORM I - IN
Texture:
Artifacts:
SW-846
3'l

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I B0GFD6
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER L Sample ID: D9128-004
Level (1ow/med): LOW Date Received: 08/16/95
Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No.
7429-90-5
7440-36-0
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7440-22-4
7440-23-S
7440-62-2
7440-66-6
Analyte Concentration C
AumTinum 28.2
Antimony_ 45.9 U
Barium 3.7
Beryllium 0.50 U
Cadmium 3.1 U
Calcium 2170
Chromium 2.8 U
Cobalt 4.3 U
Copper 4.7 U
Iron 36.8 _
Magnesium 339
Manganese 1.4 U
Nickel 14.2 U
Potassium 2030 _
Silver 2.6 _
Sodium 791
Vanadium 3.8 U
Zinc 6
Clarity Before:
Clarity After:
FORM I - IN
Q M
P
P
P
N P p
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
3g

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
% Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF81
Contract: 550.93
SAS No.: SDG No.: W0671
Lab Sample ID: 9123-004
Date Received: 08/15/95
(ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C
7429-90-5
7440-36-0
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7440-22-4
7440-23-5
7440-62-2
7440-66-6
Aluminum
Antimony_
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper_
Iron
Magnesium
Manganese
Nickel
Potasslum
Silver
Sodium
Vanadium
Zinc
24.6
45.9
50.6
0.50
3.1
------4--9100
27.8
4.3
17.8
54.2
14800
3.9
14.2
5470
2.2
11200
20.2
18.6
Clarity Before:
Clarity After:
FORM I -
U
U
U
U
_
U
_
_
_
U
U
_
_
Q
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
3Q

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGF82
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER LaE Sample ID: D9123-008
Level (low/med): LOW Date Received: 08/15/95
% Solids: 0.-0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7 2 A uminum 25.4
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 61.3
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U _N
7440-70-2 Calciucn
59400 _
7440-47-3 Chromium 33.6
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 5.1 _
7439-89-6 Iron 47.7 _
7439-95-4 Magnesium 18100 _
7439-96-5 Manganese 3.3
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 6540 _
7440-22-4 Silver 2.3 _
7440-23-5 Sodium 13900 _
7440-62-2 Vanadium 13.9 _
7440-66-6 Zinc 28.5
Clarity Before:
Clarity After:
FORM I - IN
IM
P
P
p
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
Z1 o

I
Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
a Solids: 07U
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF83
Contract: 550.93
SAS No.: SDG No.:
-LaE Sample ID:
W0671
9116-002
Date Received: 08/14/95
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 AuTminum 46.4
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 59.3
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 U
7440-70-2 Calcium-
74500 _
7440-47-3 Chromium 170
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper! 9.6 _
7439-89-6 Iron 98.4
7439-95-4
7439-96-5
Magnesium
Manganese
17300
6.7
_-
_
7440-02-0 Nickel 24.5
7440-09-7 Potass ui 4860
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 11900 _
7440-62-2 Vanadiuu 16.2 _
7440-66-6 Zinc 385
Clarity Before:
Clarity After:
FORM I - IN
IM
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
#l

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
1 B0GF84 I
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER Lab Sample ID: D9116-004
Level (low/med): LOW Date Received: 08/14/95
% Solids: 07-6
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A u 29.6
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 56.1
7440-41-7 Beryll.ium 0.50 U
7440-43-9 Cadmium
3.1 U _N
7440-70-2 Calcium-
70700 _
7440-47-3 Chromium_ 162
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 8.7 _
7439-89-6 Iron 55.9 _
7439-95-4 Magnesium 16600 _
7439-96-5 Manganese 4.8 _
7440-02-0 Nickel 19.0 _
7440-09-7 Potassi.um 6400
7440-22-4 Silver 2.2 U
7440-23-5 Sodium^--- 11200 _
7440-62-2 Vanadium 17.4 _
7440-66-6 Zinc 17.3
Clarity Before:
Clarity After:
FORM I - IN
IM
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
4°Z

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
o Solids: 0^
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGF85
Contract: 550.93
SAS No.: SDG No.: W0671
^b Sample ID: 9123-001
Date Received: 08/15/95
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
AuTinum
Antimony
Barium
Beryllium
Cadmium
Calcium
Chromiua_
24.6
45.9
128
0.50
3.1
111000
47.2
U
U
U
U
_
_N
7440-48-4
7440-50-8
7439-89-6
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7440-22-4
7440-23-5
7440-62-2
7440-66-6
Cobalt
Copper
Iron
Magnesium
Manganese
Nickel
Potassium
Silver
Sodium
Vanadium
Zinc
4.3
14.1
219
24500
12.6
14.2
6480
2.2
12100
20.6
20.4
U
_
_
_
U
U
_
_
Clarity Before:
Clarity After:
M
P
P
p
P
P
P
P
P
P
P
P
P
P
P
P
p
P
P
Texture:
Artifacts:
SW-846
1^3

U.S. EPA - CLP
1
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
Contract:
SAS No.:
550.93
SDG No.:
Lab Sample ID:
Date Received:
B0GF86
W0671
D9123-005
08/15/95
o Solids: 0.-0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No
7429-90-5
7440-36-0
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-95-4
7439-96-5
7440-02-0
7440-09-7
7440-22-4
7440-23-5
7440-62-2
7440-66-6
Analyte
AuTinum
Antimony_
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper=
Iron
Magnesium
Manganese
Nickel
Potassium
Silver
Sodium
IZinc
Concentration Q M
Clarity Before:
Clarity After:
FORM I - IN
24.6
45.9
118
0.50
3.1
104000
43.9
4.3
15.5
144
23000
6.5
14.2
6130
2.2
11300
23.2
20.8
U
N
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
44

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
°s Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF99
Contract: 550.93
SAS No.: SDG No.: W0671
LaE Sample ID: 9123-003
Date Received: 08/15/95
(ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
AuTinum
Antimony
24.6
45.9
U
U
7440-39-3 Barium 50.9
7440-41-7 Beryllium 0.50 U
7440-43-9
7440-70-2
Cadmium
Calcium
3.1
00
U
_
7440-47-3 Chromiua_ 50.6 _
7440-48-4 Cobalt 5.4 _
7440-50-8 Copper_ 9.7 _
7439-89-6 Iron 129 _
7439-95-4 Magnesium 10300 _
7439-96-5 Manganese 5.3
7440-02-0 Nickel 14.2 U
7440-09-7 Potasslum 6260
7440-22-4 Silver 2.2 T^
7440-23-5 Sodium 9760 _
7440-62-2 Vanadium 20.6 _
7440-66-6 Zinc 17.8
Clarity Before:
Clarity After:
FORM I - IN
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
Texture:
Artifacts:
SW-846
+5

Category: Annania EPA 350.1
Method: EPA 350.1
Matrix: LIQUID
Duanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra Blank Sample Prep. Analyses Detection
ID ID AnaLyte CAS Number Name Date Date ResuLt Unit Oual. Limit Dil.
BOGFD3 9116-001 Amnonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFD3 9116-OOIDUP Ammonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFD3 9116-001MS Ammonia 7664-41-7 OCBLK75910-1 08/19/95 08/19/95 78 %REC 1
800F83 9116-002 Ammonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
B00F85 9123-001 Aamonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFB9 9123-002 Amnonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
B00F99 9123-003 Anmonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGF81 9123-004 Amaonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFDS 9128-001 Aanionia 7664-41-7 0C8LK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFCI 9128-002 Aamonia 7664-41-7 QCBLK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFC3 9128-003 Ammonia 7664-41-7 0C8LK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
NA QCBLK75910-1 Anmonia 7664-41-7 QCBLK75910-1 08/19/95 '08/19/95 0.050 MG/L U 0.050 1
NA OCBLK75911-1 Anmonia 7664-41-7 DCBLK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
NA OCLCS75910-1 Amaonia 7664-41-7 QCBLK75910-1 08/19/95 '08/19/95 100 YREC 1
NA QCLCS75911-1 Amnonia 7664-41-7 aCBLK75911-1 08/19/95 08/19/95 96 %REC 1
5,)-

Category: Chloride
Method: EPA 300.0
Matrix: LIQUID
Quanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra elank Sample Prep. Analyses
ID ID Analyte CAS Number Name Date Da t e Result Unit Dual .
Detection
Limit Dil.
BOGFD3 91 16- 00 1 ChLoride 16887-00-6 QCBLK7 914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
BOGFD3 9116-001DUP Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
800F03 9116-001MS Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 108 %REC 5
80GF83 9116-002 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 23.4 MG/L 5.00 25
60GF85 9123-001 chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 46.9 MG/L 5.00 25
BOGF89 9123-002 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 4.87 MG/L 0.20 1
BOGF99 9123-003 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 9.59 MG/L 0.40 2
BOGF81 9123-004 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 14.4 MG/L 2.00 10
BOGFDS 9128-001 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
BOGFC1 9128-002 chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 4.37 MG/L 0.20 1
BOGFC3 9128-003 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 5.13 MG/L 1.00 5
NA QCBLK75914-1 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
NA QCLCS75914-1 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 92 %REC 1
53

Guanterra-Richland
P.O. Box 1970
Richtand, WA 99352
Project: 550.93
Category: Fluoride Sample Date : 08/11/95
Method: EPA 300.0 Receipt Date : 08/14/95
Matrix: LIQUID Report Date : 09/19/95
Client Quanterra BLank Sampte Prep. Analyses Detection
ID ID AnaLyte CAB Number Name Date Date Result Unit QuaL. Limit Dil.
BOGFD3 9116-001 fluoride 16984-48-8 aC81K75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 1
BOGFD3 9116-001DUP FLuoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 1
BOGFD3 9116-001MS Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 110 %REC 1
B0GF83 9116-002 FLuoride 16984-48-8 0CeLK75914-1 08/18/95 08/18/95 0.18 MG/L 0.10 1
BOGF85 9123-001 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 2
BOGFB9 9123-002 Fluoride 16984-48-8 DC8LK75914-1 08/18/95 08/18/95 0.15 MG/L 0.10 1
BOGF99 9123-003 Fluoride 16984-48-8 OC6LK75914-1 08/18/95 08/18/95 0.77 MG/L 0.20 2
BOGF81 9123-004 Fluoride 16984-48-8 OC8LK75914-1 08/18/95 08/18/95 0.19 MG/L 0.10 1
BOGFD5 9128-001 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 1
BOGFCI 9128-002 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.49 MG/L 0.10 1
BOGFC3 9128-003 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.43 MG/L 0.10 1
NA QCBLK75914-1 FLuoride 16984-48-8 OC6LK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 1
NA GCLCS75914-1 fluoride 16984-48-8 oC8LK75914-1 08/18/95 08/18/95 101 %REC 1
_
54

Ouanterra-Richtand
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Category: SuLfate
Sample Date : 08/11/95
Method: EPA 300.0 Receipt Date : 08/14/95
Matrix: LIOUID Report Date : 09/19/95
Client Quanterra Blank SampLe Prep. Analyses Detection
ID ID Analyte CAS Number Name Date Date Result Unit Oual. Limit Dil.
800F03 9 1 16-00 1 Sulfate 14808-79-8 OCB1K75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFD3 9116-001DUP Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFD3 9116-OO1M5 SuLfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 100 Y.REC 5
BOGF83 9116-002 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 113 MG/L 12.5 25
B0GF85 9123-001 Sulfate 14808-79-8 OC8LK75914-1 08/18/95 08/18/95 212 MG/L 12.5 25
BOGF89 9123-002 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 29.8 MG/L 2.50 5
BOGF99 9123-003 Sulfate 14808-79-8 OC3LK75914-1 08/18/95 08/18/95 55.1 MG/L 2.50 5
BOGF81 9123-004 Sulfate 14808-79-8 0C81K75914-1 08/18/95 08/18/95 99.6 MG/L 5.00 10
BOGFD5 9128-001 Sulfate 14808-79-8 0CBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFCI 9128-002 Sulfate 14808-79-8 OCBLK75914-1 08/18/95 08/18/95 30.5 MG/L 2.50 5
BOGFC3 9128-003 Sulfate 14808-79-8 0CB1K75914-1 08/18/95 08/18/95 34.2 MG/L 2.50 5
NA 0CBLK75914-1 SuLfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
NA OCLC575914-1 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 91 Y.REC 1
-55

Category: Nitrate/Nitrite
Method: EPA 353.1
Matrix: LIQUID
Guanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sampte Date : 08/11/95
Receipt Date : 08/14/95
Report Date 09/19/95
Client Quanterra Blank Sampte Prep. Analyses Detection
ID ID Anatyte CAB Number New Date Date ResuLt Unit Dual. Limit DiL.
BOGFD3 9116-001 Nitrate/Nitrite C-D05 QCBLK75912-1 08/19/95 08/19/95 0.050 MG/L U 0.0 5 0 1
BOGFD3 9116-001DUP Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFD3 9116-001MS Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 100 %REC 1
BOGF83 9116-002 Nitrate/Nitrite C-005 OCB1K75912-1 08/19/95 08/19/95 13.5 MG/L 1.00 20
B00F85 9123-001 Nitrate/Nitrite C-005 0CB1K75912-1 08/19/95 08/19/95 21.3 MG/L 2.50 50
BOGF89 9123-002 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 2.08 MG/L 0.50 10
B0GF99 9123-003 Nitrate/Nitrite C-005 GCB1K75912-1 08/19/95 08/19/95 3.24 MG/L 0.50 10
BOGF81 9123-004 Nitrate/Nitrite C-005 GCB1K75912-1 08/19/95 08/19/95 7.73 MG/L 1.00 20
BOGFDS 9128-001 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
B0GFC1 9128-002 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 2.11 MG/L 0.50 10
BOGFC3 9128-003 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 1.42 Ma/L 0.25 5
NA QCBLK75912-1 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
NA QCLCS75912-1 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 93 Y.REC 1
.g^^

Category: Sulfide EPA 9030
Method: EPA 9030
Matrix: LIQUID
auanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra Blank Sample Prep. Analyses Detection
ID ID Analyte CAS Number Name Date Date Result Unit Oual. Limit Oil.
BOGFD3 9116-001 SuLfide 18496-25-8 oCBLK75515-1 08116/9 5 08/16/95 0.45 MG/L 0.38 1
800FD3 9116-001DUP Sulfide 18496-25-8 0C8LK75515-1 08/16/95 08/16/95 0.41 MG/L 0.39 1
BOGFD3 9116-001145 Sulfide 18496-25-8 0C8LK75515-1 08/16/95 08/16/95 102 Y.REC 1
B00F83 9116-002 Sulfide 18496-25-8 OC8LK75515-1 08/16/95 08/16/95 0.43 MG/L 0.39 1
B00F85 9123-001 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.71 MG/L 0.39 1
BOGFB9 9123-002 sulfide 18496-25-8 0CBLK75787-1 08/18/95 08/18/95 0.80 MG/L 0.39 1
806F99 9123-003 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.86 MG/L 0.40 1
800F81 9123-004 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.73 MG/L 0.40 1
BOGFD5 9128-001 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.51 MG/L 0.40 1
BOGFCI 9128-002 Sulfide 18496-25-8 OC8LK75787-1 08/18/95 08/18/95 0.56 MG/L 0.40 1
BOGFC3 9128-003 SuLfide 18496-25-8 OC8LK75787-1 08/18/95 08/18/95 0.47 MG/L 0.40 1
NA GCBLK75515-1 SuLfide 18496-25-8 0CB1K75515-1 08/16/95 08/16/95 1.00 MG/L U 1.00 1
NA QCBLK75787-1 sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 1.00 MG/L U 1.00 1
NA 0C1CS75515-1 sulfide 18496-25-8 OCBLK75515-1 08/16/95 08/16/95 91 %REC 1
NA OCLC575787-1 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 91 %REC 1
,< I

Quanterra-Richtand
P.O. Box 1970
Richtand, WA 99352
Project: 550.93
Category: Nitrate Sampte Date : 08/11/95
Method: EPA 300.0 Receipt Date : 08/14/95
Matrix: LIQUID Report Date : 09/19/95
CLient Quanterra Btank Sample Prep. Analyses Detection
ID ID AnaLyte CAB Number Name Date Date Result Unit QuaL. Limit DiL.
BOGFD3 9116-001 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFD3 9116-001DUP Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
B0GFD3 9116-001MS Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 104 Y.REC 5
BOGF83 9116-002 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 14.6 MG/L 0.50 25
BOGF85 9123-001 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 21.6 MG/L 0.50 25
BOGFB9 9123-002 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 1.90 MG/L 0.10 5
BOGF99 9123-003 Nitrate 14797-55-8 QC6LK75914-1 08/18/95 08/18/95 234 MG/L 10.0 500
80GF81 9123-004 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 7.63 MG/L 0.20 10
BOGF05 9128-001 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFC1 9128-002 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 2.01 MG/L 0.10 5
BOGFC3 9128-003 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 1.32 MG/L 0.10 5
NA QC81K75914-1 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
NA OCLCS75914-1 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 100 Y.REC 1
53

Quanterra-RichLand
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Category: Nitrite Sample Date : 08/11/95
Method: EPA 300.0 Receipt Date : 08/14/95
Matrix: LIQUID Report Date : 09/19/95
Client Quanterra Blank Sample Prep. Analyses Detection
ID ID Analyte CAS Number Name Date Date Result Unit Qual. Limit Dil.
BOGFD3 91 1 6-001 Nitrite 14797-65-0 QC8LK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFD3 9116-001DUP Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFD3 9116-001145 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 101 %REC 5
B0GF83 9116-002 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
B00F85 9123-001 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGF89 9123-002 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGF99 9123-003 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 5
BOGF81 9123-004 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFDS 9128-001 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
B0GFC1 9128-002 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFC3 9128-003 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
NA GCBLK75914-1 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
NA QC1C575914-1 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 99 7.REC 1
d I

Ouanterra-Richland
P.O. Box 1970
Richtand, WA 99352
Project: 550.93
Category: Orthophosphete Sample Date : 08/11/95
Method: EPA 300.0 Receipt Date : 08/14/95
Matrix: LIQUID Report Date : 09/19/95
Client Quanterra Blank Sample Prep. AnaLyses Detection
ID ID AnaLyte CAS Number Name Date Date Result Unit Ouat. Limit Dil.
BOGFD3 9116-001 Ortho-Phosphate 14265-44-2 0C13LK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
80GFD3 9116-001DUP Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFD3 9116-001M5 Ortho-Phosphate 14265-44-2 OC8LK75914-1 08/18/95 08/18/95 111 %REC 1
BOGF83 9116-002 Ortho-Phosphate 14265-44-2 OCBLk75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGF85 9123-001 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFB9 9123-002 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGF99 9123-003 Ortho-Phosphate 14265-44-2 DCB1K75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGF81 9123-004 Ortho-Phosphate 14265-44-2 OCB1K75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFDS 9128-001 Ortho-Phosphate 14265-44-2 0CB1K75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFCI 9128-002 Ortho-Phosphate 14265-44-2 OC8LK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFC3 9128-003 Ortho-Phosphate 14265-44-2 0C8LK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
NA QCBLK75914-1 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
NA OCLCS75914-1 ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 94 Y.REC 1
^O

Analyst ^^+ t^Rf3P
Project No.: ^5. h
Reviewed by: p " p
LAti ID
mmmm^
STANDARD
ID
RAW
VALUE
x
DILUTION =
SAMPLE
VOLUME
(L or g)
=
Quanterra
St. Louis Laboratory
AMMONIA-N REPORT
Pg. of
at)
Batch No.:
jzs-i/O
AMMONIA-N
x
EXTRACT
VOLUME
(L)
FRACTION
SOLID
AMMONIA-N
FINAL
C TRATION
(uglL) uglg)
w o yld^, I•S SJ2. 3 Z Z10
00 2 ,$^
Ob} oo 721•L1
oz,3 1 . Sl Z
7\
0AJ } c
0^ -10.21 cSp,Q
,594 c5J.v
0^3 -

Analyst Sk-..r.v. Ts"
Project No.: m s),O-
Reviewed by:
LAB ID
STANDARD
ID
RAW
VALUE
"
DILUTION =
SAMPLE
VOLUME
(L or g)
°
Quantarra
St. Louix Laboratory
AMMONIA-N REPORT
Pg. ~L of Z
Batch No.:
15-510
AMMONIA-N
x
EXTRACT
VOLUME
(L) :
FRACTION
SOLID
=
AMMONIA-N
FINAL
CO TRATION
a i ^lag^g)
-l..tk^ sSb.u
z
?,ep LLIz: o£r-1S • 5J'
Analysis Date:
Method No.:^_ -
Date: 6''--)3 -0 5
•ti
RECOVERY RPD

Analyst S4ce., 2ApAg
ProjectNo.:
Reviewed by: R -
.S'b.^r3 J^5,135
0#^ ^-a.OV^
Batch No.:
LAB ID
STANDARD
ID
RAW
VALUE
x
DILUTION =
SAMPLE
VOLUME
(L or g)
-
Quanterra
St. Louis Laboratory
AMMONIA-N REPORT
Pg. I_ of ?-
^^1 j (
AMMONIA-N
x
EXTRACT
VOLUME
(L) -
FRACTION
SOLID
°
AMMONIA-N
FINAL
CO RATION
^g^ g^g)
4sid• -^ ^ < Sb.Ti
rc^ 5r- 4wt-SS .S y82. clli
41bb-pJ cj)J, jM
o^^w
a^iru
t
Aw4ilM
9m.
-??.
3^.1
4
S^?
3
^ Z2y3
sw.
22y
0o tt. S
y ,S
00 -I.Alp
oto 312.5
qyj. 9y8
-^ .^3
9143^^1 -9 `tl3
_tt. 53
^-.
2f^0
'-/Eo
3iZ
^ JD.O
?,pp +^k ob-^ti^9,,_
Analysis Date: J)-6 - fi
Method No.: 3s0.1
Date: 8-2 3 - 45
•,L
RECOVERY RPD

A; dlyst:
Project No.: .t)z SJ2 •53 615.13S Batch No.:
Reviewed by: 064__^
LAB ID
STANDARD
ID
RAW
VALUE
x
DILUTION =
SAMPLE
VOLUME
(L or g)
=
Quanterra
St. Louis Laboratory
AMMONIA-N REPORT
Pg. Z_ of Z
q.^/l
AMMONIA -N
x
EXTRACT
VOLUME
(L) =
FRACTION
SOLID
=
AMMONIA-N
FINAL
COWX,MTRATION
u ug/g)
1^13-^^r^5 • a' 3^.8 383
/4L•a^l 3 , ^ ^^
Analysis Date:05'iy'^
Method No.: 'W^). - -
Date: +s-13'9?
7m
RECOVERY PD
^IA/ 33.L3 ^ SZI.J y ,
b®t,A3 ^1ta5S^iS ^IZ3,3 ^ 23 ^S
4143-'auZ -ll S3 'JU
^12^17CRh V1J4- bL Ccd0.AA10J AvwAL J4MQq- C^^^Gl'M^l4"E'K+'^ J X.l^1.1 1•^l ^xIlP1 I.M.^.
^ p Ot PV1Dr nM. n
_

^
^1
f
N
Y
t
^
„
n
i3
'Y
u
u
Project #: 5.3-b• 93, Zcl.o1 s^'If.O-'1i
Analyn: 5
Reviewsd By: -
Ravlewed BY: -! 2 - S
_. O
QUANTERRA ST. LOUIS
ANIONS BY I.C.
up/p up/L^
t.b.l. nn.t
Prep Date: ^S' / 3 •• ^ ) +
Analysis Deta: Ol^-( • ^1
Loop Used:
BatchN:
Method N: 300.0
Standard Sample ID Standard Solid DB. FI Cl SO4 NOyN OPO, NOyN Sr
Valw ID Fract.
QCdLk f f^/ ^ 40.10o

^ -6-'
if
^
M
u
v
..f
^
a
U
s.
Pro!.Mr: s .93 u2•o1 iiP•a"L
Analyst:
R.vlaw.d By:
R.vi.w.d By: - 1-4
PaO•?-of Z-
Standard
Va6ue
Sampfa ID Standard
ID
Solid
Fract-
OUANTERRA ST. LOUIS
ANIONS BY I.C.
up1p ug mplL
( c(rcle one
Prep Date: OE- /8' c1 J "
Analysis Date: &Y- 1 Y -
Loop Used: JD,.^-
BatchN: 201Y
Method X: 30O.J
D'd. FI Cl SO, NOeN OPO, NOt-N Br
9133-OO2 uif r'y " /.Oy l33 - - ^ -
9136-301 u io:a" V
G34 282 /o ^ - -
-aolai 1r /.30 Zg2 /0^ -- -- -
uw:ry -^IMS Al.Ybbo•9 u^ sa,w
3,V" Z 9 (23 - - - -
- oot
ci sr u ro" r O. ^ Zo^ 321 - - - _
-003
FI t $•y
0 33-(. 34-L( - - - -
-^ C( -L^^,P 't6.R 59 t
-^f
u so / Y*4 283 - _ - -
-006 ^1; ^ r^ lO. I /2Z 1?AO - - - -
-oo^,
ci io ra, z O.^`i8 31• Lf 36.1 - - - -
-oOb^ ^c ^ s-" so'
I L.IO 9.1 -4 /S}o - - - -
'
-aoq
F1 ^ 1,
'i•19 40.1 5q.g
62CaUC^f91 -'O.lOo G O.'(AO

S
>
7
^
Quanterra
St. Louis Laboratory
NITRATE/NITRITE-N REPORT
Pg. I of Z
Analyst: S1eve^ 1 Pk
Project No.: ^.SY -= Batch No.: t Z
Reviewed by: IQ QQzUU a_Gv^
LAB ID
STANDARD
ID
RAW
VALUE x DILUTION +
SAMPLE
VOLUME
(L or g) =
NITRATEI
NITRITE x
EXTRACT
VOLUME
(L) :
FRACTION
SOLID =
prep
FINAL
CO ENTRATION
ug1L -(uglg)-N
QQM-in/2- 1 N,2y ^ So.o
^Z- A^.47+8•9S Zla:S:- S"ZtO ,3
-Z^ol ^1.2 SU 3390o
o^ 2. SO S/^0
oaS 5^1.^ Sa 970U
00^ bUZ. ZO /Z$JU
0 4 -1 4-ss
Analysis Date:
Method No.: 3S3. I
Date: 8,3r'
S8•2- Zo 13Z60
410.3 t0 yZ/p
y29.-7 y30
a^3 381.4 2-D 1to30
a^l 389.Z to 385o
91)(2-aal Lr it sA),o
OD 14DP /4.
jMs t.N^A•5j S S.3 S^s ioQ,
aa 2. (a-4S'. 20 13 5'Wz^
qiu-o)t zS.B so z/3k)0
aat 2.01- i O 20^
0,43 323.S l0 3240
304 38t,. Z^ ^^30
9^L11-oo) 20.2fC ^SO.J
)r KrU 0a4% noT x Cculc,Aaie.J S,nct 5t..,plt 0 Wy.,r 44 .( G.#, I•M•!
•/.
RECOVERY RPD

^ oa
Quanterra
St. Louis Laboratory
NITRATE/NITRITE-N REPORT
Pg. _
Analyst:
Project No.: W3 Batch No.:
Reviewed by: 0- -m
LAB ID
STANDARD
ID
RAW
VALUE x DILUTION :
SAMPLE
VOLUME
( L or g) =
Z of Z
gs`rIZ
NITRATEI
NITRITE x
EXTRACT
VOLUME
(L) =
FRACTION
SOLID =
9121'c-ooZ 211•Z I^ Z1!0
^03 z83.`1, S 14Z3
FINAL
C NTRATION
(uglL)-N uglg)-N
Zxk. ^ t5 si-
AnarysisDate: C& -6'5,3 _
Method No ^3..^-
Date: tY ^/
Y.
RECOVERY RPD

PREP DATE: 0?- / 6.- G!r
ANALYSIS DATE: 0 ^ - ^
ANALYST: TF
BATCH NO.: '45'5'15r
Lab I.D.
LPO}19-9f
Sample
Volume
Imi r g)
Actual
Volume
T'itrated
Quanterra
St. Louis Laboratory
SULFIDES
Solid
Fraction
IODINE
ml of
Iodine
REVIEWED BY: 9.Pav^:,#Orit3'30'4
PROJECT NO.: Sa3•oSid. 93
METHOD NO.: 3"}6.1. 9030
Buret Reading
ml of NazS2O3
Final Initial Net
Sulfide
nc.
(m8 gig)
2oo 2,x0 l0 q.SS 0 9.f8

)
PREP DATE: 'CFS'IEs-SS
ANALYSIS DATE: OS-1 -SJ
ANALYST: S
BATCH NO.:
Lab I.D.
Sample
A l^ ume
'C^TM^r e)
Actual
Volume
Titrated
Quanterra
St. Louis Laboratory
SULFIDES
Solid
Fraction
IODINE
ml of
Iodine
REVIEWED BY: R, Nzau,ayy^ q-1
PROJECT NO.: SJ^I-
METHOD NO.: 9J3^
Buret Reading
ml of Na2S203
Final Initial Net
Sulfide
nc.
m9/L g/g)
^^S^.^s3•I Z^ Z°` ) O 9.3) ^ 9 31

Account: 10722 OAS No. 1021 Rev. 0
Rester Sartple Login: 9116
Prolect NanaBer. H. Price - - "^ '
Draft; {Het; Enf4Ca9erdRevieked(?yi PN Revjew;^
Saaple Header Teaplate:
Sampte No.
ComnaDts
A' Container Type
Data:
C4jent jP. C Metrix Date Collected - Receivaq Due Shipper Rad C4tegory Rad Sample No.
Analyais Class Preservative Anal. Due Date Nold Date Site ( Container Numbers:X Filled)
9116-001 BOGFD3 1later 11 AfW-95 11 , 35 14-AUG-95 10:00 18-SEP-95 FED-EN 1 Screening not Required
` RICHLAN4.).4. S08744D1 . .- , - - ,. .... -.. : . .. _ . -
1 AN ? ANl)er OlaBS-5Q0iAl AN10NS/300.0/94 P COLD N/A N/A T138 ( 173879:99)
1 CL/300.0/04 C COLD 11-SEP-95 08-SEP-95 T138 ( 173879:99)
FL/300.0/04 C COLD 11-SEP-95 08-SEP-95 1138 (173879:99)
1 ICAP/6010/44 S 111103 11-SEP-95 07-FEB-96 T13B (173878:100)
1 1102/300.0/04 C COLD 11-SEP-95 13-AUG-95 T138 (173879:99)
1 N03/300.0/04 C COLD 11-SEP-95 13-AUG-95 T13B ( 173879:99)
1 OPNOS/300.0/D4 C COLD 11-SEP-95 13-AUG-95 T138 ( 173879:99)
S04/300.0/04 C COLD 11-SEP-95 08-SEP-95 T13B (173879:99)
3 PN PiqStirlL , : : S/9030/04I S NADH 11-SEP-95 18-AUG-95 1138 (176882:100 173883:99 173084:98)
I PW ^ plestlSd.O^I >NN3/350:1/44 $ . H2SO4
:11-SEP-95 OB•SEP=9S 1138 (173BB0;100)"
1 "M03/353.1%D4 S H2SO4 11-SEP-95 08-SEP-95 1138 ( 173881:99)
9116 001pUp :" BOGFR3 .- - - Wotpr - i) AUG-9$ 11 35 147AUG 95 1Q;00 JS-SEP-95 FED-EX ; 1-
Screening It Required
; "
: .
^
.
1 AN - Am6er 6lass4-500n1t-_:. - . :ANIONS/N0.0/04 p COLR _ N/A N/A T138 ( 173879:99)
1 CL/300.0%D4 C COLD 11-SEP-95 OB-SEP-95 T13B (173879:99)
1 FL/300.0/04 C COLD 11-SEP-95 08-SEP-95 T13B (173879:99)
1 1102/300.0/04 C COLD 11-SEP-95 13-AUG-95 T138 ( 173879:99)
1 1103/300.0/04 C COLD 11-SEP-95 13-AUG-95 T138 ( 173879:99)
1 OPHOS/300.0/D4 C COLD 11-SEP-95 13-AUG-95 T13B (173879:99)
504/300.0/G4 C COLD 11-SEP-95 08-SEP-95 T138 (173879:99)
3 PN,- Piesticl4-": -:S/4070/Q4;- S. NAQH 11•SEP•95 18-AUG•95 T138 (17b882:100 173881;99 173884:98)
1 PN pleaNr.S40opl :xN3/350.1/D4 : $ A2SO4. 11rSEP•95 08-SEP•95 1130 ( 173880:100I'
N03/353.1/04 5 H2SO4 11-SEP-95 08-SEP-95 T13B (173881:99)
9116-001MS ;-"BQG03
t{ntar,-
^1 AUG•95 11.35 14-AUG 95 10;OD 18•SEP-95 FER-€K = J
" Screening ...,. ^ Not Rpquir?d
` - RtONLANR I R .50824D01 ; .. : : ... : : .:
. .^:,; ..-
-. .
. :
" .. . . ,
.
I AN • Amber Olass-50!a6-- !AN10NS7S00.0/04 :P . COL4 : N"/A... N/A T138 (173879:99)
CL/300.0%R4 C COLD 11-SEP-95 08-SEP-95 i13B (173879:99)
1 FL/300.0/04 C COLD 11-SEP-95 08-SEP-95 T13B (175879:99)
1 ICAP/6010/04 S 11110.3 11-SEP-95 07-FEB-96 T138 (173878:100)
1 11t12/300.0/04 C COLD 11-SEP-95 13-AUG-95 T13B ( 173879:99)
l 1103/300.0/04 C COLD 11-SEP•95 13-AUG-95 1138 (173879:99)
C 1 OPIIOS/300.0/04 C COLD 11-SEP-95 13-AUG-95 T13B ( 173879:99)
4= 1 S04/300.0/04 C COLD 11-SEP-95 08-SEP-95 T138 ( 173879:99)
C? 3 PN:- Plasttcr7L 5/9030/441- S . NAOH 11-SEP-95 - 18-AllG•95 T138 ( 175882 100 173883:99 173884:98)
p 1 PN:- plestic-S00m1 02SO4- - :: lt•SEP-95- . 08:SEP•95 T138 (173880.100>
a, 1103/353.1/04 S H2SO4 11•SEP-95 08-SEP-95 T138 (173881:99)
^ 3*=Sa^mple has not been red screened.
Page 1

O
Q O
O
O
Pro)ecS Naneegr. - ir. ^rice
Draft; F1nai,• Entgre9 ml,Rev(CNed
Sample Header Template:
saaQle No,
Coirments
k Cantainer Type
Data;
ouarrterra August IS , 1995 11:44 am
Account: 10722 Project; 550.93 Guanterra-Richland OAS No. 1021 Rev. 0
xester Semple Login: 9116
C4ient 19 C-Natrix ., 0?tE: C911ec1?d Received Due Shipper Rad Cgtegory Red Senple No.
9116-OQINSD . 80¢FD3. Water
RICHLANO 1 I?,50824D01 - --
i AN - Aaber Glaes-500m1 ) CAP/60Q/94
9116-002 B0DF83 . Netpr ...
RICNLAND i,D,.50824003^
t
1
1
1
AN - Am1xr 6lees-50e1 AN(DNS7300.0/94
cL/300.0/04
FL/300.0/04
ICAP/6010/G4
N02/300.0/04
1
N03/300.0/04
1 DPNDS/300.0/G4
1
3
t
I
PN - _ Plestic-i4
PR:- Ptpatia-S00m1::^
S04/300.0/04
5/9030/44::
Ny3/350a/p4
1103/353.1/04
9116+003 - _ BOGFD4 N+tar
BICNLIINO I.P: $OQ24092. .
i AN Amber G4ae4-5OOmL. i¢APD/6q10/Q4-_.
9116.004 .
80GF84 -
Water
' RICHI,AND i.P.. 5^24004 ? ..- " '
t AN.- Am4er Gless-50up1 )cAPo(b0tq/44
O 3*=Saaple Was not been red screened.
PA
Analysis Class Preservative Anal. Due Date Hold Date Site (Container Numbers:X Filled)
91-AUG-95 11:35 14-AUG-95 19:00 18-SEP-95 FEP-EX
$ NN03 it-SEP•95 07-FEB-96 T138
11-AUG-95 12:38 14-AUG-95 10:00 18-SEP-95 FED-EX
P. FALO N/A N/A T130
C •COLD 11-SEP-95 08-SEP-95 1138
C COLD 11-SEP-95 08-SEP-95 T138
S 111(03 11-SEP-95 07-FES-96 T138
C COLD 11-SEP-95 13-AUG-95 T13B
C COLD 11-SEP-95 13-AUG-95 7138
C COLD 11-SEP-95 13-AUG-95 T138
C COLD 11-SEP-95 08-SEP-95 T138
S NAOH 11-SEP-95 10•AUG-95 7130
& , tA2504 11-SEP-95 08-SEP-95 T130
S H2SO4 11-SEP-95 08-SEP-95 T138
11,AUG-95 11p35 14-AUG-95 10:00 18-SEP-95 FEO-EX 1
S 003 11-SEP-95 07-FEB-96 T138
i1-AUG-95 12:38 14-AUG-95 10:00 18-SEP-95 PED-EX
S HRG3 - 11-SEP-95 07-fE9-96 T130
Page 2
(173878:100)
Screening not Required
Screening not Required
(173886:99)
(173886:99)
(173886:99)
(173885:100)
(173886:99)
(173886:99)
(173886:99)
(173886:99)
(173889:100 173890:99 173891:98)
(173887:100)
(173888:99)
(173892:100)
Screening not ReqU(red
Screening not Required
(173099:100) 1

L figur® 1
SAMPLE CHECK-IN LIST
it hr iweq Gmrrt
Date/Time Received Client Name 3H ^
Pro ject/Client 1 Batch or Case t
Coo ler ID (if noted on outside of cooler) S^^ ^ SC ?
1. Condition of shipping container?
2. Custody Seals an cooler intact? Yes No []
3. Custody Seals dated and signed? Yes No []
WHC-SOY-93-0003
Revision 4
4. Chain of Custody record is taped an inside of coaler lid? Yes [] No [x
5. Vermiculite/packing material Is: Wet Dry [] -
6. Each sample is in a plastic bag? Yes [] No
7: Number of sample containers in cooler: 3 y
6. Samples have: tape _ hazard labels
^ custody seals _ appropriate sample
labels
9. Samples are: ^ in good condition ! leaking
_ broken _ have air bubbles
_ other
10. Coolant Present? Yes [^] No [] Sample Temperature
11. The following paperwork should be accounted for (N/A if not applicable):
Chain of Custody i(s) ^144
Request for Analysis r(s) I
Airbill I Carrier
12. Have any anomalies been identified above? Yes [] No kC]
13. Memos have been Initiated for all anomalies identified above? Yes []
Printed Name/Signature - F%• ^ Date/Time i^o
33
000Q017

Pralect Matwger: H. Prlcg
Draft: _ final: Entereq and. Revieued py;
Sample Header Template:
Sample No. _
CortmentS
X Container 7ype
Date:
Client ..,. ID --
Quanterra August 16, 1 5 12:28 pn
Account: 10722 Project; 550.93 Quanterra-Richland QAS No. 1021 Rev. 0
Naster Sample Login: ?123
:--^ - .._C-N®trix
_..:.. -__ .
Analyais
Dateg -Collfctedgeceived Dye Shipper
: , ._ _ , ...._ .
Class Preservative Ana(. Due Date Hold Date Site
Rad Category Red $Paple No.
_ ,
(Container Nurbers:% Fitted) '
9123-001 BDOF95 - -Water
14-AUG-9S 12:21 15-AUG-95 09:20 19-SEP-95 FED-E% i Screenin® not Required
RICHI,AND 1.4, 5492.5101 - - -
- ^ ' ^
I AN Amber Glass-500m1 - 'ANIONS/300.0/q4 P COLD N/A N/A T11C (174068:99)
1 CL/300.0/Q4 C COLD 12-SEP-95 11-SEP-95 TIIC ( 174068:99)
FL/300.0/04 C COLD 12-SEP-95 11-SEP-95 T11C ( 174068:99)
1 ICAP/6010/44 S HN03 12-SEP-95 10-FEB-96 111C ( 174067:100)
1 1102/300.0/04 C COLD 12-SEP-95 16-AUG-95 T11C (174068:99)
1 N03/300.0/04 C COLD 12-SEP-95 16-AUG-95 T11C ( 174068:99)
1 OPHOS/300.0/04 C COLD 12-SEP-95 16-AUG-95 T11C (174068:99)
1 1 504/300.0/04 C COLD 12-SEP-95 11-SEP-95 T11C (174068:99)
3 PN - PI4Stic-tl S/9030/Q4': S XAOH 12-SEP•95 21-AUG-95 T11C (174071:100 174072c99 174073:98)
I PN - Plestio-500@t -. ^ N43/350:1/Q4 S 82504 - 12-SEP-95 11cSEP-95 T11C (174069;100)
1103/353.1/04 S H2SO4 12-SEP-95 11-SEP-95 T11C ( 174070:99)
9123-002 •. BOGF09 Waterv 14 •HUG-95 10:15 15-AUG-95 09:20 19-SEP-95 PED-EX 1 Screening not Requjred.
RICHLANp I.Di.30825103 . .. . . . a,.".; • :.. :- . . . - - -- -
1 AN - AmheP GlaSs-SOOmL ANIONS/300.0/Q4 P COLD N/A N/A T11C (174075:99)
CL/300.0/04 C COLD 12-SEP-95 11-SEP-95 T11C ( 174075:99)
1 FL/300.0/04 C COLD 12-SEP-95 11-SEP-95 T11C (174075:99)
ICAP/6010/Q4 S HN03 12-SEP-95 10-FEB-96 T11C (174074:100)
1 1102/300.0/04 C COLD 12-SEP-95 16-AUG-95 111C (174075:99)
1 1103/300.0/04 C COLD 12-SEP-95 16-AUG-95 T11C ( 174075:99)
1 OPHOS/300.0/Q4 C COLD 12-SEP-95 16-AUG-95 T11C (174075:99)
S04/300.0/04 C COLD 12-SEP-95 11-SEP-95 T11C ( 174075:99)
3 PN - Plastic-l4 . - : S/9030/941 S NAO.@ . , 121EP•95 21-AUG-95 i11C (174078 : 100 174079 99 174080:98)
1 PN - Plastiq-500p1C ..:- NN3/350 1/Q4 -:= S H2504^ . 12-SEP-95 11-SEP-95 T11C ( 174076;100)'--- - - - -
1 N03/353.1/Q4 S H2SO4 12-SEP-95 11-SEP-95 T11C ( 174077:99)
91237003 ;:- BOGF99 _.- • . Wetep 14 •AUG•95 11.25 15.AUG-95 09:20 19-SEP-95 FEp-E% I Screening not Required
RICHLAND ) 0
1AN - AmliCrGlqss-500M1 -. ,.: : ARION$1300.0/q4 P CGLD N/A N/A T11C (174082:99)
CL/300.0/Q4 C COLD 12-SEP-95 11-SEP-95 T11C (174082:99)
^
1 FL/300.0/Q4 C COLD 12-SEP-95 11-SEP-95 T11C (174082:99)
1 ICAP/6010/Q4 S 11103 12-SEP-95 10-FEB-96 T11C (174081:100)
O I 1102/300.0/04 C COLD 12-SEP-95 16-AUG-95 T11C (174082:99)
C> 1 1103/300.0/04 C COLD 12-SEP-95 16-AUG-95 T11C ( 174082:99)
h OPHOS/300.0/Q4 C COLD 12-SEP-95 16-AUG-95 111C (174082:99)
G
504/300.0/04 C COLD 12-5EP-95 11-SEP-95 T11C (174082:99)
3 PNRLestic-lL - :S/9030/Q4€ `- S NAON 12-SEP-95 21•AUG•95 T11C (174085:100 174086 99 174087:98).
1- PH PlasticsSDOmI S H2s9 12-SEP-95 11-5EP+95 T11C ( 174083:700)7
3•=3artQle has not been red screened.
Px
Page 1

h
^
C?
Project Nanagerc H. Price
Quanterra August 16, 1995 12:28 pn
Account: 10722 Project: 550.93 Ouanterra-Richland MS No. 1021 Rev. 0
Kaster Sample Login: 9123
Draft: Final: Entered and Reviewed by: PH Review:
Sample Header Template:
Sample No, Client ID .. , C-Matrix Date; Collected keceiyed Due Shipper Rad Category Rad SartQle No.
^ CoamentS
a' Container Type Analysis Class Preservative Anal. Due Date Hold Date Site (Container Nuabers:X Filled)
Data:
1 N ./04 S H2SO4 12-SEP-95 11-SEP-95 T11C (174084:99)
9123-004
RIC fl L AND
j.D,
BDGF01 Water
50825107
1 AN - Aaber Gl®ss•500mt AyiONS/300.0/G4'
i CL%300.0/C4
1 FL/300.0/04
1 ICAP/6010/Q4
I N02/300.0/04
1 N03/300.0/04
1 ^ DPHOS/300.0/04
1 504/300.0/04
3 PN - Plastic-1L _ S/9030/44
1 PN-Plastic-500m1- : NH3/350{1/04
I N03/353.1/04
9123•DOS BOGF86 Water
RICHLAND i.D. 50825102 . .
^
1 AN Aalxr Glessw50Om1 = -- .-::IC6PD/6018/QG
9123-0D6 ---. : -^ e0GFC0 Watef
RICHIARD ) .D.: 30825104.
1 AN Aiaber Glass•500m1 ICAPG/6010/Q4
9123-007 . . BOGF80 Watcr
RICHEAHD 1 D, .S.Q825106
1 AN - Amber Glessr5D0ml )CAPD/6010/q4
9123-008 B0GF82 Water
RICHI.AND L.D. iD825108
i AN - 4lmber Glass•5.00m1 _ .1CAPD/601D/Q4
d 3*=Saaple has not been red screened.
14-0G•95 13:18 15-AUG-95 09:20 19-SEp-95 FED-EX 1 Screenipg not Required
p COLD N/A N/A TIIC
C COLD 12-SEP-95 11-SEP-95 T11C
C COLD 12-SEP-95 11-SEP-95 T11C
S HNO3 12-SEP-95 10-FEB-96 T11C
C COLD 12-SEP-95 16-AUG-95 T11C
C COLD 12-SEP-95 16-AUG-95 T11C
C COLD 12-SEP-95 16-AUG-95 T11C
C COLD 12-SEP-95 11-SEP-95 Ti1C
S NAOH 12-SEP-95 21-AUG-95 T11C
S H2S04 12-SEP-95 11-SEP-95 T11C
S 112504 12-SEP-95 11-SEP-95 111C
14-AU0-95 12:21 15-AUG-95 09:20 19-SEP-95 FED-Ex
S 00 12TSEP-95 10-FEB-96 T11C
14-AUG>95 10 15 15cAUG-95 09:20 19-SEP-95 FED-Ex
S 0N03 12-SEP-95 10-FEB-96 T11C
14-AU6-95 11 25 15-AU9-95 09:20 19-SEP-95 FED-EX
S NN03 127SEP-95 10-FEB-96 T11C
14>AUG-95 13:18 15-4UG-95 09:20 19-SEP-95 FED-Ex
. - $ NN03 12nSEP•95 10-FEB-96 T11C
Page 2
(174089:99)
(174089:99)
(174089:99)
(174088:100)
(174(189:99)
(174089:99)
(174089:99)
(174089:99)
(174092000 174093:99 174094:98)
(174090:100) "
(174091:99)
(174D95:100)
(174102-100)
(174103;100)
(174:04:100)
Screening not Required
Screening not Requlred
Screening not Required
Screening not ReqUired

O
Q
0,
C;l
Q
r
Bechtel Hantord, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of _j_
Colleetor
(^L rL I ' }- 1- O
G -n ^^
l
-4 ConrPan y Conleet
R. E. Pstaaun
Telephona
1 5 091 372 - 9838
Data Turnaround
q Priority
n Normd
ProJact Dniens8on
100-HR-3 Groundwater Sampling, Round 9, Phess 2
Ice Chest No.
sh/l- 5Oj3
SNpped To
Quantern
Samplinp Locauon
100 D
Field Logbook No.
r= r [- / O 1^
Ofisite Prope 1{y ^1 o.
NA {/ ^^ " I ( ^/
SAF No.
895-098
Method of Shipment
Hand Deliverad
Bill of Ladinp/Air Bill No.
NA 1 ^
Posaible Sample HezarddRemarks Presenation
HNO, Cnol4•C HrSO° •1 HrSO° HNO, Cool4°C Coul4°C HNOz
T1pe of Conteiner
No of Container(s)
4 G 17 G P P P40 PIG G PIG G
1 1 1 3 1 q 3 1 I
Special HerdGnB and/or Storape
Meintain samples between 29C and 6eC.
-^'
Volume
500mL
ICP
Ma[Na
500m1
Anons pCl
'
SOOmL
NO, -
SOOmL
Sullide
500mL
Ammonie
1 L
Gloss
500mL
Tritium
20mL
Activity
50om1
ICP
F. p. 5O„ SAMPLE ANALYSIS
5C19
0 lY;
lvo 61 ,7l
IUnfilterad)
No„NO,.
p0,
NO3 Alpha.
Gross
Beta
Sr90.^/
Scan Metals
IFiltaredl
Sample No. Matdz• Date Sampled Time Sampled
BOGFD3 W rg((l^^S 111 33
BOGFD4
W
I° Is^ !bJ
SPECIAL INSTRUCTIONS M°"•'
CHAIN OF POSSESSION Sipn/Print Names • 1 ZnAc +NeOH s-sw
se s.an.m
Relinquished By //, c' Date/Tima
R DateRhne /
/S° _ f
^ ^ _ Z'r Semple enelysis for phasphe[a, nitrate, and nitrite by EPA 300.0; and turbidity y^
r
by EPA 180 . 1 is beinp requeeled for inlotmahon only. The ERC Contraclor w- wns,
R' Datelfime eceive By DatalTime
o- oe
U
ecknowled0es that the 48hour holding time will not be met.
A M
l a -fS DS-qune°m.
ehnquishad B y DatefThne Reee(ved By ^ I>,q )i Dale/Tima The Activity Scan is for all samples listed on this chain of
Dt - D'u" t'yJe'
custody.
T - TNw.
vn - we.
t - u
Relinquished By Detelfime Received By Dete/Fime
LABORATORY Heceived By Title DateRime
SECTION
FINAL SAMPLE Disposal Method Disposed By Date/Time
DISPOSITION
V - v.onuro„
x - oin.r

O
O
C^
n
^
w
Bechtel H6nford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page _]_ of 1
Collector
2!C ^ 2 7^
Pro(ect DaslenaNcn
100-HR-3 Groundwetar Sampling, Round 9, Phan 2
Company Contact
R. E. Patenon
Samp5n8 Loce6on
100 D
Talephona
(509) 372-9638
SAF No.
B95-068
Data Turnaround
q Pdodty
n Normal
Ica Chest No.
Field Logbook No.
Method of Shipment
Iql-- "-!O(I -
Hand Delivered
Shipped To Offaite Property No. Bill of Ladinp/Air Bill No.
Ouantarn NA I 11, NA
Possibla Sampte HazardelRanarks Praservation
HNO, Cool 4°C Ht50. •1 HAD, HNOz Cod 4sC CoaE 4°C HNO,
Type of Conteinar
No. of Containu(s)
_fi G G P/, P P/e PIG G PIG PG
1 1 1 3 1 4 3 1 1
Spacial Handling and/or Storaps
Maintain aampCas betwean 2•C and 6•C.
SAMPLE ANALYSIS
Volume
SOOmL
ICP
Metals
(Unf'ilter-
500mL
^ Oct
- F.
q' ^°
NO,.
Po, NO"
SOOmL
NO2-
NO,
500mL
Sulfide
500mL
Ammnrua
i l 500mL 20mL
Gross;
K1.
-vity
Alphe ,
Groaa
ad)
Beta,
S r- 90
Sampls No. Matr(x• Dat e Sampled Time Semplad -
BOGF83 03 W
l23
EE 03 I^ ^o^
BOGF84 (,+ q W 0 % i ^5 f 1,330 ^
aQ
(^^^ '^ o 5d8 X'j 001
SOOmL
ICP
Metals
(Filterad)
3^'r^ ^o^ toa
^
CHA^N POSSESSIhN_
0
SipnlPrint Nemes
SPECIAL INSTRUCTIONS
•1 Znqc + NaOH
M•m•'
a - sar
Ra5 iahad By
Dete Ime
'P'" ^G
^^ ^+CC t p - // ST ^3 12
5
Rel' i d C'itGDataRima iooo
IN -/ ^
e8nquished B y Dete/Tbm
fl i 8
' y
Received By
Received By
^ Date/(ima
LS Sample analyeie for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity
• iJ > ^f
b y EPA 180 . 1 is bein g re quested for inforrna8on onl y. The ERC Contractor
OateRime
D ^ acknowledges that the 48-hour holding time will not be met.
U ^n0
jop/ f.-t.^ Date ime The Activity Scan is for all samplas listed on this chain of cuatody.
a^ eWew-
wn.
o. o+
a -As
DS-pun6qb•
ayNt^°^•
T
vn-wtw
^
Relinquished By Data/Tlms Received By Dets/fime
v
x - ou»
LABORATORY Recalved By Title Date/Time
SECTION '
FINAL SAMi Disposol Method Disposed By DeteRims
"pI5P481TION

O
^
^
O
O
tV
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Pa9e ] of I
Codeotor
ift
Pr t DeeiOawdon
'L-J
Company Contact
REere n
S04 oatiun
Talephorx
18091372-8638
SAF No.
Data Turnaround
q Pdodt y
n NomW
100-HR-0 Grourdwater Sanp8n8, Round 8, Phae 2 1000 885-008
ca eat N o. Finfd o co N o. y^ Method of S pment
Shipped To ONeite Prop No.
Hand Dalivered
Bi8 of LadinO/Air Bill No.
Guenterra NA NA / /
Posaibie Sample Hazatda/Ramarka
Prazamdon
HNO, Cool4'C HtSO, 1 HrSO, HNO3 Cnul4'C Cocl4•C HNOt
Type of Contalner
tqG G P!d P P/W P/G G P/G AG
No. of Contdnerb)
1 1 1 3 1 4 3 1 1
SpedY Handling and/or Stnraye
Maintain aempfae betwnn 26C and saC.
Voiume
SOOmL 600mL SOOmL 500mL 500mL IL 600m1 20mL 500mL
SAMPLE ANALYSIS
C
C.^1^x'
^P
Motels
(Unrllter-
Aeiai. d
Cf.
^ , ^ "
P0,
NO, -
NO,
Sulfide Anvncnla
Gross
Alpha,
Grore , ^t
Tritlum
I
Activity
Scan
ICP
Meteb
(Fltered)
^a^'
GVD
Ia^
/ / ^
e d f B ate, ^•
Sr-80 /
Sampla No. Matrix• Dtle Swrpled Time Sanpld - ,^-' - ^ - - • -
BOGFBS 01 W
BOGF86 Q^ W /i Z
o^ 103 oJ 3dj oJ 100
C^IAIN_ GF RQSSESSI[1N
SIOnIPdnt Names
SPECIAL INSTRUCTIONS
• 1 2nAciNaOH
Ma.u'
a -eyr
Ra8 ehad By Datelfune
Date(Tme
9^
R v
eceived By
Dete/TIm /y/0
eteTma P-zO
Sample analysis for phosphate, nitrate, and ndtdte by EPA 300.0; and turWdity
b y EPA 180 . 1 I s b e i ng requee t e d f or I n fanoe don on l y. Th e ERC Contractor
acknowle d pee that t h e 4 8 -hour h o ld ing t i me will not be mat.
^• ^y
A- y.60•
w - w.
e «
w
D9. e,un aYw•
alinquie ed By Date/Tlma Receive By ete^ The Activity Scan is for all samples listed on this chain of cuatody. DL' N. U^W•
T - r'
^isU
^ -VAP'
Relinqulehed By Dan(flme R ed te^ t'^
v - v,awww
z
CA-#ORATQRY Recdved By Title DeteRime
S^IoM -
, F1N,A45^1 , Disposal Method Diepoeed By Data/Time
sy o>seo^^+^:;

A
O
C3
0 O
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page ^-_ of ^_
Copeotor
C /1 / 2 Zv
Company Contect
R. E. Petmrwn
Telephone
15081372-9838
Date Turnaround
q Pdodty
n NomW
Pro t dpna on
10PHR-3 Groundwater Smnp9np, Round 9. PMme 2
Smnrplinp Loca ti on
100 D
SAF No.
B8S-088
tom C mt N a. o Field L ogbook No. Method of Shipment
Sjry^- s°3 - O m Hend DeElverad
Shippsd To OH.IIe Prope Bitl of Ladinp/AIr Bip No.
Dumnutu NA NA ( A
PoF e Snrpl. Hazardellilemarks Premmrvmdon
HNO, Cool 4•C HrSO, •1 Hr804 HNO3 Cool 4•C Cool 4•C HNO,
Type of Contminer ^ G G PIJ P R# PIG G P/G !1 G
No. of Contmintt(s)
1 1 1 3 1 4 3 1 1
Sp.ciY Handling erd/or Storep.
Maintain Femplms bmtwNn 26C end BeC.
Volume
SOOmL 500mL 500mL 500mL 500mL 1 L 500mL 20mL SOOmL
ICP r1eiq1• W4
SAMPLE ANALYSIS /I,^/_
Motalm
(UnRlter-
NO+'
• F.C'^'• NO ,
No" NO'
tro,
Sulfide Anunonlm Grou
Alphe,
Groemr^
Tr(tium•/r
/^
2(,'r
0 !! i
Activity
Scan
ICP
Metel.
IRltandl
50^25/
( VW ad)
Sernplm No. Matdz• Detm Smmpled Tunm Sarnplmd `-%o - - - • '
BOGF89 03 W l1/ l`1S O S- ^
fiOGFCO w /ey/Sf /r
00 p^ ^uo 3^f^^a oJ ^rJ
cN^tN Gp'POSSESgIR ^
Re.hmdBy E-+^c DmuRime
^I
'VA
cf 11" ea
67110, Detm/Tlmm
_
'/ • Y
Sipn/Pdnt Nemas
iV
fle elved By u
DetmRimm/y/0
-
eTrtN .2G
SPECIALINSTRUCTIONS
• 1 Zn A c+ N a OH
Sarrrple .nelyels for phomphmte, nitrmte, and nltrlta by EPA 300.0; and turbidity
by EPA 180 . 1 Is bein g re quested for Information onl y. The ERC Contrmctor
acknowtedpes that the 48-hour holding time will not be mat.
Mw4'
e.= y
sF"
K: ^
wo _ w•«
A- K
oe.Drvneaw
outRuls hard By Dmu/Hme RmcNved By atslT'^^r
The Activity Scan is for all mamplee Ilatsd on this chain of custody.
it
w. - i
^
^
Rellnqu shed By
^ WQ(IATOPY
DmRimm
ReoalvedBy
R sI
rw Title
LDa P!
DateRime
vn ^Wb
L_ vL*kW^
z -am.
flNAI.SAM.P1.(:^ DlmpommlMathod DispomedBy Data/Time
:,pI5FA81T!tttJ^-^
Sr80

Q
O
^
C=)
Q
^
eeehtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
CoDector Company Contact Telephone
R. E. Petenon (5081372-9638
Project Daml9nafion SampNn9 LocaBon ,ya SAF No.
100-HR-3 Groundwater Samp8n9, Rourd 8, Ptwe 2 100 D 1395-088
Ice C eaz o.
Shipped To
Quantmrra
m c- ri6
,
Field Logbook No.
oe^L -/ a/,I ,
Ofteile Properly o.
NA '^
i
(
2
1
Method of Shipment
Hand DeNvarad
NO of Ladin9/Air Bii No.
NA
Possible Sanple Hazards/Remarks
Preservation
PeOo _j_ of I_
Data Turnaround
11 Priority
n Nomul
HNO, Cool4•C H'SO• •1 HtSOe HNO3 Cool4•C Cool4•C HNO,
Type of Conteinar A G I' G Pip P P,t7 PIG G P/G G
No. of Conteiner(d
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain aarnplmabetwen 2eC and 64C.
Volume
500mL SOOmL 500mL 500mL 500mL IL SOOmL 20m1 500mL
^
I -
ICP
A1X°"e BCl
SAMPLE ANALYSIS
r '(-
6 / - !7 I
Metals
(U n lllt ar -
'F . q w ..
^" Po, NO°
NO2'
N Oo
Sulfide Ammonie Groem
Alphm.
Gro a e
Tritium
N"
Activity
S can
ICP
Matade
(Fritared)
(ll (
eal
Bete, ^
r-
5^8^5 1 S 90
Sample No. Malda• Data Saanpled Time Samplmd - - - - - - - - - - ^
DOGF88 5 W p /r L'^f (1r
BOGFBO 06 w /ia.,t-
(dZ> ^o3 I6^- I62) oJ
R

A
G
C:k
r'
0
r3
CA
Bechtel Henford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Cdteator Company Contact Telephone
^L ^l Z Z-O R. E. Patanon (609) 372-9638
Pto ot pna on
100-HR-3 Groundwater Samplinp, Round 9. Phaaa 2
Samp np Location
100 D
SAF No.
895-068
Ice Chest N o. Field Logbook No. Method of Shipment
Hand Dedvsred
SNpped To Oft.lte Property P
Bill uf Ledinp/Air Bill No.
Duantarra NA l f ^ L NA )
Poaeible Sampte HuudalRsmarka
Preeervapnn
Type of Contdner
No. of Contdnar(a)
Page _]_ of I_
Deta Turnaround
0 Pdodry
n Normal
HNO, Cod 4eC H2SO4 •i HiSO. NNO, Cool 4•C Cool 4eC HNO,
A G jfi G P/0 P P/Q PIG G PIG G
1 1 1 3 1 4 3 1 I
'
Special Handqnp and/or Storapa
Mdntdn asrnplas between 2eC and 6eC.
SAMPLE ANALYSIS
•
f
`-^' ( , ^ D
WoNme
/^/
500mL
ICP
Metda
(Unfdter-
500mL
Arcans Ilcl
- F'p'60"
NO ,, NO ..
P0,
500mL
NO, -
NO ,
500mL
Sullide
500mL
Ammonia
IL
Gross
Alpha,
Gross
500mL
Tr'^ yt^^
20mL
Activity
Scan
ScomL
ICP
Metds
( F6tared)
IN u^ ad) Beta, F^v ry
.N(!
Sr-90
Sernple No. Matrix• Date Sampled Time Sampled ^ -
B0GF81 W
Shy s-
BOGF82 (/a W OIly S-
oJ oz:> 310-'> u^ (oJ
CNAIN DF POS$E$SIOy
SIpnlPrint Names
SPECIAL INSTRUCTIONS
•1 ZnAc+NnOH
Mrv^'
e -ay
r+ea ^ isnad av ^-y7^ D.tartime fl. Data/i'une
_
y^o
Semple analysis for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity
eE - idmrn
^_ m^,
R'
dlnqtdehed B y
DetelTime
DeteRime
ee 'ved 8
sedved By
(jt(
b y EPA 180 . 1 is bein g re q uestsd for InfonnaGon onl y. The ERC Contractor
ataRimey ^
acknowledpee that the 48-hour holding time will not be met.
DateReme
he Activity Scan is for all samplas listed on Ihie chain of custody.
^d o.v/OOC^°iiv
w -wn.
o-Cu
A -ee
ps-aueeaa.
ol T - o"'eu"u'
vn_ r^
Rdinquiahed By Deta/Tima flec ^7 B ^
t-11pi10
v - v.c.twm
x -od..
LABOMTORY
By TiOe DetaRime
FINAL $AM¢LE iepoad Method Diapo.sd By Datb/lime
nisPOamaN
I ooeivod

Figure 1
SAMPLE CHECK-IN LIST
it hr 6pwN"h^
Date/Time Received Client Name
Project/Client t .UqJF_aP Batch or Case t
Cooler ID ( if noted an outside of cooler) `SlL .'`^l/ 7
1. Condition of shipping container? eo^_
2. Custody Seals on cooler intact? Yes No ( j
3. Custody Seals dated and signed? Yes LI-If No (]
WHC-SOW-93-0003
Revision 4
4. Chain of Custody record is taped an inside of cooler lid? Yes (] No
5. Vermiculite/packing material is: Wet (x
6. Each sample is in a plastic bag? Yes (] No [
7. Number of sample containers in cooler:
Ory [] -
8. Samples have: ^ tape hazard labels
^ custody seals appropriate sample
labels
9. Samples are: X in good condition leaking
10. Coolant Present? Yes
_ brbken have air bubbles
_ other
f.Y1 No (] Sample Temperature ,^ OG
11. The following paperwork111should //l
be accounted for (N/A if not applicable):
Chain of Custody i(s) iA-
Request for Analysis
Airbill I Carrier Y1
12. Have any a nomalies been identified above? Yes (] No
13. Memos have been initiated for all anomalies identified above? Yes
Printed Name/Signature Date/Time .e/.r9S
33 aG
o0itiL29

FIgure 1
SAMPLE CHECK-IN LIST
it r. sH..,.e^
Date/Time Received Client Name
Project/Client f Q9501 ^ Batch or Case !
Cooler ID (if noted on outside of cooler) SJJJG -- ^/^
1. Condition of shipping container?
2. Custody Seals an cooler intact? Yes [)d No []
3. Custody Seals dated and signed? Yes (/i No []
WHC-SOY-43-0003
Revision 4
4. Chain of Custody record is taped on inside of cooler lid? Yes [ J No
5. Vermiculite/packing material is: Wet Dry [ J --
6. Each sample is in a plastic bag? Yes [ J No
7. Number of sample containers in cooler:
8. Samples have: ^ tape hazard 1abeTs
custody seals appropriata sample
labels
9. Samples are: ^ in good conditio n leaking
_ broken have air bubbles
other
10. Coolant Present? Yes N/ No [ J Sample Temperature y G G
11. The following paperwork should be accounted for (N/A if not applicable):
Chain of Custody Y(s) ^A-
Request for Analysis f(s)
Airbill I Carrier
12. Have any anomalies been identified above? Yes [] No [
13. Memos have been initiated for all anomalies identified above? Yes
Printed Name/Signature Date/Time
33
0000030

Quanterra August lr, 1995 11:4 am
Account: 10722 Project: 550.93 Quanterra-Richland QAS No. 1021 Rev. 0
Master Sanple Login: 128
ProJect Mane W. Price ^-
Draft: F(n®(. . Entered prd Revjewed py; P)( RevieN:
SaaQle Header Tenplate:
SartQle No. Client ID
CommentS
M Container Type
Data:
C-Hatrix Date: Collected Received Due Shipper Red Cate9ory Rad $aaQle No.
Analysis Class Preservative Anal. Due Date Hold Date Site (Container Nurbers:% Filled)
9128-001 B0GFD5 Water 15-AUG-95 11:20 16-AUG-95 09:45 20-SEP-95 FED-EIS 1 Screening not Required
RICNLARD 1.D. 50826801
1 AN AmDer ylasq-500m1 ANI0N5/300.0JR4 P COLD N/A N/A R19F (174257:99)
1 CL/300.0/04 C COLD 13-SEP-95 12-SEP-95 R19F (174257:99)
FL/300.0/Q4 C COLD 13-SEP-95 12-SEP-95 R19F (174257:99)
1 ICAP/6010/Q4 S 111103 13-SEP-95 11-FEB-96 R19F (174256:100)
N02/300.0/04 C COLD 13-SEP-95 17-AUG-95 R19F (174257:99)
1 N03/300.0/04 C COLD 13-SEP-95 17-AUG-95 R19F (174257:99)
1 OPHOS/300.0/04 C COLD 13-SEP-95 17-AUG-95 R19F (174257:99)
1 S04/300.0/Q4 C tOLD 13-SEP-95 12-SEP-95 R19F (174257:99)
3 PN - Plqstic-11. 5/9030/94: S NAOH 13-SEP-95 22-AUG-95 R19F (174260:100 174261;99 174262:98)
i PH •:Plegtic.-500(ql NH3/350:1%Q4 $ H2SO4 13-SEP-95 12-SEP195 R19F (174258:100)
i N03/353.1/Q4 S H2SO4 13-SEP-95 12-SEP-95 R19F (174259:99)
9120-002 BOGFCI Mater . 15 rAU0-95 12:1.2 16-AUy-95 09:45 20-SEP-95 FED-E% 1 ScreeninR not Required
RICHLAND ( D.:°50826803 - , . . . . .. . - - - - .
1 AN • Artber Glass-500m1 ANIONS/300.0/04 P COLD N/A N/A R19F (174264:99)
1 CL/300.0/04 C COLD 13-SEP-95 12-SEP-95 R19F (174264:99)
1 FL/300.0/Q4 C COLD 13-SEP-95 12-SEP-95 R19F (174264:99)
1 ICAP/6010/Q4 S 11103 13-SEP-95 11-FEB-96 R19F (174263:100)
1102/300.0/04 C COLD 13-SEP-95 17-AUG-95 R19F (174264:99)
1 N03/300.0/Q4 C COLD 13-SEP-95 17-AUG-95 R19F (174264:99)
OPHOS/300.0/Q4 C COLD 13-SEP-95 17-AUG-95 R19F (174264:99)
1 504/300.0/04 C COLD 13-SEP-95 12-SEP-95 R19F (174264:99)
3 PH -7PleSticA4 S/9030/44i.^: S NAOH 13-SEP-95 22-AOG-95 R19F (174267:100 174268:99 174269e98)
1 PH 'Plesti.4r500m1 _ . N93l350:1/Q4:: : S 02SO4 13=SEP-95 12-SEP-95 R19F (174265;100)^-
1 N03/353.1%G4 S H2SO4 13-SEP-95 12-SEP-95 R19F (174266:99)
9128^003 ;. :- B0GFC3 Nater 15 A11Gr9510 28 16rAp4-95 09:45 20-SEP-95 FED-E% 1 Screening not Required
: .: RICHLAND
1 AN - Am4eP Glqsr500m1 ANIONS/300.0/44 ,P COLD N/A N/A R19F (174271:99)
^ 1 CL%300.0/Q4 C COLD 13-SEP-95 12-SEP-95 R19F (174271:99)
p
1 FL/300.0/Q4 C COLD 13-SEP-95 12-SEP-95 R19F (174271:99)
^
1 ICAP/6010/04 S 11N03 13-SEP-95 11-FEB-96 R19F (174270:100)
1 1102/300.0/04 C COLD 13-SEP-95 17-AUG-95 R19F (174271:99)
1 1103/300.0/04 C COID 13-SEP-95 17-AUG-95 R19F (174271:99)
t7 1 OPHOS/300.0/Q4 C COLD 13-SEP-95 17-AUG-95 R19F (174271:99)
w 1 S04/300.0/04 C COLD 13-SEP-95 12-SEP-95 R19F (174271:99)
3 PX - Plastic1L S/9030/Q4:= .
S NAOH 13-SEP-95 22-AUG-95 R19F (174274:100 174275:99 174276:98)
1 . PN - Plestics500m1_
- Ny3/350.1/q4 S N2504 13-8EP-95 12-SEP-95 R19F (174272:100)
3*=S amQle has not been rad screened.
Page 1

CS
^
C^
O
O
Project Manager: W. Price
Quanterra August 17, 1995 11:45 am
Account: 10722 Project: 550.93 Duanterra-Richland QAS No. 1021 Rev. 0
Master Sample Login: 9128
Draft: Final: Entered and RevleReQ by; PM Review:
Sample Header Template:
Smnple No. Client iP C-Matrix Date; Collected Received Due Shipper Red Category Rad Saaple No.
Comrent§
p Container Type Analysis Class Preservative Anel. Due Date Hold Date Site (Container Nurtbers:X Filled)
Data:
1 14/ ./ S H2S04 13-SEP-95 12-SEP-95 R19F (174273:99)
912-004 BOGFD6 Yiter 15-^U1G-95 11:.20 16-A4y-95 09:45 20-SEp-95 FED-Ex 1 Screening not Required
^ RICNLAND J.D. 50826802 - : °
^-
- " " " -
1 AN - AuFxr Dlass-500m1 JCAPD/60.)B/G4 MN03 13-SEP-95 11-FEB-94 R19F (174277:100)
9128-OOS BOGFL2 4Ater 15-AUG-95 12:12 16-AU.G-95 09;45 20-SFP-95 FED-EX 1 Screeniny not Requ)red
RICBLAND I.D. 50826804
1 AN - Amber @lass-500m1 ICAPD/601D/Q4 S .HN03 13-S.EP-95 11-FEB-96 R19F (174284:100)
L
9128-006 BOGFC4 Wpter 15-ApG-95 10:26 16-AU¢-95 09:45 20-aEp-95 FED-gX 1 Screening not Required
RICH4ANR l.P. 5Q826806 '
I AN - Amber Glass•500m1 ICAPD/6010/44 $ HN03 13-SEP-95 11-FEB-96 R19F (174285000)
3•=Saaple has not been rad screened.
Page 2

c2l
th
el
el>
in
^
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
PaOa I_ of
Data Turnaround
q Pdodry
Collector Compaary Contwt
R. E. Patsroon -
Tmtaphonm
(509) 372-8038
n Normal
Project DmsipnaYon
100-HR-3 Groundwater Sampling. Round S. Pb... 2
Ica Chest No.
Sp/-- sd3
Slipped To
Duantmrra
SatpBnp Location
100 D
Field Logbook No.
E FL.'
oti olte Prope `^o.
I
NA
/Ol
I ^
SAF No.
695-068
Method of Shipment
HandDellvmred
Bill NA as Lading/Air BiA No.
Possible Sample HazardslRerrwkm Prume6on
HNOr Cool 4°C HrSO, 1 HrSO• HNO3 Cool 4 . C Cool 4 . C HNOr
Type of Contalnsr G G
No. of Contsinerlsl
P&
P Pro PIG G P!G G
1 1 1 3 1 4 3 1 1
Spsdal HandGnp and/or Storage
VoWmm
Msintaln mamples betwaen 20C and 60C.
SOOn^L 500mL SOOmL 500mL SOOmL 1L 50OmL 20mL 500mt
ICP 't"'°'° 6G NO2- Sulfide
Ammoola
Gross Tritium
Activity ICP
dl A/^-- Metals -F' Q' Sn" NO3 Alpha, ^O) Scan Metals
Groo
IRltumdl
SAMPE NALYSIS
W l0
IUnRlter- I^o,
^1 Beta,
9r-90
508^ ^l
Smmple No. Mmtrlx• Dats Sarnpld Tmnm Sampld . -^- . - . .- .
. .. _ .
..,^ . _
.. -. ...^. . _ `: -. , - - :, :.. . .
BOGFOS 0/ W
BOGFD6 W I/ bla.
V IOJ I^^ JD J^ OJ
SPECIAL INSTRUCTIONS M°u'
CHf^ln OF $b S I hl
SI 0n fPrint Nemes
1 ZnAc+NaOH e -sw
^ V ..
Rm6 uished By Dmtm/?wnm R v Dats/fimm
Semple analydm for phosphate, ribatn, and nitrite by EPA 300.0; and turbidity
w^ so
^
R' _
e
DateJT-anm
Rmcsivsd y G '/L
Datelfune 9 y Y EPA 180.1 Is betny reqummted for Informe6on only. The ERC Contrmctor
mcknnwledpes that the 48-hour hafdlnp time will not be met.
p: ^
1_,,y
s6 mh ed By Deta/funa
/' 7
Rscalved By ^1(^ DabR4tne The Activity Scan tm for all samples listed on this chain of custody.
as- t•... owa.
I
i^t4i1°•
vn - Wwv.
Relinquished By DatolRmm Rweived By DetelNma ^: y^w„
i s - om.
n ^E^n^N 13W^'p4tY W Rwsivad By Title Dete/rma
^.. Disposal Method Dlmpossd By Dete/funm

O
Q /
n
O
O
w ZT
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contact Telephone
, Le R. E. Petereon (509) 372-9638
Peee 1_ of 1
Data Turnaround
D Priority
Project DesiBnmtion Samphnll Location SAF No.
100-HR-3 Grourxlwntor Samp8n8, Round 9. Pheme 2 100 D 895-088
Ice Chest No.
^^-S/(
Field Logbook No.C [--L
G/- '
Method of Shipment
HerdDelivered
SNpped To
Ouenterra
Offmite Property
NA
. ^
^ I L
Bill of^ adin8lAir &B No.
NA If
Possible Sample He[srdmlRemmrkm
premervation
HNO, Cool4°C H,50, •1 HrS04 HNO, Cod4
e
C Cool4 . C HNO,
Type of Container
No. of Contefner(sl
n Normd
G G P!4 P PI6 PIG G PIG Ir G
1 1 1 3 1 4 3 1 1
Spnclal HandWnB and/or Storage
Maintain samples between 2eC and BeC.
Volume
500rrd- SOOmL 500mL S00mL 500mL 1L 500mL 20mL 500mL
^ll(J
SAMPLE ANALYSIS
(/ rj
l J0 lr 71
ICP
Metals
(UnRltar-
a d )
Ariwn OCI
'F'a'S0"
NO,. NO,.
Po,
NO, -
NO3
Sullide
Arnrnnna Groem Tritium
Alphn,
Gross /r I(y
/^ f p r1J
B e., Fy,
S r- 9 f1 ^/
Activity
Scan
ICP
Metole
( Filtered)
Sample No. Matdx• Data Sampled Time Sampled - - - -
BOGFCI [.%J W \ir
BOGFC2 IN W / d/
: :qT+++
oJ o^ ob 310^ 0,)
. . - . ::_.
CHAINaFPOSS_ES$IQN
Relinquished By
c^k Co
' u(
DatmlFdme
DmtaRime
9
SienlPdntNamem
Re a B
acalved By Z/ ..
Date(1-wnm
^-
ete/fNne
/ 331.
yJAy-
SPECIAL INSTRUCTIONS ^
•1 ZnAc+NaOH
Semple analysis for phosphate , nitrate, and niNite by EPA 300.0; and turbidity
b y EPA 180 . 1 Is being re q uested for Information only . The ERC Contrector
acknowledges that the 48-hour holding time will not be met.
w°^•'
s - son
fr^
ep- M-^, sqe
W - W.I.
^: o,u°,
os-o.nsar.
e8nquiehed By Dete/fnne Received By mtaTme The Activity Scan is for all samplee listed on this chain of custody. a-: d.'u^'ra'
Relinquished By Data/Tbne Received By Dete/rma
CABORATQftY
secnon
`
Received By Title Dete/Time
FINA(. SAMPLE Disposal Method Disposed By Date/iimm
'D1SP08171QN
va-wi^
L vVq^
rw.
x - om

^
^
^
t3
^
W
Bechtel Hantord, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
Data Turnaround
Collector t ^.,
' ` Z-e
Company Contact
R. E. Peterson
Telephone
(509) 372-9838
^ Priority
n Normal
Project Designation Sampling Location SAF No.
100-HR-3 Groundwater Senyrlin0. Round 9, Phese 2 100 D 895-08a
Ice Chest No. Field Logbook No. C ^•
Method of Shipment
C FL"
/ c/
Hand DaNvered
Shippad To
Ouenterre
Offaita Propa
NA
o.
1
't
^ ! -
Bi8 of Lading/Air Bill No.
NA I
I
Possible Sernpb HaaardslRemaaks
Preservation
HNO^ Cool4°C HtSO, '1 H2SO4 HNOs Cnol4•C Cool4•C HNO,
Type of Container ^ G G P/0 P P/0 PIG G PIG ^ G
No. of Contalner(s)
1 1 1 3 1 4 3 1 1
Special Handling and/or StoreBe
Maintain samples between 20C and 69C.
VoIunw,
500mL 500mL SOOmL SOOmL SOOml. IL 500mL 20mL 500mL
SAMPLE ANALYSIS
^^ - -
.
ICP
Metcls
IUnRltar-
't^"n' Oct
F. a, so„
No NO ,, NO „
Po ,
NOr -
NO 3
Sulfide Ammunia
Gross
Alpha•
Gross
Tritium Activity
Scan
ICP
Metds
IFiltered)
600^^ ^tilo^ 11 dI
Sample No. Metrix• Date Sernpled Time Sampled - - -
BOGFC3 w tC
ROGFC4 DU' w -P ^ 'G'-^ ^
CHAINbF',POSSESSIDN
. .,
Sipn/Print Names
5^90
SPECIAL INSTRUCTIONS N'oL'•
i ZnAc+NaOH
s
^
Relih - By
R" i d
Date(fune
/ ^ ^ 5 SS /3JS'
Date?ime 9•
/.^. .r ^ a-jr v
'
ecaivad By ,:.7.,.
Dete(Time ^3TS
_ -
etsTme ^^'
^ j*J'--
Sample analysis for phosphate, n i trate, and nitrite by EPA 300.0; and turbidity
by EPA 180 . 1 is bein g re q uested for Information o nl y. The ERC Cont r actor
acknowledges that the 48-hour holding time will not be met.
o- wa^
W _ w•«
o 09
A At
o9_p,unaoYM
alinquiched By Dete/Time Received By ^/-Dete/rme The Activity Scan is for all semples listed on this chain of custody.
Relinquished By Date/Time Received By Dete/Tme
^-Vr'.
t'Uqt°
V - vpn.uen
% ^ eNx
!^tTORY. Received By Title Dete/iime
TION ^ ^
20A
_ SAM}?I.E- Disposal Method Dispoaed By DateRime
CISEQSITION -

Figure 1
SAMPLE CHECK-!N UST
It hr 040006 Cumanrl
Oate/Time Received ^^6 y5 Client Name
Praject/Client Batch or Case t
Cooler ID ( if noted on outside of cooler) s^l- SG ^
1. Condition of shipping container? ^^•
2. Custody Seals on cooler intact? Yes No []
3. Custody Seals dated and signed? Yes No []
e
WHC-SOW-93-0003
Revision 4
4. Chain of Custody record is taped on inside of cooler lid? Yes [] No
5. Vermiculite/packing material is: Wet [] Dry [ --/1
6. Each sample is in a plastic bag? Yes [] No [
7. Number of sample containers in cooler:
8. Samples have: Y tape _ hazard labeTs
n custody seals appropriate sample
labels
9. Samples are: ^ in good condition leaking
broken , have air bubbles
other
10. Coolant Present? Yes [^] No [] Sample Temperature
0 G
11. The following paperwork shoulde accounted for (N/A if not applicable):
Chain of Custody Y(s) A-
Request for Analysis I(s)
Airbill i Carrier
12. Have any anomalies been identified above? Yes [] No [\141"
13. Memos have been initiated for all anomalies identified above? Yes []
Printed Name/Signature Oate/Time^
33
0000040

Figure I
SAMPLE CHECK-IN CIST
It rw siwnr cww,...e
Date/Time Received •^^^-95 Client Name
Project/Client 0
Cooler IO ( if noted an outside of cooler)
1. Condition of shipping container?
Batch or Case i
2. Custody Seals on cooler intact? Yes No (]
3. Custody Seals dated and signed? Yes (^(] No (]
WHC-SOW-93-0003
Revision 4
4. Chain of Custody record is taped an inside of cooler lid? Yes (] No (Y
5. Vermiculite/packing material is: Wet (] Ory
6. Each sample is in a plastic bag? Yes (] No ]
7. Number of sample containers in cooler:
8. Samples have: V tape hazard labels
k custody seals lappropriate sample
abels
9. Samples are: ^ in good condition leaking
_ broken have air bubbles
__ other
10. Coolant Present? Yes ^/1] No ( ] Sample Temperature
11. The following paperwork should be accounted for (N/A if not applicable):
Chain of Custody f(s) 17L-a-
Request for Analysis 1(s)
Airbill t Carrier
12. Have any anomalies been identified above? Yes (] No
13. Memos have been initiated for all anomalies identified above? Yes (]
Printed Name/Signature Date/Time
33
0fl00041

Quanrerra Incorporated
2800 George IYashington It hn•
Richland, iNashington 99353
509 375-3131 Telephone
509 375-5590 Fax
Bechtel Hanford, Inc.
345 Hills
Richland, WA 99352
October 2, 1995
Attention: Joan Kessner
SAF Number
Date SDG Closed
Number of Samples
Sample Type
SDG Number
Data Deliverable
1. Introduction
CERTIFICATE OF ANALYSIS
B95-068
August 16, 1995
Nine (9)
Water
W0671
Stand Alone
(V oca71
Quanterra
En.ironmenml
Servlret
^1234SB
OCT 1995
REDaIt^^
a
Log In
On August 14, 15, and 16, 1995, a total of nine water samples were received by the Quanterra
Environmental Services Richland Laboratory (QTESRL) for radiochemical analysis. Upon
receipt, the samples were assigned the following laboratory ID numbers to correspond with the
Bechtel Hanford, Inc. (BHI) specific IDs:
OTESRL ID BHI ID Matrix Date of Receipt
50824101 BOGFD3 Water 8/14/95
50824102 BOGF83 Water 8/14/95
50825201 B00F85 Water 8/15/95
50825202 BOGFB9 Water 8/15/95
50825203 BOGF99 Water 8/15/95
50825204 BOGF81 Water 8/15/95
50826901 BOGFD5 Water 8/16/95
50826902 BOGFCI Water 8/16/95
50826903 BOGFC3 Water 8/16/95
0004

Bechtel Hanford, Inc.
October 2, 1995
Page 2
II. Analytical Results/Methodology
^iiaanterra
Environmental
Services
The analytical results for this report are presented by laboratory sample ID. Each set of data
includes sample identification information, analytical results and the appropriate associated
statistical errors.
The requested analyses were: Gas Proportional Counting
Gross Alpha by method ITAS-RD-3214
Gross Beta by method ITAS-RD-3214
Strontium-90 by method ITAS-RD-3204
Liquid Scintillation Counting
Tritium by method ITAS-RD-3205
III. Quality Control
The analytical results for each analysis performed under SDG W0671 include a minimum of
one Laboratory Control Sample (LCS), one method (reagent) blank, and one duplicate. Any
exceptions have been noted in the "Comments" section.
Quality control sample results are reported in the same units as sample results.
IV. Comments
Gas Proportional Counting
Gross A112ha by method ITAS-RD-3214
The sample size was reduced from 200 mL to 152 mL for sample BOGF85 due to a high
precipitate weight. The sample meets the RDL requirement using the reduced volume. The
LCS, batch blank, sample and sample duplicate (BOGFD3) results are within contractual
requirements.
Gross Beta by method ITAS-RD-3214
The LCS, batch blank, sample and sample duplicate (BOGF83) results are within contractual
requirements.
C005

Bechtel Hanford, Inc.
October 2, 1995
Page 3
iiuanferra
Environmental
Sevices
Strontium-90 by method ITAS-RD-3204
The LCS, batch blank, sample and sample duplicate (BOGFD3) results are within contractual
requirements.
Liquid Scintillation Counting
Tritium by method ITAS-RD-3205
The LCS, batch blank, sample and sample duplicate (BOGFD3) results are within contractual
requirements.
I certify that this Certificate of Analysis is in compliance with the SOW, both technically and
for completeness, for other than the conditions detailed above. Release of the data contained
in this hard copy data package has been authorized by the Laboratory Manager or a designee,
as verified by the following signature.
Reviewed and approved:
Suzanne Gaines
Project Manager
.
lp^4
0006

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50824101 MATRIX: WATER
Environmental
Services
CLIENT ID: BOGFD3 DATE RECEIVED: 8/14/95 10:00:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA - 1.94E-01 1.4E-01 1.5E-01 6.58E-01 pCi/L 100.00% RD3214
BETA 8.64E-01 1.3E+00 1.3E+00 2.82E+00 pCi/L 100.00% RD3214
STRONTIUM - 1.55E-01 1.5E-01 1.6E-01 7.36E-01 pCI/L 99.70% RD3204
TRITIUM 2.26E+01 1.4E+02 2.2E+02 3.37E+02 pCi/L 88.10% RD3205
Number of Results: ®
0007

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50824102 MATRIX: WATER
°iaanterra
Environmental
Servires
CLIENT iD: BOGF83 DATE RECEIVED: 8/14/95 10:00:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(ZS) MDA UNIT YIELD NUMBER
ALPHA 2.67E+00 1.3E+00 1.4E+00 1.51E+00 pCi/L 100.00% RD3214
BETA 4.92E+00 1.8E+00 1.8E+00 3.19E+00 pCi/L 100.00% RD3214
STRONTIUM 1.51E-01 2.7E-01 2.7E-01 1.04E+00 pCi/L 69.20% RD3204
TRITIUM 1.84E+03 2.3E+02 3.4E+02 3.37E+02 pCUL 88.10% RD3205
Number of Results: Q
C-1008

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50825201 MATRIX: WATER
iiuanterra
Environmental
Services
CLIENT ID: BOGF85 DATE RECENED: 8/15/95 9:20:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR ( 2 s) ERROR ( 2 s) MDA UNIT nELD NUMBER
ALPHA 2.35E+00 1.6E+00 1.6E+00 1.98E+00 pCVL 100.00% RD3214
BETA 7.53E+01 4.6E+00 7.OE+00 3.23E+00 pCVL 100.00% RD3214
STRONTIUM 3.87E+01 1.5E+00 9.5E+00 9.15E-01 pCVL 77.90% RD3204
TRITIUM 3.63E+04 82E+02 2.8E+03 3.37E+02 pCVL 88.10% RD3205
Number of Results: ®
0009

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50825202 MATRIX: WATER
iiiuanferra
Environmental
Serviccs
CLIENT ID: BOGFB9 DATE RECEIVED: 8/15/95 9:20:00 AM
ISOTOPE RESULT
COUNTING TOTAL REPORT METHOD
ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 7.37E-01 6.1E-01 6.2E-01 9.67E-01 pCi/L 100.00% RD3214
BETA 4.10E+00 1.6E+00 1.6E+00 2.88E+00 pCi/L 100.00% RD3214
STRONTIUM -4.53E-02 1.8E-01 1.8E-01 7.89E-01 pCUL 95.70% RD3204
TRITIUM 1.15E+02 1.5E+02 2.3E+02 3.37E+02 pC'i/L 88.10% RD3205
Number of Results: ®
0010

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50825203 MATRIX: WATER
iiiuanterra
Envitonmental
Servrces
CLIENT ID: BOGF99 DATE RECEIVED: 8/15/95 9:20:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR ( 2s) ERROR ( 2 s) MDA UNIT `nELD NUMBER
ALPHA 1.01E+00 7.2E-01 7.3E-01 1.04E+00 pCIIL 100.00% RD3214
BETA 5.73E+00 1.8E+00 1.9E+00 3.09E+00 pCi/L 100.00% RD3214
STRONTIUM - 5.13E-02 1.8E-01 1.8E-01 7.89E-01 pC(!L 95.90% RD3204
TRITIUM 2.43E+02 1.5E+02 2.4E+02 3.37E+02 pCi/L 88.10% RD3205
Number of Results: ®
0011

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE iD: 50825204 MATRIX: WATER
^iuanterra
Ernironmenta/
Serrires
CLIENT ID: BOGF81 DATE RECEIVED: 8/15/95 9:20:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 2.50E+00 1.3E+00 1.3E+00 1.59E+00 pCUL 100.00% RD3214
BETA 6.54E+00 1.9E+00 1.9E+00 3.14E+00 pCi/L 100.00% RD3214
STRONTIUM 2.88E-01 2.5E-01 2.6E-01 8.63E-01 pCUL 79.40% RD3204
TRITIUM 1.73E+04 5.7E+02 1.5E+03 3.37E+02 pCUL 88.10% RD3205
Number of Results: ®
C0i2

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50826901 MATRIX: WATER
iiuanterra
Environmental
Services
CLIENT ID: BOGFD5 DATE RECEIVED: 8/16/95 9:45:00 AM
ISOTOPE RESULT
COUNTING TOTAL REPORT METHOD
ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 2.54E-01 2.9E-01 2.9E-01 5.08E-01 pC(/L 100.00% RD3214
BETA 8.64E-01 1.2E+00 1.2E+00 2.61 E+00 pCWL 100.00% RD3214
STRONTIUM -9.91E-02 1.7E-01 1.7E-01 7.73E-01 pCl/L 98.10% RD3204
TRITIUM -8.57E+01 1.3E+02 2.2E+02 3.37E+02 pCVL 88.10% RD3205
Number of Results: ®
0013

SAMPLE RESULTS
LAB NAME: ITAS-tiCHLAND SOG: W0671
LAB SAMPLE ID: 50826902 MATRIX: WATER
Environmental
Services
CLIENT ID: B0GFC1 DATE RECENED: 8/16/95 9:45:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 1.64E+00 8.5E-01 8.7E-01 9.83E-01 pCi/L 100.00% RD3214
BETA 3.76E+00 1.6E+00 1.7E+00 2.99E+00 pCUL 100.00% RD3214
STRONTIUM -2.28E-02 1.5E-01 1.8E-01 7.71E-01 pCt/L 94.80% RD3204
TRITIUM 3.98E+03 3.OE+02 4.9E+02 3.37E+02 pCl/L 88.10% RD3205
Number of Results: ©
Co14

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50826903 MATRIX: WATER
iiuanterra
Environmental
Services
CUENT ID: BOGFC3 DATE RECEIVED: 8/16/95 9:45:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 1.17E+00 7.1E-01 7.2E-01 8.38E-01 pCi/L 100.00% RD3214
BETA 4.83E+00 1.7E+00 1.7E+00 2.90E+00 pCUL 100.00% RD3214
STRONTIUM - 1.23E-03 1.8E-01 1.8E-01 7.59E-01 pCi/L 96.00% RD3204
TRITIUM 2.28E+03 2.4E+02 3.7E+02 3.37E+02 pCi/L 88.10%, RD3205
Number of Results: ®
0015

DUPLICATE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE 10: G0824101 MATRIX: WATER
10"uanterra
Enrironmental
Services
CLIENT ID: BOGFD3 DATE RECEIVED: 8/14/95 10:00:00 A
ORIG LAB SAMPLE ID: 50824101
ISOTOPE
DUP COUNTING TOTAL REPORT METHOD ORIG
RESULT ERRORV ERROR(2s) MDA UNIT YIELD NUMBER RESULT RPD
ALPHA 1.42E-01 2.4E-01 2.4E-01 4.86E-01 pCi/L 100.00% RD3214 -1.94E-01 1292.31%
STRONTIUM 3.39E-02 1.9E-01 1.9E-01 7.83E-01 pCi/L 94.80% RD3204 -1.55E-01 311.97%
TRITIUM 5.75E+01 1.4E+02 2.3E+02 3.37E+02 pCi/L 88.10% RD3205 2.26E+01 87.14%
Number of Results: 30
0016

DUPLICATE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: G0824102 MATRIX: WATER
iiiaantertrta
Environmental
Servlces
CUENT ID: B0GF83 DATE RECEIVED: 8/14/95 10:00:00 A
ORIG LAB SAMPLE ID: 50824102
ISOTOPE
DUP COUNTING TOTAL REPORT METHOD ORIG
RESULT ERRORj ERROR(2s) MDA UNIT YIELD NUMBER RESULT . RPD
BETA 4.47E+00 1.7E+00 1.7E+00 2.92E+00 pCUL 100.00% RD3214 4.92E+00 9.58%
Number of Results: 10
0017

0
0
!{^
^
Client Sample Screening Results
15-Aug-95
CLIENT C+ODE ID MATtD( EECEtVED DETECTOR ACQ DATE SAMPLE MINUTES CNTSA NET CPM A CNTS B NET CPM ll
WHC 80001 E/15N59:20:00AM QUAD2IA 8/15/951:3833PM B0GF81 30 37 1.19208333 132 3.30125
LIQUID Blcf: 8/15/95 5:26:44 AM BKG 800 33 0.04125 879 1.09875
AYDMe: i11595 TetSo,AIl: 1.00E+00 , 1.00E+0I Alp; (Dpm/ 3.53E+00 (uCV 1.59E-04 (pGd LS9E+02 ±3.2E+01 CAT 1.6E-01 LJ
PptrmS: 2.7 UeFb: L ml Bet; Alq): 6.01E+00 Si): 2.71E-04 I.i[): 2.71E+02 ± 3.3E+01 I/ I.8E-01 ^
WHC BOOPES 8/15/959.20:OOAM QUAD2IB 8/15/95198:33PM B00F85 30 13 0.39333333 102 2.52871
LIQUID Bkg: 8/15/95 5:26:44 AM BKG 800 32 0.04 697 0.87125
AYDaEe: 8/13195 Tat*A{q: I.OOE+00 1.00E+01 Alp; (Dpm/ 1.24E+00 (uCU 5.60E-05 (pCU 5.60E+01 ±2.6E+01 CAT 4.5E-01 LAi
Pp:r.q: 6.4 3 UNb: L , mI Bet; Alq): 4.72E+00 Si): 2.13E-04 LIC): 2.13E+02 ±2.9E+01
I-^
2.4E-01
A1q
LI I
WHC B00F99 8115/959:20:00AM QUAD2IC 8/15/951:38:33PM BOGF99 30 52 1.67833333 152 4.0141667
LIQUID 8lq: 8/15/955:26:44AM BKG 800 44 0.055 842 1.0525
AdDate: 8/1595 TotSo,A4: 1.00E+00 , 1.00E+01 Alp; (Dpm/4.86E+00 (uCU 2.19E-04 (pC7J 2.19E+02 ±3.4E+01 CAT 1.1E-01 Lab
Pptrtq: 1.6 3 Udb: L , ml Bet; Alq): 6.93E+00 Si): 3.12E-04 Ljg): 3.12E+02 ±3.5E+01 I 1.6E-01 ^
WHC 800PB9 8/15/959:20:00 AM QUAD2ID 9/15/951:38:33PM BOGFB9 30 29 0.91416667 81 1.72375
LIQUID Bk=: 8/15/95 5:26:44.N1 BKG 800 42 0.0525 781 0.97625
Ata1Date: 8/15195 TmtSa,Airi: 1.00E+00 1.00E+01 Alp; (Dpm/ 2.79E+00 (uCl/ 1.26E-04 (pCI/ 1.26E+02 ±2.9E+01 CAT 3 2.0E-01
PPt^a(: I / Un(tU: L , ml Bet; A1q): 2.86E+00 Si): 1.29E-04 Llt): 1•29E+02 ±2.5E+01 I 3.9E-01
1 SAug-95 I
All

*** ALPHA **+E
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 14-Aug-1995
Page 1
CUSTOMER: BHI ^^r SAMPLE DELIVERY GROUP I006 71
MATRIX : WATER W1 J BATCH NUMBER OD ^2#/
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
_=_________°------------------------------------------------°_________
# > M082411B BHI
# ) M082411S BHI EQEb F32-
3 ) 50824101 BHI BOGFD3
Q-uy 2q k 01 o.,p
4 ) 50824102 BHI BOGF83
---------------------------------------------------------------
ACTIONS ( Initial & Date)
1) INITIATED 5) COUNTING/MEASUREMENT LAB _41A-_
2) PREP LAB RECEIVED q F-RS ^ 6) DATA REVIEWED AND
ANALYTICAL PREP STORED Ak
3) SAMPLE REMAINDER STORED 9-l^-1S 5^
4) SEPARATION LAB RECEIVED
0047

CUSTOMER: BHI
MATRIX : WATER
*** ALPHA #-+•u
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 15-Aug-1995
Page 1
S^^ SAMPLE DELIVERY GROUP W O^ /I
E4 5-66 g BATCH NUMBER 0O -a5a
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
-----------------------------------------------------------------^___
1 50825201 BHI BOGF85 Sctcea„i • k^ ..^vor t^^
2 ) 50825202 BHI BOGFB9
3 ) 50825203 BHI BOGF99
4 ) 50825204 BHI BOGF81
ACTIONS (Initial & Date)
1) INITIATED 5) COUNTING/MEASUREMENT LAB A//k
2) PREP LAB RECEIVED 9^3-^15 ^ 6) DATA REVIEWED AND
ANALYTICAL PREP STORED Pit G-2o'
3) SAMPLE REMAINDER STORED R-1F-95
4) SEPARATION LAB RECEIVED ^/^
^ 0048

*** ALPHA
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 16-Aug-1995
Page 1
CUSTOMER: BHI ^^^ SAMPLE DELIVERY GROUP W^/(L //
MATRIX : WATER ^^^ 66" BATCH NUMBER ^^' ^260
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
1 ) 50826901 BHI BOGFD5
2 ) 50826902 BHI BOGFC1
3 ) 50826903 BHI BOGFC3
----------------------------------- --------------------------------------^ ----- ---- ----
ACTIONS (Initial & Date)
1) INITIATED 5) COUNTING/MEASUREMENT LAB A/d,
2) PREP LAB RECEIVED (T-?t1i5-C 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED 4-lS--95.t^'
4) SEPARATION LAB RECEIVED '14-
• 0049

^
BATCH SUNIlbIARY/CHAIN OF CUSTODY
ANALYSIS a.3sy^.uy*3L
M N/a -2M or 2S
circle)
OC BATCH MATRIX/F2FAGENT
SP II{E
G 0 9- ztil - 01 I DuplicateofSample# 5o8zv^o/
5u&zvtot
OZ
so8^szc i ^`-^ ^
so&z69oi o^ ^
Batched and QC updated bY S on 9-/&-45 Reo'd in C.R. b^ onp-6-9S
Rec'd in Prep Lab by 9- on -98-9J Data Reviewed and
anal. Prep uoced LL on q^^0-95
Rec'd in Sep Lab by ^/ 4 on-.&^L •
Rec'd in Sep lab by on ,JlA- Sampies Disposed by on
Originsl batch sheet and complete calculation file to be filed with the FIRSt listed work order number.
FORM NO.: RC-52. I/95. Rev. 5
A
, 0050 . -

CUSTOMER: BHI
MATRIX : WATER
*** BETA +E^^
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 14-Aug-1995
Page 1
^r SAMPLE DELIVERY GROUP I.V0^^l
60-z 9
BATCH NUMBER
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
------------------------
-------- --------- ------------------------------------===6
# ) M082411B BHI
M082411S BHI EIxAN z?`+-S
3 ) 50824101 BHI BOGFD3
4 ) 50824102 BHI BOGF83
Gntraa( oz D..o _
---------------------------------------------
ACTIONS (Initial & Date)
1) INITIATED sll/ 5 5) COUNTING/MEASUREMENT LAB i/./4
2) PREP LAB RECEIVED 9P 95 C 6) DATA REVIEWED AND
ANALYTICAL PREP STORED ?s7-
3) SAMPLE REMAINDER STORED
4) SEPARATION LAB RECEIVED ^.l.a
I MM 1

*** BETA
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 15-Aug-1995
Page 1
CUSTOMER: BHI ^x SAMPLE DELIVERY GROUP GVD^ ^l
MATR I X WATER ^q,5&9 BATCH NUMBER L U -^5a
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
1 ) 50825201 BHI BOGF85
2 ) 50825202 BHI BOGFB9
3 ) 50825203 BHI BOGF99
4 ) 50825204 BHI BOGF81
--- ----------- --------------------------
ACTIONS ( Initial & Date)
1) INITIATED 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED G-89s ^ 6) DATA REVIEWED AND
ANALYTICAL CAL PREP STORED
SAMPLE REMAINDER STORED 9-!I 45 ^
4) SEPARATION LAB RECEIVED tiLn-
.. 0052

*** BETA
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 16-Aug-1995
Page 1
CUSTOMER: BHI 3^^ SAMPLE DELIVERY GROUP
MATRIX : WATER i^"M BATCH NUMBER ^W
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
i ) 50826901 BHI BOGFD5
2 ) 50826902 BHI BOGFC1
3 ) 50826903 BHI BOGFC3
r C =^ _^ ^ 3
ACTIONS (Initial & Date)
1) INITIATED 5) COUNTING/MEASUREMENT LAB A//I'
2) PREP LAB RECEIVED 4-8-45 ^ 6) DATA REVIEWED AND
3) SAMPLE REMAINDER STORED
ANALYTICAL PREP STORED QV 9-3? 7'0'9
4) SEPARATION LAB RECEIVED ^11A-
^ 0053

;.:
^ BATCH ST7MIAARY/CHAIN OF CUSTODY
ANALYSIS MATRIX DUE DATE 2-3^-^s
WORK ORDER SE irENCH # CI.IFi`rr CobadEN'i'S
M -iB Q.C BATCS RFAGENT BI.ANg
M^ la -IX QC BATCH MATBLY BLANK
M ca- at4l -IM or(1^1
QC BATCS MATRIX/REAGIIVT
cfxoiel
SPISE .EG,nH Z'7143 ^. r
M N14 -2M or 2S
circ2el
ga&TCS MATRIXlREAGFNT
G okav( - oZ Duplicate of Sample # So3autoz
55 ' Ltt 1 I OZ
S06' zsZOl I OLl
Sc,Y26`lol
{
GS
I I
1 .
Batched and QC updated by lq;; on %lL9S Ree'd in C.R. byS:^ ou /^^'g^S
Reo'd in Prep Lab by on q-L45 Data Reviewed and
anal. Prep ssoced IL on 9-aD- 2S^
Rec'd in Sep Lab by oa _-i_t__
Rec'd in Sep lab by oa=^ Samples Disposed by on
origioai batch sheet and eomplete caleulatioc file to be filed with the FII2ST listed work order aumber.
FORVS NO.: RC-52. 1/95. Rev. 5
- 0054

*** TOTAL-SR ***
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 14-Aug-1995
Page 1
CUSTOMER: BHI SAMPLE DELIVERY GROUP / l
MATRIX WATER BATCH NUMBER 0J 'IN/
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
-- ---- ----- ---------------
# ) M082411B BHI
# ) MOB2411S BHI
3 ) 50824101 BHI BOGFD3
4 ) 50824102 BHI BOGF83
'Al
- ----- - -------
ACTIONS (Initial & Date)
1) INITIATED 8Iv/95 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED
4) SEPARATION LAB RECEIVED
0055

*** TOTAL-SR ***
CHAIN-OF-CUSTODY BATCH ANALYSIS REC
CUSTOMER: BHI " PC SAMPLE DELIVERY GROUP
MATR I X : WATER 13q5-00 BATCH NUMBER
CUSTOMER
ITAS ID DUP ACCOUNT ID
1 ) 50826901 BHI BOGFD5
2 ) 50826902 BHI BOGFCI
3 ) 50826903 BHI BOGFC3
ACTIONS ( Initial & Date)
7RD 16-Aug-1995
Page 1
,/t^2lv'/
Dy-M
COMMENTS
1) INITIATED jo 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED
4) SEPARATION LAB RECEIVED
0056

*** TOTAL-SR ***
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 15-Aug-1995
Page 1
CUSTOMER: BHI ^^ SAMPLE DELIVERY GROUP
MATRIX : WATER 80-069 BATCH NUMBER 0^^^5a
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
-----------------------------------------------
----------------------------------------_°___________________----
1 ) 50825201 BHI BOGF85
2 ) 50825202 BHI BOGFB9
3 ) 50825203 BHI BOGF99
4 ) 50825204 BHI BOGF81
- ----- ------
ACTIONS (Initial & Date)
1) INITIATED 11',7_Gr_L.^ 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED
4) SEPARATION LAB RECEIVED
•. 0057

BATCH SUMMARY/CHAIN OF CUSTODY
ANALYSIS T- SbZ, MATRIX /9 -, G DUE DATE
WORK ORDER SE UENCE /t CLIENT COMMENTS
M -1B QC BATCH REAGENT BLANK
M -1X QC BATCH MATRIX BLANK
M0 q -1M or E4L QC BATCH MATRIX/REAGENT
(circle ) /30a• SPIKE t . oai
M -2M or 2S
(circle )
O BATCH MATRIX/REAGENT
SP KE
G G 23a Duplicate of Sample #
s'G4f^y^ c - G ^
`^'c^S^G 9cJ o
Batched and QC updated by
/2^
on^-122 t °' ^-Rec'd in C.R. by^ on^L^?1^ ^
Rec'd in Prep Lab by •'/\ T/n on Data Reviewed and l^ (`^y
///^^ /anal. Prep stotedon /
Reo'd in Sep Lab by i\ 7 on5 ?`f cs
Rec'd in Sep lab by / N-
Original batch sheet and completecaTTl^culatio--n file to be filed with the FIRST listed work order number.
FORM NO.: RC-52. 1/95. Rev. 5
on Samples Disposed by on
0058

' *** TRITIUM ***
vA7
^D^ CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 14-Aug-1995
1Page 1
CUSTOMER: BHI J9/r" SAMPLE DELIVERY GROUP 0O0
MATRIX WATER
^jq^1069 BATCH NUMBER On'f^t'/
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
-e=-^ e-a-oo---------a---.^=evee=e=oaoaaeeavaa=vaa===ee=aaaaaaa
H'108^^{ r1/lN
vhoYZ y/,1
!^t ^ d .^ y / 3
* ) M082411)3 11- BHI U
8449/s/9s 6o s^n{ o sa/doc //o r.P#'^"/^1
# ) M082411X BHI
M082411N BHI
tt > M082411S BHI
# ) M082412N BHI
# ) M082413N BHI
7 ) 50824101 BHI BOGFD3
Go83,LKLo /
B ) 50824102 BHI BOGF83
ACTIONS (Initial & Date)
1) INITIATED "114/C^ 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED BAB 9^5(^TS 6) DATA REVIEWED AND
3) SAMPLE REMAINDER STORED fVi9
ANALYTICAL PREP STORED
4) SEPARATION LAB RECEIVED
0059

*** TRITIUM ***
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 15-Aug-1995
Page 1
CUSTOMER: BHI ^r SAMPLE DELIVERY GROUP OLl^^I
MATRIX : WATER
13^1 ^,^^ BATCH NUMBER O9
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
1 ) 50825201 BHI BOGF85
2 ) 50825202 BHI BOGFB9
3 ) 50825203 BHI BOGF99
4 ) 50825204 BHI BOGF81
ACTIONS ( Initial & Date)
1) INITIATED JL ^^( 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED R^3 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED h/
4) SEPARATION LAB RECEIVED
0060

*** TRITIUM ***
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 16-Aug-1995
Paye 1
CUSTOMER: BHI 3p r SAMPLE DELIVERY GROUP IN^//^^l
MATRIX : WATER ao,DU/(y BATCH NUMBER M';W
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
------------------------------------------------------------------------
-------------------- ---- ------- ---- ---------------- ------ -
1 ) 50826901 BHI BOGFDS
2 ) 50826902 BHI BOGFC1
3 ) 50826903 BHI BOGFC3
ACTIONS ( Initial & Date)
1) INITIATED S-lJ^ 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED R R.Ci 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED f^^r?
4) SEPARATION LAB RECEIVED
0061

V\^ i395-o^o^f
CUSTOMER: BHI
MATRIX : WATER
+c** TRITIUM #**
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD 3-Aug-1995
Page 1
SAMPLE DELIVERY GROUP
\4''a(655
BATCH NUMBER H"oGtR
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
ossasaassssaasaosaaasasaaa=aaaassasssaaaaaaassssassassassasassasasssssas
i ) 50806801 BHI BO685O
Gosrn68'o / eG^fn
aaaaaaas^a^^^sa^ a7aa^,asa^a3^asz^^^a2aaaaaad^^^aaass+aaaassams
^
^orO&t S
ACTIONS (Initial & Date)
1) INITIATED 5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED b'/IB /7 6S 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED N H
4) SEPARATION LAB RECEIVED V/
0062

*** TRITIUM ***
CHAIN-OF-CUSTODY BATCH ANALYSIS RECORD
CUSTOMER: BHI 3 SAMPLE DELIVERY GROUP
MATR I X : WATER 01f' 0 f^ BATCH NUMBER (Jn I D%/
CUSTOMER
ITAS ID DUP ACCOUNT ID COMMENTS
4-Aug-1995
Page 1
m¢aaaaaammassasmssaasssamm¢aamssamm¢smsssmasaa.msmmsaaaasmsasamsassasmssa
1 ) 30B09101 BHI BOG846
2 ) 50809102 BHI BOG868
3 ) 50809103 BHI BO6B48
a=saaaamsaaaaaamsaaxassaaaaaaoaaaaaxcaaaaxxsasassaaaamaaaaaaxasa¢asa¢mx
A TIONS (Initial & Date)
1) INITIATED "
^q5
5) COUNTING/MEASUREMENT LAB
2) PREP LAB RECEIVED BAb 6) DATA REVIEWED AND
ANALYTICAL PREP STORED
3) SAMPLE REMAINDER STORED Ni?
4) SEPARATION LAB RECEIVED
0063

Quamrm,a w ^ 44;s + C,.^d G 7/
BATCH SUMMARY/CHAIN OF CUSTODY
ANALYSIS :, MATRIX _., DUE DATE 9/30 /f,^5-
WORK ORDER SEOUENCE # ^ CLIENT ^ COMMENTS
M )q -iB 8H
Wo
QC BATCH REAGENT BLANK
M O ff;1 - 1 X QC BATCH MATRIX BLANK
M '? / - M,41S
QC BATCH MATRIX/REAGENT
circle)
SPIKE
M W^ -2M or 2S
(circle)
OI^TCH MATRIX/REAGENT
SP
G O R a /-/ / o / - N 114 - Dup iicate of Samp le # 50 8 q ^1 / o /
bi 0 8 a y l l Al
e?ak( l d l
SoY2, 5aD1 0 °
SoS^69o/ 03 ^
h'? oSo6^I! r^^ I wo^ss
o8a68 !rn$/
G+ 0$D (o$Dl / ^ 9
-#"
So
£l6L^dl
^
5 080 (e 8"0
,sa80 910( 0 3
Batched and QC updated by 13 PS^ on 5/r//sS Rec'd in C.R. by on "t h
Rec'd in Prep Lab b,v 11/ 1a on Wq Data Reviewed and
an. Prep stored W F on' y'$ -
Rec'd in Sep Lab by on
Rez'd in Sep lab by on Samples Disposed by on
Ori¢inal batch sheet and complete calculation tile to be filed with the FIRST listed work order number.
FORM NO.: RC-52. 1/95, Rev. 5
C064

lAkLos Alamos Technical Associates, Inc.
8633 Gage Blvd. / Kennewick, WA 99336 / Telephone (509) 783-4369 / FAX (509) 783-9661
November 2, 1995
LATA95-211
Ms. Joan Kessner
Bechtel
1022 Lee Boulevard
Richland, WA 99352
Subject: VB404.06, SDG W0671-QES
Dear Ms. Kessner:
4
NQV 0
uw-^a
Attached is the data validation report for analytical results for 100-HR-3
Groundwater Round 9 - Phase II, (SDG W0671-QES). The package was received
by Los Alamos Technical Associates on October 12, 1995. This data package was
initially placed on hold October 23, 1995 to request missing information deemed
necessary to the validation effort. The final information request was closed on
October 23, 1995 placing the package back in active status.
If you have any questions, please feel free to contact me.
Sincerely,
J^rto^t^ ^^^ f°'t
Marsha C. Webb
Deputy Project Manager
Attachment
cc: Jeanette Duncan, CH2M Hill
Don Smith, LATA
VB404.06
MCW/lb
In

DATA VALIDATION REPORT
for
100-HR-3 GROUNDWATER ROUND 9
PHASE II
Metals Analysis
SDG W0671-QES
LATA VB404.06
Bechtel Hanford Inc.
P.O. Box 969
Richland, Washington
November 2, 1995
40406MTL.NAR; Printed: 2-Nov-95, 11:42 am 000000

Table of Contents
Data Validation Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000002
INTRODUCTION ............................................... 000002
ANALYSES REQUESTED ......................................... 000002
DATA QUALITY OBJECTIVES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000002
REFERENCES ................................................. 000004
GLOSSARY OF VALIDATION APPLIED QUALIFIERS (CHEMISTRY) . . . . . . . . 000005
GLOSSARY OF LABORATORY APPLIED QUALIFIERS . . . . . . . . . . . . . . . . . . 000006
Qualification Summary Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000007
Data Summary Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... . . . . . . 000011
Sample Results ...................................................... 000015
Checklist ........................................................... 000034
Laboratory Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000050
Chain-of-Custody Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000055
END OF PACKAGE .......... ........................................ 000067
40406MTL.NAR; Printed: 2-Nov-95, 11:43 am 00000 1

INTRODUCTiON
100-HI23 Q2OUNDWATER ROUND 9 PHASE II
Data Validation Nanative
All samples in Sample Delivery Group (SDG) W0671-QES (VB404.06) were validated at level D as
defined in the Data Validation Procedures for Chemical Analysis (WHC-SD-EN-SPP-002, Rev. 2).
The analyses were performed by Quanterra Environmental Services.
ANALYSES REQUESTED
See Table 1.
DATA QUAIITY OBJECrWES
Ptecision: Goals for precision were met.
Accuracy: Goals for accuracy were met with the exception of those items
discussed in the "Qualification Summvy Table".
Sample Result Veiification: All sample results were supported in the raw data.
Detection limits: Detection limit goals were met for all sample results as specified
in the RCRA Facility Investigation/Corrective Measuwzs Study
Work Plcns for the 100-HI2-3 Openable Unit, DOE/RL-88-36, Rev.
0.
Completeness: The data package was 100% complete for all requested analyses.
No major deficiencies were identified during data validation which required qualification of data as
unusable.
MINOR DEFICIEIVCIES
Minor deficiencies were identified during validation which required qualification of data as estimated.
See the "Qualification Summary Table".
40406MTL.NAR; Printed: 24-Oct-95, 3:16 pm 000002

Table I
Chain-of-Custody
Analysis Request
LATA ID #: VB404.06 SDG: W0671-QES
Sam ple Information Analyses Req uested
SAMPLE DATE
FIELD QC
NO. COLLECTED MATRIX SAF INFO 1 2
BOGF81 14-Aug-95 WATER B95-068 X
BOGF82 14-Aug-95 WATER B95-068 X
BOGF83 11-Aug-95 WATER B95-068 X
BOGF84 11-Aug-95 WATER B95-068 X
BOGF85 14-Aug-95 WATER B95-068 X
BOGF86 14-Aug-95 WATER B95-068 X
BOGF99 14-Aug-95 WATER B95-068 X
BOGFBO 14-Au g -95 WATER B95-068 X
BOGFB9 14-Aug-95 WATER B95-068 X
BOGFCO 14-Aug-95 WATER B95-068 X
BOGFC1 15-Au g -95 WATER B95-068 X
BOGFC2 15-Aug-95 WATER B95-068 X
BOGFC3 15-Aug-95 WATER B95-068 X
BOGFC4 15-Aug-95 WATER B95-068 X
BOGFD3 11-Au -95 WATER B95-068 EQUIP BLANK X
BOGFD4 11-Aug-95 WATER B95-068 EQUIP BLANK X
BOGFD5 15-Au g -95 WATER B95-068 EQUIP BLANK X
BOGFD6 15-Au g -95 WATER B95-068 EQUIP BLANK X
Method References:
Analysis
1. ICP Metals (Unfiltered)
2. ICP Metals (Filtered)
Method
6010
6010
Printed 10/24/95, 3:12 PM 40406DST.XLS 000003

WHC 1993, Dcda Validntion Procedures for Chemical Analyses, WHC-SD-EN-SPP-002, Rev. 2,
Westinghouse Hanford Company, Richland, Washington.
DOE 1992, RCRA Facility Investigation/Corrective Measures Study Work Plan for the 100-HIt-3
Opernble Unit, DOFJRL-88-36, Rev. 0, Department of Energy-Hanford, Richland, Washington.
40406MTL.NAR; Printed: 20-Oct-95, 3:13 pm 000004

GIASSARY OF VALIDATION APPI.IED QUALdNZQLS (CHEIVIISTRY)
Qualifiers which may be applied by data validators in compliance with the procedures herein are as
follows.
U- Indicates the compound or analyte was analyzed for and not detected in the sample. The value
reported is the sample quantitation limit corrected for sample dilution and moisture content by
the laboratory.
UJ- Indicates the compound or analyte was analyzed for and not detected in the sample. Due to a
QC deficiency identified during data validation, the associated quantitation limit is an estimate.
J- Indicates the compound or analyte was analyzed for and detected. The associated concentration
is an estimate, but the data are usable for decision making purposes.
BJ- Applied to inorganic analyses only. Indicates the analyte concentration was greater than the IDL
but less than the CRDL and is considered an estimated value.
R- Indicates the compound or analyte was analyzed for, detected, and due to an identified QC
deficiency the data are unusable.
UR- Indicates the compound or analyte was analyzed for and not detected in the sample.
Additionally, the data are unusable due to an identified QC deficiency.
40406M'II,.NAR; Printed: 20-Oct-95, 3:01 pm 000005

GLOSSARY OF LABORATORY APPLdED QUALIFIERS
Qualifiers which may be applied by the laboratory in compliance with applicable requirements are as
follows.
Commonly used laboratory metals (inorganic) qualifiers:
U- Indicates the analyte was analyzed for but not detected in the sample.
B- Indicates the analyte concentration is less than the CRDL but greater than the IDL.
)s Indicates the value reported is estimated due to the presence of interference.
N- Indicates spiked sample recovery was not within the control limits.
Indicates duplicate analysis was not within control limits.
40406MTL.NAR; Printed: 20-Oct-95, 3:01 pm 000006

Qualification Sunnnaiy Table
40406IvITT,.NAR; Printed: 20-Oct95, 3:01 pm 000007

Qualification Summary Table
Inorganics (Metals)
ANALYTE TYPE QUALIFIER SAMPLES DQO REASON
AFFECTED
Calcium MINOR J/BJ BOGFD3 B0GF83 ACCURACY No matrix spike performed.
B0GF85 BOGFB9
BOGF99 BOGF81
BOGFD5BOGFC1
BOGFC3 BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
BOGF82 BOGFD6
BOGFC2 BOGFC4
Magnesium MINOR J/BJ BOGFD3 BOGF83 ACCURACY No matrix spike performed.
BOGF85 BOGFB9
BOGF99 BOGF81
BOGFD5BOGFCI
BOGFC3 BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
B0GF82 BOGFD6
BOGFC2 BOGFC4
Potassium MINOR J/BJ/UJ BOGFD3 BOGF83 ACCURACY No matrix spike performed.
BOGF85 BOGFB9
BOGF99 BOGF81
BOGFDSBOGFC1
BOGFC3 BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
B0GF82 BOGFD6
BOGFC2 BOGFC4
Sodium MINOR J/BJ BOGFD3 BOGF83 ACCURACY No matrix spike performed.
BOGF85 BOGFB9
BOGF99 BOGF81
BOGFD5BOGFC1
BOGFC3 BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
B0GF82 BOGFD6
BOGFC2 BOGFC4
Cadmium MINOR UJ BOGFD3 BOGF83 ACCURACY Matrix spike duplicate recovery is
BOGF85 BOGFB9 outside acceptance criteria.
BOGF99 BOGF81
BOGFD5BOGFC1
BOGFC3 BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
BOGF82 BOGFD6
BOGFC2 BOGFC4
Printed 10/20/95, 12:02 PM 40406QLS.XLS
0000M

Qualification Summary Table
Innrn^nir^ lMnfnlcl !f`.nn4 1
ANALYTE TYPE QUALIFIER SAMPLES DQO REASON
AFFECTED
Aluminum MINOR U BOGFB9 BOGFCI BLANKS Preparation blank value is positive and
BOGFC3 BOGFC4 outside acceptance criteria.
BOGFD4 BOGFD6
BOGF82 BOGF83
BOGF84
Iron MINOR U BOGFBO B0GFC0 BLANKS Preparation blank value is positive and
BOGFC1 BOGFC2 outside acceptance criteria.
BOGFC3 BOGFC4
BOGFD3 BOGFD4
BOGFD5 BOGFD6
BOGF81 BOGF82
BOGF83 BOGF84
BOGF86 BGGF99
Zinc MINOR U BOGFBO BOGFCO
BOGFC2 BOGFD5
BOGF81 BOGF84
BOGF85 BOGF86
B0GF99
BLANKS Preparation blank value is positive and
outside acceptance criteria.
Potassium MINOR U BOGFBO BOGFB9
BOGFCO BOGFC1
BOGFC2 BOGFC3
BOGFC4 BOGFD3
BOGFD4 BOGFD6
BOGF81 BOGF82
B0GF83 B0GF84
B0GF85 BOGF86
BOGF99
BLANKS Calibration blank value is positive and
outside acceptance criteria.
Barium MINOR U BOGFD3 BOGFD4 BLANKS Calibration blank value is positive and
BOGFD5 BOGFD6
outside acceptance criteria.
.
Beryllium
Copper
MINOR
MINOR
U
BJ/UJ
B0GF86
I
BOGFBO B0GFC1
BOGFC2 BOGFC3
BOGFC4 BOGFD3
BOGFD4 BOGFD5
BOGFD6 BOGF82
B0GF83
BLANKS
BLANKS
Calibration blank value is positive and
outside acceptance criteria.
Calibration blank value is negative and
outside acceptance criteria.
Manganese MINOR U BOGFBO BOGFCO
BGGFCI BOGFC2
BOGFC3 BOGFC4
BLANKS Calibration blank value is positive and
outside acceptance criteria.
BOGFD3 BOGFD4
BOGF81 BOGF82
BOGF83 BOGF84
BOGF86 BOGF99
.
Printed 10/20/95, 12:02 PM 40406QLS.XLS 000009

Qualification Summary Table
Inoroanics ( Metalsl (Cont.)
ANALYTE TYPE QUALIFIER SAMPLES DQO REASON
AFFECTED
Silver MINOR U BOGFCO BOGFC3 BLANKS Calibration blank value is positive and
BOGFD6 BOGF82 outside acceptance criteria.
Vanadium MINOR U BOGFBO BOGFB9 BLANKS Calibration blank value is positive and
BOGFCO B0GFC1 outside acceptance criteria.
BOGFC2 BOGFC3
BOGFC4 BOGF81
BOGF82 BOGF83
BOGF84 BOGF85
BOGF99
Vanadium MINOR BJ/UJ BOGFC4 BOGFD3 BLANKS Calibration blank value is negative and
BOGFD4 BOGFD5 outside acceptance criteria.
BOGFD6
Inoraanics ( Metals/Cvanide) Field QC
ANALYTE TYPE QUALIFIER FIELD QC DQO ASSESSMENT
SAMPLES
Calcium Equipment NONE BOGFD3 BLANKS Equipment blank contamination noted.
Magnesium Blank
Sodium
Zinc
Calcium Equipment NONE BOGFD4 BLANKS Equipment blank contamination noted.
Chromium Blank
Cobalt
Magnesium
Sodium
Zinc
Calcium Equipment NONE BOGFD5 BLANKS Equipment blank contamination noted.
Magnesium Blank
Sodium
Calcium Equipment NONE BOGFD6 BLANKS Equipment blank contamination noted.
Magnesium Blank
Sodium
Zinc
Comments:
Data qualification is not required based on field QC, however, field QC results are noted here
to alert the data user to uncertainties in the data set during decision making processes.
Printed 10/24/95, 10:15 AM 40406QLS.XLS
000010

40406MII,.NAR; Printed: 20-Oct-95, 3:14 pm
Data Summary Table
000011

METALS
DATA SUMMARY TABLE
LATA ID#: VB404.06 HEIS #: BOGFBO BOGFB9 BOGFCO BOGFC1 BOGFC2 BOGFC3
Date: 14-Aug-95 14-Aug-95 14-Aug-95 15-Aug-95 15-Aug-95 15-Aug-95
Matrix: WATER WATER WATER WATER WATER WATER
Constituent CAS # Units Results Q Results Q Results Q Results Q Results Q Results Q
Aluminum 7429-90-5 pg/L 24.61 U 28.8 U 24.6 U 29.7 U 24.6 U 92.8 U
Antimony 7440-36-0 pg/L 45.91 U 45.9 U 45.9 U 45.9 U 45.9 U 45.9 U
Barium 7440-39-3 pg/L 59.3 B 49.2 B 42.6. B 28.8 B 29.9 B 39.1 B
Beryllium 7440-41-7 pg/L 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U 0.50 U
Cadmium 7440-43-9 pg/L 3.1 UJ 3.1 UJ 3.1 UJ 3.1 UJ 3.1 UJ 3.1 ,UJ
Calcium 7440-70-2 pg/L 38600 J 32500 ;:J 30200 Jr 27300 28100 J. 29000 .J
Chromium 7440-47-3 pg/L 42.2 42.4 11.2; B 13.8 B 9.6 B 24.5
Cobalt 7440-48-4 pg/L 4.3 U 4.3 U 4.31 U 4.3 U 4.3 U 4.8 B
Copper
Iron
7440-50-8
7439-89-6
pg/L
pg/L
4 7 W
48 0 U
9.8
993
B 12.5
31.0
B 4 . 7 ^J
59 . 1 ^
4 . 7 ':UJ
29.3
4.7 ^1J
# ^ 138 Uy;
Magnesium
Manganese
Nickel
Potassium
Silver
Sodium
7439-95 -4
7439-96-5
7440-02-0
7440-09-7
7440-22-4
7440-23-5
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
/L
12400
2.6 ^=
14.2 U
5630 5, 2.2 U
12000 J"
15 2 ^J
5550
8.6 B
14.2 U
3750 UJ's
2.2 U
5140 ^J4
9 8
5160 ^Ja^ 10600 .J.; 10900 9710
3.2 2.3 .1 2.0 5 . 4
14.2 U 14.2 U 14.2 U 14.2 U
2080 _ 6020 U 5560 ^ 6790 • %
3.3 ` 2.2 U 2.2 U 4.0
4550 J^V
11 7 ^ 19150
Vanadium
Zinc
7440-62-2
7440-66-6
pg
pg/L
r
20.5 ^
. ^
56.7
00 J-{ 19600 ^ 17500
.
4
15 . 2 ^•
Uf: 9 . 4 .
1 1 . 9 ;•..U . 34 . 4
16 . 5 z`^U ^ 69 . 3
Shaded areas indicate changes by the validator.
10/20195, 12:14 PM 40406DST.XLS, METALS
8m
ll-ro46
0000/2
}+OOu.Lv

METALS
DATA SUMMARY TABLE
LATA ID#: VB404.06 HEIS #: BOGFC4 BOGFD3 BOGFD4 BOGFDS BOGFD6 B0GF81
Date: 15-Aug-95 11-Aug-95 11-Aug-95 15-Aug-95 15-Aug-95 14-Aug-95
Matrix: WATER WATER WATER WATER WATER WATER
Constituent CAS # Units Results Q Results Q Results Q Results Q Results Q Results Q
Aluminum 7429-90-5 pg/L 34.4 U 24.6 U 32.61 U 24.61 U 28.21 U 24.61 U
Antimony 7440-36-0 pg/L 45.9 U 45.9 U 45.9 U 45.9 U 45.9 U 45.9 U
Barium 7440-39-3 pg/L 38.6 B 3.4 , U 3.71 U 3.5 3.71 U 50.6 B
Beryllium 7440-41-7 pg/L 0.50 U 0.50 U 0.50 U 0.50 U 0.50' U 0.50 U
Cadmium 7440-43-9 pg/L 3.1 U4 3.1 UJ 3.11 UJ 3.1 UJ 3.1 UJ 3.1 UJ
Calcium 7440-70-2 pg/L 28300 1940 BJ 2280 BJ 2330 15 2170 BJ 49100 ' J
Chromium 7440-47-3 pg/L 18.1 B 2.8 U 5.0 B 2.8 U 2.81 U 27.8
Cobalt 7440-48-4 pg/L 4.3 U 4.3 U 4.8; B 4.3 U 4.3! U 4.3 U
Copper 7440-50-8 pg/L 4.7 UJ 4.7 . ^UJ
4.7 UJ 4.7 i J 4.7 UJ 17.8 B
Iron 7439-89 -6 pg/L 60.3 ^U , 33.0 /^U_ 26.9 U. 23 ^"s 36.8 ".U : 54 2 ` U
il
Magnesium 7439-95 -4 Ng/L 9550 291 BJ 420 309 BJ; 339 14800
Manganese 7439-96-5 pg/L 1.7 ;, 1.8 WE
2.1 1.4 U 1.4 U 3.9 U:f
Nickel 7440-02-0 pg/L 14.2 U 14.2 U 14.2 U 14.2 U 14.2 U 14.2 U
Potassium 7440-09-7 pg/L 5890 ^7J 1470 2010 1060 ; . ili 2030 UJ; 5470 ,.
Silver 7440-22-4 pg/L 2.2 U 2.2 U 2.2 U 2.2 U 2.6 2.2 U
Sodium 7440-23-5 pg/L 17300 *J ry 424 BJ` 501 B I 495 .BJ. 791 °B^ 11200
Vanadium 7440-62-2 pg/L 7 . 4 'y
3 . 8 UJ 3 . 8 UJ 3 8 ^J J 3 . 8 tl^J ^ 20 2 U a
°^ . ^
Zinc 7440-66-6 pg/L 43.8 29.8 24.8 ^ 19.4
. U.j: 32.6 18.6
N
©D00l3
o99012^
Shaded areas indicate changes by the validator.
10/24/95, 3:19 PM 40406DST.XLS, METALS ' ,,,

LATA ID#: VB404.06 HEIS #:
Date:
Matrix:
METALS
DATA SUMMARY TABLE
B0GF82
14-Aug-95
WATER
BOGF83
11-Aug-95
WATER
BOGF84
11-Aug-95
WATER
B0GF85
14-Aug-95
WATER
B0GF86
14-Aug-95
WATER
B0GF99
14-Aug-95
WATER
.
Constituent CAS # Units Results Q Results Q Results Q Results Q Results Q Results Q
Aluminum 7429-90-5 pg/L 25.4 U 46.4 U 29.6 U 24.6 U 24.6 U 24.6 U
Antimony 7440-36-0 pg/L 45.9 U 45.9 U 45.9 U 45.9 U 45.9 U 45.9 U
Barium 7440-39-3 Ng/L 61.3 B 59.3 B 56.1 B 128 B 118 B 50.9 B
Beryllium 7440-41-7 pg/L 0.50 U 0.50 U 0.50 U 0.50 U 0.50 'lf 0.50 U
Cadmium 7440-43-9 pg/L 3.1 UJ 3.1 U,1 3.1 U.! 3.1 UJ 3.1 UJ 3.1 UJ
Calcium 7440-70-2 pg/L 59400 J 74500 J 70700 J 111000 J 104000 32300 J
Chromium 7440-47-3 pg/L 33.6 170 162 47.2 43.9 50.6
Cobalt 7440-48-4 pg/L 4.3 U 4.3 U 4.3 U 4.3 U 4.3 U 5.4 B
Copper 7440-50-8 pg/L 5.1 BJ 9.6 BJ 8.7 B 14.1 B 15.5 B 9.7 B
Iron 7439-89-6 pg/L 47 . 7 l^. 98.4 U 55.9 U 219 144 U- 129 U
Magnesium 7439-95-4 pg/L 18100 J 17300 J 16600 J 24500 J, 23000 J 10300 J
Manganese 7439-96-5 pg/L 3.3 U 6.7 U 4.8 U. 12.6 B 6.5 U 5.3 U
Nickel 7440-02-0 pg/L 14.2 U 24.5 B 19.0 B 14.2 U 14.2 U 14.2 U
Potassium 7440-09-7 pg/L 6540 UJ 4860 UJ 6400 UJ 6480 UJ 6130 UJ 6260 UJ
Silver 7440-22-4 pg/L 2.3 U 2.2 U 2.2 U 2.2 U 2.2 U
Sodium 7440-23-5 Ng/L 13900 1 11900 J 11200L j-' 1 J 11300 J 9760 J
Vanadium 7440-62-2 pg/L 13.9 U 16.2 U. 17.4
U 23.2 20.6
Zinc 7440-66-6 Ng/L 28.5 385 17.3 U. 20.8 U 17.8 U
Shaded areas indicate changes by the validator.
10/20/95, 12:16 PM 40406DST.XLS, METALS
000014

Sample Results (Fonn I's)
40406MTL.NAR; Printed: 20-Oct-95, 3:01 pm 000015

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFBO
I
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER Lab Sample ID: D9123-007
Level (low/med): LOW Date Received: 08/15/95
% Solids: 07-u
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No. Analyte Concentration C Q
7429-90-5 AumTinum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 59.3 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 kf _N
7440-70-2
Calciu[n
3T600
7440-47-3 Chromiua 42.2
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 4.7 Z
7439-89-6 Iron 48.0 Z
7439-95-4 Magnesium 12400
7439-96-5 Manganese 2.6 ^
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 5630
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 12000
7440-62-2 Vanadium 15.2
7440-66-6 Zinc 20.5
Clarity Before:
Clarity After:
'vVVl11G
M
P
P
P
P
P vT
P J--
P
P
P
P V
P T
P J
P
P (JS
P
P J"
P U
P
Texture:
Artifacts:
SW-846

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
% Solids: 0.0
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGFB9
Contract: 550.93
SAS No.: SDG No.: W0671
LaF Sample ID: 9123-002
Date Received: 08/15/95
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A uminum 28.8 ^
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 49.2 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium_
3.1
7440-70-2 Calcium
32500 _
7440-47-3 Chromium_ 42.4
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 9.8 B
7439-89-6 Iron 993 _
7439-95-4 Magnesium 5550
7439-96-5 Manganese 8.6 B
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 3750 X
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 5140
7440-62-2 Vanadiuu 9.8
7440-66-6 Zinc 56.7
Clarity Before:
Clarity After;
FORM I - IN
_N
IM
oooos7
P U
P
P
P
P U^
P J'
P
P
P
P
P T
P
P
P
P
P_ T
P (J
P
Texture:
Artifacts:
SW-846
co- G-0-44`5

Lab Name: QUANTERRA MO
Lab Code: ITMO -'ase No.:
Matrix (soil/water): WATER
Level (low/med): LOW
o Solids: 0.0
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
BOGFCO
Contract: 550.93
SAS No:: SDG No.: W0671
LaT^ Sample ID: D9123-
Date Received: 08/15/95
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No. Analyte Concentration C Q
7429-90-5 AuTminum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 42.6 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 jd _N
7440-70-2
Calcium-
30200
7440-47-3 Chromium 11.2 B
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 12.5 B
7439-89-6 Iron 31.0
7439-95-4 Magnesium 5160
7439-96-5 Manganese 3.2 ^
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 2080 X
7440-22-4 Silver 3.3 19
7440-23-5 Sodium 4550
7440-62-2 Vanadiuu_ 11.7
7440-66-6 Zinc 11.9
Clarity Before:
Clarity After:
IM
P
P
P
P
P vT
P ,T
P
P
P
P U
P_ f
P U
P
P VT
P V
P r
P U
P_ ll
Texture:
Artifacts:
6^9s
ft100 :
SW-846
caGc.9 7^

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFC1
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER LaE bample ID: 9128-002
Level (low/med): LOW Date Received: 08/16/95
% Solids: 07
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A unum 29.7 X
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 28.8 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 11 _N
7440-70-2
Calcium
27300
7440-47-3 Chromium 13.8 B
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper_ 4.7
7439-89-6 Iron 59.1
7439-95-4 Magnesium 10600
7439-96-5 Manganese 2.3 JT
7440-02-0 Nickel 14.2 U
7440-09-7 Potass ium 6020
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 19000
7440-62-2 Vanadiuu 15.4
7440-66-6 Zinc 34.4
Clarity Before:
Clarity After:
FORM I - IN
IM
/0-209^
P U
P
P
P oJ
P_J-
P
P
P Uzi-
P_ U
P_ S
P
P UJ
P
P_
P_ U
flOQO19
Texture:
Artifacts:
SW-846
000001^

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
% Solids: 0.-0
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFC2 I
Contract: 550.93
SAS No.: SDG No.: W0671
LaT^ Sample ID: D9128-005
Date Received: 08/16/95
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A uminum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 29.9 B
7440-41-7 Beryllium 0.50 U
7440-43-9
7440-70-2
Cadmium
Calcium
3.1
28100 rd"
7440-47-3 Chromiua_ 9.6 B
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper_ 4.7 U
7439-89-6 Iron 29.3
7439-95-4 Magnesuim 10900
7439-96-5 Manganese 2.0
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 5560
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 19600
7440-62-2 Vanadium 15.2
7440-66-6 Zinc 16.5 ^
Clarity Before:
Clarity After:
FM
P
P_
IP
P
P Vj-
P ..T
P
P
P clT
P V
P ,T
P ()
P
PtIS
P
P_ 5
P_
I I
FORM I - IN ^
Texture:
Artifacts:
/O.?P 75
0U0Om
SW-846
O6CCG"'

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFC3 I
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
SAS No.: SDG No.:
- LT Sample ID:
W0671
9128-003
Level (low/med): LOW Date Received: 08/16/95
°c Solids: 0-0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 AuTinum 92.8
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 39.1 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1
7440-70-2 Calcium
29000 _
7440-47-3 Chromium_ 24.5
7440-48-4 Cobalt 4.8 B
7440-50-8 Copper 4.7
7439-89-6 Iron 138 _
7439-95-4 Magnesium 9710
7439-96-5 Manganese 5.4
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 6790
7440-22-4 Silver 4.0
7440-23-5 Sodium 17500
7440-62-2 Vanadium_ 9.4 b'
7440-66-6 Zinc - 7T9.3
Clarity Before:
Clarity After:
IM
P U
P
P
P ^
P
P
P
P U^
P U
P ,T
P U
P
P US
P U
P
P U
P
Texture:
Artifacts:
^^-^^
^00M
SW-846
Li 0 tl ii lJ ^

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGFC4
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER La Sample ID: D9128-006
Level (low/med): LOW Date Received: 08/16/95
o Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A uminum 34.4
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 38.6 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 X _N
7440-70-2 Calcium
28300
7440-47-3 Chromium_ 18.1 B
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper_ 4.7 e
7439-89-6 Iron 60.3 .9
7439-95-4 Magnesium 9550
7439-96-5 Manganese 1.7 ,$
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 5890
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 17300
7440-62-2 Vanadium 7.4
7440-66-6 Zinc 43.8
Clarity Before:
Clarity After:
FORM I - IN
M
P (I
P
P
P
P (.S
P ^
P
P
P_ CJT
P U
P J
P [J
P
P U'r
P
P ^
P 0,S
P
Texture:
Artifacts:
C^ ^^ CO
0
000=
SW-846

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
% Solids: 0^
Color Before:
Color After:
Comments:
U.S. EPA - CLP
1
INORGANIC ANALYSES DATA SHEET
I
EPA SAMPLE NO.
BOGFD3
Contract: 550.93
SAS No.: SDG No.: W0671
Lab Sample ID: 9116-001
Date Received: 08/14/95
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No. Analyte Concentration C Q
7429-90-5 AuTmunuu 24.6 U
7440-36-0
7440-39-3
Antimony_
Barium
45.9 U
3.4 g
7440-41-7 Berylllum 0.50 U
7440-43-9 Cadmium_
3.1 Jd'
7440-70-2
7440-47-3
Calcium
Chromiua_
1940
2.8
)2'
U
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper_ 4.7 ,Y1
7439-89-6 Iron 33.0
7439-95-4 Magnesium 291
7439-96-5 Manganese 1.8 z
7440-02-0 Nickel 14.2 U
7440-09-7 Potassim 1470 B
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 424
7440-62-2 Vanadiuu 3.8 j^
7440-66-6 Zinc 29.8
Clarity Before:
Clarity After:
IM
P
P
P l)
P (JJ-
P- 2rT
P
P
P .T
P (J
P_ zzy
P (]
P
P Uo--
P
P Ti-
P UT
P
Texture:
Artifacts:
/1 SW-846
/'r/
lD.2o.9^
00pp=
OGv^O ^

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGFD4
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER --L--aS °ample ID: D9116-003
Level (low/med): LOW Date Received: 08/14/95
s Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
7440-39-3
AuTminum
Antimony
Barium
32.6
45.9
3.7
W
U
7440-41-7
7440-43-9
Beryllium
Cadmium
0.50
3.1
U
^
7440-70-2
Calcium
2280
7440-47-3 Chromium 5.0 B
7440-48-4 Cobalt 4.8 B
7440-50-8 Copper 4.7
7439-89-6 Iron 26.9 ^
7439-95-4 Magnesium 420
7439-96-5 Manganese 2.1 ,B
7440-02-0 Nickel 14.2 U
7440-09-7 Potass^.um 2010 ,g
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 501
7440-62-2 Vanadium_ 3.8 T^
7440-66-6 Zinc 24.8
Clarity Before:
Clarity After:
,B
N
IM
P U
P
P U
P
P U.T
P
p
P
P (^CT
P cJ
P P
P
P
P_
P
P bJ
P UJ
P
Texture:
Artifacts:
SW-846
000024 00 0 e0`G

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
Lab Name: QUANTERRA MO Contract: 550.93
I BOGFDS I
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix ( soil/water): WATER Lab Sample ID: 9128-001
Level ( 1ow/med): LOW Date Received: 08/16/95
% Solids: 0-.U
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 AuTminum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 3.5 }3'
7440-41-7 Beryllium 0.50 U
7440-43r9 Cadmium
3.1 ,Y(
7440-70-2 Calcium -7330 ^
7440-47-3 Chromiua 2.8 U
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper_ 4.7 J^
7439-89-6
Iron 23.5 ,8
7439-95-4 Magnesium 309 ^
7439-96-5 Manganese 1.4 U
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 1060 J-,r _
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 495 X
7440-62-2 Vanadium 3.8 I?
7440-66-6 Zinc 19.4 ^
Clarity Before:
Clarity After:
FORM I - IN
N
IM
P
P
P
P
P_ UT
P
P
P
P UT
P_ U
P
P_
P UT
P
P S3^
P_tJT
P U
Texture:
Artifacts:
SW-846
000025 0000
0^3

U.S. EPA - CLP
1 EPA SAMPLE NO
INORGANIC ANALYSES DATA SHEET
I BOGFD6 I
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER LaE Sample ID: D9128-004
Level (low/med): LOW Date Received: 08/16/95
% Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
A uminum
Antimony
28.2 )9
45.9 U
7440-39-3
7440-41-7
Barium
Beryllium
3.7
X
0.50 U
7440-43-9 Cadmium
3 . 1 J^
7440-70-2 Calcium
2170 ^
7440-47-3 Chromium 2.8 U
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper_ 4.7 f^
7439-89-6
Iron 36.8
7439-95-4 Magnesium 339
7439-96-5 Manganese 1.4 U
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 2030
7440-22-4 Silver 2.6 9
7440-23-5 Sodium 791
7440-62-2 Vanadiuu 3.8 R7
7440-66-6 Zinc 32.6
Clarity Before:
Clarity After:
N,
IM
P U
P
P f)
P
P vs
P P
P
P U0-
P P
P PP US
P U
P
P /J'.S
P
0000=
Texture:
Artifacts:
SW-846
cocca 4

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF81
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: WO 71
Matrix (soil/water): WATER --L-aE Sample ID: 9123-004
Level (low/med): LOW Date Received: 08/15/95
°s Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 A um 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 50.6 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3 . 1
7440-70-2 Calcium
49100 _
7440-47-3 Chromiua 27.8
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 17.8 B
7439-89-6 Iron 54.2 ^
7439-95-4 Magnesium 14800 _
7439-96-5 Manganese 3.9
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 5470
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 11200
7440-62-2 Vanadium 20.2
7440-66-6 Zinc 18.6
Clarity Before:
Clarity After:
FORM I - IN
_N
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
p
P
P
P
U
^
Q-
U
v
Texture:
Artifacts:
SW-846
000027 000C0^s/

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
.
BOGF82
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No:: SDG No.: W0671
Matrix (soil/water): WATER Lab Sample ID: D9123-008
Level (low/med): LOW Date Received: 08/15/95
Solids: o-.U
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 AuTminum 25.4
7440-36-0 Antimony 45.9 U
7440-39-3 Barium 61.3 B
7440-41-7 Beryllium 0.50 U
7440-43-9 Cadmium
3.1 XJ _N
7440-70-2 Calcium'
59400 _
7440-47-3 Chromiua 33.6
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 5.1 ^
7439-89-6 Iron 47.7
7439-95-4 Magneslum 18100
7439-96-5 Manganese 3.3
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 6540
7440-22-4 Silver 2.3 9
7440-23-5 Sodium 13900
7440-62-2 Vanadium 13.9
7440-66-6 Zinc 28.5
Clarity Before:
Clarity After:
M
P
P
P
P
P rJT
P .T
P
P
P gJ
P_
P S
P Cl
P_
P (/T
P
p_ .T
P V
P
a
Texture:
Artifacts:
^f SW-846
/la-20 9S
000028 Q
0 G ^'0 6

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
I BOGF83
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER ---L--aB Cample ID: 9116-002
Level (low/med): LOW Date Received: 08/14/95
% Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No. Analyte Concentration C Q
7429-90-5 A umm 46.4
7440-36-0
7440-39-3
7440-41-7
7440-43-9
7440-70-2
7440-47-3
7440-48-4
7440-50-8
7439-89-6
Antimony_
Barium
Beryllium
Cadmium
Calcium
Chromium_
Cobalt
Copper
Iron
45.9
59.3
0.50
3.1
74500
170
4.3
9.6
U
B
U
;d _N
_
U
7439-95-4
7439-96-5
Magnesium
Manganese
17300
6.7
7440-02-0
7440-09-7
7440-22-4
7440-23-5
7440-62-2
7440-66-6
Nickel
Potassium
Silver
Sodium
Vanadium
Zinc
24.5 B
4860 0
2.2 U
11900
16.2
385
Clarity Before:
Clarity After:
IM
FORM I - IN a^
^/
y
P U
P
P
P
P (Ja
P T
P
P
P_ LiT
P_
P_ T
P v
P_
P /JT
P
P_ T
P
P
Texture: _
Artifacts:
119_20.9^
SW-846
000029 0 0 G C 3,8f

Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (low/med): LOW
°s Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units
U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF84
Contract: 550.93
SAS No.: SDG No.: W0671
LaB Sample ID: D9116-004
Date Received: 08/14/95
(ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
A uum
Antimony_
29.6
45.9 U
7440-39-3
7440-41-7
7440-43-9
Barium
Beryllium
Cadmium
56.1
0.50
3.1
B
U
7440-70-2
Calcium
70700 _
7440-47-3 Chromium_ 162
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper 8.7 B
7439-89-6 Iron 55.9 ,e
7439-95-4 Magnesium 16600
7439-96-5 Manganese 4.8
7440-02-0 Nickel 19.0 B
7440-09-7 Potass^.um 6400
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 11200
7440-62-2 Vanadium 17.4
7440-66-6 Zinc 17.3
Clarity Before:
Clarity After:
FORM I - IN
_N
IM
/0-71^ •9s
P (1
P
P
P uJ'
P .7-
P
P
P
P U
P_ T
P_ U
P
P UT
P
P
P_ U
P_ U
Texture:
Artifacts:
SW-846
ocJcW^
000030

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF85
Lab Name: QUANTERRA MO
Lab Code: ITMO Case No.:
Matrix (soil/water): WATER
Level (1ow/med): LOW
o Solids: 0.0
Contract: 550.93
SAS No.': SDG No.:
--TaE Sample ID:
Date Received:
W0671
9123-001
08/15/95
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
7440-39-3
AuTminum
Antimony_
Barium
24.6
45.9
128
U
U
B
7440-41-7 Beryllium 0.50 U
7440-43-9
7440-70-2
Cadmium
Calcium
3.1
111000
Jd _N
_
7440-47-3 Chromiua 47.2
7440-48-4 Cobalt 4.3 U
7440-50-8
7439-89-6
Copper
Iron
14.1
219
B
_
7439-95-4 Magnesium 24500
7439-96-5 Manganese 12.6 B
7440-02-0 Nickel 14.2 U
7440-09-7 Potassium 6480
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 12100
7440-62-2 Vanadium_ 20.6
7440-66-6 Zinc 20.4
Clarity Before:
Clarity After:
11V
IM
P
P
P
P
P_ US
P T
P
P
P
P
P ^
P
P
P (JT
P_
P- J-
P_ v
P U
Texture:
Artifacts:
lp'^7 9^ SW-846
/r2
000031

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF866
Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER ----L-aE Sainple ID: D9123-005
Level ( low/med): LOW Date Received: 08/15/95
a Solids: 0.-0
Color Before:
Color After:
Comments:
Concentration Units ( ug/L or mg/kg dry weight): UG/L_
CAS No. Analyte Concentration C Q
7429-90-5 Au.Tinum 24.6 U
7440-36-0 Antimony_ 45.9 U
7440-39-3 Barium 118 B
7440-41-7 Beryllium 0.50 X
7440-43-9 Cadmium
3 . 1 ^J' _N
7440-70-2 Calcium
104000 _
7440-47-3 Chromium_ 43.9
7440-48-4 Cobalt 4.3 U
7440-50-8 Copper_ 15.5 B
7439-89-6 Iron 144 _
7439-95-4 Magnesium 23000 _
7439-96-5 Manganese 6.5
7440-02-0 Nickel 14.2 U
744C-09-7 Potassium 6130
7440-22-4 Silver 2.2 U
7440-23-5 Sodium 11300
7440-62-2
7440-66-6
Vanadium
Zinc
23.2
20.8
B
Clarity Before:
Clarity After:
M
P
P
P
/o •2^'9^
P 1lT
P T
P
P
P
P V
P= T
P V
P
P uJ"
P
P 0-
P_
P (f
Texture:
Artifacts:
000032
SW-846
0 GAGR-6'

U.S. EPA - CLP
1 EPA SAMPLE NO.
INORGANIC ANALYSES DATA SHEET
BOGF99
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER LaS Sample ID: 9123-003
Level (low/med): LOW Date Received: 08/15/95
o Solids: 0.0
Color Before:
Color After:
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L
CAS No. Analyte Concentration C Q
7429-90-5
7440-36-0
7440-39-3
7440-41-7
7440-43=9
7440-70-2
A uminum
Antimony
Barium
Beryllium
Cadmium
Calcium
24.6
45.9
50.9
0.50
3.1
32300
U
U
B
U
J3
_
_N_
7440-47-3
7440-48-4
7440-50-8
7439-89-6
7439-95-4
7439-96-5
7440-02-0
7440-09-7
Chromiua_
Cobalt
Copper_
Iron
Magnesium
Manganese
Nickel
Fotassium
50.6
5.4
9.7
129
10300
5.3
14.2
6260
B
B
_
U
7440-22-4
7440-23-5
7440-62-2
7440-66-6
Silver
Sodium
Vanadium
Zinc
2.2
9760
20.6
17.8
U
Clarity Before:
Clarity After:
M
P
P
P
P-
P
P
P
P
P_
P
P
P
P
P
P
P
P
P
S
S
v
Cl^
S
v
v
Texture:
Artifacts:
SW-846
000033 0 0 G 0J,W 0

40406MTL.NAR; Printed: 20-Oct-95, 3:01 pm
Checklist
000034

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
VALIDATIONF A B C ',v ^ E
LEVEL: LY ;^;^•`. ., s:;
. .
. . . .
VALIDATION
PROCEDURE:
. . , . ,:. . . < . .........
q WHC-CM-5-3, Rev. 0
... .. " .. .... . . .... . , . .., . . .., .. ,<
q WHC-SD-EN-SPP-002, Rev. 2
.. » ,.. < ^.,.
PROJECT:
100-HR-3 ROUND
9 PHASE II
dyV1
SDG: W0671-QES
VALIDATOR: B MORRISI!- P9+ LATA NO: VB404.06 DATE: 19-Oct-95
REVIEWER:
h`5 A-1rt
B SEYMOUR LAB: QES
DOE/RL-88-36,
CASE: N/A
SAF NO: B95-068 QAPP NO: Rev. 0 SAP NO: N/A
ANALYSES REQUESTED
ICP Metals q ICP Metals
(Unfiltered)
( Filtered)
6010 6010
SAMPLE NO. MATRIX SAMPLE NO. MATRIX
BOGFD3 BOGF83 WATER BOGFD4 BOGF84 WATER
B0GF85 BOGFB9 BOGF86 BOGFCO
BOGF99 BOGF81 BOGFBO B0GF82
BOGFD5 BOGFCI B0GFD6 BOGFC2
BOGFC3 BOGFC4
1. DATA PACKAGE COMPLETENESS AND CASE NARRATIVE
Yes NU NIH
Is technical verification documentation present? --^ qq
Is a case narrative present? q qq
2. HOLDING TIMES
YES NO NIA
II See HOLDING TIME SUMMARY form II
3. INSTRUMENT PERFORMANCE AND CALIBRATIONS
Were initial calibrations performed on all instruments? --^
q q
Are initial calibrations acceptable? ^-- ^ q q
Are ICP interference checks acceptable? '-- ^ q
Were ICV and CCV checks performed on all instruments? '- ) q q
rul
Are ICV and CCV checks acceptable? '- j q q
Validation calculation checks were performed and are acceptable.
ai q q
11 If NO(s) are checked, see CALIBRATION DATA SUMMARY form . 11
40406MTL.XLS, Checklist
PNO-DVF-014, R2 10/24/95, 3:15 PM
000035

4. BLANKS
LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
Were ICB and CCB checks performed for all applicable analyses?
Are IC8 and CCB results accep ta
bl e?
YES NO NIA
Were preparat i on bl anks ana l yze d ?
q q^} q
Are preparation blank results acceptable? q ^. ! q
5. ACCURACY
If NO(s) are checked, see BLANK AND SAMPLE DATA SUMMARY form
Were spike samples analyzed at the proper frequency?
Are all spike sample recoveries acceptable? ^^.'J
Are all elements spiked at an appropriate level?
Was a post digestion spike ana l yzed?
q
^'
^J
q
t^y:^l
q
q
YES NO N/A
^^:Jy
^:!
q
q
U q^_ q
^:J q
Are all post digestion spike recoveries acceptable? q^y q -- ^
Were laboratory control samples ( LCS) analyzed at the proper frequency?
Are all LCS recoveries accepta b le? ^^. 1y
q
Validation calculation checks were performed and are acceptable.
6. PRECISION
If NO(s) are checked, see ACCURACY DATA SUMMARY form
Were laboratory duplicates analyzed at the proper frequency?
Are all duplicate RPD values acceptable?
Were MS/MSDs analyzed?
Are all MS/MSD RPD values acceptable?
Were ICP serial dilution samples analyzed at the proper frequency?
Are all ICP serial dilution %D values acceptable?
Validation calculation checks were performed and are acceptable.
q
(^} q
J
^J q q
YES NO N/A
J q i^J
y
q^y q
IJ
4^1 ^ y ^..1 q
^A q q^y
q^y q
4J
^J ^ y q q
^1 q q
11 If NO(s) are checked, see PRECISION DATA SUMMARY form 11
40406MTL.XLS, Checklist
PNO-DVF-014, R2 10/20/95, 11:30 AM
000036

7. FIELD QC SAMPLES
LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
Were field QC samples (field/trip/equip blanks, duplicates, splits, performance audit) identified?
Are fi el d/ tr i p / equ i p bl an k resu lt s accept
a bl e ? ( see Bl ank
Data S ummary form)
Are fi el d d up li cate RPD va l ues accep t a bl e ? (see Fi e ld QC
eva l uation)
A re fi e ld sp lit RPD va l ues accept
a bl e ? (see Fi e ld QC eva l uat i on)
YES NO N/A
^I
q^y
q
U
L_ ! q
q q
Are performance au dit samp l e resu lts accepta bl e?
q
Comments: BOGFD3, BOGFD4, BOGFD5 and BOGFD6 were identified as Equipment Blanks.
8. FURNACE AA QUALITY CONTROL
q
q^}
( ^J
'^y
^^y1 YES NO N/A
Were duplicate injections required? q q ^^}
f
Are all duplicate injection %RSD values acceptable? q q
Were analytical spikes required? q q
Are all analytical spike recoveries acceptable? q^y q ^.I ^
Was MSA required?
Are all MSA results acceptable? q q ^::J
Validation calculation checks were performed and are acceptable. q q q
Comments:
9. REPORTED RESULTS AND DETECTION LIMITS
Are results reported for a ll requested ana l yses?
Are all results supported in th e raw d ata?
q^y ^1 q^y
Are results calculate d proper l y? U^ q^
Do results meet the CRDLs?
Validation calculation check s were performe d and are acceptable.
q
Comments:
VALIDATION SUMMARY
For deficiencies (major and minor) and comments, please refer to the Qualification Summary Table.
40406MTL.XLS, Checklist
PNO-DVF-014, R2 11/1/95, 4:40 PM
YES
L;J
I:J
NO
q
^, J
000037
^:. ^} 1
^} ::. 1
NIA
q
L.
J
q
q q

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
Nnl nIN[; TIME SUMMARY
SDG: W0671-QES VALIDATOR: B MORRIS DATE: 19-Oct-95
PROJECT: 100-HR.3 ROUND 9 PHASE II REVIEWER: B SEYMOUR LATA NO.: VB40406
HEIS-SN
MATRIX
CODE ANALYSIS
DATE
COLLECTED
PREP
DATE
ANALYSIS
DATE
PREP
HT
(days)
Required
HT
da
ANALYSIS
HT
(davs)
Required
HT
da s
BOGF81 WATER ICP Metals 14-AU -95 N/A 06-Sep-95 N/A N/A 23 180 NONE
B0GF82 WATER ICP Metals 14-Au -95 N/A 06-Sep-95 N/A N/A 23 180 NONE
BOGF83 WATER ICP Metals 11-Au -95 N/A OS-Se SS N/A N/A 26 180 NONE
BOGF84 WATER ICP Metals 11-Au g-95 N/A 06-Se -95 N/A N/A 26 180 NONE
BOGF85 WATER ICP Metals 14-Au -86 N/A 06-Se p-95 N/A N/A 23 180 NONE
BOGF86 WATER ICP Metals 14-Au ^S N/A 06-Se ;16 N/A N/A 23 180 NONE
BOGF99 WATER ICP Metals 14-Au S5 N/A 06-Sep-95 N/A N/A 23 180 NONE
BOGFBO WATER ICP Metals 14-Au N/A 06-Sep-95 N/A N/A 23 180 NONE
BOGFB9 WATER ICP Metals 14-Au 96 N/A 06-Se -95 N/A N/A 23 180 NONE
B0GFC0 WATER ICP Metals 14-Au 35 N/A 06-Se p -95 N/A N/A 23 180 NONE
BOGFC1 WATER ICP Metals 15-Au -95 N/A 06-Se 96 N/A N/A 7L 180 NONE
BOGFC2 WATER ICP Metals 15-Au 55 N/A 06-Se p-95 N/A N/A 22 180 NONE
BOGFC3 WATER ICP Metals 15-Aug-95 N/A 06-Se SS N/A N/A 22 180 NONE
BOGFC4 WATER ICP Metals 15-Au g-95 N/A 06•Se J5 N/A N/A 22 180 NONE
BOGFD3 WATER ICP Metals 11-Au g -95 N/A 06-Sep-95 N/A N/A 26 180 NONE
BOGFD4 WATER ICP Metals 11-AU ^S N/A 06•Se -95 N/A N/A 26 180 NONE
BOGFDS WATER ICP Metals 14AU 55 N/A 06-Se N/A N/A 23 180 NONE
B0GFD6 WATER ICP Metals 15-AU -95 N/A 06-Se p-95 N/A N/A 22 180 NONE
PNO-DVF-014, R2
40406MTL.XLS, hold times
10/20195, 11:25 AM
1111 :
VAL
Q

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
RI AAIK IIATA CIIMMARV
SDG: W0671-QES VALIDATOR: B MORRIS DATE: 19-Oct95
PROJECT: 100-HR3 ROUND 9 PHASE II REVIEWER: B SEYMOUR LATA NO.: VB404.06
LAB 2X 5X 10X VAL
BLANK ID ANALYTE RESULT Q RT UNITS RESULT RESULT RESULT SAMPLES AFFECTED Q
Prep Blank Aluminum 76.630 B Ng/L 383.15 BOGFB9 BOGFC1 U
BOGFC3BOGFC4
BOGFD4BOGFD6
BOGF82BOGF83
BOGF84
Prep Blank Iron 40.580 B Pg/L 202.9 BOGFBO BOGFCO U
BOGFC1BOGFC2
BOGFC3BOGFC4
BOGFD3BOGFD4
BOGF05BOGFD6
BOGF81 BOGF82
BOGF83BOGF84
BOGF86BOGF99
Prep Blank 7Jnc 4.490 B Pg/L 2245 BOGFBO BOGFCO U
BOGFC2BOGFDS
BOGF81 BOGF84
BOGF85 BOGF86
BOGF99
Cal Blank Po[assium 2057.4 B Ng/L 10287 BOGFBO BOGFB9 U
BOGFCOBOGFC1
BOGFC2BOGFC3
BOGFC4BOGFD3
BOGFD4BOGFD6
BOGF81 BOGF82
BOGF83BOGF84
BOGF85 BOGF86
BOGF99
Cal Blank Badum 1.4 B Pg/L 7 BOGFD3 BOGFD4 U
BOGFDSBOGFD6
Cal Blank Beryllium 1.2 B Ng/L 6 BOGF86 U
Cal Blank Copper -4.8 B pg/L 9.6 BOGFBO BOGFCI BJ/UJ
BOGFC2BOGFC3
BOGFC4BOGFD3
BOGFD4BOGFDS
BOGFD6 BOGF82
BOGF83
Cal Blank Manganese 1.6 B Ng/L 8 BOGFBO BOGFCO U
BOGFC1BOGFC2
BOGFC3BOGFC4
BOGFD3BOGFD4
BOGFBI BOGF82
BOGF83BOGF84
BOGF86BOGF99
Cal Blank Silver 4.8 B Pg/L 24 BOGFCO BOGFC3 U
BOGFD6BOGF82
Cal Blank Vanadium 4.4 B Pg/L 22 BOGFBO BOGFB9 U
BOGFCOBOGFC1
BOGFC2BOGFC3
BOGFC4BOGF81
BOGF82BOGF83
BOGF84BOGF85
BOGF99
Cal Blank Vanadium -4.3 B NgIL 8.6 BOGFC4BOGFD3 BJ/UJ
PNO-DVF-014, R2
I
40406MTL.XLS, blanks
10124195, 10:12AM
BOGFD4BOGFD5
BOGFD6
000035

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
BLANK DATA SUMMARY
SDG: W0671-QES VALIDATOR: B MORRIS DATE: 19-Oct-95
PROJECT: 100•HR3 ROUND 9 PHASE 11 REVIEWER: B SEYMOUR LATA NO.: VB404.06
LAB 2X 5X 10X VAL
BLANK ID ANALYTE RESULT Q RT UNITS RESULT RESULT RESULT SAMPLES AFFECTED Q
Equipment Blank
BOGFD3 Calcium 1940 B /L NONE NONE
Equipment Blank
BOGFD3 Ma g nesium 291 B /L NONE NONE
Equipment Blank
BOGFD3 Sodium 424 B /L NONE NONE
Equipment Blank
BOGFD3 Inc 29.8 /L NONE NONE
Equipment Blank
BOGFD4 Calcium 2280 B /L NONE NONE
Equipment Blank
BOGFD4 Chromium 5.0 B ijo A- NONE NONE
Equipment Blank
BOGFD4 Cobatt 4.8 B iL NONE NONE
Equipment Blank
BOGFD4 Ma g nesium 420 B /L NONE NONE
Equipment Blank
BOGFD4 Sodium 501 B /L NONE NONE
Equipment Blank
BOGFD4 Inc 24.8 IL NONE NONE
Equipment Blank
BOGFD5 Calcium 2330 B IL NONE NONE
Equipment Blank
B0GFD8 Ma g nesium 309 B /L NONE NONE
Equipment Blank
BOGFDS Sadium 495 B IL NONE NONE
Equipment Blank
BOGFD6 Calcium 2170 B /L NONE NONE
Equipment Blank
BOGFD6 Ma g nesium 339 B /L NONE NONE
Equipment Blank
BOGFD6 Sodium 791 B /L NONE NONE
Equipment Blank
BOGFD6 Zinc 326 /L NONE NONE
40406MTL.XLS, blanks
PNO-DVF-014, R2 10/24KJ5, 10:12 AM
0OD040

U.S. EPA - CLP
3
BLANKS
Lab Name: QUANTERRA MO Contract: 550.93
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Preparation Blank Matrix (soil/water): WATER
Preparation Blank Concentration Units (ug/L or mg/kg): UG/L_
Analyte
AIminum
Antimony=
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt -
Copper_
Iron
Magnesium
Manganese
Nickel
Potassium
Silver
Sodium
Vanadium
Zinc
Initial
Calib.
Blank
(ug/L)
45.9-
0.9
1.1_
3.4
18.2-
2.8-
4.3
4.7
13.7_
51.2
1.4
14.2
3.
2.
C
U
B
B
B
U
U
U
U
B
U
U
U
U
Continuing Calibration
Blank (ug/L)
1 C 2 C 3 C
45.9
4_ U
B
45.9_ U
0.4 U
45.9
0
U
0.6 B 1.2 B
3.1 U 3.1 U
18.2 U
2.8- U
4.3 - U
4.7 U
13.9 B
51.2 U
18.2 U
2.8-_ U
4 U
4.8_ B
_12.7
74.6_ B
1.4_ U
26.9-
2.8 U
4.3 - U
4.7 U
26.7_ B
51.2_ U
1.4_ U
1.
1105.8
U
B
14.2
_1603.6
U
B 2
4.2
57.4
U
B
^ 2.2 U 2.2 _ U
52.5 B 47.4 U 47.4 U
4. .8_ U
U 5 U 2.5 U
FORM III - IN
Preparation
Blank C
45.900 U
0.400 U
0.500 U
3.100 U
85.110 B
2.800 U
4.300 U
0
1.400 U
14.200 U
12 97.210 B
2.200 U
T7.400 U
8DQ- U
490 B
9/l/
lp. yp..95^
vooo4i. 0 ac 4
M
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P
P_
SW-846

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
ACCURACY DATA SUMMARY
SDG: W0671-QES VALIDATOR: B MORRIS DATE: 19-Oct-95
100-HR-3 ROUND 9
PROJECT: PHASE II REVIEWER: B SEYMOUR LATA NO.: VB404.06
PERCENT RECOVERY %R)
Lab
Actual
Spiking
Minimum
Required
Spiking Matrbc
Matrix
Spike
Post
Digestion
Laboratory
Control VAL
HEIS-SN
BOGFD3
ANALYTE
Calcium
RESULTS Q Level Level
No matrix spike performed.
Difference S ike Duplicate Spike Standard SAMPLES AFFECTED
BOGFD3 BOGF83
BOGF85 BOGFB9
BOGF99 BOGFSI
BOGFD5 BOGFC1
BOGFC3BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
BOGF82BOGFD6
BOGFC2 BOGFC4
Q
J/BJ
BOGFD3 Magnesium No matrix spike performed. BOGFD3 BOGF83
BOGF85 BOGFB9
BOGF99 BOGF81
BOGFD5 BOGFC1
BOGFC3BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
BOGF82 BOGFD6
BOGFC2 BOGFC4
J/BJ
BOGFD3 Potassium No matrcc spike performed. BOGFD3 BOGF83
BOGF85 BOGFB9
BOGF99 BOGF81
BOGFD5 BOGFC1
BOGFC3BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
BOGF82 B0GFD6
BOGFC2BOGFC4
J/BJ/UJ
BOGFD3 Sodium No matrix spike performed. BOGFD3 BOGF83
BOGF85 BOGFB9
BOGF99 BOGF81
BOGFD5BOGFCI
BOGFC3BOGFD4
B0GF84 BOGF86
BOGFCOBOGFBO
BOGF82 a0GFD6
BOGFC2 BOGFC4
J/BJ
BOGFD3 Cadmium 3.1 U 50.0 3.1 46.9 77.2% 73.4% BOGFD3 BOGF83
B0GF85 BOGFB9
BOGF99 BOGF81
BOGFD5B0GFC1
BOGFC3 BOGFD4
BOGF84 BOGF86
BOGFCO BOGFBO
BOGF82 BOGFD6
BOGFC2 BOGFC4
UJ
PNO-DVF-014, R2
40406MTL.XLS, accuracy
10/20/95, 11:24AM
^^04d-20

U.S. EPA - CLP
5A
SPIKE SAMPLE RECOVERY
BOGFD3SD
Lab Name: QUANTERRA MO Contract: 550.93 I_
Lab Code: ITMO Case No.: SAS No.: SDG No.: W0671
Matrix (soil/water): WATER_ Level (low/med): LOW_
% Solids for Sample: _0.0
Analyte
A uminum
Antimony_
Barium
Beryllium
C
Calcium
Cobalt -
Copper_
Iron
agnesium
anganese
Nickel
c
S er
odium
Vana ium_
Zinc
Comments:
Concentration Units (ug/L or mg/kg dry weight): UG/L_
Control
Limit
oR
75-125
75-125
75-125
75-125_
75-125_
75-125
75-125
75-1251
75-125
75-125
75-125
Spiked Sample
Result (SSR) C
1990. 8 600
517.0000_
1910.9500_
49.8300_
36.6800_
196.1600
487.1400_
245.9300
1036.7800
484. 400
490.5600
_
_
-_
_
-
_
_
Sample
Result (SR) C
24.6000
45.9000
3.4500
0.5000
3.1000
2.8000
4.3000
4.7000
33.0500
1.8000
14.2000
U
U
B
U
U
U
U
U
B
B
U
Spike
Added (SA) oR
2000.00
500.00
2000.00
50.00
50.00
200.00
500.00
250.00
1000.00
500.00
500.00
99.5
_103.4
_95.4
.4
_98.1
_97.4
98.4
100.4
_96.4
98.1
75-1^ 47.2300 B 2.20 0 U 50.00 94^
75-125
75-125
487.1700
504.3200
3.8000
29.7600
U 500.00
500.00
_97.4
94.9
Q M
FORM (Part 1- IN SW-846
000043
EPA SAMPLE NO.
v'^.^-2o9f
^^
P
P
NR P
P
P
P
-
NR P
NFZ
P
N-R P
P

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
PERCENT RECOVERY (ICV/CCV)
SDG: W0671-QES Date: 19-Oct-95
LATA No.: VB404.06 Validator: B MORRIS
Analyte ICV/CCV ID Observed Value True Value
F O A
Aluminum ICV 39925 40000
Aluminum CCV 38794 40000
Calcium ICV 19891 20000
Calcium CCV 20450 20000
PNO-DVF-014, R2
40406MTL.XLS, ICV CCV recovery
10/20/95, 1:49 PM
%R
99.8%
97.0%
99.5%
102.3%
0000"

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
MATRIX SPIKE RECOVERY (MS)
SDG: W0671-QES Date: 19-Oct-95
LATA No.: VB404.06 Validator: B MORRIS
Analyte Sample ID
Barium BOGFD3
Zinc BOGFD3
PNO-DVF-014, R2
Spike Sample Sample Spike
Result Result Added
F77ii77 SR SA
1907.00 3.45 2000.00
504.54 29.76 500.00
40406MTL.XLS, MS recovery
10/20/95, 1:50 PM
%R
95.2%
95.0%
000045

Aluminum
Zinc
LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
PERCENT RECOVERY (LCS)
SDG: W0671-QES Date: 19-Oct-95
LATA No.: V6404.06 Validator: B MORRIS
Observed value
OLCS
987.65
976.95
ALCS
1000.00
1000.00
40406MTL.XLS, LCS recovery
PNO-DVF-014, R2 10/20/95, 1:50 PM
%R
98.8%
97.7%
000046

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
RELATIVE PERCENT DIFFERENCE
SDG: W0671-QES Date: 19-Oct-95
LATA No.: VB404.06 Validator: B MORRIS
Matrix Spike Matrix Spike
Analyte Sample ID Duplicate
%R %R
Aluminum BOGFD3 99.20 99.50
Manganese BOGFD3 95.60 96.40
40406MTL.XLS, RPD p^ ^ ^ V 1 ^ ^
PNO-DVF-014, R2 11/10/95, 1:48 PM U V
RPD
0.3%
0.8%

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
PERCENT DIFFERENCE (ICP SERIAL DILUTION)
SDG: W0671-QES
LATA No.: VB404.06
Analyte Concentration Analyte Concentration
Analyte before Dilution after Serial Dilution
I
S
Date: 19-Oct-95
Validator: B MORRIS
Calcium 1941.04 2089.13 I 7.6%
Zinc 29.76 42.36 42.3%
PNO-DVF-014, R2
40406MTL.XLS, serial dilution
10120/95, 1:50 PM
%D
000048

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
INORGANICS RESULTS CALCULATION, WATER
SDG: W0671-QES Date: 19-Oct-95
LATA No.: VB404.06 Validator: B MORRIS
Concentration Dilution
Analyte from curve Factor Concentration
CONCW units DFW
Barium-BOGFD3 0.00345 mg/L 1 3.5
Calcium-BOGF83 74.503 mg/L 1 74503
Calcium-BOGFD4 2.2784 mg/L 1 2278
Iron-BOGF84 0.05587 mg/L 1 55.9
40406MTL.XLS, water results
PNO-DVF-014, R2 10/20/95, 1:51 PM
000049

Laboratory Case Nanative
40406MTL.NAR; Printed: 20-Oct-95, 3:01 pm 0CM50

Quanterra 6uorporated
13715 Rider Trail North
Earth City, Missouri 63045
314 298-8566 Telephone
314 298-8757 Fax
Bechtel Hanford Incorporated
P.O. Box 1970
CERTIFICATE OF ANALYSIS
iiiuanterra
Environmental
Services
^^234$s^
Richland, Washington 99352 OCT M5
RECEIVED
September 19, 1995 Data
Log In
Attention: Joan Kessner
lZ0Z6"-
Project number 550.93
Dates Received by Lab August 14, 15, and 16, 1995
Number of Samples . Eighteen (18)
Sample Type Water
SDG Number W0671
Data Deliverable Standalone
1. Introduction
Between August 14 and 16, 1995, eighteen (18) water samples were received by Quanterra,
Richland and transferred to Quanterra, St. Louis for chemical analysis. Upon receipt, the samples
were given the following laboratory ID numbers to correspond with their specific client ID's:
St Louis ID WHC ID Richland ID Matrix Date of Receiot
9116-001 BOGFD3 50824001 Water 08/14/95
9116-002 BOGF83 50824003 Water 08/14/95
9116-003 BOGFD4 50824002 Water 08/14/95
9116-004 BOGF84 50824004 Water 08/14/95
9123-001 BOGF85 50825101 Water 08/15/95
9123-002 BOGFB9 50825103 Water 08/15/95
9123-003 BOGF99 50825105 Water 08/15/95
9123-004 BOGF81 50825107 Water 08/15/95
9123-005 BOGF86 50825102 Water 08/15/95
9123-006 BOGFCO 50825104 Water 08/15/95
9123-007 BOGFBO 50825106 Water 08/15/95
9123-008 BOGF82 50825108 Water 08/15/95
9128-001 BOGFD5 50826801 Water 08/16/95
9128-002 B0GFC1 50826803 Water 08/16/95
000051
♦
T
.. ^n s

Bechtel Hanford Incorporated
September 19, 1995
Project Number: 550.93
SDG: W0671
Page 2
11hranterra
Envitonmental
Services
St Louis ID WHC ID Richland ID Matrix Date of Receipt
9128-003 BOGFC3 50826805 Water 08/16/95
9128-004 BOGFD6 50826802 Water 08/16/95
9128-005 BOGFC2 50826804 Water 08/16/95
9128-006 BOGFC4 50826806 Water 08/16/95
II. Analytical Results/ Methodology
The analytical results for this report are presented by analytical test. Each set of data includes
sample identification information, analytical results and the appropriate detection limits.
Analyses requested: Chloride, Fluoride, Nitrite, Nitrate, Phosphate and Sulfate by EPA method
300.0. ICAP Metals by EPA method 6010. Ammonia by EPA method
350.1. Nitrate/Nitrite by EPA method 353.1. Sulfide by EPA method 9030.
III. Quality Control
A Laboratory (^ontrol Sample and Method Blank were analyzed with each preparation batch.
Matrix Spike and Matrix Spike Duplicate or Sample Duplicate analyses were performed per the
protocol for each analyte.
W. Definitions
The following codes are used to denote laboratory quality control samples and can be found in the
data summary section of this report:
QCBLK- Quality Control Blank, Method Blank
QCLCS- Quality Control Laboratory Control Sample, Blank Spike
000052
^jM^o .2^1-95
^^

Bechtel Hanford Incorporated
September 19, 1995
Project Number: 550.93
SDG: W0671
Page 3
V. Comments
iiuanterra
Enviconmental
9erviccs
The Matrix Spike Duplicate recovery for Cadmium (73.4%) was less than 75 %a therefore all
associated data was flagged with an "N".
The Fluoride analysis on sample 9123-001 was run at a two times dilution because of an
interfering peak, which raised the detection limit.
The Nitrite analysis on sample 9123-003 was run at a five times dilution because of
interference, which raised the detection limit.
The Relative Percent Difference could not be calculated because both values were less than the
detection limit for the Fluoride, Chloride, Sulfate, Phosphate, Nitrite and Nitrate analyses on
sample 9116-001.
On sample 9123-001 a Fluoride peak was integrated as a hit but the peak area is less than the
peak area of the lowest calibration standard, hence, it was reported as less than the detection
limit.
The Relative Percent Difference could not be calculated for the Nitrate/Nitrite and Ammonia
analyses due to the values being below the detection limit for sample 9116-001 and it's
duplicate.
000053
"Jo2{"c1J^

Bechtel Hanford Incorporated
September 19, 1995
Project Number: 550.93
SDG: W0671
Page 4
iouanterra
Enrironmental
Ser,'ic'es
I certify that this data package is in compliance with the SOW, both technically and for
completeness, for other than the conditions detailed above. Release of the data contained in
this hard copy data package has been authorized by the Laboratory Manager or a designee, as
verified by the following signature.
Wade H. Price
Project Manager
e:\\price$\abbydave\hanw0671.nar
000054 ^^y^^

Chain-of-Custody Infonmation
40406MTL.NAR; Printed: 20-Oct-95, 3:01 pm 000055

0A
NVV^
o^ f
Bechtel Henford , Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contect
R. E. Paterson -
Telephone
(509) 372-8638
Project Designation
100-HR-3 Groundwater SampllnH. Round 9. Phase 2
Ice Chest No.
Sampling Location
100 D
Field Logbook No.
SAF No.
D95-088
Method of Shipment
S^L S03 EFG /o! Hand Delivered
Shipped To Offalte Prope ^o.
Quanterre
NA
^
Ponible Sample Hazarda/Remndca preeervaUUon
Special Handling and/or Storage
Melnteln aamplea between 20C and 66C,
BOGFDS
Papa I of 1
Data Turnaround
El Priority
n Normd
Bill ol Lading/Air Bill No.
NA I I
HNO, Cool4•C H3SO4 1 H,SOc HNO3 Cool4•C Cool4°C HNO,
Type of Contelner G G pAlf P pro PIG G PIG A G
No. of Container(e) 1 1 1 3 1 4 3 1 1
Volume
SAMPLE
5nX^
NALYSIS
,506 -
1.\^ /-/ 'r/
lN lJ/
500h,L SOOmL 600mL 500mL 500m? IL 500mL 20mL SOOmL
ICP r1P0n° IICI Metala
(Unfilterad)
F.
o• w«
o,. NO„
po,
NO2 -
NO3
Sulfide
Ammonia Gross
Alpha,
Gross
een.
9r.9D
Tritiu Activity
Scan
lp
]DI
ICP
Metab
(Fllteredl
Sample No. vu Matdz° Data Sempled Time Sampled - ' - -
w
BOGFD6 w
v ^DJ I^^ Jt) J^ OJ
SPECIAL IN::1.iUCTIONS Ma`o`
CHAN.OFPOSSSSION
Sia".'-^ne!'+mee •1
^ .-
ZnAc +N^OH s -sw
:.. ,:k,,:.:^'.:' . .h.
st.e^r
Reli uish If By
3r
S,Aw
h i
d b EPA 300 0 and turbidit
, Y ^ ^^ j^ ^f ^ ^t^o
' it it
L .F n(.^ ^^^^jJ /.^J !^ I ^
r
S•^
phorn nU, n trate, an n r e y - p
y X- ALO"
_ - -- 1 = -^^ ^ • h:. ;on r.ouontad for Infermetion only, The ERC C ontractor w - W . I.
o - ON
..nl••'.afineeillnotbemet.
v• - ' :
r r.-ue
, . . .
.. - ''
...
..
. ..,.
. -... ^
/^^^^a ;^'r.^%:^.^
...
._.:- t
'
.
I. ...... ..- -.^ . _ . . . . . . . ....- , ,^_rv. !..

O O
O
I
^
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of
Data Turnaround
Collector
• Le
Company Contact
R. E. Paterson
Telephone
(509) 372-9838
0 Priority
n Normal
Project Designation
100-HR-3 Groundwater SampBnp, Round 9. Phase 2
Sampling Location
100 D
SAF No.
B95-068
Ice Chest No.
Field Logbook No.
Method of Shipment
^A^-S/ ^
EFL
• / Ulr^ Hand Delivered
Shipped To Offsite Property Bill of Ledine/Air Bill No.
Quanterra NA NA !
Possible Sample Hazards/Remarks
Preservation
Type of Container
HNO3 Cnul4°C H,SO° •1 HtSO. HNOs Cod4°C Cool4°C HNO3
G 'a G P140 P P/0 P)G G PIG /r G
No. of Containerlsl
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain samples between 2°C and G°C.
Volume
SOOmL 500mL 500mL 500mL 500mL 1 L 500mL 20mL 500mL
//
^ L
ICP
Am«u eq
- F. a• So,• NO2 -
SAMPLE ANALYSIS
l.'
^
/ -
() ^ ( f 7
Metals
NO,. NO,.
NO
Sulfide Ammonia Gross Tritium
Alpha ,
Activity
Scan
ICP
Meteb
I
'
J
IUnfiltarad)
Po• Grosa /' ^V
8ete, {-/,
t
^
Sr-90 !
IFilta ra dl
Sample No. Matrix Data Sampled Time Samplad
BOGFC7 (A W 6•lS ij /vy' F y Y+
BOGFC2 Oy W
oJ o) 0-6 3100 0) ^0J
SPECIAL INSTRUCTIONS , uan.•
CHAIN QF POSSESSION Sign/Print Names
•1 ZnAc+NnOH
s - s.i
Relinquished By ^c Dete/Time
Re e B DetaRime SE - sw^.,u
'• k
•
-!i
^js
so
.{•/J^ GSl /3.^5
Sample analysis for
. /f
phosphate, nitrate, and nitrite by
-
EPA 300.0; and turbidity
saa
st - swuo.
qui Oate(rme 9 ecaivad By c^Date/Time
Y EPA 180.1 Is being requested for information only. The ERC Contractor o_ W.I.
^
^- / ecknowled0ae that the 48-hour holding time will not be met. a - µ
a
- - ' >
o s -p,m, sab.
elinquiehed By Data/Time Received By ate/Time The Activity Scan is for all samples listed on this chain of custody.
pt - tLd,t tpue.
T -TUw
YN -
Relinquished By Date/Tme Received by Date/Time L tqIAe
V -VpnJ
% - attw
LAB(JRATORY Received By Title Data/Time
SECpON
FINAI. SAMPLE Disposal Method Disposed By DateMme
dISPOSITIDl1

^
0
Bechtel Hanfard, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector
K
e
L
Com P an y Contact
R. E. Petenon
Tela hone
p
( 50 9) 3 72 -9 638
Project Deeipna6on Sampling Location SAF No.
100-HR-3 Groundwater Samplin0, Round 9, Phase 2 100 D .895-068
Ice Cheet No.
Field Logbook No. C Method of Shipment
-D^
C /O/ Hand DaVivered
Shipped To Offsite Prnpe o. Bill of LadinOfAir Bill No.
Quanterra NA N A I
Possible Sample Hazarde/Remerks Preservation
Type of Container
No. of Containarld
Page 1 of1
Data Turnaround
q Priority
^ Normal
HNO3 Cool4°C H3SO• •1 HiSO' HNO^ Cool4°C Cuol4°C HNO^
G G PIO P P/0 PIG G PIG G
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage Volume
Maintain samples between 2°C and S°C. 500mL SOOmL 500mL SOOmL 500mL IL SOOmL 20mL 500mL
Arueo° llcl
ICP
NO, -
.
Sulfide Ammonia Gross Tritium Activity
ICP
f. a. so..
NO
l h
Scan
Metale
Metale
3
No NO ,
A p a,
SAMPLE ANALYSIS ( Unfilter- po,„ Gross
(Filtered)
^osa^^
Sample No. Matrix• Data Sampled Time Sampled
BOGFC3 D^ W .rs. 1/1
BOGFC4 ol.Y W
^)
(pJ ^O'J 03 OJ 163 IJ^
CHAIN OF POSSESSION Sign/Print Names
SPECIAL INSTRUCTIONS
• 1 2nAc +NeOH
M•"^•'
s - s°+
Rali ha By
R ui
alinquishad By
Deta/Time
'.•L¢^
'^" S s5 /31S
Dete/Time 9•
^/6-fY
Date/Time
R rv
-
Recaived By
Received By
6 Date/iime /j^?s-
^ -^
:./., ete/Time ^^
-^ ^i1-
^Date/rme
SE - Sw°m u
so- sau
Sample analysis for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity y-
b y EPA 180 . 1 is being requested for information only. The ERC Contractor w-^
o- o0
acknowledges that the 48-hour holding time will not be met.
us-n sae°
DL - un.n Iqua°
The Activity Soen is for all samples listed on this chain of custody.
T -Tww
YA - Wp•
Relinquished By Date/Time Received By Date/Time t-
V -
Iqie
vw.r.um
x - mw
LABORATORY
Sl:CTION
Received By Title DataRime
FINAL SAMPLE
DISPO.SITION
Disposal Method Disposed By Date/Time
eate,
9r-9G
'

^
^
N
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1_ of I_
Collector
I'^, Z J
Company Contact
R. E. Pate
Telephone
(509) 372-8638
Data Turnaround
11 Pdodry
n Nortnal
Pro eot Designation Sampbna ocetlon SAF No.
100-HR-3 Groundwatar Sampllny, Round 9, Phaaa 2 100 D fi95-088
Ice Chaat No. Field Logbook No. v^
Method of Stupment
s O 1'
C -/'^ / d
Hand Delivered
Shipped To
Quantarra
ONeita Prop
NA
No.
I
I
I
^1
/''
Bill of LadinO/Au Bill No-
NA / I
Possible Sample HazarddRamerks Preaerve8on
Type of Container
No. of Conteinerlsl
HNO3 Coot4'C HrSO• . 1 H,S04 HNO3 Cool4°C Caol4°C HNO,
AG G P14V P PI® P!G G PIG G
1 1 1 3 1 4 3 1 1
Spacid Handlinp and/or Storage Vulume
Maintain aamplaa between 2•C and 6'C. 500mL 500mL SODmL 500mL 500mL 1L 500mL 20mL SOOmL
C
ICP "u^a I1 NO2 -
Sulfide
Ammonia
Gross Tritium Activity ICP
C^f " x"' Metala - F. Q. $0` NO, Alpha.
Scan Metala
No. NO.
SAMPLE ANALYSIS
(UnBltar- pD,
Gross !ll
IFiltaredl
5o 9a5^ ^^6^ ^1
edl
Bete,
Sr-80
Sample No. Matriz• Date Sampled Time Samplad
BOGF85 01 W
BOGF86 W /1 y
CHAINOFPOSSESSION
Sian/PdntNamea
o::- I03 oD 3dio oJ 10^
SPECIAL INSTRUCTIONS M^^•'
•1 ZnAc+NeOH
.
Rali uithedBy DateTme
^
R v EjL OateRme ^y/0
- _ Sample analyeic for phoephate, nitrete, and rutrite by EPA 300.0; and turbidity
^_^
^_
^-^ Del e(Time
9',^/'
eceived By Gqa,t ata(Time ^Zd
by EPA 180.1 6 beinp requested for Information only. The ERC Contractor
acknowledaee that the 48-hour hoMinp time will not be met.
o- o n
A Nr
DS- D,^ Saas
Relinquie ed By DaleRime Received By The Acdviry Scan is for all samples Pistad on this chain of custody. ^_^tbi1ei
'
Relinqui4had By DataTme fl l ad
"
teTry
/^JU
,
H+ - ww
t- v- u°ize v.w,w>
LABORATORY Raceivad By Title DateRime
.- SECTION
FINAL SAMPLE Disposel Method Disposed By Date/Fime
=-'DI6P68t{iGN-

0
^
a3
r ^ ^
h
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contact Telepfwne
L Q/ l ZU R. E. Peterson (509 ) 372-9638
Page of __]_
Date Turnaround
Proje ct Dealpnation Sampling L ocation SAF No.
100-HR-3 Groundweter SampNnp, Rourd 9, Phaea 2 100 D B95068
lee C aet a. Field Logbook No. Method of Shipment
Shippad To
Sjry[- s°3
Offelte Propert N P .
&cc -/tl 1
Hand Depvered
Bill of Lading/Alt Bill No.
Quantarra NA (7 NA ( A
Possible Sampta HazardelRemarke
Prenrvadon
HNO3 Cool 4•C HrSO, • 1 HtSO. HNO, Cool 4°C Cool 4•C HNO,
0 Poodry
n NomW
Typa of Contalner ^ G G P4 P P,{(t' PIG G PIG /1 G
No. of Container(e)
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Volume
Mdnteln templea between 20C and 69C. 500mL 500mL 500mL SOOmL SOOmL 1 L 500mL 20mL SOOmL
' ,^ / ICP '^"1010 pn NO, - ^^ / y
Sulfide Ammonia Gross Tritium Activity ICP
^'^'` Metals NqNo„- NO, Alpha Qn^ Scan Metals
SAMPLE ANALYSIS ,`
1)1. IUnNter-
171
P01 q, ,
Gross
(Filtered)
ad) Beta, ( ^ 1 W
^v
Sr-9G
50^25/
Sample No. Metrlt• Data Sampled Time Sampled -
BOGFB9 03 W gI, CY'l9S 0 c
BOGFCO 197 W f! Af to if
pO p v ^ o0 3i(lo^ pJ ^rJ
C^AIN QFPQS9E5$IDH Sipn/Pdnt Names
SPECIAL INSTRUCTIONS
• 1 ZnAc+NaOH
r.+.m.^
y _ayi
Re n IehedO Y
R
elinqule ed B y
/r--t ^c Dete/Tima
^^^Clf /^Ca
Dete/Ftme
/.^
Dete/fime
v
Ra eived By
flecelved By
u
Dete(Time ///0 t
Sample andyeia f or phosphate, nitrate, and ni0ite by EPA 300.0; and turbidity
b EPA 180 1 i b i t d f I f tl l Th ERC C t t
eliims .2G y . s e ng reques e or n orrna on on y. e on rac or
ac know i e d pee t h at t h e 48 - h our h o ldi ng t i me w il l not b e met.
ate/Time ^^
a^c^e The Activity Scan is for all eamplee listed on this chain of custody.
/m iri-
SE "
So- aaa
&_OLF10,
Wo _ow
..° ^
4_ u
tu - on.n eae.
D L - T^tW^'
W : Relinquished By Dete/Time R el B
WIP.
l - tp,u
v v.wrw^
lt - oar
LABONATORY Received By Title Date/Time
SECTION -
F1NA1, $AMPLE: Disposal Method Disposed By Date/Time
'°^DISPQBfTYON^

0
0
VuI
r
^
0
h
Bechfel Hanford. Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page _j_ of I_
Collector
I p (r /2 Z ^
Company Contact
R. E. Petsrson
Telephona
(609) 372-9638
Data Turnaround
El Priorit y
^ Normel
ProJeot Dasl9naucn Sampling Location SAF No.
100-HR-3 Groundweter Sampling, Round 8, Phaee 2 100 D B95-088
Ice C est No.
Field Logbook No.
Method of Shipment
/n z-S,( 7
,e FL 0 4' Hand Delivered
Shipped To
Guenturra
Offeitn PtoPerlYo.
NA 1-^
2
(
Bill of Lading /Air Bill No.
NA
Possible Sample Ha:arda/flemarks
Praea(vatlon
HNO, Conl4°C H,SO, •1 H,SO1 HNO, Cool4°C Cool4°C HNO,
Type of Container
No. of Containarlsl
6 G 11 G PQ P PA7 P/G G P/G G
1 1 1 3 1 4 3 1 1
Spacial HendGnp and/or Storage
Maintain samples between 20C and 6•C.
Volume
SOOmL 50GmL SOOmL 500m1 SOOmL 1 L 600mL 20mL 500mL
SAMPLE ANALYSIS
r(
(/I{ l
ICP
Metels
(U o fitt e r-
ad)
A"10"'IICI
-F , a , 60„
NO,. No..
I ' o,
NO2 -
NO3
Sulfids Ammonia
Gross
Alpha,
Groee
Beta, /-
Sr- 9D
Tritium Activity
Seen
ICP
Metals
IFJtered)
50825 ^
Semple No. MatriX• Date Sampled Time Samplad ' " - ' - - - ' -
B0GF99 UJ W
BOGFBO 06 W 5-
' R L (' 1 P4 1 N ^G `a- ^
r) S i goZS IJO
SPECIAL INSTRUCTIONS M•^i.•
CHAIN OF POSSESSION
SiOn/Print
, . -
Names
•1 2nAc+NeOH
y -a°a
.
flali ishad By Date/flme R d Y Dete/Time
3 -/ _
Sanpla analysis for phosphate, nitrnte, and nitrite by EPA 300.0; and turbldity
^: ^a'"Me
tt- y^
q' u' e 6;^L DaIalTime
/^;^/
.
ecaivad By Q// ete/rimn
b y EPA 180 . 1 is bein g re quested for Information onl y. Th e ERC C on t ra ctor
ac k now l e d ges th at t h e 48-h ouf h o ldin g ti me w ill no t b e me t .
w- w.nw
^ -^
elinquishad.By Date/Time Received By Data(Tirn^a The Actlvity Scan is for all enmples listed on this chain of custody.
Its - m.saw
Tt = T^t4"a'
Ww°
Relinquished By
LABDRATORY
SECTION
Date/iime
Received By
Ikk
d BIt .
itle Dete/lime
t- u°"a
V - V9•tWm
X -etl r
FINAL SAMPLE Dispoeal Method Disposed By Dare/Tume
;pISPOSN7GN

^
^
^
- Page 1 of I_
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Data Turnaround f
Colbator
,4(- t o
Co mp any Contact
R.E.Petaraon
Telephone
(5091372-9838
11 Priority
n Normal
Pro(eot Designation SampGnO LoceBon SAF No.
100-HR•3 Groundwater Sampling. Round 9, Pluse 2 100 D B95-088
Ice Chest No.
Field Lopbuok No. ^- ^
Method of Shipment
G-57'L
rL /=C (O/0' Hand Delivered
Shipped To
Qunnterra
Olfeite Proparty
NA
P
h f
Bill of LedinOlAlr Bill No.
NA )
d
Possible Sample HazardslRemarks
prasarvaUon
HNO, Cool4°C HtSO, •1 Hr50, HNO, Cool4°C Coul4°C HNO,
Type of Container ^ G fi-G PIQ P Pl0 PIG G PIG G
No. of Containerls)
1 1 1 3 1 4 3 1 1
Spacld Handling and/or Storage
Maintain samples between 26C and 86C.
' Volume
Snl~
500mL
ICP
SOOmL
A""1O
SOOmL 500mL 500mL 1L 500mL 20mL SOOmL
IICI
SAMPLE ANALYSIS ^ D /_ ^/ .
Metals
(Unfilter-
- Cl . SO. .
F •
K. NO..
Po,
NOt -
NO t
Sulfida
Ammonia
Gross
Alpha,
Groee D
Tq'^( t^l
^Ad
ry'11
^
Activity
Scen
ICP
Metels
IFiltaredl
(l
ad)
Betq
S r-90
^8^51
Sample No. Matrix• Date Sampled Time Sampled
BOGF81 D / W Vey ( 47
BOGF82 W 9/(Y l- /3/&
oJ oz:' oJ 3X(o^ u^ (oJ
CHAIN Q. -
FPOSSESSON
. .., ;.

^
0
GS
Oj
lk
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
'
Collector
f^ ( i t ! 2 Z v /^ ^^ ^ ^
CompsnyContact
R. E. Peterson
Telephone
(509) 372-9838
Data Turnaround
0 Priorit y
^ Normal
Project Designation Sampling Location SAF No.
100•HR-3 Groundwater Sampling, Round 9, Phase 2 100 D 895-088
Ice Chest No.
S/»1- 503
Field Logbook No.
r,= O 1 Y
Method of Shipment
Hand Delivered
Shipped To Ol(sile Prope y QI o.
Bill of Lading/Air Bill No.
Ouantarre NA ^(^" f (^/ NA I
Possible Sample Hazards/Remarka
Preservation
HNO3 CooI4°C H,SO, •1 HrSO• HNO3 Cool4°C Cool4°C HNO,
Tlpe of Conteiner
Na of Containm(e)
4 G 17 G PQ P PA P/G G P/G G
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
yoluma
Maintain samples between 2'C and 8°C. 500mL 500mL 500mL SOOrnl 500nrL 1 L 500mL 201nL SOOmL
SAMPLE ANALYSIS
509 04-0
`u ` 'U t
Sample No. Matrix• Data Sampled Time Sampled
ICP ^1XO"• aCl NO, - Metals ^
Sulfide Ammonia Gross Trilium Activity ICP
F. IUnfiller-
q' W` No,
NO,. NO,.
P0'
Alphe,
Gross
I I I^
Scan Metals
IFilteredl
ed1
Beta .
9 r- 90
BOGFD3 61 W ^/ 3S ^ .^" ^ ' -
BOGFD4 G'.U W ^//^yS //?1^ ^
0 L
^, r^^ r„
CHAIN OF POSSESSION
RelinqvishedBy
_
/^
/
R eGnquished B y
Relinquished By
Dete(Time
ji3
f -
Data/Time
Dete/Tima
Dete/Time
SiOn/Print Names
aceived By
Reeeived By L, I^q
Received By
Oete/time
Data/fime
U
O 9 S
, I h DelelTime
Date/lime
/ 325
SPECIAL INSTRUCTIONS
• 1 Znqc+NeOH
Sample analysis for phosphete, nilrete, and nilrite by EPA 300.0; and turbidity
bb y y EPA 180 . 1 i s b e i ng reques t e d f or i n forma ti on on l y. Th e ERC C ontraclor
acknowled0es that the 46-hour holding time will not be met.
TNe ACIIVIty Scen is for all sampleC llated on this chain of custody.
M•nr.'
S -sa
SE - s.mr,,.m
so-s°xe
o -
•
A o
ur
ps- orun sa.e•
nL - prun LiqW
T - tlsvn-we•
L Lpuda
V - Vq•INi>n
x - UIM
LABORATORY
.SECTION
Received By Tille Dele/lime
FINAL SAMPLE
DISpO5ITI0N
R
Dispoaal Method Disposed By Date/Time

^
^
^VhI
1!^
O^
^s
\
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
'
Collector
2
Comprny Contact
R. E. Pstarron
Telephons
(509) 372-9638
Data Turnaround
0 Pdanty
^ Normal
Project Designation SnmpGnO Lucadon SAF No.
100-HR-3 Groundwater Sampling, Round 9. Phase 2 100 D 895-088
Ice Chest No.
Field Logbook No.
Method of Shipment
M^_fo} ^^
-/0(^ HendDelivered
Shipped To Ollrite Property No. Bill of Ladina/Air Bill No.
Quentern NA t o I I I L NA I
Possible Sample Hazards/Remarks Preearvation
HNOs Cocl4°C HrSO° '1 HrSO. HNOs Cool4°C Coul4°C HNO,t
Type of Container
No. of Conteiner(r)
G G P/, P P/0 P/G G P/G G
1 1 1 3 1 4 3 1 1
Spacial Handling and/or Storage
Maintain sampies between 20C and 60C.
Volume
50omL 500mL 500rnL 500mL 50OmL 1 L 500mL 20mL SOOmL
ICP
Metele
aM°nr11G
'F,a,so,. NOr-
SAMPLE ANALYSIS
^
( Unfiltered)
No,. no,.
I'o,
NO,
Sulfide Ammonia Gross
Alphe ,
Gross
Beta, (,^)
Tritium
^ 1.^
Activity
Scan
ICP
Meteds
IFilteredl
x I ^
S r-90
Sample No. Matrix' Date Sampled Time Sampled -
BOGF83 03 W rQ^^ 5- e_s BOGF84 W
^^ ^^ IoJ 3^r^^ 1.7J (oa
o,, cos
CHAIN OF POSSESSION
Relinqpished B Y ,F..4G Dete rme
Jt LC C
^Deta/Tima
S. 5
Si®n/Print Names
R i B '
^
Received By
Date/Time
Date/time
L
5-
SPECIAL INSTRUCTIONS
' 1 ZnAc + NaOH
Semple analysis for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity
b y EPA 180 . 1 is bein g re quested for Information onl y. The ERC Contractor
acknowled0es that the 48-hour holdinB time will not be met.
M'W°'
s -sml
SE - s°m"."r
u: y^
w - w°uw
o- ou
a-
DS-Uiun6aW
P4
dy DetelTime
Received By 'GCfC ^.q„^ Date ime The Activity Seen is for all samples listed an this chain of custody. ^: ^Mw tb'b°
Relinquiehed By Dete/Time Received By Dete/Fime
yn y/iw
L
v -
tb'b
v.c.ran,
LABORATORY Received By Title Date/Time
SECTION
FINALSAMPLE Dispocel Method Disposed By Date/Time
DISPOSITION
001 1

40406MTL.NAR; Printed: 24-Oct-95, 11:08 am
Supplemental Infobmalion
000065

Z00f(7j
LATA INORGANIC (METALS)
DATAVALIDATION CHECKLIST
INFORMATION REQUEST FORM R
To: Jeanetfe Duncan, WHC/BNI bate: 10/23/95
YM1y
^ li
)7^f
^i 413_
NOW . i
. ^^^ 1Ya ( 'eua , JA:i::N
^ : Y ya ^ ^
PROJECT NAME: 100-1-1R3 ROUND 9 PHASE il
SDG NUMBER: 671-QES
LATA NO.: V54UG.08
LABORATORY: QES
CASE NUMBER: N/A
ANALYSIS METHOD:
ANALYSIS DATE:
ITEM S MISSINCi:
iSF.xy.vy/ y *' 4, gyq l
Comenents: It appeats from the raw data that samples BOGFDS and
BOGFDB are field blanks. These samples are not listed on the Sample SUmmary Table
as field blanKs.
Attention: B MORRIS
RETURN TO LATa
INFORMATION RECEIVED FROM WHC (fNITIALS/DATE): (.e^'
INFORMATION ACCEPTABLE?: YES ^ NO a
If No is checked, send a new LIRF to request additional Information.
000066
40408MTLXLS, URF-1
1023195, 9:17AM
S'IHSBE RSVH OH61 90iZ ZLC 605SI 00:1,T 96/CZ/Oi

40406MTL.NAR; Printed: 20-Oct-95, 3:01 pm
END OF PACKAGE
000067

DATA VALIDATION REPORT
for
100-HR3 GROUNDWATER ROUND 9
PHASE II
General Chemistry Analysis
SDG W0671-QES
LATA VB404.06
Bechtel Hanford Inc.
P.O. Box 969
Richland, Washington
November 2, 1995
404.06GNC.NAR; Printed: 2-Nov-95, 12:50 pm 000000

Table of Contents
Data Validation Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000002
INTRODUCTION .... ........................................... 000002
ANALYSES REQUESTED ......................................... 000002
DATA QUALITY OBJECTIVES ..................................... 000002
REFERENCES ................................................. 000004
GLOSSARY OF VALIDATION APPLIED QUALIFIERS (CHEMISTRY) . . . . . . . . 000005
GLOSSARY OF LABORATORY APPLIED QUALIFIERS . . . . . . . . . . . . . . . . . . 000006
Qualification Summary Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000007
Data Summary Table ... ............................................... 000009
Sample Results ...................................................... 000012
Checklist ........................................................... 000022
Laboratory Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000036
Chain-of-Custody Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000041
Supplemental Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000051
END OF PACKAGE ........... ....................................... 000053
404.06GNC.NAR; Printed: 2-Nov-95, 11:28 am 000001

INTRODUCTION
100-HR-3 GROUNDWATER ROUND 9 PHASE II
Data Validation Narrative
All samples in Sample Delivery Group (SDG) W0671-QES (VB404.06) were validated at level D as
defined in the Data Validation Procedures for Chemical Analysis (WHC-SD-EN-SPP-002, Rev. 2).
The analyses were performed by Quanterra Environmental Services.
ANALYSES REQUESTED
See Table 1.
DATA QUALITY OBJECTIVES
Precision: Goals for precision were met.
Accuracy: Goals for accuracy were met.
Sample Result Verification: All sample results were supported in the raw data.
Detection Limits: Detection limit goals were met for all sample results as specified
in the RCRA Facility InvestigatiordCorrective Measures Study
Work Plan for the 100-HR-3 Operable Unit, DOE/RL-88-36, Rev.
0.
Completeness: The data package was 93% complete for all requested analyses.
MAJOR DEFICIENCIES
Major deficiencies were identified during validation which required qualification of data as unusable.
See the "Qualification Summary Table".
MINOR DEFICIENCIES
Minor deficiencies were identified during validation which required qualification of data as estimated.
See the "Qualification Summary Table".
404.06GNC.NAR; Printed: 26-Oct-95, 12:21 pm 000002

Table I
Chain-of-Custody
Analysis Request
LATA ID #: VB404.06 SDG: W0671-QES
Samp le Informat ion Analyses Requested
SAMPLE DATE
FIELD QC
NO. COLLECTED MATRIX SAF INFO 1 2 3 4
BOGFD3 11-Aug-95 WATER B95-068 EQUIP BLANK X X X X
BOGF83 11-Aug-95 WATER B95-068 X X X X
B0GF85 14-Aug-95 WATER B95-068 X X X X
BOGFB9 14-Aug-95 WATER B95-068 X X X X
B0GF99 14-Aug-95 WATER B95-068 X X X X
BOGF81 14-Aug-95 WATER B95-068 X X X X
BOGFD5 14-Aug-95 WATER B95-068 EQUIP BLANK X X X X
BOGFC1 15-Aug-95 WATER B95-068 X X X X
BOGFC3 15-Aug-95 WATER B95-068 X X X X
Method References:
Analysis Method
1. Anions(CI,F,N02,N03,PO4,SO4) 300.0
2. Ammonia 350.1
3. NO2+N03 353.1
4. Sufide 9030
Printed 10/26/95, 11:07 AM 40406DST.XLS 000003

REFERENCES
WHC 1993, Data Validation Procedures for Chemical Analyses, WHC-SD-EN-SPP-002, Rev. 2,
Westinghouse Hanford Company, Richland, Washington.
DOE 1992, RCRA Facility Investigation/Corrective Measures Study Work Plan for the 100-HR-3
Operable Unit, DOE/RL-88-36, Rev. 0, Department of Energy-Hanford, Richland, Washington.
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm 000004

GLOSSARY OF VALIDATION APPLIED QUALIFIERS (CHEMISTRY)
Qualifiers which may be applied by data validators in compliance with the procedures herein are as
follows.
U- Indicates the compound or analyte was analyzed for and not detected in the sample. The value
reported is the sample quantitation limit corrected for sample dilution and moisture content by
the laboratory.
UJ- Indicates the compound or analyte was analyzed for and not detected in the sample. Due to a
QC deficiency identified during data validation, the associated quantitation limit is an estimate.
J- Indicates the compound or analyte was analyzed for and detected. The associated concentration
is an estimate, but the data are usable for decision making purposes.
BJ- Applied to inorganic analyses only. Indicates the analyte concentration was greater than the IDL
but less than the CRDL and is considered an estimated value.
R- Indicates the compound or analyte was analyzed for, detected, and due to an identified QC
deficiency the data are unusable.
UR- Indicates the compound or analyte was analyzed for and not detected in the sample.
Additionally, the data are unusable due to an identified QC deficiency.
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm 000005

GLOSSARY OF LABORATORY APPLIED QUALIFIERS
Qualifiers which may be applied by the laboratory in compliance with applicable requirements are as
follows.
Commonly used laboratory general chemistry qualifiers:
U- Indicates the analyte was analyzed for but not detected in the sample.
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm 000006

Qualification Summary Table
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm 000007

Qualification Summary Table
General Chemistrv
ANALYTE TYPE QUALIFIER SAMPLES DQO REASON
AFFECTED
Nitrate MAJOR UR BOGFD3 HOLD TIME Holding time is exceeded by greater
than 2 times.
Nitrite MAJOR UR BOGFD3 BOGF83 HOLD TIME Holding time is exceeded by greater
than 2 times.
Ortho-Phosphate MAJOR UR BOGFD3 BOGF83 HOLD TIME Holding time is exceeded by greater
than 2 times.
Nitrate MINOR J/UJ BOGF83 B0GF85 HOLD TIME Holding time is exceeded by 2 times or
BOGFB9 BOGF99 less.
BOGF81BOGFCI
BOGFC3 BOGFD5
Nitrite MINOR UJ BOGF85 BOGFB9 HOLD TIME Holding time is exceeded by 2 times or
BOGF99 BOGF81 less.
BOGFD5 BOGFCI
BOGFC3
Ortho-Phosphate MINOR UJ ' BOGF85 BOGFB9 HOLD TIME Holding time is exceeded by 2 times or
BOGF99 BOGF81 less.
BOGFDS BOGFC1
BOGFC3
General Chemistrv Field QC
ANALYTE TYPE QUALIFIER FIELD QC DQO ASSESSMENT
SAMPLES
Sulfide FIELD QC NONE B0GFD3 BOGFDS BLANKS
Equip. Blk. Equipment Blank contamination noted.
Comments:
Data qualification is not required based on field QC, however, field QC results are noted here to alert the data user
to uncertainties in the data set during decision making processes.
Printed 11/1/95, 12:35 PM 40406QLS.XLS 000WIS

404.06GNC.NAR; Printed: 24-Oct-95, 9:43 am
Data Summary Table
000009

LATA ID#: VB404.06 HEIS #:
Date:
GENERAL CHEMISTRY
DATA SUMMARY TABLE
Matrix:
BOGFD3
11-Aug-95
WATER
BOGF83
11-Aug-95
WATER
BOGF85
14-Aug-95
WATER
BOGFB9
14-Aug-95
WATER
BOGF99
14-Aug-95
WATER
Constituent CAS # Units Results Q Results Q Results Q Results Q Results Q
Chloride by IC 16887-00-6 mg/L 0.20 U 23.4 46.9 4.87! 9.59
Fluoride by IC 16984-48-8 mg/L 0.10 U 0.18 0.20 U 0.151 0.77
Sulfate by IC 14808-79-8 mg/L 0.50 U 113 212 29.8 55.1
Nitrate 14797-55-8 mg/L 0.020 UR 14.6 21.6 J 1.90 234 J
Nitrite 14797-65-0 mg/L 0.020 UR 0.020 tIR 0.020 !IJ 0.020 UJ 0.10 UJ
Ortho-Phosphate by IC 14265-44-2 mg/L 0.50 UR 0.50 UR 0.50 UJ 0.50 UJ 0.50 UJ
Nitrite+Nitrate NOZ+N03 mg/L 0.050 U 13.5 21.3 2.081 3.24
Ammonia 7664-41-7 mg/L 0.050 U 0.050 U 0.050 1 U 0.0501 U 0.050 U
Sulfide 18496-25-8 mg/L 0.45 0.43 0.71 1 0.801 0.86
10/26/95, 11:23 AM
Shaded areas indicate changes by the validator.
40406DST.XLS, GENERAL CHEMISTRY
OOOOl.1011

LATA ID#: VB404.06 HEIS #:
Date:
GENERAL CHEMISTRY
DATA SUMMARY TABLE
Matrix:
BOGF81
14-Aug-95
WATER
BOGFD5
15-Aug-95
WATER
BOGFC1
15-Aug-95
WATER
BOGFC3
15-Aug-95
WATER
Constituent CAS # Units Results Q Results Q Results Q Results Q
Chloride by IC 16887-00-6 mg/L 14.41 0.20 U 4.37 5.13
Fluoride by IC 16984-48-8 mg/L 0.19i 0.10 U 0.49 0.43
Sulfate by IC 14808-79-8 mg/L 99.6'i 0.50 U 30.5 34.2
Nitrate 14797-55-8 mg/L 7.63 J 0.020 (f'J 2.01 J 1.32 J
Nitrite 14797-65-0 mg/L 0.020 UJ 0.020 U^ 0.020 UJ 0.020 UJ
Ortho-Phosphate by IC 14265-44-2 mg/L 0.50 UJ 0.50 UJ 0.50 UJ 0.50 UJ
Nitrite+Nitrate N02+N03 mg/L 7.731 0.050 U 2.11 1.42
Ammonia 7664-41-7 mg/L 0.0501 U 0.050 U 0.050 U 0.050 U
Sulfide 18496-25-8 mg/L 0.73! 0.51 1 0.56 0.47
Shaded areas indicate changes by the validator.
11/1/95, 12:37 PM 40406DST.XLS, GENERAL CHEMISTRY
000011

Sample Results (Form I's)
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm
000012

Duanterra-Richland
P.O. Box 1970
Richtand, WA 99352
Project: 550.93
Category: Amnonia EPA 350.1 Sample Date : 08/11/95
Method: EPA 350.1 Receipt Date : 08/14/95
Matrix: LIQUID Report Date : 09/19/95
Client Quanterra BLank Sample Prep. Analyses Detection
ID ID AnaLyte CAS Number Name Date Date Result Unit DuaL. Limit DiL.
BOGFD3 9116-001 Anmonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFD3 9116-001DUP Amnonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFD3 9116-001MS Amnonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 78 %REC 1
80GF83 9116-002 Amoonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGF85 9123-001 Amiwnia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFB9 9123-002 Ammonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
B06F99 9123-003 Amnonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGF81 9123-004 Ammonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFDS 9128-001 Ammonia 7664-41-7 DCBLK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFCI 9128-002 Ammonia 7664-41-7 DCBLK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFC3 9128-003 Amonia 7664-41-7 DCBLK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
NA QCBLK75910-1 Artmonia 7664-41-7 QCBLK75910-1 08/19/95 '08/19/95 0.050 MG/L U 0.050 1
NA DCBLK75911-1 Ammonia 7664-41-7 OC8LK75911-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
NA aCLC875910-1 Amnonia 7664-41-7 QCBLK75910-1 08/19/95 08/19/95 100 %REC 1
NA GCLCS75911-1 Anmonia 7664-41-7 0C8LK75911-1 08/19/95 08/19/95 96 %REC 1
000013
bis
,la ^s
ID

Quanterra-RichLand
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Category: Chloride Sample Date : 08/11/95
Method: EPA 300.0 Receipt Date : 08/14/95
Matrix: LIQUID Report Date : 09/19/95
Client Quanterra Blank Sample Prep. Analyses Detection
ID ID Analyte CAB Numher Name Date Date Result Unit QuaL. Limit Dil.
BOGFD3 9116-001 Chlon e 16887-00- QCBLK7591 -1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
BOGFD3 9116-001DUP Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
BOGFD3 9116-001MS Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 108 7.REC 5
BOGF83 9116-002 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 23.4 MG/L 5.00 25
BOGF85 9123-001 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 46.9 MG/L 5.00 25
80GF89 9123-002 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 4.87 MG/L 0.20 1
80GF99 9123-003 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 9.59 MG/L 0.40 2
BOGF81 9123-004 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 14.4 MG/L 2.00 10
BOGFD5 9128-001 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
BOGFC1 9128-002 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 4.37 MG/L 0.20 1
BOGFC3 9128-003 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 5.13 MG/L 1.00 5
NA QCBLK75914-1 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 1
NA QCLCS75914-1 Chloride 16887-00-6 QCBLK75914-1 08/18/95 08/18/95 92 Y.REC 1
000014
^O v5
'° 3

Category: Fluoride
Method: EPA 300.0
Matrix: LIQUID
Quanterra-Richtand
P.O. Box 1970
RichLand, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra Blank sample Prep. Analyses Detection
ID ID Analyte CAS Numher Name Date Date Result Unit Qual. Limit Dil.
BOGFD3 9116-001 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 1
BOGFD3 9116-001DUP Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 1
BOGFD3 9116-001MS Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 110 %REC 1
B0GF83 9116-002 FLuoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.18 MG/L 0.10 1
80GF85 9123-001 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.20 MG/L U 0.20 2
BOGFB9 9123-002 FLuoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.15 MG/L 0.10 1
BOGF99 9123-003 FLuoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.77 MG/L 0.20 2
BOGF81 9123-004 FLuoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.19 MG/L 0.10 1
BOGFD5 9128-001 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10 1
BOGFC1 9128-002 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.49 MG/L 0.10 1
BOGFC3 9128-003 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.43 MG/L 0.10 1
NA QCBLK75914-1 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 0.10 MG/L U 0.10
NA QCLCS75914-1 Fluoride 16984-48-8 QCBLK75914-1 08/18/95 08/18/95 101 YAEC 1
UO0U1.S , q5
y\^

Quanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Category: Sulfate Sample Date : 08/11/95
Method: EPA 300.0 Receipt Date : 08/14/95
Matrix: LIQUID Report Date : 09/19/95
CLieht Quanterra Blank Sample Prep. Anatyses Detection
ID ID Analyte CAS Number Name Date Date ResuLt Unit QuaL. Limit Dit.
BOGFD3 9116-001 Sulfate 14808-79-8 0BLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0. 50 1
600FD3 9116-001DUP SuLfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFD3 9116-001MS Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 100 %REC 5
B00F83 9116-002 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 113 MG/L 12.5 25
800F85 9123-001 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 212 MG/L 12.5 25
BOGF89 9123-002 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 29.8 MG/L 2.50 5
B0GF99 9123-003 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 55.1 MG/L 2.50 5
BOGF81 9123-004 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 99.6 MG/L 5.00 10
BOGFD5 9128-001 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFCI 9128-002 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 30.5 MG/L 2.50 5
BOGFC3 9128-003 Sulfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 34.2 MG/L 2.50 5
NA QCBLK75914-1 SuLfate 14808-79-8 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
NA QCLCS75914-1 Sulfate 14808-79-8 QC8LK75914-1 08/18/95 08/18/95 91 %REC 1
000016 b`' y
^,^'S^

Category: Nitrate/Nitrite
Method: EPA 353.1
Matrix: LIQUID
euanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra Blank Sample Prep. Analyses Detection
ID ID AnaLyte CAS Number Name Date Date Result Unit aual. Limit Dil.
BOGFD3 9 16-001 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/9 5 08/19/95 0.0 5 0 MG/L U 0.050 1
BOGFD3 9116-001DUP Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFD3 9116-OOIMS Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 100 %REC 1
B0GF83 9116-002 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 13.5 MG/L 1.00 20
800F85 9123-001 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 21.3 MG/L 2.50 50
BOGFB9 9123-002 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 2.08 MG/L 0.50 10
BOGF99 9123-003 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 3.24 MG/L 0.50 10
BOGF81 9123-004 Nitrate/Nitrite C-005 0CBLK75912-1 08/19/95 08/19/95 7.73 MG/L 1.00 20
BOGFD5 9128-001 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
BOGFC1 9128-002 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 2.11 MG/L 0.50 10
BOGFC3 9128-003 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 1.42 MG/L 0.25 5
NA QCBLK75912-1 Nitrate/Nitrite C-005 OCBLK75912-1 08/19/95 08/19/95 0.050 MG/L U 0.050 1
NA OCLCS75912-1 Nitrate/Nitrite C-005 QCBLK75912-1 08/19/95 08/19/95 93 %REC 1
000017
l ^(^

Category: Sulfide EPA 9030
Method: EPA 9030
Matrix: LIQUID
Ouanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Clieht Guanterre Blank Sample Prep. Analyses Detection
ID ID Analyte CAS Number Name Date Date Result Unit oual. Limit Dil.
BOGFD3 9116-001 Sulfide 18496-25-8 oCBLK75515-1 08/16/95 08/16/95 0.45 MG/L 0.38 1
BOGFD3 9116-001DUP Sulfide 18496-25-8 QCBLK75515-1 08/16/95 08/16/95 0.41 MG/L 0.39 1
BOGFD3 9116-001M6 Sulfide 18496-25-8 OC3LK75515-1 08/16/95 08/16/95 102 Y.REC 1
800F83 9116-002 Sulfide 18496-25-8 OCBLK75515-1 08/16/95 08/16/95 0.43 MG/L 0.39 1
800F85 9123-001 Sulfide 18496-25-8 0C8LK75787-1 08/18/95 08/18/95 0.71 MG/L 0.39 1
BOGFB9 9123-002 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.80 MG/L 0.39 1
800F99 9123-003 Sulfide 18496-25-8 OC8LK75787-1 08/18/95 08/18/95 0.86 MG/L 0.40 1
BOGF81 9123-004 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.73 MG/L 0.40 1
BOGFD5 9128-001 sulfide 18496-25-8 0C8LK75787-1 08/18/95 08/18/95 0.51 MG/L 0.40 1
BOGFC1 9128-002 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.56 MG/L 0.40 1
BOGFC3 9128-003 Sulfide 18496-25-8 QCBLK75787-1 08/18/95 08/18/95 0.47 MG/L 0.40 1
NA oCBLK75515-1 Sulfide 18496-25-8 oCB1K75515-1 08/16/95 08/16/95 1.00 MG/L U 1.00 1
NA 0CB1K75787-1 Sulfide 18496-25-8 0CB1K75787-1 08/18/95 08/18/95 1.00 MG/L U 1.00 1
NA OCLCS75515-1 Sulfide 18496-25-8 QCBLK75515-1 08/16/95 08/16/95 91 ZREC 1
NA 0C1C875787-1 Sulfide 18496-25-8 OCBLK75787-1 08/18/95 08/18/95 91 %REC 1
000018 b\^
^

Category: Nitrate
Method: EPA 300.0
Matrix: LIQUID
Ouanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra Blank SampLe Prep. Analyses Detection
ID ID AnaLyte CAS Number Name Date Date Result Unit Oual. Limit Dit.
BOGFD3 9116-001 Nitrate 14797-55-8 OCB1K75914-1 08/18/95 08/18/95 0.020 MG/L ld. (Ak 0.020 1
BOGFD3 9116-001DUP Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFD3 9116-00148 Nitrate 14797-55-8 OC8LK75914-1 08/18/95 08/18/95 104 %REC 5
BOGF83 9116-002 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 14.6 MG/L J- 0.50 25
B00F85 9123-001 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 21.6 MG/L J' 0.50 25
BOGFB9 9123-002 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 1.90 MG/L f 0.10 5
BOGF99 9123-003 Nitrate 14797-55-8 0CBLK75914-1 08/18/95 08/18/95 234 MG/L J' 10.0 500
BOGF81 9123-004 Nitrate 14797-55-8 0CBLK75914-1 08/18/95 08/18/95 7.63 MG/L .7' 0.20 10
BOGFD5 9128-001 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L tl, aS 0.020 1
BOGFC1 9128-002 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 2.01 MG/L .1 0.10 5
BOGFC3 9128-003 Nitrate 14797-55-8 0C8LK75914-1 08/18/95 08/18/95 1.32 MG/L f 0.10 5
NA QCBLK75914-1 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
NA QCLCS75914-1 Nitrate 14797-55-8 QCBLK75914-1 08/18/95 08/18/95 100 %REC 1
000015
b a^
lS
lD . 8'
/5°

Category: Nitrite
Method: EPA 300.0
Matrix: LIQUID
Duanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra Blank Sample Prep. Analyses Detection
ID ID Analyte CAS Number Name Date Date Result Unit Oual. Limit Dit.
BOGFD3 9116-001 Nitrite 14797-65-0 OCBLK75914-1 08/18/95 08/18/95 0.020 MG/L tl.uR 0.020 1
BOGFD3 9116-001DUP Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
BOGFD3 9116-001MS Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 101 Y.REC 5
B0GF83 9116-002 Nitrite 14797-65-0 OC8LK75914-1 08/18/95 08/18/95 0.020 MG/L ^tt4k 0.020 1
H0GF85 9123-001 Nitrite 14797-65-0 OC8LK75914-1 08/18/95 08/18/95 0.020 MG/L 6l.I4J' 0.020 1
BOGF89 9123-002 Nitrite 14797-65-0 OCBLK75914-1 08/18/95 08/18/95 0.020 MG/L N..uT 0.020 1
BOGF99 9123-003 Nitrite 14797-65-0 DCBLK75914-1 08/18/95 08/18/95 0.10 MG/L 'U, Wj 0.10 5
BOGF81 9123-004 Nitrite 14797-65-0 0CB1K75914-1 08/18/95 08/18/95 0.020 MG/L tY.l4T 0.020 1
806FD5 9128-001 Nitrite 14797-65-0 DCB1K75914-1 08/18/95 08/18/95 0.020 MG/L lri (AT 0.020 1
BOGFC1 9128-002 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L -4LWf 0.020 1
BOGFC3 9128-003 Nitrite 14797-65-0 QCBLK75914-1 08/18/95 08/18/95 0.020 MG/L Z1,, ks 0.020 1
NA GCB1K75914-1 Nitrite 14797-65-0 OCB1K75914-1 08/18/95 08/18/95 0.020 MG/L U 0.020 1
NA qC1CS75914-1 Nitrite 14797-65-0 OC81K75914-1 08/18/95 08/18/95 99 Y.REC 1
)
000020 ';^

Category: Orthophosphate
Method: EPA 300.0
Matrix: LIQUID
Quanterra-Richland
P.O. Box 1970
Richland, WA 99352
Project: 550.93
Sample Date : 08/11/95
Receipt Date : 08/14/95
Report Date : 09/19/95
Client Quanterra Blank Sample Prep. Analyses Detection
ID ID Analyte CAS Number Name Date Date Result Unit Quat. Limit Dit.
BOGFD3 9116-001 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U,(.j/t 0.50 1
BOGFD3 9116-001DUP Ortho-Phosphate 14265-44-2 OCBLK75914-1 08/18/95 08/18/95 0.50 MG/L U 0.50 1
BOGFD3 9116-001MS Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 111 %REC 1
BOGF83 9116-002 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L VLLtP\ 0.50 1
BOGF85 9123-001 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L -4 lAf 0.50 1
BOGFB9 9123-002 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L H..tAJ- 0.50 1
B06F99 9123-003 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L T1, iL7 0.50 1
BOGF81 9123-004 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L A. UJ 0.50 1
BOGFDS 9128-001 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L -liAf' 0.50 1
BOGFCI 9128-002 Ortho-Phosphate 14265-44-2 QCBLK75914-1 08/18/95 08/18/95 0.50 MG/L tl, t.l.r 0.50 1
BOGFC3 9128-003 Ortho-Phosphate 14265-44-2 QCBLK75914-1
NA QCBLK75914-1 Ortho-Phosphate 14265-44-2 QCBLK75914-1
NA QCLCS75914-1 Ortho-Phosphate 14265-44-2 QCBLK75914-1
08/18/95 08/18/95 0.50 MG/L Jj NJ' 0.50 1
08/18/95 08/18/95 0.50 MG/L U 0.50 1
08/18/95 08/18/95 94 %REC 1
'0OOp,2l
JD- l
1--1K

404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm
Checklist
000022

VALIDATION
LEVEL:
VALIDATION
PROCEDURE:
LATA GENERAL CHEMISTRY
DATA VALIDATION CHECKLIST
A B C p E
WHC-CM-5-3, Rev. 0 ^ WHC-SD-EN-SPP-002, Rev. 2
100-HR-3 ROUND
PROJECT: 9 PHASE II SDG: W0671-QES
yb i^••Ae
VALIDATOR: BJ SEYMOUR LATA NO: VB404.06 DATE: 17-Oct-95
BM
REVIEWER: BJ MORRIS /-z7• AB: QES CASE: N/A
DOE/RL-88-36,
SAF NO: B95-068 QAPP NO: Rev. 0 SAP NO: N/A
ANALYSES REQUESTED
Anions x I Ammonia ^ N02+N03 Sulfide
300.0 ^ 350.1 353.1 9030
SAMPLE NO. MATRIX
COMMENTS:
BOGFD3 BOGF83
BOGF85 BOGFB9
BOGF99 BOGF81
BOGFD5 BOGFCI
BOGFC3
WATER
1. DATA PACKAGE COMPLETENESS AND CASE NARRATIVE
Is technical verification documentation present?
Is a case narrative present?
2. HOLDING TIMES
YES NO N/A
YES NO N/A
Are sample holding times acceptable? ^D
3. INSTRUMENT PERFORMANCE AND CALIBRATIONS
Were initial calibrations performed on all instruments?
Are initial calibrations acceptable?
See HOLDING TIME SUMMARY form I I
YES NO NIA
Were calibration checks performed on all instruments? ^ j 'J
Are calibration checks acceptable? LXJ D. q
Validation calculation checks were performed and are acceptable. ^ ^ q
11 If NO(s) are checked, see CALIBRATION DATA SUMMARY form . 11
40406GNC.XLS, Checklist
PNO-DVF-013, R2 10/26/95, 11:32 AM

LATA GENERAL CHEMISTRY
DATA VALIDATION CHECKLIST
4. BLANKS YES NO N/A
Were laboratory blanks performed for all applicable analyses? q q ID
Are laboratory blank results acceptable? q q q
Were preparation blanks analyzed? J lJ J
Are preparation blank results acceptable? ^J q !,J
11 If NO(s) are checked, see BLANK AND SAMPLE DATA SUMMARY form 11
5. ACCURACY
YES NO N/A
Were spike samples analyzed at the proper frequency? ^^ q q
Are all spike sample recoveries acceptable? ^J I^ J
Were laboratory control samples (LCS) analyzed at the proper frequency? ^ q '^
Are all LCS recoveries acceptable? '.^ q q
Validation calculation checks were performed and are acceptable.
X
'^ '^y
tJ
11 If NO(s) are checked, see ACCURACY DATA SUMMARY form 11
6. PRECISION
YES NO N/A
Were laboratory duplicates analyzed at the proper frequency? q(^ q i..1
Are all duplicate RPD values acceptable?
tJ q
Were MS/MSDs analyzed? q q q
Are all MS/MSD RPD values acceptable? q q _J
Validation calculation checks were performed and are acceptable. q ^.J ^J
11 If NO(s) are checked, see PRECISION DATA SUMMARY form 11
7. FIELD QC SAMPLES
YES NO N/A
Were field QC samples ( field/equip. blanks, duplicates, splits, performance audit) identified? Fj q {...I
Are field/equip. blank results acceptable? ( see Blank Data Summary form) q q
Are field duplicate RPD values acceptable? ( see Field QC calculations) q q IJ
Are field split RPD values acceptable? ( see Field QC calculations) q
Are performance audit sample results acceptable? _I q ',_I
Comments: Sample BOGFD3 is identified as an Equipment Blank.
Sample BOGFD5 is identified as an Equipment Blank.
40406GNC.XLS, Checklist
PNO-DVF-013, R2 11/1/95, 12:41 PM
000024

8. ANALYTE QUANTITATION
LATA GENERAL CHEMISTRY
DATA VALIDATION CHECKLIST
YES NO N/A
Was analyte quantitation performed properly? q q q
Are results calculated properly? X q q
Validation calculation checks were performed and are acceptable. iJ q ^
Comments:
9. REPORTED RESULTS AND DETECTION LIMITS
YES NO N/A
Are results reported for all requested analyses? q q q
Are all results supported in the raw data? q -J ^
Do results meet the CRDLs? q q q
Validation calculation checks were performed and are acceptable. I^ ^ q
Comments:
VALIDATION SUMMARY
For deficiencies (major and minor) and comments, please refer to the Qualification Summary Table.
40406GNC.XLS, Checklist 000O2•1.
PNO-DVF-013, R2 10/23/95, 12:13

LATA GENERAL CHEMISTRY
DATA VALIDATION CHECKLIST
HOLDING TIME SLIMMARV
SDG: W0671-QES VALIDATOR: BJ SEYMOUR DATE: 17-Oct-95
PROJECT: 100-HR-3 ROUND 9 PHASE II REVIEWER: BJ MORRIS LATA NO.: V8404.06
HEIS-SN
MATRIX
CODE ANALYSIS
DATE
COLLECTED
PREP
DATE
ANALYSIS
DATE
PREP
HT
(days)
Required
HT
(days)
ANALYSIS
HT
(days)
Required
HT
(days)
B0GFD3 WATER Anions(CL,F,SO4) 11-Aug-95 N/A 18-Aug-95 N/A N/A 7 28 NONE
B0GF83 WATER Anions(CL,F,SO4) 11-Aug-95 N/A 18-Aug-95 N/A N/A 7 28 NONE
BOGF85 WATER Anions(CL,F,S04) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 28 NONE
BOGFB9 WATER Anions(CL,F,S04) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 28 NONE
B0GF99 WATER Anions(CL,F,SO4) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 28 NONE
BOGF81 WATER Anions(CL,F,SO4) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 28 NONE
BOGFD5 WATER Anions(CL,F,SOq) 15-Aug-95 N/A 18-Aug-95 N/A N/A 3 28 NONE
BOGFCI WATER Anions(CL,F,SOa) 15-Aug-95 N/A 18-Aug-95 N/A N/A 3 28 NONE
BOGFC3 WATER Anions(CL,F,S04) 15-Aug-95 N/A 18-Aug-95 N/A N/A 3 28 NONE
BOGFD3 WATER Anions(NO2,NO3,PO4) 11-Aug-95 N/A 18-Aug-95 N/A N/A 7 2 UR
BOGF83 WATER Anions(NOz,NOa,POq) 11-Aug-95 N/A 18-Aug-95 N/A N/A 7 2 J/UR
BOGF85 WATER Anions(NOz,NO3,PO4) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 2 J/UJ
BOGFB9 WATER Anions(N02,NO3,PO4) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 2 J/UJ
BOGF99 WATER Anions(NO2,NO3,P04) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 2 J/UJ
B0GF81 WATER Anions(N02,NO3,PO4) 14-Aug-95 N/A 18-Aug-95 N/A N/A 4 2 J/UJ
BOGFD5 WATER Anions(NOs,NO3,PO4) 15-Aug-95 N/A 18-Aug-95 N/A N/A 3 2 UJ
BOGFC1 WATER Anions(N02,NO3,P04) 15-Aug-95 N/A 18-Aug-95 N/A N/A 3 2 J/UJ
BOGFC3 WATER Anions(NOz,NOs,PO4) 15-Aug-95 N/A 18-Aug-95 N/A N/A 3 2 J/UJ
BOGFD3 WATER Ammonia 11-Aug-95 N/A 19-Aug-95 N/A N/A 8 28 NONE
BOGF83 WATER Ammonia 11-Aug-95 N/A 19-Aug-95 N/A N/A 8 28 NONE
BOGF85 WATER Ammonia 14-Aug-95 N/A 19-Aug-95 N/A N/A 5 28 NONE
B0GFB9 WATER Ammonia 14-Aug-95 N/A 19-Aug-95 N/A N/A 5 28 NONE
B0GF99 WATER Ammonia 14-Aug-95 N/A 19-Aug-95 N/A N/A 5 28 NONE
BOGF81 WATER Ammonia 14-Aug-95 N/A 19-Aug-95 N/A N/A 5 28 NONE
BOGFD5 WATER Ammonia 15-Aug-95 N/A 19-Aug-95 N/A N/A 4 28 NONE
B0GFC1 WATER Ammonia 15-Aug-95 N/A 19-Aug-95 N/A N/A 4 28 NONE
BOGFC3 WATER Ammonia 15-Aug-95 N/A 19-Aug-95 N/A N/A 4 28 NONE
BOGFD3 WATER NOz+NOs 11-Aug-95 N/A 19-Aug-95 N/A N/A 8 28 NONE
BOGF83 WATER N02+NO3 11-Aug-95 N/A 19-Aug-95 N/A N/A 8 28 NONE
BOGF85 WATER NO2+NO3 14-Aug-95 N/A 19-Aug-95 N/A N/A 5 28 NONE
BOGFB9 WATER NO2+NOs 14-Aug-95 N/A 19-Aug-95 N/A N/A 5 28 NONE
BOGF99 WATER NOZ+NO3 14-Aug-95 N/A 19-Aug-95 N/A N/A 5 28 NONE
40406GNC.XLS, hold times 000026
PNO-DVF-013, R2 11/1/95, 12:42 PM
VAL
Q

LATA GENERAL CHEMISTRY
DATA VALIDATION CHECKLIST
HOLDING TIME SUMMARY
SDG: W0671-QES VALIDATOR: BJ SEYMOUR DATE: 17-Oct-95
PROJECT: 100-HR-3 ROUND 9 PHASE II REVIEWER: BJ MORRIS LATA NO.: V8404.06
HEIS-SN
MATRIX
CODE ANALYSIS
DATE
COLLECTED
PREP
DATE
ANALYSIS
DATE
PREP
HT
(days)
Required
HT
(days)
ANALYSIS
HT
(da ys)
Required
HT
(days)
BOGFCI WATER N02+NO3 15-Aug-95 N/A 19-Aug-95 N/A N/A 4 28 NONE
BOGFC3 WATER NO2+NO3 15-Aug-95 N/A 19-Aug-95 N/A N/A 4 28 NONE
BOGFD3 WATER Sulfide 11-Au g-95 N/A 16-Au g -95 N/A N/A 5 7 NONE
BOGF83 WATER Sulfide 11-Au -95 N/A 16-Au -95 N/A N/A 5 7 NONE
BOGF85 WATER Sulfide 14-Au g -95 N/A 18-Au g -95 N/A N/A 4 7 NONE
BOGFB9 WATER Sulfide 14-Au g -95 N/A 18-Au g -95 N/A N/A 4 7 NONE
BOGF99 WATER Sulfide 14-Au -95 N/A 18-Au -95 N/A N/A 4 7 NONE
BOGF81 WATER Sulfide 14-Au g -95 N/A 18-Au -95 N/A N/A 4 7 NONE
BOGFD5 WATER Sulfide 14Au -95 N/A 18-Au -95 N/A N/A 4 7 NONE
BOGFCI WATER Sulfde 15-Au -95 N/A 18-AU -95 N/A N/A 3 7 NONE
BOGFC3 WATER Sulfide 15-Au g -95 N/A 18-Au -95 N/A N/A 3 7 NONE
40406GNC.XLS, hold times
PNO-DVF-013, R2 10/18/95, 2:22 PM
000027
VAL
Q

LATA GENERAL CHEMISTRY
DATA VALIDATION CHECKLIST
BLANK DATA SUMMARY
SDG: W0671-QES VALIDATOR: BJ SEYMOUR DATE: 17-Oct-95
PROJECT: 100-HR-3 ROUND 9 PHASE II REVIEWER: BJ MORRIS LATA NO.: VB404.06
BLANK ID ANALYTE RESULT
LAB
Q RT UNITS
2X
RESULT
5X
RESULT
10X
RESULT SAMPLES AFFECTED
BOGFD3
Equi . Blank Sulfide 0.45 mg/L NONE NONE
BOGFD5
Equi p . Blank Sulfide 0.51 mg/L NONE NONE
40406GNC.XLS, blanks
PNO-DVF-013, R2 10/26/95, 11:45AM
000028
VAL
0

SDG: W0671-QES
LATA No.: VB404.06
Analyte/Calibration Date: Ammonia/8-19-9 5
Concentration Absorbance
SDG: W0671-QES
LATA No.: VB404.06
LATA GENERAL CHEMISTRY
CALCULATION SPREADSHEET
LINEAR REGRESSION ANALYSIS
Date: 17-Oct-95
Validator: BJ SEYMOUR
x y r r^
0 0.00 0.9998 0.9995
50 51.06
100 101.2 slope x intercept
300 307.5 0.9987 - 0.4080
500 498.0
700 683.9 1/slope y intercept
1000 1009 1.0013 0.5890
Analyte/Calibration Date: Fluoride/8-18-95
Concentration Absorbance
x y
LINEAR REGRESSION ANALYSIS
Date: 17-Oct-95
Validator: BJ SEYMOUR
0.000 0 0.9995 0.9990
0.100 1303
0.500 8518 slope x intercept
1.000 23076 26018.5826 0.0865
2.500 61895
5.000 128707 1/slope y intercept
40406GNC.XLS, linear regression
PNO-DVF-013, R2 10/18/95, 4:40 PM
0.0000 11 -2211.6837 1
000029

LATA GENERAL CHEMISTRY
CALCULATION SPREADSHEET
LINEAR REGRESSION ANALYSIS
SDG: W0671-QES Date: 17-Oct-95
LATA No.: VB404.06 Validator: BJ SEYMOUR
Analyte/Calibration Date: N02+NO3/8-19- 95
Concentration Absorbance
x y
0 5.754 0.9998 0.9996
50 49.33
100 97.44 slope x intercept
300 292.3 0.9997 0.0088
500 498.1
700 712.7 1/slope y intercept
1000 994.4 1.0003 0.1246
40406GNC.XLS, linear regression (2) 000030
PNO-DVF-013, R2 10/18/95, 4:40 PM

LATA GENERAL CHEMISTRY
CALCULATION SPREADSHEET
PERCENT RECOVERY (ICV/CCV)
SDG: W0671-QES Date: 17-Oct-95
LATA No.: VB404.06 Validator: BJ SEYMOUR
Analyte Sample ID Observed Value True Value
O A
Fluoride ICV 2.090 2
Fluoride CCV 2.097 2
Ammonia lCV 407.0 400
Ammonia CCV 403.4 400
N02+N03 ICV 605.5 600
NO2+N03 CCV 599.2 600.0
40406GNC.XLS, ICV CCV recovery
PNO-DVF-013, R2 10/23/95, 9:35
%R
105%
105%
102%
101%
101%
100%
000031

SDG: W0671-QES
LATA No.: VB404.06
Analyte Sample ID
Fluoride BOGFD3
Ammonia BOGFD3
N02+N03 BOGFD3
Sulfide B0GFD3
LATA GENERAL CHEMISTRY
CALCULATION SPREADSHEET
MATRIX SPIKE RECOVERY (MS)
Date: 17-Oct-95
Validator: BJ SEYMOUR
Spike Sample Sample Spike
Result Result Added
SSR SR SA
2.193 0 2
389.2 0 500
565.3 0 564
14.80 0.446 14.10
40406GNC.XLS, MS recovery
PNO-DVF-013, R2 11/10/95, 2:19 PM ^O O O 2`
%R
110%
78%
100%
102%

Fluoride
Ammonia
N02+N03
Sulfide
LATA GENERAL CHEMISTRY
CALCULATION SPREADSHEET
PERCENT RECOVERY (LCS)
SDG: W0671-QES Date: 17-Oct-95
LATA No.: VB404.06 Validator: BJ SEYMOUR
Observed value
OLCS
1.013
481.5
526.50
12.30
True value
ALCS
1
480.00
565.00
40406GNC.XLS, LCS recovery 000033
PNO-DVF-013, R2 10/26/95, 11:48 AM
13.50
%R
101%
100%
93%
91%

SDG: W0671-QES
LATA No.: VB404.06
LATA GENERAL CHEMISTRY
CALCULATION SPREADSHEET
RELATIVE PERCENT DIFFERENCE
Original (Sample) Duplicate
Anafyte Sample ID concentration concentration
OS D
Fluoride BOGFD3 0.000 0.000
Ammonia BOGFD3 0.050 0.050
N02+N03 BOGFD3 0.050 0.050
Sulfide BOGFD3 0.446 0.410
Date: 17-Oct-95
Validator: BJ SEYMOUR
40406GNC.XLS, RPD 000034
PNO-DVF-013, R2 10/23/95, 12:09
RPD
0.0%
0.0%
0.0%
8.4%

Analyte
Fluoride (BOGF81)
Ammonia (BOGF83)
N02+N03 (BOGFB9)
Sulfide (BOGF99)
SDG: W0671-QES
LATA No.: VB404.06
LATA GENERAL CHEMISTRY
CALCULATION SPREADSHEET
RESULTS CALCULATION, WATER
Concentration Dilution
from curve Factor
CONCW units DFW
0.188 mg/L 1
0.05 mg/L 1
20.79 mg/L 1
0.855 mg/L 1
40406GNC.XLS, water results
PNO-DVF-013, R2 10/23/95, 12:01
Date: 17-Oct-95
Validator: BJ SEYMOUR
Concentration
0.19
0.050
20.8
0.86
000035

Laboratory Case Narrative
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm 000036

Quanterra Incorporated
13715 Rider Trail North
Earth City, Missouri 63045
314 298-8566 Telephone
314 298-8757 Fax
Bechtel Hanford Incorporated
P.O. Box 1970
Richland, Washington 99352
September 19, 1995
Attention: Joan Kessner
CERTIFICATE OF ANALYSIS
Project number 550.93
Dates Received by Lab . August 14, 15, and 16, 1995
Number of Samples Eighteen (18)
Sample Type Water
SDG Number W0671
Data Deliverable Standalone
I. Introduction
iiuanterra
Environmental
Services
4
OCT 7895
REDa^
loB in
Between August 14 and 16, 1995, eighteen (18) water samples were received by Quanterra,
Richland and transferred to Quanterra, St. Louis for chemical analysis. Upon receipt, the samples
were given the following laboratory ID numbers to correspond with their specific client ID's:
St Louis ID WHC ID Richland ID Matrix Date of Receipt
9116-001 BOGFD3 50824001 Water 08/14/95
9116-002 BOGF83 50824003 Water 08/14/95
9116-003 BOGFD4 50824002 Water 08/14/95
9116-004 BOGF84 50824004 Water 08/14/95
9123-001 BOGF85 50825101 Water 08/15/95
9123-002 BOGFB9 50825103 Water 08/15/95
9123-003 BOGF99 50825105 Water 08/15/95
9123-004 BOGF81 50825107 Water 08/15/95
9123-005 BOGF86 50825102 Water 08/15/95
9123-006 BOGFCO 50825104 Water 08/15/95
9123-007 BOGFBO 50825106 Water 08/15/95
9123-008 BOGF82 50825108 Water 08/15/95
9128-001 BOGFD5 50826801 Water 08/16/95
9128-002 B0GFC1 50826803 Water 08/16/95
O0©U37 `^,07 \a ^J

Bechtel Hanford Incorporated
September 19, 1995
Project Number: 550.93
SDG: W0671
Page 2
iiiaanterra
St Louis ID WHC ID Richland ID Matri Date of Receivt
9128-003 BOGFC3 50826805 Water 08/16/95
9128-004 BOGFD6 50826802 Water 08/16/95
9128-005 BOGFC2 50826804 Water 08/16/95
9128-006 BOGFC4 50826806 Water 08/16/95
H. Analytical Results/ Methodology
Environmemal
Services
The analytical results for this report are presented by analytical test. Each set of data includes
sample identification information, analytical results and the appropriate detection limits.
Analyses requested: Chloride, Fluoride, Nitrite, Nitrate, Phosphate and Sulfate by EPA method
300.0. ICAP Metals by EPA method 6010. Ammonia by EPA method
350.1. Nitrate/Nitrite by EPA method 353.1. Sulfide by EPA method 9030.
III. Quality Control
A Laboratory Control Sample and Method Blank were analyzed with each preparation batch.
Matrix Spike and Matrix Spike Duplicate or Sample Duplicate analyses were performed per the
protocol for each analyte.
IV. Definitions
The following codes are used to denote laboratory quality control samples and can be found in the
data summary section of this report:
QCBLK- Quality Control Blank, Method Blank
QCLCS- Quality Control Laboratory Control Sample, Blank Spike
0OOO38 y ^s a-5^

Bechtel Hanford Incorporated
September 19, 1995
Project Number: 550.93
SDG: W0671
Page 3
V. Comments
^iuanterra
The Matrix Spike Duplicate recovery for Cadmium (73.4%) was less than 75% therefore all
associated data was flagged with an "N".
The Fluoride analysis on sample 9123-001 was run at a two times dilution because of an
interfering peak, which raised the detection limit.
The Nitrite analysis on sample 9123-003 was run at a five times dilution because of
interference, which raised the detection limit.
The Relative Percent Difference could not be calculated because both values were less than the
detection limit for the Fluoride, Chloride, Sulfate, Phosphate, Nitrite and Nitrate analyses on
sample 9116-001.
On sample 9123-001 a Fluoride peak was integrated as a hit but the peak area is less than the
peak area of the lowest calibration standard, hence, it was reported as less than the detection
limit. ,
The Relative Percent Difference could not be calculated for the Nitrate/Nitrite and Ammonia
analyses due to the values being below the detection limit for sample 9116-001 and it's
duplicate.
000039

Bechtel Hanford Incorporated
September 19, 1995
Project Number. 550.93
SDG: W0671
Page 4
ii^ranterra
Environmennl
Servicer
I certify that this data package is in compliance with the SOW, both technically and for
completeness, for other than the conditions detailed above. Release of the data contained in
this hard copy data package has been authorized by the Laboratory Manager or a designee, as
verified by the following signature.
Wade H. Price
Project Manager
e:\\pxiceSlabbydave\hanw0671.nu
000040 ^S
11

Chain-of-Custody Information
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm
000041

_
^
^
I c
U\
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
Data Turnaround
Collector
14
0 P
-n-e
FlC rC l2 L o
Company Contact
R. E. Pateraon
Telephone
15091 3Z2-9638
riority
n N ormal
Project Designation SampGnp Location SAF No.
100-HR-3 Groundwater Samplinp, Round 9, Phase 2 100 D B95-068
ice Chest No. Field Logbook No. Method of Shipment
^^^ S^•3 rFj!- 10 1^ Hand Delivered
Shipped To Offsile Prope o. Bill of Lading/Air Bill No.
Quanterra NA P NA f
Possible Sample Hezards/flemarka
Preservation
HNO, Cnnl4•C HrSO° •1 H2SO° HNO, Cool4°C Cuul4°C HNO,,
Tlpe of Container I7 G
Ij G Pv P PA PIG G P/G G
No of Cantainerlsl ^1 1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain samples between 20C and B°C.
yolume
SOOmL SOOmL 500mL 500mL 5D0mL 1L SOOmL 20mL SOOmL
r
• _^^^
t-
ICP
Metals
A1NOe• pcl
F.
O' eQ"
NO, -
NO,
Sulfide Ammonia Gross
Alpha,
Tritium Activity
Scan
ICP
Melala
SAMPLE ANALYSIS
509 ^ l ;
f //^
ILIL ^u
I
/
^l
(Unfilter-
a dl
^Po•" N0"
Gtoss r
B eta, i
Sr-90
"
^ t I Iv ( ll
IFilteredl
Sample No. Matrix' Dale Sempled Time Sampled
90GF03 oI W 3S- ^ r - ^ -
BOGFD4 (.'.U W ///
CHAIN OF POSSESSION 9ien/Print Names
10 0 f(
c) f^a c^
SPECIAL INSTRUCTIONS rn.m,•
'1 ZnAe+NeOH s -^
i
Relinquished By // , ^ Dete/Time
^ .^;.
( ^ ° . ^%^^ . ^ / y > f
fl /^ Dete/Fime i^ z , •)
-
/ m aaA J -^ ^
elinqnished B y Deta(Time
Relinquished By Oe[e(Time
R Dale/Fime
c^ -
R eceived By Deta/fime
J
-- ^ O •Y S
Received By L 1 I y,, I h DetelTime
Received By Dete/Fime
/jzs-
/!Xt'
Sample analysis for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity
by EPA 180.1 is being requested f or information only. The ERC Contractor
acknowlad0es that the 48-hour holding time will nol be mnt.
The Activity Seen is for all eamples listed on this chain of custody.
SE -
SD - Said
a- Slwa.
D-
e -ti
o ^^
DS - D,unsaaa
OL - D,,.n U°w.
T . r,.•„a
vn-we.
t- tqw
V - vynn,e+
x -oa,
LABORATORY
SECTION
Received By Title Date/fime
FINALSAMPLE DispoealMethod DispoeedBy Date/Iime
DISPOSITION

O
^
^
0 ^
ir
0 O J
Bechtel Henford, Inc.
CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
PaOe I of 1
Collector
d z
F
(i' r j t d
Company Contact
R. E. Petanon
Telephone
(509) 372-9638
Data Turneround
q P r i or it y
^ Normal
Project Designation Sampling Locauon SAF No.
100-HR-3 Groundwater Samplinq, Round 9, Phase 2 100 D 895-068
lce Chest No. Field Logbook No.
Method of Shipment
M^^ SO 1 /' 17 /-- Hend Delivered
Shipped To Offeile Property No. BIII of Lading/Air Bill No.
'
Ouenterre NA
NA
Possible Sample Hexerdc/Remnka
Pmeervetion
rNN
Cool4°C HSO° •1 HrSO° HNO, Cool4°C Cool4°C HNO,
TypeolContainer
G P/# P Pilo PIG G PIG /'G
No. orContainer(s)
1 1 3 1 4 3 1
Speciel Handlinp and/or Storape
Maintain eemplae between 2eC ud 6°C.
Volume
500mL 500mL SOOmL 500mL 1 L 500mL 20mL SOOmL
SAMPLE ANALYSIS
'I /^
/)OSa f ( ^ r
) Unlilterad)
11e'0erp&
-F'a'sD"
Hq. no,.
po,
N0+-
NO3
Sulfide Ammonie
Gross
Alpha,
Gross
Beta,
Sr-9G
1
Tritium
N-
Activity
Scan
ICP
Metals
( F iltnre d )
Sample No. MatriK° Date Sampled Time Sampled
BOGF83 O^ W
BOGF84 W
03 10 0 3^103 (oa
2 )E v1f ^ 0 4 ^ .r . cos 001
SPECIAL INSTRUCTIONS M.m.•
CHAIN OF POSSESSION SiOn/Print Names
1 2nAc +NeOH
s- mu
Relinqpiehed By
Rel i d -
Date ima
^S ^^ -^
S
C'itc-DeteRime ^000
fl i B
y
Received By
^ Date/fime
DeleRime D
j
s Sample analysis for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity
by EP A 180.1 Is being requented for Informetion only. The ERC Contrector
acknowledges that the 48-hour holding time will not be met.
SE - 5.emrn
so s aa
w- w°i.,
o- ou
DS- D tun eda r
aGnquished B y DataRime fleceiveJ By '^(t^ f,'ry ^t Dele Ime 7he Actlvity Scan is for all eamplae listed on this chain of custody.
ot - D,uo tpw.
i - Twv
w+-ww
Relinquished By Date/Time Received By DaleRime t -tkw
V - Vyn.u°e
LABORATORY Received By Title DateRime
SECTION
FINAL SAMPLE Disposal Method Disposed By Date/fime
DISPOSITION

0
^
opt
°1 J
J a
•^ u^
Bechtel Hanford, inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page I of I_
Collector
L't
Compmny Contact
R. E. Pater It
Telephone
( 509) 372-9638
Data Turnaround
0 Pdodty
n Nonnd
Pro j ect Designation Sarnpknp ocmUon SAF No.
100-HR-3 Groundwater Samplirq, Round 9, Phase 2 100 D B95-088
Ice C emt o.
Shipped To
s O 3
Field L ogbook No.
OHeite Prop No.
VIv/
IF
Method of Shipment
Hand DmBvered
Bill of LadinglAir Bill No.
Ouantmrra NA
if
NA / )
Possible Sample Hezerdmlflemerkm
Promarva8on
HNO3 Cool4°C H2SO. 1 H'SO1 HNO3 Cool4°C Ccul4°C HNO3
Type of Container
No. of Contadnmr(m)
Special Handling ardlor Storapm
Volume
Malntdn samples hmtwman 20C and 60C. SOOmL SOOmL
SAMPLE ANALYSIS ^^0^7 ^J/
/
5oS^5r
AG ' G P140 P Pl® P/G G PIG AG
1 1 1 3 1 4 3 1 1
SOOmL 500mL SOOmL iL SOOmL 20mL 50omL
ICP
P ET-
• F. 0. Metdm
IUnN ter-
&o`
NO,. No ..
p0,
NO, -
NO 3
Sulfide Ammonia Groem
Alphn,
Gw mm
Tritium Activity
Scan
a d ) B e t e
.^
Sr.9G
Sampb No. Mmtdx• Date Sampled Time Semplmd - - - '
BOGF85 O I W fl/^'I 5- 1 L
BOGF86 O,^J w /2 L
o^ 3Xio 03
SPECIAL INSTRUCTIONS
Mwl°'
CHAIN 0F POSSESSION S18nIPrint
.
Names
1 Zn A c+NeO H
a • ey^
Reli uimhad By Dete/ilme R v LG^ Date/Time /y/O
Sample analysis for phoephate, nitrate, and nitrite by EPA 300.0; and turbidity
^_ S^"
yL • p.do,
Gr^71, Date/Time
9:V
ece(ved By ^^js eteRme flZQ
b y EPA 180 . 1 I s bein g r eques ted for Inform
ation onl y. The ERC Contractor
nc k now l e d pee t h at t h e 48 - h uur h o ldi ng t i me w ill not b e met.
o. ON r°
e_ Nr
.
^
Relinquim ed By
•
Relinquished By.
Datemme
Date/rlme
Received By
R ed teT
//aU
The Activity Scan is for ell samples listed on this chain of custody.
oL - o .un LqW ,
T TWw
W, _ v+w
L' u^"°
"
x - oiw
t.ABORATORY Received By Title Oate/Time
SECTION
FINA1. SAMP1IE Disposal Method Disposed By Dete/Tima
DISPt7SH10N:
ICP
Matale
IFilterodl

Q
O
^O^
T
U^.
O ^
^v
Bechtel H®nford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contact Telephone
ZU R. E. Peterson ( 508) 372-9638
Page 1 of -I
Data Turnaround
Proj ect Daslpnaoon Samplinp Location SAF No.
100-HR-3 Groundwuu Samppnp, Round 9, Pheae 2 100 D BeFi068
Ice C at o. Field Logbook No. Method of Shipment
-/q >
Hand Delivered
Shippad To ONelte Propen NP . r Bill of LadinplAir Bill No.
Quanturn NA t7 ( ( 2/ NA ( A
Possible Sampte Hazude/Ramarkt
Preservation
HNO3 Cool4•C HrSO• •1 HtSO• HNO, Cool4°C Cool4°C HNO,
q Priodly
n Normal
Type of Contalnar ^ G G P!{ P R(1' PIG G PIG !/ G
No. of Contalnerlel
1 1 1 3 1 4 3 1 1
Special Handling nnd/or Storage
Maintain aamplo betwaan 20C and 69C.
Volume
SOOm1 500mL 500mL 500mL SOOmL IL SOOmL 20mL 500mL
G/^/-
^f'1'
ICP
AN. pCl
F. a. e0,.
SAMPLE ANALYSIS /^n/-
Metala
IUnflltu-
NO,.
Hpe,
Hq,
NO2 -
NO 3
Sulfide Ammonia Groce
Alphe,
Gron
Litium
nr126'
Activity Scan Metde
(Filteredl
` ( . LP
ad) Bate,
S 0f^
:f(/rJ J r-9
Sample No. Matrix• Date Sampled T-ime Sampled
BOGFB9 03 w S/ fS''/9S O^-
BOGFCO 97 w Af /U i.f
00 p 0 ( o0 3^1^^ oJ lrJ
CHAIN OF PQSSES$ION
1
Sign/Print Names
SPECIAL INSTRUCTIONS
1 ZnAc+NeOH
M•v^•'
y _cy^
fle n Iehed By iyc.c Dele/Time
Data/Tlme
^.^
Ra
iv
bed By ^
0
DetuRime lt/j0
Semple mdyeia for phosphate, nitrate, and ritrite by EPA 300.0; and turbidity
b EPA 180 1 I b i r t d for I f tion l The EflC Contractor
alTime .2G y . . e ng eques e n orma on y.
9 acknowledges that the 48-hour holding time will not be met.
So- saua^
u^W„dg,
wo _ w.w o r
A. N,
De-o^^msow.
elinqule ed By onteRle r ReceivedBy eteRi
/aa
The Activity Scan is for all aamplea listed on this chain of cuelody.
^_
it - pwtqae.
t++=ww
flelinyuiahed8y . OeteRune fl sI 8 ///LDe P
^
5-
LABOf1ATOHY
SECTION
Received By Title DateRime
FINAL SAMPLE Diapoad Method Disposed By Dale/Time
nIsrpsmoN,
V v.ouw•„
x-on,.

•
0
^0A
T
Q•
Q S
^
r ^
Bechtel Hanlord, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Pape 1 of 1-
CoUwtor
^^- 2 o
Company Contact
R. E. Patenon
Telephona
( 609) 372-9638
Data Turnaround
0 Pdority
n Normal
Pro ct asl8nedon Samplinp Location SAF No.
100-HR-3 Grourxlwater Sampling, Round S. PFwe 2 100 D B95-088
Ice C eat No.
14L-516 Field Logbook No.
le FL - / d/P
Method of Shipment
HandDeBvered
SNpped To
Ouermms
Olleita Pruperty ^1 o.
NA r '}- Il
j 2
Bill of Ladine IAir Bill No.
NA
Possible Semple HaZard•/Ramark•
Preservation
HNO,r Cool4°C Hr50, •1 HtSO• HNO,t Cool4°C Cool4"C HNO,
Type of Container
No. of Conteinar(e)
6 G I, G Pip P P0C P/G G P/G G
1 1 1 3 1 4 3 1 1
'
Spacial Hend6np and/or Storapa
Maintain aamplaa batwem 20C and 64C.
Volume
SOOmL 50OmL 500mL SOOmL 500mL 1 L SOOmL 20mL 500mL
SAMPLE ANALYSIS
5og25^
151:6`" WD
1 _ /] I
(° (
ICP
Metale
(Unfilt

O
^
0
t^ I
?oJ
r .^
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Paee 1 of 1
Data Turnaround
I
Collector ^
I/ [ .
Company Contact
R. E. Petarson
Telephone
(509) 372-9638
0 Priority
N Nurmal
Pro eot Deaipnaeon Samplinp Location SAF No.
100-HR-3 Groundwater Sampling, Round 9, Phese 2 100 D B95-088
Ice Chest No. Field Logbook No. ^-- /y
Method of Shipment
G•-^r.
ry /^L -/ U^d Hand Delivered
Shipped To Oflsite Property P` Bill of Ledin0lAir Bill No.
Quentern NA ('1 ^ L NA / d
Possible Sample HezerdslRsmuke
Prerorvatlon
HNOz Cool4°C Hr50, •1 H'50' HNO3 Cuol4°C Cuol4°C HNO3
Type of Container
No. of Contalner(s)
G ( i G P/0 P Pilo PIG G PIG G
1 1 1 3 1 4 3 1 1
Specid Hsndlinp andlor Storepe
Malntaln semples between 2•C and 6°C.
Volume
SOOmL 500mL SOOmL 500mL SOOmL 1 L 500mL 2OmL SOOmL
Snl
ICP
A1MO"° IiQ
' a so
F
SAMPLE ANALYSIS
508^51
Metals
(Unfltered)
, . ,.
NO,. No,.
Pe,
NO, -
NO3
Sulfide Ammonia Grues
Alphe,
Gross
Bete, r D
Sr-9Q J
TrI
a t r
yl^^
J
Activity
S can
ICP
M ete l e
(Filtered)
Semple No. Matriz• Date Sampled Time Sampled
BOGF81 W
BOGF82 (/tT W
o^ o^ oJ 31!(^ o^ /oJ
SPECIAL INSTRUCTIONS M•r^^•'
CHAINOFPOSSESSIQN Sipn/PrintNamee •1 ZnAc+NeOH 5 -ew
.
ReG iehed By
Rd
alinquiahed B y
DateRime
^
Dele/iime
Dnte/Time
Z?12'
&
9^
Re e
ec 'ved B
ecsivedBy
Clt^
d(
DateTme z//O
/
ete/fimey-'
Dete/Time
^^.>
Sample analysis for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity
by EPA 1 B0 . 1 i s b e i ng reques t e d f or I n forma ti on o nl y. Th e ERC Co n tr a ctor
acknowledges that the 48hour holding time will not be met .
he Activity Scan is for all semples Ssted on this chain of custody.
?.rv/OOfiallv
sr -^°°^^"
^_ y
W - W
o- ou
A - Al,
oe _ bna, sae°
o1-o,^e,tq°e.
t- Ti.w
^ _ yry,
Relinquiahed B
-
y Date/Time
Rec 4 B
y
^G
etp
L ^t'
tbW
v - v.vnweo
z - oa.r
LABORATORY
SECTION
Received By Title DatelTime
FINAL SAMPLE Disposal Method Disposed By Date/Fime
DISPDSITION

cl;
^
^
^
0
1ry ^.
K
^
'j
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contact Telephone
R. E. Peteraon 16091 372-9638
Page 1_ of _]_
Data Turnaround
D Pnodry
Project Designation Sampling Location SAF No.
100-HR-3 Groundwater Sampling. Round 9, Pheee 2 100 D 895-088
Ice Chest No. Field Logbook No. Method of Shipment
S/ryL $-^3 ^-F[, - /Ol Hand Delivered
Shipped To Offeite Prape o. 818 of LadinplAir Bill No.
Quenterra NA ( NA I I
Poeeible Sample Hazarde/Rernarka
Preservation
Type ofContainer
No. of Container(a)
^ Normd
HNO, Cool4°C HrSO, '1 HrSO° HNO, Coul4°C Cool4°C HN%
G G
PAN
P P!Q P/G G P/G f7 G
1 1 3 1 4 3 1 1
Special Handling and/or Storage
MAntdnamnpleabetween2•C and6°C.
volume
500mL 500mL 6OOmL 50OmL 500m: 1L 500mL 20mL 500mL
C!l/. ICP p110ef Ocl NO2 - SAMPLE _ s NALYSIS 1 , 1 / - /'7/
IN0 CD
Metals
N n fdt er -
ad)
-F'Q'SO"
NO3, NOw
po,
NO3
Sulfide AmmoMe
Gross
Alpha,
Gross ^n
Bate,
9r-90
Tritium
nl
V
J
Activity
Scan
ICP
Metals
lRltersdl
508^Ca b'
Snmple No. Matdx• Dete Sempled Time Sempled - - `' - -: ' ' = - - ^'- - - - ^ - - - ^-
BOGFDS W ^ • /,S 9,(- / a'o ^i ^
BOGF06 W
CHMN OF P9§,SES$IQN Sign/Print Names
^ IO^ I^^ JO J^ pJ
SPECIAL INSTRUCTIONS
Mre4•
' 1 ZnAc+NaOH e -sw
fteli lehadBy DeteTme ve Deta(rune 13jr
^
_ Sample analysis for phosphate, nitrate, and nitrite by EPA 300.0; and turbidity
eo-4ab^
^- y'd,
e
elinqu ehad By
Data/Fbne
DeteRme
1
Received y
Received By
4'Q
^f(^
rv
Date(Time
Date/Time
^J
y EPA 180-1 is being requested for informetion only. The ERC Contractor
acknowlad8ea that the 48-hour holding time will not be met.
The Activity Scan is for all samples Neted on this chain of custody .
W - we.
o- ON
A A
os _ mvn saie.
Of - p,,.n tqda.
T -Tww
WI- Wp
Relinquished By Datc/Nme Received By DateTme L c°"d .
x -aa^
,;.,@QFlATORY Received By Title DateTme
A DbpoealMethod DlaposedBy DateTme

^
a f
n "\
0
0
'Pill
W
PeOe 1 of i
Bechtel Hanford, inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
- Data Turnaround
Collector
. L^
•
Company Contact
R. E. Pateraon
Telephone
( 509) 372-9638
q Pdarit y
^ Normal
Project Designation Semplina Location SAF No.
100-HR-3 Groundwater SampBnO. Round 9, Phase 2 " 100 D 895-068
Ice Chest No. Field Logbook No.C Method of Shipment
,^jnF ^- S/[ C^FL •/ (-zI )S Hand Delivered
Shipped To Offsite Property Biq of Lading/Air Bill No.
Ouantarra NA NA I
Possible Sample Hezards/Remarka
Preservation
HNO, Cuol4°C H,50, •1 H,SO4 HNO, Cod4°C Cool4°C HNO,
Type of Container
No. of Conteiner(s)
G OG P!D P P/t PIG G P/G /r G
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Volume
Maintain samples between 2°C and 6°C. 500mL 500mL SOOmL 500mL SOOmL IL 500mL 20mL 500mL
^/ ' ^
^1/^L
ICP
Metals
A^"n• (la)
-
NO, - Sulfide Ammonia Gross Tritium Activity ICP
F, a, s0,. SAMPLE ANALYSIS ^
(Unfilter-
No„ NO,,
p0,
NO, Alpha
Gross ,(Y
Seen Metals
(Filteredl
(j //vI
ed)
Beta,
xJ.^((
D lJ^
Sr-90
Sample No. Mavix• Data Sampled Time Sampled
BOGFCI 0 W )S' i)
BOGFC2 W S' S-
/ /t
/C}
oJ o) 0b 3100 o')
. CHAIN OF
-
POSSESSION
. ,
Relinquished By DeteRime
k^crC _
Sign/Print Nemae
SPECIAL INSTRUCTIONS
•1 2nAc+NeOH
M•r^^•'
s -sw
Re a Deta(Tme ^
Cc• gis^ t^ i3^s
' q ui Dete/Tme 9
-
alinquiahed By' Dete/Tme ^
eceivad B y ^(^^/
fleceived By
Dete(Time
ateRme
^3^1'
Sample ane ysis for phosphate , nitrata , and n i trite by EPA 300 . 0; and turbidity
b y EPA 180 . 1 i s b e i ng requee ta d f or i n l orma ti on on l y. Th e ERC C on t ractor
ac k now l e d ges t h at t h e 48 - h our h o ldi ng t i me w ill not b e met.
The Activity Scan is for all samples listed on this chain of custody .
sr - s.am.or
so- swd
x_ y^•
w- w.r.,
o- ou
A _ N,
ps- o,un soea.
Of.
- d"L" tb^i
T - T.
Nt- WW
Relinquished By Date/Tme Received By Date/Time t- tb'*
V - vq.uu°n
It - 00w
LABORATORY
BEOTION
Received By Title Date/Time
FINAL BAMPLF Disposal Method Disposed By Date/lime
DIBPO6ITfON:

^
i
v'^
^
^
^
'vv
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Pepe1of 1
Collector 1^
1^- ^ e
Company Contact
R. E. Peterson
Telephone
( 509) 372-9638
Data Turnaround
q Priorit y
^ Normal
Project Designation Sampling Location SAF No.
100-HR-3 Groundwater Sampling, Round 9, Phase 2 100 D 895-088
Ice Chest No.
Field Logbook No. C
Method of Shipment
.5/h ^'.s^^ C f^ - /U( Hand Delivered
SNpped To
Quenterra
Offsite Prnpe
NA
o.
^
Bill of Lading/Air Bill No.
NA I
I
Possible Sample Hatardel88marks
Pracerva6on
HNO3 Coul4°C HtSO, •1 HrSO• HNO3 Cool4°C Cool4°C HNO3
Type of Container
. No. of Container(s)
G G P/b P Pl0 PIG G PIG G
1 1 1 3 1 4 3 1 1
Special Handling and(or Storapa
Maintain samples between 26C and 8°C.
Volume
500mt 50OmL 500mL 500mL SOOmL 1 L SOOmL 20mL 500mL
^L
S
ICP
Ao1O^s tlcl
SAMPLE ANALYSIS
i
[i
. Metals
(Unfilter-
-P, ta, so„
NO,. NO,.
no,
NO2 -
NO 3
Sulfide Ammonia Gross
Alpha,
Gross
Tritium
/^
/I^rl N'
Activity
Scan
ICP
Metals
(Filtered)
Db,^I
'
^sa^ ^ . ,
ad) Beta.
Sr-9G 6D
Sample No. Matrix• Data Sampled Time Semplnd - - - -' - "
BOGFC3 D5 W YS' / f4- If
BOGFC4 D(y W 7 ^Gc^ d^'
+
+
(o3 lo') 0J (o^ Jo^
.
CHAIN OFPOSSES$ION
Si9nlPrint
,_. :
- .
Names
Reli ' he By Date(Tme
R rv Dete/fime 13?5e'^`v
.^' S S5J/37S' ' JJL- -'^
Rul d Data/Time 9 • Recaivad By .:., ateTma
^ l
^
^- 6-fY
' i . . ^ , / !^elinquished
By Dete/fime Received By ^/-DalafTme
SPECIAL INSTRUCTIONS
•1 ZnAc+NaOH
Sample enalysia for phoaphate, nitrate, and nitrite by EPA 300.0; and turbidity
by EPA 180 . 1 i s b e i ng reques t e d f or i n f ormet i on onl y. Th e ERC C ontractor
acknowledges that the 48-hour holding time will not be met.
The Activity Scan is for all samples liated on this chain of custody.
M•r^•'
a - s°r
SE
^ i4
a
- y^•
W - w . u ,
o- oa
A - "°
DS - D,un e W4
m- o"'" Liqidi
T - Tiw
WI. Wp•
Relinquished By Date/Tima Received By DatelTime t- th"a
V - VyiM°o
x - eew
LABORATORY
SECTIpN
Received By Title DetalTime
FfNA1. SAMPLE Dieposal Method Disposed By Date/Time
I AISPOSITIQN,
{^
/`

Supplemental Information
404.06GNC.NAR; Printed: 26-Oct-95, 12:50 pm
000051

LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
INFORMATION REQUEST FORM R
i
To: Jeanette Duncan, WHCIBFiI bate: 10123195
^.
^
uf.. ,'^ ••cuvnw _ asw: :^:II. z y ^,. n^i, r 5 ^ ,•ri
PROJECT NAME: 100-HR3 ROUND 9 PHASE II
SDG NUMBER: Vu0871-QES
LATA NO.: V5404.08
LABORATORY: QES
CASE NUMBER: N!A
ANALYSIS METFiOD:
ANALYSIS DATE:
ITEM (S) MISSIN
Comrnents; It appears from the raw data that samples BOGFD5 and
BOGFDB are field blanks. These samples are not listed on the Sample Summary Table
as field blanlcs.
Attention: B MORRIS
RETURN TO LATA
INFORMATION RECEIVED FROM WHC (INITIALSlDATE);
INFORMATION ACCEPTABLE?- YES NO ^
If NO is checked, send a new LIRF to request additional Information.
000052
40400MTL);LS, LIRF-1
10l23/BS. 9:17 AM
Zoo Di S'iHSFC KSVH DHa 90iZ ZLC B09a 00:bi 96/CZ/0T

Ir
END OF PACKAGE
404.06GNC.NAR; Printed: 23-Oct-95, 3:25 pm ooooss

i -f
DATA VALIDATION REPORT
for
100-HR3 GROUNDWATER ROUND 9
PHASE II
Radiochemistry Analysis
SDG W0671-QES
LATA VB404.06
Bechtel Hanford Inc.
P.O. Box 969
Richland, Washington
November 2, 1995
40406RAD.NAR; Printed: 2-Nov-95, 11:51 am 000000

Table of Contents
Data Validation Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000002
INTRODUCTION ...... ......................................... 000002
ANALYSES REQUESTED ......................................... 000002
DATA QUALITY OBJECTIVES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000002
REFERENCES ...... ........................................... 000004
GLOSSARY OF VALIDATION APPLIED QUALIFIERS (RADIOCHEMISTRY) .. 000005
GLOSSARY OF LABORATORY APPLIED QUALIFIERS . . . . . . . . . . . . . . . . . . 000006
Qualification Summary Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000007
Data Summary Table .......... ........................................ 000009
Sample Results ...................................................... 000012
Checklist ........................................................... 000022
Laboratory Case Narrative . I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000033
Chain-of-Custody Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000037
Supplemental Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 000050
END OF PACKAGE .... .............................................. 000053
40406RAD.NAR; Printed: 2-Nov-95, 11:49 am 00000 1

INTRODUCTION
100-HR-3 GROUNDWATER ROUND 9 PHASE II
Data Validation Narrative
All samples in Sample Delivery Group (SDG) W0671-QES (VB404.06) were validated at level D as
defined in the Data Validation Procedures for Radiochemical Analyses (WHC-SD-EN-SPP-001, Rev. 1).
The analyses were performed by Quanterra Enviromental Services.
ANALYSES REQUESTED
See Table 1.
DATA QUALITY OBJECTIVES
Precision: Goals for precision were met.
Accuracy: Goals for accuracy were met.
Sample Result Verification: All sample results were supported in the raw data.
Detection Limits: Detection limit goals were met for all sample results as specified
in the RCRA Facility InvestigationlCorrective Measures Study
Work PLan for the 100-HR-3 Operable Unit, DOE/RL-88-36, Rev.
0.
Completeness: The data package was 100% complete for all requested analyses.
MAJOR DEFICIENCIES
No major deficiencies were identified during data validation which required qualification of data as
unusable.
MINOR DEFICIENCIES
No minor deficiencies were identified during data validation which required qualification of data as
estiritated.
40406RAD.NAR; Printed: I-Nov-95, 11:57 am 000002

Table 1
Chain-of-Custody
Analysis Request
LATA ID #: VB404.06 SDG: W0671-QES
Sample Information Analyses Requested
SAMPLE DATE
FIELD QC
NO. COLLECTED MATRIX SAF INFO 1 2 3 4 5 6
BOGFD3 11-Aug-95 WATER 95-068 EQUIP BLANK X X X X X X
BOGF83 11-Aug-95 WATER 95-068 X X X X X X
BOGF85 14-Aug-95 WATER 95-068 X X X X X X
BOGFB9 14-Aug-95 WATER 95-068 X X X X X X
BOGF99 14-Aug-95 WATER 95-068 X X X X X X
BOGF81 14-Aug-95 WATER 95-068 X X X X X X
BOGFD5 15-Aug-95 WATER 95-068 EQUIP BLANK X X X X X X
BOGFC1 15-Aug-95 WATER 95-068 X X X X X X
BOGFC3 15-Aug-95 WATER 95-068 X X X X X X
Method References:
Analysis
1. Gross Alpha
2. Gross Beta
3. Strontium-90
4. Tritium
5. Rad Screen
6. Activity Scan
Method
ITAS-RD-3214
ITAS-RD-3214
ITAS-RD-3204
ITAS-RD-3205
Lab Specific
Lab Specific
NOTES: ( complete documentation of these notes can be found in the Supplemental Information Section of this report)
NOTE 1:
The Rad Screen was deemed unnecessary prior to off-site shipment.
Printed 10/24/95, 13:09 40406DST.XLS 000003

REFERENCES
WHC 1993, Data Validation Procedures for Radiochemical Analyses, WHC-SD-EN-SPP-001, Rev. 1,
Westinghouse Hanford Company, Richland, Washington.
DOE 1992, RCRA Facility Investigation/Corrective Measures Study Work PLan for the 100-HR-3
Operable Unit, DOE/RL-88-36, Rev. 0, Department of Energy-Hanford, Richland, Washington.
40406RAD.NAR; Printed: 24-Oct-95, 6:55 am 000004

GLOSSARY OF VALIDATION APPLIED QUALIFIERS (RADIOCHEMISTRY)
Qualifiers which may be applied by data validators in compliance with the procedures herein are as
follows.
U- Indicates the constituent was analyzed for, but was not detected at a concentration above the
Minimum Detectable Activity (MDA). The concentration reported is the sample result corrected
for sample aliquot size, dilution factors, and percent solids (in the case of solid matrices) by the
laboratory. The associated data should be considered usable for decision making purposes.
UJ- Indicates the constituent was analyzed for and was not detected at a concentration above the
Minimum Detectable Activity (MDA). Due to a quality control deficiency identified during data
validation, the result reported may not accurately reflect the sample concentration. The
associated data should be considered usable for decision making purposes.
J- Indicates a constituent was analyzed for and detected. The associated value is estimated due to
a quality control deficiency identified during validation. The data should be considered usable
for decision making purposes.
R- Indicates the constituent was analyzed for and detected; however, due to an identified quality
control deficiency the data should be considered unusable for decision making purposes.
UR- Indicates the constituent was analyzed for and not detected; however, due to an identified quality
control deficiency the data should be considered unusable for decision making purposes.
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm 000005

GLOSSARY OF LABORATORY APPLIED QUALIFIERS
Qualifiers which may be applied by the laboratory in compliance with applicable requirements are as
follows.
Commonly used laboratory radiochemistry qualifiers:
U- Indicates the analyte was analyzed for but not detected in the sample.
J- Indicates the value reported is estimated due to the presence of interference.
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm 000006

Qualification Summary Table
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm 000007

ANALYTE
I
Qualification Summary Table
TYPE QUALIFIER
Radiochemistry
SAMPLES
AFFECTED
DQO REASON
No qualifiers were assigned by the validator.
Radiochemistrv Field QC
ANALYTE TYPE QUALIFIER FIELD QC DQO ASSESSMENT
SAMPLES
All Equip Blank NONE BOGFD3 BLANKS Equipment blank results were
acceptable.
All Equip Blank NONE BOGFD5 BLANKS Equipment blank results were
acceptable.
Comments:
The "U" qualifers added to the Data Summary Tables and Form Is are laboratory concentration qualifiers to indicate
that the results are

Data Summary Table
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm 000009

RADIOCHEMISTRY
DATA SUMMARY TABLE
LATA ID#: VB404.06 HEIS #: BOGFD3 BOGF83 BOGF85 BOGFB9
Date: 11-Aug-95 11-Aug-95 14-Aug-95 14-Aug-95
Matrix: WATER WATER WATER WATER
Constituent CAS # Units Results Q Results Q Results Q Results Q
Gross Alpha ALPHA pCi/L -1.94E-01 U 2.67E+00 2.35E+00 7.37E-01 U
Gross Beta BETA pCi/L 8.64E-01 U 4.92E+00 7.53E+01 4.10E+00
Strontium-90 10098-97-2 pCi/L -1.55E-01 U 1.51E-01 U 3.87E+01 -4.53E-02 U
Tritium 10028-17-8 pCi/L 2.26E+01 U 1.84E+03 3.63E+04 1.15E+02 U
Shaded areas indicate changes by the validator.
11/1/95, 11:51 40406DST.XLS, RADIOCHEMISTRY
000010

RADIOCHEMISTRY
DATA SUMMARY TABLE
LATA ID#: VB404.06 HEIS #: BOGF99 B0GF81 BOGFD5 BOGFC1 BOGFC3
Date: 14-Aug-95 14-Aug-95 15-Aug-95 15-Aug-95 15-Aug-95
Matrix: WATER WATER WATER WATER WATER
Constituent CAS # Units Results Q Results Q Results Q Results Q Results Q
Gross Alpha ALPHA pCi/L 1.01E+00 U 2.50E+00 2.54E-01 U 1.64E+00 U 1.17E+00
Gross Beta BETA pCi/L 5.73E+00 6.54E+00 8.64E-01 U 3.76E+00 4.83E+00
Strontium-90 10098-97-2 pCi/L -5.13E-02 U 2.88E-01 U -9.91E-02 U -2.28E-02 U -1.23E-03 U
Tritium 10028-17-8 pCi/L 2.43E+02 U 1.73E+04 -8.57E+01 U 3.98E+03 2.28E+03
Shaded areas indicate changes by the validator.
10/17/95, 12:09 40406DST.XLS, RADIOCHEMISTRY
000011

Sample Results (Form I's)
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm OOOOlW

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50824101 MATRIX: WATER
1,011
iiuanterra
Emironmema!
Services
CLIENT ID: BOGFD3 DATE RECEIVED: 8/14/95 10:00:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA -1.94E-01 1.4E-01 1.5E-01 6.58E-01 pCUL 100.00% RD3214 /.(.
BETA 8.64E-01 1.3E+00 1.3E+00 2.82E+00 pCi/L 100.00% RD3214 GG.
STRONTIUM -1.55E-01 1.5E-01 1.6E-01 7.36E-01 pCi/L 99.70% RD3204 /,(„
TRITIUM 2.26E+01 1.4E+02 2.2E+02 3.37E+02 pCI/L 88.10% RD3205 u^
Number of Results: ®
000013 ^ e^

LAB NAME: ITAS-RICHLAND
LAB SAMPLE ID: 50824102
CLIENT ID: BOGF83
SAMPLE RESULTS
SDG:
MATRIX:
DATE RECEIVED:
^iaanterra
Environmenta!
Services
W0671
WATER
8/14/95 10:00:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR (2 s) ERROR (2 s) MDA UNIT YIELD NUMBER
ALPHA 2.67E+00 1.3E+00 1.4E+00 1.51E+00 pCi/L 100.00% RD3214
BETA 4.92E+00 1.8E+00 1.8E+00 3.19E+00 pCi/L 100.00% RD3214
STRONTIUM 1.51E-01 2.7E-01 2.7E-01 1.04E+00 pCUL 69.20% RD3204 /,t...
TRITIUM 1.84E+03 2.3E+02 3.4E+02 3.37E+02 pCUL 88.10% RD3205
Number of Results: ®
n
-96'
000014 ,,0,08

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50825201 MATRIX: WATER
fAl"uanterra
Ernironmenta/
Services
CLIENT ID: B0GF85 DATE RECEIVED: 8/15/95 9:20:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 2.35E+00 1.6E+00 1.6E+00 1.98E+00 pCi/L 100.00% RD3214
BETA 7.53E+01 4.6E+00 7.OE+00 3.23E+00 pCi/L 100.00% RD3214
STRONTIUM 3.87E+01 1.5E+00 9.5E+00 9.15E-01 pCi/L 77.90% RD3204
TRITIUM 3.63E+04 8.2E+02 2.8E+03 3.37E+02 pCVL 88.10% RD3205
Number of Results: ®
000015 reog

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50825202 MATRIX: WATER
^iiuanterra
Environmental
Services
CLIENT ID: BOGFB9 DATE RECEIVED: 8/15/95 9:20:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR (2 s) ERROR (2 s) MDA UNIT YIELD NUMBER
ALPHA 7.37E-01 6.1E-01 6.2E-01 9.67E-01 pCi/L 100.00% RD3214 GL
BETA 4.10E+00 1.6E+00 1.6E+00 2.88E+00 pCi/L 100.00% RD3214
STRONTIUM -4.53E-02 1.8E-01 1.8E-01 7.89E-01 pCi/L 95.70% RD3204 G(r
TRITIUM 1.15E+02 1.5E+02 2.3E+02 3.37E+02 pCi/L 88.10% R03205 g^
Number of Results: ®
)/0
^ q5
00001ti J p-ro

LAB NAME: ITAS-RICHLAND
LAB SAMPLE ID: 50825203
CLIENT ID: BOGF99
SAMPLE RESULTS
SDG:
MATRIX:
DATE RECEIVED:
^iiuanterra
Environmemal
Services
W0671
WATER
8115/95 9:20:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 1.01E+00 7.2E-01 7.3E-01 1.04E+00 pCi/L 100.00% RD3214 GC:
BETA 5.73E+00 1.8E+00 1.9E+00 3.09E+00 pCUL 100.00% RD3214
STRONTIUM - 5.13E-02 1.8E-01 1.8E-01 7.89E-01 pCi/L 95.90% RD3204 L.
TRITIUM 2.43E+02 1.5E+02 2.4E+02 3.37E+02 pCi/L 88.10% RD3205 w
Number of Results: ®
000017
j^
i

LAB NAME: ITAS-RICHLAND
LAB SAMPLE ID: 50825204
CLIENT ID: BOGF81
SAMPLE RESULTS
SDG:
MATRIX:
DATE RECEIVED:
^^aanterra
Environmental
Services
W0671
WATER
8/15/95 9:20:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 2.50E+00 1.3E+00 1.3E+00 1.59E+00 pCi/L 100.00% RD3214
BETA 6.54E+00 1.9E+00 1.9E+00 3.14E+00 pCi/L 100.00% RD3214
STRONTIUM 2.88E-01 2.5E-01 2.6E-01 8.63E-01 pCi/L 79.40% RD3204
TRITIUM 1.73E+04 5.7E+02 1.5E+03 3.37E+02 pCi/L 88.10% RD3205
Number of Results: ®
000018 ^ 12

LAB NAME:
LAB SAMPLE ID:
CLIENT ID:
ITAS-RICHLAND
50826901
BOGFD5
SAMPLE RESULTS
SDG:
MATRIX:
DATE RECEIVED:
^^uanterra
Environmental
Servlces
W0671
WATER
8/16/95 9:45:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR ( 2 s) ERROR (2 s) MDA UNIT YIELD NUMBER
ALPHA 2.54E-01 2.9E-01 2.9E-01 5.08E-01 pCi/L 100.00% RD3214 G^-
BETA 8.64E-01 1.2E+00 1.2E+00 2.61E+00 pCi/L 100.00% RD3214 Gc_
STRONTIUM - 9.91E-02 1.7E-01 1.7E-01 7.73E-01 pCUL 98.10% RD3204 w
TRITIUM -8.57E+01 1.3E+02 2.2E+02 3.37E+02 pCi/L 88.10% RD3205 w
Number of Results: ®
ooooso
D^
/

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50826902 MATRIX: WATER
iiiuanterra
Environmental
Services
CLIENT ID: BOGFC1 DATE RECENED: 8/16/95 9:45:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 1.64E+00 8.5E-01 8.7E-01 9.83E-01 pCi/L 100.00% RD3214 ! t-
BETA 3.76E+00 1.6E+00 1.7E+00 2.99E+00 pCi/L 100.00% RD3214
STRONTIUM -2.28E-02 1.8E-01 1.8E-01 7.71 E-01 pCi/L 94.80% RD3204 /,t-.
TRITIUM 3.98E+03 3.0E+02 4.9E+02 3.37E+02 pCUL 88.10% RD3205
Number of Results: ®
000020 94

SAMPLE RESULTS
LAB NAME: ITAS-RICHLAND SDG: W0671
LAB SAMPLE ID: 50826903 MATRIX: WATER
^iuanterra
Environmental
Services
CLIENT ID: BOGFC3 DATE RECEIVED: 8/16/95 9:45:00 AM
COUNTING TOTAL REPORT METHOD
ISOTOPE RESULT ERROR(2s) ERROR(2s) MDA UNIT YIELD NUMBER
ALPHA 1.17E+00 7.1E-01 7.2E-01 8.38E-01 pCt/L 100.00% RD3214
BETA 4.83E+00 1.7E+00 1.7E+00 2.90E+00 pCilL 100.00% R03214
STRONTIUM -1.23E-03 1.8E-01 1.8E-01 7.59E-01 pCi/L 96.00% RD3204 GC,
TRITIUM 2.28E+03 2.4E+02 3.7E+02 3.37E+02 pCi/L 88.10% RD3205
Number of Results: ®
oooozI
^ k ,^- 9S

Checklist
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm 0000=

LATA RADIOCHEMISTRY
DATA VALIDATION CHECKLIST
VALIDATION A B C (^ E
LEVEL:
VALIDATION Rev. 0 q WHC-SD-EN-SPP-001, Rev. 1
PROCEDURE:
PROJECT: 100-HR-3 RO ND 9 HASE 11 SDG: W0671-QES
VALIDATOR: AM FREIER D^^^ LATA NO: VB404.06 DATE: 17-Oct-95
er^
REVIEWER: BJ MORRIS ID 30 LAB: QES CASE: N/A
DOE/RL-88-36,
SAF NO: B95-068 QAPP NO: Rev. 0 SAP NO: N/A
ANALYSES REQUESTED
14 ross Alpha/Beta Strontium-90 ^l
Tritium
ITAS-RD-3214 ITAS-RD-3204 ITAS-R D-3205
SAMPLE NO. MATRIX
COMMENTS:
BOGFD3 BOGF83
B0GF85 BOGFB9
BOGF99 BOGF81
BOGFD5 BOGFCI
BOGFC3
WATER
1. DATA PACKAGE COMPLETENESS AND CASE NARRATIVE
Is technical verification documentation present?
Is a case narrative present?
2. HOLDING TIMES
Are sample holding times acceptable?
Are samples preserved correctly?
,.,,.
^Jy q L-I
^1 q q
YES NO N/A
} U q
J q q
IF-- See HOLDING TIME SUMMARY form 11
3. INSTRUMENT PERFORMANCE AND CALIBRATIONS
Were instruments/detectors calibrated within one year of sample analysis?
Are initial calibrations acceptable?
Are standards NIST traceable?
^_! q t...l
ax ^} q q
Are standards acceptable?
iJ q q
Comments: Calibration of instruments/detectors was not performed within one year of sample analysis,
however continuing calibration data is acceptable. Therefore, no qualifiers are assigned.
PNO-DVF-015, R2
40406RAD.XLS, Checklist
10/24/95, 7:28
000023

LATA RADIOCHEMISTRY
DATA VALIDATION CHECKLIST
4. CONTINUING CALIBRATION YES NO N/A
Background checked at proper frequency? q ^ q
Background check acceptable? q ^ q
Efficiency checked at proper frequency? q ^
Efficiency check acceptable? q J q
Calibration check standards NIST traceable? ^^ J q
Calibration check standards acceptable? i^ q
11 If NO(s) are checked, see CALIBRATION DATA SUMMARY form 11
5. BLANKS YES NO N/A
Were method blanks analyzed? I^
Are the method blanks free of analytes? ^
Were method blank results acceptable?
Validation calculation/transcription checks were performed and are acceptable. qq
11 If NO(s) are checked, see BLANK DATA SUMMARY form 11
6. ACCURACY YES NO N/A
Were spike samples analyzed at the proper frequency? q !^ 1E)
Are all spike sample recoveries acceptable? q q ^
Were laboratory control standards ( LCS) analyzed at the proper frequency? q ^ q
Are all LCS recoveries acceptable? ^ -j q
Was a tracer/chemical carrier added? q IJ q
Was the tracer/chemical carrier recovery acceptable? I^ - J q
Are standard sources traceable? q ^ q
Are standards acceptable? q ^ q
Validation calculation checks were performed and are acceptable. q q q
11 If NO(s) are checked, see ACCURACY DATA SUMMARY form 11
40406RAD.XLS, Checklist 000024
PNO-DVF-015, R2 10/17/95, 11:59

7. PRECISION
Were laboratory duplicates analyzed at the proper frequency?
LATA RADIOCHEMISTRY
DATA VALIDATION CHECKLIST
YES NO N/A
Are all duplicate RPD values acceptable? IJ 'J I-D
Validation calculation checks were performed and are acceptable. [E] ID J
11 If NO(s) are checked, see PRECISION DATA SUMMARY form 11
8. FIELD QC SAMPLES
Were field QC samples ( equip/trip blanks, duplicates, splits, performance audit) identified?
Are equip/trip blank results acceptable? (see Blank Data Summary form)
Are field duplicate RPD values acceptable? ( see Field QC calculations)
Are field split RPD values acceptable? ( see Field QC calculations)
Are performance audit sample results acceptable?
Comments: BOGFD3 and BOGFD5 are equipment blanks.
9. REPORTED RESULTS AND DETECTION LIMITS
Are results reported for all requested analyses?
Are all results supported in the raw data?
Are results calculated properly?
Do MDAs meet the RDLs?
Validation calculation checks were performed and are acceptable.
Comments:
VALIDATION SUMMARY
For deficiencies (major and minor) and comments, please refer to the Qualification Summary Table.
PNO-DVF-015, R2
40406RAD.XLS, Checklist
11/1/95, 11:49
^J
-J
^.!
i.J
YES
IEJy
DX
^J
IJ
J
NO
iJ
J
0U002.5
IF
L I
1'J
[^
I_.1
N/A
J
IJ
^

LATA RADIOCHEMISTRY
DATA VALIDATION CHECKLIST
HOLDING TIME SUMMARY
SDG: W0671-QES VALIDATOR: AM FREIER DATE: 17-Oct-95
PROJECT: 100-HR-3 REVIEWER: BJ MORRIS LATA NO.: VB404.06
HEIS-SN
MATRIX
CODE ANALYSIS
DATE
COLLECTED
PREP
DATE
ANALYSIS
DATE
PREP
HT
(days)
Required
HT
(days)
ANALYSIS
HT
(day s)
Required
HT
(days)
BOGFD3 WATER Gross Alpha/Beta 11-Aug-95 N/A 18-Sep-95 N/A N/A 38 180 NONE
BOGFD3 WATER Strontium-90 11-Aug-95 N/A 25-Aug-95 N/A N/A 14 180 NONE
BOGFD3 WATER Tritium 11-Aug-95 N/A 07-Sep-95 N/A N/A 27 180 NONE
BOGF83 WATER Gross Alpha/Beta 11-Aug-95 N/A 18-Sep-95 N/A N/A 38 180 NONE
B0GF83 WATER Strontium-90 11-Aug-95 N/A 25-Aug-95 N/A N/A 14 180 NONE
BOGF83 WATER Tritium 11-Aug -95 N/A 07-Sep-95 N/A N/A 27 180 NONE
BOGF85 WATER Gross Alpha/Beta 14-Aug-95 N/A 18-Sep-95 N/A N/A 35 180 NONE
BOGF85 WATER Strontium-90 14-Aug-95 N/A 25-Aug-95 N/A N/A 11 180 NONE
BOGF85 WATER Tritium 14-Aug-95 N/A 07-Sep-95 N/A N/A 24 180 NONE
BOGFB9 WATER Gross Alpha/Beta 14-Aug-95 N/A 18-Sep-95 N/A N/A 35 180 NONE
BOGFB9 WATER Strontium-90 14-Au -95 N/A 25-Aug-95 N/A N/A 11 180 NONE
BOGFB9 WATER Tritium 14-Au -95 N/A 07-Sep-95 N/A N/A 24 180 NONE
BOGF99 WATER Gross Alpha/Beta 14-Aug-95 N/A 18-Sep-95 N/A N/A 35 180 NONE
BOGF99 WATER Strontium-90 14-Aug-95 N/A 25-Aug-95 N/A N/A 11 180 NONE
BOGF99 WATER Tritium 14-Aug-95 N/A 07-Sep-95 N/A N/A 24 180 NONE
BOGF81 WATER Gross Alpha/Beta 14-Aug-95 N/A 18-Sep-95 N/A N/A 35 180 NONE
B0GF81 WATER Strontium-90 14-Aug-95 N/A 25-Aug-95 N/A N/A 11 180 NONE
BOGF81 WATER Tritium 14-Aug-95 N/A 07-Sep-95 N/A N/A 24 180 NONE
BOGFD5 WATER Gross Alpha/Beta 15-Aug-95 N/A 18-Sep-95 N/A N/A 34 180 NONE
BOGFD5 WATER Strontium-90 15-Aug-95 N/A 25-Aug-95 N/A N/A 10 180 NONE
BOGFD5 WATER Tritium 15-Aug-95 N/A 07-Sep-95 N/A N/A 23 180 NONE
BOGFC1 WATER GrossAlpha/Beta 15-Aug-95 N/A 18-Sep-95 N/A N/A 34 180 NONE
BOGFCI WATER Strontium-90 15-Aug-95 N/A 25-Aug-95 N/A N/A 10 180 NONE
B0GFC1 WATER Tritium 15-Aug-95 N/A 07-Sep-95 N/A N/A 23 180 NONE
BOGFC3 WATER Gross Alpha/Beta 15-Aug-95 N/A 18-Sep-95 N/A N/A 34 180 NONE
BOGFC3 WATER Strontium-90 15-Aug-95 N/A 25-Aug-95 N/A N/A 10 180 NONE
BOGFC3 WATER Tritium 15-Aug-95 N/A 07-Sep-95 N/A N/A 23 180 NONE
40406RAD.XLS, HOLD TIME
PNO-DVF-015, R2 10/24/95, 7:31
000026
VAL
Q

LATA RADIOCHEMISTRY
DATA VALIDATION CHECKLIST
BLANK DATA SUMMARY
SDG: W0671-QES VALIDATOR: AM FREIER DATE: 17-Oct-95
PROJECT: 100-HR-3 ROUND 9 PHASE II REVIEWER: BJ MORRIS LATA NO.: VB404.06
BLANK ID ANALYTE RESULT
LAB
Q UNITS
5X
RESULT SAMPLES AFFECTED
BOGFD3
Equip Blank Equipment blank results are acceptable. NONE NONE
BOGFDS
Equip Blank Equipment blank results are acceptable. NONE NONE
40406RAD.XLS, BLANKS
PNO-DVF-015, R2 10/24/95, 13:14
000027
VAL
Q

SDG: W0671-QES
LATA No.: V8404.06
LATA RADIOCHEMISTRY
CALCULATION SPREADSHEET
Analyte Observed value
Tritium 2.90E+03
Gross Alpha
Strontium
PERCENT RECOVERY (LCS)
2.17E+01
1.26E+01
True value
2.74E+03
2.24E+01
1.39E+01
Date: 17-Oct-95
Validator: AM FREIER
%R
105.8°/a
96.9%
90.6%
40406RAD.XLS, LCS %R 000028
PNO-DVF-015, R2 10/17/95, 12:00

PNO-DVF-015, R2
SDG: W0671-QES
LATA No.: VB404.06
Analyte Sample ID
Gross Alpha BOGFD3
Strontium BOGFD3
Tritium BOGFD3
LATA RADIOCHEMISTRY
CALCULATION SPREADSHEET
RELATIVE PERCENT DIFFERENCE
Date: 17-Oct-95
Validator: AM FREIER
Original
(Sample) Duplicate
concentration concentration RPD
40406RAD.XLS, RPD
10/17/95, 12:00
ND ND NC
ND ND NC
ND ND NC
oooozy

SDG: W0671-QES
LATA No.: VB404.06
LATA RADIOCHEMISTRY
CALCULATION SPREADSHEET
MINIMUM DETECTABLE ACTIVITY (MOA)
Date: 17-Oct-95
Validator: AM FREIER
Bkgmd
counts/
min (cpm)
or Count Tracer/
Std Dev time for Ingrowth Carrier Chemical Sample
of bkgmd assoc. Detector corr. recovery Decay yield volume
Analyte Sample ID (cpm) sample Efficiency factor factor factor factor (L or g) MDA
Grass Alpha BOGFD3 0.0480 100 2.27 1.00 1.00 1.00 1.00 0.20 0.66
Strontium BOGFD3 1.002 50 2.33 1.00 0.997 1.00 1.00 1.02 0.74
Tritium BOGF03 6.180 40 3.47 1.00 0.88 1.00 1.00 0.01 337
404o6RAD.XLS, MDA 000030
PNO-DVF-015, R2 10/17/95, 12:00

SDG: W0671-QES
LATA No.: VB404.06
LATA RADIOCHEMISTRY
CALCULATION SPREADSHEET
RESULTS CALCULATION GROSS ALPHA/BETA AND TRITIUM
Gross Background
Counts Counts
Analyte per minute per minute Yield
Gross Beta BOGFD3 1.26 1.10 1.00
Tritium BOGFD3 6.28 6.18 0. 88
PNO-DVF-015, R2
40406RAD.XLS, ALPHA, BETA & TRITIUM
10/17/95, 12:01
Date: 17-Oct-95
Validator: AM FREIER
Sample
Detector volume
Efficiency (L or g) Result
2.43 0.20 0.86
3.46 0.01 17.68
000031

SDG: W0671-QES
LATA No.: VB404.06
LATA RADIOCHEMISTRY
CALCULATION SPREADSHEET
RESULTS CALCULATION TOTAL STRONTIUM
Gross Background
Counts Counts per Detector dpc Sr/
Analyte per minute minute Yield Efficiency dpc Y
Strontium BOGDF3 0.74 1.002 0.997 2.327 1.154
40406RAD.XLS, Sr-TOTAL
PNO-DVF-015, R2 10/17/95, 12:01
Date: 17-Oct-95
Validator: AM FREIER
Strontium Sample
decay volume
factor (L or g) Result
0.91 1.02 -1.32E-01
OODU31G

Laboratory Case Narrative
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm 000033

Quanterra hncorporated
2800 George Washington Way
Richland, Washington 99352
509 375-3131 Telephone
509 375-5590 Fax
Bechtel Hanford, Inc.
345 Hills
Richland, WA 99352
October 2, 1995
Attention: Joan Kessner
SAF Number
Date SDG Closed
Number of Samples
Sample Type
SDG Number
Data Deliverable
I. Introduction
CERTIFICATE OF ANALYSIS
B95-068
August 16, 1995
Nine (9)
Water
W0671
Stand Alone
^iiuanterra
GnvGa„nercat
123456
4
OCT 1995
RECEIVED
Data
Log In
On August 14, 15, and 16, 1995, a total of nine water samples were received by the Quanterra
Environmental Services Richland Laboratory (QTESRL) for radiochemical analysis. Upon
receipt, the samples were assigned the following laboratory ID numbers to correspond with the
Bechtel Hanford, Inc. (BHl) specific IDs:
OTESRL ID BHI ID Matrix Date of Receint
50824101 BOGFD3 Water 8/14/95
50824102 BOGF83 Water 8/14/95
50825201 BOGF85 Water 8/15/95
50825202 BOGFB9 Water 8/15/95
50825203 BOGF99 Water 8/15/95
50825204 BOGF81 Water 8/15/95
50826901 BOGFD5 Water 8/16/95
50826902 B0GFC1 Water 8/16/95
50826903 BOGFC3 Water 8/16/95
000034
IV.I
0 4

Bechtel Hanford, Inc.
October 2, 1995
Page 2
II. Analytical Results/Methodology
oiuanterra
Environmental
Services
The analytical results for this report are presented by laboratory sample ID. Each set of data
includes sample identification information, analytical results and the appropriate associated
statistical errors.
The requested analyses were:
III. Quality Control
Gas Proportional Counting
Gross Alpha by method ITAS-RD-3214
Gross Beta by method ITAS-RD-3214
Strontium-90 by method ITAS-RD-3204
Liquid Scintillation Counting
Tritium by method ITAS-RD-3205
The analytical results for each analysis performed under SDG W0671 include a minimum of
one Laboratory Control Sample (LCS), one method (reagent) blank, and one duplicate. Any
exceptions have been noted in the "Comments" section.
Quality control sample results are reported in the same units as sample results.
IV. Comments
Gas Proportional Counting
Gross Alpha by method ITAS-RD-3214
The sample size was reduced from 200 mL to 152 mL for sample B0GF85 due to a high
precipitate weight. The sample meets the RDL requirement using the reduced volume. The
LCS, batch blank, sample and sample duplicate (BOGFD3) results are within contractual
requirements.
Grs^ta by method ITAS-RD-3214
The LCS, batch blank, sample and sample duplicate (BOGF83)
requirements.
results are within contractual
000035
/
^ q5
t../ "

Bechtel Hanford, Inc.
October 2, 1995
Page 3
iiiuanterra
Environmental
Services
Strontium-90 by method ITAS-RD-3204
The LCS, batch blank, sample and sample duplicate (BOGFD3) results are within contractual
requirements.
Liquid Scintillation Counting
Tritium by method ITAS-RD-3205
The LCS, batch blank, sample and sample duplicate (BOGFD3) results are within contractual
requirements.
I certify that this Certificate of Analysis is in compliance with the SOW, both technically and
for completeness, for other than the conditions detailed above. Release of the data contained
in this hard copy data package has been authorized by the Laboratory Manager or a designee,
as verified by the following signature.
Reviewed and approved:
Suzanne Gaines
Project Manager
00003ti
;0'a
to
C'0'0 s

Chain-of-Custody Information
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm
000037

Q
^
O
Wry
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
Data Turnaround
q Priority
Collector
f)L it IT fiz "nu C
Company Contact
Telephone
( 509) 372 9838
n Normal
7, p R. E. Petereon Project Designation
100-HR-3 Groundwater Sampling, Round 9, Phase 2
Ice Chest No.
Sn7l SfO-^
Shipped To
Quanterra
Sampling Location
100 D
Field Logbook No.
rFL- / O
Offsite Property No.
NA
-
SAF No.
B95-068
Method of Shipment
Hand Delivered
Bill of Lading/Air Bill No.
NA
Possible Sample Hazards/Remarks
Preservation
HNO3, Cool4°C HtSO, '1 HisO. HNOe Coo14°C Cao14°C HNO3
Type of Container
No. of Container(s)
G G P/G P PIG PIG G PIG G
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain samples between 2°C and 6°C.
SAMPLE ANALYSIS
50^ ^ o
^/^
061 q /
Volume
SOOmL
ICP
Metals
(Unfiltered)
SOOmL
A°1°M 11C1
• F, a, sq,.
N q. Nq,
P0,
SOOmL
NO,
-
NOo
SOOmL
Sulfide
SOOmL
Ammonia
1 L
Gross
AI
p
ha
Gross eeta, Sr-90 -
SOOmL
Tritium
I
V
20mL
Activity
Scan
SOOmL
ICP
Metals
(Filtered)
Sample No. Matdx' Data Sampled Time Sampled
BOGFD3 W 31/d} 5
BOGFD4 G ' W ^735 ^
CHAIN OF POSSESSION
Relinquished By Dete/Tima
R" ^ Date/Fime
_
/y'J.f
^
Sign/Print Names
R 'txiZ
y/
eceiva By
DetelTime
^ -
Dete/Time
/
SPECIAL INSTRUCTIONS
•i Znqc+NeOH
Sample analysis for phosphe[e, nitrate, and nitrite by EPA 300.0; and turbidity
b y EPA 180 . 1 is being requested for information only. The ERC Contractor
acknowledges that the 48-hour holding time will not be met.
^^•"'"'
s- Soil
sE - semm°nm
so - smu
SL - srWc°
w- w.r.,
o- Oil
x -N,
elinquished B y
/ . 3 '/
DetelTima
-
Received By L I QC'C 10"Dete/Time The Activity Scan is for all samples listed on this chain of custody.
Os-DrunsaN.
^t - a^Liqindt
WI - Wip
Relinquished By Date/Time Received By DalelTime t- v L1p Wd
x - OtMr
LABORATOgY Received By Title DateRime
SECTION
FINAL SAMPLE Disposal Method Disposed By Date(fima
bISPO51TI0N

^
^
B ec htel Hanford , inc .
CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
Data Turnaround
q Priority
Collector
It l^ r 2 t ^
Project Designation
10D-HR-3 Groundwater Sampling, Round 9, Phnee 2
Ice Chest No.
54 3
Shipped To
Quanterre
Company Contact
R. E. Petersen
Semplin0 Location
100 D
Field Logbook No.
t^
ONsite Property No.
NA
O(B"
Telephone
(509) 372-9638
SAF No.
B95-068
Method of Shipment
Hand Delivered
Bill of Ladinp/Air Bill No.
NA
n Normel
Possible Sample HezardelRemerks Preservatlon
HNO^ Cool4°C Hr90. •1 H2SO4 HNO3 Cool4'C Coo14°C HNO^
Type of Container
No. of Conteinet(s)
G G PIG P PIG PIG G PIG G
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain semples between 2°C and 8°C
Volume
500mL
ICP
SOOmL
Anton.llel
sO,.
SOOmL 500mL SOOmL IL SOOmL 20mL 500mL
NOt
SAMPLE ANALYSIS
Metals
(Unfilter-
ad)
fM" NO"
P0,
NO3
Sulfide
Ammonia Gross
Al p ha
Gross
Bete. `
Tritium
Acuvip'
1 n^ Scan
O a LI
ICP
Metals
(Filtered)
^ U^`^f O
Sr-90'J
Sample No. Matrix• Date Sempled Time Sampled
B O GF83 01 W
BOGF84 ^-I W lyS
SPECIALINSTRUCTIONS
M'v1-
CHA(N OF POSSESSIbN Sign/Print Names • 1 Znqc+NaOH s- Soil
-' ^ SE - S.dtmam
RaGnqUishad By Data^ ime R i B ^ DetelTime LS So _ saa
Sample anelysis for phosphate, nitrete, and n i trite by EPA 300.0; and turbidity ^- swc°
J GCC /3a by EPA 180 . 1 is being requested for Information only. The ERC Contractor w - W.i°r
Rel' i d t/^GDataRime Received By
De[e/Time
i000
acknowledges that the 48-hour holding time will not be met. p_ N
/N /C100 Ds - DrnmS°Ik.
'rry l-frl
elinquished By DeteRime Recaived By 11 pot^.,1 Deta ime
Dt _ OTIr. ^lqw.
The Activity Scan is for all samples listed on this chain of custody.
T
mww
L
Relinquished By Date/Time Received By Dete/Time v - U9^ v.cn.eoe
x - orn.r
LABORATORY Received By Title Date/Time
Tt SECTIOK:,-'
FINAL SAMPLE Disposel Method Disposed By Dete/Time
`DI5PO8i71oN

0
0
IP
^
Ct
♦
Bechtel Hanford , Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contect
R. E. Peterson -
Telephone
(509) 372-9638
ProJect Designation
100-HR-3 Groundwater SempRnB, Round 9, Phase 2
Ice Cheat No.
5/1JG Sb3
Sanpllnp oca nn
100 D
Field Logbook No.
^!`Z-' /O<
SAF No.
1395-068
Method of Shipment
Hand Delivered
Shipped To
Quenterre
ON®Ite Property No.
NA
Bill of Lad ing/Air Bill No.
NA
Possible Sample Hatards/Remarks
Special Handling andfor Storepe
Maintain semples between 2oC and 6°C.
Preaervatlon
Type of Container
No. of Conta(nerls)
Volume
Page 1_ of 1
Data Turnaround
q Pdodty
n Normal
HNO, Cool 4 . C Hr50' •i HtSOi HNO, Cool 4 0 C Cool 4 0 C HNO,
G G PIG P PIG PIG G PIG G
1 1 1 3 1 4 3 1 1
SOOmL SOOmL 500mL 500mL 500mL 1 I. SOOmL 20mL 500mL
SAMPLE
5UOLCY 0
NALYSIS
C!^/ ,
CJI d/^-l/l!
ICp
Metels
( Unlllter•
ed)
a"'o^• nG
- F ' a' GO`
^;^ p D Ha^
NOr -
NO,
Sulfide Ammonia Gross
Alpha,
Grose
Be[e,
Sr-90
Tritium
^O I
I^^p
V
Activity
Scan
ICP
Metals
( Hltered)
Semple No. Matdx° Data Sarnpled Time Sampled
BOGFDS Q^ W 9 f-" / Zl-c]
B0GFD6 Qz W l/ ba.
^a;
CHAIN OP POSS€SSlflti Sipn/Print Names
SPECIAL INSTRUCTIONS
Mn"'
• 1 ZnAc+Na OH
e- sai_
fleR Iehed ByDetelrane R rv DateTme
Sample analyela for phoaphate, nitrate, and nitdte by EPA 300.0; and turbidity
Sq- a,qe
a _^^
R' Dete/furw
s
Received y llllL DeteTma
9 y
y EPA 180.1 Is bein8 requeeted for Informat(on only. The ERC Contraetor
acknowledges that the 48-hour holding time will not be met.
o_ ow
A
_ N,
D9 - Dvn Boeb
etinqu shed By Dete/rme Recelved By

^
^
Opt
cr \
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contact Telephone
. Lf?
k
Project Designation
100-HR3 Groundwater Sampling, Round 9, Phase 2
R. E. Petersen
Samplinp ocatlon
100 D
(509) 372-9638
SAF No.
B95-068
Ice Cheet No. Field L ogbotck No. Method of Shipment
.^Y C-S/[ E-FL ' / V I8 Hand Delivered
Shipped To Olfelte Property No. Bill of Ladinp/Air Bill No.
Quanterra NA NA
Possible Sample Hazarde/Remarks
Preservation
Type of Container
No. of Contalner(s)
Page 1 of 1
Data Turnaround
q Pdority
n Normel
HNO3 Cool4°C HiSO, •1 HiSO. HNO3 Cool4°C Coul4 o C HNO3
G G P/G P P!G P/G G P!G G
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain samples between 2°C and 6°C.
Volume
500mL 5OOmL 5OOmL 5OOmL SOOmL 1L 50OmL 20mL 5OOmL
^^,/^y/
^
ICP /`O10"' IICI
SAMPLE ANALYSIS
^L J^ lf jj
%d /l.'
loo
Metals
^' Rlter-
.
No No „
po,
NO2 -
NO ,
Sulfide
Ammonia
Gross
Alpha,
Gros s
B ete9
Sr-9t1
Tritium
+^ C' D
Acevity
Scan
ICP
Metals
(Filtered)
Sample No. Metdz• Date Sampled Time Sempled
BOGFC1 bJ W 6 '/S°'i,f-
BOGFC2 ON W 0/S' 4r ^a^
CHAIN OF POSSESSION SiOn/Print Names
SPECIAL INSTRUCTIONS
i ZnAc+NaOH
"'"^I•'
s - s°n
RelinquiehedBy DatelTime
i
^
Re 8
-
Datefrme
Sample analysis for phosphate nitrate and nitrite by EPA 300.0; and turbidity
Sp^ a^nr
v
- qui it^
/3^5
DataTme
9
eceived By
-/ -
eteRme
, ,
b y EPA 180 . 1 I . bei ng re ques ted for I n forr n atio n onl y. The ERC Contractor
acknowled9ee that the 48-hour holding time will not be met.
K
- yw,
W - w.r«
0 -ou
A -N,
elinquiehed By
Relinquished By
D®teRme
Date/Time
^
Received By
Received By ^
ate/Time
Date/Rima
"ys
The Activity Scan is for all samples listed on this chain of custody .
Ds - b,. aa16
DL
- tq^'
r - txw.
vn-ww
L
v -
tqi1°
vw.Wioe
X -om.r
LABORATORY
SECTION
Received By Title Date/iime
F1NAL:SAMPLE Disposal Method Disposed By DatelTime
bisPOSmoN =-

O
^
^
l^
V\
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
Date Turnaround
Collector
{-^
1
Company Contact
R. E. Peterson
Telephone
(509) 372-9638
^ Pri ority n Normal
ProJect Desipnation
100-HR-3 Groundwater Sampling, Round 9, Phase 2
Sampling Locetion
100 D
SAF No.
895-068
Ice Chest No.
Field Logbook No.
Method of Shipment
5/11&S-02 ^, ^L • ^p/ Hand Delivered
Shipped To ONsite Property No. Bill of Lading/Air Bill No.
Quenterre NA NA
Possible Sampfe Hazerds/Remerks
Preservation
HNO, Cool 4°C HrSO. •1 H2SO1 HNO, Cool 4°C Cool 4"C HNO,
Type of Container
G G PIG P PIG PIG G PIG G
No. of Contefner(e)
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain samples between 2°C and 80C.
Volume
500mL 500mL SOOmL 50omL 500mL 1L 500mL 20mL 500mL
SAMPLE ANALYSIS
•;/' ^
ICP
Metals
(Unfilter-
fixanij10j
F,a,so„
NO
Po,
"Ne"
NO, -
NO
c
Sulfide Ammonia Gross
Alphe,
Gross
Tritium
/y
/llxl J,
Activity
Scen
ICP
M e t e l e
IFlteredl
ed)
5 90 ^
S amp l e N o. Metdx' Dete Sempled Time Sempled .. r.._.^ : . !^
BOGFC3 05 W y' ^GC1 `^ tl'
BOGFC4 D^Q W
CHAlN OF POSSESSION.
Reli' h By Dete/Time R
Sign/Print Names
W ild Dete/fime 1j2s
SPECIAL INSTRUCTIONS
1 ZnAc+NeOH
Sample analysis for phoephate, nitrate, and nitdte by EPA 300.0; and turbidity
um^.•
s - s.a
SE - s•e4n•m
^: y^
fld E Date/Time
RaceivaBy
1
by PA 180.1 h bein0 requested for Infortnetion only. The ERC Contrector
ecknowled0es thet the 48-hour holdinp time will not be met.
w- w.r.,
^: µ
elinquished By
Relinquiehed By
Dete/Time
Date/Time
Received By
Received By
ete/fma
Date/Time
The Activity Scan is for all samples listed on this chain of custody.
os-mumsa+a
DL - 0,ue iqwe.
T - n^
wu - v+w
t- Lkwe
V ^ Vp°t.4on
tiABORATORy _
'` S.ECTION - :
Received By Title Date/Time
x ^ OtM1w
.FINALSAMP.LE' Disposal Method Disposed By Dete/Time
'0I5POSITION

^
^
T
G
^
J
v\
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector Company Contact Telephone
'}, "LV R. E. Patenon (509) 372-9638
Pro eut Designation Semplin0 ocatlon SAF No.
100-HR-3 Groundwater Sampling, Round 9, Pheaa 2 100 D B95-088
Ice C eet No. Field Logbook No. Method of Shipment
Hand Delivered
Shipped To Oftaite Property No. Bill of LadinD/Air Bill No.
Quanterra NA NA
Possible Sample Hazarda/Remarks
Preservation
Type of Container
Pepe 1 of I
Data Turnaround
q Priority
0 Normal
HNO3, Cool4°C HtSO, •1 HtSO, HNO3 CouI4°C Cool4°C HNO3
G G P/G P P/G P/G G P/G G
No. of Container(s)
1 1 1 3 1 4 3 1 1
Special Handling and/or Storage
Maintain samples between 2°C and 8°C-
Volume
SOOmL 500mL 500mL 500mL 500mL 1L 5OOmL 20mL 501mL
^^ ,-.^ 7/
C^'^-r"
ICP
Metals
tmian. llcl
-
NO, Sulfide Ammonia
Gross Tritlum Activity ICP
F. SAMPLE ANALYSIS
5n
^0^, ^/ (Unfilter-
e d )
a' SO°
NO,, No.,
p0,
NO3 Alpha,
Groaa //^
B eta, /^ ,
1
^r^
)
S can Metals
1Filtered )
(^
Sr•9D /-
Sample No, Matdx' Date Sampled Time Sampled
BOGF85 Q^ W V/V^ ^ ?-2
BOGF86 O^J W /yrlff- 112, 1
CHAIN QF POSBES516N Sign/Print Names
SPECIAL INSTRUCTIONS
• 1 ZnAc+NeOH
M.oi•'
s -sai
Reli uiahedBy Datetme R v LG^ DateTme /y/^ ^1'"`
^ Semple enelyeie for phoaphate, nitrete, and nitrite by EPA 300,0; and turbidity yl ytW~
w
C_ DeteTme 9 eceived By eteTma 9zO
by EPA
180,1 Is bainq requeated for Informedon only, The ERC Contrector
o ai rar
acknowledges that the 48-hour holding time will not be met. A_ µ
Ralinquie edBy
Relinquished By
Dete/Time
DataRme
Received By
Received By
atem n ;' ,a,^ . .
//e!f
Dete/fine
The Activity Scan Is for all semplee listed on this chain of custody.
oto^^Lq
T
wd.
^
va - vra
L th^
v - vaw.u°o
X -om.
LABORATORY^ Received By Title Date/Time
:^:SECTJON `;'
F1NAlSAMPLE' Diaposal Method Disposed By DateRime
`D15PC&171QN;'

^
^
O
!^f
?
^
tn
I
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collectur Company Contact Telephone
^/ 2 w R. E. Petenon (509) 372-9838
Project Designation Sampling Location SAF No.
100-HR-3 Groundwater Sampling, Rourd 9, Phase 2 100 D 885-088
Ice Cheet No. Field Logbook No. Method of Shipment
&C{ -/O y Hard Delivered
Shipped To Offeite Property No. Bill of Lading/Air Bill No.
Quanterre NA NA
Possible Sample Hazards/Ramarke
Preeervetion
Type of Container
Pa9e 1 of 1
Data Turnaround
q Pdodty
^ Normal
HNO, Cool4°C HzSO, '1 HiSO. HNO, Cool4°C Cool4°C HNO,
G G PIG P PIG PIG G PIG G
No. of Conteiner(e)
1 1 1 3 1 4 3 1 1
Special Handling andlor Storage
Maintain aemplea between 2°C and 8°C.
Volume
SOOmL SOOmL 500mL SOOmL 500mL IL 500mL 20mL 500mL
SAMPLE ANALYSIS
^`
` ( L11 /
ICP
Metele
(Un8lterad)
p ^1:
F
NO N , NO .,
P0,
NOt-
NO,
Sulfide
Ammonla
Groee
Alpha
Gross
S ft^ e o ( h
Tritium
/ Q 2
Qr1(- ^
J /
Activity
Scen
ICP
Metals
( Filtered)
5a
^^5i
Sample No. Metdx' Deta Semplad Time Sampled
BOGFB9 03 w &/(S`'el9S 0 S' " X
BOGFCO O7 W J ^fS /Ur^
CHAtN OF POSSESSION Si9n/Print Names
SPECIAL INSTRUCTIONS
' 1 ZnAc+NeOH
M•u^••
s -sai
fta'n ished By
R' - e
-
elinquie nd By
rye.^ Oete/Time
g^^YlFf ^^C°
DetaTme
^^0
i-r
DatelTme
iv
-
fle eived By
Received By
W
u
Q
OateRime
Sempla analyaie for phoephate, ni[rate, and nitrite by EPA 300.0; and turbidity
b y EPA 180.1 i s beinp reQueetad for infortnetion only. The ERC Contractor
lTme
92G ecknowledeae that the 48-hour holdin8 time will not be met.
atetr^^^^
The Activity Scan is for all samples listed on this chain of custody.
so s°ua
^-S^
w- w•r•r
^_^
os- D^sau.
DL - DruntWWe•
T - Tbaw
WI - NAp•
Relinquiehed By Date/Tme Received By DatelTime L
V
Us°°
- v°on•u,e
LABORATORY Received By Title Date/Time
^^ECTION
FlNAL SAN^PLF.;^ Dispocel Method Disposed By DetelTime
,Ai.SPOl;kTlilN:^"

Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Page 1 of 1
Data Turnaround
Collector
^L
12/2 2 o
Company Contact
R. E. Peteraon
Telephone
(509) 372-9839
q Priority
n N ortna l
Project Designation
100-HR-3 Groundwater Sampling, Round 9, Phaee 2
Ice C h est No.
m L-
s/6
Shipped To
Quanterra
Sampling Location
100 0
Field Logbook No.
Offsite Property No.
NA
'e 1c;G - /0 /J1 SAF No.
895-088
Method of Shipment
Hand Delivered
Bill of Lading/Air Bill No.
NA
Possible Sample Hazards/Remerka
Preservation
HNO, Cool 4°C HrSO, •1 Hr50, HNO3 Cool 4°C Cool 4°C HNO,
Type of Container
G G P/G P P/G P/G G P/G G
. .
Special Handling and/or Storage
Maintain samples between 2°C and 8°C.
No. of Containar(s)
Volume
1
506mL
1
500mL
1
500mL
3
500mL
1
500mL
4
iL
3
SOOmL
1
20mL
1
500mL
SAMPLE ANALYSIS
50825^
7^
J,\r( l _ /] I
^l/(lU 1
ICP
Mete4s
(Unfilterad)
Aninm OCI
^ N0^"
P0,
NO z-
No,
Sulfide Ammonia
Gross
Alpha,
G ross
Beta,
Sr_9D
Tritium R Ac6vity
/)/]J Scan
ICP
Metals
(Filtered)
Sample No. Matrix• Date Sempled Time Sempled _: : . , ,....: ..U,:. , .. ;., .m.:.;. . ; . ,..
BOGF99 05 W
BOGFBO 06 W ^^h•-^5s• ^ jr-
CHAIN OF POSSES511)N
Raliiahad By DateTme R
SiOn/Print Names
d y ^ Data/Time /y/U
SPECIAL INSTRUCTIONS
•1 ZnAc+NaOH
mnri.•
s - sal
sE - sairvr.M
0
0
R' u' e 6e2 Date/Time eceivad By
12 ,
Qj^
- ,
ta/Time
^
Sample anelyeis for phoephate, nitrete, and nitrite by EPA 300 . 0; and turbidity
by EPA 180.1 is belnp requeated for information only. The ERC Contractor
ecknowledges that the 48-huur holdin0 time will not be met.
SO:^^
wo _ w.wr
A
CA /
CZ)
_ elinquished By Data/Time Received By Date/Time
Th e Aetivty Scan is for all aemplee listed on this chain of custody.
Nr
Os - D. sawe
T - T^wO°"u•
t
Relinquished By Deta/Time Received By Dete/Time t. - tkw
LABORATORY .-
SECTION ;..
Received By Title Date/Time
V
X
- Vyneacn
- om«
J
1
^
FlNAL SAMPLE,; Disposal Method Disposed By Date/Time
DISPC&t'flQN:'::

0
^
lip,
Q I
<
J 1
V\
Bechtel Hanford, Inc. CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST
Collector
Company Contact
Telephone
^7 L ^ / 2 'Z--O
R. E. Peterson (509) 372-9838
ProJeot Designation Sampling Location SAF No.
100-HR-3 Groundwater Sampling, Round 9, Phase 2 100 D B95-088
ice Chest No. Field Logbook No. Method of Shipment
Hand Delivered
Shipped To Offeite Property No. B711 of Lading/Air Bill No.
Quanterra NA NA
Possible Sample Hezarda/Remarks
Preeervetion
Type of Contelner
No. of Conteiner(e)
PeOe 1 of 1
Data Turnaround
q Pdorlty
n Normal
HNO, Cool4°C H2SO. •1 HrS04 HNO, Cool4°C Cool4°C HNO,
G G P/G P P/G P/G G P/G G
1 1 1 3 1 4 3 1 1
Special Handling end/or Storage
Maintain samples between 2°C and 8°C.
Volume
SOOmL 50OmmL 50omL 500mL 50omL 1 L 500mL 2OmL 500mL
SAMPLE ANALYSIS
1
5'^/
/ `, ICP
Metele
^'filter-
Am°nrllCl
F a ' 80"
NO,. NO.,
p0,
NOr-
NOe
Sulfide Ammonia Gross
Alpha,
G
B ete $
Tq"¢ ^
a#Y^ IpIJ' G,
Activity
S can
ICP
M eta l s
(Flteredl
W u/
Sr-90 -
Sample No. Matrix• Date Sampled Time Sampled
BOGF81 W
BOGF82 W
CIIAIN GF POSSE$SION
7 e ..
Sipn/Print Names
SPECIAL INSTRUCTIONS
' 1 ZnAc+NaOH
mmix•
s
Relinuiehed By
R'
elinquiahed By -
Dete/Time
Data/Time
Date/Time
9
Re
ac 'ved B
eceived By
qp{
Date/Time
te!lime y'^
Dete/Time
^ite
Sample enalysie for phocphate, nitrete, and nitrite by EPA 300.0; and turbidity
by EPA 180 . 1 I s b e i nq requeste d for i n format i on on l y. Th e ERC C ontrector
aeknowlad®ea that the 48-hour holdinp time will not be met.
he Activity Scan is for all samples listed on this chain of custody.
SE:
Ud,
W
o o
A- All
Ds - D. saa.
DL - D. U°JG,
T_ Tu.w
M-Ww
Relinquished By Date/Time Received By DeteTme L' Lb"a
V - V.o.uaa,
x -om,.
LABO.HATORY!
::.. SEGTION
Received By Title Date/Time
F1NAL.SAMPtE Disposal Method Disposed By Date/Time
-'Df$PQClT10Ni'.`

Client Sample Screening Results
ISAug-9S
CLIENTCODEDI MATRIX RECEIVED DETECTOR ACQ DATE SAMPLE MINUTES CNTSA NETCPMA CNTSB NETCPMB
W$C BOOFEI E/15959:20:00AM QUAD2IA 8/15/95138:33PM BOGF81 30 37 1.19208333 132 330125
LIQUID Bkg: 8/15/95 5:26:44 AM BKG 800 33 0.04125 879 1.09875
AalDatt: t/1591 TotSo,Atq: I.OOE+00 , I.OOE+01 Alp; (Dpm/3.53E+00 (uCV 1.59F1I4 (pCy 1.59E-r02 ±3.2E+01 CAT 1.6E-01 Lab
tptmq: 2.7 ^ Udb: L ml Bet; Alq): 6.01E+00 Sn): 2.71E.04 L)C): 2.71E+02 ±3.3E+01 1 ^ 1.8E-01
WHC B00F85 8/15959:20:00AM QUAD2IB 8/15/95 1:38:33 PM BOGF83 30 13 0.39333333 102 2.52873
UQUID B4C: 8/15/95 5:26:44 AM BKG 800 32 0.04 697 0.87125
AdDMr. 8/1595 TotSs,Alq: L00E+00 1.00E+01 Alp; (DpM 1.24E+00 (uCV 5.60E-05 (pCU 5.60E+01 ±2.6E+01 CAT 4.5E-0I Ld
Pptoq: 6.4 3 Unfb: L , ml Bet; Alq): 4.72E+00 So): 2.13E-04 LIC): 2.13E+02 ±2.9E+01
111
2.4E-01
A4
114
WIiC B00F99 8/15959:20:00AM QUAD2IC 8/15/951:38:33PM 600F99 30 52 1.67833333 152 4.0141667
LIQUID Bkg: 8/15/95 5:26:44 AM BKG 800 44 0.055 842 1.0525
AnIDNe: 8/1595 TutS,A)I: 1.00E+00,/ 1.00E+01 Alp; (DpM 4.86E+00 (uCU 2.19E-04 (pCV 2.19E+02 ±3.4E+01 CAT I.IE-01 Lab
Pptuq: 1.6 3 UuBa: L , ml Bet; Alq): 6.93E+00 So): 3.12E-04 L4C): 3.12E+02 ±3.5E+01 I-^ 1.6E-01
WHC B00F89 8/15959:20:00AM QUAD2ID 8/15/95 1:38:33 PM BOGFB9 30 29 0.91416667 81 1.72375
LIQUID Bkg: 8/15i95 5:26:44 AM BKG 800 42 0.0525 781 0.97625
^ Aa1DMe: 8/1595 TutSyAlq: 1.00E+00 , 1.00E+01 Alp; (DpM 2.79E+00 (uCl/ 1.26E-04 (pCV 1.26E+02 ±2.9E+01 CAT 3 2.0E-0I
O Pptnq: I / Unlh: L m1 Bet; Aiq): 2.86E+00 So): 1.29E-04 L^C): 1.29E+02 ±2.5E+0I I 3.9E-01
1!^
1
^I SAug-95
N\
.
I

0
O OO
ient Sample Screening Results
16-Aug-95
5og^c^^ ^^
CI.IENT(.'ODE ID MATRIX RECEIVED DETEGTOR ACQ DATE SAMPLE MINUTES CNTSA NETCPMA CNTSB NETCPMi
BB1 BOOPC3
05406
ylk 16-Aag-9S
BHI BOGFCI e02) d16959:45:00 AM QUAD2IA 8/161952:54:33PM BOGFCI 30 9 0.25625 55 0.7845833
603 1 Qy uQUH) Blq: 8/16/95 5:40:40 AM BKG 800 35 0.04375 839 1.04875
Ad Dstc: 8/16NS Tot BNAIB; i.00E3 00 ,).00Er01 Alp; (Dpm/ 7.47E-0I (uCV 3.36E-05 (PQ! 336E+01 ± 2.4E+01 CAT 7AE-01
Pri oL: 2 Uwb: L / , ml Bep Alq): 1.44E+00 Sa): 6.48E-05 148): 6.48E+01 ±2.2E+01 I J 7.7E-01
lo 5 8/16195 9:4500 AM QUAD21B 8/16/95 2:54:33 PM BOGFC3 30 6 0.16125 42 0.5025
LIQUID 8IcB: 8/161955:40:40AM BKG 800 31 0.03873 718 0.8975
AYDafe: 8/16195 T9t8yA1q: 1.00&M0 , LOOE+01 Alp; (Dptrol 5.00E-01 (uCi/ 2.25E-05 (PGV 2.25E+01 ±2.2Ea01 CAT I.lEM0 Lab
PPtow. 2
/ 11
Udb: L m1 Bet; Alq): 8.78E-01 Sa): 3.95E.05 L48): 3.95E+01 ±1.9E•101 I ^I.3E+00
All
L49
BIB BOGFD5 (D/ 8/161959:45:00AM QUAD21C 8/161952:54:33PM BOGFD5 30 0 -0.03875 29 -0.110833
0 14 D 2 LIQUm B4: 8/16P95 5:40:40 AM BKG 800 31 0.03875 862 1.0775
Aa1Drte: 8/16/93 TuISk AIq: I.OOEi00 , I.OOEi01 Alp; (Dpua/ -1.09E-01 (uCl/ -4.90E-06 (P(.U 4.90Et00 ±2.0E+01 CAT 1.0E+00
PPIaK: 0 Udh: L" , ml Bet; A1q): -1.95E-0I 8o): -8.78E-06 uU: -8.78E+00 ± 1.8E+01 1 IAE+00
I
A1q
ut
AIq
uc

14-
^o ULef/L^
^Ao
(56 g 201 PuLd )
^j lqk5
CLIENT CODE ID MATRIX RECEIVED DLrrELrOR ACQ DATE SAMPLE MINUTES CNTSA NETCPMA CNTSB NETCPMB
WHC BOGB76 8/14/951:10:00PM QUAD24A. &114/953:17:54PM BOGB76 30 29 0.90766667 81 1.729
LIQUID BkC: V12195 7:35:40 AM BKO IGOO 59 0.059 971 0.971
ArdD&tr. 9114195 TatSxAlg: LOOE+00 , I.OOE+01 Alp; (Dptd 2.91E+00 (uCY 1.31E-04 q" 1.31E+02 + 3.IE+01 CAT 1.9E-01 Lab
Pptmg: 3.8 Utdts: L ' / , nil Bet, Alaj: 2.97E+00 Sa): 1.29F,04 14g): 1.29E+02 ±2.5E+01
1 11
3.9E-01
AIq
Lit
WHC BOGB86 8/14/95 1:10:00 PM QUAD24B 8/14/95 3:17:54 PM BOGB86 30 14 0.42666667 76 1.5493333
LIQUID Bkg: 9/12195 7:35:40 AM BKO 1000 40 0.04 984 0.984
AnlDste: 9114195 TotSnAJq: I.OOE+00 I.OOE+01 Alp; (Dprd 1.30E+00 (uCl/ 5.86E-05 (pCV 5.86E+01 ±2.5E+01 CAT 4.313-01 Lab
I
Atq
Pptmg: 4.2
v
Urdts: L Bet; Alq): 2.78E+00 Sa): 1.25E-04 LIZ): 1.25E+02 + 2.SE+01
1^ 4.OE-01
1,19
WHC MOB98 8114195 1:10:00 PM QUAD24C 8/14/95 3:17:54 PNI BOOB98 30 17 0,51666667 89 1.9776667
LIQUID Bkg: 8112/95 7:35:40 AM BKG 1000 50 0.05 989 0.989
An] Date: 8/14195 Tot SmA19; I.O-OE+00 I.OOE+01 Alp; (Dprid 1.54E+00 (uCY 6.91&05 (pCV 6.91E+01 ±2.5E+01 CAT 3.6E-01 LAb
I
Alq
Pptmg: 3.3 Units: L nil Bet; Alq): 3A5E+00 Sa): 1.55E-04 LIX): 1.55E+02 ± 2.6E+01 / 3.2E-01
14g
WHC BOGF93 8/14195 10:00:00 AM QUAD24D 8/14/95 3:17:54 PM BOGF83 30 13 0.39533333 51 0.639
65 4- oq LIQUID Bkg: 9/121937;35:4OAht BKG 1000 38 0.038 1061 1.061
ArdDate: 8114195 TotS&,Alq: LOOE+00 LOOE+01 Alp; (Dpnd 1.19E+00 (uCV 5.37E-05 (pCif 5.37E+01 ±2.5E+01 CAT 4.7E-01 Lab
I AJq
Ppt mg: 4.3
ll^
Uwt3: L nil Bet; Alq): 1.04E+00 Sa): 4.68FA3 Llg): 4.68E+01 ± 2.OE+O I / I.IE+00
'At
WIIC BOGFD3 8/14195i0:00:00AM QUAD21B 8/14/95 3:51:13 Phi BOGFD3 30 1 -0.0016667 30 0-149
ol ^oz
LIQUID Bkg: 8/12195 7:35:44 AM BKG 1000 35 0.035 851 0-951
AnI Date:
Ppt mg:
8/14/95
0 -
Tc4S&,Alq;
Urdts:
I.OOE+00
/I
L
I.OOE+01
ml
Alp;
Bet;
(DprrL(
Alq):
.9.87E-03
2.89E-01
(uCU
Sm):
4.45E-07
L30E-05
(pCll
Ljg):
4.45E-01
1.30E+01
+ 1.913+01
± 1.6E+01
CAT
I ^
I.OE+00
3.8EiOO
Lab
Alq
14C
WHC TEDF081495001 8/1419512:10:OOPM QUAD21C 8114/95 3:51:13 Phi TEDF081495001 30 2 0.02866667 57 0.844
LIQUID Bkg; 8/12195 7:33:44 Ahl BKG 1000 38 0.039 1056 1.056
AnI Date: 8/14/95 TotSaAlq: 1.00E+00,,^ I.OOE+01 Alp; (Dpnif 6.41E-02 (uCY 2.89E-06 (pCV 2.89E+00 + 2.2E+01 CAT^ 8.7E+GO Lab
I Alq
Ppt ing: 5.9 Units; L H Be4 Alq): 1.66E+00 Sa): 7.46E-05 Lig); 7.46E+01 ± 2.3E+ol 6.7E-0 I
Ljg
14-Aug-95
3

Supplemental Information
40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm
000050

WF 23
Z0001
LATA INORGANIC (METALS)
DATA VALIDATION CHECKLIST
i
To: Jeanette Duncan, WHGBHI Date: 10/23/95
PROJECT NAME: i00-NR3 ROUND 9 PHASE It
SDG NUMBER: W0871-QES
LATA NO.: V8404.08
LABORATORY: QES
CASE NUMBER: N!A
ANALYSIS METHOD:
ANALYSIS DATE:
ITEM (S) MISSING:
i _.
Comments: It appears from the raw data that sampies BOGFDS and
B0GFD8 are field blanks. Th'ese samples are not listed on the Sample Summary Table
as field 61anKs.
Attention: B MORRIS
RETURN TO LATA
INFORMATION RECEIVED FROM WHC (fNITIALSlDATE): L0W 16-^3'q5
INFORMATION ACCEPTABLE?- YES n NO 0
NO is checked, send a new LIRF to request additional Infoimatlon.
40d08MTLJCLS, LIRF-1
10l23/95. 9:17 AM
S'IHS6C TiSVH 0HAt 90TZ ZLC 602$
000051
00:6i
36/CZ/OT

^ 0130s6
Environmental
Restoration ERC Team
Job No. =^
Contractor CM WA
O h WDIQ-)
Interoffice Memorandum ^ w^
aho.^ =
W. S. Thompson N3-06 DAm July 26, 1995
R. L.
Biggerstaff H4-91 ^o^' S. K. De Mers^/
Radiological Controls
T7-05/373-1913
somacn 1995 Phase 2, Round 9 sampling for 100-HR-3
^
There is no need to perform total activities prior to offsite shipment to NRC licensed labs of
samples taken from the attached list of wells.
All wells listed in the attachment were reviewed for radiological content based on the previous 4
years of sampling data. No well listed has a0 activity in excess of 100,000 pCi/1 (

40406RAD.NAR; Printed: 17-Oct-95, 12:56 pm
END OF PACKAGE
000053