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Lattice Dynamics (LD)<br />

1. The Debye temperature of diamond is 2000 K, its density is 3500 kgm -3<br />

and the interatomic spacing is 0.15 nm. Calculate the velocity of sound<br />

in diamond. Make an estimate of the dominant phonon wavelength at<br />

300 K and the frequency of lattice vibration to which this corresponds.<br />

The Free Electron Model (FEM)<br />

1. Calculate the Fermi energy EF for Na, Li and Al with the help of suitable<br />

information from a handbook. The normal valences can be assumed.<br />

2. In a measurement of the resistance of a copper wire, the voltage was<br />

measured to be 1.7 mV when the current was 0.5 A. The wire has a cross<br />

sectional area of 1 mm 2 and is 20 cm long (between the voltage contacts).<br />

Determine the average mean free path for a conduction electron if one<br />

takes a valence of one for copper.<br />

3. Determine the order of magnitude of the electric field strength that is<br />

required to bring about a field induced "shift" Δk of the Fermi surface for<br />

copper, that is equivalent to 1% of the wavevector kF.<br />

Use the free electron model with a valence of one and the relaxation time<br />

for copper at room temperature. What value of the current density is valid<br />

for the field estimated?<br />

4. Let the electrical conductivity be given by σ = ne 2 τ/m. What temperature -<br />

coefficient should we expect to find for the resistivity of copper in the<br />

interval 0 to 100 ˚C if the relaxation time is assumed to be independent of<br />

temperature? Discuss the result in comparison with the experimental value<br />

for the temperature coefficient.<br />

2

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