Recommended Liquid–Liquid Equilibrium Data. Part 4. 1-Alkanol ...
Recommended Liquid–Liquid Equilibrium Data. Part 4. 1-Alkanol ...
Recommended Liquid–Liquid Equilibrium Data. Part 4. 1-Alkanol ...
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higher. The solubility of water in 1-alkanols can be calculated<br />
with EoSC in conjunction with Eq. 11. Empirical constants<br />
used in the calculations were obtained from regression<br />
of all available solubility data, which assures the good accuracy<br />
of the constants determination. Once these constants are<br />
established, no experimental solubility data are necessary for<br />
the calculation of the mutual solubility. The calculated solubility<br />
was treated as reference values for selecting the recommended<br />
data. This approach allows us to have confidence<br />
in the internal consistency and good quality of the recommended<br />
data.<br />
5. Description of Tables Containing<br />
the <strong>Recommended</strong> <strong>Data</strong><br />
Each system is presented in separate table, which includes<br />
LLE data along the three phase equilibrium line and optionally<br />
the corresponding figures.<br />
The tables contain data, which deviate from the calculated<br />
solubility by less than 10% or 20%. If more data at the same<br />
LIQUID–LIQUID EQUILBRIUM. 4 1397<br />
temperature fulfills the assumed limit, then only one selected<br />
experimental point was chosen and placed in the table. The<br />
selection was done taking into account the agreement with<br />
the recommended data at other temperatures and the agreement<br />
with the calculated reference solubility. The tables<br />
contain experimental mole fractions of the solute and the<br />
corresponding calculated values. Symbol x 1 denotes mole<br />
fraction of 1-alkanol in water-rich phase, x 2 denotes mole<br />
fraction of water in the 1-alkanol-rich phase. Values denoted<br />
by x 1,calc were calculated with Eq. 11 or 18. The data<br />
necessary for using these equations are given in Table 1.<br />
Values of x 2,calc were calculated with Eq. 27 or 28. Coefficients<br />
of these equations are given in Table 2. These coefficients<br />
were found in the following way: 1 LLE calculations<br />
were performed with EOSC using solubility of<br />
1-alkanols predicted with Eq. 11 or 18 and 2 the calculated<br />
solubility of water was approximated with Eq. 27 or<br />
28. See Tables 3–21.<br />
J. Phys. Chem. Ref. <strong>Data</strong>, Vol. 35, No. 3, 2006