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Evaluation of Plastic Waste Management in Thailand Using Material ...

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Figure 2.24 Coke oven chemical feedstock recycl<strong>in</strong>g (<strong>Plastic</strong> Technology Center, 2008)<br />

2.3.2.4 Blast furnace feedstock recycl<strong>in</strong>g: <strong>Plastic</strong>s used as a reduc<strong>in</strong>g agent<br />

The process by which plastics are used as a reduc<strong>in</strong>g agent is as follows. <strong>Plastic</strong> waste<br />

collected from factories and homes is cleansed <strong>of</strong> non-combustible matter and other<br />

impurities such as metals, then f<strong>in</strong>ely pulverized and packed to reduce its volume. <strong>Plastic</strong>s<br />

that do not conta<strong>in</strong> PVC are granulated, and then fed <strong>in</strong>to the blast furnace with coke.<br />

<strong>Plastic</strong>s that do conta<strong>in</strong> PVC are fed <strong>in</strong>to the blast furnace after first separat<strong>in</strong>g the<br />

hydrogen chloride at a high temperature <strong>of</strong> around 350 ºC <strong>in</strong> the absence <strong>of</strong> oxygen, as the<br />

emission <strong>of</strong> hydrogen chloride can damage a furnace. The hydrogen chloride thus extracted<br />

is recovered as hydrochloric acid and put to other uses, such as acid scrubb<strong>in</strong>g l<strong>in</strong>es for hot<br />

roll<strong>in</strong>g at steel mills.<br />

2.3.3 <strong>Material</strong> Recycl<strong>in</strong>g<br />

There are many treatments and processes for plastic waste recycl<strong>in</strong>g such as wash<strong>in</strong>g to<br />

remove dirt and contam<strong>in</strong>ants, gr<strong>in</strong>d<strong>in</strong>g and crush<strong>in</strong>g to reduce the plastic particle size,<br />

extrusion by heat and reprocess<strong>in</strong>g <strong>in</strong>to new plastic goods.<br />

Mechanical recycl<strong>in</strong>g is limited by the non-compatibility between the different types <strong>of</strong><br />

polymers <strong>in</strong> the mix. A higher quality <strong>of</strong> recycled plastics is achieved when there is the<br />

separation <strong>of</strong> recycled res<strong>in</strong>s prior to the remold<strong>in</strong>g process. Moreover, the color <strong>of</strong><br />

recycled res<strong>in</strong>s is also the one important issue <strong>of</strong> material recycl<strong>in</strong>g, especially grey color<br />

<strong>of</strong> recycled res<strong>in</strong>s which is an undesirable color. Recycled plastics cannot be used <strong>in</strong> food<br />

conta<strong>in</strong>ers, unless direct content with the food can be avoided. The recycled products are<br />

usually produced by two plastic res<strong>in</strong>s such as recycled res<strong>in</strong> and virg<strong>in</strong> res<strong>in</strong>, and the<br />

proportion <strong>of</strong> both res<strong>in</strong>s is based on the demand <strong>of</strong> market. Some material recycl<strong>in</strong>g are<br />

described as below:<br />

22

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