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TECHNOLOGY, ENERGY EFFICIENCY AND<br />

ENVIRONMENTAL EXTERNALITIES IN THE PULP<br />

AND PAPER INDUSTRY<br />

RAW MATERIAL<br />

PREPARATION<br />

PULPING<br />

Χ Chemical Pulping<br />

Alkaline<br />

- Kraft or sulfate √<br />

- Soda pulping<br />

Acidic or sulfite<br />

Χ Mechanical<br />

- GWP - RMP<br />

- TMP - CTMP<br />

Χ Semi-chemical Pulping<br />

- Neutral sulfite<br />

BLEACHING<br />

PAPER MAKING<br />

220-300 kWh/t<br />

400-520 kWh/t<br />

Electricity<br />

Steam<br />

(180°C,<br />

12-13 GJ/t)<br />

Electricity<br />

Steam<br />

(5 GJ/t)<br />

Electricity<br />

Electricity<br />

Steam<br />

(5-6 GJ/t)<br />

Steam<br />

(8 GJ/t)<br />

Electricity<br />

Pulp & Paper Industry<br />

Energy Flow<br />

Effluents & Emissions<br />

Raw Materials<br />

(Conventional: Wood<br />

O<strong>th</strong>ers: Grass,<br />

Bagasse, Straw etc.)<br />

Chipper<br />

Debarked Wood / Woodchips<br />

Pulp Digester<br />

Crude Pulp<br />

Screening &<br />

Washing<br />

Fine Purified Pulp<br />

Thickening<br />

Unble<strong>ac</strong>hed Pulp<br />

Ble<strong>ac</strong>hing<br />

Ble<strong>ac</strong>hed pulp<br />

Stock<br />

Preparation<br />

Paper M<strong>ac</strong>hine<br />

Drying &<br />

Finishing<br />

Finished Paper<br />

Products<br />

Waste paper<br />

(secondary<br />

intake)<br />

Refining<br />

Raw Materials<br />

(Conventional: Wood<br />

O<strong>th</strong>ers: Grass,<br />

Bagasse, Straw etc.)<br />

Chipper<br />

Debarked Wood / Woodchips<br />

Pulp Digester<br />

Crude Pulp<br />

Screening &<br />

Washing<br />

Thickening<br />

Unble<strong>ac</strong>hed Pulp<br />

Ble<strong>ac</strong>hing Plant<br />

Ble<strong>ac</strong>hed pulp<br />

Stock<br />

Preparation<br />

Paper M<strong>ac</strong>hine<br />

Drying &<br />

Finishing<br />

Finished Paper<br />

Products<br />

School <strong>of</strong> Environment, R<br />

<strong>Asian</strong> Institut<br />

Bangkok<br />

Weak bl<strong>ac</strong>k liquor<br />

Sedimentation &<br />

Aerobic<br />

treatment<br />

Evaporator<br />

to pulp digester<br />

Fine Purified Pulp<br />

Chemical reuse<br />

Chemical<br />

recovery boiler<br />

Sludge,<br />

Ble<strong>ac</strong>h water<br />

Waste paper<br />

(secondary<br />

intake)<br />

Refining<br />

Heat emission<br />

White water,<br />

Fiber, Fillers,<br />

Broke, etc.<br />

Liquid clean-up,<br />

Broke, Coatings<br />

etc.<br />

to Treatment plants<br />

Evaporative emission<br />

Strong bl<strong>ac</strong>k liquor<br />

toCombustion<br />

School <strong>of</strong> Environment, Resources and Development<br />

<strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong><br />

Bangkok - Thailand<br />

ASIAN INSTITUTE<br />

OF TEC HN OLOGY<br />

19 5 9<br />

Condensat<br />

Gaseseous e<br />

emission<br />

Effluent<br />

Fiber & ink<br />

sludge<br />

to<br />

Anaerobic<br />

treatment


TECHNOLOGY, ENERGY EFFICIENCY AND<br />

ENVIRONMENTAL EXTERNALITIES IN THE PULP<br />

AND PAPER INDUSTRY<br />

RAW MATERIAL<br />

PREPARATION<br />

PULPING<br />

Χ Chemical Pulping<br />

Alkaline<br />

- Kraft or sulfate √<br />

- Soda pulping<br />

Acidic or sulfite<br />

Χ Mechanical<br />

- GWP - RMP<br />

- TMP - CTMP<br />

Χ Semi-chemical Pulping<br />

- Neutral sulfite<br />

BLEACHING<br />

PAPER M AKING<br />

220-300 kWh/t<br />

400-520 kWh/t<br />

Electricity<br />

Steam<br />

(180°C,<br />

12-13 GJ/t)<br />

Electricity<br />

Steam<br />

(5 GJ/t)<br />

Electricity<br />

Electricity<br />

Steam<br />

(5-6 GJ/t)<br />

Steam<br />

(8 GJ/t)<br />

Electricity<br />

Pulp & Paper Industry<br />

Energy Flow<br />

Effluents & Emissions<br />

Raw Materials<br />

(Conventional: Wood<br />

O<strong>th</strong>ers: Grass, Bagasse,<br />

Straw etc.)<br />

Chipper<br />

Debarked Wood / Woodchips<br />

Pulp Digester<br />

Crude Pulp<br />

Screening &<br />

Washing<br />

Fine Purified Pulp<br />

Thickening<br />

Unble<strong>ac</strong>hed Pulp<br />

Ble<strong>ac</strong>hing<br />

Ble<strong>ac</strong>hed pulp<br />

Stock<br />

Preparation<br />

Paper M<strong>ac</strong>hine<br />

Drying &<br />

Finishing<br />

Finished Paper<br />

Products<br />

Waste paper<br />

(secondary intake)<br />

Refining<br />

to pulp digester<br />

Brahmanand Mohanty<br />

Raw Materials<br />

(Conventional: Wood<br />

O<strong>th</strong>ers: Grass, Bagasse,<br />

Straw etc.)<br />

Debarked Wood / Woodchips<br />

School <strong>of</strong> Environment, Resources and Development<br />

<strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong><br />

Bangkok - Thailand<br />

Chipper<br />

Pulp Digester<br />

Crude Pulp<br />

Screening &<br />

Washing<br />

Thickening<br />

Unble<strong>ac</strong>hed Pulp<br />

Ble<strong>ac</strong>hing Plant<br />

Ble<strong>ac</strong>hed pulp<br />

Stock<br />

Preparation<br />

Paper M<strong>ac</strong>hine<br />

Drying &<br />

Finishing<br />

Finished Paper<br />

Products<br />

Weak bl<strong>ac</strong>k liquor<br />

Evaporator<br />

Fine Purified Pulp<br />

Chemical reuse<br />

Chemical<br />

recovery boiler<br />

Sedimentation &<br />

Aerobic treatment<br />

Sludge,<br />

Ble<strong>ac</strong>h water<br />

Waste paper<br />

(secondary intake)<br />

Refining<br />

Heat emission<br />

White water,<br />

Fiber, Fillers,<br />

Broke, etc.<br />

Liquid clean-up,<br />

Broke, Coatings etc.<br />

to Treatment plants<br />

Evaporative emission<br />

Strong bl<strong>ac</strong>k liquor<br />

to Combustion<br />

Condensate<br />

Gaseseous emission<br />

Effluent<br />

Fiber & ink<br />

sludge<br />

to Anaerobic<br />

treatment


<strong>Technology</strong>, Energy Efficiency and Environmental Externalities<br />

in <strong>th</strong>e Pulp and Paper Industry<br />

© <strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong>, 1997<br />

Edited by Brahmanand Mohanty<br />

Published by School <strong>of</strong> Environment, Resources and Development<br />

<strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong><br />

P.O. Box 4, Pa<strong>th</strong>um<strong>th</strong>ani 12120<br />

Thailand<br />

e-mail: visu@<strong>ait</strong>.<strong>ac</strong>.<strong>th</strong><br />

NOTICE<br />

Nei<strong>th</strong>er <strong>th</strong>e Swedish International Development Cooperation Agency (Sida) nor <strong>th</strong>e <strong>Asian</strong><br />

<strong>Institute</strong> <strong>of</strong> <strong>Technology</strong> (AIT) makes any warranty, expressed or implied, or assume any<br />

legal liability for <strong>th</strong>e <strong>ac</strong>cur<strong>ac</strong>y, completeness, or usefulness <strong>of</strong> any information, appratus,<br />

product, or represents <strong>th</strong>at its use would not infringe privately owned rights. Reference<br />

herein to any trademark, or manuf<strong>ac</strong>turer, or o<strong>th</strong>erwise does not constitute or imply its<br />

endorsement, recommendation, or favoring by Sida or AIT.<br />

ISBN 974 - 8256 - 72 - 3<br />

Printed in India by All India Press, Pondicherry.


FOREWORD<br />

The use <strong>of</strong> fossil fuels leads to <strong>th</strong>e emission <strong>of</strong> so-called "Green House Gases (GHG)", a<br />

concept which comprises carbon dioxide, nitrous oxides, sulfur oxides, etc. In recent years,<br />

a good deal <strong>of</strong> research has provided enough material to put forward <strong>th</strong>e claim <strong>th</strong>at a big<br />

increase in <strong>th</strong>e concentration <strong>of</strong> carbon dioxide in <strong>th</strong>e atmosphere would lead to a rise in<br />

<strong>th</strong>e average global temperature, wi<strong>th</strong> negative consequences for <strong>th</strong>e global climate. This<br />

claim has been confirmed by <strong>th</strong>e United Nations Intergovernmental Panel on Climate<br />

Change (IPCC) in its second scientific assessment published in 1996.<br />

Global warming can have catastrophic imp<strong>ac</strong>t on human and global security: island nations<br />

and low lying coastal regions would be permanently drowned by <strong>th</strong>e rise in <strong>th</strong>e level <strong>of</strong> <strong>th</strong>e<br />

oceans brought on by <strong>th</strong>e melting <strong>of</strong> polar ice; drought would become widespread; and<br />

desertification would expand and <strong>ac</strong>celerate. Persistent famines, mass migrations and largescale<br />

conflict would be <strong>th</strong>e result. Agriculture, food and water security, and international<br />

trade would come under severe strain.<br />

Until recently, industrialized countries have <strong>ac</strong>counted for most <strong>of</strong> <strong>th</strong>e emission <strong>of</strong> <strong>th</strong>e<br />

GHG, in particular carbon dioxide, because <strong>th</strong>eir economic development has been very<br />

strongly based on <strong>th</strong>e use <strong>of</strong> fossil fuels. However, <strong>th</strong>e same dynamic has also led to a<br />

situation where <strong>th</strong>e newly industrializing countries <strong>of</strong> Asia and Latin America (<strong>th</strong>e strong<br />

Sou<strong>th</strong>) are today contributing significantly to <strong>th</strong>e emission <strong>of</strong> carbon dioxide. This tendency<br />

will spread to and encompass an increasing number <strong>of</strong> developing countries unless bo<strong>th</strong><br />

<strong>th</strong>e industrialized and <strong>th</strong>e developing countries jointly agree on implementing <strong>th</strong>e measures<br />

to halt and <strong>th</strong>en reverse <strong>th</strong>e global trend towards a rapid rise in <strong>th</strong>e emission <strong>of</strong> carbon<br />

dioxide. That is <strong>th</strong>e central purpose <strong>of</strong> <strong>th</strong>e IPCC, which has succeeded in obtaining<br />

commitments from most <strong>of</strong> <strong>th</strong>e industrialized countries to reduce <strong>th</strong>eir emissions <strong>of</strong> carbon<br />

dioxide.<br />

At <strong>th</strong>e 1995 meeting in Berlin <strong>of</strong> <strong>th</strong>e Conference <strong>of</strong> <strong>th</strong>e Parties (CoP) to <strong>th</strong>e United<br />

Nations Climate Convention, it was decided to initiate negotiations to streng<strong>th</strong>en <strong>th</strong>e<br />

emission-reduction measures by <strong>th</strong>e industrialized countries, as well as countries <strong>of</strong> Eastern<br />

Europe and <strong>th</strong>e Former Soviet Union. The final negotiations are planned to take pl<strong>ac</strong>e at<br />

<strong>th</strong>e December 1997 meeting in Kyoto <strong>of</strong> <strong>th</strong>e CoP, which ought to result in legal<br />

instruments to ensure <strong>th</strong>at <strong>th</strong>e agreed measures are being fulfilled.<br />

The fossil fuel generated climate problem is very complex, wi<strong>th</strong> strong vested interests and<br />

special alliances. There is still considerable skepticism in <strong>th</strong>e developing world about <strong>th</strong>e<br />

need for measures to counter global warming, in particular in <strong>th</strong>e strong Sou<strong>th</strong>, which in no<br />

way wants to jeopardize its own rapid economic development. It is <strong>th</strong>erefore imperative to<br />

find innovative solutions, bo<strong>th</strong> technical and institutional, to <strong>th</strong>e climate problem, which<br />

are <strong>ac</strong>ceptable to bo<strong>th</strong> <strong>th</strong>e Nor<strong>th</strong> and <strong>th</strong>e Sou<strong>th</strong>. Meeting <strong>th</strong>is challenge calls for inter alia<br />

research programs <strong>th</strong>at t<strong>ac</strong>kle <strong>th</strong>e technological, techno-economic and policy problems in


promoting <strong>th</strong>e transition to decreasing use <strong>of</strong> fossil fuels, increasing energy efficiency and<br />

fuel substitution, and carbon recycling systems <strong>of</strong> energy production and use.<br />

The <strong>Asian</strong> Regional Research Programme on Energy, Environment and Climate<br />

(ARRPEEC) is part <strong>of</strong> <strong>th</strong>is global effort, which Sida is very pleased to have initiated and is<br />

fully supporting. The ARRPEEC comprises technological, techno-economic and policy<br />

research on energy efficiency, fuel substitution and carbon recycling in <strong>th</strong>e principal<br />

economic sectors <strong>of</strong> East, Sou<strong>th</strong>east and Sou<strong>th</strong> <strong>Asian</strong> countries.<br />

M R Bhagavan<br />

Senior Research Adviser, Department for Research Cooperation<br />

Swedish International Development Cooperation Agency, Sida


PREFACE<br />

Industries have always played a crucial role in <strong>th</strong>e socio-economic development <strong>of</strong> a<br />

country. They have contributed primarily to increased prosperity, greater employment and<br />

livelihood opportunities. On <strong>th</strong>e o<strong>th</strong>er hand, industries are <strong>ac</strong>cused <strong>of</strong> <strong>ac</strong>celerating <strong>th</strong>e<br />

consumption <strong>of</strong> scarce fossil fuels and <strong>of</strong> polluting <strong>th</strong>e local, regional, and global<br />

environment by releasing solid, liquid and gaseous pollutants to <strong>th</strong>eir surroundings.<br />

Experiences gained worldwide have shown <strong>th</strong>at <strong>th</strong>ese imp<strong>ac</strong>ts <strong>of</strong> industries on resource use<br />

and <strong>th</strong>e environment can be contained <strong>th</strong>rough more efficient production processes and<br />

adoption <strong>of</strong> cleaner technologies and procedures. Thus, fossil fuel consumption can be cut<br />

down drastically and waste generation can be avoided or minimized to <strong>th</strong>e lowest possible<br />

level. Regulatory regimes introduced in several countries have led <strong>th</strong>e industries to adopt<br />

appropriate measures. Some countries have adopted economic instruments to reflect <strong>th</strong>e<br />

true cost <strong>of</strong> goods and services by internalizing <strong>th</strong>e environmental costs <strong>of</strong> <strong>th</strong>eir input,<br />

production, use, recycling and disposal.<br />

The improvement <strong>of</strong> production system <strong>th</strong>rough <strong>th</strong>e use <strong>of</strong> technologies and processes <strong>th</strong>at<br />

utilize resources more efficiently and <strong>ac</strong>hieve “more wi<strong>th</strong> less” is an important pa<strong>th</strong>way<br />

towards <strong>th</strong>e long-term sustenance <strong>of</strong> industries. It is in <strong>th</strong>is context <strong>th</strong>at a research project<br />

was undertaken by <strong>th</strong>e <strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong> (AIT), wi<strong>th</strong> <strong>th</strong>e support <strong>of</strong> <strong>th</strong>e<br />

Swedish International Development Cooperation Agency (Sida). The project entitled<br />

“Development <strong>of</strong> Energy Efficient and Environmentally Sound Industrial Technologies in<br />

Asia” was launched wi<strong>th</strong> <strong>th</strong>e specific objective to enhance <strong>th</strong>e synergy among selected<br />

<strong>Asian</strong> developing countries in <strong>th</strong>eir efforts to grasp <strong>th</strong>e mechanism and various aspects<br />

related to <strong>th</strong>e adoption and propagation <strong>of</strong> energy efficient and environmentally sound<br />

technologies. Three energy intensive and environmentally polluting industrial sub-sectors<br />

(cement, iron & steel, and pulp & paper) and four <strong>Asian</strong> countries <strong>of</strong> varying sizes, political<br />

systems and stages <strong>of</strong> development (China, India, Philippines, Sri Lanka) were selected in<br />

<strong>th</strong>e framework <strong>of</strong> <strong>th</strong>is study. To enhance in-country cap<strong>ac</strong>ity building in <strong>th</strong>e subject matter,<br />

collaboration was sought from reputed national institutes who nominated experts to<br />

<strong>ac</strong>tively participate in <strong>th</strong>e execution <strong>of</strong> <strong>th</strong>e project.<br />

The <strong>ac</strong>tivities undertaken in <strong>th</strong>e first phase <strong>of</strong> <strong>th</strong>e project were <strong>th</strong>e following:<br />

- Evaluation <strong>of</strong> <strong>th</strong>e status <strong>of</strong> technologies in selected energy intensive and<br />

environmentally polluting industries;<br />

- Identification <strong>of</strong> potential areas for energy conservation and pollution abatement<br />

in <strong>th</strong>ese industries;<br />

- Analysis <strong>of</strong> <strong>th</strong>e technological development <strong>of</strong> energy intensive and polluting<br />

industries in relation wi<strong>th</strong> <strong>th</strong>e national regulatory measures;<br />

- Identification <strong>of</strong> major barriers to efficiency improvements and pollution<br />

abatement in <strong>th</strong>e industrial sector.


Based on <strong>th</strong>e initial guidelines prepared at AIT under <strong>th</strong>e leadership <strong>of</strong> Dr. X. Chen,<br />

discussions were held wi<strong>th</strong> <strong>th</strong>e experts from <strong>th</strong>e national research institutes (NRIs) <strong>of</strong> <strong>th</strong>e<br />

four participating countries. The outcomes <strong>of</strong> <strong>th</strong>ese meetings were used as a basis for <strong>th</strong>e<br />

preparation <strong>of</strong> country reports which were presented at two project workshops held at<br />

Manila in May 1995 and at Bangkok in November 1995. On <strong>th</strong>e basis <strong>of</strong> <strong>th</strong>e reports<br />

submitted, cross-country comparison reports were prepared at AIT and additional relevant<br />

information was sought from <strong>th</strong>e NRIs to bridge some <strong>of</strong> <strong>th</strong>e gaps found in <strong>th</strong>eir<br />

respective reports. This is <strong>th</strong>e <strong>th</strong>ird <strong>of</strong> <strong>th</strong>e four volumes <strong>of</strong> documents which have resulted<br />

from <strong>th</strong>is inter<strong>ac</strong>tive research work between AIT and <strong>th</strong>e NRIs.<br />

This volume on “<strong>Technology</strong>, energy efficiency and environmental externalities in <strong>th</strong>e pulp<br />

and paper industry” covers a description <strong>of</strong> <strong>th</strong>e paper manuf<strong>ac</strong>turing process, and <strong>th</strong>e<br />

energy and environmental aspects associated wi<strong>th</strong> it. Then <strong>th</strong>ere is a cross-country<br />

comparison <strong>of</strong> <strong>th</strong>e pulp and paper sector in <strong>th</strong>e four countries, followed by individual<br />

country reports prepared by <strong>th</strong>e four NRIs. The first five chapters were prepared by Dr. B.<br />

Mohanty and Dr. Uwe Stoll wi<strong>th</strong> <strong>th</strong>e assistance <strong>of</strong> research associates figuring in <strong>th</strong>e Project<br />

Team.<br />

Sincere <strong>th</strong>anks are extended to all <strong>th</strong>e members <strong>of</strong> <strong>th</strong>e Project Team including <strong>th</strong>e<br />

supporting staff, past and present, for <strong>th</strong>eir <strong>ac</strong>tive participation and contribution to <strong>th</strong>e<br />

project. The en<strong>th</strong>usiasm and dynamism <strong>of</strong> Dr. X. Chen during <strong>th</strong>e execution <strong>of</strong> <strong>th</strong>e first<br />

phase and <strong>th</strong>e understanding and leadership provided by Dr. C. Visvana<strong>th</strong>an in <strong>th</strong>e crucial<br />

completion period <strong>of</strong> <strong>th</strong>e project are <strong>ac</strong>knowledged here. The project would have never<br />

seen <strong>th</strong>e light <strong>of</strong> <strong>th</strong>e day wi<strong>th</strong>out <strong>th</strong>e support <strong>of</strong> Sida. Finally, appreciations are due to two<br />

individuals who have <strong>ac</strong>tually conceived <strong>th</strong>e <strong>Asian</strong> Regional Research Programme on<br />

Energy, Environment and Climate (ARRPEEC) and provided constant support and<br />

encouragement to <strong>th</strong>is specific project under <strong>th</strong>e overall program: Dr. M.R. Bhagawan,<br />

Senior Research Adviser at Sida, and Dr. S.C. Bhatt<strong>ac</strong>harya, Pr<strong>of</strong>essor at AIT.<br />

Brahmanand Mohanty<br />

<strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong><br />

June, 1997


PROJECT TEAM<br />

F<strong>ac</strong>ulty Members (<strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong> - School <strong>of</strong> Environment,<br />

Resources and Development)<br />

- Dr. Xavier Chen, Energy Program (Until February 1996)<br />

- Dr. Brahmanand Mohanty, Energy Program<br />

- Dr. Uwe Stoll, Environmental Engineering Program (Until January 1996)<br />

- Dr. C. Visvana<strong>th</strong>an, Environmental Engineering Program (From January 1996)<br />

Research Associates (<strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong> - School <strong>of</strong> Environment,<br />

Resources and Development)<br />

- Ms. Nahid Amin<br />

- Ms. Lilita B. B<strong>ac</strong>areza<br />

- Mr. Z. Khandkar<br />

- Mr. Aung Naing Oo<br />

- Mr. K. Parameshwaran<br />

National Research <strong>Institute</strong>s<br />

- <strong>Institute</strong> for Techno-Economics and Energy System Analysis, Tsinghua<br />

University, Beijing, China (Pr<strong>of</strong>. Qiu Daxiong)<br />

- Energy Management Centre, Ministry <strong>of</strong> Power, New Delhi, India (Mr. S.<br />

Ramaswamy)<br />

- Department <strong>of</strong> Energy, Manila, Philippines (Mr. C.T. Tupas)<br />

- Energy Conservation Fund, Ministry <strong>of</strong> Irrigation, Power and Energy, Colombo,<br />

Sri Lanka (Mr. U. Daranagama)<br />

Research Fellows<br />

- Dr. Wu Xiaobo, School <strong>of</strong> Management, Zhejiang University, China (January-<br />

June 1996)<br />

- Ms. Wang Yanjia, Tsinghua University, China (May-November 1996)<br />

- Mr. Anil Kumar Aneja, Thapar Corporate R&D Centre, India (May-November<br />

1996)<br />

- Ms. Marisol Portal, National Power Corporation, Philippines (May-November<br />

1996)<br />

- Mr. Gamini Senanayake, Industrial Services Bureau <strong>of</strong> Nor<strong>th</strong> Western Province,<br />

Sri Lanka (May-November 1996)


CONTENTS<br />

FOREWARD<br />

PREFACE<br />

PROJECT TEAM<br />

1. GENERAL........................................................................................................................................ 1<br />

2. PRODUCTION PROCESSES ......................................................................................................... 2<br />

2.1 PULPING PROCESSES .................................................................................................................................................2<br />

2.1.1 Sulfite pulping process .............................................................................................................................................4<br />

2.1.2 Kraft (sulfate) pulping process..................................................................................................................................4<br />

2.1.3 Semi-chemical pulping process..................................................................................................................................5<br />

2.1.4 Mechanical pulping process......................................................................................................................................6<br />

2.2 CHEMICAL PROCESSING LINE ..................................................................................................................................6<br />

2.3 FIBER PROCESSING LINE ...........................................................................................................................................9<br />

2.4 BLEACHING OF PULP .................................................................................................................................................9<br />

2.5 CHEMICAL PLANT ................................................................................................................................................... 11<br />

2.6 MANUFACTURING PROCESS OF PAPER ............................................................................................................... 11<br />

3. ENERGY ISSUES IN PULP AND PAPER INDUSTRY...............................................................13<br />

3.1 TYPICAL ENERGY CONSUMPTION PATTERNS ................................................................................................... 13<br />

3.2 ENERGY EFFICIENT MEASURES........................................................................................................................... 15<br />

3.2.1 Short term measures............................................................................................................................................. 15<br />

3.2.2 Medium term measures......................................................................................................................................... 15<br />

3.2.3 Long term measures ............................................................................................................................................. 17<br />

3.3 NEW ENERGY EFFICIENT TECHNOLOGIES FOR PAPERMAKING .................................................................. 19<br />

3.4 CONCLUDING REMARKS ON ENERGY ISSUES ................................................................................................... 20<br />

4. SOURCES OF POLLUTION AND ITS MANAGEMENT.......................................................... 22<br />

4.1 SOURCES AND CHARACTERISTICS OF POLLUTANTS ......................................................................................... 22<br />

4.1.1 Sources <strong>of</strong> wastewater generated ............................................................................................................................ 22<br />

4.1.2 Char<strong>ac</strong>teristics <strong>of</strong> wastewater generated ................................................................................................................. 23<br />

4.1.3 Sources and char<strong>ac</strong>teristics <strong>of</strong> gaseous emissions..................................................................................................... 25<br />

4.1.4 Sources and char<strong>ac</strong>teristics <strong>of</strong> solid wastes ............................................................................................................. 25<br />

4.2 CURRENT POLLUTION ABATEMENT STRATEGIES AND TECHNOLOGIES..................................................... 25<br />

4.2.1 Water pollution control......................................................................................................................................... 25<br />

4.2.2 Solid waste disposal.............................................................................................................................................. 29<br />

4.3 POSSIBILITIES FOR APPLICATION OF ALTERNATIVE TECHNOLOGIES FOR POLLUTION CONTROL ....... 29<br />

4.3.1 Anaerobic treatment <strong>of</strong> wastes .............................................................................................................................. 29<br />

4.3.2 Membrane technology ........................................................................................................................................... 29<br />

4.3.3 Dissolved air floatation for fiber recovery............................................................................................................... 30<br />

4.3.4 Ozone ble<strong>ac</strong>hing ................................................................................................................................................... 30<br />

4.3.5 Modified continuous cooking process (MCC)........................................................................................................ 31<br />

4.3.6 DARS in soda pulping <strong>of</strong> bagasse ....................................................................................................................... 32<br />

4.3.7 Dry forming <strong>of</strong> paper web..................................................................................................................................... 32


4.4 CONCLUDING REMARKS ON POLLUTION MANAGEMENT...................................................................................<br />

5. CROSS COUNTRY REPORT ON THE PULP AND PAPER INDUSTRY................................ 34<br />

5.1 INTRODUCTION ....................................................................................................................................................... 34<br />

5.2 OVERVIEW OF THE INDUSTRY.............................................................................................................................. 34<br />

5.2.1 Role in <strong>th</strong>e national economy ................................................................................................................................ 34<br />

5.2.2 Share in total energy consumption......................................................................................................................... 34<br />

5.2.3 Production trends ................................................................................................................................................. 35<br />

5.2.4 Mills and <strong>th</strong>eir cap<strong>ac</strong>ities...................................................................................................................................... 36<br />

5.3 CHARACTERISTICS OF THE PARAMETERS AFFECTING ENERGY EFFICIENCY ............................................. 38<br />

5.3.1 Raw material mix................................................................................................................................................ 39<br />

5.3.2 Level <strong>of</strong> waste paper utilization ............................................................................................................................ 39<br />

5.3.3 Energy consumption by type.................................................................................................................................. 39<br />

5.3.4 Awareness about energy conservation .................................................................................................................... 40<br />

5.4 CHARACTERISTICS OF THE PARAMETERS AFFECTING POLLUTION ABATEMENT MEASURES..................... 41<br />

5.4.1 Causes <strong>of</strong> pollution............................................................................................................................................... 42<br />

5.4.2 Current water pollution control strategies .............................................................................................................. 42<br />

5.4.3 Current air pollution control strategies .................................................................................................................. 44<br />

5.4.4 Current solid waste control strategies..................................................................................................................... 44<br />

5.4.5 Comparison <strong>of</strong> effluent and emission char<strong>ac</strong>teristics............................................................................................... 44<br />

5.5 POTENTIAL FOR ENERGY EFFICIENCY IMPROVEMENT .................................................................................. 46<br />

5.5.1 Structure <strong>of</strong> <strong>th</strong>e industry ....................................................................................................................................... 46<br />

5.5.2 Raw materials...................................................................................................................................................... 46<br />

5.5.3 Potential for energy conservation............................................................................................................................ 46<br />

5.6 POTENTIAL FOR POLLUTION ABATEMENT......................................................................................................... 46<br />

5.7 CONCLUSION............................................................................................................................................................ 49<br />

6. PROFILE OF THE PULP AND PAPER INDUSTRY IN SELECTED ASIAN<br />

COUNTRIES…………………………………………………………………………………………….50<br />

6.1 COUNTRY REPORT: CHINA.................................................................................................................................... 50<br />

6.1.1 Introduction.......................................................................................................................................................... 50<br />

6.1.2 Technological trajectory <strong>of</strong> China’s paper industry................................................................................................. 54<br />

6.1.3 Evolution <strong>of</strong> energy efficiency in Chinese pulp & paper industry ........................................................................... 61<br />

6.1.4 Environmental externalities <strong>of</strong> <strong>th</strong>e pulp & paper industry in China..................................................................... 67<br />

6.1.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough technological changes.......................... 70<br />

6.1.6 Status <strong>of</strong> application <strong>of</strong> new technologies................................................................................................................ 75<br />

6.1.7 Conclusions.......................................................................................................................................................... 77<br />

6.2 COUNTRY REPORT: INDIA............................................................................................................................ 79<br />

6.2.1 Introduction.......................................................................................................................................................... 79<br />

6.2.2 Technological trajectory <strong>of</strong> <strong>th</strong>e Indian paper industry ............................................................................................. 79<br />

6.2.3 Evolution <strong>of</strong> energy efficiency in Indian pulp and paper industry ........................................................................... 87<br />

6.2.4 Environmental externalities <strong>of</strong> technological development in <strong>th</strong>e pulp and paper industry....................................... 89<br />

6.2.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough technological change........................... 93<br />

6.2.6 Status <strong>of</strong> <strong>th</strong>e application <strong>of</strong> new technologies.......................................................................................................... 99<br />

6.3 COUNTRY REPORT: PHILIPPINES............................................................................................................ 100<br />

6.3.1 Introduction........................................................................................................................................................ 100<br />

6.3.2 Technological trajectory <strong>of</strong> <strong>th</strong>e paper industry in <strong>th</strong>e Philippines........................................................................... 100<br />

6.3.3 Evolution <strong>of</strong> energy efficiency in <strong>th</strong>e pulp and paper industry <strong>of</strong> <strong>th</strong>e Philippines.................................................... 106


6.3.4 Environmental externalities <strong>of</strong> <strong>th</strong>e pulp and paper industry <strong>of</strong> <strong>th</strong>e Philippines..................................................... 109<br />

6.3.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough technological changes........................ 111<br />

6.3.6 Status <strong>of</strong> application <strong>of</strong> new technologies.............................................................................................................. 113<br />

6.3.7 Concluding remarks ........................................................................................................................................... 114<br />

6.4 COUNTRY REPORT: SRI LANKA................................................................................................................ 115<br />

6.4.1 Introduction........................................................................................................................................................ 115<br />

6.4.2 Technological trajectory <strong>of</strong> <strong>th</strong>e Sri Lankan pulp and paper industry.................................................................... 115<br />

6.4.3 Evolution <strong>of</strong> energy efficiency in <strong>th</strong>e pulp and paper industry <strong>of</strong> Sri Lanka ......................................................... 117<br />

6.4.4 Environmental externalities in <strong>th</strong>e pulp and paper industry <strong>of</strong> Sri Lanka.......................................................... 117<br />

6.4.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough technological changes........................ 118<br />

7. BIBLIOGRAPHY ..........................................................................................................................120


General 1<br />

1. GENERAL<br />

Wi<strong>th</strong> paper being an essential commodity <strong>of</strong> today’s society, <strong>th</strong>e pulp and paper industry<br />

has been growing rapidly all over <strong>th</strong>e world. The industry rates among <strong>th</strong>e highest energy<br />

consumers in many countries. Theoretically, <strong>th</strong>e pulp and paper industry should not<br />

require any purchased energy, because waste materials generated can be re-used as fuels.<br />

However, most pulp and paper mills normally purchase 20-50% <strong>of</strong> <strong>th</strong>eir total energy,<br />

mostly as electricity. Al<strong>th</strong>ough <strong>th</strong>e specific energy consumption values <strong>of</strong> paper products<br />

have been decreasing steadily, <strong>th</strong>ere is still potential for energy saving by employing<br />

advanced technologies and by modifying <strong>th</strong>e current energy use pr<strong>ac</strong>tices. One <strong>of</strong> <strong>th</strong>e<br />

distinguishing char<strong>ac</strong>teristics <strong>of</strong> <strong>th</strong>e pulp and paper industry is <strong>th</strong>e enormous generation <strong>of</strong><br />

wastes. Therefore, an integrated appro<strong>ac</strong>h towards energy and environment could be highly<br />

beneficial for <strong>th</strong>e future betterment <strong>of</strong> <strong>th</strong>e industry.<br />

Environmental pollution caused by industries is closely related to <strong>th</strong>e technologies used and<br />

to <strong>th</strong>e pattern <strong>of</strong> energy consumption by <strong>th</strong>e technologies. The key to <strong>th</strong>e success <strong>of</strong><br />

pollution abatement in industrial sector will depend on <strong>th</strong>e appro<strong>ac</strong>h <strong>of</strong> regulations,<br />

promotion <strong>of</strong> new technologies in <strong>th</strong>e production and waste minimization <strong>ac</strong>tivities (clean<br />

technologies), and improvement <strong>of</strong> industrial energy efficiency. Energy efficiency<br />

improvement and environmental pollution reduction can only be <strong>ac</strong>hieved by ei<strong>th</strong>er retr<strong>of</strong>it<br />

measures (modification <strong>of</strong> <strong>th</strong>e existing technology and equipment) or by installation <strong>of</strong><br />

clean technologies, or bo<strong>th</strong>.<br />

This document describes <strong>th</strong>e production processes and technologies in use (Sec. 2), <strong>th</strong>e<br />

energy saving opportunities and potential in light <strong>of</strong> bo<strong>th</strong> <strong>th</strong>e existing and new technologies<br />

(Sec. 3), as well as <strong>th</strong>e issues <strong>of</strong> sources <strong>of</strong> pollution and pollution abatement measures<br />

including <strong>th</strong>e possibilities for pollution abatement in <strong>th</strong>e pulp and paper industry in future<br />

(Sec. 4). It also provides a cross country comparison <strong>of</strong> <strong>th</strong>e sector (Sec. 5) followed by<br />

individual country reports on <strong>th</strong>e pulp and paper industry <strong>of</strong> four <strong>Asian</strong> industrializing<br />

nations (Sec. 6).


2 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

2. PRODUCTION PROCESSES<br />

Raw materials primarily considered for commercial scale production <strong>of</strong> pulp and paper<br />

include pine, bamboo, rubber wood, mixed tropical hardwood, bagasse, Burma grass and<br />

rice straw. These raw materials consist mainly <strong>of</strong> cellulose, hemicellulose and lignin.<br />

Cellulose and hemicellulose are polys<strong>ac</strong>charides as starch. Target <strong>of</strong> <strong>th</strong>e pulping process is<br />

to cr<strong>ac</strong>k and remove <strong>th</strong>is matrix and separate out <strong>th</strong>e pure cellulose as a natural and<br />

resistant raw product. Lignin, hemicellulose and <strong>th</strong>e extr<strong>ac</strong>ts are separated by cooking in a<br />

digester. Lignin becomes dissolved by sulfonization, hemicellulose gets hydrolyzed and <strong>th</strong>e<br />

extr<strong>ac</strong>ts get partly dissolved under <strong>ac</strong>idic conditions. In <strong>th</strong>e ensuing procedural steps<br />

(ble<strong>ac</strong>hing process), <strong>th</strong>e remaining lignin gets oxidized, bo<strong>th</strong> in <strong>ac</strong>idic and alkaline phase,<br />

whereas <strong>th</strong>e hemicellulose and extr<strong>ac</strong>ts get dissolved mainly in <strong>th</strong>e alkaline phase.<br />

Only about 40% <strong>of</strong> <strong>th</strong>e raw material input is represented in <strong>th</strong>e solid yield. The<br />

environmental problem wi<strong>th</strong> <strong>th</strong>e pulp and paper industry is evidently <strong>th</strong>e o<strong>th</strong>er 60%, which<br />

is <strong>th</strong>e liquid by-product and has to be treated fur<strong>th</strong>er. General flowchart <strong>of</strong> <strong>th</strong>e pulp and<br />

paper making process is given in Figure 2.1. The pulp may be broadly classified as follows:<br />

- High quality pulp<br />

- Sulfite pulp (SP)<br />

- Kraft / Sulfate pulp (KP)<br />

- Low quality pulp (wood fibric)<br />

- Semichemical pulp (SCP)<br />

- Ground or Mechanical pulp (GP)<br />

2.1 Pulping Processes<br />

The main manuf<strong>ac</strong>turing processes <strong>of</strong> pulp production are:<br />

- Sulfite Pulping (SP): chemical pulping, <strong>ac</strong>idic process, cooks <strong>th</strong>e chips wi<strong>th</strong> <strong>ac</strong>id<br />

sulfite solution at a high temperature for half a day.<br />

- Kraft or Sulfate Pulping (KP): chemical pulping, alkaline process, cooks <strong>th</strong>e chips<br />

wi<strong>th</strong> caustic soda and sodium sulfate at a high temperature (160°C) for several<br />

hours. Ble<strong>ac</strong>hed Kraft pulp can be processed into papers <strong>of</strong> high grade.<br />

- Semichemical Pulping (SCP): combination <strong>of</strong> chemical and mechanical pulping processes.<br />

- Ground or Mechanical Pulping (GP): involves mechanical grinding <strong>of</strong> wood,<br />

generates less pollution. However, <strong>th</strong>is process is not suitable for products wi<strong>th</strong><br />

quality requirements, because <strong>of</strong> less durability and poor color.


Production Processes 3<br />

RAW MATERIAL<br />

PREPARATION<br />

PULPING<br />

Χ Chemical Pulping<br />

Alkaline<br />

- Kraft or sulfate√<br />

- Soda pulping<br />

Acidic or sulfite<br />

Χ Mechanical<br />

- GWP - RMP<br />

- TMP - CTMP<br />

Χ Semi-chemical Pulping<br />

- Neutral sulfite<br />

BLEACHING<br />

PAPER MAKING<br />

Process Flow (including<br />

Raw Materials & By-Products)<br />

Steam / Hot water<br />

Chemicals<br />

- Alkaline sulfate liquor (Kraft)<br />

- Acid sulfite liquor (Acidic)<br />

- Neutral sulfite liquor<br />

(Semi-chemical)<br />

White water<br />

(Reuse water),<br />

or Fresh water<br />

Ble<strong>ac</strong>hing<br />

Chemicals<br />

White water or<br />

Fresh water<br />

Fillers, Dye,<br />

Alum, Starch<br />

White water or<br />

Fresh water<br />

Fresh water or<br />

White water<br />

Steam<br />

Coating<br />

Chemicals<br />

Raw Materials<br />

(Conventional: Wood<br />

O<strong>th</strong>ers: Grass, Bagasse,<br />

Straw etc.)<br />

Chipper<br />

Debarked Wood / Woodchips<br />

Pulp Digester<br />

Crude Pulp<br />

Screening &<br />

Washing<br />

Fine Purified Pulp<br />

Chemical reuse<br />

Chemical<br />

recovery boiler<br />

Thickening<br />

Unble<strong>ac</strong>hed Pulp<br />

Ble<strong>ac</strong>hing Plant<br />

Ble<strong>ac</strong>hed pulp<br />

Stock<br />

Preparation<br />

Paper M<strong>ac</strong>hine<br />

Drying &<br />

Finishing<br />

Finished Paper<br />

Products<br />

Wood wastes, barks etc.<br />

to Waste Boiler<br />

Weak bl<strong>ac</strong>k liquor<br />

Evaporator<br />

Sedimentation &<br />

Aerobic treatment<br />

Waste paper<br />

(secondary intake)<br />

Refining<br />

to Treatment plants<br />

Strong bl<strong>ac</strong>k liquor to Combustion<br />

Condensate<br />

to Anaerobic<br />

treatment<br />

Electricity<br />

Steam<br />

(180°C,<br />

12-13 GJ/t)<br />

Electricity<br />

220-300 kWh/t<br />

400-520 kWh/t<br />

Steam<br />

(5 GJ/t)<br />

Electricity<br />

Electricity<br />

Steam<br />

(5-6 GJ/t)<br />

Steam<br />

(8 GJ/t)<br />

Electricity<br />

Energy Flow<br />

Raw Materials<br />

(Conventional: Wood<br />

O<strong>th</strong>ers: Grass, Bagasse,<br />

Straw etc.)<br />

Debarked Wood / Woodchips<br />

Pulp Digester<br />

Crude Pulp<br />

Screening &<br />

Washing<br />

Fine Purified Pulp<br />

Thickening<br />

Unble<strong>ac</strong>hed Pulp<br />

Ble<strong>ac</strong>hed pulp<br />

Stock<br />

Preparation<br />

Paper M<strong>ac</strong>hine<br />

Drying &<br />

Finishing<br />

Finished Paper<br />

Products<br />

Figure 2.1. Process flow chart <strong>of</strong> <strong>th</strong>e pulp and paper industry<br />

Chipper<br />

Ble<strong>ac</strong>hing<br />

Waste paper<br />

(secondary intake)<br />

Refining<br />

to pulp digester<br />

Effluents & Emissions<br />

Raw Materials<br />

(Conventional: Wood<br />

O<strong>th</strong>ers: Grass, Bagasse,<br />

Straw etc.)<br />

Chipper<br />

Debarked Wood / Woodchips<br />

Pulp Digester<br />

Crude Pulp<br />

Screening &<br />

Washing<br />

Fine Purified Pulp<br />

Chemical reuse<br />

Chemical<br />

recovery boiler<br />

Thickening<br />

Unble<strong>ac</strong>hed Pulp<br />

Ble<strong>ac</strong>hing Plant<br />

Ble<strong>ac</strong>hed pulp<br />

Stock<br />

Preparation<br />

Paper M<strong>ac</strong>hine<br />

Drying &<br />

Finishing<br />

Finished Paper<br />

Products<br />

Weak bl<strong>ac</strong>k liquor<br />

Evaporator<br />

Sedimentation &<br />

Aerobic treatment<br />

Sludge,<br />

Ble<strong>ac</strong>h water<br />

Waste paper<br />

(secondary intake)<br />

Refining<br />

Heat emission<br />

White water,<br />

Fiber, Fillers,<br />

Broke, etc.<br />

Liquid clean-up,<br />

Broke, Coatings etc.<br />

to Treatment plants<br />

Evaporative emission<br />

Strong bl<strong>ac</strong>k liquor<br />

to Combustion<br />

to Anaerobic<br />

Condensate treatment<br />

Gaseseous emission<br />

Effluent<br />

Fiber & ink<br />

sludge


4 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

It is estimated <strong>th</strong>at <strong>th</strong>e proportion <strong>of</strong> pulp produced in <strong>th</strong>e world using <strong>th</strong>ese major processes<br />

are: 75% chemical pulp (mostly Kraft), 20% mechanical pulp, and <strong>th</strong>e remaining 5% o<strong>th</strong>er<br />

pulps (RAO et al, 1995).<br />

2.1.1 Sulfite pulping process<br />

The fiber binding lignin is s<strong>of</strong>tened and dissolved to a considerable extent in a solution<br />

-<br />

containing dissolved SO2, hydrogensulfite (bisulfite) ion (HSO3 ), or sulfite ions, producing <strong>ac</strong>id<br />

-<br />

sulfite or bisulfite chemical pulps. The HSO3 re<strong>ac</strong>ts in <strong>th</strong>e digester wi<strong>th</strong> <strong>th</strong>e phenolic group on<br />

<strong>th</strong>e lignin, forming sulfonic <strong>ac</strong>ids.<br />

The yield varies from 45 to 65% depending on <strong>th</strong>e cooking degree, usually <strong>th</strong>e yield is about<br />

50% for standard non-ble<strong>ac</strong>hed pulps. If <strong>th</strong>e pulp is ble<strong>ac</strong>hed, ano<strong>th</strong>er 4 to 5% <strong>of</strong> <strong>th</strong>e original<br />

wood may be lost in <strong>th</strong>e process. This sulfite me<strong>th</strong>od is one <strong>of</strong> two major wood-pulping<br />

processes. The cellulose fiber obtained from <strong>th</strong>e sulfite process is less strong compared to <strong>th</strong>e<br />

Kraft process.<br />

2.1.2 Kraft (sulfate) pulping process<br />

The soda process has been largely repl<strong>ac</strong>ed by <strong>th</strong>e sulfate or (Kraft) process. This process<br />

includes not only NaOH, but also Na 2S in <strong>th</strong>e cooking liquor. The presence <strong>of</strong> caustic soda in<br />

<strong>th</strong>e cooking liquor makes <strong>th</strong>is pulping process suitable for use wi<strong>th</strong> all wood species. Sodium<br />

sulfate plays a buffering role <strong>th</strong>at allows digestion to be possible at lower pH, <strong>th</strong>us reducing<br />

damage to <strong>th</strong>e fibers and producing pulp wi<strong>th</strong> high streng<strong>th</strong> property. In water solution, <strong>th</strong>e<br />

sulfide ion (S 2- ) hydrolyzes to form hydroxide ions (OH - ) and hydrogen sulfide ions (HS - )<br />

<strong>ac</strong>cording to <strong>th</strong>e formula :<br />

S 2-- + H 2 O → HS - + OH -<br />

The initial high concentration <strong>of</strong> NaOH (hence OH - ions) forces <strong>th</strong>e equilibrium to <strong>th</strong>e left,<br />

<strong>ac</strong>cording to Le Chatelier’s principle. The net result being <strong>th</strong>at delignification occurs at a more<br />

steady rate and HS - can also re<strong>ac</strong>t wi<strong>th</strong> <strong>th</strong>e lignin to enhance its solubility. The residual liquor is<br />

very dark, and is called <strong>th</strong>e “Bl<strong>ac</strong>k liquor”. The flowchart <strong>of</strong> Kraft or sulfate process is shown in<br />

Figure 2.2.<br />

As ano<strong>th</strong>er alkaline pulping process, soda pulping process is used in which <strong>th</strong>e cooking liquor is<br />

sodium hydroxide, obtained by adding a mixture <strong>of</strong> soda ash (Na 2CO 3) and lime [Ca(OH) 2] to<br />

<strong>th</strong>e digester. The digestion phase is in operation for about 10 hours under high pressure and<br />

temperature. The digestion decomposes or separates <strong>th</strong>e binding, non-cellulose materials such<br />

as lignin and resins, from <strong>th</strong>e fibers and consequently, weakens <strong>th</strong>em. This me<strong>th</strong>od is rarely<br />

used at present and has been largely repl<strong>ac</strong>ed by <strong>th</strong>e Kraft pulping process.


Production Processes 5<br />

Wood Chios<br />

Water<br />

Pulp to Ble<strong>ac</strong>h<br />

Plant<br />

Evaporator<br />

Evaporator<br />

Condensates<br />

Digester<br />

Brownst<strong>ac</strong>k<br />

Washers<br />

Weak Bl<strong>ac</strong>k<br />

Liquor<br />

NaOH /<br />

Na 2 S<br />

Na 2 SO 4 +<br />

organics<br />

Strong<br />

Bl<strong>ac</strong>k Liquor<br />

Make-Up Caustic<br />

(NaOH)<br />

2.1.3 Semi-chemical pulping process<br />

White Liquor<br />

Storage<br />

White Liquor<br />

Clarifier<br />

Recovery<br />

Boiler<br />

Slaker and<br />

Caustizers<br />

Green Liquor<br />

Clarifier<br />

Smelt<br />

Lime<br />

Mud<br />

Washer<br />

Make- Up Saltcake ( Na 2 SO 4 )<br />

Na 2 S / Na 2 CO 3<br />

Smelt<br />

Dissolving<br />

Tank<br />

Lime Mud<br />

Thickener<br />

Lime Kiln<br />

Figure 2.2. Kraft (sulfate) pulping process<br />

Weak Wash<br />

Water<br />

Dregs<br />

Washer<br />

In <strong>th</strong>is process, hardwood and s<strong>of</strong>t wood pulp is obtained by a series <strong>of</strong> chemical and<br />

mechanical wood treatments, none <strong>of</strong> which by itself is sufficient to make fibers separate<br />

readily. Unlike chemical pulping, <strong>th</strong>is process enables more <strong>of</strong> <strong>th</strong>e lignin and hemicellulose<br />

constituents <strong>of</strong> wood to be retained in <strong>th</strong>e pulp and <strong>th</strong>us <strong>th</strong>e pulp yield is <strong>of</strong>ten very high (about<br />

75-80%, based on dried wood). The process involves cooking <strong>of</strong> chips (hardwood) for 10-20<br />

minutes at a temperature <strong>of</strong> 175-185 0 C wi<strong>th</strong> an aqueous solution <strong>of</strong> sodium sulfite and sodium<br />

carbonate. The amount <strong>of</strong> pulping chemical required is about 9-19% Na 2CO 3 and 4-7% SO 2 per<br />

ton <strong>of</strong> dried wood. The pulp is defiberized mechanically in disc refiners and washed by a<br />

counter-current me<strong>th</strong>od on rotary drums (Kleppe and Rogers, 1970).<br />

Lime<br />

Stone


6 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

2.1.4 Mechanical pulping process<br />

Mechanical pulp is produced by grinding or shredding raw materials to free fibers. In addition,<br />

heat under pressure may be applied to assist <strong>th</strong>e process. It consists <strong>of</strong> two principal physical<br />

me<strong>th</strong>ods <strong>of</strong> producing ground wood pulp. The older technology involves grinding <strong>th</strong>e logs and<br />

stone grinding on large grind stones, whereas <strong>th</strong>e modern technology employs chip refining or<br />

refined ground-wood. Ble<strong>ac</strong>hing may be done by adding a small amount <strong>of</strong> sodium peroxide<br />

and/or hydrogen sulfite. Mechanical pulping provides low grade pulps wi<strong>th</strong> high color and<br />

relatively short fibers, but produces a high yield, converting about 95% <strong>of</strong> <strong>th</strong>e wood into pulp;<br />

minimal on-site air pollution is produced and relatively low water loads are generated<br />

(Anonymous 1981). The modern mechanical pulping process is illustrated in Figure 2.3.<br />

2.2 Chemical processing line<br />

Recovery <strong>of</strong> pulping chemicals is, in f<strong>ac</strong>t, limited to sodium and magnesium-based liquors, since<br />

calcium cannot be recovered economically and <strong>th</strong>ere is only limited experience on recovery <strong>of</strong><br />

ammonia (Anonymous, 1982). In <strong>th</strong>e chemical processing, high-efficiency recovery <strong>of</strong> chemicals<br />

is <strong>ac</strong>hieved. Maximum recovery <strong>of</strong> <strong>th</strong>e chemicals may result in a relatively cleaner effluent in<br />

which chemical toxicants are no longer a significant f<strong>ac</strong>tor as far as stream pollution is<br />

concerned.<br />

In <strong>th</strong>e sulfite pulping process, magnesium bisulfite is recovered. Dissolved wood substances are<br />

99% in <strong>th</strong>e weak bl<strong>ac</strong>k liquor obtained from cooking after pulp separation. This weak bl<strong>ac</strong>k<br />

liquor has about 13% <strong>of</strong> dry solids (DS). After evaporation, <strong>th</strong>e weak bl<strong>ac</strong>k liquor is converted<br />

to a strong liquor containing about 45% <strong>of</strong> DS. The bl<strong>ac</strong>k liquor from <strong>th</strong>e evaporation plant is<br />

led to <strong>th</strong>e recovery boiler. This liquor is fur<strong>th</strong>er evaporated in a cascade evaporator in <strong>th</strong>e<br />

recovery boiler up to 60% total solids before being burnt in <strong>th</strong>e boiler. Ash from gas cleaning<br />

consists mainly <strong>of</strong> magnesium oxide. It gets hydrolyzed to magnesium hydroxide which, in turn,<br />

is used for flue gas cleaning. Final product is magnesium bisulfite solution to which SO 2 and<br />

MgO are added for its reuse in <strong>th</strong>e cooking process.<br />

The treatment <strong>of</strong> bl<strong>ac</strong>k liquor from Kraft mills involves evaporation and incineration in order to<br />

recover <strong>th</strong>e chemicals and to utilize <strong>th</strong>e heating value <strong>of</strong> <strong>th</strong>e dissolved wood substance. During<br />

<strong>th</strong>e recovery process, Na 2SO 4 (wi<strong>th</strong> or wi<strong>th</strong>out added sulfur) is added to make up <strong>th</strong>e relatively<br />

small proportion <strong>of</strong> chemicals lost in various steps <strong>of</strong> <strong>th</strong>e process, and to form <strong>th</strong>e green liquor.<br />

The chemical compounds in <strong>th</strong>is green liquor are converted to desired cooking chemicals by <strong>th</strong>e<br />

addition <strong>of</strong> lime so as to form <strong>th</strong>e white liquor and a lime-mud consisting chiefly <strong>of</strong> CaCO 3. The<br />

white liquor is returned to <strong>th</strong>e pulping operation as <strong>th</strong>e cooking liquor. Lime mud is calcined to<br />

form CaO which is reused by converting o<strong>th</strong>er green liquor to white liquor. By-product<br />

recovery <strong>of</strong> turpentine, resin and fatty <strong>ac</strong>ids also aids in reducing <strong>th</strong>e streng<strong>th</strong> <strong>of</strong> Kraft pulp<br />

waste water.


Production Processes 7<br />

Sewer<br />

Water<br />

White Water<br />

Tank<br />

Saveall<br />

Wood<br />

Grinder Room<br />

Storage<br />

Grinder<br />

Coarse Screen<br />

Fine Screen<br />

Centrifugal<br />

Cleaners<br />

Deckers<br />

Storage<br />

Ble<strong>ac</strong>hing<br />

Paper M<strong>ac</strong>hine<br />

Paper<br />

2 % Consistency<br />

0.6 - 0.8 % Consistency<br />

Sewer<br />

Figure 2.3. Flow chart <strong>of</strong> <strong>th</strong>e mechanical pulping process<br />

Refiners<br />

Water


8 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Special Issues Related to Chemical Processing Line<br />

A. Chemical recovery <strong>of</strong> bl<strong>ac</strong>k liquor from rice straw pulping<br />

Rice straw contains 8-14 % <strong>of</strong> silica (SiO2). For chemical pulp produced from rice straw, about<br />

half <strong>of</strong> <strong>th</strong>is silica gets dissolved in <strong>th</strong>e bl<strong>ac</strong>k liquor. This causes problems in all stages <strong>of</strong> <strong>th</strong>e<br />

chemical recovery process.<br />

For a pulp mill <strong>th</strong>at depends on non-wood fiber, silica must be eliminated from bl<strong>ac</strong>k liquor to<br />

produce pulp economically and to meet environmental restrictions. The chemical recovery in<br />

<strong>th</strong>is application is relatively new and <strong>th</strong>ere is only limited information and experience today.<br />

Following is an example <strong>of</strong> such a recovery me<strong>th</strong>od:<br />

Investigations on desilication <strong>of</strong> rice straw bl<strong>ac</strong>k liquor started in <strong>th</strong>e 1970s and a pilot plant was<br />

started in 1985 (UNEP IE/PAC, 1992). In <strong>th</strong>e proposed chemicals recovery and desilication<br />

process, bl<strong>ac</strong>k liquor coming from <strong>th</strong>e washing unit is filtered in a drum-filter. The out-flowing<br />

bl<strong>ac</strong>k liquor is fed <strong>th</strong>rough a buffering tank to <strong>th</strong>e four-effect evaporator plant. For low<br />

concentrations, evaporation takes pl<strong>ac</strong>e in <strong>th</strong>ree long-tube falling film evaporators. Higher<br />

concentrations are attained in a forced circulation evaporator, which pre-concentrates <strong>th</strong>e bl<strong>ac</strong>k<br />

liquor to a DS content <strong>of</strong> between 8 and 14% - <strong>th</strong>e optimum for effective desilication. The<br />

forced-circulation stage fur<strong>th</strong>er concentrates <strong>th</strong>e desilicated bl<strong>ac</strong>k liquor.<br />

Next, a stream <strong>of</strong> pre-concentrated bl<strong>ac</strong>k liquor is fed to a draft-tube re<strong>ac</strong>tor equipped wi<strong>th</strong><br />

stirrer and foam breaker, where it is brought into intimate cont<strong>ac</strong>t wi<strong>th</strong> a continuous stream <strong>of</strong><br />

flue gas from <strong>th</strong>e power station st<strong>ac</strong>k. Here, soluble sodium silicates are converted into sodium<br />

carbonate and largely insoluble SiO 2. This two-phase mixture is routed <strong>th</strong>rough an intermediate<br />

tank to a decanter which separates <strong>th</strong>e precipitates from <strong>th</strong>e clean liquor. For final clarification,<br />

<strong>th</strong>e liquor is passed <strong>th</strong>rough a separator ,where <strong>th</strong>e residual insoluble particles are removed.<br />

Subsequently, <strong>th</strong>is desilicated bl<strong>ac</strong>k liquor is <strong>th</strong>en burned in <strong>th</strong>e conventional way. The optimum<br />

pH value is between 9 and 10. The corresponding specific flue gas rate at a CO 2 concentration<br />

<strong>of</strong> 6-8% is in <strong>th</strong>e range <strong>of</strong> 50 to 150 m 3 gas (at NTP) per m 3 <strong>of</strong> bl<strong>ac</strong>k liquor. Irrespective <strong>of</strong> <strong>th</strong>e<br />

silica content <strong>of</strong> <strong>th</strong>e incoming bl<strong>ac</strong>k liquor, which typically is <strong>of</strong> <strong>th</strong>e order <strong>of</strong> 1% (by weight),<br />

total silica contents <strong>of</strong> 0.05% by weight were attained downstream <strong>of</strong> <strong>th</strong>e separator. The silica<br />

extr<strong>ac</strong>ted from <strong>th</strong>e bl<strong>ac</strong>k liquor, toge<strong>th</strong>er wi<strong>th</strong> some alkali and organic matter, forms a sludge<br />

which is discharged from <strong>th</strong>e decanter at a DS content <strong>of</strong> 30-40%, and burnt in a fuel-oil-fired<br />

incinerator. Elution <strong>of</strong> <strong>th</strong>e alkali from <strong>th</strong>e ash wi<strong>th</strong> water, followed by filtering and drying, yields<br />

almost white silica granulates, which can be used as a filler in paper making.


Production Processes 9<br />

B. Use <strong>of</strong> bl<strong>ac</strong>k liquor as fertilizers<br />

Potassium fertilizer<br />

A potassium alkaline sulfite process can be used to produce <strong>th</strong>e chemical pulp. The pulping<br />

bl<strong>ac</strong>k liquor as well as ble<strong>ac</strong>hing effluent <strong>of</strong> alkaline or neutral sulfite may be collected and<br />

evaporated to obtain a salable liquid fertilizer product, (UNEP IE/PAC, 1992). Solid<br />

organo-potassium fertilizer can also be prepared (ANONYMOUS , 1982).<br />

Ammonia fertilizer<br />

Ano<strong>th</strong>er new process <strong>of</strong> ammonium bisulfite straw pulp has been popularized in many small<br />

size paper mills. By <strong>th</strong>is process, its wastewater can be directly used for farm irrigation as<br />

ammonia fertilizer (WANG YANJIA, 1995).<br />

2.3 Fiber processing line<br />

The fiber processing line employs washing <strong>of</strong> <strong>th</strong>e fibers and separation <strong>of</strong> contaminants from<br />

<strong>th</strong>e raw fibers in a cascaded counter-current process to produce <strong>th</strong>e concentrated pulp. The<br />

remaining liquid is called <strong>th</strong>e weak bl<strong>ac</strong>k liquor.<br />

2.4 Ble<strong>ac</strong>hing <strong>of</strong> pulp<br />

Chemical pulping, especially <strong>th</strong>e Kraft process, produces dark colored pulp owing to a number<br />

<strong>of</strong> f<strong>ac</strong>tors, among which are: remaining lignin, wood components which make paper turn yellow<br />

and brittle, and resinous bark as well as knot particles which leave tiny dark spots on <strong>th</strong>e paper.<br />

In order to obtain white and strong paper, <strong>th</strong>ese constituents should be removed fur<strong>th</strong>er by<br />

ble<strong>ac</strong>hing operations. Ble<strong>ac</strong>hing is a successive process involving multiple steps (normally 4-6)<br />

consisting <strong>of</strong> several oxidation stages (one or two alkaline). It utilizes various chemical agents,<br />

such as chlorine, sodium hydroxide, sodium hypochlorite and chlorine dioxide. Sulfite pulp<br />

needs less ble<strong>ac</strong>hing agents <strong>th</strong>an sulfate pulp.<br />

According to S DERGREN (1993), <strong>th</strong>ere are two types <strong>of</strong> ble<strong>ac</strong>hing sequences: conventional<br />

and modern ble<strong>ac</strong>hing processes (Figure 2.4). The conventional ble<strong>ac</strong>hing technique consists <strong>of</strong><br />

six stages in which chlorine gas is <strong>th</strong>e dominating delignifying agent whereas chlorine dioxide is<br />

used only in <strong>th</strong>e final ble<strong>ac</strong>hing stage. The amount <strong>of</strong> chlorine in <strong>th</strong>e first ble<strong>ac</strong>hing stage is<br />

about 50 to 70 kg per ton <strong>of</strong> pulp. The modern ble<strong>ac</strong>hing technique has been developed since<br />

<strong>th</strong>e mid 1970’s in Sweden. It aims to avoid <strong>th</strong>e discharge <strong>of</strong> chlorinated organic matter from <strong>th</strong>e<br />

ble<strong>ac</strong>hing plant. In modern ble<strong>ac</strong>hing technology, oxygen delignification is used; <strong>th</strong>e charge <strong>of</strong><br />

chlorine in <strong>th</strong>e first ble<strong>ac</strong>hing stage has gradually been reduced by <strong>th</strong>e introduction <strong>of</strong> low<br />

multiple chlorination and by a gradual substitution <strong>of</strong> chlorine by chlorine dioxide to totally<br />

eliminate <strong>th</strong>e use <strong>of</strong> elemental chlorine as <strong>th</strong>e ble<strong>ac</strong>hing agent.


10 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Figure 2.4 Scheme <strong>of</strong> conventional and modern ble<strong>ac</strong>hing sequence


Production Processes 11<br />

2.5 Chemical Plant<br />

Many pulp and paper mills have <strong>th</strong>eir own chemical plants where caustic soda and chlorine are<br />

produced <strong>th</strong>rough electrolysis in diaphragm cells, and calcium hypochlorite is produced from<br />

lime, H 2O, and Cl 2.<br />

2.6 Manuf<strong>ac</strong>turing Process <strong>of</strong> Paper<br />

In <strong>th</strong>is process <strong>th</strong>e pulp is converted into paper. The first stage <strong>of</strong> paper making operation is <strong>th</strong>e<br />

stock preparation. The fibers to be included in <strong>th</strong>e stock are heated and mixed. Different<br />

chemicals and fillers such as aluminum sulfate, clay and starch are also added to <strong>th</strong>e pulp stock<br />

for enhancement <strong>of</strong> certain properties <strong>of</strong> <strong>th</strong>e paper or board. The stock is <strong>th</strong>en pumped to <strong>th</strong>e<br />

paper m<strong>ac</strong>hine system where it is screened and finally brought to <strong>th</strong>e paper-forming m<strong>ac</strong>hine<br />

itself. In <strong>th</strong>e paper m<strong>ac</strong>hine, <strong>th</strong>e pulp sheet is dewatered on a fine mesh wire, pressed in several<br />

roll presses and air-dried in a semi-heated pulp dryer section. The paper making process is<br />

illustrated in Figure 2.5.<br />

Figure 2.5 Overall paper making process


12 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Recovery processes in <strong>th</strong>e paper mill attempt to recover <strong>th</strong>e washed out fibers and fillers. These<br />

processes are based on sedimentation and floatation principles. Conical or o<strong>th</strong>er sedimentation<br />

tanks are used to separate <strong>th</strong>e suspended solid. Floatation devices are revolving, cylindrical,<br />

perforated screens or filters to remove <strong>th</strong>e suspended solid in <strong>th</strong>e form <strong>of</strong> a mat which is<br />

subsequently scraped <strong>of</strong>f <strong>th</strong>e drum and returned to <strong>th</strong>e paper making stock system.<br />

The use <strong>of</strong> wastepaper as a raw material for paper production is being emphasized nowadays.<br />

This process requires <strong>th</strong>e de-inking <strong>of</strong> <strong>th</strong>e waste paper. The de-inking process has two main<br />

steps (<strong>th</strong>e flotation process and <strong>th</strong>e washing process) and employs various equipment, like pulp<br />

shredder, drum screen, high density cleaner, floatater (closed injection floatater, Sweetmark<br />

floatater, and Lamort floatater), pressurized screen and washer.<br />

When waste newsprint paper is stored for a short period, <strong>th</strong>e ink carrier on <strong>th</strong>e wastepaper is<br />

not sufficiently dried. However, it is absorbed by <strong>th</strong>e fiber only. Under <strong>th</strong>e <strong>ac</strong>tion <strong>of</strong> chemical<br />

reagents and under conditions <strong>of</strong> suitable temperature and consistency, <strong>th</strong>e carrier is saponified.<br />

The ink is dispersed easily and <strong>th</strong>e pigment is also released easily. The pigment, which consists<br />

<strong>of</strong> carbon bl<strong>ac</strong>k, usually forms good particles under <strong>th</strong>e treatment <strong>of</strong> pulp shredder. If waste<br />

paper has been stored for a long time, <strong>th</strong>e ink carriers are solidified due to drying and aging. In<br />

<strong>th</strong>is case, an increased quantity and density <strong>of</strong> de-inking chemical (such as NaOH) must be<br />

added and re<strong>ac</strong>tion temperature and re<strong>ac</strong>tion time should be increased so <strong>th</strong>at <strong>th</strong>e ink can be<br />

saponified. Shredding <strong>of</strong> <strong>th</strong>e wastepaper and putting it in <strong>th</strong>e de-inking chemical are done in<br />

high density pulp shredder, in which <strong>th</strong>e waste newsprint paper is soaked, osmosed, absorbed<br />

and expanded by <strong>th</strong>e solution <strong>of</strong> de-inking chemicals. The main chemicals used in de-inking<br />

process are NaOH and formic <strong>ac</strong>id (HCOOH).


Energy Issues in <strong>th</strong>e Pulp and Paper Industry 13<br />

3. ENERGY ISSUES IN PULP AND PAPER INDUSTRY<br />

3.1 Typical Energy Consumption Patterns<br />

The primary energy sources used in <strong>th</strong>e pulp and paper industry are <strong>th</strong>ermal energy in <strong>th</strong>e<br />

form <strong>of</strong> steam and mechanical energy converted from electricity. The <strong>th</strong>ermal energy<br />

<strong>ac</strong>counts for about 70-80% <strong>of</strong> <strong>th</strong>e total primary energy and is mainly used in pulping and<br />

drying processes. The process steam is generated from waste raw materials, concentrated<br />

bl<strong>ac</strong>k liquor and o<strong>th</strong>er fuels such as coal, fuel oil and gas. In <strong>th</strong>e pulp and paper mills, onsite<br />

electricity generation typically ranges from 0-60% <strong>of</strong> <strong>th</strong>e total power consumption.<br />

The energy consumption <strong>of</strong> a pulp and paper mill depends on <strong>th</strong>e raw materials used, type<br />

<strong>of</strong> pulping process and <strong>th</strong>e degree and type <strong>of</strong> final products. The typical specific energy<br />

consumption values <strong>of</strong> different paper-making processes are shown in Figure 3.1.<br />

GJ/ton <strong>of</strong> Paper Products<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

Acid Sulfite<br />

4%<br />

25%<br />

17.5%<br />

8.5%<br />

45%<br />

Kraft<br />

4%<br />

24.5%<br />

17%<br />

15.5%<br />

39%<br />

Semi-<br />

Chemical<br />

3.5%<br />

24%<br />

16.5%<br />

10.5%<br />

45.5%<br />

Groundwood<br />

3.5%<br />

25.5%<br />

17.5%<br />

3.5%<br />

50%<br />

Pulping Ble<strong>ac</strong>hing Paperforming Drying and finishing O<strong>th</strong>ers<br />

Thermomechanical<br />

Figure 3.1 Typical energy consumption <strong>of</strong> paper-making processes<br />

26.5%<br />

From Figure 3.1, it can be seen <strong>th</strong>at <strong>th</strong>e highest energy consumer in a pulp and paper mill is<br />

<strong>th</strong>e pulping process. The average specific energy consumption <strong>of</strong> pulping process is low in<br />

industrialized countries because <strong>of</strong> <strong>th</strong>e higher percentage <strong>of</strong> waste-paper pulp in total pulp<br />

produced. The specific energy consumption <strong>of</strong> waste-paper pulp is about 3 times less <strong>th</strong>an<br />

<strong>th</strong>at <strong>of</strong> wood pulp.<br />

3.5%<br />

18%<br />

4%<br />

48%


14 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

The average specific electricity consumption <strong>of</strong> pulp and paper industry is 1000-1300 kWh<br />

per ton <strong>of</strong> paper products. The percentage <strong>of</strong> total electrical power consumed in different<br />

stages <strong>of</strong> a typical paper manuf<strong>ac</strong>turing process is shown in Figure 3.2.<br />

11%<br />

22%<br />

13%<br />

12%<br />

2%<br />

Paperforming Pulping Chemical plant<br />

Boiler house Water treatment O<strong>th</strong>ers<br />

Figure 3.2 Breakdown <strong>of</strong> electricity consumption in an integrated mill<br />

The temperature level <strong>of</strong> process steam <strong>of</strong> a pulp and paper mill is normally below 200°C.<br />

The typical specific steam requirement is 8-12 tons per ton <strong>of</strong> paper products. The<br />

breakdown <strong>of</strong> process steam is given in Figure 3.3.<br />

5%<br />

21%<br />

33%<br />

Pulping Ble<strong>ac</strong>hing<br />

Hot watermaking Drying<br />

O<strong>th</strong>ers<br />

1%<br />

40%<br />

40%<br />

Figure 3.3 Breakdown <strong>of</strong> process steam in an integrated mill


Energy Issues in <strong>th</strong>e Pulp and Paper Industry 15<br />

3.2 Energy Efficient Measures<br />

As mentioned earlier, <strong>th</strong>e overall energy requirement <strong>of</strong> a pulp and paper mill can be<br />

<strong>th</strong>eoretically met by waste materials and concentrated bl<strong>ac</strong>k liquor. Therefore, <strong>th</strong>e<br />

objectives <strong>of</strong> energy conservation measures in <strong>th</strong>e pulp and paper industry are to reduce <strong>th</strong>e<br />

purchased energy and to recover as much energy from <strong>th</strong>e internal waste fuels as possible.<br />

3.2.1 Short term measures<br />

The immediate <strong>ac</strong>tions which can be taken wi<strong>th</strong>out substantial investment to <strong>ac</strong>hieve a<br />

certain level <strong>of</strong> energy savings in pulp and paper industry are:<br />

- inspection to encourage conservation <strong>ac</strong>tivity<br />

- excess air and flue gas temperature control<br />

- recovery <strong>of</strong> heat from boiler blowdown<br />

- proper insulation <strong>of</strong> steam lines<br />

- power f<strong>ac</strong>tor improvement <strong>of</strong> electric motors<br />

- ensuring an efficient washing (to minimize <strong>th</strong>e dilution <strong>of</strong> bl<strong>ac</strong>k liquor)<br />

- recovery <strong>of</strong> heat from extr<strong>ac</strong>ted bl<strong>ac</strong>k liquor after cooking<br />

- recovery <strong>of</strong> heat from condensate <strong>of</strong> drying process (about 5% <strong>of</strong> fuel can be<br />

saved)<br />

3.2.2 Medium term measures<br />

The medium term measures include modifications in processes and materials, recovery <strong>of</strong><br />

waste heat and self power generation wi<strong>th</strong> moderate to large investments.<br />

3.2.2.1 Measures on processed materials<br />

(i) Higher percentage <strong>of</strong> waste-paper pulp<br />

The recycling <strong>of</strong> more waste paper in pulping can lead to not only energy saving but also<br />

conservation <strong>of</strong> forest and environment. An increase in <strong>th</strong>e percentage <strong>of</strong> waste-paper pulp<br />

by 10% can save about 6.5% <strong>of</strong> energy required for pulping process.<br />

(ii) Recovery <strong>of</strong> chemicals<br />

The amount <strong>of</strong> chemicals recovered in pulping process has an effect on <strong>th</strong>e overall specific<br />

energy consumption <strong>of</strong> <strong>th</strong>e pulp and paper industry. Al<strong>th</strong>ough <strong>th</strong>e chemical recovery rate is<br />

usually high in <strong>th</strong>e larger mills (over 90%), <strong>th</strong>at <strong>of</strong> medium and small mills are low, typically<br />

50-70%. Therefore, proper chemical recovery systems should be installed in <strong>th</strong>e pulp and<br />

paper mills.


16 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

The recovery <strong>of</strong> chemical products by a membrane process, particularly using mineral<br />

membrane <strong>th</strong>rough ultrafiltration, can result in higher recovery rate and less pollution.<br />

Al<strong>th</strong>ough <strong>th</strong>e membrane process consumes electricity required by <strong>th</strong>e pumps to pressurize<br />

<strong>th</strong>e liquid and to circulate it, cogenerated electricity (elaborated later) can support <strong>th</strong>e case<br />

for ultrafiltration.<br />

3.2.2.2 Self energy production<br />

(i) Cogeneration<br />

Cogeneration is a promising technology for better utilization <strong>of</strong> energy sources if process<br />

steam demand is high. Therefore, <strong>th</strong>e pulp and paper industry has a high potential for<br />

application <strong>of</strong> cogeneration. For <strong>th</strong>e high pressure steam systems (60-80 bar), it is possible<br />

to generate excess electricity by as much as 600 kWh per ton <strong>of</strong> paper, which could be sold<br />

to <strong>th</strong>e grid.<br />

The generation <strong>of</strong> surplus electricity is <strong>of</strong> no interest to <strong>th</strong>e industry if <strong>th</strong>e regulation in <strong>th</strong>e<br />

country does not permit <strong>th</strong>e selling <strong>of</strong> <strong>th</strong>is electricity to <strong>th</strong>e grid. As a consequence <strong>of</strong> such<br />

a case, <strong>th</strong>e upper limit is an electrical-match process: <strong>th</strong>e maximum amount <strong>of</strong> electricity<br />

generated is <strong>th</strong>e same as <strong>th</strong>at needed by <strong>th</strong>e f<strong>ac</strong>tory. The pay-b<strong>ac</strong>k period <strong>of</strong> cogeneration<br />

system is around 3-5 years.<br />

(ii) Me<strong>th</strong>anogenesis<br />

The technology <strong>of</strong> me<strong>th</strong>ane generation from organic wastes <strong>th</strong>rough anaerobic digestion<br />

permits at <strong>th</strong>e same time energy recovery and reduction in environmental pollution. The<br />

me<strong>th</strong>anogenesis can compete wi<strong>th</strong> o<strong>th</strong>er waste treatment processes because <strong>of</strong> its potential<br />

for energy production. As an example, <strong>th</strong>e anaerobic digestion process can produce energy<br />

<strong>of</strong> <strong>th</strong>e order <strong>of</strong> 6.4 GJ per ton <strong>of</strong> paper and <strong>th</strong>e pay-b<strong>ac</strong>k period is about 4 years.<br />

3.2.2.3 Modifications in <strong>th</strong>e sub-processes<br />

(i) Conversion <strong>of</strong> batch to continuous digester<br />

Up to 40% <strong>of</strong> steam consumption can be saved by converting <strong>th</strong>e pulping process from<br />

batch to continuous. The continuous pulping can also <strong>of</strong>fer steady recovery <strong>of</strong> heat from<br />

<strong>th</strong>e outgoing materials <strong>of</strong> <strong>th</strong>e digester.<br />

(ii) Mechanical vapor compression<br />

Large amounts <strong>of</strong> energy (in <strong>th</strong>e form <strong>of</strong> steam) are required for concentration <strong>of</strong> bl<strong>ac</strong>k<br />

liquor from 10 to 60% before firing in a heat recovery boiler. This is <strong>ac</strong>hieved<br />

conventionally in a multi-effect evaporator where <strong>th</strong>e vapors from last effect are finally<br />

condensed in a surf<strong>ac</strong>e condenser. Energy <strong>th</strong>us transferred to cooling water cannot<br />

normally be put to useful purpose, especially in <strong>th</strong>e hot tropical climate, due to its lower<br />

heat content.


Energy Issues in <strong>th</strong>e Pulp and Paper Industry 17<br />

The use <strong>of</strong> mechanical vapor recompression (MVR) is suitable for partial concentration (up<br />

to about 23%) <strong>of</strong> bl<strong>ac</strong>k liquor by repl<strong>ac</strong>ing <strong>th</strong>e first stages <strong>of</strong> multi-effect evaporators. The<br />

energy demand <strong>of</strong> bl<strong>ac</strong>k liquor concentration process can be reduced by 70-80% by<br />

pr<strong>ac</strong>tically repl<strong>ac</strong>ing <strong>th</strong>e direct distillation wi<strong>th</strong> MVR. The installation <strong>of</strong> MVR would be<br />

economically more attr<strong>ac</strong>tive wi<strong>th</strong> <strong>th</strong>e availability <strong>of</strong> cogenerated electricity. The pay-b<strong>ac</strong>k<br />

period <strong>of</strong> MVR installation is site specific and varies from 1.5 to 6 years.<br />

(iii) V<strong>ac</strong>uum pump in paperforming<br />

The repl<strong>ac</strong>ement <strong>of</strong> v<strong>ac</strong>uum pump in paperforming can save about 25% <strong>of</strong> electricity<br />

consumed.<br />

(iv) Change in pressing<br />

The use <strong>of</strong> longer nips or hot press which is heated by waste streams can save <strong>th</strong>e steam<br />

consumption <strong>of</strong> drying process by 15-20%.<br />

3.2.2.4 Waste heat recovery<br />

(i) Heat pump hot water system<br />

In <strong>th</strong>e drying process, <strong>th</strong>e water contained in <strong>th</strong>e paper is evaporated and is normally<br />

rejected to <strong>th</strong>e atmosphere. The energy content <strong>of</strong> evaporated water can be recovered by a<br />

heat pump to produce hot water for washing <strong>of</strong> <strong>th</strong>e pulp. This system can save about 1.3<br />

MJ per ton <strong>of</strong> paper.<br />

(ii) Flash steam recovery in drying process<br />

The typical pressure <strong>of</strong> steam used in <strong>th</strong>e drying process is 3-4 bar. The condensate coming<br />

from <strong>th</strong>e dryers is returned to <strong>th</strong>e condensate tank where some amount is flashed into <strong>th</strong>e<br />

environment. The flash steam can be recovered for fur<strong>th</strong>er use in <strong>th</strong>e processes by one <strong>of</strong><br />

<strong>th</strong>e following systems:<br />

- absorption heat transformer (energy saved = 200 MJ/ton <strong>of</strong> paper)<br />

- vapor compression heat pump (energy saved = 600 MJ/ton <strong>of</strong> paper)<br />

- ejecto-compressor (energy saved = 600 MJ/ton <strong>of</strong> paper)<br />

3.2.3 Long term measures<br />

The long term measures include better site arrangement <strong>of</strong> <strong>th</strong>e industry, excess power<br />

generation for <strong>th</strong>e grid, adaptation <strong>of</strong> <strong>th</strong>e new emerging processes and computerization <strong>of</strong><br />

<strong>th</strong>e manuf<strong>ac</strong>turing processes.


18 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

(i) Interconnected f<strong>ac</strong>tories: sugar mills and pulp mills<br />

The sugar industry, due to its generation <strong>of</strong> bagasse, is a very important source <strong>of</strong> raw<br />

material for pulping. By employing cogeneration, a well-designed sugar plant is normally<br />

able to produce its electricity while a considerable amount <strong>of</strong> excess bagasse still remains.<br />

This bagasse can be burnt in order to produce electricity if its buy-b<strong>ac</strong>k by <strong>th</strong>e grid is<br />

permitted. But bagasse can be used for pulping too. The coupling <strong>of</strong> a paper mill and a<br />

sugar plant is <strong>th</strong>erefore interesting.<br />

There are several modes <strong>of</strong> coupling <strong>th</strong>e two plants. Some possibilities are:<br />

- The sugar plant produces its electricity and sells excess bagasse to <strong>th</strong>e pulp plant.<br />

The latter produces electricity <strong>th</strong>rough cogeneration and combustion <strong>of</strong> bl<strong>ac</strong>k<br />

liquor.<br />

- Several sugar plants providing extra bagasse to one pulp plant; <strong>th</strong>e sugar mills and<br />

<strong>th</strong>e pulp mill are completely independent as far as energy use is concerned.<br />

- A pool is formed in order to manage <strong>th</strong>e energy usage jointly by <strong>th</strong>e sugar and<br />

pulp mills wi<strong>th</strong> any surplus electricity eventually sold b<strong>ac</strong>k to <strong>th</strong>e grid.<br />

This kind <strong>of</strong> management is very attr<strong>ac</strong>tive from <strong>th</strong>e point <strong>of</strong> view <strong>of</strong> appropriate use <strong>of</strong><br />

raw material and energy, and regional development, but several constraints must be taken<br />

into <strong>ac</strong>count:<br />

- Seasonal working conditions <strong>of</strong> <strong>th</strong>e sugar industry<br />

- Competition between <strong>th</strong>e buy-b<strong>ac</strong>k rate <strong>of</strong> electricity by <strong>th</strong>e grid (if allowed)<br />

and <strong>th</strong>e benefit <strong>of</strong> producing paper (wi<strong>th</strong> additional investment)<br />

- Technical problems related to pulping from bagasse, etc.<br />

(ii) Excess power generation<br />

The pulp and paper industry <strong>of</strong>fers <strong>th</strong>e pr<strong>ac</strong>tice <strong>of</strong> industrial cogeneration since <strong>th</strong>e<br />

demand <strong>of</strong> process steam is high. Since decentralization <strong>of</strong> power sector is beneficial bo<strong>th</strong><br />

at <strong>th</strong>e m<strong>ac</strong>ro and micro levels, excess power generation from <strong>th</strong>e pulp and paper industry<br />

should be a long term objective for better utilization <strong>of</strong> energy sources.<br />

(iii) Adaptation <strong>of</strong> new emerging processes<br />

The pulp and paper industry is one <strong>of</strong> <strong>th</strong>e most pollution producers in <strong>th</strong>e industrial sector.<br />

New pulping processes are still emerging (mentioned in <strong>th</strong>e following section) as clean<br />

technologies. Therefore adaptation <strong>of</strong> new emerging processes will enhance <strong>th</strong>e integrated<br />

appro<strong>ac</strong>h to energy and environment.


Energy Issues in <strong>th</strong>e Pulp and Paper Industry 19<br />

(iv) Computerization<br />

Like o<strong>th</strong>er industries, computer-control <strong>of</strong> processes in <strong>th</strong>e pulp and paper industry can<br />

result in a better management <strong>of</strong> all <strong>th</strong>e resources. The computerization will lead to <strong>th</strong>e<br />

reduction in fuel cost, chemicals, electrical charge and personnel services, etc., and<br />

guarantee a better quality pulp.<br />

As an example, <strong>th</strong>e pay-b<strong>ac</strong>k period <strong>of</strong> <strong>th</strong>e computer-controlled system in a Kraft pulp mill<br />

wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 300 tons <strong>of</strong> pulp per day was estimated as less <strong>th</strong>an 6 years.<br />

3.3 New Energy Efficient Technologies for Papermaking<br />

Among <strong>th</strong>e new emerging processes, ozonation, BG-TAG-LAMORT process and<br />

organocell process are <strong>th</strong>e <strong>th</strong>ree most promising options.<br />

(i) Ozonation<br />

Ozone has a very high oxidizing and disinfecting power. Its use in water treatment is well<br />

established and is gradually increasing. The development <strong>of</strong> integrating an ozonizing stage<br />

into <strong>th</strong>e ble<strong>ac</strong>hing sequences in <strong>th</strong>e pulp and paper industry, however, is new and has been<br />

driven by environmental, economic and energy-related considerations. Energy requirement<br />

for ozone production has been consistently reduced during <strong>th</strong>e last ten years. Only 10<br />

kWh is now needed for <strong>th</strong>e production <strong>of</strong> 1 kg <strong>of</strong> ozone instead <strong>of</strong> <strong>th</strong>e 20 kWh required in<br />

<strong>th</strong>e past.<br />

Ozone is an oxide but it is a clean one. It can be used anytime <strong>th</strong>ere is a requirement <strong>of</strong> an<br />

oxidizer. Its uses for <strong>th</strong>e pulp industry can be <strong>th</strong>rough at least <strong>th</strong>ree options:<br />

- by repl<strong>ac</strong>ing chlorine as an environmentally safe ble<strong>ac</strong>hing agent in <strong>th</strong>e chemical<br />

process. The re<strong>ac</strong>tion can be carried out at room temperature and atmospheric<br />

pressure; 1% <strong>of</strong> ozone increases <strong>th</strong>e brightness <strong>of</strong> <strong>th</strong>e pulp from 45 up to 75 ISO<br />

in a single stage.<br />

- by re<strong>ac</strong>ting wi<strong>th</strong> lignin in <strong>th</strong>e <strong>th</strong>ermomechanical process and modifying its<br />

structure. About 2% <strong>of</strong> ozone appears to be able to keep a high yield <strong>of</strong> <strong>th</strong>e<br />

<strong>th</strong>ermomechanical process (around 90%) providing a streng<strong>th</strong> comparable to <strong>th</strong>at<br />

<strong>of</strong> <strong>th</strong>e chemical pulp.<br />

- in <strong>th</strong>e pollution abatement process, a specific quality <strong>of</strong> ozone for oxidizing at<br />

different levels can be used for classical type <strong>of</strong> water treatment, but it can also<br />

contribute to help in rapid flocculation or <strong>th</strong>e deterioration <strong>of</strong> microorganisms,<br />

for example.


20 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

An oxygen recycled process is also available, permitting considerable decrease in oxygen<br />

requirement. Oxygen process, however, requires to be carried out at high pressure and<br />

temperature.<br />

(ii) BG-TAG-LAMORT process<br />

One <strong>of</strong> <strong>th</strong>e main sources <strong>of</strong> pollution <strong>of</strong> <strong>th</strong>e pulp industry lies in <strong>th</strong>e cooking process as it<br />

needs chemical agents and a large quantity <strong>of</strong> water. The BG-TAG-LAMORT process<br />

uses a dry cooker to avoid <strong>th</strong>is problem. The raw material is soaked in a minimum amount<br />

<strong>of</strong> solution, so <strong>th</strong>at <strong>th</strong>e volume <strong>of</strong> bl<strong>ac</strong>k liquor is reduced and its concentration is high. The<br />

volume <strong>of</strong> water required can in f<strong>ac</strong>t be reduced 5 folds. The bl<strong>ac</strong>k liquor can be<br />

transferred directly to <strong>th</strong>e furn<strong>ac</strong>e <strong>of</strong> a boiler for combustion.<br />

This process is particularly suitable for small and medium size production plants and is well<br />

suited for raw materials such as bagasse. A plant producing 60,000 t/year <strong>of</strong> pulp costs<br />

about 80 million US dollars. The process is based on a 50 t/day module.<br />

(iii) Organocell process<br />

The objective is <strong>th</strong>e same as for <strong>th</strong>e o<strong>th</strong>er processes: reducing <strong>th</strong>e pollution as a result <strong>of</strong><br />

<strong>th</strong>e presence <strong>of</strong> sulfur in wastes.<br />

The organocell process extr<strong>ac</strong>ts <strong>th</strong>e lignin by alcohol, and sodium hydroxide. The<br />

advantage is a non-degradation <strong>of</strong> lignin. The interest lies in <strong>th</strong>e possibility <strong>of</strong> using lignin<br />

for producing chemical products such as polymers and derivatives. This process can be<br />

seen in <strong>th</strong>e light <strong>of</strong> a new biomass chemistry. The energy consumption is at <strong>th</strong>e level <strong>of</strong><br />

solvent regeneration.<br />

3.4 Concluding Remarks on Energy Issues<br />

The management pr<strong>ac</strong>tices to obtain better energy efficiency in <strong>th</strong>e pulp and paper industry<br />

are illustrated in Figure 3.4.<br />

The regular energy conservation pr<strong>ac</strong>tices such as insulation maintenance <strong>of</strong> steam lines,<br />

excess air control, checking <strong>of</strong> steam leakage, etc., can save certain amount <strong>of</strong> energy<br />

consumption, since <strong>th</strong>e pulp and paper industry consumes a large amount <strong>of</strong> steam. The<br />

temperature levels <strong>of</strong> processes are normally below 200°C. Therefore, application <strong>of</strong><br />

<strong>th</strong>ermal upgrading systems can <strong>of</strong>fer significant energy savings, especially in <strong>th</strong>e large mills.<br />

The higher recovery rate <strong>of</strong> chemicals and materials is also an important issue in <strong>th</strong>e pulp<br />

and paper industry for <strong>th</strong>e preservation <strong>of</strong> resources. Since <strong>th</strong>e full utilization <strong>of</strong> internal<br />

energy sources is <strong>th</strong>e major goal for higher energy efficiency, cogeneration and me<strong>th</strong>ane<br />

production would be beneficial bo<strong>th</strong> at <strong>th</strong>e plant and m<strong>ac</strong>ro levels.


Energy Issues in <strong>th</strong>e Pulp and Paper Industry 21<br />

Fuel<br />

(external + internal)<br />

Cogeneration<br />

Membrane<br />

Seperation<br />

Management Pr<strong>ac</strong>tices Benefits<br />

To<br />

Grid<br />

Thermal<br />

Upgrading<br />

Electricity<br />

Effluent<br />

Me<strong>th</strong>ane<br />

Production<br />

Ozonation<br />

- Rational use <strong>of</strong><br />

energy sources<br />

- Energy recovery<br />

- Depollution<br />

- Fibre recovery<br />

- Water<br />

recycling<br />

- Depollution<br />

- Chemical saving<br />

- Energy recovery<br />

- Water saving<br />

- Depollution<br />

- Energy Saving<br />

Figure 3.4. Management pr<strong>ac</strong>tices for better energy efficiency


22 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

4. SOURCES OF POLLUTION AND ITS MANAGEMENT<br />

4.1 Sources and Char<strong>ac</strong>teristics <strong>of</strong> Pollutants<br />

The major environmental problems in <strong>th</strong>e pulp and paper industry come from <strong>th</strong>e<br />

production <strong>of</strong> pulp. Different me<strong>th</strong>ods are used for pulp production. The specific<br />

environmental effects vary depending upon <strong>th</strong>e pulping process used. Mechanical pulping<br />

requires relatively small quantities <strong>of</strong> water for chipping and milling <strong>of</strong> <strong>th</strong>e fibers and <strong>th</strong>is<br />

water is only slightly polluted. On <strong>th</strong>e o<strong>th</strong>er hand, chemical pulping requires large quantities<br />

<strong>of</strong> water and causes severe water pollution. The use <strong>of</strong> chemical pulping is, <strong>th</strong>erefore,<br />

restricted to areas where a large receiving water body is available to absorb <strong>th</strong>e<br />

contaminants remaining after <strong>th</strong>e treatment <strong>of</strong> wastewater.<br />

Water-, air-, solid- and indirect pollutants are generated from <strong>th</strong>e different processes.<br />

Suspended solids and dissolved organic substances (including lignin) <strong>th</strong>at are not readily<br />

biodegradable are <strong>th</strong>e major pollutants. Most air pollution problems are related to sulfur<br />

and sulfur dioxide and o<strong>th</strong>er sulfur compounds.<br />

4.1.1 Sources <strong>of</strong> wastewater generated<br />

The sources and char<strong>ac</strong>teristics <strong>of</strong> wastewater in <strong>th</strong>e pulp and paper industry are as follows:<br />

(i) Chipping<br />

Wastewater from <strong>th</strong>e chipping process contains coarse materials, i.e. barks and chips.<br />

(ii) Bl<strong>ac</strong>k liquor<br />

Bl<strong>ac</strong>k liquor is <strong>th</strong>e wastewater from <strong>th</strong>e digestion and <strong>th</strong>e rinsing process.<br />

(iii) Evaporator condensate<br />

The condensate from <strong>th</strong>e evaporator in <strong>th</strong>e chemical recovery process contains odorous<br />

alkyl sulfides, which is treated by steam stripping before being transferred to <strong>th</strong>e treatment<br />

plant. This wastewater is rich in <strong>ac</strong>etate and me<strong>th</strong>anol and is usually treated wi<strong>th</strong> o<strong>th</strong>er<br />

wastewater.<br />

(iv) Wastewater from ble<strong>ac</strong>hing<br />

The most problematic wastewater generated in ble<strong>ac</strong>hed Kraft pulp (BKP) production is<br />

from <strong>th</strong>e ble<strong>ac</strong>hing process, especially in <strong>th</strong>e initial ble<strong>ac</strong>hing stages. It contains<br />

hard-biodegradable organics (such as lignin and hemicellulose), chlorinated organics and<br />

dioxin, and 2,3,7,8-tetr<strong>ac</strong>hlorodibenzo-p-dioxin (2,3,7,8-TCDD) compounds. Fur<strong>th</strong>ermore,<br />

it is highly colored wi<strong>th</strong> brown substances. The effluents not only have negative imp<strong>ac</strong>t on<br />

plant and animal life in <strong>th</strong>e receiving areas, but are also “persistent”, i.e., <strong>th</strong>ey bio-degrade<br />

very slowly.


Sources <strong>of</strong> Pollution and its Management in <strong>th</strong>e Pulp and Paper Industry 23<br />

(v) White water<br />

Wastewater from <strong>th</strong>e paper making process contains fine fibers and o<strong>th</strong>er solids such as<br />

fillers. The excess white water after fiber recovery is treated by coagulation/flocculation<br />

process and is discharged to <strong>th</strong>e treatment plant.<br />

4.1.2 Char<strong>ac</strong>teristics <strong>of</strong> wastewater generated<br />

The wastewater <strong>of</strong> pulp and paper effluents may contain dissolved organic compounds and<br />

chemicals used in <strong>th</strong>e process, fibers, fillers and additives, color, bark, ash and lime sludge.<br />

The dissolved compounds originate in pulping process, suspended solids are present in<br />

effluents from pr<strong>ac</strong>tically all stages and parts <strong>of</strong> <strong>th</strong>e industry. The suspended matter<br />

consists generally <strong>of</strong> fibers and bark residue, ash lime and clay. Dissolved organic<br />

substances include lignin, carbohydrates, organic <strong>ac</strong>ids and alcohol which, wi<strong>th</strong> <strong>th</strong>e<br />

exception <strong>of</strong> lignin, are readily biodegradable.<br />

Conventional parameters to quantify <strong>th</strong>e pollution load are biochemical oxygen demand<br />

(BOD 5), dry solids (DS) and pH. Toxic pollutants present are pent<strong>ac</strong>hlorophenol (PCP),<br />

trichlorophenol (TCP), zinc, chlor<strong>of</strong>orm, ble<strong>ac</strong>h plant derivatives, PCB-1 2 4 2, o<strong>th</strong>er<br />

pollutants, ammonia, color, resin, and <strong>ac</strong>ids.<br />

The effluent char<strong>ac</strong>teristics <strong>of</strong> different ble<strong>ac</strong>hed Kraft pulp mills in Sweden and Finland<br />

are shown in Table 4.1.<br />

Table 4.1. Effluent from ble<strong>ac</strong>hed Kraft pulp mills prior to external treatment<br />

Type <strong>of</strong> wood and <strong>Technology</strong><br />

S<strong>of</strong>t wood<br />

BOD7 kg/t<br />

COD<br />

kg/t<br />

SS<br />

kg/t<br />

TOCl<br />

kg/t<br />

<strong>Technology</strong> in Finland & Sweden 1970<br />

<strong>Technology</strong> in Finland 1988<br />

<strong>Technology</strong> in Sweden 1988<br />

Hard wood<br />

55<br />

24<br />

19<br />

190<br />

85<br />

65<br />

15<br />

11<br />

8<br />

>6<br />

5<br />

3.5<br />

<strong>Technology</strong> in Finland & Sweden 1970<br />

<strong>Technology</strong> in Finland 1988<br />

<strong>Technology</strong> in Sweden 1988<br />

60<br />

25<br />

25<br />

180<br />

75<br />

75<br />

28<br />

12<br />

9<br />

4<br />

2.5<br />

2.5<br />

Source: Adapted from BONSOR et al, 1988<br />

The char<strong>ac</strong>teristic <strong>of</strong> de-inking wastewater from paper industry where waste paper is used<br />

as raw material is given in Table 4.2.


24 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 4.2. Char<strong>ac</strong>teristics <strong>of</strong> de-inking wastewater from waste paper mill<br />

Country Flow rate<br />

m 3 TSS BOD COD Product<br />

/ t kg / t kg / t kg / t<br />

Philippine paper mill 26 10.0 5.0 Newsprint<br />

German paper mill 10.5 4.7 10.5 Carton<br />

German paper mill 4.2 5.9 13.4 Testliner paper<br />

Source: Adapted from C. T. Tupas, 1995<br />

Char<strong>ac</strong>teristics <strong>of</strong> combined effluent <strong>of</strong> pulp and paper mills, and distribution <strong>of</strong> pollution<br />

load from different sections <strong>of</strong> pulp and paper mills are shown in Table 4.3.<br />

Table 4.3. Char<strong>ac</strong>teristics <strong>of</strong> combined effluent <strong>of</strong> pulp and paper mills and<br />

distribution <strong>of</strong> pollution load from different sections <strong>of</strong> a mill<br />

Item Small mill<br />

Large mill<br />

(Sastry et al.)<br />

(Subrahmanyam et al.)<br />

Produces 20 tons <strong>of</strong> paper Produces 2000 tons <strong>of</strong> paper<br />

Flow per day<br />

Color<br />

pH<br />

Total solids, mg /l<br />

Suspended solids mg /l<br />

COD mg /l<br />

BOD mg /l<br />

COD/BOD ratio<br />

Flow %<br />

Small<br />

Large<br />

BOD %<br />

Small<br />

Large<br />

Suspended Solid %<br />

Small<br />

Large<br />

per day<br />

330 m 3 / t<br />

-<br />

8.2-8.5<br />

-<br />

900-2000<br />

4300-5780<br />

680-1250<br />

3.9-5<br />

Item Digester<br />

section<br />

45.5<br />

9.75<br />

66<br />

32.5<br />

60<br />

3<br />

Ble<strong>ac</strong>hing<br />

section<br />

16.2<br />

27.8<br />

18.4<br />

32.5<br />

14.5<br />

1.35<br />

per day<br />

222 m 3 / t<br />

7800 units<br />

8.5-9.5<br />

4410<br />

3300<br />

716<br />

155<br />

4.6<br />

Paper mill<br />

section<br />

10.8<br />

16.7<br />

2<br />

1.43<br />

7.75<br />

3.4


Sources <strong>of</strong> Pollution and its Management in <strong>th</strong>e Pulp and Paper Industry 25<br />

4.1.3 Sources and char<strong>ac</strong>teristics <strong>of</strong> gaseous emissions<br />

Gaseous emissions <strong>of</strong> concern are <strong>th</strong>e discharges <strong>of</strong> <strong>th</strong>ose components considered as air<br />

pollutants and odorous components. These pollutants <strong>of</strong> <strong>th</strong>e pulping industry, especially<br />

from chemical pulping, are hydrogen sulfides, organic sulfide, SO x and NO x.<br />

The release <strong>of</strong> sulfur containing gases during Kraft digestion and burning <strong>of</strong> bl<strong>ac</strong>k liquor<br />

generates H 2S, a highly malodorous gas, SO 2, and various me<strong>th</strong>yl derivatives such as me<strong>th</strong>yl<br />

mercaptan (CH 3SH), dime<strong>th</strong>yl sulfide (CH 3) 2S, and dime<strong>th</strong>yl disulfide (CH 3-S-S-CH 3) .<br />

Odorous components as phenols and turpenes are liberated from all o<strong>th</strong>er pulping<br />

processes.<br />

4.1.4 Sources and char<strong>ac</strong>teristics <strong>of</strong> solid wastes<br />

The pulp and paper industry produces solid wastes which, depending on <strong>th</strong>e pulping<br />

process and <strong>th</strong>e chemical processing, consist <strong>of</strong> waste water sludge, ash, bark, woodwaste<br />

and paper. These wastes have high pollution potential and should be disposed <strong>of</strong> in<br />

controlled landfills to avoid le<strong>ac</strong>hing <strong>of</strong> <strong>th</strong>e sub-soil.<br />

4.2 Current Pollution Abatement Strategies and Technologies<br />

4.2.1 Water pollution control<br />

Pulp and paper mill wastes are treated by <strong>th</strong>e following processes:<br />

- Recovery processes.<br />

- Sedimentation and floatation to remove suspended matter.<br />

- Chemical precipitation to remove color and suspended and colloidal particulate<br />

matter.<br />

- Biological treatment to remove oxygen demanding matter/dissolved organic<br />

matter.<br />

The treatment <strong>of</strong> waste water may consist <strong>of</strong> all or a combination <strong>of</strong> some <strong>of</strong> <strong>th</strong>ese<br />

processes.<br />

(i) Recovery processes<br />

The recovery <strong>of</strong> <strong>th</strong>e process chemicals and fibers reduces <strong>th</strong>e pollution load to a great<br />

extent. Where <strong>th</strong>e economy permits, <strong>th</strong>e color bearing ‘bl<strong>ac</strong>k liquor’ is treated for <strong>th</strong>e<br />

recovery <strong>of</strong> chemicals. However, in <strong>th</strong>is process <strong>th</strong>e lignin is destroyed. The lignin may be<br />

recovered from <strong>th</strong>e bl<strong>ac</strong>k liquor by precipitation and by <strong>ac</strong>idulation wi<strong>th</strong> ei<strong>th</strong>er carbon<br />

dioxide or sulfuric <strong>ac</strong>id. These recovered lignins have got various uses in o<strong>th</strong>er industries.<br />

The alkali lignins <strong>of</strong> Kraft process may be used as a dispersing agent in various<br />

suspensions. Lignins may be used as raw materials for various o<strong>th</strong>er substances, e.g.<br />

dime<strong>th</strong>yl sulfur oxide, which is used as spinning solvent for poly<strong>ac</strong>rylonitrile fibers.<br />

Activated carbon may also be manuf<strong>ac</strong>tured from <strong>th</strong>e lignin recovered from bl<strong>ac</strong>k liquors.


26 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

The fibers in <strong>th</strong>e white water from <strong>th</strong>e paper mills are recovered ei<strong>th</strong>er by sedimentation or<br />

by floatation using forced air in <strong>th</strong>e tank.<br />

The recovery <strong>of</strong> lime from <strong>th</strong>e lime mud can be <strong>ac</strong>hieved by <strong>th</strong>e process <strong>of</strong> calcination.<br />

(ii) Chemical treatment for color removal<br />

The chemical coagulation for <strong>th</strong>e removal <strong>of</strong> color is found to be uneconomical. Attempts<br />

have been made to recover color from <strong>th</strong>e waste using <strong>th</strong>e lime sludge; <strong>th</strong>e results are not<br />

at all encouraging. “Massive Lime Treatment” process, developed by <strong>th</strong>e National Council for<br />

Stream Improvement in <strong>th</strong>e USA is said to be capable <strong>of</strong> removing about 90% <strong>of</strong> color and<br />

40 to 60% <strong>of</strong> BOD from <strong>th</strong>e waste. In <strong>th</strong>is process, <strong>th</strong>e entire quantity <strong>of</strong> lime, normally<br />

required for <strong>th</strong>e re-causticization <strong>of</strong> green liquor into white liquor, is allowed to re<strong>ac</strong>t wi<strong>th</strong><br />

<strong>th</strong>e colored waste effluent first. The color is absorbed by <strong>th</strong>e lime, and <strong>th</strong>e sludge after<br />

settling is used in recausticizing <strong>th</strong>e green liquor. The treatment <strong>of</strong> green liquor wi<strong>th</strong><br />

colored lime sludge results in <strong>th</strong>e formation <strong>of</strong> dark brown liquor, containing bo<strong>th</strong> desired<br />

cooking chemicals and color-producing components, like lignin. The lignin-bearing liquor<br />

is used as digested liquid, and <strong>th</strong>en is destroyed along wi<strong>th</strong> <strong>th</strong>e fresh lignins in <strong>th</strong>e<br />

subsequent operations <strong>of</strong> concentration and incineration in <strong>th</strong>e process <strong>of</strong> chemical<br />

recovery.<br />

In a study conducted by NEERI, it has been observed <strong>th</strong>at <strong>ac</strong>idic <strong>ac</strong>tivated carbon can<br />

remove up to 94% <strong>of</strong> <strong>th</strong>e color from <strong>th</strong>e pulp mill waste. However, pH <strong>of</strong> <strong>th</strong>e waste is<br />

required to be reduced to 3.0 before <strong>th</strong>is <strong>ac</strong>tivated carbon treatment.<br />

(iii) Physical treatment for clarification<br />

Mechanically cleaned circular clarifiers alone are capable <strong>of</strong> 70-80% removal <strong>of</strong> <strong>th</strong>e<br />

suspended solids from <strong>th</strong>e combined mill effluent. About 95 to 99% removal <strong>of</strong> settleable<br />

solids can be <strong>ac</strong>complished in <strong>th</strong>e clarifiers. However, <strong>th</strong>e BOD reduction is comparatively<br />

small and <strong>of</strong> <strong>th</strong>e order <strong>of</strong> 25-40% only. A surf<strong>ac</strong>e loading in <strong>th</strong>e order <strong>of</strong> 30 to 31<br />

m 3 /m 2 /day is found to be adequate for up to 79% removal <strong>of</strong> suspended solids and 52%<br />

removal <strong>of</strong> COD at a detention time <strong>of</strong> 30 minutes.<br />

The primary sludge produced in <strong>th</strong>e clarifiers can be <strong>th</strong>ickened to such a consistency in <strong>th</strong>e<br />

clarifier itself <strong>th</strong>at it can be easily dewatered mechanically.<br />

(iv) Biological treatment <strong>of</strong> <strong>th</strong>e waste<br />

Considerable reduction <strong>of</strong> BOD from <strong>th</strong>e waste can be <strong>ac</strong>complished in bo<strong>th</strong> conventional<br />

and low cost biological treatment processes. Some are also effective in <strong>th</strong>e reduction <strong>of</strong><br />

color from <strong>th</strong>e waste.


Sources <strong>of</strong> Pollution and its Management in <strong>th</strong>e Pulp and Paper Industry 27<br />

If sufficient area is available, <strong>th</strong>e waste stabilization ponds <strong>of</strong>fer <strong>th</strong>e cheapest means for<br />

treatment. Dep<strong>th</strong> <strong>of</strong> <strong>th</strong>ese ponds vary from 0.9 m to 1.5 m; <strong>th</strong>e detention period may vary<br />

from 12 to 30 days. A minimum <strong>of</strong> 85% removal <strong>of</strong> BOD is <strong>ac</strong>hievable, wi<strong>th</strong> a loading rate<br />

<strong>of</strong> up to 56 kg/hectare/day.<br />

Aerated lagoons are <strong>th</strong>e improved forms <strong>of</strong> <strong>th</strong>e stabilization ponds. They can be adopted to<br />

upgrade <strong>th</strong>e performance <strong>of</strong> already present quiescent stabilization ponds <strong>th</strong>at have become<br />

inadequate because <strong>of</strong> <strong>th</strong>e increased loading or more stringent receiving water criteria. The<br />

mechanical surf<strong>ac</strong>e aerators are <strong>th</strong>e most satisf<strong>ac</strong>tory oxygen transfer device. BOD<br />

reduction up to 50 to 95% can be <strong>ac</strong>hieved in <strong>th</strong>e aerated lagoons by varying nutrients feed,<br />

air supply and detention time (3 to 20 days), at <strong>th</strong>e loading range <strong>of</strong> 670 to 1340 kg <strong>of</strong> BOD<br />

per hectare per day. Aerated lagoons are employed, ei<strong>th</strong>er when <strong>th</strong>e effluent BOD is<br />

moderate (where a partial chemical recovery from <strong>th</strong>e bl<strong>ac</strong>k liquor is pr<strong>ac</strong>ticed), or as a<br />

polishing device. In one particular case, a detention period <strong>of</strong> 5 days was found adequate<br />

for 90% BOD removal; <strong>th</strong>e system rate constant was found to be 0.21/day. It may be<br />

noted <strong>th</strong>at <strong>th</strong>e pulp and paper mill waste does not contain necessary nutrients for <strong>th</strong>e<br />

b<strong>ac</strong>terial grow<strong>th</strong>, and hence nitrogen and phosphorous are to be added into <strong>th</strong>e lagoons in<br />

<strong>th</strong>e form <strong>of</strong> urea or ammonia and phosphoric <strong>ac</strong>id in a BOD:N:P ratio <strong>of</strong> 100:5:1. The<br />

nutrient addition is not necessary when a detention period <strong>of</strong> more <strong>th</strong>an 10-15 days are<br />

provided.<br />

Segregated strong waste or combined wastes may be well treated in Anaerobic lagoons wi<strong>th</strong><br />

nutrient supplement. A BOD loading <strong>of</strong> 0.048 kg/m 3 /day and a detention time <strong>of</strong> 20 days<br />

were found to be adequate for 72.5% removal <strong>of</strong> BOD in a particular case. In ano<strong>th</strong>er case,<br />

77.5% removal <strong>of</strong> BOD was reported at a detention time <strong>of</strong> 6-8 days and a loading <strong>of</strong> 0.017<br />

kg <strong>of</strong> BOD/m 3 /day. Aerated lagoons may be employed after <strong>th</strong>e anaerobic lagoons where<br />

a high effluent quality is required. The system rate constant in <strong>th</strong>e aerated lagoons,<br />

preceded by <strong>th</strong>e anaerobic lagoons may be taken as 0.15-0.17 per day. A detention period<br />

<strong>of</strong> 7 days in <strong>th</strong>ese aerated lagoons are adequate.<br />

Activated sludge process is <strong>th</strong>e most satisf<strong>ac</strong>tory and sophisticated system for <strong>th</strong>e effluent<br />

treatment. Instead <strong>of</strong> porous diffusers, <strong>th</strong>e surf<strong>ac</strong>e aerators are <strong>of</strong>ten suggested as <strong>th</strong>e<br />

oxygen transfer device in <strong>th</strong>e aeration tanks treating pulp and paper mill effluent. It is<br />

reported <strong>th</strong>at about 80 to 90% BOD removal can be <strong>ac</strong>hieved wi<strong>th</strong> a loading rate <strong>of</strong> 0.2 to<br />

0.3 kg <strong>of</strong> BOD per kg <strong>of</strong> MLSS for a detention time <strong>of</strong> 3 to 9 hours, MLSS concentration<br />

<strong>of</strong> 2000-4000 mg/l, recirculation ratio <strong>of</strong> 0.3-0.5, and a nutrient supplement at <strong>th</strong>e<br />

BOD:N:P ratio <strong>of</strong> 100:5:1.<br />

While designing <strong>th</strong>e secondary settling tank in an <strong>ac</strong>tivated sludge process, it should be<br />

borne in mind <strong>th</strong>at a large portion <strong>of</strong> <strong>th</strong>e fine fibers is not biodegradable and also does not<br />

settle easily. Flow diagram for <strong>th</strong>e treatment <strong>of</strong> waste from a typical pulp mill is given in<br />

Figure 4.1.


28 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Bl<strong>ac</strong>k<br />

Liquor<br />

O<strong>th</strong>er<br />

Waste<br />

Lime<br />

Lime<br />

treatment<br />

Clarifier<br />

Calcium Hypochloride<br />

Grift Cham Clarifier<br />

Cooling<br />

Tower<br />

Nutrients<br />

BOD reduction 87%<br />

Detention Time 1.5 days<br />

Anaerobic<br />

Lagoon<br />

Stabilization<br />

Tank<br />

Aerated<br />

Lagoon<br />

Colour reduction=70%<br />

BOD reduction=40-50%<br />

Detention time=4 Hrs<br />

Detention Time<br />

= 3 Days<br />

Aerated<br />

Lagoon<br />

Figure 4.1 Flow diagram <strong>of</strong> wastewater treatment <strong>of</strong> a typical pulp mill<br />

Effluent<br />

Trickling filter has got a limited use in <strong>th</strong>e treatment <strong>of</strong> <strong>th</strong>e pulp and paper mill effluent,<br />

due to <strong>th</strong>e greater chances <strong>of</strong> clogging <strong>of</strong> <strong>th</strong>e media wi<strong>th</strong> fibrous material. Also <strong>th</strong>e trickling<br />

filter system is not capable <strong>of</strong> providing a high degree <strong>of</strong> treatment even wi<strong>th</strong> <strong>th</strong>e new<br />

plastic media. Wi<strong>th</strong> greater specific surf<strong>ac</strong>e area, <strong>th</strong>e BOD removal is found to be only 40-<br />

50%.<br />

(vi) Land treatment me<strong>th</strong>od<br />

Some types <strong>of</strong> soil are capable <strong>of</strong> removing color from <strong>th</strong>e waste. The waste is stored and<br />

allowed to be absorbed in such a soil. The capability <strong>of</strong> <strong>th</strong>e soil in removing <strong>th</strong>e color<br />

depends on <strong>th</strong>e cation exchange cap<strong>ac</strong>ity <strong>of</strong> <strong>th</strong>e soil. In addition to cation exchange<br />

cap<strong>ac</strong>ity, <strong>th</strong>e soil should be sufficiently permeable to <strong>ac</strong>cept <strong>th</strong>e entire volume <strong>of</strong> waste.<br />

(vii) Disposal <strong>of</strong> waste by irrigation<br />

The pulp mill effluent may be utilized for irrigation. No adverse effect on crops are<br />

reported for crops like maize, paddy, jowar and kenaf. Yields almost identical to <strong>th</strong>ose wi<strong>th</strong><br />

conventional irrigation pr<strong>ac</strong>tices are reported for wheat and sugarcane (RAO & DATTA,<br />

1987).


Sources <strong>of</strong> Pollution and its Management in <strong>th</strong>e Pulp and Paper Industry 29<br />

4.2.2 Solid waste disposal<br />

Application <strong>of</strong> incineration furn<strong>ac</strong>e for heat/energy recovery from combustion <strong>of</strong> fibers,<br />

barks, wood residues, o<strong>th</strong>er organic materials and wastewater sludge is pr<strong>ac</strong>ticed today but<br />

still needs more attention.<br />

4.3 Possibilities for Application <strong>of</strong> Alternative Technologies for Pollution Control<br />

Since it is impossible to completely eliminate <strong>th</strong>e waste coming out <strong>of</strong> <strong>th</strong>e production<br />

process, it is always necessary to have some sort <strong>of</strong> end-<strong>of</strong>-<strong>th</strong>e-pipe treatment to meet <strong>th</strong>e<br />

stringent environmental discharge regulations. There have been numerous developments<br />

towards cleaner production opportunities in <strong>th</strong>e industry. In <strong>th</strong>is section some <strong>of</strong> <strong>th</strong>e recent<br />

technological developments on bo<strong>th</strong> end-<strong>of</strong>-<strong>th</strong>e-pipe treatment and production process<br />

modification as well as raw material changes for waste reduction are discussed.<br />

4.3.1 Anaerobic treatment <strong>of</strong> wastes<br />

In recent years, <strong>th</strong>e trend in <strong>th</strong>e industry has changed from resource-destroying aerobic to<br />

resource-conserving anaerobic wastewater treatment. By anaerobic treatment, a<br />

combination <strong>of</strong> energy-efficient wastewater purification and energy recovery in <strong>th</strong>e form <strong>of</strong><br />

biogas production can be <strong>ac</strong>hieved. Such a full-scale application <strong>of</strong> anaerobic process is<br />

widespread in <strong>th</strong>e developed countries. Originally, conventional anaerobic treatment in an<br />

economic manner required highly concentrated wastewater. The development <strong>of</strong> anaerobic<br />

process-technology during recent years has drastically reduced <strong>th</strong>is requirement.<br />

Pulp and paper industries discharge large quantities <strong>of</strong> fibers and different types <strong>of</strong> sludge.<br />

These wastes correspond to large quantities <strong>of</strong> energy consumed by <strong>th</strong>e treatment and<br />

disposal process and large amounts <strong>of</strong> potential energy stored in <strong>th</strong>e materials. Because <strong>of</strong><br />

<strong>th</strong>e savings in processing energy and <strong>th</strong>e recovery <strong>of</strong> potential energy, <strong>th</strong>e demand for using<br />

anaerobic treatment <strong>of</strong> <strong>th</strong>ese wastes has greatly increased.<br />

4.3.2 Membrane technology<br />

Several membrane processes (reverse osmosis, electrodialysis, and ultrafiltration) have<br />

recently been developed to treat <strong>th</strong>e wastewater. Electrodialysis procedures have been<br />

successfully used to treat bisulfite spent liquor generated in a sulfite pulping process. In<br />

electrodialysis process, an imposed electric current is used to cause selective movement <strong>of</strong><br />

charged ions. A traditional electrodialysis system can be modified for <strong>th</strong>is particular<br />

application by pl<strong>ac</strong>ing sulfurous <strong>ac</strong>id (H 2SO 3) in several compartments and <strong>th</strong>e spent liquor<br />

(containing large amounts <strong>of</strong> lignosulfonic <strong>ac</strong>id sodium salt and small amounts <strong>of</strong> nonionizable<br />

sugars) in ano<strong>th</strong>er set <strong>of</strong> compartments. The compartments and membranes are<br />

arranged such <strong>th</strong>at <strong>th</strong>e sodium and bisulfite ions combine in a <strong>th</strong>ird set <strong>of</strong> compartments,<br />

forming sodium bisulfite (NaHSO 3). This NaHSO 3 can be recycled as cooking liquor. In


30 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

addition, <strong>th</strong>e remaining mixture <strong>of</strong> sugars and lignosulfonic <strong>ac</strong>id can be sold as plywood<br />

adhesives. One difficulty wi<strong>th</strong> <strong>th</strong>e process is high power requirement.<br />

The greater amount <strong>of</strong> dilute wastes, arising primarily from <strong>th</strong>e washing <strong>of</strong> pulp for fur<strong>th</strong>er<br />

lignin removal, also constitutes a serious waste problem. Typically, <strong>th</strong>is wastewater may<br />

contain about 1% dissolved solids. These dilute streams can be treated by a combination <strong>of</strong><br />

ultra-filtration followed by reverse osmosis, or by just <strong>th</strong>e reverse osmosis step. The<br />

purified water can be returned to <strong>th</strong>e system; <strong>th</strong>e small-volume concentrated wastes can<br />

<strong>th</strong>en be treated as digester wastes.<br />

4.3.3 Dissolved air floatation for fiber recovery<br />

This process is based on <strong>th</strong>e f<strong>ac</strong>t <strong>th</strong>at, addition <strong>of</strong> air to <strong>th</strong>e waste stream could enhance <strong>th</strong>e<br />

natural propensity <strong>of</strong> <strong>th</strong>e fibers to float, <strong>th</strong>ereby separating <strong>th</strong>em from <strong>th</strong>e water. Initially,<br />

polymeric flocculating agents are added, causing <strong>th</strong>e suspended fibers to coagulate toge<strong>th</strong>er<br />

into flocs. The stream is <strong>th</strong>en mixed wi<strong>th</strong> water in which air has been dissolved under<br />

pressure. When <strong>th</strong>e pressure is released, air comes out <strong>of</strong> solution as small bubbles which<br />

att<strong>ac</strong>h <strong>th</strong>emselves to <strong>th</strong>e flocs, bringing <strong>th</strong>em to <strong>th</strong>e surf<strong>ac</strong>e from where <strong>th</strong>ey can be readily<br />

skimmed <strong>of</strong>f. The success <strong>of</strong> <strong>th</strong>e technology is due to:<br />

- its versatility and ease <strong>of</strong> operation.<br />

- <strong>th</strong>e economic returns associated wi<strong>th</strong> fiber recovery.<br />

- substantially reduced residence times, which removes <strong>th</strong>e possibility <strong>of</strong> any<br />

organic material becoming contaminated by microorganisms, and speedy recirculation,<br />

<strong>th</strong>ereby limiting <strong>th</strong>e loss <strong>of</strong> process heat.<br />

- levels <strong>of</strong> clarification superior to what can be <strong>ac</strong>hieved wi<strong>th</strong> traditional me<strong>th</strong>ods.<br />

4.3.4 Ozone ble<strong>ac</strong>hing<br />

The 5-stage ble<strong>ac</strong>hing sequence (CEDED process) is <strong>th</strong>e most common and one <strong>of</strong> <strong>th</strong>e<br />

most economical ble<strong>ac</strong>hing processes for <strong>th</strong>e pulp. For e<strong>ac</strong>h stage, <strong>th</strong>e dissolved organics<br />

and <strong>th</strong>e inorganic ble<strong>ac</strong>hing chemicals must be washed out <strong>of</strong> <strong>th</strong>e pulp before entering <strong>th</strong>e<br />

next stage. Al<strong>th</strong>ough <strong>th</strong>e amount <strong>of</strong> wash water and <strong>th</strong>e resulting effluent could be<br />

minimized by reuse <strong>of</strong> <strong>th</strong>e washings as wash water for <strong>th</strong>e prior stage in a counter-current<br />

feedb<strong>ac</strong>k fashion, eventually it is necessary to sewer all <strong>th</strong>e washings for treatment in <strong>th</strong>e<br />

plant’s effluent treatment system. The result is a high BOD, high COD, high color and<br />

highly chlorinated solution <strong>of</strong> organics, which are formed principally from <strong>th</strong>e re<strong>ac</strong>tion <strong>of</strong><br />

chlorine wi<strong>th</strong> pulp.<br />

The repl<strong>ac</strong>ement manuf<strong>ac</strong>turing process is a 4-stage ble<strong>ac</strong>hing sequence, using oxygen wi<strong>th</strong><br />

caustic as <strong>th</strong>e ble<strong>ac</strong>hing agents in <strong>th</strong>e first stage (O), followed by ozone treatment in <strong>th</strong>e<br />

second stage (Z), caustic extr<strong>ac</strong>tion augmented by oxygen in <strong>th</strong>e <strong>th</strong>ird stage (EO), and a<br />

final chlorine dioxide stage (D). Since <strong>th</strong>ere is no use in <strong>th</strong>e O, Z, or EO stages <strong>of</strong><br />

chemicals <strong>th</strong>at are incompatible wi<strong>th</strong> recycle and recovery in <strong>th</strong>e mill’s existing pulping


Sources <strong>of</strong> Pollution and its Management in <strong>th</strong>e Pulp and Paper Industry 31<br />

liquor closed-cycle system, virtually all <strong>of</strong> <strong>th</strong>e washings from <strong>th</strong>ese <strong>th</strong>ree stages are<br />

recovered wi<strong>th</strong>out sewering. The only significant effluent from <strong>th</strong>e ble<strong>ac</strong>h plant is <strong>th</strong>e small<br />

amount <strong>of</strong> contaminated washings coming out <strong>of</strong> <strong>th</strong>e final chlorine dioxide stage. This<br />

process is successfully used in <strong>th</strong>e USA.<br />

Since essentially all <strong>th</strong>e caustic used in <strong>th</strong>e oxygen stage treatment <strong>of</strong> <strong>th</strong>e OZ(EO)D<br />

ble<strong>ac</strong>hing is recovered and recycled b<strong>ac</strong>k to <strong>th</strong>e cooking liquor closed recycle system, one is<br />

able to use it as <strong>th</strong>e caustic for <strong>th</strong>e oxygen stage when caustic makeup is needed for <strong>th</strong>e<br />

cooking liquor cycle, disposing <strong>of</strong> <strong>th</strong>e cost for purchasing additional caustic. However,<br />

when no caustic make-up is required, one can oxidize wi<strong>th</strong> oxygen <strong>th</strong>e product from <strong>th</strong>e<br />

cooking liquor recycle (white liquor) and use <strong>th</strong>e oxidized white liquor for <strong>th</strong>e alkali<br />

requirement. This results in an extra load (regeneration load <strong>of</strong> about 5% more cooking<br />

liquor for <strong>th</strong>e pine pulp) on <strong>th</strong>e cooking liquor recycle equipment’s cap<strong>ac</strong>ity.<br />

The recovery and recycle <strong>of</strong> organic and inorganic solids, purged in <strong>th</strong>e ble<strong>ac</strong>h plant<br />

effluents, give about 7% more solids <strong>th</strong>an normal for pine pulp production. While it is true<br />

<strong>th</strong>at <strong>th</strong>is is an extra use <strong>of</strong> recovery cap<strong>ac</strong>ity, it also results in extra solids which may be<br />

used as fuel for producing steam in <strong>th</strong>e recovery boiler. About 6% more steam per ton <strong>of</strong><br />

pine pulp can be produced.<br />

4.3.5 Modified continuous cooking process (MCC)<br />

MCC adapts <strong>th</strong>e principles <strong>of</strong> extended delignification to continuous pulping and rectifies<br />

<strong>th</strong>e drawb<strong>ac</strong>ks <strong>of</strong> a conventional, continuous Kraft cook. The effective alkali concentration<br />

<strong>th</strong>rough <strong>th</strong>e duration <strong>of</strong> cooking is evened out by decreasing it at <strong>th</strong>e beginning <strong>of</strong> cooking<br />

and increasing it at <strong>th</strong>e end. In a conventional cooking, <strong>th</strong>e high bulk lignin concentration<br />

at <strong>th</strong>e end hinders diffusion <strong>of</strong> dissolved lignin out <strong>of</strong> <strong>th</strong>e chips, causing re-precipitation.<br />

The MCC process has been <strong>ac</strong>complished <strong>th</strong>rough <strong>th</strong>e modification <strong>of</strong> 2-vessel Kamyr<br />

continuous digesters to allow bo<strong>th</strong> <strong>th</strong>e introduction <strong>of</strong> white liquor at several points and<br />

counter-current flow <strong>of</strong> <strong>th</strong>e liquor during <strong>th</strong>e final cooking phase. Moreover, a<br />

nonchlorine fiber line which is used in <strong>th</strong>e mill, consists <strong>of</strong> a digester for mediumconsistency<br />

cooking and a medium consistency oxygen-delignification stage, followed by an<br />

efficient post-oxygen washing stage wi<strong>th</strong> pressure diffuser and a wash press. Kappa<br />

number reductions <strong>of</strong> 8 units for s<strong>of</strong>twood and 4 to 5 units for hardwood have been<br />

<strong>ac</strong>complished wi<strong>th</strong>out loss <strong>of</strong> streng<strong>th</strong> properties. About 20-25% less total <strong>ac</strong>tive chlorine<br />

is needed to ble<strong>ac</strong>h <strong>th</strong>e pulp to about 90% ISO brightness compared to <strong>th</strong>e conventional<br />

Kraft pulp.<br />

The MCC fiber line can be regarded as one <strong>of</strong> <strong>th</strong>e most advanced in <strong>th</strong>e world today,<br />

meeting current and future requirements for <strong>th</strong>e environment while still producing fully<br />

competitive pulp. It is possible to produce ble<strong>ac</strong>hed pulp wi<strong>th</strong>out using chlorine, <strong>ac</strong>hieving<br />

brightness even above 90% ISO, <strong>th</strong>e level required for <strong>th</strong>e most demanding market pulps.


32 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

4.3.6 DARS in soda pulping <strong>of</strong> bagasse<br />

The basic principle <strong>of</strong> <strong>th</strong>e DARS process involves <strong>th</strong>e production <strong>of</strong> sodium ferrite by<br />

auto-causticization <strong>of</strong> sodium carbonate wi<strong>th</strong> ferric oxide and subsequently to obtain<br />

sodium hydroxide by hydrolyzing <strong>th</strong>e sodium ferrite. Silica is an undesirable element in all<br />

<strong>th</strong>e spent liquors from pulping <strong>of</strong> agricultural residues. Extensive studies on <strong>th</strong>e effect <strong>of</strong><br />

silica impurity in <strong>th</strong>e recovery loop revealed <strong>th</strong>at only a minor proportion <strong>of</strong> silica passes<br />

into white liquor during ferrite auto-causticization process. This is an advantage <strong>of</strong> <strong>th</strong>e<br />

process and, unlike conventional recovery, it may not be necessary to go for additional<br />

stages <strong>of</strong> desilication <strong>of</strong> spent liquor prior to recovery operation.<br />

Among <strong>th</strong>e benefits <strong>of</strong> <strong>th</strong>e process are operational flexibility, comp<strong>ac</strong>t and simple<br />

operation, less sp<strong>ac</strong>e requirement, most economic use <strong>of</strong> fuel by way <strong>of</strong> minimized quantity<br />

<strong>of</strong> high cost fuels, non-requirement <strong>of</strong> a high degree <strong>of</strong> process automation. Unlike <strong>th</strong>e<br />

smelt in conventional recovery, <strong>th</strong>e combustion product is solid, so <strong>th</strong>e process is safe.<br />

4.3.7 Dry forming <strong>of</strong> paper web<br />

The dry forming me<strong>th</strong>od can, in principle, be divided into <strong>th</strong>e following phases: defibration<br />

<strong>of</strong> raw materials, forming, binder application, curing, and finishing.<br />

The main raw material, mostly wood pulp, is defiberized in a hammer mill. After <strong>th</strong>is, <strong>th</strong>e<br />

fibers are transported by means <strong>of</strong> a fan to <strong>th</strong>e forming section. E<strong>ac</strong>h former consists <strong>of</strong><br />

two perforated drums rotating inside <strong>th</strong>e forming head. The fibers circulate horizontally<br />

between <strong>th</strong>e drums. The <strong>ac</strong>cepted fiber material is formed onto <strong>th</strong>e moving forming wire<br />

by suction. After forming, <strong>th</strong>e web is led <strong>th</strong>rough heated comp<strong>ac</strong>tor and embosser rolls.<br />

In <strong>th</strong>e <strong>th</strong>ird phase, a binder solution is sprayed onto <strong>th</strong>e web. The application is made<br />

separately on bo<strong>th</strong> sides <strong>of</strong> <strong>th</strong>e web, e<strong>ac</strong>h application being followed by <strong>th</strong>orough-drying.<br />

<strong>Full</strong> streng<strong>th</strong> is <strong>ac</strong>hieved during <strong>th</strong>e curing as <strong>th</strong>e binder is cross-linked. The curing is also<br />

performed in a <strong>th</strong>rough-dryer. To improve <strong>th</strong>e final properties, <strong>th</strong>e web is led <strong>th</strong>rough a<br />

finishing calendar.<br />

In <strong>th</strong>e dry forming process, <strong>th</strong>e fresh water demand is only 0.8 liters per kilogram <strong>of</strong><br />

produced material (air dry). It is totally used to dilute <strong>th</strong>e binder. The dry forming process<br />

creates nei<strong>th</strong>er waste water nor effluent gases.<br />

Dry formed materials have unique absorption and wet streng<strong>th</strong> properties. They are nonabrasive,<br />

s<strong>of</strong>t, and feel like textile. The products are suitable for different kinds <strong>of</strong> toweling<br />

and wiping, in heal<strong>th</strong>-care, hygiene and for table settings. The process is non-polluting,<br />

<strong>th</strong>ere are no waste water problems, and <strong>th</strong>e mill can be located ei<strong>th</strong>er close to consumers in<br />

an urban location or near <strong>th</strong>e sources <strong>of</strong> raw materials.


Sources <strong>of</strong> Pollution and its Management in <strong>th</strong>e Pulp and Paper Industry 33<br />

4.4 Concluding Remarks on Pollution Management<br />

The most significant environmental issue is <strong>th</strong>e use <strong>of</strong> chlorine in ble<strong>ac</strong>hing. Industrial<br />

developments demonstrate <strong>th</strong>at totally chlorine-free ble<strong>ac</strong>hing is feasible for many pulp and<br />

paper products, but it cannot produce certain grades <strong>of</strong> paper. Implementation <strong>of</strong> cleaner<br />

production process and pollution prevention measures can provide bo<strong>th</strong> economic and<br />

environmental benefits. Wherever feasible, use <strong>of</strong> a total wastewater recycling system along<br />

wi<strong>th</strong> a total chlorine-free pulp ble<strong>ac</strong>hing system is, <strong>th</strong>erefore, recommended. As a<br />

minimum, total elemental chlorine-free pulp ble<strong>ac</strong>hing system may be employed.<br />

Sulfur oxide emissions are scrubbed wi<strong>th</strong> slightly alkaline solutions. Electrostatic<br />

precipitators are used to control <strong>th</strong>e release <strong>of</strong> particulate matter to <strong>th</strong>e atmosphere.<br />

Effluent treatment typically includes neutralization, primary treatment to remove<br />

suspended solids, and biological/secondary treatment to reduce BOD 5 and toxicity.<br />

Flocculation to assist in <strong>th</strong>e removal <strong>of</strong> suspended solids is also sometimes necessary.<br />

Biological treatment systems, such as <strong>ac</strong>tivated sludge and anaerobic treatment, can reduce<br />

BOD 5 by over 95 percent. Tertiary treatment may be performed to remove toxicity, color,<br />

and coliform. Solid waste treatment steps include de-watering and combustion in an<br />

incinerator, bark boiler, or a utility boiler along wi<strong>th</strong> fossil fuels. If a mechanical clarifier is<br />

used in primary treatment, <strong>th</strong>e sludge is dewatered and may be incinerated; o<strong>th</strong>erwise it is<br />

land filled.<br />

The uses <strong>of</strong> ozone for partial degradation <strong>of</strong> lignin, solvent, or dry cooking result from<br />

ano<strong>th</strong>er consideration <strong>of</strong> how to <strong>ac</strong>hieve a “clean process”. The future <strong>of</strong> <strong>th</strong>e pulp and<br />

paper industry rests wi<strong>th</strong> an objective <strong>of</strong> avoiding or reducing <strong>th</strong>e waste instead <strong>of</strong> treating<br />

it. Therefore, <strong>th</strong>e adoption <strong>of</strong> emerging clean technologies along wi<strong>th</strong> <strong>th</strong>e computerization<br />

<strong>of</strong> processes will guarantee a cleaner and highly energy efficient pulp and paper industry in<br />

<strong>th</strong>e future.


34 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

5. CROSS COUNTRY REPORT ON THE PULP AND PAPER INDUSTRY<br />

5.1 Introduction<br />

The pulp and paper industry has been growing very rapidly in <strong>th</strong>e developing countries. As an<br />

essential commodity for <strong>th</strong>e society and <strong>th</strong>e consumption <strong>of</strong> paper being normally parallel wi<strong>th</strong> <strong>th</strong>e<br />

economic grow<strong>th</strong> <strong>of</strong> a particular country, <strong>th</strong>e production <strong>of</strong> paper products are expected to increase<br />

in <strong>th</strong>e future, especially in <strong>th</strong>e developing countries. The pulp and paper industry is capital, energy<br />

and pollution intensive; however, <strong>th</strong>e pr<strong>of</strong>its from <strong>th</strong>is industry are usually marginal. Therefore,<br />

many developing countries have avoided investment risks and have been importing <strong>th</strong>e pulp and<br />

high quality paper products. Along wi<strong>th</strong> <strong>th</strong>e rapid industrialization, <strong>th</strong>e developing countries have<br />

been trying to increase <strong>th</strong>eir domestic productions to meet <strong>th</strong>e higher share <strong>of</strong> national demands.<br />

Considering <strong>th</strong>e competitiveness wi<strong>th</strong> <strong>th</strong>e outside world, <strong>th</strong>e energy consumption which is one <strong>of</strong><br />

<strong>th</strong>e major inputs to <strong>th</strong>e pulp and paper industry has become an important issue in <strong>th</strong>e developing<br />

countries.<br />

This section presents a comparative study <strong>of</strong> <strong>th</strong>e pulp and paper industries <strong>of</strong> China, India, <strong>th</strong>e<br />

Philippines and Sri Lanka. The production trends and <strong>th</strong>e role <strong>of</strong> <strong>th</strong>e industry are presented for e<strong>ac</strong>h<br />

country. A comparison has been done in order to understand <strong>th</strong>e major causes <strong>of</strong> inefficiency in<br />

energy use and pollution abatement in <strong>th</strong>e industry. The possible improvements are identified and<br />

<strong>th</strong>e potential for <strong>th</strong>e introduction <strong>of</strong> energy efficient and environmentally sound technologies is<br />

assessed.<br />

5.2 Overview <strong>of</strong> <strong>th</strong>e industry<br />

To have an overview <strong>of</strong> <strong>th</strong>e pulp and paper industries <strong>of</strong> <strong>th</strong>e countries under study, comparisons<br />

have been made on <strong>th</strong>e role <strong>of</strong> <strong>th</strong>e industry in e<strong>ac</strong>h country, shares in industrial and total national<br />

energy consumption, production trends and number <strong>of</strong> mills and <strong>th</strong>eir cap<strong>ac</strong>ities.<br />

5.2.1 Role in <strong>th</strong>e national economy<br />

In 1993, <strong>th</strong>e Chinese pulp and paper industry <strong>ac</strong>counted for 1.54% <strong>of</strong> <strong>th</strong>e total industrial sector’s<br />

gross output value.<br />

5.2.2 Share in total energy consumption<br />

In China, <strong>th</strong>e pulp and paper industry is <strong>th</strong>e largest energy consumer among all light industries. In<br />

1992, <strong>th</strong>e energy consumption <strong>of</strong> Chinese pulp and paper industry <strong>ac</strong>counted for 3.25% and 1.74%<br />

<strong>of</strong> total industrial and national energy consumptions, respectively.<br />

In India, <strong>th</strong>e pulp and paper industry is ranked as <strong>th</strong>e six<strong>th</strong> largest energy consumer in <strong>th</strong>e country.


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry35<br />

In 1992, <strong>th</strong>e Philippines’ pulp and paper industry <strong>ac</strong>counted for 8.45% <strong>of</strong> industrial sector’s energy<br />

consumption and 2.5% <strong>of</strong> total national energy consumption.<br />

5.2.3 Production trends<br />

Among <strong>th</strong>e countries under <strong>th</strong>is study, China ranked as <strong>th</strong>e world’s <strong>th</strong>ird largest paper and paper<br />

board producer in 1992 after USA and Japan. The trends <strong>of</strong> pulp and paper and paper board<br />

productions are shown in Figure 5.1.<br />

Million Tons<br />

Thousand Tons<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

500<br />

400<br />

300<br />

200<br />

100<br />

Pulp Production<br />

1980 1985 1990 1992<br />

China<br />

India<br />

Philippines' Paper & Paper Board Production<br />

0<br />

1980 1981 1982 1983 1984 1985 1986 1987 1988<br />

Million Tons<br />

Thousand Tons<br />

14<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

China<br />

India<br />

Paper & Paper Board Production<br />

1980 1985 1990 1992<br />

Sri Lankan Pulp and Paper & Paper Board Production<br />

Pulp<br />

Paper Products<br />

1980 1990 1992<br />

Figure 5.1 Production trends <strong>of</strong> pulp, paper & paper board<br />

The pulp and paper industry is growing very rapidly in China wi<strong>th</strong> an average grow<strong>th</strong> rate in paper<br />

and paper board production <strong>of</strong> about 14% in <strong>th</strong>e last decade, <strong>th</strong>e highest value in <strong>th</strong>e world.<br />

However, China is still importing pulp and paper products to meet <strong>th</strong>e national demand. In 1992,<br />

net imported paper and paper board was 2.34 million tons and commercial pulp was 0.6 million<br />

tons. Wi<strong>th</strong> low per capita consumption <strong>of</strong> 16.7 kg per year (world average per capital consumption is<br />

45.3 kg per year), <strong>th</strong>e demand and production <strong>of</strong> paper products are expected to increase in China.


36 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

From Figure 5.1, it can be seen <strong>th</strong>at Indian pulp and paper and paper board production had a<br />

significant increase in <strong>th</strong>e last decade. The pulp production remained nearly constant from 1990 to<br />

1992 while <strong>th</strong>e paper products had been increasing along wi<strong>th</strong> <strong>th</strong>e increase in imported commercial<br />

pulp.<br />

In Philippines, <strong>th</strong>e production <strong>of</strong> paper and paper board was greatly fluctuating in <strong>th</strong>e last decade<br />

and has been <strong>ac</strong>hieving significant grow<strong>th</strong> since 1985. Sri Lankan paper industry has become more<br />

dependent on <strong>th</strong>e imported commercial pulp.<br />

5.2.4 Mills and <strong>th</strong>eir cap<strong>ac</strong>ities<br />

The average plant cap<strong>ac</strong>ity <strong>of</strong> <strong>th</strong>e pulp and paper industries in <strong>th</strong>e countries under study are shown<br />

in Figure 5.2.<br />

'000 Tons per year<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

2.5<br />

10.166<br />

China India Philippines Sri Lanka<br />

Figure 5.2 Average plant cap<strong>ac</strong>ity (paper and paper board production)<br />

At <strong>th</strong>e end <strong>of</strong> 1992, <strong>th</strong>ere were 11,940 enterprises in Chinese pulp and paper industry. The pulp and<br />

paper board cap<strong>ac</strong>ity <strong>of</strong> <strong>th</strong>e biggest mill is 150,000 tons per year. The breakdown <strong>of</strong> <strong>th</strong>e Chinese mill<br />

by annual plant cap<strong>ac</strong>ity is given in Figure 5.3. Therefore, <strong>th</strong>e small mills dominate in China,<br />

contributing to about 57% <strong>of</strong> <strong>th</strong>e total production.<br />

In India, <strong>th</strong>ere are 325 mills, 26 integrated mills and 297 small paper mills in <strong>th</strong>e pulp and paper<br />

industry. The number <strong>of</strong> small mills has been increasing more rapidly <strong>th</strong>an <strong>th</strong>e large mills so <strong>th</strong>at<br />

average plant cap<strong>ac</strong>ity has decreased from 12,222 tons <strong>of</strong> paper products in 1980 to 10,166 tons in<br />

1992. Wi<strong>th</strong> <strong>th</strong>e increasing paper demand and shortage <strong>of</strong> forest based raw material, <strong>th</strong>e Government<br />

<strong>of</strong> India has formulated a policy <strong>of</strong> promoting small mills based on straw and bagasse.<br />

15<br />

25.5


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry37<br />

88%<br />

>30,000 10,000-30,000


38 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

5.3 Char<strong>ac</strong>teristics <strong>of</strong> <strong>th</strong>e Parameters Affecting Energy Efficiency<br />

The specific energy consumption <strong>of</strong> <strong>th</strong>e pulp and paper industry depends on <strong>th</strong>e following:<br />

- Raw material mix<br />

- Share <strong>of</strong> imported pulp<br />

- Pulping process mix<br />

- Share <strong>of</strong> waste-paper pulp<br />

- Level <strong>of</strong> bl<strong>ac</strong>k liquor recovery<br />

- Share <strong>of</strong> cogenerated electricity<br />

- Product mix, etc.<br />

The overall specific energy consumption <strong>of</strong> <strong>th</strong>e pulp and paper industries <strong>of</strong> <strong>th</strong>e selected countries<br />

and world average are given in Figure 5.5.<br />

GJ/Ton <strong>of</strong> Paper Products<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

China India Philippines Japan World<br />

Average<br />

Figure 5.5 Specific energy consumption <strong>of</strong> <strong>th</strong>e pulp and paper industry<br />

It can be seen <strong>th</strong>at <strong>th</strong>e specific energy consumption <strong>of</strong> Indian pulp and paper industry is significantly<br />

too high. In comparison wi<strong>th</strong> Japan, <strong>th</strong>e Chinese pulp and paper industry consumes more <strong>th</strong>an<br />

double <strong>th</strong>e energy to produce <strong>th</strong>e same amount <strong>of</strong> paper products. The low specific energy<br />

consumption <strong>of</strong> <strong>th</strong>e industry in <strong>th</strong>e Philippines is due to <strong>th</strong>e high share <strong>of</strong> imported pulp. The trends<br />

<strong>of</strong> specific energy consumption in China and India are given in Figure 5.6.<br />

One can observe a gradual reduction <strong>of</strong> specific energy consumption <strong>of</strong> <strong>th</strong>e order <strong>of</strong> 5.33% in China<br />

in <strong>th</strong>e last decade. However, <strong>th</strong>e specific energy consumption <strong>of</strong> Indian pulp and paper industry did<br />

not reduce significantly in <strong>th</strong>e last decade; it has only started decreasing since 1990.<br />

In order to understand <strong>th</strong>e major causes <strong>of</strong> <strong>th</strong>e inefficiency in energy use, some parameters affecting<br />

<strong>th</strong>e energy efficiency are compared in <strong>th</strong>is section.


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry39<br />

GJ/Ton <strong>of</strong> Paper Products<br />

90<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

China<br />

India<br />

1980 1981 1984 1985 1990 1992<br />

Figure 5.6 Trends <strong>of</strong> specific energy consumption in China and India<br />

5.3.1 Raw material mix<br />

The major difference between <strong>th</strong>e developing countries and <strong>th</strong>e industrialized countries in raw<br />

material mix is <strong>th</strong>e share <strong>of</strong> wood pulp in paper making. The share <strong>of</strong> wood pulp in national total is<br />

given in Figure 5.7. The higher <strong>th</strong>e share <strong>of</strong> wood pulp, <strong>th</strong>e lower is <strong>th</strong>e overall specific energy<br />

consumption <strong>of</strong> <strong>th</strong>e pulp and paper industry.<br />

In China, straw-material-made pulp holds a dominant share in <strong>th</strong>e mix, <strong>ac</strong>counting for 63% <strong>of</strong> <strong>th</strong>e<br />

total pulp. In India, bamboo pulp <strong>ac</strong>counted for 43.42% and bagasse and straw pulp toge<strong>th</strong>er had a<br />

share <strong>of</strong> 33.38% <strong>of</strong> <strong>th</strong>e total pulp produced.<br />

5.3.2 Level <strong>of</strong> waste paper utilization<br />

Greater level <strong>of</strong> waste paper utilization in pulping leads to resources conservation, energy saving and<br />

environmental protection. Developing countries however tend to use lower percentage <strong>of</strong> waste<br />

paper in comparison wi<strong>th</strong> <strong>th</strong>e developed countries. The level <strong>of</strong> waste paper utilization is shown in<br />

Figure 5.8 for selected countries. This is found to be quite low in China and India, leading to <strong>th</strong>e<br />

higher specific energy consumption <strong>of</strong> <strong>th</strong>e industry.<br />

5.3.3 Energy consumption by type<br />

The breakdown <strong>of</strong> specific energy consumption by type is given in Table 5.1. The major steam<br />

consumers in <strong>th</strong>e pulp and paper industry are digesters and dryers. It can be seen in <strong>th</strong>is table <strong>th</strong>at<br />

<strong>th</strong>e specific steam consumption <strong>of</strong> Indian pulp and paper mills is too high, reflecting <strong>th</strong>e inefficiency<br />

<strong>of</strong> digesters and dryers. The higher steam consumption in digesters is due to <strong>th</strong>e non-wood pulping.<br />

The high electricity consumption can be reduced by repl<strong>ac</strong>ing/modifying outdated paper-making<br />

m<strong>ac</strong>hines which are <strong>th</strong>e major electricity consumers.


40 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

% <strong>of</strong> Total Pulp<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

23.9 23.2<br />

47.63<br />

23.03<br />

95.1<br />

99.3 99.1<br />

China India Philippines Sri Lanka Japan US France<br />

Figure 5.7 Share <strong>of</strong> wood pulp in selected countries<br />

% <strong>of</strong> Total Pulp<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

22.5<br />

29<br />

51.2<br />

52.57<br />

China Philippines Japan<br />

* % <strong>of</strong> total installed cap<strong>ac</strong>ity<br />

Figure 5.8 Level <strong>of</strong> waste paper utilization<br />

Table 5.1 Specific energy consumption by type<br />

China India Philippines Developed<br />

Countries<br />

Steam Consumption (Tons/ton paper) N/A 10-16 6-7 4-6.5<br />

Electricity Consumption (kWh/ton Paper) 1100-1800 1200-1700 1000-1100 500-1100<br />

5.3.4<br />

5.3.5 Awareness about energy conservation<br />

Wi<strong>th</strong> increasing energy cost and international competitiveness, some energy conservation measures<br />

<strong>th</strong>at have been undertaken in <strong>th</strong>e selected countries are summarized in Table 5.2.<br />

50<br />

48


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry41<br />

Table 5.2 Energy conservation measures undertaken in different countries<br />

Country Energy Conservation Measures<br />

China - Holding energy management training workshops<br />

- Improving efficiency <strong>of</strong> boilers and condensate recovery<br />

- Enhancing <strong>th</strong>ermal insulation performance<br />

- Popularizing energy saving electrical appliances<br />

- Increasing level <strong>of</strong> chemicals recovery<br />

- Conversion <strong>of</strong> cylindrical to Fourdrinier paper m<strong>ac</strong>hines<br />

- Conversion <strong>of</strong> batch to continuous digesters<br />

- Installation <strong>of</strong> on-line moisture monitoring and control systems<br />

- Installation <strong>of</strong> efficient press<br />

- Installation <strong>of</strong> jump-pro<strong>of</strong> energy-saving pumps<br />

- Employment <strong>of</strong> heat pump in dryer section<br />

- Enhancing bl<strong>ac</strong>k liquor recovery<br />

- Installation <strong>of</strong> computer-controlled cooking<br />

- Pr<strong>ac</strong>ticing cogeneration<br />

India - Installation <strong>of</strong> condensate recovery systems<br />

- Conversion <strong>of</strong> batch to continuous digesters<br />

- Conversion <strong>of</strong> cylindrical to Fourdrinier paper m<strong>ac</strong>hines<br />

- Enhancing chemical recovery<br />

- Installation <strong>of</strong> falling film type evaporators<br />

- Employing process automation<br />

- Repl<strong>ac</strong>ement <strong>of</strong> disc chippers by drum chippers<br />

- Conversion <strong>of</strong> pneumatic conveyors to mechanical types<br />

- Conversion <strong>of</strong> spreader stoker to fluidized bed combustion boilers<br />

Philippines - Installation <strong>of</strong> computerized moisture control system<br />

- Taking energy audits<br />

- Installation <strong>of</strong> cogeneration systems<br />

- Power f<strong>ac</strong>tor improvements<br />

Therefore, it can be seen <strong>th</strong>at some advanced energy efficient technologies have been already<br />

installed in <strong>th</strong>e developing countries. However, <strong>th</strong>e dissemination rate <strong>of</strong> <strong>th</strong>ese technologies is very<br />

limited in comparison wi<strong>th</strong> <strong>th</strong>e industrialized countries.<br />

5.4 Char<strong>ac</strong>teristics <strong>of</strong> <strong>th</strong>e parameters affecting pollution abatement measures<br />

There is great potential for resources recovery in <strong>th</strong>is industry <strong>th</strong>rough pollution abatement<br />

measures. But less attention was paid in <strong>th</strong>is direction mainly due to limited dissemination <strong>of</strong> <strong>th</strong>ose<br />

technologies and high capital share for <strong>th</strong>e industry which is categorized as small scale in <strong>th</strong>ese<br />

developing countries. However, some local environmental regulations and public awareness due to<br />

growing industrialization in <strong>th</strong>e region has forced <strong>th</strong>e industries to introduce some pollution


42 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

abatement programs. The obsolete m<strong>ac</strong>hinery and technologies generally in use in <strong>th</strong>is region fur<strong>th</strong>er<br />

weaken <strong>th</strong>e already deteriorated environment. The type and quantity <strong>of</strong> pollutants produced vary<br />

from industry to industry depending on <strong>th</strong>e process employed.<br />

5.4.1 Causes <strong>of</strong> pollution<br />

The causes <strong>of</strong> pollution from pulp and paper industries in <strong>th</strong>e countries studied are attributed to <strong>th</strong>e<br />

following:<br />

- Type <strong>of</strong> raw material in use (predominantly agro-residue based industry)<br />

- Type <strong>of</strong> fuel in use to meet energy demand<br />

- Obsolete technology and m<strong>ac</strong>hinery in use<br />

- Lower production cap<strong>ac</strong>ities <strong>of</strong> <strong>th</strong>e mills, using inferior technical equipment<br />

- No strict enforcement <strong>of</strong> environmental regulations<br />

- <strong>th</strong>inking <strong>th</strong>at it is an extra expenditure wi<strong>th</strong>out any return<br />

- A marginal pr<strong>of</strong>it making industry<br />

As shown in <strong>th</strong>e Figure 5.7, <strong>th</strong>e share <strong>of</strong> wood pulp in <strong>th</strong>e countries under study is about one four<strong>th</strong><br />

<strong>of</strong> <strong>th</strong>e production except in <strong>th</strong>e Philippines where it is nearly 50%. But in developed countries <strong>th</strong>e<br />

share is almost 100% which implies <strong>th</strong>at more research and development are under way to eliminate<br />

pollution problem by wood pulping. The agro-residue based raw materials cause more pollution<br />

problems <strong>th</strong>an <strong>th</strong>e wood. In India, China and Sri Lanka straw dominates <strong>th</strong>e share <strong>of</strong> <strong>th</strong>e raw<br />

material for pulping. Among all <strong>th</strong>e non-woody raw materials, straw poses <strong>th</strong>e most serious<br />

environmental pollution problem because <strong>of</strong> <strong>th</strong>e difficulties in chemical recovery from bl<strong>ac</strong>k liquor<br />

due to its high silica content. The use <strong>of</strong> waste paper as raw material reduces bo<strong>th</strong> energy<br />

consumption and pollution problems. As seen in Figure 5.8 <strong>th</strong>e utilization levels <strong>of</strong> waste paper in<br />

Sri Lanka and Philippines are <strong>th</strong>e same as <strong>th</strong>e industrialized countries (about 50% <strong>of</strong> <strong>th</strong>e pulp<br />

production), whereas it is only 25% <strong>of</strong> total pulp production in India and China.<br />

5.4.2 Current water pollution control strategies<br />

As pulp and paper is a serious water polluting industry, some measures are under way to abate<br />

pollution problems whose potential for improvements is very high. Current pr<strong>ac</strong>tices to abate water<br />

pollution in <strong>th</strong>ese countries are reported as below.<br />

5.4.2.1 In China<br />

During <strong>th</strong>e period <strong>of</strong> 1980 to 1988<br />

- BOD discharge decreased by 33%<br />

- Suspended solids decreased by 36%<br />

- Alkali recovery increase at <strong>th</strong>e rate <strong>of</strong> 5.3%<br />

These reductions were <strong>ac</strong>hieved by<br />

- Integrated exploitation <strong>of</strong> digested wastewater


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry43<br />

- White water recycling<br />

- Fiber recovery<br />

- Alkali recovery<br />

However <strong>th</strong>ose developments are mainly reported for <strong>th</strong>e large and medium scale pulp and paper<br />

industries. In 1990, alkali recovery rate in <strong>th</strong>e wood pulp mills is reported as more <strong>th</strong>an 60% whereas<br />

<strong>th</strong>e recovery rate in straw pulp mill is around 6%. This should be mainly because <strong>of</strong> <strong>th</strong>e high silica<br />

content in <strong>th</strong>e bl<strong>ac</strong>k liquor <strong>of</strong> rice straw for which <strong>th</strong>ere have been limited technological<br />

developments.<br />

In 1989 - 1990:<br />

- 13% <strong>of</strong> <strong>th</strong>e total discharged wastewater met <strong>th</strong>e local regulatory standards<br />

- for <strong>th</strong>e first time a regulation was set up for wastewater disposal<br />

- no regulation related to air pollution existed<br />

- average alkali recovery percentage 34%<br />

- average alkali recovery rate in large scale enterprise was 80 -90%<br />

- average alkali recovery rate in medium scale enterprise was 75 - 80%<br />

- wastewater treated and recycling ratio was 30 - 50%<br />

5.4.2.2 In India<br />

- small mills generate more pollutants due to <strong>th</strong>e absence <strong>of</strong> chemical recovery system<br />

- Production process control to reduce wastewater volume and pollutants<br />

- Wastewater treatment technologies to reduce <strong>th</strong>e pollution streng<strong>th</strong><br />

- Use <strong>of</strong> oxygen and peroxide as ble<strong>ac</strong>hing agents<br />

- Chemical recovery<br />

During <strong>th</strong>e period <strong>of</strong> 1985 to 1993<br />

- Alkali recovery per year increased from 285,000 to 455,000 tons<br />

- Wastewater treated and recycled per year increased from 1520 to 520 million m 3<br />

- Material recovery and recycling per year increased from 1,520,000 to 2,550,000 tons<br />

5.4.2.3 In Philippines<br />

- Most <strong>of</strong> <strong>th</strong>e old mills only have filters for fiber recovery<br />

- Chemical recovery is pr<strong>ac</strong>ticed to certain extent<br />

In Sri Lanka, <strong>of</strong> <strong>th</strong>e only two pulp and paper mills, one has no chemical recovery f<strong>ac</strong>ilities. Though<br />

<strong>th</strong>e second plant has <strong>th</strong>e f<strong>ac</strong>ility, it was never commissioned because <strong>of</strong> <strong>th</strong>e higher silica content in<br />

<strong>th</strong>e bl<strong>ac</strong>k liquor. As a remedial measure, raw material for pulping was changed to waste paper from<br />

rice straw.


44 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

5.4.3 Current air pollution control strategies<br />

The major sources <strong>of</strong> air pollution are burning <strong>of</strong> fuels for power generation and dedusting <strong>of</strong> raw<br />

materials. Since air pollution in <strong>th</strong>is industry is not serious as water pollution, much less attention is<br />

paid in <strong>th</strong>is area. To give an example, no air emission regulations were en<strong>ac</strong>ted in China until 1990.<br />

But in India, <strong>th</strong>e air pollution <strong>ac</strong>t was en<strong>ac</strong>ted in 1981; cyclones and Electrostatic precipitators are<br />

mainly used as air pollution control equipment whose share <strong>of</strong> 20% in 1960 increased to 60% in<br />

1992.<br />

5.4.4 Current solid waste control strategies<br />

In all <strong>th</strong>ese countries, solid wastes generated from <strong>th</strong>e process itself and secondary wastes derived<br />

from pollution control measures such as dust collection equipment and wastewater treatment, are<br />

dumped at landfill sites wi<strong>th</strong>out any pretreatment. In some plants <strong>th</strong>e solid waste which can be used<br />

as fuel is recycled to repl<strong>ac</strong>e <strong>th</strong>e boiler fuels.<br />

5.4.5 Comparison <strong>of</strong> effluent and emission char<strong>ac</strong>teristics<br />

In general, <strong>th</strong>e information provided in <strong>th</strong>e country reports are quite diverse and use different basis.<br />

As some <strong>of</strong> <strong>th</strong>em are given for per ton production basis whereas o<strong>th</strong>ers in ambient standards, it is<br />

not possible to make any comparison in some cases. For <strong>th</strong>e purpose <strong>of</strong> comparison it is preferable<br />

to have <strong>th</strong>e amount <strong>of</strong> pollutant released per ton <strong>of</strong> product <strong>th</strong>an in ambient standards. It is mainly<br />

because <strong>th</strong>e allowable limit <strong>of</strong> pollutant discharge to <strong>th</strong>e surrounding in different countries depends<br />

on <strong>th</strong>e geographical location, climatic condition and overall intensity <strong>of</strong> pollutants released from all<br />

o<strong>th</strong>er sources.<br />

A comparison <strong>of</strong> fresh water consumption, quantity and char<strong>ac</strong>teristics <strong>of</strong> wastewater wi<strong>th</strong> German<br />

standards is presented in Table 5.3. Even <strong>th</strong>ough a number <strong>of</strong> parameters are tabulated, most <strong>of</strong><br />

<strong>th</strong>em cannot be compared due to <strong>th</strong>e limitation <strong>of</strong> data availability. Also, as seen from Table 5.3, no<br />

data are available for <strong>th</strong>e Philippines and Sri Lanka, may be due to <strong>th</strong>e minor share <strong>of</strong> <strong>th</strong>ese<br />

industries in <strong>th</strong>eir national economy.<br />

A similar comparison for air emission are shown in Table 5.4. As said earlier <strong>th</strong>e comparison was<br />

not possible in most <strong>of</strong> <strong>th</strong>e cases because <strong>of</strong> non-availability <strong>of</strong> data from any <strong>of</strong> <strong>th</strong>e countries under<br />

study. It implies <strong>th</strong>at none <strong>of</strong> <strong>th</strong>e countries pays any attention to air pollution abatement.


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry45<br />

Table 5.3 Quantity and char<strong>ac</strong>teristics <strong>of</strong> wastewater released<br />

Parameters<br />

Water consumption<br />

Germany * China India Philippine<br />

s<br />

Sri Lanka<br />

(ton/ton ble<strong>ac</strong>hed pulp produced) 70 - 130<br />

(ton/ton paper produced)<br />

Wastewater discharged<br />

220 30<br />

(ton/ton ble<strong>ac</strong>hed pulp produced) 7 - 12<br />

(ton/ton paper produced)<br />

PH<br />

70-380**<br />

Suspended solids (mg/l)<br />

Settleable solids (ml/l)<br />

DS (mg/l)<br />

50 151*** 10***<br />

BOD5 (kg/ton pulp)<br />

5<br />

10-270<br />

(kg/ton paper)<br />

1-6<br />

COD (kg/ton pulp)<br />

70<br />

50-1100**<br />

(kg/ton paper)<br />

Oil and Grease (mg/l)<br />

Total N (mg/l)<br />

3-12 150<br />

5<br />

Wastewater reuse rate (%)<br />

Treatment rate <strong>of</strong> wastewater (%)<br />

Proportion re<strong>ac</strong>hing discharge<br />

standards (%)<br />

68.6 90-95<br />

Hydro carbons (kg/ton pulp) 1.0<br />

(kg/ton paper) 0.01-0.04<br />

* The German regulatory standard; BOD & COD based on 24 hour sample<br />

** Depending on <strong>th</strong>e raw material; waste paper lowest & rice straw etc. high<br />

*** in kg/ton paper<br />

Table 5.4 Quantity and char<strong>ac</strong>teristics <strong>of</strong> air pollutants released<br />

Parameters German China* Indi Philippine<br />

y<br />

a s<br />

Dust discharged (TSP) (mg/m3) 30 260,000<br />

SO2 (mg/m3) 100 270,000<br />

NOx (mg/m3) 500<br />

CO (mg/m3) Organics (mg/m<br />

100<br />

3)<br />

Treatment rate <strong>of</strong> waste gas (%)<br />

Rate <strong>of</strong> treated waste gas discharged<br />

which meet standards (%)<br />

* in tons<br />

Sri<br />

Lanka


46 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

5.5 Potential for Energy Efficiency Improvement<br />

5.5.1 Structure <strong>of</strong> <strong>th</strong>e industry<br />

One <strong>of</strong> <strong>th</strong>e major reasons for <strong>th</strong>e high specific energy consumption in China and India is <strong>th</strong>e small<br />

scale <strong>of</strong> <strong>th</strong>e mills. Taking m<strong>ac</strong>ro economic consideration into <strong>ac</strong>count, <strong>th</strong>e expansion <strong>of</strong> small mills<br />

based on non-wood materials might be suitable for some countries. In such a case, <strong>th</strong>e expansion <strong>of</strong><br />

small mills should be planned ensuring <strong>th</strong>at <strong>th</strong>ey incorporate energy efficient technologies and<br />

chemical recovery systems.<br />

In <strong>th</strong>e case <strong>of</strong> India, <strong>th</strong>e capital utilization f<strong>ac</strong>tor is too low, <strong>th</strong>erefore, closure <strong>of</strong> inefficient small<br />

mills would improve <strong>th</strong>e overall energy efficiency <strong>of</strong> <strong>th</strong>e industry.<br />

Finally, <strong>th</strong>e future expansion <strong>of</strong> <strong>th</strong>e industry should be based on <strong>th</strong>e large-scale mills so <strong>th</strong>at<br />

cogeneration f<strong>ac</strong>ilities and <strong>th</strong>ermal upgrading systems can be employed economically.<br />

5.5.2 Raw materials<br />

The specific energy consumption <strong>of</strong> <strong>th</strong>e pulp and paper industry can be reduced by increasing <strong>th</strong>e<br />

share <strong>of</strong> wood pulp. However, <strong>th</strong>is is a question <strong>of</strong> m<strong>ac</strong>ro economics and <strong>th</strong>e concern for <strong>th</strong>e<br />

preservation <strong>of</strong> forest resources. The current level <strong>of</strong> waste paper recycling in <strong>th</strong>e developing<br />

countries is lower <strong>th</strong>an <strong>th</strong>at in industrialized countries. Therefore, increasing <strong>th</strong>e share <strong>of</strong> recycled<br />

paper could improve <strong>th</strong>e overall energy efficiency <strong>of</strong> <strong>th</strong>e industry.<br />

5.5.3 Potential for energy conservation<br />

The potential for major energy conservation in <strong>th</strong>e countries under <strong>th</strong>is study is summarized in<br />

Table 5.5.<br />

5.6 Potential for pollution abatement<br />

Use <strong>of</strong> non-wood raw materials are identified as one <strong>of</strong> <strong>th</strong>e major source <strong>of</strong> pollutant in <strong>th</strong>is region.<br />

Due to <strong>th</strong>e economic level and availability <strong>of</strong> non-wood raw material in plenty, it is impossible to<br />

eliminate its use. Since in developed countries wood covers almost all <strong>th</strong>e raw material requirements,<br />

<strong>th</strong>e developing countries which use non-wood products as raw material must have <strong>th</strong>eir own<br />

research and development f<strong>ac</strong>ilities to develop environmentally sound technologies. As a serious<br />

water polluting industry, its future expansion in <strong>th</strong>is region should be well planned to abate pollution<br />

load on <strong>th</strong>e environment. As seen earlier, <strong>th</strong>e pollution abatement measures in <strong>th</strong>ese countries are in<br />

<strong>th</strong>eir infancy. So as a first step, records should be maintained about pollution loads and water<br />

consumption.


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry47<br />

Table 5.5 Potential for energy conservation #<br />

Energy Conservation Measures China India Philippines Sri<br />

Lanka<br />

Short Term Measures<br />

- Management pr<strong>ac</strong>tices<br />

- Boiler efficiency improvement<br />

- Insulation improvement<br />

- Power f<strong>ac</strong>tor improvement<br />

Medium Term Measures<br />

- Chemical recovery<br />

- Condensate recovery<br />

- Cogeneration<br />

- Me<strong>th</strong>anogenesis<br />

- Conversion <strong>of</strong> batch to continuous digesters<br />

- Mechanical vapor compression <strong>of</strong> bl<strong>ac</strong>k<br />

liquor<br />

- V<strong>ac</strong>uum pump installation<br />

- Installation <strong>of</strong> efficient press<br />

- Heat pump hot water system<br />

- Flash steam recovery in dryers<br />

- Process automation<br />

Long Term Measures<br />

- Interconnected f<strong>ac</strong>tories (wi<strong>th</strong> sugar mills)<br />

- Excess power generation<br />

- Adaptation <strong>of</strong> new pulping processes<br />

- Computerization<br />

**<br />

**** 1<br />

***<br />

***<br />

*** 3<br />

***<br />

*** 5<br />

****<br />

****<br />

****<br />

****<br />

**** 7<br />

****<br />

****<br />

****<br />

***<br />

****<br />

****<br />

****<br />

****<br />

*** 2<br />

****<br />

****<br />

**** 4<br />

****<br />

**** 6<br />

****<br />

****<br />

****<br />

****<br />

**** 8<br />

****<br />

****<br />

*** 9<br />

****<br />

****<br />

****<br />

****<br />

****<br />

***<br />

****<br />

***<br />

***<br />

****<br />

****<br />

****<br />

***<br />

***<br />

****<br />

****<br />

****<br />

****<br />

****<br />

**<br />

****<br />

***<br />

****<br />

# For e<strong>ac</strong>h energy conservation measure, <strong>th</strong>e relative scope <strong>of</strong> application is shown by <strong>th</strong>e number <strong>of</strong><br />

asterisks. For instance, <strong>th</strong>e measure <strong>of</strong> connecting wi<strong>th</strong> sugar mills has a higher scope in India, where <strong>th</strong>e<br />

share <strong>of</strong> bagasse-pulp is significant, <strong>th</strong>an in China where straw-pulp is more important.<br />

****<br />

***<br />

***<br />

***<br />

***<br />

***<br />

***<br />

****<br />

***<br />

***<br />

****<br />

****<br />

****<br />

****<br />

****<br />

-<br />

****<br />

***<br />

****<br />

1 Most <strong>of</strong> <strong>th</strong>e Chinese mills have boiler efficiencies below 60%<br />

2 Boiler efficiency in small mills is 50-60%, however, most <strong>of</strong> <strong>th</strong>e medium and large mills<br />

employ fluidized boilers wi<strong>th</strong> an efficiency <strong>of</strong> 70-80%<br />

3 Alkali recovery rate in China was 36.66% <strong>of</strong> total consumption in 1988<br />

4 Nearly all agro-based paper mills have no chemical recovery system<br />

5 Almost all mills have cogeneration systems but <strong>th</strong>ey could meet only 10.5% <strong>of</strong> electricity<br />

demand<br />

6 Only 40% <strong>of</strong> Indian large mills have cogeneration f<strong>ac</strong>ilities<br />

7 Dryness <strong>of</strong> wet paper from paper m<strong>ac</strong>hine is about 30% in China<br />

8 Dryness <strong>of</strong> wet paper from paper m<strong>ac</strong>hine is 35-38% (50% in developed countries)<br />

9 About 25% <strong>of</strong> Indian mills have installed electronic automation systems


48 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

The source reduction and waste minimization measures ra<strong>th</strong>er <strong>th</strong>an end <strong>of</strong> pipe treatment not only<br />

lead to cost saving in waste treatment but also save <strong>th</strong>e depleting natural resources. Recovering and<br />

recycling <strong>of</strong> fibers seems to be <strong>th</strong>e most promising <strong>of</strong> all <strong>th</strong>e measures. Larger <strong>th</strong>e mill, lesser is <strong>th</strong>e<br />

specific treatment cost, bo<strong>th</strong> in terms <strong>of</strong> capital as well as operation and maintenance costs. But due<br />

to <strong>th</strong>e nature <strong>of</strong> <strong>th</strong>e industry and availability <strong>of</strong> raw materials, it is difficult to control <strong>th</strong>e grow<strong>th</strong> <strong>of</strong><br />

<strong>th</strong>e small scale industries in <strong>th</strong>is region. Therefore, <strong>th</strong>e optimum level <strong>of</strong> mill cap<strong>ac</strong>ity should be<br />

estimated on <strong>th</strong>e basis <strong>of</strong> various considerations to plan <strong>th</strong>e future expansion <strong>of</strong> <strong>th</strong>e industry.<br />

The potentials for major pollution abatement options based on <strong>th</strong>e available technologies are<br />

summarized in <strong>th</strong>e Table 5.6.<br />

Table 5.6 Potentials for pollution abatement measures #<br />

Pollution Abatement Measures China India Philippines Sri Lanka<br />

Short Term Measures<br />

- Management pr<strong>ac</strong>tices<br />

- Good house keeping<br />

- Operating at optimized parameters<br />

- <strong>Full</strong> cap<strong>ac</strong>ity utilization<br />

- Prevention <strong>of</strong> leakage, spills, overflows et.<br />

- Resource recovery and recycling<br />

- Improving water recycle utilization ratio (e.g. white<br />

water recycling for washing <strong>of</strong> pulp)<br />

- Implementation <strong>of</strong> environmental regulations<br />

strictly<br />

Medium Term Measures<br />

- Improved chemical recovery<br />

- Substitution for Chlorine wi<strong>th</strong> ozone, oxygen and<br />

hydrogen peroxide in ble<strong>ac</strong>hing<br />

- Increased rate <strong>of</strong> waste paper utilization<br />

- Removal <strong>of</strong> silica before evaporation process (for<br />

rice straw)<br />

- Efficient air pollution control equipment<br />

- Advance wastewater treatment<br />

Long Term Measures<br />

- Prohibiting new small scale mill development<br />

wherever possible<br />

- Process monitoring and control by expert system<br />

***<br />

***<br />

***<br />

***<br />

***<br />

***<br />

****<br />

***<br />

***<br />

***<br />

****<br />

****<br />

****<br />

****<br />

****<br />

***<br />

***<br />

***<br />

***<br />

***<br />

****<br />

***<br />

***<br />

***<br />

****<br />

****<br />

***<br />

****<br />

****<br />

***<br />

***<br />

***<br />

***<br />

***<br />

****<br />

***<br />

*****<br />

**** **** **** ****<br />

#<br />

For e<strong>ac</strong>h pollution abatement measure, <strong>th</strong>e relative scope <strong>of</strong> application is shown by number <strong>of</strong><br />

asterisks as in Table 5.5.<br />

****<br />

****<br />

****<br />

***<br />

***<br />

****<br />

****<br />

***<br />

****<br />

***<br />

***<br />

***<br />

***<br />

***<br />

****<br />

***<br />

****<br />

****<br />

***<br />

****<br />

****<br />

****<br />

***


Cross Country Comparison <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry49<br />

5.7 Conclusion<br />

The energy saving potential in <strong>th</strong>e pulp and paper industry for <strong>th</strong>e European Community as a whole<br />

was estimated as 20-30% <strong>of</strong> <strong>th</strong>e current energy consumed. Therefore, <strong>th</strong>e potential <strong>of</strong> energy saving<br />

in <strong>th</strong>e developing countries where outdated technologies dominate, could be substantially higher.<br />

Since <strong>th</strong>e industry generates waste materials which can be used as fuel, self-power generation in<br />

cogeneration mode could be one <strong>of</strong> <strong>th</strong>e most promising measures to improve <strong>th</strong>e overall energy<br />

efficiency <strong>of</strong> <strong>th</strong>e industry. Major energy savings could also <strong>ac</strong>crue from <strong>th</strong>e application <strong>of</strong> <strong>th</strong>ermal<br />

upgrading systems.<br />

The pulp and paper industry is a favorable candidate for excess power generation and supply to <strong>th</strong>e<br />

grid. Therefore, encouragement from <strong>th</strong>e governmental institutions by means <strong>of</strong> regulations and<br />

incentives would not only improve <strong>th</strong>e energy efficiency <strong>of</strong> <strong>th</strong>e industry but also be economically<br />

beneficial to <strong>th</strong>e country. To <strong>ac</strong>hieve better energy efficiency in <strong>th</strong>e pulp and paper industry, <strong>th</strong>e type<br />

<strong>of</strong> useful support <strong>th</strong>e government institutions can extend are setting target for dissemination <strong>of</strong> e<strong>ac</strong>h<br />

promising energy efficient technology, spreading knowledge about new technologies, organizing<br />

energy conferences and workshops, and encouraging research and development <strong>ac</strong>tivities.<br />

Energy efficient and environmentally sound pulping processes have been mainly developed for<br />

wood pulp which currently <strong>ac</strong>counts for 90% <strong>of</strong> <strong>th</strong>e world’s pulp. Therefore, for countries like<br />

China and India where non-wood pulps dominate, it is necessary to carry out research work on<br />

energy efficient and environmentally sound pulping for non-wood materials. For countries where<br />

limited or no energy conservation measures have been undertaken, installation <strong>of</strong> measuring<br />

equipment in <strong>th</strong>e processes and data <strong>ac</strong>quisition could help to plan and take <strong>ac</strong>tions in improving<br />

energy efficiency and reducing pollution from <strong>th</strong>e industry.<br />

As <strong>th</strong>is industry is an important water polluter, serious consideration should be given to recycle and<br />

reuse <strong>th</strong>e water wi<strong>th</strong>in <strong>th</strong>e plant as much as possible. Due to <strong>th</strong>e chemical content <strong>of</strong> pulp washing<br />

water, it is toxic for aquatic lives; <strong>th</strong>erefore improved chemical recovery me<strong>th</strong>ods should be<br />

pr<strong>ac</strong>ticed to recover as much chemicals as possible, which does not only reduce <strong>th</strong>e pollution load<br />

but also <strong>th</strong>e amount <strong>of</strong> chemical required for <strong>th</strong>e process. Burning fuels for power generation and in<br />

<strong>th</strong>e boilers is a source <strong>of</strong> air pollution. Any measure taken for energy efficiency improvement<br />

ultimately leads to reduction in air pollution loads.


50 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

6. PROFILE OF THE PULP AND PAPER INDUSTRY IN SELECTED ASIAN<br />

COUNTRIES<br />

This section evaluates <strong>th</strong>e current status and technological trajectory <strong>of</strong> <strong>th</strong>e pulp and paper industry<br />

in four <strong>Asian</strong> countries, namely China, India, <strong>th</strong>e Philippines and Sri Lanka.<br />

6.1 COUNTRY REPORT: CHINA<br />

6.1.1 Introduction<br />

The pulp and paper industry is one <strong>of</strong> <strong>th</strong>e most energy-intensive and polluting industries in China.<br />

In 1993, it <strong>ac</strong>counted for 9.8% <strong>of</strong> <strong>th</strong>e total industrial waste water discharge and 38.2% <strong>of</strong> <strong>th</strong>e total<br />

BOD discharge from <strong>th</strong>e industrial sector. Serious environmental pollution becomes increasingly<br />

un<strong>ac</strong>ceptable as it harms <strong>th</strong>e heal<strong>th</strong> <strong>of</strong> local residents and destroys <strong>th</strong>e local ecology. The Chinese<br />

government has been trying to tighten environmental regulations in order to reduce <strong>th</strong>e pollution<br />

level from paper mills. Implementation <strong>of</strong> <strong>th</strong>ese regulations, however, has encountered numerous<br />

difficulties due to <strong>th</strong>e complexities <strong>of</strong> <strong>th</strong>e industry.<br />

Low energy efficiency and high environmental pollution from <strong>th</strong>e pulp and paper industry are not<br />

only caused by <strong>th</strong>e b<strong>ac</strong>kwardness <strong>of</strong> technological f<strong>ac</strong>ilities, <strong>th</strong>ey are also consequences <strong>of</strong> <strong>th</strong>e<br />

industry’s organization in terms <strong>of</strong> plant distribution and ownership. Problems in <strong>th</strong>e industry<br />

should <strong>th</strong>erefore by analyzed in a systematic manner to take into consideration various inter<strong>ac</strong>tive<br />

f<strong>ac</strong>tors <strong>th</strong>at determine energy efficiency and environmental pollution.<br />

The objective <strong>of</strong> <strong>th</strong>is section is to find out <strong>th</strong>e determining f<strong>ac</strong>tors and major causes <strong>of</strong><br />

environmental pollution in <strong>th</strong>e pulp and paper industry. In what follows, an analysis <strong>of</strong> <strong>th</strong>e<br />

evolution <strong>of</strong> energy efficiency and environmental pollution in relation to its technological evolution<br />

is presented. Firstly, <strong>th</strong>e technological trajectory <strong>of</strong> <strong>th</strong>e pulp and paper industry is laid out, and<br />

secondly, an analysis <strong>of</strong> <strong>th</strong>e evolution <strong>of</strong> energy efficiency and assessment <strong>of</strong> <strong>th</strong>e environmental<br />

externalities is done. Then <strong>th</strong>e potential for energy efficiency improvement and pollution<br />

abatement <strong>th</strong>rough technological changes is analyzed. Finally, <strong>th</strong>e status <strong>of</strong> <strong>th</strong>e application <strong>of</strong> new<br />

technologies is presented and some recommendations for fur<strong>th</strong>er studies are proposed.<br />

6.1.1.1 Evolution <strong>of</strong> China’s pulp and paper industry<br />

It is well known <strong>th</strong>at <strong>th</strong>e ancient paper making technology was one <strong>of</strong> <strong>th</strong>e four famous ancient<br />

inventions <strong>of</strong> China. It is also <strong>ac</strong>knowledged <strong>th</strong>at China's ancient paper making technology had<br />

played a great role in <strong>th</strong>e global paper making industry, and in <strong>th</strong>e progress and dissemination <strong>of</strong><br />

human science and culture <strong>ac</strong>ross countries in <strong>th</strong>e history <strong>of</strong> human development.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 51<br />

The sole process used in <strong>th</strong>e pulp and paper mills in China, however, was <strong>th</strong>e simple manual<br />

operation me<strong>th</strong>od. Not until 1884, when Shanghai Huazhang Paper Mill was put into operation in<br />

East China, was <strong>th</strong>e m<strong>ac</strong>hine-made paper production technology introduced. The technology was<br />

invented in Europe in <strong>th</strong>e year 1799. The country’s pulp and paper industry developed slowly due<br />

to various internal as well as external reasons. By 1949, <strong>th</strong>e national m<strong>ac</strong>hine-made paper and<br />

paperboard production was only 108 <strong>th</strong>ousand tons compared to <strong>th</strong>e manual production <strong>of</strong> 120<br />

<strong>th</strong>ousand tons.<br />

Generally, <strong>th</strong>e features <strong>of</strong> Old China's paper making industry can be summarized as follows:<br />

- From <strong>th</strong>e point <strong>of</strong> view <strong>of</strong> paper making, manually operated paper production<br />

<strong>ac</strong>counted for two <strong>th</strong>irds, while m<strong>ac</strong>hine-made paper production <strong>ac</strong>counted for only<br />

one-<strong>th</strong>ird <strong>of</strong> <strong>th</strong>e total paper output.<br />

- From <strong>th</strong>e point <strong>of</strong> view <strong>of</strong> paper consumption, domestic mechanical paper production<br />

met just less <strong>th</strong>an one <strong>th</strong>ird <strong>of</strong> <strong>th</strong>e national demand. The rest was met by imports.<br />

- As for <strong>th</strong>e local distribution <strong>of</strong> <strong>th</strong>e industry <strong>ac</strong>ross China, mechanized paper making<br />

plants were found mainly in a few coastal provinces, while manually operated paper<br />

making mills were located mainly in several sou<strong>th</strong>ern provinces abundant in bamboo<br />

resources.<br />

- As far as mechanical paper making technology is concerned, most key m<strong>ac</strong>hine<br />

components needed for <strong>th</strong>e industry were imported from abroad because <strong>of</strong> <strong>th</strong>e severe<br />

l<strong>ac</strong>k <strong>of</strong> industrial infrastructure.<br />

6.1.1.2 Major <strong>ac</strong>hievements in China’s pulp and paper industry<br />

Since P.R. China was founded in 1949, a drastic change has occurred in its booming pulp and<br />

paper industry. By <strong>th</strong>e year 1992, China's pulp production, paper & paperboard production and<br />

national paper & paperboard consumption ranked <strong>th</strong>ird in <strong>th</strong>e world, after USA and Japan.<br />

China's current pulp and paper industry has developed since 1952, when its total mechanical paper<br />

& paperboard output was only 372,000 tons, to 17.25 million tons by <strong>th</strong>e year 1992 wi<strong>th</strong> a<br />

consistent annual grow<strong>th</strong> rate <strong>of</strong> 10%. Particularly during <strong>th</strong>e last decade, <strong>th</strong>e average grow<strong>th</strong> <strong>of</strong><br />

paper & paperboard production re<strong>ac</strong>hed 14%, a high value in <strong>th</strong>e history <strong>of</strong> world paper industry.<br />

Its gross output in 1993 re<strong>ac</strong>hed 61.12 billion Yuan, or 1.54% <strong>of</strong> <strong>th</strong>e total industry gross output<br />

value. Its net output <strong>of</strong> 15.1 billion Yuan <strong>ac</strong>counted for 1.18% <strong>of</strong> <strong>th</strong>e national industry value.<br />

Table 6.1.1 shows <strong>th</strong>e contribution <strong>of</strong> China's pulp, paper & paperboard production to <strong>th</strong>e world<br />

total. Table 6.1.2 gives <strong>th</strong>e situation <strong>of</strong> paper production and consumption in <strong>th</strong>e world and in <strong>th</strong>e<br />

country as well.


52 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.1.1 Status <strong>of</strong> China's mechanical pulp, paper & paperboard productions<br />

Year 1985 1986 1987 1988 1989 1990<br />

Share <strong>of</strong> pulp production in <strong>th</strong>e<br />

world output, %<br />

4.5 4.5 4.8 5.2 5.68 5.91<br />

Ranked position worldwide 7 7 7 7 6 5<br />

Share <strong>of</strong> <strong>th</strong>e world paper &<br />

paperboard production, %<br />

4.7 4.9 5.3 5.6 5.70 5.75<br />

Ranked position worldwide<br />

Sources: [1,2,3,10]<br />

6 5 4 4 4 4<br />

Table 6.1.2 Global paper industry production and consumption in 1990<br />

Item Number <strong>of</strong><br />

F<strong>ac</strong>tories<br />

Production<br />

cap<strong>ac</strong>ity<br />

(10 3 ton)<br />

Per capita<br />

consumption<br />

(kg)<br />

Superficial<br />

consumption<br />

(10 3 ton)<br />

Production<br />

(10 3 ton)<br />

(1) (2) (1) (2) (1) (2) (1) (2)<br />

China 250* 176* 15500 11000 12.6 14429 9838 13719 9500<br />

World 4372 1352 266253 183503 44.8 237107 160577 238781 160649<br />

China’s share in 5.7 13 5.8 6.0 ~6.09 5.98 ~ 5.70 ~ 5.91<br />

<strong>th</strong>e world (%)<br />

Notes: (1) Paper & paperboard; (2) Pulp<br />

6.13 5.75<br />

* The f<strong>ac</strong>tories counted here refer only to <strong>th</strong>ose wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> more <strong>th</strong>an 30,000<br />

ton/year.<br />

Source: [10]<br />

Figures 6.1.1 and 6.1.2 show China's pulp, paper & paperboard production.<br />

Though a considerable <strong>ac</strong>hievement has been made in China's Pulp & Paper Industry since 1949,<br />

<strong>th</strong>ere still exists a strong impetus to boost China's pulp & paper industry to meet its immense<br />

market demand for paper consumption by more <strong>th</strong>an 1.2 billion people. It can be seen from Table<br />

6.1.2 <strong>th</strong>at <strong>th</strong>e 1990 average paper & paperboard consumption per capita in China was still only a<br />

quarter <strong>of</strong> world average level. China's paper & paperboard consumption <strong>ac</strong>counted only for 6%<br />

<strong>of</strong> <strong>th</strong>e world’s total volume, while its population <strong>ac</strong>counted for some 20% <strong>of</strong> <strong>th</strong>e global<br />

population. In 1992, net imports <strong>of</strong> paper & paperboard re<strong>ac</strong>hed 2.34 million tons, and imported<br />

commercial pulp also re<strong>ac</strong>hed 600,000 ton to fill <strong>th</strong>e gap between domestic production and<br />

demand. Self-sufficiency rate for paper demand has decreased recently in line wi<strong>th</strong> China's<br />

escalating economic development. It is predicted by o<strong>th</strong>er relevant research <strong>th</strong>at China’s economy<br />

will maintain current aggressive grow<strong>th</strong> trend in a foreseeable period. By <strong>th</strong>e turn <strong>of</strong> <strong>th</strong>e century,<br />

its grow<strong>th</strong> rate will be maintained at 7-9%. According to a synchronous grow<strong>th</strong> principle <strong>of</strong> paper<br />

& paperboard consumption wi<strong>th</strong> GDP, <strong>th</strong>e grow<strong>th</strong> rate <strong>of</strong> domestic paper demand will also be<br />

maintained at 7-9%. This means <strong>th</strong>at <strong>th</strong>e market demand for paper in 2000 will re<strong>ac</strong>h 331 million<br />

tons.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 53<br />

Production 10,000 tonne<br />

Production 10,000 tonne<br />

1800<br />

1600<br />

1400<br />

1200<br />

1000<br />

800<br />

600<br />

400<br />

200<br />

total<br />

manual<br />

mechanical<br />

0<br />

1940 1950 1960 1970 1980 1990 2000<br />

Figure 6.1.1 Production <strong>of</strong> paper & paperboard in China since 1949<br />

1000<br />

900<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

0<br />

1945 1950 1955 1960 1965 1970 1975 1980 1985 1990<br />

Figure 6.1.2 M<strong>ac</strong>hine-made pulp production in China since 1949


54 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Though paper & paperboard consumption <strong>of</strong> China was at number 3 in <strong>th</strong>e world in 1992, its<br />

average consumption per capita was only 16.7 kg per person, or less <strong>th</strong>an one half <strong>of</strong> <strong>th</strong>e world<br />

average value <strong>of</strong> 45.3 kg per person. If <strong>th</strong>is indicator for China is to re<strong>ac</strong>h one half <strong>of</strong> <strong>th</strong>e world<br />

average level by 2000, a production increment <strong>of</strong> more <strong>th</strong>an 10 million tons from 1992's 17.25<br />

million tons will <strong>th</strong>en be required.<br />

Considering <strong>th</strong>erefore <strong>th</strong>e impossibility <strong>of</strong> too much dependence on imports to meet <strong>th</strong>e domestic<br />

paper market demand, China’s pulp and paper industry in <strong>th</strong>e foreseeable future calls for a fast and<br />

sustainable development.<br />

6.1.2 Technological trajectory <strong>of</strong> China’s paper industry<br />

6.1.2.1 Pulp and paper production and development<br />

In 1949, m<strong>ac</strong>hine-made paper output <strong>ac</strong>counted only for 47% <strong>of</strong> total volume. By 1985, <strong>th</strong>e share<br />

<strong>of</strong> mechanical paper to <strong>th</strong>e total output rose to 97.9%. Manually operated paper production (less<br />

<strong>th</strong>an 366,000 tons, <strong>th</strong>e peak volume in 1932) is reserved for some special kinds <strong>of</strong> traditional<br />

papers such as <strong>th</strong>e most famous Xuanzi. Figure 6.1.3 illustrates <strong>th</strong>e evolution <strong>of</strong> China's mechanical<br />

paper making capability.<br />

Production Cap<strong>ac</strong>ity million ton<br />

20<br />

18<br />

16<br />

14<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

1945 1950 1955 1960 1965 1970 1975 1980 1985 1990 1995<br />

Figure 6.1.3 Production cap<strong>ac</strong>ities <strong>of</strong> China's paper & paperboard


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 55<br />

Before 1949, <strong>th</strong>e types <strong>of</strong> mechanical papers were only several dozens, wi<strong>th</strong> some common kinds<br />

for printing, writing, p<strong>ac</strong>kaging, etc. The key reason for <strong>th</strong>is was <strong>th</strong>e severe l<strong>ac</strong>k <strong>of</strong> mechanical<br />

manuf<strong>ac</strong>turing capability. Along wi<strong>th</strong> <strong>th</strong>e rapid grow<strong>th</strong> <strong>of</strong> mechanical pulp and paper production<br />

cap<strong>ac</strong>ity, <strong>th</strong>e number <strong>of</strong> types <strong>of</strong> various paper & paperboard has also increased to a great extent.<br />

Wi<strong>th</strong>in <strong>th</strong>e first five-year planning period, for instance, newly-added types <strong>of</strong> paper re<strong>ac</strong>hed 79,<br />

including paper s<strong>ac</strong>k, condenser paper, blue print base paper, pictorial paper, fax paper, etc. By <strong>th</strong>e<br />

end <strong>of</strong> 1985, <strong>th</strong>e total number <strong>of</strong> paper & paperboard products in China increased to more <strong>th</strong>an<br />

five hundred, a number which could meet all sectoral basic demands. The types <strong>of</strong> pulp also<br />

increased simultaneously wi<strong>th</strong> <strong>th</strong>e increased demand for diverse kinds <strong>of</strong> paper products during <strong>th</strong>e<br />

same period. The share <strong>of</strong> various paper & paperboard products in China in 1992 is shown in<br />

Table 6.1.3.<br />

Table 6.1.3 Composition <strong>of</strong> types <strong>of</strong> paper and paperboard in China in 1992<br />

Type Press &<br />

printing<br />

Writing<br />

paper<br />

P<strong>ac</strong>kin<br />

g paper<br />

Industrial<br />

paper<br />

Paperboard Living<br />

&<br />

o<strong>th</strong>er<br />

Share(%) 25 10.6 11 3.0 42 8.4<br />

The quality <strong>of</strong> <strong>th</strong>e different paper & paperboard products has also been improving gradually. By<br />

1985, six products were honored as <strong>th</strong>e State Golden Quality Products, 46 products as State Silver<br />

Quality Products and o<strong>th</strong>er 176 products as Light Industry Excellent Quality Products. For<br />

example, a paper for computer use made by <strong>th</strong>e Shandong Paper Mill General, is regarded to be <strong>of</strong><br />

good quality from all major technical performance indicators, and is reckoned to catch up wi<strong>th</strong><br />

and/or exceed international levels <strong>of</strong> paper <strong>of</strong> <strong>th</strong>e same kind. Ano<strong>th</strong>er example is <strong>th</strong>e Chinesemade<br />

toilet papers which held a 90% share <strong>of</strong> <strong>th</strong>e market in <strong>th</strong>e Hong Kong area in 1986.<br />

The much increased number <strong>of</strong> product types as well as <strong>th</strong>e much improved quality <strong>of</strong> paper<br />

product embody <strong>th</strong>e rise <strong>of</strong> <strong>th</strong>e technical level in <strong>th</strong>e Chinese paper industry.<br />

6.1.2.2 Development <strong>of</strong> pulp & paper enterprises<br />

In <strong>th</strong>e context <strong>of</strong> China, pulp and paper mills can be classified into <strong>th</strong>ree categories in terms <strong>of</strong><br />

<strong>th</strong>eir cap<strong>ac</strong>ity <strong>of</strong> production: large mills wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> more <strong>th</strong>an 30,000 tons/year; medium<br />

size mills wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 10,000 to 30,000 tons/year; and small mills wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> less <strong>th</strong>en<br />

10,000 tons/year.<br />

In 1949, <strong>th</strong>ere were only little more <strong>th</strong>an 100 mills <strong>ac</strong>ross <strong>th</strong>e country. By <strong>th</strong>e end <strong>of</strong> 1992,<br />

however, <strong>th</strong>e number <strong>of</strong> paper mills increased to more <strong>th</strong>an 9,000 [13]. From Chinese statistics<br />

[11], <strong>th</strong>e number <strong>of</strong> total enterprises was 11,940. The production <strong>of</strong> <strong>th</strong>e biggest scale paper mill<br />

increased from 30,000 to more <strong>th</strong>an 150,000 tons/year. Among <strong>th</strong>em, 1665 paper mills belonged<br />

to <strong>th</strong>e China Light Industry Commission (CLIC, i.e., <strong>th</strong>e former Light Industry Ministry <strong>of</strong> China)


56 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

wi<strong>th</strong> an average enterprise scale <strong>of</strong> around 4700 tons/year. The o<strong>th</strong>er mills belonged to <strong>th</strong>e<br />

agriculture, forest or rural township systems wi<strong>th</strong> an average enterprise scale <strong>of</strong> only 1842<br />

tons/year. Thus, <strong>th</strong>e national average paper mill cap<strong>ac</strong>ity was only about 2500 tons/year. In<br />

comparison, <strong>th</strong>e average pulp mill cap<strong>ac</strong>ity in some industrialized countries is 170,000 tons/year,<br />

wi<strong>th</strong> <strong>th</strong>e average output being 61 <strong>th</strong>ousand tons per unit paper and paperboard mill. The large<br />

number <strong>of</strong> dispersed paper making enterprises wi<strong>th</strong> smaller cap<strong>ac</strong>ities is considered to be <strong>th</strong>e main<br />

reason for bad scale-benefit, low management level, lagging behind technical level as well as severe<br />

environmental pollution.<br />

In most cases, China’s paper enterprises are integrated pulp and paper mills, while <strong>th</strong>ose which<br />

solely produce commercial pulp number a few. Only a minority <strong>of</strong> paper mills located in urban<br />

areas use commercial pulp or waste paper for production.<br />

88%<br />

large scale medium scale<br />

small scale<br />

2%<br />

10%<br />

57%<br />

28%<br />

large scale medium scale small scale<br />

Figure 6.1.4 Composition <strong>of</strong> paper mills and <strong>th</strong>eir contribution to <strong>th</strong>e total production<br />

Not all paper enterprises belong to <strong>th</strong>e China Light Industry Commission (CLIC) or <strong>th</strong>e<br />

pr<strong>of</strong>essional management ministry for light industrial products such as paper, sugar, glass, wine,<br />

etc. The agricultural sector (including rural township and reclamation systems), forest sector and<br />

military systems have <strong>th</strong>eir own paper mills. In township paper mills, <strong>th</strong>e dominant process is<br />

ei<strong>th</strong>er <strong>th</strong>e lime-based yellow strawboard production or p<strong>ac</strong>kaging-paper production by recovery <strong>of</strong><br />

waste paper. Most mills belonging to <strong>th</strong>e forest system mainly use timber materials to produce<br />

unble<strong>ac</strong>hed pulp and/or paperboard. Those belonging to <strong>th</strong>e agricultural reclamation and military<br />

systems are usually straw-based integrated mills. This complex mix creates a barrier for <strong>th</strong>e<br />

pr<strong>of</strong>essional management <strong>of</strong> <strong>th</strong>e pulp and paper industry.<br />

15%


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 57<br />

6.1.2.3 Technological progress in China’s pulp and paper industry<br />

a. Technological events<br />

In <strong>th</strong>e course <strong>of</strong> <strong>th</strong>e paper industry’s technological development, two aspects were equally focused<br />

and combined. One, it deeply depended on domestic R&D capability and diffusion <strong>of</strong> domestic<br />

advanced experiences and technologies. Second, much efforts were pl<strong>ac</strong>ed on introducing foreign<br />

advanced technologies and equipment as well as learning and digesting internationally advanced<br />

expertise. Some important milestones in <strong>th</strong>e progress <strong>of</strong> <strong>th</strong>e paper making technology in China can<br />

be briefly depicted as follows:<br />

- During <strong>th</strong>e 1950s, a series <strong>of</strong> Fourdrinier paper m<strong>ac</strong>hines and auxiliary f<strong>ac</strong>ilities, e<strong>ac</strong>h<br />

wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 50 tons/day, were designed and manuf<strong>ac</strong>tured by domestic R&D<br />

experts for some key expansion projects.<br />

- In 1957, <strong>th</strong>e first ejection furn<strong>ac</strong>e made in China for alkali recovery was installed in<br />

Jiamusi Paper Mill.<br />

- In <strong>th</strong>e meantime, some large cap<strong>ac</strong>ity paper making m<strong>ac</strong>hines <strong>of</strong> 100, 150, or 200<br />

tons/day cap<strong>ac</strong>ity were imported. Log-milling m<strong>ac</strong>hines <strong>of</strong> international standards were<br />

also imported.<br />

- Around 1970, some key imported foreign equipment included continuous digester <strong>of</strong><br />

straw pulp, pressurized pulp ble<strong>ac</strong>hing m<strong>ac</strong>hines, ejection furn<strong>ac</strong>es for alkali recovery,<br />

150 tons/day heat wood-chip milling m<strong>ac</strong>hines, etc.<br />

- Some domestically developed technologies, such as on-line moisture control system,<br />

paper fold-pressing technology & mill pulp making were popularized in national paper<br />

mills.<br />

- Alkali recovery capability from pulp making bl<strong>ac</strong>k liquor increased from a trifle in 1957<br />

to 362,200 ton/year in 1988 or 36.66% <strong>of</strong> <strong>th</strong>e total alkali consumption for <strong>th</strong>e year. In<br />

Qingzhou Paper Mill, Nanping Paper Mill and Jiamusi Paper Mill, production-needed<br />

alkali can approximately be provided by <strong>th</strong>eir alkali recovery systems. Electrostatic<br />

precipitators were also disseminated to large and medium size paper mills, which proved<br />

beneficial bo<strong>th</strong> for alkali recovery and for dust prevention. Figure 6.1.5 illustrates <strong>th</strong>e<br />

grow<strong>th</strong> curve <strong>of</strong> alkali recovery from 1979.<br />

- The capability <strong>of</strong> integrated exploitation <strong>of</strong> sulfite pulp wastewater for production <strong>of</strong><br />

some by-products was also boosted


58 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

- Since 1968, <strong>th</strong>e new process <strong>of</strong> utilizing ammonium bisulfite straw pulp has been<br />

popularized in many small paper mills in Shandong, Sichuan and o<strong>th</strong>er provinces. Using<br />

<strong>th</strong>is process, wastewater can be directly used for farm irrigation.<br />

- Since 1978, new systems for loop or cycle utilization <strong>of</strong> clean water in paper mills were<br />

created, e.g. tilt-plate precipitating me<strong>th</strong>od in Tianjing Paper Mill, tilt-tube precipitating<br />

me<strong>th</strong>od in Shanghai Vanguard Paper Mill, and air buoyancy me<strong>th</strong>od in Suzhou Huashen<br />

Paper Mill.<br />

1000 ton<br />

400<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

Cap<strong>ac</strong>ity<br />

Production<br />

0<br />

1979 1980 1982 1984 1986 1988<br />

Year<br />

Figure 6.1.5 Grow<strong>th</strong> curves <strong>of</strong> alkali recovery from 1979 to 1988<br />

b. Technological advances wi<strong>th</strong> imported foreign technologies, f<strong>ac</strong>ilities and equipment<br />

Since <strong>th</strong>e early 1980s, <strong>th</strong>e scale <strong>of</strong> technology import has been increasing step by step so as to<br />

narrow <strong>th</strong>e technical gap between <strong>th</strong>e paper industry <strong>of</strong> China and <strong>th</strong>e developed countries. From<br />

1980 to 1988, about US$ 300 million had been spent to update <strong>th</strong>e pulp and papermaking<br />

technologies and equipment in <strong>th</strong>e country. It is also estimated <strong>th</strong>at more <strong>th</strong>an US$ 1 billion had<br />

been spent for importing technologies and equipment from 1989 to 1995. The technology<br />

processes adopted toge<strong>th</strong>er wi<strong>th</strong> <strong>th</strong>e import <strong>of</strong> equipment are listed below:<br />

- Technological transformation, upgrading and/or overhauling in some state-owned key<br />

enterprises: 150 t/d paper m<strong>ac</strong>hine transformation at <strong>th</strong>e Qinzhou Paper Mill, combined<br />

wi<strong>th</strong> <strong>th</strong>e installation <strong>of</strong> advanced equipment from Beloit Corp. (<strong>th</strong>e project proved to be<br />

very successful and brought about 50% increment in production cap<strong>ac</strong>ity, better quality<br />

<strong>of</strong> paper s<strong>ac</strong>k product and new type <strong>of</strong> elastic paper s<strong>ac</strong>k); 200 t/d paper m<strong>ac</strong>hine<br />

transformation at <strong>th</strong>e Jiamusi Paper Mill; 100 t/d paper m<strong>ac</strong>hine transformations at <strong>th</strong>e


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 59<br />

Yueyang and Liujiang Paper Mills; and Nanpin No. 1 paper m<strong>ac</strong>hine transformations<br />

which was a typical case <strong>of</strong> optimum adoption <strong>of</strong> imported equipment to match wi<strong>th</strong> <strong>th</strong>e<br />

local situation.<br />

- Installation <strong>of</strong> new and advanced technology and equipment, including exhausted heat<br />

recovery equipment from Sweden for a 150 t/d TMP production line at Jilin Pulp &<br />

Paper Mill, enabling it to produce CTMP and make newsprint paper; 60 t/d<br />

sulf<strong>of</strong>ication CMP line imported from Finland at <strong>th</strong>e Shiyan Pulp and Paper Mill;<br />

horizontal continuous digesters <strong>of</strong> Sunds Defibration Corp. <strong>of</strong> Sweden installed at<br />

Jiaozuo, Dezhou, Fuzhou and Jihe, etc.; <strong>th</strong>e first set <strong>of</strong> Swedish Kamyr’s Vertical<br />

Continuous Digester installed at Yibin Paper Mill; plank-style membrane vaporizer and<br />

concentrator from Finland Ahlstrom Corp. installed at <strong>th</strong>e Jiamusi and Liujiang paper<br />

mills; white silt kiln imported from <strong>th</strong>e same corporation for Jilin Paper Mill; horizontal<br />

belt-style v<strong>ac</strong>uum washer for spent sulfite liquor (so-called red liquor) from English<br />

Bl<strong>ac</strong>k Clawson Corp. installed at Kaisan Pulp Mill and Guangzhou Paper Mill; de-inking<br />

equipment <strong>of</strong> <strong>th</strong>e same corporation at Beijing’s No. 1 Paper Mill; nearly 50 sets <strong>of</strong><br />

constant moisture-control systems for paper making from Measurex Corp. and Accupay<br />

Corp. <strong>of</strong> USA and Lippka Corp. <strong>of</strong> Germany, etc., which can stabilize paper moisture<br />

and paper mass; coated paper m<strong>ac</strong>hine and coating material process line imported from<br />

France and Germany at Shanghai Jiangnan Pulp & Paper Mill. Besides <strong>th</strong>e abovementioned<br />

state-<strong>of</strong>-art technological equipment from <strong>th</strong>e industrialized countries, a<br />

number <strong>of</strong> second-hand paper m<strong>ac</strong>hines and paperboard m<strong>ac</strong>hines were also purchased<br />

at costs <strong>of</strong> about one fif<strong>th</strong> to one ten<strong>th</strong> <strong>th</strong>at <strong>of</strong> <strong>th</strong>e brand-new ones.<br />

c. Recent developments in <strong>th</strong>e domestic production process and equipment<br />

Some dominant home-developed technological advances since 1990 include:<br />

- Large-size alkali recovery furn<strong>ac</strong>es wi<strong>th</strong> cap<strong>ac</strong>ities <strong>of</strong> 200 and 300 t/d have been built at<br />

Jiamusi and Jilin paper mills, respectively. Fur<strong>th</strong>ermore, a set <strong>of</strong> alkali recovery furn<strong>ac</strong>e<br />

wi<strong>th</strong> <strong>th</strong>e biggest pulp-dealing cap<strong>ac</strong>ity <strong>of</strong> 1000 t/d was exported to Indonesia.<br />

- Small-size whole system equipment <strong>of</strong> 30 t/d CTMP cap<strong>ac</strong>ity has been successfully<br />

manuf<strong>ac</strong>tured in Shanghai and put into operation in Fujian Province.<br />

- Several sets <strong>of</strong> locally made horizontal-tube continuous digester <strong>of</strong> 50 t/d straw pulp<br />

making cap<strong>ac</strong>ity have been made and put into operation in China, after importing and<br />

adapting relative technologies from Swedish Sunds Corp.<br />

- New jam-pro<strong>of</strong> energy-saving pump for pulp transport was designed successfully wi<strong>th</strong> an<br />

energy conservation benefit <strong>of</strong> 20% compared to conventional pumps. These pumps


60 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

were installed at a dozen paper mills, proving additional comp<strong>ac</strong>t, low-noise and little<br />

oscillation features.<br />

- Locally made new v<strong>ac</strong>uum pulp washers wi<strong>th</strong> 35 m 2 area were used at some newly built<br />

paper projects.<br />

- As an advancement in <strong>th</strong>e bl<strong>ac</strong>k liquor vaporization system, a whole set <strong>of</strong> plate-style<br />

membrane vaporizer systems (wi<strong>th</strong> 50% higher efficiency <strong>th</strong>an <strong>th</strong>e old ones and bigger<br />

load) have been commissioned at <strong>th</strong>e Qinzhou Pulp & Paper Mill.<br />

- Small-size domestic-made waste paper disposing and de-inking systems have been put<br />

into operation at Xingshi Paper Mill.<br />

- High intensity press and polyester dry net for repl<strong>ac</strong>ement <strong>of</strong> conventional dry canvas in<br />

<strong>th</strong>e process <strong>of</strong> papermaking.<br />

- Heat pump systems for <strong>th</strong>e paper m<strong>ac</strong>hine’s dryer section were used at Minfen Pulp &<br />

Paper Group, Tianjing Paper Mill and Qiqihar Pulp & Paper Mill. Their operations<br />

showed <strong>th</strong>at specific steam consumptions per ton <strong>of</strong> paper were reduced by 29.4%,<br />

28.3% and 36.6%, respectively. The heat pump-based technology can substitute<br />

conventional two- or <strong>th</strong>ree-stage cascade system, making full use <strong>of</strong> steam <strong>th</strong>ermal<br />

energy and available energy to remove condensate smoo<strong>th</strong>ly.<br />

During <strong>th</strong>e last four decades, China’s researchers in <strong>th</strong>e paper field have made many more<br />

<strong>ac</strong>hievements, including <strong>th</strong>e development <strong>of</strong> new types <strong>of</strong> raw materials for pulp making,<br />

development <strong>of</strong> new types <strong>of</strong> paper & paperboard, retr<strong>of</strong>itting or improvement <strong>of</strong> pulping<br />

processes, R&D for some key equipment, integrated utilization <strong>of</strong> digested wastewater,<br />

development and utilization <strong>of</strong> emulsion materials, filling materials and o<strong>th</strong>er chemical agents in<br />

<strong>th</strong>e paper producing processes, as well as some basic <strong>ac</strong>ademic researches in universities and<br />

research institutes. As for wastewater pollution abatement, eight key <strong>ac</strong>hievements have also been<br />

made concerning chemical agents recovery, sulfite pulping wastewater integrated exploitation, biochemical<br />

treatment <strong>of</strong> pulping wastewater, etc.<br />

6.1.2.4 Two prominent technological char<strong>ac</strong>teristics<br />

In <strong>th</strong>e mixes <strong>of</strong> pulp production, <strong>th</strong>ere exists an eminent char<strong>ac</strong>teristic for China's paper industry,<br />

i.e., straw-material-made pulp holds a dominant share in <strong>th</strong>e mix (grass-straw pulp 63%), while<br />

wood pulp <strong>ac</strong>counted for as low as 26% in <strong>th</strong>e mix. It is well known <strong>th</strong>at using wood as a pulping<br />

raw material is better <strong>th</strong>an using straw from <strong>th</strong>e point <strong>of</strong> view <strong>of</strong> pulp production efficiency,<br />

environmental protection, or from wood material's economical utilization. At present, wood<br />

material <strong>ac</strong>counts for more <strong>th</strong>an 90% <strong>of</strong> <strong>th</strong>e global pulp production.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 61<br />

Ano<strong>th</strong>er problem existing in China’s paper industry is <strong>th</strong>e very low level <strong>of</strong> waste paper recycling.<br />

In 1988, waste-paper pulp (including imported waste paper) <strong>ac</strong>counted for 22.5% only, while <strong>th</strong>e<br />

same indicators for Japan and European Union were 50% and 48%, respectively. A higher<br />

percentage <strong>of</strong> waste paper pulp in <strong>th</strong>e total pulp production is beneficial for resource conservation,<br />

energy savings and environmental protection.<br />

Generally, China’s pulp & paper industry has made a great technological <strong>ac</strong>hievement, <strong>th</strong>ough<br />

some problems should be solved when f<strong>ac</strong>ing <strong>th</strong>e next century.<br />

6.1.3 Evolution <strong>of</strong> energy efficiency in Chinese pulp & paper industry<br />

6.1.3.1 General situation <strong>of</strong> energy consumption<br />

The pulp & paper industry <strong>of</strong> China is <strong>th</strong>e biggest energy consuming industry among all light<br />

industries. Table 6.1.4 shows <strong>th</strong>e overall energy consumption <strong>of</strong> <strong>th</strong>e industry, while Table 6.1.5<br />

and Figure 6.1.6 show <strong>th</strong>e unit energy consumption <strong>of</strong> its major products. Table 6.1.6 shows <strong>th</strong>e<br />

unit energy consumption for 870 paper mills belonging to <strong>th</strong>e CLIC from 1985 to 1990.<br />

Table 6.1.4 Overall energy consumption by <strong>th</strong>e industry from 1985 to 1992<br />

Indicator Coal<br />

Electricity<br />

Total<br />

10,000 ton billion kWh 10,000 toe<br />

Year 1985 1990 1992 1985 1990 1992 1985 1990 1992<br />

Data<br />

Share in<br />

1251 1640 1787 8.09 11.98 13.97 847.5 1109 1240<br />

national total<br />

%<br />

Source: [11]<br />

1.53 1.55 1.57 1.96 1.92 1.84 1.69 2.13 1.74<br />

Table 6.1.5 Unit product energy consumption in <strong>th</strong>e paper industry<br />

Item Unit 1980 1985 1988 1989 1990<br />

Electricity consumption for wood KWh/to 1522 1588 1560 1566<br />

pulp<br />

n<br />

SOE consumption for total pulp toe/ton 0.419 0.406 0.445<br />

Electricity for newsprint KWh/to<br />

n<br />

556 565 568 583<br />

SOE for paper & paperboard toe/ton 0.99 0.60 0.57<br />

Integrated energy consumption toe/ton 1.257 0.910 0.805<br />

Source: [6,12], bo<strong>th</strong> SOE and oe are standard oil equivalent


62 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.1.6 Specific energy consumption <strong>of</strong> major products for 870 paper mills <strong>of</strong> CLIC<br />

Indicator Unit 1985 1988 1989 1990<br />

Integrated<br />

consumption<br />

specific energy toe/t 1.07 1.01 1.01<br />

Mechanical wood pulp kWh/t 1522 1588 1560 1566<br />

Newsprint<br />

Source: [1, 3]<br />

kWh/t 556 565 568 583<br />

Though integrated unit energy consumption has decreased in recent years, <strong>th</strong>e unit electricity<br />

consumption for mechanical wood pulp and newsprint increased on <strong>th</strong>e contrary.<br />

For <strong>th</strong>e same paper & paperboard products, specific energy consumption values <strong>of</strong> non-CLIC<br />

paper mills are generally higher <strong>th</strong>an <strong>th</strong>at <strong>of</strong> CLIC ones, except for <strong>th</strong>e township case. The reason<br />

for <strong>th</strong>e very low specific energy consumption <strong>of</strong> <strong>th</strong>e latter is <strong>th</strong>e low quality <strong>of</strong> its products and <strong>th</strong>e<br />

simple, crude equipment being employed. Table 6.1.7 gives a comparison <strong>of</strong> <strong>th</strong>e unit energy<br />

consumption <strong>of</strong> paper mills among various sectors.<br />

ton ce/ton(paper & paperboard)<br />

2.5<br />

2<br />

1.5<br />

1<br />

0.5<br />

0<br />

1981 1984 1985<br />

Year<br />

1990 1992<br />

Figure 6.1.6 Integrated energy consumption <strong>of</strong> <strong>th</strong>e paper industry in China<br />

Table 6.1.7 Specific energy consumption by various owners (1990)<br />

Item National CLIC Agricultural system Forest Military<br />

total Reclamation Township system system<br />

Production, Mt 13.72 7.71 0.38 5.23 0.10 0.30<br />

Energy consumption (103 toe)<br />

Specific energy consumption<br />

11086 7330 377 2982 99 299<br />

<strong>of</strong> paper & paper board, toe/t<br />

Source: [1]<br />

0.805 0.949 0.995 0.569 0.995 0.995


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 63<br />

From 1985 to 1990, energy consumption per 10,000 Yuan gross output volume (in 1980 fixed<br />

price) <strong>of</strong> paper industry wi<strong>th</strong>in CLIC system decreased from 3.93 toe/10,000 Yuan to 3.01<br />

toe/10,000 Yuan. The energy consumption elasticity was 0.28, and <strong>th</strong>e annual average energy<br />

saving rate was 5.33% during <strong>th</strong>e period. It should be noted <strong>th</strong>at <strong>th</strong>e decrease <strong>of</strong> energy<br />

consumption cannot be fully attributed to direct energy conservation via technology or process<br />

advances. Two aspects can be highlighted for <strong>th</strong>e decrease. One is <strong>th</strong>e change in product mix and<br />

<strong>th</strong>e emergence <strong>of</strong> new high value-added paper products. The o<strong>th</strong>er is <strong>th</strong>e change in raw material<br />

mix, i.e., grow<strong>th</strong> <strong>of</strong> imported commercial pulp and waste paper as secondary fibrous raw material.<br />

These two f<strong>ac</strong>tors enable <strong>th</strong>e paper industry to augment its production and output wi<strong>th</strong>out any<br />

proportional increase in energy demand.<br />

6.1.3.2 Major endeavors for <strong>th</strong>e progress in energy efficiency<br />

From <strong>th</strong>e above tables and Figure 6.1.6, it can be seen <strong>th</strong>at <strong>th</strong>e integrated energy consumption<br />

indicator decreased by 42.7% from 1981 to 1992 wi<strong>th</strong> an average annual reduction rate <strong>of</strong> 5.2%.<br />

Therefore, much energy conservation was obtained <strong>th</strong>roughout <strong>th</strong>is period. The main causes can<br />

be attributed to <strong>th</strong>e following:<br />

- Enhancement <strong>of</strong> enterprise energy management from all aspects including setting up a<br />

national energy conservation network, holding energy management/saving training<br />

workshops, issuing rated energy consumption norms for special paper products in<br />

August 1985 (four grades for a paper product: Testing Norm, Average Advanced Norm,<br />

Domestic Pr<strong>of</strong>essional Advanced Norm and International Advanced Norm).<br />

- Retr<strong>of</strong>itting some old and low efficiency boilers, remolding a batch <strong>of</strong> oil-fired boilers<br />

into coal-fired boilers (under <strong>th</strong>e stringent oil energy supply situation) and improving<br />

technical skills <strong>of</strong> operators.<br />

- Enhancement <strong>of</strong> <strong>th</strong>ermal insulating performance <strong>of</strong> steam tubes and digester equipment.<br />

- Popularizing and disseminating some energy saving equipment such as Electric Loci<br />

V<strong>ac</strong>uum Fans, Pan mills and double-paned mills, speed-adjustable electrical fans,<br />

electricity-saving appliances, etc..<br />

- By 1991, more <strong>th</strong>an sixty large scale pulp & paper mill cogeneration plants were installed<br />

wi<strong>th</strong> a total power cap<strong>ac</strong>ity <strong>of</strong> 473 MW. Of <strong>th</strong>ese, 422 MW cap<strong>ac</strong>ity belonged to <strong>th</strong>irty<br />

key enterprises. For comparison, cogeneration cap<strong>ac</strong>ity in 1949 was only 10 MW. In<br />

1990, power generation by cogeneration plants amounted to 1.65 billion kWh. At <strong>th</strong>e<br />

same time, newly-built large and/or medium scale paper mills had <strong>th</strong>eir own<br />

cogeneration plants [5].


64 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

- A number <strong>of</strong> technological transformations for paper making m<strong>ac</strong>hine parts had been<br />

implemented, including white liquor recovery, dryer condensate recovery, <strong>th</strong>ree-stage<br />

steam feed, etc..<br />

- Minicomputer-based systems had been primarily used for <strong>th</strong>e cooking process and<br />

automation control for constant moisture content <strong>of</strong> paper in <strong>th</strong>e paper making process.<br />

- Since 1980, much efforts have been made to popularize and disseminate energy-saving<br />

spray nozzles as well as white liquor circulation recovery. This has led to <strong>th</strong>e decrease in<br />

specific water consumption in <strong>th</strong>e paper making process. For example, utilization <strong>of</strong> a<br />

fan-pattern spray nozzle can bring about water savings <strong>of</strong> 18-20%. Adoption <strong>of</strong> white<br />

liquor circulating loop can enable specific water consumption to decrease from 200-300<br />

m 3 to 50 m 3 <strong>of</strong> water per ton <strong>of</strong> paper.<br />

6.1.3.3 Comparison <strong>of</strong> <strong>th</strong>e energy consumption <strong>of</strong> Chinese pulp & paper industry wi<strong>th</strong><br />

o<strong>th</strong>er countries<br />

The overall energy consumption level in China’s pulp and paper industry is much higher when<br />

compared to its foreign counterparts in spite <strong>of</strong> <strong>th</strong>e above <strong>ac</strong>hievements in energy conservation<br />

during <strong>th</strong>e last years.<br />

As for <strong>th</strong>e integrated unit energy consumption <strong>of</strong> paper & paperboard product, <strong>th</strong>e indicator in <strong>th</strong>e<br />

United States had decreased to 1.17 tce/ton <strong>of</strong> paper and paperboard (0.766 toe/t) as early as <strong>th</strong>e<br />

mid-70s[12], which means <strong>th</strong>at China's energy level lags some 20 years behind <strong>th</strong>at <strong>of</strong> <strong>th</strong>e USA.<br />

By <strong>th</strong>e end <strong>of</strong> <strong>th</strong>e 1970s, <strong>th</strong>e same indicator in industrialized countries generally went down to <strong>th</strong>e<br />

level <strong>of</strong> 1.15 - 1.22 tce/t (0.753-0.798 toe/t), which was only 64% or even less <strong>th</strong>an China's value at<br />

<strong>th</strong>e same time.[12] In 1989, integrated energy consumption for Japanese pulp & paper industry<br />

was 14.5 GJ/ton* or 0.495 tce/ton (0.324 toe/t), which was only 40% <strong>th</strong>at <strong>of</strong> China. A<br />

comparison <strong>of</strong> <strong>th</strong>e unit energy consumption <strong>of</strong> China and some developed countries, and <strong>th</strong>e<br />

world average level are shown in Figure 6.1.7 and Table 6.1.8.<br />

* 1 tce = 0.654 toe = 29.31 GJ and 1 toe = 44.76 GJ


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 65<br />

ton ce/ton(paper & paperboard)<br />

1.4<br />

1.2<br />

1<br />

0.8<br />

0.6<br />

0.4<br />

0.2<br />

0<br />

Advanced in<br />

Nor<strong>th</strong>Europe<br />

Australia England<br />

newsprint Newsprint newsprit (low<br />

(low limit)<br />

limit)<br />

England<br />

newsprint<br />

(up limit)<br />

USA<br />

newsprint<br />

Japan P.R.China<br />

Figure 6.1.7 Comparison <strong>of</strong> integrated energy consumption among various countries<br />

Table 6.1.8 Domestic and international integrated product energy consumption<br />

Minimum energy<br />

consumption<br />

toe/t<br />

Maximum energy<br />

consumption toe/t<br />

Average level<br />

toe/t<br />

China 0.818 1.113 1.010<br />

World 0.330 0.779 0.556<br />

6.1.3.4 Main reasons for <strong>th</strong>e low efficiency energy situation in <strong>th</strong>e paper industry<br />

There are many complex reasons for <strong>th</strong>e low energy efficiency in China. The most prominent<br />

among <strong>th</strong>em are identified as follows.<br />

First, <strong>th</strong>ere are more <strong>th</strong>an 10,000 paper enterprises, most <strong>of</strong> which are small in size (wi<strong>th</strong> an<br />

average per enterprise scale <strong>of</strong> 2550 ton/year), owned by diverse sectors and township industries.<br />

Most <strong>of</strong> <strong>th</strong>ese small paper mills use straw as raw material wi<strong>th</strong>out any recovery <strong>of</strong> ei<strong>th</strong>er valuable<br />

chemicals or <strong>th</strong>ermal energy. Such small scale pulp and paper mills are reputed not to be adopting<br />

alkali recovery processes, cogeneration, as well as o<strong>th</strong>er high-energy, high efficiency technologies.<br />

These mills are also not easily monitored for <strong>th</strong>eir energy consumption due to <strong>th</strong>e severe l<strong>ac</strong>k <strong>of</strong><br />

technical streng<strong>th</strong>. Moreover, many entrepreneurs do not care about <strong>th</strong>eir f<strong>ac</strong>tories' energy<br />

efficiency for some complex reasons.


66 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Second, wi<strong>th</strong> regard to large size paper mills, <strong>th</strong>ere still exists a big gap between <strong>th</strong>e most energy<br />

efficient enterprises and <strong>th</strong>e lowest ones. A survey conducted in 1986 in 32 key enterprises showed<br />

<strong>th</strong>at <strong>th</strong>e average integrated energy consumption was about 1.48 tce/t (0.969 toe/t). The indicator<br />

for <strong>th</strong>e most energy efficient enterprise was 0.78, which can compete wi<strong>th</strong> internationally advanced<br />

levels, while <strong>th</strong>e same for <strong>th</strong>e lowest one was 2.6 tce/t (1.70 toe/t), or <strong>th</strong>ree times higher <strong>th</strong>an <strong>th</strong>e<br />

former.[12]<br />

Third, as mentioned above, <strong>th</strong>ere were only 60 large size paper mills wi<strong>th</strong> cogeneration power<br />

plants among <strong>th</strong>e ten <strong>th</strong>ousand paper mills nationwide in 1990. For <strong>th</strong>e total 4500 MW power<br />

cap<strong>ac</strong>ity <strong>of</strong> electric equipment in <strong>th</strong>e sector, self-generation <strong>of</strong> power could only meet 10.5% <strong>of</strong><br />

electricity demand. It has been proven <strong>th</strong>at a cogeneration plant can do <strong>th</strong>e paper mill itself much<br />

good due to its greater and stable combined <strong>th</strong>ermal and power load. Once again, <strong>th</strong>e size <strong>of</strong> small<br />

paper mills is blamed for <strong>th</strong>e non-installation <strong>of</strong> cogeneration systems. [5]<br />

Four<strong>th</strong>, perhaps <strong>th</strong>e root cause <strong>of</strong> <strong>th</strong>e problem <strong>of</strong> low energy efficiency is <strong>th</strong>e low efficiency <strong>of</strong><br />

boilers used in <strong>th</strong>e paper mills. Despite some medium-pressure boilers installed in a few large size<br />

paper enterprises wi<strong>th</strong> a <strong>th</strong>ermal efficiency <strong>of</strong> 80%, <strong>th</strong>ose installed in myriad small paper mills have<br />

efficiencies as low as 60%[4]. On <strong>th</strong>e contrary, <strong>th</strong>e efficiency for industrial boilers in developed<br />

countries is wi<strong>th</strong>in <strong>th</strong>e range <strong>of</strong> 80-85%. Often, heat loss rates <strong>of</strong> <strong>th</strong>ermal network exceed 10%.<br />

Therefore, overall <strong>th</strong>ermal efficiency for China's pulp & paper enterprises might be lower <strong>th</strong>an<br />

30%, some even less <strong>th</strong>an 25%.[4]<br />

Fif<strong>th</strong>, most <strong>of</strong> <strong>th</strong>e high calorific wastewater and o<strong>th</strong>er associated energy carriers (bark, sawdust etc.)<br />

are abandoned wi<strong>th</strong>out recovery <strong>of</strong> relevant chemicals and for energy supply. For <strong>th</strong>e time being,<br />

<strong>th</strong>ere are only <strong>th</strong>ree paper mills (Jilin Pulp & Paper Mill, Jiamusi Pulp & Paper Mill and Wufu<br />

Eastern Pulp & Paper Mill) installed wi<strong>th</strong> waste recovery boilers in which bark, sawdust and wood<br />

chips are fired. Beside <strong>th</strong>e loss <strong>of</strong> energy, <strong>th</strong>e environment is polluted. In comparison, some<br />

Western European paper mills can provide 87% <strong>of</strong> energy for <strong>th</strong>eir whole pulping process by fully<br />

exploiting waste materials such as bark and bl<strong>ac</strong>k liquor.<br />

Six<strong>th</strong>, energy consumed for <strong>th</strong>e digestion process usually <strong>ac</strong>counts for 45% <strong>of</strong> <strong>th</strong>e total pulping and<br />

paper making process. Usually, continuous digestion process can save 40% <strong>of</strong> <strong>th</strong>e amount <strong>of</strong> steam<br />

compared wi<strong>th</strong> <strong>th</strong>e intermittent digestion process, whereby much <strong>th</strong>ermal energy savings can be<br />

obtained. Unfortunately, most digestion processes in China are intermittent ones except in rare<br />

cases. At present, <strong>th</strong>e best figure for pulping process in China is about 1.6 ton steam/ton <strong>of</strong> pulp.<br />

The same indicator for foreign countries is just 0.4-0.6 ton steam/ton <strong>of</strong> pulp. Most equipment<br />

used for cooking in foreign countries are ei<strong>th</strong>er <strong>th</strong>e continuous digestion process or <strong>th</strong>e lowenergy-consuming<br />

intermittent digestion (RDH).<br />

Seven<strong>th</strong>, cylinder m<strong>ac</strong>hines for paper making in China’s paper mills <strong>ac</strong>count for only 83% <strong>of</strong> <strong>th</strong>e<br />

total number <strong>of</strong> paper m<strong>ac</strong>hines wi<strong>th</strong> speeds <strong>of</strong> lower <strong>th</strong>an 200 m/min and wid<strong>th</strong>s <strong>of</strong> 1m to 2m. In


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 67<br />

comparison, <strong>th</strong>e wid<strong>th</strong> <strong>of</strong> Fourdrinier m<strong>ac</strong>hine is generally between 5-10m, wi<strong>th</strong> m<strong>ac</strong>hine speeds <strong>of</strong><br />

800-1200 m/min.<br />

Finally, as for <strong>th</strong>e fuel mix pertaining to <strong>th</strong>e pulp & paper industry <strong>of</strong> China, coal is <strong>th</strong>e dominant<br />

fuel <strong>ac</strong>counting for 95% <strong>of</strong> <strong>th</strong>e total. Most types <strong>of</strong> coal used are <strong>of</strong> low grade.<br />

6.1.4 Environmental externalities <strong>of</strong> <strong>th</strong>e pulp & paper industry in China<br />

6.1.4.1 Liquid, gaseous and solid pollutants<br />

The pulp & paper industry is a typical pollution intensive industry among all industries. The most<br />

serious externality is <strong>th</strong>e water pollution due to <strong>th</strong>e highly concentrated organic wastewater<br />

effluents. Table 6.1.9 shows <strong>th</strong>e amount <strong>of</strong> wastewater discharged from 2282 pulp & paper mills<br />

counted in 1993. BOD (biochemical oxygen demand) discharge by <strong>th</strong>e paper mills was 2.716<br />

billion tons, <strong>ac</strong>counting for 38.2% <strong>of</strong> national BOD discharge, holding <strong>th</strong>e first position among all<br />

industries in China. If all pulp & paper mills were taken into <strong>ac</strong>count, <strong>th</strong>e total wastewater amount<br />

discharged from <strong>th</strong>e industry would have re<strong>ac</strong>hed as high as 3 billion tons in 1992, <strong>ac</strong>counting for<br />

about one eigh<strong>th</strong> <strong>of</strong> national total wastewater amount, ranking <strong>th</strong>ird after <strong>th</strong>e chemical and ferrous<br />

industries.<br />

Table 6.1.9 Wastewater discharge and treatment by Chinese paper industry in 1993 (Mt)<br />

Number <strong>of</strong> enterprise<br />

counted<br />

Total<br />

wastewater<br />

discharged<br />

Discharge<br />

d directly<br />

to inland<br />

water body<br />

Discharged<br />

directly to<br />

sea<br />

Discharge<br />

d <strong>th</strong>rough<br />

treatment<br />

plant<br />

Wastewater<br />

under State<br />

Discharge<br />

Standards<br />

2282 pulp & paper mills 2158 1713 18 21.4 314<br />

All industries 21949 NA NA 17934 12049<br />

Share <strong>of</strong> pulp & paper<br />

industry<br />

9.8% – – 1.2‰ 2.6%<br />

Besides slag (coal combustion cinders and white silt from alkali recovery), dust and ash, pungent<br />

smell and noise have also <strong>th</strong>eir environmental imp<strong>ac</strong>ts. In 1992, slag and cinder discharged by <strong>th</strong>e<br />

paper industry rose to 4.8 million tons, 296,000 tons <strong>of</strong> SO 2, 267,000 tons <strong>of</strong> soot and dust, and<br />

2.34 million tons <strong>of</strong> CO 2.<br />

Table 6.1.10 shows some gaseous emissions from <strong>th</strong>e industry. It can be found <strong>th</strong>at two-<strong>th</strong>irds <strong>of</strong><br />

<strong>th</strong>e gaseous emissions are from fuel combustion in industrial boilers, and one-<strong>th</strong>ird is from <strong>th</strong>e<br />

production processes.


68 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.1.10 Gaseous emissions by pulp & paper industry in China in 1993<br />

Indicator<br />

Total<br />

gaseous<br />

emission<br />

s billion<br />

m3 Emissions<br />

from fuel<br />

combustio<br />

n billion<br />

m3 Emissions<br />

from<br />

production<br />

process<br />

billion m3 SO2 emissions<br />

104 Soot<br />

discharged<br />

t 104 Dust<br />

discharge<br />

d<br />

t<br />

104 t<br />

Pulp & Paper<br />

industry<br />

173.1 117.1 56.0 28.177 28.7497 3.9332<br />

All industries 9342 6004 3338 1292 880 617<br />

National 10960 1795 1416<br />

From Table 6.1.11, which shows <strong>th</strong>e water pollution discharge loads in China from 1980 to 1988, it<br />

can be seen <strong>th</strong>at specific water pollution loads (including BOD and SS) decreased by 33% to 36%.<br />

The reduction stemmed from alkali recovery, integrated exploitation <strong>of</strong> digested wastewater, use <strong>of</strong><br />

recycled white water as well as fiber recovery which were popularized and used in some large and<br />

medium scale pulp & paper mills. Never<strong>th</strong>eless, total water pollution amounts escalated gradually.<br />

Table 6.1.11 Estimation <strong>of</strong> <strong>th</strong>e total amount <strong>of</strong> water pollution and discharge load[9]<br />

Year Wastewater<br />

discharged<br />

BOD SS<br />

Unit 108<br />

m3/year<br />

m3/ton<br />

paper<br />

10,000<br />

ton/year<br />

kg/ton<br />

paper<br />

10,000<br />

ton/year<br />

kg/ton<br />

paper<br />

1980 27.6 516 125.5 235 120.3 225<br />

1985 33 362 143 157 146 160<br />

1988 40 315 190 150 192 151<br />

Note: BOD – Biochemical or Biological Oxygen Demand, SS – fiber, fillings suspensions<br />

6.1.4.2 Pollution from paper mill: a case <strong>of</strong> Qiqihar pulp & paper mill<br />

Considering <strong>th</strong>e 33 key large size pulp & paper mills belonging to <strong>th</strong>e China Light Industries<br />

Commission (CLIC), not all <strong>of</strong> <strong>th</strong>em are environmentally sound. For example, Qiqihar pulp &<br />

paper mill,[7,14] famous for its newsprint paper production, <strong>ac</strong>counted for 11.5% <strong>of</strong> <strong>th</strong>e national<br />

total newsprint paper production from 1954 to 1991. In 1991, its wastewater discharge was 70344 -<br />

77446 tons/day, from which <strong>th</strong>e COD (Chemical Oxygen Demand) discharge was 40.125 - 41.029<br />

tons/day, BOD discharge was 6.836 tons/day, SS was 25.821 - 3.3821 tons/day, emitted gaseous<br />

pollutant soot and dust was 4112 tons/year, SO2 was at 1133 tons/year, total amount <strong>of</strong> solid<br />

waste was 63331 tons/year, and <strong>th</strong>e strongest noise intensity was at 110 - 136 dB(A). A more<br />

detailed pollution situation <strong>of</strong> <strong>th</strong>e paper mill is shown in Table 6.1.12-a & b and Table 6.1.13.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 69<br />

Table 6.1.12-a Status <strong>of</strong> water pollution in Qiqihar pulp & paper mill (summer)<br />

Pollution source Pollutants Unit Amount Recept<strong>ac</strong>le<br />

water effluent m 3/d 51631<br />

White liquor COD cr kg/d 30101 oxidizing<br />

outlet BOD5 kg/d 4698 pond<br />

SS kg/d 19973<br />

water effluent m 3/d 19815<br />

Bl<strong>ac</strong>k liquor CODcr kg/d 10106 oxidizing<br />

outlet BOD5 kg/d 2140 pond<br />

SS kg/d 9348<br />

water effluent m 3/d 6000<br />

Ash outlet CODcr kg/d 822 oxidizing<br />

BOD5 kg/d - pond<br />

SS kg/d 4500<br />

Table 6.1.12-b Status <strong>of</strong> water pollution in Qiqihar pulp & paper mill (winter)<br />

Pollution source Pollutants Unit Amount Recept<strong>ac</strong>le<br />

water effluent m 3/d 44529<br />

White liquor CODcr kg/d 39197 oxidizing<br />

outlet BOD5 kg/d 4698 pond<br />

SS kg/d 11973<br />

water effluent m 3/d 19815<br />

Bl<strong>ac</strong>k liquor CODcr kg/d 10106 oxidizing<br />

outlet BOD5 kg/d 2140 pond<br />

SS kg/d 9348<br />

water effluent m 3/d 6000<br />

Ash outlet CODcr kg/d 822 oxidizing<br />

BOD5 kg/d pond<br />

SS kg/d 4500<br />

Table 6.1.13 Gaseous and solid pollution by Qiqihar pulp & paper mill<br />

Pollution source Pollutants Unit Amount Recept<strong>ac</strong>le<br />

Cogeneration smoke & soot t/year 3558-1015 atmosphere<br />

Kilns TSP t/year. 555 atmosphere<br />

SO2 t/year 119<br />

Alkali recovery workshop H2S mg/m3 ~90 near <strong>th</strong>e workshop<br />

Cogeneration Slag & Ash m3/year 50000 ash storage field<br />

Wood preparing bark m3/year 54 filler or<br />

workshop residential fuel<br />

Alkali recovery white silt and t/d 32.8 to lime kiln for<br />

workshop alkaline ash lime recovery


70 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

According to <strong>th</strong>e wastewater discharging norm for pulp & paper industry (GB3544-92), its total<br />

wastewater discharged was about two times greater <strong>th</strong>an <strong>th</strong>e set quota; COD was 1.7 - 2.0 times<br />

greater and SS was 1.5 - 2.9 times greater <strong>th</strong>an <strong>th</strong>e set quota. Much reductions should be <strong>ac</strong>hieved<br />

if all <strong>th</strong>e paper mills abide by <strong>th</strong>e set regulation. [7]<br />

6.1.4.3 Major causes <strong>of</strong> <strong>th</strong>e increasing pollution<br />

Recently, pulp & paperboard production rose rapidly. This could be attributed mainly to <strong>th</strong>e high<br />

increase in production <strong>of</strong> many small size straw-based township enterprises. This change resulted<br />

in bo<strong>th</strong> average unit enterprise scale decrease and overall technical level fall, because most <strong>of</strong> <strong>th</strong>em<br />

were furnished wi<strong>th</strong> low-technical-level equipment. O<strong>th</strong>er reasons are summarized as follows:<br />

- Indifference to environmental pollution from enterprises leaders to workers.<br />

- The share <strong>of</strong> non-wood fiber raw material is too large. For <strong>th</strong>e prevailing straw pulp<br />

pollution in China, <strong>th</strong>ere are no technically mature and economically feasible clean<br />

production and/or environment-protecting technologies available.<br />

- As for <strong>th</strong>e vast capital investment demand for clean production and environmental<br />

treatment in China's various paper mills, <strong>th</strong>ere are no special and definite financial<br />

channels as yet.<br />

- No stern environmental assessment is stipulated as an indispensable prerequisite to <strong>th</strong>e<br />

plant before <strong>th</strong>e construction <strong>of</strong> many new pulp and paper mills, especially <strong>th</strong>ose in rural<br />

townships.<br />

6.1.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough<br />

technological changes<br />

From <strong>th</strong>e above analysis, it can be concluded <strong>th</strong>at <strong>th</strong>ere exists great potential for energy savings as<br />

well as environmental alleviation. The potentials identified can be summarized as follows:<br />

1. Adjustment <strong>of</strong> <strong>th</strong>e present structure <strong>of</strong> <strong>th</strong>e enterprises (scale), and development <strong>of</strong> a scaleeconomy<br />

<strong>of</strong> large cap<strong>ac</strong>ity enterprises and/or groups.<br />

There is a worldwide development trend in pulp & paper industry for <strong>th</strong>e time being: many pulp &<br />

paper mills ally toge<strong>th</strong>er to pursue stronger market competitive ability. In Japan, two leading pulp<br />

& paper companies, e<strong>ac</strong>h <strong>of</strong> which had a cap<strong>ac</strong>ity more <strong>th</strong>an 1 million tons per year have merged<br />

into a super-enterprise recently.<br />

As mentioned above, China's average size per enterprise is much lower compared to its foreign<br />

counterparts, which results in a series <strong>of</strong> problems <strong>th</strong>at encumber its energy efficiency as well as<br />

environment-friendly development. It is a common consensus among Chinese paper experts <strong>th</strong>at


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 71<br />

construction <strong>of</strong> large size paper mills installed wi<strong>th</strong> modern technological equipment is <strong>of</strong> great<br />

importance. Many township mills and o<strong>th</strong>er little enterprises should be merged into bigger ones for<br />

higher productivity, higher energy efficiency and more sound environmental compatibility.<br />

Moreover, larger scale paper mills will pave <strong>th</strong>e way for a series <strong>of</strong> subsequent measures to deal<br />

wi<strong>th</strong> existing problems.<br />

2. Changing raw material composition <strong>of</strong> China's current pulp production, raising <strong>th</strong>e share <strong>of</strong><br />

wood pulp and waste-paper pulp.<br />

According to statistics on straw pulp production, China has been <strong>th</strong>e first in <strong>th</strong>e world for years. It<br />

had been found, however, <strong>th</strong>at <strong>th</strong>e dominant fr<strong>ac</strong>tion <strong>of</strong> straw pulp production is also a barrier to<br />

energy efficiency improvement and pollution abatement. In <strong>th</strong>e United States and Japan, wood<br />

pulp's fr<strong>ac</strong>tion in <strong>th</strong>e total pulp production was more <strong>th</strong>an 99% (Table 6.1.14):<br />

Table 6.1.14 Global pulp production cap<strong>ac</strong>ity and share <strong>of</strong> wood pulp (FAO, 1987)<br />

Country Total production cap<strong>ac</strong>ity<br />

(10 3 Wood pulp's share in national<br />

ton)<br />

total (%)<br />

USA 53,677 99.3<br />

Japan 12,675 95.1<br />

former USSR 12,408 99.9<br />

China 10,679 23.9<br />

Brazil 4,375 93.4<br />

India 2,790 26.9<br />

France 2,310 99.1<br />

Exploitation <strong>of</strong> wood resources for boosting wood pulp production will not only raise <strong>th</strong>e quality<br />

<strong>of</strong> <strong>th</strong>e final paper products, it will also create a favorable condition for “associated biomass energy”<br />

recovery utilization. Moreover, all kinds <strong>of</strong> mature pollution abatement technologies pertaining to<br />

<strong>th</strong>e wood pulp process can be implemented easily.<br />

To reduce fiber raw material consumption in pulp production, an effective way is to enhance waste<br />

paper recovery. It has been proven <strong>th</strong>at wastepaper-derived pulp uses only around 1/4 or 1/3 <strong>of</strong><br />

<strong>th</strong>e energy claimed by <strong>th</strong>e wood-derived pulp. In 1988, China's waste-paper pulp (including<br />

imported waste paper) <strong>ac</strong>counting for 22.5% <strong>of</strong> <strong>th</strong>e total pulp production, implied a big potential<br />

when compared to <strong>th</strong>e same indicators <strong>of</strong> Japan and <strong>th</strong>e European Union (50% and 48%<br />

respectively). Exploitation <strong>of</strong> waste paper for pulp production not only reduces consumption <strong>of</strong><br />

energy and o<strong>th</strong>er resources, but also improves <strong>th</strong>e quality <strong>of</strong> <strong>th</strong>e environment.


72 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

3. Technological reform and renovation on outdated boilers.<br />

There are many old industrial coal-fired boilers wi<strong>th</strong> a total cap<strong>ac</strong>ity <strong>of</strong> more <strong>th</strong>an 14,000 tons/h in<br />

<strong>th</strong>e Chinese paper industry, and most <strong>of</strong> <strong>th</strong>em have efficiencies lower <strong>th</strong>an 60% or even 50%. This<br />

status indicates a great potential for energy savings <strong>th</strong>rough <strong>th</strong>e improvement <strong>of</strong> <strong>th</strong>e boiler<br />

efficiency.<br />

Combining technical renovation <strong>of</strong> some appropriate boilers and simple elimination <strong>of</strong> some is a<br />

better appro<strong>ac</strong>h for efficiency improvement. There exist many mature and technical-economically<br />

feasible processes which can be used for boiler renovation. For example, <strong>th</strong>e efficiency <strong>of</strong> small<br />

boilers wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> less <strong>th</strong>an 1 ton/h can be upgraded from 45% to 60% by a series <strong>of</strong><br />

renovations. For boilers wi<strong>th</strong> a cap<strong>ac</strong>ity between 1-4 tons/h, <strong>th</strong>e efficiency can be raised even to<br />

75% by technical renovation at a lower cost. Besides <strong>th</strong>is, boosting workers’ operational skill is<br />

also important.<br />

4. Development <strong>of</strong> cogeneration<br />

Cogeneration is a very useful technology for efficiency improvement in a pulp & paper mill, which<br />

can provide <strong>th</strong>ermal energy and electricity for its various processes. Compared to separate heat and<br />

power generation, it can get a prominent energy conservation effect <strong>of</strong> more <strong>th</strong>an 20%. As a rule,<br />

any paper mill which owns two or more sets <strong>of</strong> boilers wi<strong>th</strong> unit cap<strong>ac</strong>ity <strong>of</strong> more <strong>th</strong>an 10 t/h<br />

should build its corresponding cogeneration plant. Chinese experts estimated <strong>th</strong>at [8] total<br />

cogeneration installed cap<strong>ac</strong>ity in <strong>th</strong>e paper industry may be as much as 1600 MW by <strong>th</strong>e year<br />

2000. In 1991, total cogeneration cap<strong>ac</strong>ity was just 473 MW. The energy saving potential by<br />

cogeneration in <strong>th</strong>e Chinese paper industry will re<strong>ac</strong>h more <strong>th</strong>an 2 million tce (1.31 million toe) by<br />

2000 if 1600 MW installed cogeneration cap<strong>ac</strong>ity can be realized. The potential for cogeneration,<br />

<strong>th</strong>erefore, is great.<br />

5. Recovery <strong>of</strong> waste liquors and o<strong>th</strong>er associated energy carriers such as digested bl<strong>ac</strong>k liquor,<br />

bark, and sawdust.<br />

Recovery <strong>of</strong> associated energy carriers such as bl<strong>ac</strong>k liquor is <strong>of</strong> great benefit bo<strong>th</strong> for energy<br />

savings and for environmental protection. A ton <strong>of</strong> dried solid remnant <strong>of</strong> bl<strong>ac</strong>k liquor in <strong>th</strong>e<br />

process <strong>of</strong> sulfate pulping can provide <strong>th</strong>ermal energy <strong>of</strong> 0.43~0.49 tce (0.28 toe ~ 0.32 toe). In<br />

<strong>th</strong>e paper industry <strong>of</strong> developed countries, energy supply from associated energy carriers such as<br />

bl<strong>ac</strong>k liquor and bark <strong>ac</strong>count for a remarkable share. For instance, bl<strong>ac</strong>k liquor and bark supplied<br />

37.3% and 4.3%, respectively, <strong>of</strong> <strong>th</strong>e total paper industry energy demand in <strong>th</strong>e USA in <strong>th</strong>e early<br />

1980s. In Finland and Sweden, <strong>th</strong>e two items toge<strong>th</strong>er could meet more <strong>th</strong>an 50% <strong>of</strong> <strong>th</strong>e total<br />

energy demand. In some cases, even <strong>th</strong>e total energy demand by all processes can be met fully by<br />

recovery <strong>of</strong> bl<strong>ac</strong>k liquor and bark.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 73<br />

It is estimated <strong>th</strong>at <strong>th</strong>e total bl<strong>ac</strong>k liquor <strong>of</strong> <strong>th</strong>e industry can provide at least 3 million toe based on<br />

1990’s conditions. In comparison, <strong>th</strong>e level <strong>of</strong> wastewater recovery and utilization in China lags<br />

behind. At present, alkaline pulp cap<strong>ac</strong>ity wi<strong>th</strong> bl<strong>ac</strong>k liquor recovery is only 1.2 million tons,<br />

<strong>ac</strong>counting for 41% <strong>of</strong> <strong>th</strong>e total alkaline pulping cap<strong>ac</strong>ity nationwide. Most <strong>of</strong> <strong>th</strong>e paper mills do<br />

not have <strong>th</strong>e f<strong>ac</strong>ilities to exploit ei<strong>th</strong>er bl<strong>ac</strong>k liquor or bark to recover chemicals and <strong>th</strong>ermal<br />

energy. It is projected by CLIC <strong>th</strong>at if 1.2 million newly-added alkaline pulp cap<strong>ac</strong>ity wi<strong>th</strong> bl<strong>ac</strong>k<br />

liquor recovery is realized by 2000, <strong>th</strong>en 130,000 toe energy can be saved, and 450,000 tons caustic<br />

soda can be recycled while reducing BOD discharge by 250,000 tons.<br />

Combustible waste residue from large scale wood pulp mills alone amounts to 240,000 ton/year.<br />

As only <strong>th</strong>ree mills are installed wi<strong>th</strong> waste boilers firing <strong>th</strong>ese waste solid, <strong>th</strong>ere is an immense<br />

potential for energy efficiency improvement and environmental protection.<br />

6. To adopt advanced pulp and paper making technologies bo<strong>th</strong> for paper mills modernization<br />

and for building new large scale paper mills.<br />

Generally, <strong>th</strong>e energy consumed is distributed among all production processes as follows: 2% for<br />

wood material preparation, 46% for pulping (digestion, cleansing and alkali recovery), 4% for<br />

ble<strong>ac</strong>hing, 43% for paper shaping, 5% for paper processing. Among <strong>th</strong>e pulping processes,<br />

digestion <strong>ac</strong>counts for 97% <strong>of</strong> energy demand. Attention should be given <strong>th</strong>erefore to <strong>th</strong>e two<br />

energy-consuming processes, digestion and paper making.<br />

There exist two digestion processes: continuous digestion process and intermittent digestion.<br />

Compared to <strong>th</strong>e latter, <strong>th</strong>e former can avoid steam load fluctuation, <strong>th</strong>us reducing steam<br />

consumption by 40%. Continuous digestion process should be recommended to repl<strong>ac</strong>e<br />

intermittent one. At present, medium or small size continuous digestion equipment can be made in<br />

China, and a number <strong>of</strong> such equipment have already been commissioned. Moreover, a new lowenergy,<br />

cold-spouting intermittent digestion process (RDH) invented abroad is found to save 50%<br />

or more steam while raising productivity by 10-15% when compared to <strong>th</strong>e conventional<br />

intermittent digestion process. This new process can <strong>th</strong>erefore find a promising market in China,<br />

<strong>th</strong>ough <strong>th</strong>e use <strong>of</strong> such technology is not yet realized in <strong>th</strong>e country. Additionally, <strong>th</strong>e direct<br />

heating process for digestion should be substituted by <strong>th</strong>e indirect heating process since <strong>th</strong>e former<br />

consumes 15-20% more energy <strong>th</strong>an <strong>th</strong>e latter.<br />

Ano<strong>th</strong>er process which should also be given attention for energy savings is <strong>th</strong>e paper making stage.<br />

There are a number <strong>of</strong> feasible technological transformation me<strong>th</strong>ods for comprehensive energyrelated<br />

improvement <strong>of</strong> <strong>th</strong>e paper m<strong>ac</strong>hines. Medium speed Fourdrinier m<strong>ac</strong>hines can substitute<br />

existing cylinder m<strong>ac</strong>hines. The drying ability <strong>of</strong> <strong>th</strong>e m<strong>ac</strong>hines can also be boosted by polyester<br />

former, new pulp feeder and new drying apparatus. High intensity multi-press can be used in<br />

m<strong>ac</strong>hine press parts to raise wet paper dryness from <strong>th</strong>e current 32%-38% to 48%-50%. It has<br />

been proven <strong>th</strong>at reduction <strong>of</strong> 1% <strong>of</strong> moisture content <strong>of</strong> wet paper before drying can save 5% <strong>of</strong><br />

<strong>th</strong>e steam consumption for drying. The dryness <strong>of</strong> wet paper in Chinese paper mills is usually


74 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

around 30%, while <strong>th</strong>at <strong>of</strong> western countries is more <strong>th</strong>an 50%. Some technical measures to raise<br />

<strong>th</strong>ermal efficiency for drying include multi-stage steam feed, whole-sealed cover, recovery <strong>of</strong><br />

exhaust heat from its cover, etc. Computer-controlled steam feed for dry oven in some foreign<br />

countries also proved to be a useful way to save steam consumption. Computer-based constant<br />

moisture control systems should be disseminated in large or medium-size key paper mills. It is<br />

estimated <strong>th</strong>at specific energy consumption <strong>of</strong> paper m<strong>ac</strong>hines would be reduced by 30% <strong>th</strong>rough<br />

<strong>th</strong>e above-mentioned technologies. If 20% <strong>of</strong> <strong>th</strong>e existing paper m<strong>ac</strong>hines are retr<strong>of</strong>itted by <strong>th</strong>e<br />

year 2000, 650,000 toe can be conserved.<br />

7. Application <strong>of</strong> electricity-saving equipment for technical renovation, repl<strong>ac</strong>ement <strong>of</strong> outmoded<br />

appliances and dissemination <strong>of</strong> computer-controlled automation processes.<br />

The performance <strong>of</strong> electrical equipment directly affects <strong>th</strong>e electricity consumption <strong>of</strong> <strong>th</strong>e whole<br />

paper mill. Some available low-electricity-consuming equipment such as double-panned mill, Loci<br />

electric fan, axial-flow fan and speed-adjustable electric motor have better electricity saving effects<br />

compared to <strong>th</strong>eir respective old generation equipment. For instance, <strong>th</strong>e repl<strong>ac</strong>ement <strong>of</strong> variable<br />

frequency- speed-adjustable electric motor could save electricity by some 30% in most cases, while<br />

its cost could be paid b<strong>ac</strong>k in a few years. Here, existing barriers in <strong>th</strong>e Chinese case are mainly<br />

incentives and initial investments.<br />

On <strong>th</strong>e o<strong>th</strong>er side, computer controlled automation process may bring 10% steam reduction for<br />

<strong>th</strong>e process <strong>of</strong> pulping and 15% energy savings for paper shaping process in <strong>th</strong>e Chinese<br />

context.[12]<br />

8. For environmental protection, especially water pollution control, challenges and opportunities<br />

exist toge<strong>th</strong>er. Potential for pollution abatement includes:<br />

- For <strong>th</strong>e alkali pulping process, alkali recovery rates <strong>of</strong> various raw material-based mills<br />

can be increased to various levels: 90% alkali recovery rate for wood pulp, 80% for<br />

bamboo/bagasse pulp, and 70% for wheat straw pulp can be re<strong>ac</strong>hed.<br />

- For <strong>th</strong>e <strong>ac</strong>id process, efforts should be made to integrate exploitation <strong>of</strong> wastewater to<br />

produce adhesives, alcohol by products, etc.<br />

- For ammonium bisulfite pulp, wastewater can be used for agricultural irrigation & farm<br />

fertilizer. Recovery exploitation rate <strong>of</strong> wastewater for <strong>th</strong>is process can increase to 60%<br />

or higher.<br />

9. There is still a great potential for water conservation by improving water recycle utilization rate.<br />

Current white liquor recovery rate <strong>of</strong> paper m<strong>ac</strong>hine is 30%, while <strong>th</strong>e dryer condensate recovery<br />

rate is 50%


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 75<br />

10. Enhancement <strong>of</strong> pulp & paper industry pr<strong>of</strong>essional management, effective implementation <strong>of</strong><br />

existing regulations relevant to energy consumption and environmental protection issues.<br />

6.1.6 Status <strong>of</strong> application <strong>of</strong> new technologies<br />

Because most paper mills in China do not belong to <strong>th</strong>e CLIC, <strong>th</strong>ere is no strong au<strong>th</strong>ority or<br />

administrative department responsible for <strong>th</strong>e pr<strong>of</strong>essional management <strong>of</strong> <strong>th</strong>e pulp & paper<br />

industry. Much data concerning <strong>th</strong>e status <strong>of</strong> <strong>th</strong>e application <strong>of</strong> new technologies are not available.<br />

Following is an example <strong>of</strong> application <strong>of</strong> Alkali Recovery (AR) process in China:<br />

This technology is reckoned by <strong>th</strong>e industry to be <strong>th</strong>e key appro<strong>ac</strong>h for environmental control. By<br />

<strong>th</strong>e end <strong>of</strong> 1992, <strong>th</strong>ere were 63 paper mills installed wi<strong>th</strong> alkali recovery f<strong>ac</strong>ilities. Total alkali<br />

recovery cap<strong>ac</strong>ity hit 450,000 tons/year, while <strong>ac</strong>tual alkali recovery amount was 380,000<br />

tons/year. By <strong>th</strong>e AR process, about 400,000 tons <strong>of</strong> organic pollutants were refined. The AR<br />

rates in large size wood pulp mills re<strong>ac</strong>hed 90%, and in medium cap<strong>ac</strong>ity wood pulp mills, 75-80%.<br />

AR rate in large size straw pulp mills was 70% or so, medium size straw ones, 50-60%. There was<br />

about 1.2 million tons/year pulping cap<strong>ac</strong>ity matched wi<strong>th</strong> alkali recovery f<strong>ac</strong>ilities in 1992,<br />

<strong>ac</strong>counting for 41.4% <strong>of</strong> <strong>th</strong>e total 2.9 million tons/year pulping cap<strong>ac</strong>ity which needed <strong>th</strong>e<br />

technology (Table 6.1.15).<br />

Figure 6.1.8 shows <strong>th</strong>e alkali recovery evolution during <strong>th</strong>e decade from 1980 to 1990. It can be<br />

found <strong>th</strong>at overall alkali recovery and wood pulp alkali recovery kept similar increasing trends, wi<strong>th</strong><br />

annual grow<strong>th</strong> rates <strong>of</strong> 5.3% and 5.9%, respectively. Meanwhile, recovery <strong>of</strong> straw pulp alkali<br />

increased from 54,200 tons to 73,000 tons.<br />

Table 6.1.15 Status <strong>of</strong> AR utilization in China in 1992<br />

Alkali-based pulp Wood pulp Straw pulp<br />

Pulping cap<strong>ac</strong>ity wi<strong>th</strong> AR, Mt 1.2 0.80 0.40<br />

Pulping cap<strong>ac</strong>ity demanding AR, Mt 2.9 0.90 2.00<br />

Diffusion rate % 41.4 88.9 20<br />

AR rate % 22.6 70 6<br />

Wi<strong>th</strong> regards to <strong>th</strong>e total amount <strong>of</strong> alkali recovery, <strong>th</strong>e wood pulp mills’ situation was generally<br />

better <strong>th</strong>an <strong>th</strong>at <strong>of</strong> <strong>th</strong>e straw pulp mills. Figure 6.1.9 shows <strong>th</strong>e alkali recovery rates <strong>of</strong> <strong>th</strong>e situation<br />

in <strong>th</strong>e two pulp mills. Alkali recovery rate in <strong>th</strong>e wood pulp mills exceeded 60% in 1990. In <strong>th</strong>e<br />

straw pulp case, <strong>th</strong>e indicator was maintained at lower <strong>th</strong>an 10%. If <strong>th</strong>ose straw pulp mills outside<br />

<strong>th</strong>e CLIC (which <strong>of</strong>ten consumed alkali wi<strong>th</strong>out recovery ) were taken into <strong>ac</strong>count, however, <strong>th</strong>e<br />

real indicator <strong>of</strong> alkali recovery for whole straw pulp case should be lower <strong>th</strong>an 6% (Figure 6.1.9).


76 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

1000 ton<br />

400<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

Total AR<br />

Wood Pulp AR<br />

Straw Pulp AR<br />

1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1992<br />

Figure 6.1.8 Alkali recovery by wood pulp and straw pulp from 1980 to 1990<br />

Percent<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

Total AR rate<br />

Wood Pulp AR<br />

rate<br />

Straw pulp AR<br />

rate<br />

Year<br />

0<br />

1980 1981 1982 1983 1984 1985<br />

Year<br />

1986 1987 1988 1989 1990<br />

Figure 6.1.9 National m<strong>ac</strong>ro alkali recovery rates vs. year<br />

Since 1980, some important alkali recovery projects had been completed in large or medium size<br />

wood pulp mills such as <strong>th</strong>e Jiamusi Paper Mill, Jilin Paper Mill, Zhalandun Pulp & Paper Mill,<br />

Helongjiang Paper Mill, Yalujiang Paper Mill, Nanping Paper Mill and Qingzhou Paper Mill. At <strong>th</strong>e<br />

same time, technical transformations to large size straw pulp mills had also been made successfully.<br />

For instance, plate membranous concentrating vaporizers had been added into alkali recovery<br />

systems in Zhenjing Pulp & Paper Mill, Yueyang and Liujing Paper Mills. In a few cases, technical<br />

transformation and cap<strong>ac</strong>ity extension for alkali recovery in medium or small size straw pulp mills<br />

had been made wi<strong>th</strong> satisfying techno-economic effects, as in <strong>th</strong>e case <strong>of</strong> <strong>th</strong>e Guigang, Shanghai<br />

Songjiang Pulp & Paper Mills, etc.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 77<br />

Unfortunately, alkali recovery situation for most medium and small size straw pulp mills (wi<strong>th</strong><br />

cap<strong>ac</strong>ity <strong>of</strong> 15-35 tons pulp/day) was problematic due to reasons such as small economies <strong>of</strong> scale,<br />

low technical equipment installation, poor operation management as well as immature technologies<br />

available for bl<strong>ac</strong>k liquor treatment in straw pulp mills.<br />

By <strong>th</strong>e end <strong>of</strong> 1994, <strong>th</strong>ere were 73 AR projects wi<strong>th</strong> a total AR cap<strong>ac</strong>ity <strong>of</strong> 370,000 tons/year. Of<br />

<strong>th</strong>ese, 37 projects wi<strong>th</strong> a total AR cap<strong>ac</strong>ity <strong>of</strong> 120,000 tons/year were built but not commissioned,<br />

and 36 projects <strong>of</strong> total AR cap<strong>ac</strong>ity <strong>of</strong> 250,000 ton/year were under construction. By <strong>th</strong>e end <strong>of</strong><br />

1995, <strong>th</strong>ere will be a total <strong>of</strong> 30 paper mills installed wi<strong>th</strong> AR f<strong>ac</strong>ilities wi<strong>th</strong> a total AR cap<strong>ac</strong>ity <strong>of</strong><br />

820,000 tons/year.<br />

During <strong>th</strong>e last decades, <strong>th</strong>e AR cap<strong>ac</strong>ity wi<strong>th</strong> an annual grow<strong>th</strong> rate <strong>of</strong> 5.3% still lagged behind<br />

<strong>th</strong>at <strong>of</strong> <strong>th</strong>e paper & paperboard at 15% and <strong>th</strong>e pulp grow<strong>th</strong> rate <strong>of</strong> 13.7% during <strong>th</strong>e same period.<br />

This <strong>th</strong>erefore suggests <strong>th</strong>at more alkali is to be consumed to meet faster demand.<br />

For improvement <strong>of</strong> <strong>th</strong>e AR rate and wastewater integrated exploitation, wastewater abstr<strong>ac</strong>tion is<br />

<strong>th</strong>e primary process to be solved. Several hundreds <strong>of</strong> domestically-developed belt pulp scrubbers<br />

have been built since <strong>th</strong>e 1970s. Some large size paper mills also imported new high-efficiency pulp<br />

scrubbers. In a Guangzhou paper mill, where an imported advanced pulp scrubber was installed,<br />

<strong>th</strong>e AR was boosted to more <strong>th</strong>an 80%.<br />

As for many AR processes concerning straw pulp production and o<strong>th</strong>er digested wastewater<br />

recovery technologies, an eminent problem in <strong>th</strong>e Chinese situation is how to commercialize<br />

and/or disseminate <strong>th</strong>e results <strong>of</strong> <strong>th</strong>e studies in paper mills.<br />

6.1.7 Conclusions<br />

From <strong>th</strong>e above discussion, some main conclusions concerning <strong>th</strong>e pulp & paper industry in<br />

China can be briefly summarized as follows:<br />

- The pulp & paper industry <strong>of</strong> China is a fast developing industry, and currently ranks<br />

<strong>th</strong>ird in <strong>th</strong>e world. It could probably catch up wi<strong>th</strong> Japan to become <strong>th</strong>e second largest<br />

producer in <strong>th</strong>e world by 2000.<br />

- The pulp & paper industry <strong>of</strong> China is a highly energy-intensive and polluting industry,<br />

and is particularly blamed for water pollution.<br />

- China's integrated energy consumption indicator in <strong>th</strong>e pulp & paper industry is 2.45<br />

times as high as <strong>th</strong>at <strong>of</strong> Japan, 1.45 times as high as <strong>th</strong>at <strong>of</strong> USA. Therefore, its energy<br />

efficiency is much lower.


78 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

- Due to <strong>th</strong>e l<strong>ac</strong>k <strong>of</strong> wastewater recovery, exploitation and treatment technologies and/or<br />

measures, <strong>th</strong>e industry is responsible for 1/8 <strong>of</strong> <strong>th</strong>e national wastewater discharge, and<br />

more <strong>th</strong>an 1/3 <strong>of</strong> <strong>th</strong>e national BOD discharge. Thus, it is urgent to curb <strong>th</strong>e rampant<br />

environmental damaging behavior <strong>of</strong> <strong>th</strong>e pulp & paper industry.<br />

- There exists a great potential for energy efficiency improvement and environmental<br />

pollution mitigation from <strong>th</strong>e industry <strong>th</strong>rough a number <strong>of</strong> technical measures,<br />

including technological renovation and substitution for existing processes;<br />

transformation <strong>of</strong> existing paper mills; improvement <strong>of</strong> boiler efficiency; installation <strong>of</strong><br />

cogeneration; recovery <strong>of</strong> wastewater and o<strong>th</strong>er associated energy carriers (bark,<br />

sawdust); digestion process repl<strong>ac</strong>ement; computed-based automation etc.<br />

- From <strong>th</strong>e viewpoint <strong>of</strong> national m<strong>ac</strong>ro-system, enhancement <strong>of</strong> waste paper recycling,<br />

reshaping <strong>of</strong> enterprise scales, as well as <strong>th</strong>e change <strong>of</strong> raw materials for pulping should<br />

help in fur<strong>th</strong>er improvement and pollution abatement.<br />

- Consolidating pulp & paper pr<strong>of</strong>essional management and tightening <strong>th</strong>e<br />

implementation <strong>of</strong> existing pollution control regulations, as well as even legislating<br />

appropriate laws for discharge norm from paper mill are urgently needed.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 79<br />

6.2 COUNTRY REPORT: INDIA<br />

6.2.1 Introduction<br />

The paper industry in India has been established for over a century, wi<strong>th</strong> four paper manuf<strong>ac</strong>turing<br />

units initially in operation wi<strong>th</strong> an annual output <strong>of</strong> 20,000 tons. From an installed cap<strong>ac</strong>ity <strong>of</strong><br />

137,000 tons in <strong>th</strong>e year 1951, <strong>th</strong>e paper industry has grown during <strong>th</strong>e last four decades to an<br />

installed cap<strong>ac</strong>ity <strong>of</strong> 3,463,000 tons <strong>of</strong> paper and paperboard, and 300,000 tons <strong>of</strong> newsprint. The<br />

development <strong>of</strong> India’s paper industry centered on bamboo for raw material, ra<strong>th</strong>er <strong>th</strong>an wood as<br />

in o<strong>th</strong>er countries. Wi<strong>th</strong> bamboo resources falling short <strong>of</strong> <strong>th</strong>e requirement due to <strong>th</strong>e short term<br />

planning adapted <strong>th</strong>en, <strong>th</strong>e use <strong>of</strong> tropical hardwood started in <strong>th</strong>e 1960s. Until <strong>th</strong>e start <strong>of</strong> <strong>th</strong>e<br />

70s, <strong>th</strong>e paper industry had been forest-based and industrial units were integrated wi<strong>th</strong> pulp, paper<br />

and chemical recovery systems.<br />

Being highly capital-intensive, new investments were not for<strong>th</strong>coming at <strong>th</strong>e desired levels.<br />

Anticipating a shortage <strong>of</strong> paper in <strong>th</strong>e 1960s, a crash program for <strong>th</strong>e expansion <strong>of</strong> <strong>th</strong>e industry<br />

was devised, under which, second-hand plants and m<strong>ac</strong>hinery were allowed to be imported.<br />

The number <strong>of</strong> units in <strong>th</strong>e process increased from 25 in 1960-1961 to <strong>th</strong>e current 340 units. Most<br />

<strong>of</strong> <strong>th</strong>e small paper mills are ei<strong>th</strong>er agro-based or waste paper-based. At present, 29 units wi<strong>th</strong> a<br />

cap<strong>ac</strong>ity <strong>of</strong> 1,485,000 tons, representing 43% <strong>of</strong> <strong>th</strong>e installed cap<strong>ac</strong>ity for paper and paper board,<br />

rely on forest-based raw materials. Eighty-nine units wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 974,000 tons, representing<br />

28% <strong>of</strong> <strong>th</strong>e installed cap<strong>ac</strong>ity, are based on agricultural residues. These units use imported pulp<br />

and recycled fiber as well. Added to <strong>th</strong>ese are some 22 units wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 1,004,000 tons,<br />

representing 29% <strong>of</strong> <strong>th</strong>e installed cap<strong>ac</strong>ity, which are largely dependent on imported recycled<br />

fibers.<br />

The effective cap<strong>ac</strong>ity utilization <strong>of</strong> bamboo and wood-based units is 95%, 80% for agro-based<br />

units, 63% for recycled fiber-based units, wi<strong>th</strong> an average effective cap<strong>ac</strong>ity utilization <strong>of</strong> 82%<br />

(Figure 6.2.1). The overall cap<strong>ac</strong>ity utilization in relation to installed cap<strong>ac</strong>ity is 62%.<br />

The demand for paper and paperboard by <strong>th</strong>e turn <strong>of</strong> <strong>th</strong>e century shall be reckoned in terms <strong>of</strong> <strong>th</strong>e<br />

development phase which has already started. The per capita consumption <strong>of</strong> newsprint paper,<br />

currently at 2.4 kg, shall increase to 4.5 kg by <strong>th</strong>e year 2000 (Figure 6.2.2). The demand for paper<br />

and paperboard products would vary from <strong>th</strong>e p<strong>ac</strong>kaging to newsprints, and o<strong>th</strong>ers.<br />

6.2.2 Technological trajectory <strong>of</strong> <strong>th</strong>e Indian paper industry<br />

6.2.2.1 Structure <strong>of</strong> <strong>th</strong>e paper industry<br />

At <strong>th</strong>e start <strong>of</strong> <strong>th</strong>e 1950s, <strong>th</strong>e average production size <strong>of</strong> <strong>th</strong>e paper mills was only 8,000 t/year.<br />

Integrated paper mills based on forest raw materials set up during 1955-1960 resulted in an<br />

increase in <strong>th</strong>e average unit size to 16,000 t/year. In <strong>th</strong>e next decades, additional cap<strong>ac</strong>ity was


80 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

mostly due to <strong>th</strong>e expansion <strong>of</strong> existing mills and commissioning <strong>of</strong> small paper mills, but <strong>th</strong>e<br />

average size declined to 13,500 t/year. During 1970-1980, al<strong>th</strong>ough 8 large integrated mills wi<strong>th</strong><br />

production sizes <strong>of</strong> 20,000 t/year were commissioned, <strong>th</strong>e added cap<strong>ac</strong>ity was mainly in <strong>th</strong>e form<br />

<strong>of</strong> small units and <strong>th</strong>e average size remained at 12,500 t/year. From 1980-1985, an increase in <strong>th</strong>e<br />

number <strong>of</strong> units by more <strong>th</strong>an 100% was realized, wi<strong>th</strong> small paper mills registering a grow<strong>th</strong> <strong>of</strong><br />

129% and cap<strong>ac</strong>ity increase <strong>of</strong> 50%. However, only one large integrated mill (<strong>th</strong>e Nagaland Pulp<br />

and Paper Mill wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 33,000 t/year) was commissioned during <strong>th</strong>e period, while four<br />

o<strong>th</strong>er large mills effected expansion for a total <strong>of</strong> 44,500 tons. A small pulp mill (<strong>th</strong>e Century Pulp<br />

and Paper Mill wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 20,000 t/year) was commissioned in 1981 and <strong>th</strong>e average unit<br />

size came down to about 9,400 t/year.<br />

Ton / Year<br />

4000<br />

3500<br />

3000<br />

2500<br />

2000<br />

1500<br />

1000<br />

500<br />

0<br />

1960 1970 1980 1990 1992<br />

Installed Cap<strong>ac</strong>ity<br />

Production<br />

Figure 6.2.1 Installed cap<strong>ac</strong>ity and production <strong>of</strong> India’s pulp & paper industry<br />

Figure 6.2.2 Per capita paper consumption in India<br />

In 1988, only one large integrated pulp and paper mill (<strong>th</strong>e C<strong>ac</strong>har Paper Project <strong>of</strong> Hindustan<br />

Paper Corporation, wi<strong>th</strong> a cap<strong>ac</strong>ity <strong>of</strong> 100,000 tons) was commissioned. The rest <strong>of</strong> <strong>th</strong>e additions<br />

to <strong>th</strong>e existing cap<strong>ac</strong>ity was by way <strong>of</strong> expanding a few small paper mills. After <strong>th</strong>e commissioning<br />

<strong>of</strong> <strong>th</strong>e C<strong>ac</strong>har project, <strong>th</strong>ere has been no fur<strong>th</strong>er commissioning <strong>of</strong> integrated pulp and paper mills<br />

based on forest raw materials.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 81<br />

The number <strong>of</strong> large mills went up to 25 in 1990, and in 1992, <strong>th</strong>ree large mills (Pudumjee Pulp<br />

and Paper Mill, Balkrishna Papers, and Tribeni Tissues, Ltd.) were added as a result <strong>of</strong> expansion<br />

from <strong>th</strong>e small category. Similarly in 1993, two large mills have been added <strong>th</strong>rough expansion and<br />

two new agro-residues-based units have been set up. During <strong>th</strong>e last five years, only <strong>th</strong>ree new<br />

units were set up in <strong>th</strong>e large paper mill category. The trend <strong>of</strong> setting up small paper mills<br />

<strong>ac</strong>counting for about 50% <strong>of</strong> <strong>th</strong>e total cap<strong>ac</strong>ity is continuing. The average unit has also remained at<br />

about 10,000 tons. The grow<strong>th</strong> <strong>of</strong> <strong>th</strong>e paper industry in India is shown in Figure 6.2.3.<br />

# <strong>of</strong> mills<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

Small Paper Mills<br />

Integrated Paper Mills<br />

1960 1970 1980<br />

Year<br />

1990 1992<br />

Figure 6.2.3 Grow<strong>th</strong> <strong>of</strong> <strong>th</strong>e paper industry in India (1960 to 1992)<br />

6.2.2.2 Raw materials scenario<br />

Twenty years ago, <strong>th</strong>e Indian paper industry started wi<strong>th</strong> bamboo as <strong>th</strong>e sole major raw material.<br />

The restricted availability <strong>of</strong> <strong>th</strong>e material, however, has curtailed its usage to about 40% at present.<br />

Because <strong>of</strong> <strong>th</strong>is, <strong>th</strong>ere has been a considerable shift towards <strong>th</strong>e use <strong>of</strong> tropical hardwood,<br />

eucalyptus, and o<strong>th</strong>er non-conventional raw materials.<br />

Today, depending on <strong>th</strong>e source <strong>of</strong> raw material, <strong>th</strong>e paper industry is classified as follows:<br />

- Forest-based: bamboo & hardwood (plantation-grown raw materials: mainly Eucalyptus<br />

and Subabul)<br />

- Unconventional raw materials (agro-residues, jute, grass straw, bagasse, etc.)<br />

- Waste paper-based<br />

Segment wise, effective installed cap<strong>ac</strong>ities in <strong>th</strong>e paper industry are as follows:<br />

Forest-based raw material: 43%<br />

Agro-based 28%<br />

Waste paper-based 29%


82 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Today, <strong>th</strong>e large gap between <strong>th</strong>e demand and supply for paper is basically for <strong>th</strong>e newsprint type<br />

while future requirements for paper and paper board are expected to register a sharp increase.<br />

There is <strong>th</strong>erefore a need to substitute scarce forest resources wi<strong>th</strong> non-conventional raw materials<br />

as an immediate measure to meet raw material requirements in <strong>th</strong>e pulp & paper industry.<br />

Plantations on long-term basis by using modern silviculture pr<strong>ac</strong>tices and o<strong>th</strong>er technologies like<br />

tissue culture for improving <strong>th</strong>e productivity <strong>of</strong> <strong>th</strong>e forest-based raw materials should be<br />

considered.<br />

6.2.2.3 Technological advancement<br />

Since its establishment, <strong>th</strong>e paper industry in India underwent a lot <strong>of</strong> changes by way <strong>of</strong><br />

equipment and process development. A hundred years ago, <strong>th</strong>e m<strong>ac</strong>hinery and equipment available<br />

for pulping, ble<strong>ac</strong>hing and papermaking, limited <strong>th</strong>e size <strong>of</strong> <strong>th</strong>e mills to about 50 t/d. Apart from<br />

constraints such as <strong>th</strong>e availability <strong>of</strong> energy, raw materials and o<strong>th</strong>er inputs, one reason for <strong>th</strong>e low<br />

cap<strong>ac</strong>ity utilization <strong>of</strong> <strong>th</strong>e mills is <strong>th</strong>e f<strong>ac</strong>t <strong>th</strong>at productive assets are <strong>of</strong>ten not at optimum levels <strong>of</strong><br />

efficiency due to <strong>th</strong>e l<strong>ac</strong>k <strong>of</strong> modernization and renovation <strong>of</strong> old equipment. Fur<strong>th</strong>ermore, <strong>th</strong>e<br />

Indian paper industry has adopted equipment primarily designed for <strong>th</strong>e processing <strong>of</strong> indigenous<br />

s<strong>of</strong>twood materials, such as bamboo, but <strong>th</strong>ese are used for hardwood as well. Consequently,<br />

operating efficiencies are low and processes require modernization <strong>of</strong> techniques to ensure better<br />

yields, reduce costs and conserve raw materials.<br />

In view <strong>of</strong> <strong>th</strong>e increasing paper demand and shortage <strong>of</strong> forest-based raw materials, <strong>th</strong>e<br />

government has drawn up a policy to promote small mills based on straw and bagasse. The size <strong>of</strong><br />

<strong>th</strong>e mill has to be restricted due to <strong>th</strong>e seasonal availability <strong>of</strong> <strong>th</strong>e raw materials, and technical<br />

problems involved. These agro-based paper mills produce almost all kinds <strong>of</strong> paper and boards for<br />

writing and printing. In <strong>th</strong>e absence <strong>of</strong> a chemical recovery system and high cost <strong>of</strong> alkali, <strong>th</strong>ese<br />

mills use low amounts <strong>of</strong> chemicals at <strong>th</strong>e cooking stage and excess amounts <strong>of</strong> chlorine in <strong>th</strong>e<br />

ble<strong>ac</strong>hing stage. Second-hand paper m<strong>ac</strong>hines which are used for papermaking are energy<br />

deficient, and since <strong>th</strong>ese mills do not have chemical recovery units, <strong>th</strong>e discharge <strong>of</strong> spent liquor,<br />

and excess consumption <strong>of</strong> chlorine are major causes <strong>of</strong> water and environmental pollution.<br />

On <strong>th</strong>e o<strong>th</strong>er hand, <strong>th</strong>e large integrated mills which mainly produce writing and printing grade<br />

papers are equipped wi<strong>th</strong> full-fledged chemical recovery systems and effluent treatment plants.<br />

Developments in <strong>th</strong>e pulp and paper industry has been gradual, <strong>th</strong>ough systematic and elaborate<br />

research <strong>ac</strong>tivities in <strong>th</strong>e fields <strong>of</strong> fiber chemistry, morphology, engineering, have been continuing.<br />

Today, advanced knowledge in morphology and structure <strong>of</strong> fibers, chemical re<strong>ac</strong>tions <strong>of</strong> wood<br />

components such as carbohydrates and lignin during pulping and ble<strong>ac</strong>hing, has led to several<br />

technological innovations in <strong>th</strong>e field <strong>of</strong> pulping. The spectrum <strong>of</strong> fibrous raw materials which was<br />

initially limited to wood, has widened to non-wood fibrous raw materials.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 83<br />

The papermaking process involves <strong>th</strong>ree main stages: raw material preparation, pulping and<br />

ble<strong>ac</strong>hing, and papermaking.<br />

A. Raw material preparation<br />

Wood and bamboo are felled at <strong>th</strong>e forests. Wood is debarked at <strong>th</strong>e felling or mill site. The fiber<br />

losses in handling is more <strong>th</strong>an 10%. Agricultural residues like straws & bagasse are stored in<br />

bales. Being seasonal crops, <strong>th</strong>eir storage for long periods are prone to microbial degradation<br />

which <strong>of</strong>ten affects <strong>th</strong>e quality <strong>of</strong> pulp produced.<br />

Chipping<br />

The wood is chipped in disc chippers which are also used for bamboo chipping, <strong>th</strong>ough <strong>th</strong>e<br />

Palman Drum type is nowadays commonly used for bamboo. About 53% <strong>of</strong> <strong>th</strong>e total number <strong>of</strong><br />

chippers (<strong>ac</strong>counting for 58% <strong>of</strong> <strong>th</strong>e total installed cap<strong>ac</strong>ity) were installed since 1975, and are<br />

mostly <strong>of</strong> <strong>th</strong>e drum types. While <strong>th</strong>e aggregate cap<strong>ac</strong>ity <strong>of</strong> chippers for individual units range<br />

between 35 to 168 t/h, most units fall between 45-50 t/h cap<strong>ac</strong>ity. Straws are cut by chop cutters,<br />

which are not power efficient, while bagasse is de-pi<strong>th</strong>ed before digestion.<br />

B. Pulping and ble<strong>ac</strong>hing<br />

Indian mills predominantly use <strong>th</strong>e alkaline pulping process. Large mills based on forest raw<br />

materials use <strong>th</strong>e Kraft process, whereas agro-based mills use <strong>th</strong>e soda process. Newsprint mills<br />

use mechanical, chemical, chemi-mechanical and chemi-<strong>th</strong>ermomechanical (CTMP) processes.<br />

Digestion<br />

The predominant pr<strong>ac</strong>tice for digestion is <strong>th</strong>e use <strong>of</strong> batch digesters. Two large mills use<br />

continuous digesters for bamboo and wood, whereas some <strong>of</strong> <strong>th</strong>e agro-based mills use Pandya<br />

digesters. The reasons for not using continuous digesters in agro-based mills include:<br />

- higher outlays for m<strong>ac</strong>hinery repl<strong>ac</strong>ement in <strong>th</strong>e existing units<br />

- l<strong>ac</strong>k <strong>of</strong> flexibility in <strong>th</strong>e continuous digester process system to <strong>ac</strong>cept varying raw material<br />

mix<br />

- <strong>th</strong>e relatively small size <strong>of</strong> <strong>th</strong>e mills makes it uneconomical to use continuous digesters<br />

more efficiently<br />

Ble<strong>ac</strong>hing<br />

Most Indian mills use chlorine-based ble<strong>ac</strong>hing chemicals wi<strong>th</strong> barometer drop leg or displ<strong>ac</strong>ement<br />

type <strong>of</strong> washers. Common ble<strong>ac</strong>hing sequences are CEHH, CEH, and CHHH, <strong>of</strong> which CEHH is<br />

most commonly used in order to <strong>ac</strong>hieve a brightness level <strong>of</strong> over 75%. Some large mills have


84 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

started using chlorine dioxide and peroxide partially, i.e., CE (p)HH, while many paper mills propose<br />

to go for oxygen ble<strong>ac</strong>hing.<br />

Pulp Washing<br />

Small mills wi<strong>th</strong>out chemical recovery systems normally employ <strong>th</strong>e po<strong>ac</strong>her-type washer followed<br />

by one or two drum washers. The fresh water consumption is as high as 20-50 m 3 /t (paper) in<br />

<strong>th</strong>ese mills. Integrated mills have 3-4 drum washers wi<strong>th</strong> counter-current washing.<br />

Stock Preparation<br />

Most <strong>of</strong> <strong>th</strong>e units have repl<strong>ac</strong>ed conical and wide angle refiners wi<strong>th</strong> <strong>th</strong>e relatively energy efficient<br />

double disc refiners.<br />

C. Paper m<strong>ac</strong>hines<br />

Three types <strong>of</strong> paper m<strong>ac</strong>hines are commonly employed in <strong>th</strong>e industry: cylinder molds,<br />

Fourdrinier formers, and twin wire formers<br />

The cylinder molds are commonly used for small mills engaged in <strong>th</strong>e manuf<strong>ac</strong>ture <strong>of</strong> multi-layered<br />

boards. The Fourdrinier m<strong>ac</strong>hines are most commonly employed bo<strong>th</strong> in small and big mills for<br />

<strong>th</strong>e manuf<strong>ac</strong>ture <strong>of</strong> varieties <strong>of</strong> paper. About 81% <strong>of</strong> <strong>th</strong>e total paper m<strong>ac</strong>hines have Fourdrinier<br />

formers and 84% have speeds <strong>of</strong> 150 to 300 meters per minute (mpm). Only 5 m<strong>ac</strong>hines have<br />

operating speeds <strong>of</strong> more <strong>th</strong>an 400 mpm.<br />

Twinformers <strong>th</strong>at are commonly employed in <strong>th</strong>e newsprint industry, have high speeds and can<br />

<strong>ac</strong>cept weaker pulp. However, <strong>th</strong>eir application in small units is not economically viable.<br />

O<strong>th</strong>er data regarding paper m<strong>ac</strong>hines used in <strong>th</strong>e industry are as follows: 56% <strong>of</strong> <strong>th</strong>e total number<br />

<strong>of</strong> paper m<strong>ac</strong>hines have <strong>th</strong>yrister control drives; 30% have sectorial drives, and 33% have<br />

line/pulley drives; 48% have open type <strong>of</strong> head boxes; 52% have closed-type head boxes; 62%<br />

have suction processes; 39% are equipped wi<strong>th</strong> size presses while 69% are equipped wi<strong>th</strong><br />

calendars. The condensate recovery in most <strong>of</strong> <strong>th</strong>e mills is between 60% to 90%.<br />

D. Chemical recovery system<br />

While all wood-based paper mills have chemical recovery systems, most <strong>of</strong> <strong>th</strong>e small mills do not<br />

have one, and <strong>th</strong>e efficiency attained in <strong>th</strong>e recovery units are below 90%. Impressive<br />

developments, however, have been made in <strong>th</strong>e evaporation and combustion <strong>of</strong> spent liquor.<br />

From <strong>th</strong>e 60s to <strong>th</strong>e 80s mills have installed ei<strong>th</strong>er short-tube or long-tube variety types <strong>of</strong><br />

evaporators. Since spent liquor exhibit very high viscosity, <strong>th</strong>is restricts <strong>th</strong>e evaporator outlet<br />

concentration to 40-45% solids. Scaling tendencies and colloidal instability <strong>of</strong> spent liquor are also<br />

<strong>th</strong>e common problems f<strong>ac</strong>ed in evaporator units. Recently, <strong>th</strong>e use <strong>of</strong> <strong>th</strong>e falling-film type <strong>of</strong>


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 85<br />

evaporator has been favored. Experience wi<strong>th</strong> <strong>th</strong>ese evaporators have shown clean benefits like<br />

high-end concentration, maximum steam economy and improved condensate quality.<br />

Boilers used in <strong>th</strong>e industry are <strong>th</strong>e coal-fired types. About 11% <strong>of</strong> <strong>th</strong>e total installed cap<strong>ac</strong>ity,<br />

mainly fluidized bed boilers, are 5 years <strong>of</strong> age. Prior to 1975, <strong>th</strong>e cap<strong>ac</strong>ity was 20 t/h <strong>of</strong> steam<br />

generated at 20-30 kg/cm 2 pressure and 380 o C to 400 o C temperature, wi<strong>th</strong> a <strong>th</strong>ermal efficiency <strong>of</strong><br />

50-60%. From 1975 onwards, <strong>th</strong>e steam generation cap<strong>ac</strong>ity increased to 25-27 t/h at 40-60<br />

kg/cm 2 pressure and 400 o C to 480 o C temperature. Thermal efficiency has increased to 70-80%.<br />

The Central Pulp and Paper Research <strong>Institute</strong> (CPPRI) is engaged in developing <strong>th</strong>e Direct Alkali<br />

Recovery System (DARS) for agro-based mills. Organizations like ESVIN Technologies and Amrit<br />

Banaspati Company are also engaged in R&D work for chemical recovery. CPPRI has made<br />

break<strong>th</strong>roughs in <strong>th</strong>e desilication <strong>of</strong> bl<strong>ac</strong>k liquor <strong>th</strong>at will improve performance <strong>of</strong> <strong>th</strong>e recovery<br />

unit in non-wood-based paper mills, while opening <strong>th</strong>e option for lime sludge reburning.<br />

E. O<strong>th</strong>er m<strong>ac</strong>hinery and equipment<br />

The manuf<strong>ac</strong>ture <strong>of</strong> paper from raw materials storage & transport to <strong>th</strong>e p<strong>ac</strong>king and handling <strong>of</strong><br />

<strong>th</strong>e finished product requires utilization <strong>of</strong> a wide range <strong>of</strong> equipment. In addition, various auxiliary<br />

items such as steam boilers, power generation equipment, effluent treatment equipment, etc., are<br />

also required.<br />

India has now developed its capability to manuf<strong>ac</strong>ture and supply almost <strong>th</strong>e entire range <strong>of</strong><br />

equipment for <strong>th</strong>e paper industry, specifically for <strong>th</strong>e pulping plant and stock preparation;<br />

equipment such as paper m<strong>ac</strong>hines, steam and power generation equipment, chemical recovery<br />

equipment, etc. Figure 6.2.4 shows <strong>th</strong>e general distribution <strong>of</strong> process automation in <strong>th</strong>e paper<br />

industry <strong>of</strong> India.<br />

6.2.2.4 Human resource in <strong>th</strong>e Indian paper industry<br />

Despite <strong>th</strong>e grow<strong>th</strong> <strong>of</strong> <strong>th</strong>e paper industry, industrial performance has been unsatisf<strong>ac</strong>tory due to<br />

<strong>th</strong>e poor management <strong>of</strong> materials, money, and manpower, <strong>of</strong> which manpower planning and<br />

training is most neglected. For a sustained performance, <strong>th</strong>e industry should have <strong>th</strong>e ability to<br />

adopt appropriate technology to conserve energy and raw materials, and to cut down costs. This<br />

challenge can be f<strong>ac</strong>ed only <strong>th</strong>rough a competent and skilled manpower at all levels. On <strong>th</strong>e<br />

average, <strong>th</strong>e industry utilizes 78 persons in <strong>th</strong>e production line per 1,000 annual tons <strong>of</strong><br />

production. The technical manpower components are 35-40 and 40-60 for every 1,000 annual<br />

tons in <strong>th</strong>e large and small mills, respectively. For <strong>th</strong>e whole Indian paper industry, pr<strong>of</strong>essional<br />

and technical manpower comprise 13% <strong>of</strong> <strong>th</strong>e total manpower; administrative/executive and<br />

managerial personnel constitute 23%; 12% are clerical personnel, 7% are service workers, and 45%<br />

are production-related workers.


86 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

To meet <strong>th</strong>e challenges <strong>of</strong> technical upgrading and productivity improvement, <strong>th</strong>e industry will<br />

strive for a reduction in its manpower usage wi<strong>th</strong> an associated rise in workers’ competence. For<br />

<strong>th</strong>e next 10-12 years, it is estimated <strong>th</strong>at <strong>th</strong>e average manpower utilization in <strong>th</strong>e country will be 35<br />

persons per 1,000 annual tons in <strong>th</strong>e paper & paper board sector, and 15-20 persons per 1,000<br />

annual tons in <strong>th</strong>e newsprint sector. Training programs in <strong>th</strong>e pulp and paper industry will be<br />

modified to fit into <strong>th</strong>e national pattern for degree/polytechnic diploma levels. The entire strategy<br />

<strong>of</strong> manpower development will involve training competent/skilled personnel to move <strong>th</strong>e industry<br />

to perform at its best level.<br />

Status (% <strong>of</strong> F<strong>ac</strong>tories)<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

1985 1990 1991 1992 1993<br />

Computerization Electronic Automation<br />

Electro Mechanical Regulation Manual Operation<br />

Figure 6.2.4. Status <strong>of</strong> process automation in <strong>th</strong>e paper industry<br />

6.2.2.5 Current status <strong>of</strong> <strong>th</strong>e pulp and paper industry in Indian national economy<br />

The paper industry constitutes <strong>th</strong>e core <strong>of</strong> industries directly linked to <strong>th</strong>e national economy.<br />

Current per capita consumption <strong>of</strong> paper is 2.5 kg, and is expected to grow to 4.2 kg by <strong>th</strong>e end <strong>of</strong><br />

<strong>th</strong>e century. Efforts to build additional cap<strong>ac</strong>ity to meet <strong>th</strong>e future requirements <strong>of</strong> various grades<br />

<strong>of</strong> paper are on-going. In f<strong>ac</strong>t, <strong>th</strong>e country has attained self-sufficiency in most varieties <strong>of</strong><br />

industrial paper. Newsprint, <strong>th</strong>ough, is still imported at 40% levels, implying a considerable<br />

outflow <strong>of</strong> foreign exchange.<br />

Considering <strong>th</strong>e huge amount <strong>of</strong> non-conventional raw materials available for pulp and paper<br />

manuf<strong>ac</strong>ture, <strong>th</strong>ere exists a big export potential in <strong>th</strong>e pulp and paper sector. In 1994-1995 alone,<br />

nearly 200,000 tons <strong>of</strong> paper had been exported to <strong>th</strong>ird world countries.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 87<br />

6.2.3 Evolution <strong>of</strong> energy efficiency in Indian pulp and paper industry<br />

Pulp and paper being an energy intensive industry, is ranked <strong>th</strong>e six<strong>th</strong> largest energy consumer in<br />

<strong>th</strong>e country. Fuels from external sources comprise 70% <strong>of</strong> <strong>th</strong>e total used, as compared to 30-40%<br />

for <strong>th</strong>ose in developed countries. The energy component in <strong>th</strong>e Indian paper industry is as high as<br />

30% <strong>of</strong> <strong>th</strong>e total cost <strong>of</strong> production, consuming about 7% <strong>of</strong> <strong>th</strong>e country’s coal and approximately<br />

3% <strong>of</strong> <strong>th</strong>e electrical energy requirements <strong>of</strong> <strong>th</strong>e whole manuf<strong>ac</strong>turing sector. Unlike o<strong>th</strong>er<br />

industries, <strong>th</strong>e paper industry requires large quantity <strong>of</strong> low grade energy (200 o C). Of <strong>th</strong>e total<br />

energy requirements, about 15-25% is <strong>of</strong> high grade (electrical energy), and <strong>th</strong>e rest is constituted<br />

by low grade energy. In terms <strong>of</strong> <strong>th</strong>ermodynamic efficiency, <strong>th</strong>e industry is lowest among <strong>th</strong>e<br />

energy intensive manuf<strong>ac</strong>turing units <strong>of</strong> <strong>th</strong>e steel and cement industries.<br />

The industry was greatly affected by <strong>th</strong>e energy crisis in <strong>th</strong>e early 1970s, which led to <strong>th</strong>e adoption<br />

<strong>of</strong> energy conservation me<strong>th</strong>ods. Most <strong>of</strong> <strong>th</strong>e mills installed before <strong>th</strong>e 1970 crisis however, were<br />

not energy conserving in design and technology. Even <strong>th</strong>ough <strong>th</strong>e concept <strong>of</strong> energy savings<br />

intensity had already been identified in <strong>th</strong>e 80s, consumption patterns remained <strong>th</strong>e same, brought<br />

about by <strong>th</strong>e following:<br />

- l<strong>ac</strong>k <strong>of</strong> modernization<br />

- use <strong>of</strong> obsolete technology<br />

- l<strong>ac</strong>k <strong>of</strong> process control system<br />

- change in fibrous raw material mix<br />

The estimated energy consumption in <strong>th</strong>e pulp and paper industry is 2.42 tons <strong>of</strong> oil equivalent per<br />

ton <strong>of</strong> paper. The major energy-consuming plants are <strong>th</strong>e chippers, digesters, refiners, paper<br />

m<strong>ac</strong>hines and evaporation plants. The present specific energy consumption patterns show higher<br />

variations in <strong>th</strong>e integrated pulp and paper mills. The specific steam consumption varies from 10.2<br />

to 17.4 tons/ton <strong>of</strong> paper produced, while <strong>th</strong>e specific power consumption varies from 1,300 to<br />

1,940 kWh/ton <strong>of</strong> paper. Water consumption also varies from 225 m 3 to 450 m 3 /ton <strong>of</strong> paper.<br />

In <strong>th</strong>e last decade, <strong>th</strong>e cost <strong>of</strong> coal and electricity has increased by 500% and fuel oil by 1000%.<br />

Based on <strong>th</strong>e industry’s 4.25 million tons <strong>of</strong> total installed cap<strong>ac</strong>ity and cap<strong>ac</strong>ity utilization for all<br />

products, <strong>th</strong>e projected consumption <strong>of</strong> <strong>th</strong>e paper industry by year 2000 would require an<br />

additional 3.0 million tons <strong>of</strong> coal and about 1.82 million kWh electricity. This means a 76%<br />

increase in coal requirements and 139% increase in electricity requirements. Wi<strong>th</strong> rising energy<br />

costs, ways and means to conserve energy now becomes a major <strong>th</strong>rust in <strong>th</strong>e industry.<br />

Energy consumption patterns in developed countries and in India<br />

Between 1975-1983, <strong>th</strong>e Japanese paper industry has reduced its specific energy consumption from<br />

0.662 toe to 0.437 toe per ton <strong>of</strong> paper, <strong>ac</strong>counting for a 34% reduction in specific energy


88 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

consumption. This could be attributed to <strong>th</strong>e country’s heavy investments in fossil fuel substitution<br />

energy programs. European oil consumption has also been cut down from 37% to 8%. The<br />

Swedish paper industry managed to cut its oil fuel consumption by over 70% between 1973 and<br />

1983. In <strong>th</strong>e USA, energy from residual fuel and self-generating sources now <strong>ac</strong>counts for an<br />

estimated 57-58 percent.<br />

Clearly, most <strong>of</strong> <strong>th</strong>e developed countries have made significant progress to conserve energy, and<br />

are presently depending only on 30-40% <strong>of</strong> fuels from external sources. India however, is still 70%<br />

dependent on external fuels. The industry’s specific energy consumption varies between 0.76 to<br />

1.325 toe per ton <strong>of</strong> paper.<br />

Table 6.2.1, Table 6.2.2 and Figure 6.2.5 show a comparison between mills in India and <strong>th</strong>e<br />

developed countries, and energy consumption patterns in <strong>th</strong>e country. It is wor<strong>th</strong>while to note<br />

<strong>th</strong>at some Indian paper mills have already taken some in-plant energy conservation measures.<br />

Table 6.2.1 Comparison <strong>of</strong> energy consumption <strong>of</strong> developed countries and India<br />

Particulars Developed countries India<br />

Total specific steam consumption, t/t paper 6.5-8.5 10-16<br />

Digester 1.9-2.3 2.3-3.9<br />

Evaporator 1.5-2.2 2.5-4.0<br />

Paper m<strong>ac</strong>hine 1.9-2.0 3.0-4.0<br />

S/R plant 0.3-0.5 0.5-1.1<br />

Ble<strong>ac</strong>h plant 0.2-0.25 0.35-0.40<br />

Steam generator per ton <strong>of</strong> bl<strong>ac</strong>k solids 3.0-3.5 1.5-2.5<br />

Table 6.2.2 Electricity consumption <strong>of</strong> paper in Developing countries and India (kWh/t)<br />

Particulars Developed countries India<br />

Total Consumption 1150-1250 1200-1700<br />

Chipper 92-98 112-128<br />

Digester 43-46 58-62<br />

Washing and screening 116-122 145-155<br />

Ble<strong>ac</strong>hing plant 66-69 88-92<br />

Stock preparation 164-175 275-286<br />

Paper m<strong>ac</strong>hine 410-415 465-475<br />

S/R plant 127-135 170-190<br />

Utilities & o<strong>th</strong>ers 160-165 246-252<br />

Total specific energy (Gcal/t) 4.14-4.50 4.32-6.12


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 89<br />

2.5<br />

2.0<br />

1.5<br />

1.0<br />

0.5<br />

0<br />

1960 1970 1980 1990 1992<br />

Specific electricity, MWh / ton Paper<br />

Specific coal, toe / ton Paper<br />

Specific fuel oil, toe / ton Paper<br />

Specific non-conventional energy, toe / ton Paper<br />

Integrated specific energy, toe / ton Paper<br />

Figure 6.2.5 Energy consumption pattern in <strong>th</strong>e Indian paper industry<br />

6.2.4 Environmental externalities <strong>of</strong> technological development in <strong>th</strong>e pulp and paper<br />

industry<br />

The pulp and paper industry is essentially a chemical process industry wi<strong>th</strong> a distinctive imp<strong>ac</strong>t on<br />

<strong>th</strong>e environment. It is estimated <strong>th</strong>at about 41.8% <strong>of</strong> wood is recovered as ble<strong>ac</strong>hed pulp, roughly<br />

4.2% <strong>of</strong> <strong>th</strong>e remaining wood ends up as solid waste, as 5.25% goes into waste waters as dissolved<br />

organic matter, and 2.3% ends up as suspended solids also in wastewater.<br />

The potential pollutants from a pulp and paper mill fall into four categories as follows:<br />

- effluents<br />

- air pollutants<br />

- solid wastes<br />

- noise pollution


90 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

6.2.4.1 Effluents<br />

Waste water is discharged from almost all unit operations. Large paper mill waste waters are<br />

generally segregated into streams, namely, colored streams (due to lignin from pulp washing,<br />

caustic extr<strong>ac</strong>tion and chemical recovery sector), and colorless stream (chipper house, chlorination,<br />

hypochlorite and paper m<strong>ac</strong>hines). Ble<strong>ac</strong>h plant effluents constitute nearly 65% <strong>of</strong> <strong>th</strong>e total BOD<br />

and 90% <strong>of</strong> <strong>th</strong>e total color load <strong>of</strong> combined effluents in large mills.<br />

Small mills generate ostensibly higher pollution <strong>th</strong>an larger mills mainly due to <strong>th</strong>e absence <strong>of</strong><br />

chemical recovery systems. Major pollution loads come from spent pulping liquor, <strong>of</strong> which 90%<br />

<strong>of</strong> <strong>th</strong>e color and 50% <strong>of</strong> <strong>th</strong>e COD is due to lignin which is almost completely bio-refr<strong>ac</strong>tory.<br />

Tables 6.2.3 and 6.2.4 show <strong>th</strong>e effluent char<strong>ac</strong>teristics and <strong>th</strong>e pollution loads <strong>of</strong> bl<strong>ac</strong>k liquor and<br />

organics in Indian pulp and paper mills.<br />

Table 6.2.3 Char<strong>ac</strong>teristics <strong>of</strong> effluents from <strong>th</strong>e pulp and paper mills<br />

Integrated pulp Newsprint Agro-based small Waste paper<br />

& paper mills mills paper mills mills<br />

Raw material bamboo, hardwood bamboo, rice straw, wheat waste paper<br />

hardwood straw, bagasse, etc.<br />

waste water, m3/ton 230-250 200 200-380 70-150<br />

PH<br />

Pollution load, kg/ton paper:<br />

6.0-9.0 7.2-7.3 6.0-8.5 6.0-8.5<br />

Suspended solids 100-150 100 90-240 50-80<br />

BOD5 35-50 45 85-270 10-40<br />

COD 150-200 135 500-1100 50-90<br />

Table 6.2.4 Pollution loads <strong>of</strong> bl<strong>ac</strong>k liquor and organics<br />

Parameters Bagasse Rice straw<br />

COD, kg/t pulp 1075 1247<br />

BOD, kg/t pulp 216 234<br />

Bl<strong>ac</strong>k liquor COD/BOD<br />

5.0<br />

5.3<br />

Color, kg/t pulp (PCU)<br />

1394<br />

1514<br />

Acid precipitation COD, kg/t pulp 530 628<br />

Lignin separated BOD, kg/t pulp was not biodegradable was not biodegradable<br />

Color, kg/t pulp (PCU)<br />

1283<br />

1444<br />

Supernatant free<br />

from lignin<br />

COD, kg/t pulp<br />

BOD, kg/t pulp<br />

COD/BOD<br />

Color, kg/t pulp (PCU)<br />

417<br />

197<br />

2.1<br />

82<br />

381<br />

247<br />

1.5<br />

1113


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 91<br />

Al<strong>th</strong>ough <strong>th</strong>e spent pulping liquor is <strong>th</strong>e major source <strong>of</strong> pollution in terms <strong>of</strong> depleting oxygen<br />

conditions, <strong>th</strong>e toxicity <strong>of</strong> <strong>th</strong>e effluents in terms <strong>of</strong> Total Organic Chlorine (TOCl) originates from<br />

<strong>th</strong>e ble<strong>ac</strong>hing plant <strong>of</strong> <strong>th</strong>e large and small mills. The amount <strong>of</strong> TOCl produced is dependent on<br />

<strong>th</strong>e amount <strong>of</strong> free Cl2 used during ble<strong>ac</strong>hing operations and is roughly calculated by <strong>th</strong>e following<br />

equation:<br />

TOCl = K(C+D/5 +H/2) kg TOCl/air dried ton <strong>of</strong> pulp,<br />

where C, D, & H are doses <strong>of</strong> Cl 2, ClO 2 and hypochlorite.<br />

In India, <strong>th</strong>e situation due to <strong>th</strong>ese chloro compounds becomes more alarming in <strong>th</strong>e small paper<br />

mills. Increasing caustic soda prices and increasing gap between caustic soda and chlorine prices<br />

indicate a tendency to decrease alkali charge in cooking, <strong>th</strong>ereby increasing lignin content and<br />

chlorine consumption.<br />

6.2.4.2 Solid wastes<br />

Solid wastes constitute a complex problem in <strong>th</strong>e industry due to <strong>th</strong>e varying nature and enormity<br />

<strong>of</strong> <strong>th</strong>e wastes generated. Table 6.2.5 shows <strong>th</strong>e solid waste generation from <strong>th</strong>e small and large<br />

paper mills. The main sources <strong>of</strong> solid wastes are:<br />

- The raw material handling/preparation<br />

- The effluent sludge from <strong>th</strong>e combined mills effluent treatment plant<br />

- Flue dust from coal-fired boilers and fines in <strong>th</strong>e coal<br />

- Coal cinders from coal-fired boilers<br />

- Lime sludge from <strong>th</strong>e chemical recovery plant<br />

- Hypo mud from <strong>th</strong>e hypo plant<br />

- Pi<strong>th</strong> generation from <strong>th</strong>e de-pi<strong>th</strong>ing plant.<br />

Wastes from raw materials handling are burnt, discharged as effluent, or dumped in barren lands.<br />

Burning <strong>of</strong> lime sludge from causticizers and hypochlorite preparation plants in India, however, is<br />

unsuccessful due to <strong>th</strong>e high silica content. Hence, <strong>th</strong>e desilication <strong>of</strong> <strong>th</strong>e bl<strong>ac</strong>k liquor is essential.<br />

Moreover, sludge from water treatment or effluent treatment plants contains nearly 72% organic<br />

compounds and has 45-50% water content. Therefore, dewatering <strong>of</strong> <strong>th</strong>e sludge, and stabilizing <strong>th</strong>e<br />

water is necessary before its final disposal.<br />

Coal ash which <strong>ac</strong>counts for 30-32% <strong>of</strong> <strong>th</strong>e total coal burnt also adds to <strong>th</strong>e solid waste disposal<br />

problem. Most <strong>of</strong> it is used as landfill, al<strong>th</strong>ough its disposal is still a cause for concern.<br />

From <strong>th</strong>e foregoing discussion, <strong>th</strong>e seriousness <strong>of</strong> <strong>th</strong>e problems due to wastes generated from <strong>th</strong>e<br />

pulp and paper industry is not some<strong>th</strong>ing to be taken for granted. The pressure on land is already<br />

high, and unless long term plans are made to ei<strong>th</strong>er reburn <strong>th</strong>e lime sludge, to separate and re-use<br />

fibrous wastes, and to use coal ash for building materials, <strong>th</strong>e mills will f<strong>ac</strong>e serious problems for


92 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

solid waste disposal in <strong>th</strong>e coming years. The rising consciousness for a clean, heal<strong>th</strong>y environment<br />

and <strong>th</strong>e implementation <strong>of</strong> stringent measures for solid waste disposal will force <strong>th</strong>e industry to<br />

make decisions in order to stop environmental degradation.<br />

Table 6.2.5 Solid waste generation in paper mills<br />

Waste source Large paper mills<br />

(kg dry solids / ton<br />

paper)<br />

Raw material<br />

handling/preparation<br />

Small paper mills<br />

(kg dry solids / ton<br />

paper)<br />

45 210*<br />

Hypochlorite preparation grit 20 nil<br />

Recausticizing lime mud 593 nil<br />

Power plant/boiler ash** 656 1300<br />

Waste treatment plant***<br />

1. Primary sludge 159 105<br />

2. Secondary sludge 34 105<br />

TOTAL 1507 1731<br />

% inorganic solids 84 75<br />

% organic solids 16 25<br />

6.2.4.3 Air pollution<br />

Particulate and gaseous pollutants from <strong>th</strong>e pulp and paper mills are discharged <strong>th</strong>rough <strong>th</strong>e<br />

following:<br />

- Digester relief<br />

- Brown stock washers<br />

- Washer-ble<strong>ac</strong>h liquor preparation plant<br />

- Multi-effect evaporators for bl<strong>ac</strong>k liquor<br />

- Direct cont<strong>ac</strong>t evaporators like cascades, cyclones, etc.<br />

- Chemical recovery furn<strong>ac</strong>e<br />

- Smelt dissolving and slaking tanks<br />

- Lime kilns<br />

- Boiler flue gases<br />

* When bagasse is used in pl<strong>ac</strong>e <strong>of</strong> straw in SPM, solid waste generated from raw materials handling will<br />

be 550 kg/ton paper and total solid wastes will be 2071 kg/t wi<strong>th</strong> 65% inorganic solids.<br />

** Ash generation depends on % ash in coal and <strong>th</strong>e amount <strong>of</strong> power/steam generation.<br />

*** Estimated (assuming 0.5 kg mixed liquor suspended solids produced / kg BOD removed in <strong>ac</strong>tivated<br />

sludge treatment plant.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 93<br />

Air pollutants are generally controlled by <strong>th</strong>e dust-collecting equipment. Chemical particulates<br />

emitted from recovery furn<strong>ac</strong>es, smelt dissolving tanks and lime kilns, mostly <strong>of</strong> sodium sulfate<br />

and sodium carbonate, are controlled to a considerable extent by <strong>th</strong>e use <strong>of</strong> venturi scrubbers,<br />

electrostatic precipitators, and o<strong>th</strong>er effective dust-collecting devices.<br />

Emitted gases which are a variable mixture <strong>of</strong> hydrogen sulfide, me<strong>th</strong>yl mercaptans, dime<strong>th</strong>yl<br />

sulfide and sulfur dioxide, originate mainly from <strong>th</strong>e sulfate pulping process. Table 6.2.6 shows <strong>th</strong>e<br />

main emissions <strong>of</strong> reduced sulfur compounds from <strong>th</strong>e sulfate pulping process.<br />

Table 6.2.6 Main emissions <strong>of</strong> sulfur compounds from <strong>th</strong>e sulfate pulping process<br />

Emission rate, kg/t90<br />

Emission source<br />

Batch digester<br />

H2S 0-0.15<br />

*MM<br />

CH3SH 0-1.3<br />

*DMS<br />

CH3SCH3 0.05-3.3<br />

*DMDS<br />

CH3SSC H3 0.05-2.0<br />

Continuous digester 0-0.10 0.5-1 0.05-0.5 0.05-0.4<br />

Washing 0-0.10 0.05-1 0.1-1.0 0.1-0.08<br />

Evaporation 0.05-1.5 0.05-0.8 0.05-1.0 0.05-1.0<br />

Recovery Furn<strong>ac</strong>e (wi<strong>th</strong><br />

DCE)<br />

0-2.50 0-2 0-1 0.03<br />

Smelt dissolving tank 0-1.0 0-0.08 0-0.5 0.03<br />

*MM: Me<strong>th</strong>yl-mercaptan; DMS: Dime<strong>th</strong>yl sulfide; DMDS: Dime<strong>th</strong>yl Disulfide<br />

6.2.4.4 Noise pollution<br />

The major contribution to noise pollution comes from <strong>th</strong>e chipper house, v<strong>ac</strong>uum pumps and<br />

compressors. Mufflers are necessary to reduce noise in v<strong>ac</strong>uum pumps; and in <strong>th</strong>e paper m<strong>ac</strong>hine<br />

drive, changing <strong>th</strong>e material <strong>of</strong> construction not only reduces noise, it also has <strong>th</strong>e additional<br />

advantage <strong>of</strong> self-lubrication. Wherever possible, <strong>th</strong>e paper m<strong>ac</strong>hine drive gears are made <strong>of</strong><br />

polypick or nylon material to serve <strong>th</strong>e purpose <strong>of</strong> reducing noise.<br />

6.2.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough<br />

technological change<br />

6.2.5.1 Energy saving potential<br />

It is estimated <strong>th</strong>at <strong>th</strong>e energy bill <strong>of</strong> <strong>th</strong>e pulp and paper industry is about Rs 10 billion wi<strong>th</strong> a<br />

savings potential <strong>of</strong> at least 20% or Rs 2 billion, if a proper impetus is given to energy<br />

management. Technological renovations can play a significant role in improving <strong>th</strong>e energy<br />

efficiency <strong>of</strong> <strong>th</strong>e processes and lead to a reduction in specific energy consumption, improvement<br />

<strong>of</strong> energy and productivity and product quality. These may include major modifications <strong>of</strong> <strong>th</strong>e<br />

existing plants and changes in <strong>th</strong>e operating pr<strong>ac</strong>tices or process controls and equipment.


94 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

The industry can <strong>ac</strong>hieve better energy performance in a number <strong>of</strong> ways:<br />

- short-term schemes wi<strong>th</strong> small investments and improved housekeeping measures<br />

estimated to reduce <strong>th</strong>e energy bill by 5%<br />

- medium-term schemes wi<strong>th</strong> attr<strong>ac</strong>tive pay-b<strong>ac</strong>k periods can reduce <strong>th</strong>e energy bill by 10-<br />

15%<br />

- long-term schemes wi<strong>th</strong> major investments can cut <strong>th</strong>e energy bill by 5-10%.<br />

6.2.5.2 Energy and environmental audits, process modifications, optimization and control,<br />

and energy generation<br />

A. Energy and environmental audits<br />

Energy audit is used as a tool in defining and pursuing comprehensive energy management<br />

programs. Its primary objective is to determine ways <strong>of</strong> reducing energy consumption per unit <strong>of</strong><br />

product output. The process is conducted in two ways: preliminary audit and <strong>th</strong>e detailed audit.<br />

The preliminary audit is conducted in a limited span <strong>of</strong> time, focusing on <strong>th</strong>e major energy supply<br />

and demand aspects which <strong>ac</strong>count for 70% <strong>of</strong> <strong>th</strong>e total energy requirements. The detailed audit<br />

goes beyond <strong>th</strong>e quantitative estimates to cost savings.<br />

Environmental audits also help in identifying areas <strong>of</strong> high pollution loads which can be useful for<br />

<strong>th</strong>e management to come up wi<strong>th</strong> measures to reduce pollution discharges. In general, Indian<br />

paper mills adopt pollution abatement strategies <strong>of</strong> two types:<br />

- Internal measure: production process control aimed at reducing waste water volume and<br />

pollutant discharge load from <strong>th</strong>e mill<br />

- External measure: waste water treatment technologies or end-<strong>of</strong>-pipe treatment systems<br />

aimed at reducing discharges <strong>of</strong> pollutants to <strong>th</strong>e environment.<br />

B. Process modifications, optimization and advanced controls<br />

Through <strong>th</strong>e combination <strong>of</strong> modifying existing processes and <strong>th</strong>e development <strong>of</strong> new ones, <strong>th</strong>e<br />

objective <strong>of</strong> improving energy efficiency can be <strong>ac</strong>hieved. Considerable energy savings in <strong>th</strong>e<br />

industry has been reported brought about by such measures:<br />

- Digester: 10-20%<br />

- Ble<strong>ac</strong>hing 5-10%<br />

- Evaporator 3-5%<br />

- Recovery boiler 20-50%<br />

- Paper m<strong>ac</strong>hines 10-20%<br />

Following are some latest technologies <strong>th</strong>at are applied in <strong>th</strong>e pulp and paper industry <strong>of</strong> India:


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 95<br />

Raw Materials Handling<br />

1. Repl<strong>ac</strong>ement <strong>of</strong> disc chippers by drum chippers<br />

In some <strong>of</strong> <strong>th</strong>e mills, it has been observed <strong>th</strong>at <strong>th</strong>e repl<strong>ac</strong>ement <strong>of</strong> large numbers <strong>of</strong> disc-type low<br />

cap<strong>ac</strong>ity chippers wi<strong>th</strong> high cap<strong>ac</strong>ity chippers made it possible to reduce energy consumption from<br />

35 kWh to as low as 7 kWh/ TBD1 chips.<br />

Table 6.2.7 Comparative energy consumption <strong>of</strong> different chippers used<br />

Type <strong>of</strong> chippers Cap<strong>ac</strong>ity TBD Energy consumption<br />

kWh/ton <strong>of</strong> BD chip<br />

1. Drum type 20-25 7<br />

2. Disc type 6-10 30<br />

(Status: already in use in <strong>th</strong>ree large mills)<br />

2. Conversion <strong>of</strong> pneumatic conveyor to <strong>th</strong>e mechanical type<br />

80% <strong>of</strong> <strong>th</strong>e mills in India have resorted to <strong>th</strong>e mechanical type <strong>of</strong> conveying, and a reduction <strong>of</strong> 4-<br />

5 tons energy consumption had been realized. Performance-wise, <strong>th</strong>e cleated conveyor belts <strong>of</strong>fer<br />

an excellent alternative to <strong>th</strong>e pneumatic conveyors. Due to layout restrictions, however, <strong>th</strong>e o<strong>th</strong>er<br />

mills are not able to likewise do conversions.<br />

Pulping<br />

1. Installation <strong>of</strong> continuous digesters in pl<strong>ac</strong>e <strong>of</strong> batch digesters<br />

In some <strong>of</strong> <strong>th</strong>e large integrated mills mainly in <strong>th</strong>e public sector units, <strong>th</strong>e old conventional batch<br />

digesters are now being repl<strong>ac</strong>ed by continuous digesters, and are found to be energy efficient<br />

(Table 6.2.8). Advantages brought about by <strong>th</strong>e latter are:<br />

- uniform cooking and better pulp quality<br />

- low specific energy consumption<br />

- less alkali charge<br />

- shorter cooking cycle<br />

- higher liquor concentration for recovery<br />

2. RDH/Cold Blow System<br />

This technological innovation has been introduced for energy conservation <strong>of</strong> 20-25%, and are<br />

ideally suited for stationary digesters.<br />

1 TBD : Ton Bone Dry


96 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.2.8 Comparative performance <strong>of</strong> different digesters used<br />

Batch Continuous<br />

Steam/ton <strong>of</strong> pulp 1.6 1.0<br />

Power units/ton <strong>of</strong> pulp 150 56<br />

Alkali (%) 16 14<br />

(Status: HPC units (Nawgaon, C<strong>ac</strong>har) have Kamyr digesters whereas Seshashayee<br />

Paper Boards and Tamilnadu News Print Ltd. have Pandia continuous digesters.)<br />

Ble<strong>ac</strong>hing<br />

1. Oxygen ble<strong>ac</strong>hing<br />

This process is being used in paper mills which go for a low kappa number pulping. The<br />

introduction <strong>of</strong> oxygen delignification before ble<strong>ac</strong>hing reduces <strong>th</strong>e ble<strong>ac</strong>h consumption, making<br />

<strong>th</strong>e ble<strong>ac</strong>h effluent less toxic towards <strong>th</strong>e environment wi<strong>th</strong> <strong>th</strong>e added advantage <strong>of</strong> being able to<br />

generate additional steam from extr<strong>ac</strong>ted organics at <strong>th</strong>e oxygen stage.<br />

Ano<strong>th</strong>er recently introduced ble<strong>ac</strong>hing technique is <strong>th</strong>e use <strong>of</strong> peroxide in <strong>th</strong>e conventional<br />

systems, which has already been adopted in one <strong>of</strong> <strong>th</strong>e paper mills in <strong>th</strong>e country.<br />

2. Stock preparation<br />

Most <strong>of</strong> <strong>th</strong>e Indian integrated and non-integrated paper mills are repl<strong>ac</strong>ing <strong>th</strong>e conventional conical<br />

and wide angle refiners wi<strong>th</strong> disc refiners, which are found to be comparatively highly energy<br />

efficient (Table 6.2.9).<br />

Table 6.2.9 Comparative power consumption <strong>of</strong> different refiners used<br />

Type Specific energy consumption<br />

(kWh / sr / ton <strong>of</strong> pulp)<br />

Wide angle refiner 14-18<br />

Conical refiner 9-13<br />

Double disc refiner 7-9<br />

Triple disc refiner 6<br />

Chemical Recovery<br />

1. Evaporators<br />

The type <strong>of</strong> evaporators being used in <strong>th</strong>e Indian paper industry has been <strong>th</strong>e long & short tube<br />

evaporators. These are currently being repl<strong>ac</strong>ed by <strong>th</strong>e 7-effect free falling film type evaporators<br />

which reduce steam consumption by 25-30% in <strong>th</strong>e evaporator section. Increasing <strong>th</strong>e number <strong>of</strong><br />

effects <strong>of</strong> falling film evaporators can <strong>ac</strong>hieve a steam economy as high as 8.0.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 97<br />

Recently, high pressure pumps have also been installed in some <strong>of</strong> <strong>th</strong>e paper mills which help to<br />

improve steam economy from 4.2 to 4.8.<br />

2. Energy cogeneration <strong>th</strong>rough boiler modifications<br />

A number <strong>of</strong> improvements in <strong>th</strong>e paper industry are needed wi<strong>th</strong> regards to <strong>th</strong>e following:<br />

configuration <strong>of</strong> recovery boilers wi<strong>th</strong> respect to liquor firing, efficient <strong>th</strong>ree zone air distribution,<br />

auxiliary fuel furn<strong>ac</strong>e construction corrosion, protection and steam pressure. Earlier, boilers were<br />

giving steam pressures <strong>of</strong> 20 kg/cm 2 but mills are now able to produce steam pressures <strong>of</strong> 40-60<br />

kg/cm 2 . Wi<strong>th</strong> new designs, boilers can now produce high pressure steam <strong>of</strong> 100 kg/cm 2 . By<br />

incorporating <strong>th</strong>e above-mentioned improvement, <strong>th</strong>e West Coast Paper Mills in India is now<br />

going for recovery wi<strong>th</strong> steam pressure <strong>of</strong> 80 kg/cm 2 .<br />

3. Introduction <strong>of</strong> on-line measurement and control system<br />

On-line measurements and control systems have lately been introduced in Indian paper m<strong>ac</strong>hines<br />

in <strong>th</strong>e Tribeni and HNL paper mills. O<strong>th</strong>er mills are following suit. The introduction <strong>of</strong> such<br />

systems aids in <strong>th</strong>e following:<br />

- high fiber savings<br />

- improved and consistent quality <strong>of</strong> paper<br />

- optional moisture content<br />

- reduction in energy consumption due to high % <strong>of</strong> moisture in paper.<br />

Digesters<br />

It has been observed <strong>th</strong>at <strong>th</strong>e use <strong>of</strong> low liquor to material ratio is quite effective in reducing <strong>th</strong>e<br />

energy consumption in <strong>th</strong>e digester section. In small agro-based pulp mills, <strong>th</strong>is is <strong>ac</strong>hieved by <strong>th</strong>e<br />

constant monitoring <strong>of</strong> low moisture in <strong>th</strong>e raw material, maintaining a high concentration <strong>of</strong> <strong>th</strong>e<br />

cooking liquor (100g/li) and a high temperature or shorter cooking cycle.<br />

Installation <strong>of</strong> screw press for efficient washing <strong>of</strong> pulp<br />

In conventional washing systems, non-woody raw materials are more difficult to wash compared<br />

to woody raw materials. The usual equipment being used is <strong>th</strong>e counter current multistage v<strong>ac</strong>uum<br />

drum filters. It is observed, however, <strong>th</strong>at for every percent increase in solids, a savings potential <strong>of</strong><br />

25 tons <strong>of</strong> steam per day in a 100 tons per day pulp mill is possible. Table 6.2.10 shows how <strong>th</strong>e<br />

steam requirement in evaporators is reduced wi<strong>th</strong> an increase in inlet solid concentrations.<br />

In one <strong>of</strong> <strong>th</strong>e straw-based mills, it was observed <strong>th</strong>at <strong>th</strong>e installation <strong>of</strong> <strong>th</strong>e screw press before <strong>th</strong>e<br />

v<strong>ac</strong>uum washer increased <strong>th</strong>e specific loading rate and initial concentration <strong>of</strong> weak bl<strong>ac</strong>k liquor to<br />

<strong>th</strong>e evaporator. This reduced <strong>th</strong>e steam requirement during <strong>th</strong>e evaporation process. Table 6.2.11<br />

shows <strong>th</strong>e effects <strong>of</strong> process modification.


98 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.2.10 Steam requirements wi<strong>th</strong> varying inlet and outlet concentrations<br />

White bl<strong>ac</strong>k liquor Final concentration Steam requirement<br />

(%)<br />

(t/t <strong>of</strong> pulp)<br />

6 40 10.6<br />

42 10.7<br />

45 10.8<br />

8 40 7.5<br />

42 7.6<br />

45 7.7<br />

10 40 5.6<br />

42 5.7<br />

45 5.8<br />

Table 6.2.11 Conventional and screw pressing followed by conventional washing<br />

Mode Specific loading<br />

rate<br />

BDMT/m<br />

Conventional washer (3-<br />

stage)<br />

Screw press followed by<br />

conventional washer (3stage)<br />

Bl<strong>ac</strong>k liquor<br />

solids<br />

%<br />

Chemical loss<br />

kg NaOH/t<br />

1.46 10 18<br />

1.73 12 12<br />

High solids evaporation <strong>th</strong>rough <strong>th</strong>ermal depolymerization<br />

The energy in terms <strong>of</strong> steam <strong>th</strong>at can be generated per ton <strong>of</strong> bl<strong>ac</strong>k liquor solids is dependent on<br />

<strong>th</strong>e concentration <strong>of</strong> bl<strong>ac</strong>k liquor <strong>th</strong>at is fired in <strong>th</strong>e recovery boiler. Since it is difficult to handle<br />

highly viscous bl<strong>ac</strong>k liquor from non-woody materials in <strong>th</strong>e evaporator, heat treatment <strong>of</strong> bl<strong>ac</strong>k<br />

liquor at temperatures higher <strong>th</strong>an <strong>th</strong>e cooking temperature could reduce <strong>th</strong>e viscosity <strong>of</strong> bl<strong>ac</strong>k<br />

liquor tremendously, making it possible for <strong>th</strong>e bl<strong>ac</strong>k liquor to evaporate, leaving behind some<br />

70% solids. The advantages <strong>of</strong> <strong>th</strong>e bl<strong>ac</strong>k liquor treatment are <strong>th</strong>e following:<br />

- Instead <strong>of</strong> a 50-55% <strong>th</strong>ermal efficiency for 55% bl<strong>ac</strong>k liquor solids, <strong>th</strong>e net <strong>th</strong>ermal<br />

efficiency is likely to re<strong>ac</strong>h 70% in cases <strong>of</strong> 65% solid concentration.<br />

- The use <strong>of</strong> direct cont<strong>ac</strong>t evaporator is eliminated, <strong>th</strong>ereby reducing gaseous pollution.<br />

C. Energy generation<br />

Wi<strong>th</strong> regards to energy generation, small paper plants operating wi<strong>th</strong> lower cap<strong>ac</strong>ity boilers<br />

consume waste fuels such as rice husk, bagasse, etc., and depend greatly on purchased power.<br />

Large mills on <strong>th</strong>e o<strong>th</strong>er hand, generate part <strong>of</strong> <strong>th</strong>eir own power <strong>th</strong>rough cogeneration.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 99<br />

Commonly-used boilers are <strong>th</strong>e stoker-fired boilers which may ei<strong>th</strong>er be <strong>th</strong>e chain grate or<br />

spreader-stoker type, wi<strong>th</strong> cap<strong>ac</strong>ities ranging from 6-80 t/h. Most medium and large-size mills<br />

currently have installed fluidized bed combustion (FBC) boilers or are in <strong>th</strong>e process <strong>of</strong> converting<br />

spreader stoker to FBC boilers.<br />

6.2.6 Status <strong>of</strong> <strong>th</strong>e application <strong>of</strong> new technologies<br />

The extent <strong>of</strong> employment <strong>of</strong> energy-efficient and environmentally sound technologies (EEESTs)<br />

in <strong>th</strong>e pulp and paper mills <strong>of</strong> India is summarized in Table 6.2.12.<br />

Table 6.2.12 EEESTs in <strong>th</strong>e pulp and paper mills <strong>of</strong> India<br />

<strong>Technology</strong> No. <strong>of</strong> mills using <strong>th</strong>e technology<br />

Palman chippers 7<br />

Kamyr continuous digesters 2<br />

Pandia continuous digesters 3<br />

Oxidative extr<strong>ac</strong>tion (OE) 4<br />

Elemental chlorine-free ble<strong>ac</strong>hing 3<br />

Double disk refiners 50% <strong>of</strong> <strong>th</strong>e mills<br />

Twin wire m<strong>ac</strong>hines 5<br />

Free flowing falling film evaporators 3<br />

Long tube vertical type evaporators most integrated mills have LTV<br />

evaporators<br />

High pressure boilers (40-60 kg/cm) 5<br />

Electrostatic precipitator 70% <strong>of</strong> <strong>th</strong>e integrated mills<br />

Lime sludge reburning 5<br />

<strong>Full</strong> fledged effluent treatment system 80-90% <strong>of</strong> <strong>th</strong>e integrated mills and some<br />

selected medium and small-sized mills<br />

Despite <strong>th</strong>e changes occurring wi<strong>th</strong> regards to environmental consciousness, public concerns and<br />

customer preferences in <strong>th</strong>e country, <strong>th</strong>e pulp and paper industry is still in a difficult position to<br />

impose total environmental management and undergo environmental control modifications in <strong>th</strong>e<br />

f<strong>ac</strong>ilities. Never<strong>th</strong>eless, some new trends are currently being realized in a number <strong>of</strong> paper mills in<br />

<strong>th</strong>e country in order to combat environmental problems (see Table 6.2.12).


100 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

6.3 COUNTRY REPORT: PHILIPPINES<br />

6.3.1 Introduction<br />

All industrial processes generate waste. Since no production system can transform all input<br />

resources completely into end-products, waste generation is inevitable. Problems arise when <strong>th</strong>ese<br />

wastes are discharged in excess <strong>of</strong> what <strong>th</strong>e environment can absorb.<br />

The industrial sector which <strong>ac</strong>counts for a large share in <strong>th</strong>e country’s energy consumption, is also<br />

a major source <strong>of</strong> environmental pollution. Industrial pollution has earlier been considered a local<br />

problem but is today recognized as regional as well as global. Common sources <strong>of</strong> industrial<br />

pollution are <strong>th</strong>e waste water used in <strong>th</strong>e manuf<strong>ac</strong>turing process and <strong>th</strong>e emissions from<br />

combustion <strong>of</strong> fossil fuel. There is a wide array <strong>of</strong> technically feasible abatement measures ranging<br />

from efficiency improvement in <strong>th</strong>e process to <strong>th</strong>e more common and usually more expensive end<strong>of</strong>-pipe<br />

pollution abatement technologies.<br />

The pulp and paper industry is one <strong>of</strong> <strong>th</strong>e industrial sector’s high energy consumers and major<br />

contributors in pollution. Attention to <strong>th</strong>e pulp and paper industry, <strong>th</strong>erefore, deserves a high<br />

priority. This section looks into <strong>th</strong>e technological status <strong>of</strong> <strong>th</strong>e pulp and paper industry <strong>of</strong> <strong>th</strong>e<br />

Philippines wi<strong>th</strong> regards to energy efficiency and environmental soundness. Through <strong>th</strong>e historical<br />

and present techno-economic data <strong>of</strong> <strong>th</strong>e industry, <strong>th</strong>e potential for improving <strong>th</strong>e current status <strong>of</strong><br />

technologies for energy and environmental management is analyzed.<br />

6.3.2 Technological trajectory <strong>of</strong> <strong>th</strong>e paper industry in <strong>th</strong>e Philippines<br />

6.3.2.1 Structure <strong>of</strong> <strong>th</strong>e paper industry<br />

Pulp and paper production in <strong>th</strong>e Philippines was pioneered by Compania de Cellulosa de Filipinas<br />

when it established an integrated pulp and paper mill in 1948 in Bais, Negros Occidental. The mill<br />

which produced 10 tons <strong>of</strong> bond paper per day using bagasse as raw material is still in operating<br />

condition. Ano<strong>th</strong>er pioneer in <strong>th</strong>e paper industry was established in 1950 in Metro Manila to<br />

operate a second-hand board m<strong>ac</strong>hine. This m<strong>ac</strong>hine is still operational and currently produces<br />

chipboard.<br />

A number <strong>of</strong> paper mills were established during <strong>th</strong>e 1950s and <strong>th</strong>e early 1960s when <strong>th</strong>e industry<br />

had to contend wi<strong>th</strong> two sets <strong>of</strong> import duty levels - a lower rate for pulp and a higher rate for<br />

finished paper and brand products. This encouraged <strong>th</strong>e mills to utilize <strong>th</strong>e cheaper imported raw<br />

materials. In effect, plans to build pulping f<strong>ac</strong>ilities for most <strong>of</strong> <strong>th</strong>e mills never materialized.<br />

Several non-integrated paper mills were established during <strong>th</strong>e 1970s and 1980s but <strong>th</strong>ese were<br />

based mainly on imported and local recycled waste paper. The list <strong>of</strong> paper mills in <strong>th</strong>e country<br />

and <strong>th</strong>eir dates <strong>of</strong> establishment are shown in Annex 1.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 101<br />

From 1978 to 1991, paper production in <strong>th</strong>e Philippines remained flat. Consumption on one hand<br />

increased from 440,000 tons in 1978 to 753,000 tons in 1993 (Table 6.3.1). To meet increasing<br />

demand, <strong>th</strong>e country had to rely on imports. In contrast, production <strong>of</strong> paper and board in o<strong>th</strong>er<br />

ASEAN countries rose from 820,000 to 2,100,000 tons wi<strong>th</strong> marginal increase in net imports<br />

during <strong>th</strong>e same ten-year period.<br />

Despite <strong>th</strong>e problem <strong>of</strong> power shortages in <strong>th</strong>e last two years, <strong>th</strong>e industry managed to continue<br />

operations and, aided by resilient domestic market, was able to post moderate gains. Total<br />

production <strong>of</strong> <strong>th</strong>e country’s operating mills re<strong>ac</strong>hed 490,000 tons in 1992 and increased by 6% to<br />

518,000 tons in 1993.<br />

Table 6.3.1 Evolution <strong>of</strong> paper industry: total paper and paperboard (10 3 tons)<br />

Year Installed<br />

Cap<strong>ac</strong>ity<br />

Production Consumption Imports<br />

1987 439 319.5 475.0 200.8<br />

1988 506 341.0 493.9 193.0<br />

1989 564 345.0 554.6 216.4<br />

1990 579 325.0 481.6 205.3<br />

1991 579 392.0 626.0 245.2<br />

1992 635 489.0 743.1 279.5<br />

1993 650 517.5 753.1 279.5<br />

Source: Aragon, P.M., Country Focus.<br />

A. Production cap<strong>ac</strong>ity<br />

From a 1989 survey, <strong>th</strong>e industry coverage was 33 pulp and paper mills, wi<strong>th</strong> 4 integrated mills<br />

(shown in Table 6.3.2) and 5 pulp manuf<strong>ac</strong>turers (Table 6.3.3). The remaining 24 are nonintegrated<br />

paper mills. Exclusive <strong>of</strong> two non-operating mills, <strong>th</strong>e total production cap<strong>ac</strong>ity <strong>of</strong> <strong>th</strong>e<br />

integrated mills is 410,000 tons per annum.<br />

The total pulp cap<strong>ac</strong>ity <strong>of</strong> <strong>th</strong>e Philippines is about 289,000 tons per annum while aggregate paper<br />

cap<strong>ac</strong>ity is approximately 611,000 tons per year. In view <strong>of</strong> several closures, <strong>th</strong>e average annual<br />

operating cap<strong>ac</strong>ities for pulp and paper production are 223,000 tons and 526,000 tons, respectively<br />

(Table 6.3.4).<br />

The industry structure is very small compared to international standards. Of <strong>th</strong>e 28 paper mills,<br />

only 3 have a cap<strong>ac</strong>ity <strong>of</strong> over 50,000 tons per annum (Table 6.3.5). The average size <strong>of</strong> mills<br />

ranges from 10,000 to 15,000 tons per annum. The industry structure is also outmoded and as a<br />

result, suffers from leng<strong>th</strong>y m<strong>ac</strong>hine downtime due to difficulties in obtaining outdated<br />

repl<strong>ac</strong>ement parts.


102 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.3.2 Integrated pulp and paper mills in <strong>th</strong>e Philippines, 1989<br />

Company/Mill Pulp Paper<br />

Cap<strong>ac</strong>ity<br />

(10 3 Materials Cap<strong>ac</strong>ity<br />

t/year)<br />

(10 3 Main Grades<br />

t/year)<br />

PICOP 180 Mech, UKP, 150 Newsprint, Linerboard,<br />

BKP<br />

Corrugated Medium<br />

Central Azucarera 9 Bagasse 14 Printing<br />

United Pulp & Paper 16 Bagasse 31 S<strong>ac</strong>k Kraft, Corrug.<br />

Menzi Dev’t. Corp. 3 Ab<strong>ac</strong>a 7<br />

Medium, Linerboard<br />

Printing & Writing<br />

Table 6.3.3 Pulp mills in <strong>th</strong>e Philippines, 1989<br />

Company/Mill Cap<strong>ac</strong>ity (10 3 t/year) Materials<br />

Albay Agro-Ind’l. Dev’t. Corp. 1 Ab<strong>ac</strong>a<br />

Canlubang Pulp Mfg. Company 4.5 Ab<strong>ac</strong>a<br />

Cellophil Resources Corporation 66 Wood Pulp<br />

Isarog Pulp and Paper Co. 4.5 Ab<strong>ac</strong>a<br />

PICOP 5 Ab<strong>ac</strong>a<br />

Table 6.3.4 Total pulp and paper mill cap<strong>ac</strong>ities in <strong>th</strong>e Philippines, 1989<br />

Mill Categories Cap<strong>ac</strong>ity (10 3 t/year)<br />

Pulp Paper<br />

Integrated mills 208 202<br />

Pulp mills 81 -<br />

Paper mills - 409<br />

Total cap<strong>ac</strong>ities 289 611<br />

Operational cap<strong>ac</strong>ities 223 536<br />

Table 6.3.5 Philippine paper mills categorized by rated cap<strong>ac</strong>ity (t/year)<br />

Rated Cap<strong>ac</strong>ity Number <strong>of</strong> paper mills<br />

Below 10,000 10<br />

10,000 to 20,000 10<br />

20,000 to 50,000 5<br />

50,000 & above 3<br />

B. Paper m<strong>ac</strong>hines<br />

There are currently 45 paper m<strong>ac</strong>hines in <strong>th</strong>e country wi<strong>th</strong> a total cap<strong>ac</strong>ity <strong>of</strong> 540,000 tons per<br />

annum, or an average <strong>of</strong> 12,000 tons annually (Table 6.3.6).


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 103<br />

Table 6.3.6 Paper m<strong>ac</strong>hine structure in <strong>th</strong>e Philippines in terms <strong>of</strong> cap<strong>ac</strong>ity (10 3 t/year),<br />

trim wid<strong>th</strong> per cm, and start-up year<br />

PM cap<strong>ac</strong>ity Operating Total paper % Share<br />

m<strong>ac</strong>hines<br />

cap<strong>ac</strong>ity<br />

below 10 33 166 31.0<br />

10 - 19 7 102 19.0<br />

20 - 29 1 27 5.0<br />

30 - 39 1 31 5.8<br />

40 - 49 - - -<br />

50 - 59 - - -<br />

60 - 69 2 128 23.9<br />

over 69 1 82 15.3<br />

Total 45 536 100.0<br />

PM trim/cm<br />

below 201 22 132 24.6<br />

201 - 300 16 118 22.0<br />

301 - 400 5 144 26.9<br />

401 - 500 - - -<br />

501 - 600 1 60 11.2<br />

over 600 1 82 15.3<br />

Total 45 536 100.0<br />

Start-up Year<br />

before 1960 7 57 10.6<br />

1960s 19 132 24.6<br />

1970s 10 240 44.8<br />

1980s 9 107 20.0<br />

Total 45 536 100.0<br />

As can be seen in Table 6.3.6, only <strong>th</strong>ree <strong>of</strong> <strong>th</strong>e m<strong>ac</strong>hines operate at a minimum <strong>of</strong> 60,000 tons per<br />

year, representing less <strong>th</strong>an 40 percent <strong>of</strong> <strong>th</strong>e total industry cap<strong>ac</strong>ity. Most <strong>of</strong> <strong>th</strong>e m<strong>ac</strong>hines were<br />

bought second-hand and are very small bo<strong>th</strong> in terms <strong>of</strong> cap<strong>ac</strong>ity and wid<strong>th</strong>. Only two have a<br />

wid<strong>th</strong> greater <strong>th</strong>an 5 meters. The m<strong>ac</strong>hines are also very old. However, it is quite difficult to<br />

establish <strong>th</strong>e ex<strong>ac</strong>t age <strong>of</strong> <strong>th</strong>ese m<strong>ac</strong>hines because almost all have been bought second-hand.<br />

Twenty m<strong>ac</strong>hines have reportedly been installed during <strong>th</strong>e past 20 years.<br />

Of <strong>th</strong>e 45 operating m<strong>ac</strong>hines, 5 can easily absorb 50 percent <strong>of</strong> <strong>th</strong>e total annual production<br />

cap<strong>ac</strong>ity. In f<strong>ac</strong>t, <strong>th</strong>e 2 biggest m<strong>ac</strong>hines (wi<strong>th</strong> a trim exceeding 500 cm) have a combined cap<strong>ac</strong>ity<br />

constituting 26.5 percent <strong>of</strong> total. Essentially, <strong>th</strong>e country’s aggregate paper requirements may be<br />

supplied by only ten medium-sized (not necessarily modern) paper m<strong>ac</strong>hines. Table 6.3.7 presents<br />

<strong>th</strong>e status <strong>of</strong> <strong>th</strong>e country’s paper m<strong>ac</strong>hines in 1989, relative to <strong>th</strong>at <strong>of</strong> <strong>th</strong>e o<strong>th</strong>er ASEAN countries.


104 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.3.7 Total cap<strong>ac</strong>ities <strong>of</strong> paper m<strong>ac</strong>hines in ASEAN countries by mill cap<strong>ac</strong>ity,<br />

age, and wid<strong>th</strong>, 1989 (10 3 t/year)<br />

Distribution Indonesia Malaysia Philippines Singapore Thailand Total<br />

PM Cap<strong>ac</strong>ity<br />

below 20,000 455 136 294 42 330 1257<br />

21,000-40,000 464 - 103 77 161 805<br />

41,000-60,000 155 - 60 60 50 325<br />

61,000-80,000 285 130 72 - 220 707<br />

over 80,000 225 - 82 - 200 507<br />

Total 1584 266 611 179 961 3601<br />

# <strong>of</strong> m<strong>ac</strong>hines 90 27 52 13 78 260<br />

Average cap<strong>ac</strong>ity 17.6 9.9 11.8 13.8 12.3 13.9<br />

Start-up year<br />

before 1950s 375 82 160 38 116 771<br />

1950s 10 - 55 - 6 71<br />

1960s 156 13 111 1 162 443<br />

1970s 281 26 238 47 287 879<br />

1980s 762 145 47 93 390 1437<br />

Total 1584 266 611 179 961 3601<br />

Median age (yr.) 10 8 21 9 12 13<br />

Wire wid<strong>th</strong> (m)<br />

below 3 602 121 301 64 540 1628<br />

3 - 5 617 15 168 115 351 1266<br />

5 - 7 140 130 142 - 70 482<br />

over 7 225 - - - 225<br />

Total 1584 266 611 179 961 3601<br />

Median wid<strong>th</strong> (m) 3.35 3.80 3.06 3.46 2.25 3.02<br />

Local mills l<strong>ac</strong>k <strong>th</strong>e simplest instrumentation and process control systems. The speed <strong>of</strong> most<br />

m<strong>ac</strong>hines is quite slow and consumption <strong>of</strong> energy is high. They are also ill-equipped in terms <strong>of</strong><br />

environmental protection. Prolonged shutdowns have become common due to l<strong>ac</strong>k <strong>of</strong> spare parts<br />

and inadequate engineering/consulting companies. Safety standards are generally low and fatal<br />

<strong>ac</strong>cidents frequently occur.<br />

6.3.2.2 <strong>Technology</strong><br />

Standard manuf<strong>ac</strong>turing technology is being used in <strong>th</strong>e industry. Given <strong>th</strong>e papermaking<br />

equipment and f<strong>ac</strong>ilities available and <strong>th</strong>e flexible requirements <strong>of</strong> <strong>th</strong>e domestic market, <strong>th</strong>is is<br />

found to be adequate for <strong>th</strong>e industry. There appears to be an adequate supply <strong>of</strong> trained<br />

technicians and skilled personnel. Some big mills also engage foreign technicians as needed.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 105<br />

Based on <strong>th</strong>e study commissioned by <strong>th</strong>e Development Bank <strong>of</strong> <strong>th</strong>e Philippines (DBP) in 1992, it<br />

was observed <strong>th</strong>at <strong>th</strong>e technological framework <strong>of</strong> <strong>th</strong>e pulp and paper industry is essentially<br />

structured as follows:<br />

- Only 5 <strong>of</strong> <strong>th</strong>e country’s operating mills are integrated wi<strong>th</strong> pulp production, representing<br />

36% <strong>of</strong> total production cap<strong>ac</strong>ity.<br />

- The industry is heavily dependent on imported raw materials, particularly virgin pulp,<br />

waste paper, and papermaking chemicals.<br />

- Existing paper m<strong>ac</strong>hines are generally small and do not have economies <strong>of</strong> scale to<br />

compete wi<strong>th</strong> foreign products. Even <strong>th</strong>e 3 biggest m<strong>ac</strong>hines representing 40% <strong>of</strong> <strong>th</strong>e<br />

total production cap<strong>ac</strong>ity do not have <strong>th</strong>e economies <strong>of</strong> scale to be internationally<br />

competitive. Of <strong>th</strong>e 45 operating m<strong>ac</strong>hines, 40 have production cap<strong>ac</strong>ities below 20,000<br />

tons.<br />

- Most <strong>of</strong> <strong>th</strong>e paper m<strong>ac</strong>hines are old and obsolete. Many were bought second-hand and<br />

were already outmoded on start-up.<br />

- One reason for <strong>th</strong>e industry’s low operating efficiency is <strong>th</strong>e difficulty to find spare parts<br />

for <strong>th</strong>e outmoded m<strong>ac</strong>hines. Shutdowns due to l<strong>ac</strong>k <strong>of</strong> spare parts are common among<br />

local mills.<br />

- High energy consumption is also an effect <strong>of</strong> obsolete m<strong>ac</strong>hinery. Only a handful <strong>of</strong> <strong>th</strong>e<br />

local m<strong>ac</strong>hines have some sort <strong>of</strong> heat recovery system.<br />

- High energy costs, in turn, result in high production costs. To compare, a modern<br />

newsprint paper mill based on waste paper consumes about 900 to 1,000 kWh per ton,<br />

while a standard Philippine mill consumes 1,275 kWh per ton.<br />

- Modern integrated process control devices which are standard equipment for all m<strong>ac</strong>hines<br />

in Western countries are not available in Philippine mills. Local mills are basically<br />

equipped wi<strong>th</strong> conventional pneumatic instrumentation, only 3 m<strong>ac</strong>hines use<br />

computerized weight and moisture control systems, and a few operate wi<strong>th</strong>out any kind<br />

<strong>of</strong> instrumentation at all.<br />

- Most m<strong>ac</strong>hines operate at speeds below 500 m/min. The fastest newsprint m<strong>ac</strong>hine runs<br />

at 760 m/min, slower <strong>th</strong>an <strong>th</strong>e speed <strong>of</strong> modern m<strong>ac</strong>hines, which is 1,000 m/min.<br />

- Faulty process designs result from l<strong>ac</strong>k <strong>of</strong> engineering and technical expertise specific to<br />

<strong>th</strong>e pulp and paper sub-sector. Extra operation costs are <strong>th</strong>us incurred, fur<strong>th</strong>er<br />

aggravating <strong>th</strong>e low operating efficiency <strong>of</strong> <strong>th</strong>e industry.


106 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

- Safety standards in most mills are very low and fatal <strong>ac</strong>cidents frequently occur.<br />

Unprotected rotating parts, roll nips and pulpers are safety hazards in many mills.<br />

6.3.3 Evolution <strong>of</strong> energy efficiency in <strong>th</strong>e pulp and paper industry <strong>of</strong> <strong>th</strong>e Philippines<br />

6.3.3.1 Energy pr<strong>of</strong>ile<br />

The pulp and paper industry is an energy-intensive industry where energy consumption varies wi<strong>th</strong><br />

respect to <strong>th</strong>e manuf<strong>ac</strong>turing operations and processes involved. From 1984 to 1992, figures show<br />

an increasing trend in <strong>th</strong>e total consumption <strong>of</strong> energy for <strong>th</strong>e pulp and paper sector. (Figure<br />

6.3.1). Oil, non-oil and electricity consumption comprise 40%, 35% and 25%, respectively, <strong>of</strong> <strong>th</strong>e<br />

total energy consumption in <strong>th</strong>e industry.<br />

toe<br />

450000<br />

400000<br />

350000<br />

300000<br />

250000<br />

200000<br />

150000<br />

100000<br />

50000<br />

0<br />

1984 1985 1986 1987 1988 1989 1990 1991 1992<br />

Oil Non-oil Electricity Total Energy<br />

Figure 6.3.1 Historical energy consumption <strong>of</strong> <strong>th</strong>e pulp and paper sector in <strong>th</strong>e Philippines<br />

(koe, 1984 to 1992)<br />

The industry is also considered one <strong>of</strong> <strong>th</strong>e high fuel oil consuming sectors among <strong>th</strong>e Philippine<br />

industries wi<strong>th</strong> a share <strong>of</strong> 2.5% <strong>of</strong> <strong>th</strong>e total industrial fuel oil consumption. The pr<strong>of</strong>ile on energy<br />

use as is described below was based on six mills studied (Table 6.3.8 and Figure 6.3.2).<br />

A. Energy consumption<br />

Total annual energy consumption in six plants is 182,258 toe. This is broken down into 141,154<br />

toe (77%) bunker fuel and 284,64 toe (16%) electricity, and 12,640 toe (7%) for o<strong>th</strong>ers. The energy<br />

requirement is used mainly as heat for steam generation/process heating and as mechanical power<br />

to run <strong>th</strong>e plants’ electrical motors.<br />

Consumption <strong>of</strong> energy depends largely on <strong>th</strong>e type <strong>of</strong> m<strong>ac</strong>hine, its process design, operating<br />

efficiency, and production rate. Normally, smaller m<strong>ac</strong>hines consume less energy because <strong>th</strong>ey


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 107<br />

involve simpler processes wi<strong>th</strong> less automation. However, specific energy consumption is higher<br />

in smaller production units. As a result, energy utilization <strong>of</strong> local mills is 20 to 40% higher <strong>th</strong>an<br />

standard levels.<br />

B. Energy source mix<br />

The energy use pattern in <strong>th</strong>e six mills is based mainly on electricity and oil sources. One firm uses<br />

non-oil energy sources in <strong>th</strong>e form <strong>of</strong> waste wood and bl<strong>ac</strong>k liquor. More <strong>th</strong>an half <strong>of</strong> <strong>th</strong>e energy<br />

input in <strong>th</strong>e industry is used to generate steam for process heating. Supply <strong>of</strong> electricity differs<br />

among <strong>th</strong>e plants. Most companies utilize electricity which is entirely supplied from outside, while<br />

one company internally generates a small portion <strong>of</strong> its electricity requirements.<br />

Table 6.3.8 Annual energy consumption <strong>of</strong> six mills <strong>of</strong> <strong>th</strong>e Philippine paper industry<br />

Bunker Fuel Electricity O<strong>th</strong>ers Total<br />

Company 10 3 liters toe MWh toe GJ toe toe<br />

A 2224 2202 11197 955 3157<br />

B 20700 20500 45528 3884 24384<br />

C 1104 1093 1877 160 1253<br />

D 10490 10388 84530 7211 17599<br />

E 4056 4016 14853 1267 5283<br />

F 10971 102955 175680 14987 533398 12640 130582<br />

Total 142544 141154 333665 28464 533398 12640 182258<br />

77.45% 15.62% 6.93% 100.00%<br />

Average 23757 28231 55611 5693 36452<br />

Bunker<br />

Fuel<br />

77%<br />

Electricity<br />

16%<br />

O<strong>th</strong>ers<br />

7%<br />

Figure 6.3.2 Distribution <strong>of</strong> annual energy consumption <strong>of</strong> six Philippine paper mills<br />

C. Energy application<br />

About 72% <strong>of</strong> energy input goes for process heating. The use <strong>of</strong> electricity, mostly in electric<br />

motors, <strong>ac</strong>counts for 23%. O<strong>th</strong>er small applications such as materials handling and transportation,<br />

which utilizes petroleum products, <strong>ac</strong>count for 5% (Table 6.3.9).


108 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Table 6.3.9 Energy utilization pr<strong>of</strong>ile <strong>of</strong> 3 energy-intensive industries in <strong>th</strong>e Philippines<br />

Energy Applications (%) Paper<br />

Industry<br />

Cement (Dry) Steel/Metal<br />

Mechanical Power Drive 23% 24% 30.3%<br />

Process Heating 72% 74.5% 66.0%<br />

Transport/Handling 5% 0.5% 1.5%<br />

Lighting/Airconditioning<br />

1.0% 2.2%<br />

Total 100.00% 100.00% 100.00%<br />

D. Specific Energy Consumption<br />

On <strong>th</strong>e average, energy consumed in six mills in <strong>th</strong>e country is about 475.6 kgoe/t <strong>of</strong> paper<br />

produced. This ratio can be broken down into 364.5 kgoe (bunker fuel) per ton paper and 1,084<br />

kWh <strong>of</strong> electricity inputs per ton (Table 6.3.10).<br />

Table 6.3.10 Specific energy consumption <strong>of</strong> <strong>th</strong>e six paper mills in <strong>th</strong>e Philippines<br />

Company SFC in kgoe/t SELC in kWh/t SEC in kgoe/t<br />

A 310.9 1,580.0 445.6<br />

B 512.9 1,139.0 612.5<br />

C 239.2 410.8 274.3<br />

D 131.2 1,067.3 240.1<br />

E 306.5 1,133.5 403.2<br />

F 686.3 1,171.2 877.0<br />

Average 364.5 1,083.6 475.6<br />

E. Energy cost<br />

A previous survey revealed <strong>th</strong>at from 1983 to 1986, fuels purchased <strong>ac</strong>counted for 48% <strong>of</strong> <strong>th</strong>e total<br />

<strong>of</strong> <strong>th</strong>e sector, while electricity <strong>ac</strong>counted for 52% (Table 6.3.11). The average cost <strong>of</strong> fuels and<br />

electricity purchased during <strong>th</strong>e same period was P728,669 and P804,813, respectively. At present,<br />

<strong>th</strong>e cost <strong>of</strong> bunker fuel oil which is <strong>th</strong>e main source <strong>of</strong> energy for <strong>th</strong>e industry, ranges from P2.65<br />

to P2.99 per liter. Electricity cost varies between P1.275 to P2.86 per kWh.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 109<br />

Table 6.3.11 Historical energy cost data <strong>of</strong> <strong>th</strong>e Philippine paper industry (10 3 US$)<br />

Year Fuels Purchased Electricity Purchased Total<br />

1983 31937 25162 58377<br />

1984 50786 33440 86258<br />

1985 17614 28594 46913<br />

1986 16250 41574 58473<br />

Average 29147 32193 62505<br />

% <strong>of</strong> Total 48% 52% 100%<br />

Source: National Statistics Office, Annual Survey <strong>of</strong> Establishments<br />

6.3.4 Environmental externalities <strong>of</strong> <strong>th</strong>e pulp and paper industry <strong>of</strong> <strong>th</strong>e Philippines<br />

6.3.4.1 Environmental concerns<br />

The industry is heavily concentrated in Metro Manila wi<strong>th</strong> strong pressure to establish adequate<br />

pollution control measures. No mill can be expected to comply wi<strong>th</strong> <strong>th</strong>e required environmental<br />

protection standards due to <strong>th</strong>e high investment needed for proper pollution control measures.<br />

A. Water pollution<br />

The mills in <strong>th</strong>e Philippines are mostly old and obsolete wi<strong>th</strong> limited pollution control f<strong>ac</strong>ilities.<br />

The problem <strong>of</strong> pollution is more pronounced in <strong>th</strong>e Metro Manila area where most <strong>of</strong> <strong>th</strong>e mills<br />

are located. To worsen matters, Metro Manila has no common sewer system to ensure adequate<br />

waste water treatment. The main pollutants for <strong>th</strong>e pulp and paper industry are <strong>th</strong>e biological<br />

oxygen demand (BOD5) and <strong>th</strong>e total suspended solids (TSS).<br />

Water pollution in Metro Manila has become very alarming. Bo<strong>th</strong> <strong>th</strong>e industrial sector and private<br />

individuals are guilty <strong>of</strong> contributing to <strong>th</strong>e city’s pollution problem. The huge influx <strong>of</strong> people<br />

from <strong>th</strong>e provinces who do not have adequate sanitary f<strong>ac</strong>ilities aggravates <strong>th</strong>e situation.<br />

Meanwhile, most <strong>of</strong> <strong>th</strong>e old paper mills only have filters for fiber recovery.<br />

Effluent water standards in <strong>th</strong>e Philippines are set as ambient combinations. In contrast, o<strong>th</strong>er<br />

pulp and paper producing countries base <strong>th</strong>eir standards on <strong>th</strong>e kilogram <strong>of</strong> pollutant discharged<br />

per ton <strong>of</strong> pulp and paper produced. There is no point, <strong>th</strong>erefore, in comparing <strong>th</strong>e two standards.<br />

The ambient water concentration applied in <strong>th</strong>e Philippines is, however, close to <strong>th</strong>e standard set in<br />

developed countries, particularly in <strong>th</strong>e USA.<br />

B. In-plant measures and external effluent water treatment<br />

Aside from minimized water consumption, recovery <strong>of</strong> fiber, energy and chemicals is equally<br />

important for paper mills. The most common measures to effect <strong>th</strong>is include <strong>th</strong>e following:


110 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

- collection and recirculation <strong>of</strong> clean, cool water<br />

- installation <strong>of</strong> a v<strong>ac</strong>uum sealing water system equipped wi<strong>th</strong> its own cooling tower and<br />

cooling water recirculation system<br />

- minimized flow <strong>of</strong> fresh water shower<br />

- use <strong>of</strong> mechanical seals to minimize sealing water consumption <strong>of</strong> pumps, agitators, and<br />

refiners<br />

- sufficient white water storage to equalize water flow and make operations more stable<br />

- use <strong>of</strong> effective fiber filters (fiber save all) or o<strong>th</strong>er equally effective recovery equipment<br />

to minimize fiber content in white water overflow<br />

The introduction <strong>of</strong> <strong>th</strong>e above measures is expected to enable paper mills in areas wi<strong>th</strong> insufficient<br />

fresh water supply to fur<strong>th</strong>er reduce water consumption to 10 m 3 per ton. In <strong>th</strong>e Philippines,<br />

average water consumption is higher, at 30 m 3 per ton. This is because most <strong>of</strong> <strong>th</strong>e mills are old<br />

and small, and it is very expensive to undertake a total rebuild. Also, waste paper is used as furnish<br />

in many mills and fresh water consumption is vital in <strong>th</strong>e operation <strong>of</strong> <strong>th</strong>ese mills to ensure better<br />

quality <strong>of</strong> paper produced.<br />

In-plant measures alone cannot adequately control <strong>th</strong>e presence <strong>of</strong> effluents and pollutants in<br />

water. It is necessary to undertake fur<strong>th</strong>er treatment <strong>of</strong> effluents before final discharge is made.<br />

Before discharge, effluents must first be externally treated. A primary clarifier can reduce TSS by<br />

as much as 70 to 95 percent but BOD can only be reduced marginally by <strong>th</strong>is me<strong>th</strong>od. A<br />

secondary treatment in an aerated lagoon or an <strong>ac</strong>tivated sludge plant is necessary to shrink BOD<br />

by about 50 to 90 percent TSS can be minimized fur<strong>th</strong>er by a secondary clarifier.<br />

Primary treatment should be compulsory for all pulp and paper mills starting from 1994.<br />

Secondary treatment including sludge handling should be obligated by <strong>th</strong>e year 2000 or earlier.<br />

Also, new paper mills are encouraged to be built outside Metro Manila.<br />

A 1992 DBP study showed <strong>th</strong>at environmental protection cost for <strong>th</strong>e projected paper cap<strong>ac</strong>ity in<br />

<strong>th</strong>e year 2000 is estimated to be about US$ 70 million. This includes in-plant measures, primary<br />

and secondary treatment, and sludge handling. Project financing could come from grants and<br />

long-term loans sourced from international financing institutions. The total investment for<br />

installing environmental control measures for <strong>th</strong>e five mills in 1992 is summarized in Table 6.3.12.<br />

C. Emissions to <strong>th</strong>e atmosphere<br />

Pr<strong>ac</strong>tically all paper mills in <strong>th</strong>e country have power boilers using Bunker C oil as fuel. Only one<br />

mill has a recovery boiler. The power boilers in most paper mills are generally small and mediumsized.<br />

When oil is burned, particulate matter and sulfur compounds are formed. The amount <strong>of</strong><br />

sulfur compound depends on <strong>th</strong>e amount <strong>of</strong> sulfur in oil.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 111<br />

Table 6.3.12 Investment for environmental control measures in 5 paper mills (10 3 US $)<br />

Case In-plant Primary Secondary Sludge Total<br />

measures treatment treatment handling<br />

A 190 1650 6100 1590 9530<br />

B 100 710 2210 860 3880<br />

C 85 370 860 760 2075<br />

D 100 660 1940 910 3610<br />

E 80 280 590 730 1680<br />

Reducing sulfuric emission may be realistically effected by <strong>th</strong>e use <strong>of</strong> sulfur-free fuel or fuel wi<strong>th</strong><br />

low sulfuric content and, treatment <strong>of</strong> flue gas after combustion. Using oil wi<strong>th</strong> low sulfur content<br />

is very effective in regulating sulfuric emissions. This kind <strong>of</strong> oil, however, is more expensive <strong>th</strong>an<br />

<strong>th</strong>e normal heavy oil. Electrostatic precipitators and scrubbers used for external treatment <strong>of</strong> flue<br />

gas are likewise effective but expensive. Particulate matter is pr<strong>ac</strong>tically eliminated (99 percent)<br />

wi<strong>th</strong> <strong>th</strong>e application <strong>of</strong> <strong>th</strong>e electrostatic precipitator. To reduce <strong>th</strong>e sulfuric compounds H 2S and<br />

SO 2, it is necessary to wash <strong>th</strong>e gases in scrubbers. This process reduces sulfur emission by as<br />

much as 90 to 95 percent.<br />

6.3.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough<br />

technological changes<br />

6.3.5.1 Energy conservation opportunities<br />

The following are <strong>th</strong>e general observations and identified technologies wi<strong>th</strong> potentials for<br />

conserving energy for <strong>th</strong>e industry on <strong>th</strong>e basis <strong>of</strong> previous sectoral studies, surveys and energy<br />

audits conducted in <strong>th</strong>e pulp and paper industry.<br />

- Combustion tests conducted during recent energy audits showed <strong>th</strong>at majority <strong>of</strong> boilers<br />

were operating well wi<strong>th</strong>in or near <strong>th</strong>e optimum operating condition wi<strong>th</strong> boiler<br />

efficiencies varying from 72.4% to 87.7%.<br />

Four <strong>of</strong> <strong>th</strong>e six companies surveyed, have, in one time or ano<strong>th</strong>er, purchased and used a<br />

portable or on-line flue gas analyzer to monitor <strong>th</strong>e combustion performance <strong>of</strong> <strong>th</strong>eir<br />

boilers and adjust/fine tune <strong>th</strong>e air-fuel ratio. Of <strong>th</strong>ese four companies, only two have a<br />

functioning flue gas analyzer, one portable and one on-line. In <strong>th</strong>e o<strong>th</strong>er two companies,<br />

<strong>th</strong>e analyzers had not been operational for quite some time due to exhausted oxygen<br />

absorbent/cell. Most <strong>of</strong> <strong>th</strong>e companies get a free boiler efficiency testing from <strong>th</strong>e<br />

bunker fuel and/or fuel additive supplier on a mon<strong>th</strong>ly basis, while one company never<br />

had its boiler tested.<br />

- Boiler feedwater treatment is generally adequate, except in at least 3 companies where<br />

about 1/8 inch <strong>th</strong>ick scale was found inside <strong>th</strong>e boiler tubes during descaling.


112 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

- Fuel oil metering is usually done via day tank level monitoring. Only half <strong>of</strong> <strong>th</strong>e<br />

companies surveyed are maintaining boiler operation logsheets.<br />

- Condensate recovered from <strong>th</strong>e paper m<strong>ac</strong>hines and returned b<strong>ac</strong>k to <strong>th</strong>e boiler house<br />

varied from as low as 30% to as high as 85%.<br />

- Leaks were <strong>of</strong>ten noted on <strong>th</strong>e steam and condensate lines. Steam and condensate lines<br />

were also commonly observed to be inadequately insulated in most <strong>of</strong> <strong>th</strong>e plants visited.<br />

Insulation usually consists <strong>of</strong> wool blanket or asbestos wi<strong>th</strong> aluminum cladding.<br />

- There is at least one opportunity to investigate <strong>th</strong>e feasibility <strong>of</strong> installing waste heat<br />

recovery system in <strong>th</strong>e form <strong>of</strong> economizer to recover heat from boiler flue gas and a heat<br />

exchanger to recover heat from boiler blowdown.<br />

- Historical data is not always available to show <strong>th</strong>e distribution <strong>of</strong> electrical energy to <strong>th</strong>e<br />

paper m<strong>ac</strong>hines and o<strong>th</strong>er consumers. Fur<strong>th</strong>ermore, <strong>th</strong>ere is <strong>of</strong>ten a l<strong>ac</strong>k <strong>of</strong> watt-hour<br />

sub-metering system for <strong>th</strong>e major process areas/equipment. Electrical power distribution<br />

in a paper mill goes mainly to <strong>th</strong>e paper m<strong>ac</strong>hine to provide motive power, <strong>th</strong>e balance<br />

goes to <strong>th</strong>e boiler house, lighting, air conditioning, <strong>of</strong>fice equipment and miscellaneous<br />

loads.<br />

- Natural lighting is effectively utilized in most <strong>of</strong> <strong>th</strong>e companies surveyed. However, most<br />

installed skylights need to be cleaned/repl<strong>ac</strong>ed. The installation/retr<strong>of</strong>itting <strong>of</strong> reflectors<br />

on existing fluorescent fixtures is uncommon in <strong>th</strong>e industry. The rapid start type ballasts<br />

are still commonly used. Indoor lighting is predominated by fluorescent fixtures. A<br />

typical fixture is surf<strong>ac</strong>e-mounted and consists <strong>of</strong> two 4-watt fluorescent tubes, wi<strong>th</strong>out<br />

reflectors or diffusers but only a casing for <strong>th</strong>e ballast.<br />

- Motor loads <strong>ac</strong>count for <strong>th</strong>e largest portion <strong>of</strong> <strong>th</strong>e total electrical load. This is an<br />

indication <strong>th</strong>at <strong>th</strong>ere are energy conservation opportunities in <strong>th</strong>e system.<br />

- The electrical power f<strong>ac</strong>tor <strong>of</strong> five plants ranged between 83.75% and 99.5%. In one<br />

plant, however, <strong>th</strong>e mon<strong>th</strong>ly metered power f<strong>ac</strong>tor <strong>of</strong> <strong>th</strong>e plant’s electrical system<br />

averages at a very low 72.58%. As a result <strong>of</strong> <strong>th</strong>is very low power f<strong>ac</strong>tor, a power f<strong>ac</strong>tor<br />

adjustment or penalty is added to <strong>th</strong>e electricity bill.<br />

- To ensure a reliable supply <strong>of</strong> electricity, at least two paper mills are seriously considering<br />

to install 12 to 20 MW cogeneration systems. Assuming <strong>th</strong>at 50% <strong>of</strong> <strong>th</strong>e industry will<br />

install cogeneration systems to be self-sufficient in its <strong>th</strong>ermal and electrical requirements,<br />

a considerable amount <strong>of</strong> savings in annual fuel consumption can be realized.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 113<br />

- Air intake in compressed air systems is <strong>of</strong>ten from <strong>th</strong>e same enclosed area/surroundings<br />

where <strong>th</strong>e compressors are located.<br />

- Pumps and refiners utilized by <strong>th</strong>e paper industry are quite inefficient. Pumps normally<br />

consume 25 to 35% <strong>of</strong> electrical energy, while refiners use up 15 to 25%. The low<br />

efficiency <strong>of</strong> <strong>th</strong>ese m<strong>ac</strong>hines may be attributed to design cap<strong>ac</strong>ity and <strong>ac</strong>tual process<br />

requirements. O<strong>th</strong>er f<strong>ac</strong>tors which significantly influence power consumption and<br />

refining results are <strong>th</strong>e types <strong>of</strong> refiner, plate pattern, and speed.<br />

- Paper drying consumes <strong>th</strong>e biggest share <strong>of</strong> <strong>th</strong>e process steam. An increase <strong>of</strong> about 2 to<br />

35% <strong>of</strong> paper web dryness after press may be <strong>ac</strong>hieved if a typical press part is improved.<br />

This alone would reduce steam consumption <strong>of</strong> paper drying by 8 to 12%. It could also<br />

improve <strong>th</strong>e m<strong>ac</strong>hine’s efficiency.<br />

6.3.5.2 Energy conservation program<br />

Majority <strong>of</strong> <strong>th</strong>e companies in <strong>th</strong>e industry do not have formal energy conservation committee at<br />

present. Some used to be very <strong>ac</strong>tive in energy conservation earlier and have, in <strong>th</strong>e past,<br />

implemented a number <strong>of</strong> energy conservation measures or are still carrying out energy<br />

conservation <strong>ac</strong>tivities but in a much less aggressive manner.<br />

6.3.6 Status <strong>of</strong> application <strong>of</strong> new technologies<br />

In spite <strong>th</strong>e opportunities for energy conservation in <strong>th</strong>e industry, <strong>th</strong>ere are barriers to <strong>th</strong>eir<br />

effective implementation. These include technical, financial, institutional and o<strong>th</strong>er related issues as<br />

perceived by <strong>th</strong>e industry.<br />

The technical barriers in <strong>th</strong>e implementation <strong>of</strong> energy conservation technologies are mostly due to<br />

existing plant layout, support f<strong>ac</strong>ilities and services <strong>of</strong>fered by suppliers. For waste fuel utilization<br />

and coal conversion, problems on pollution, safety, and effects on quality <strong>of</strong> products were noted.<br />

These barriers include <strong>th</strong>e l<strong>ac</strong>k <strong>of</strong> information on reliable suppliers and services <strong>of</strong>fered, l<strong>ac</strong>k <strong>of</strong><br />

expertise regarding operation, maintenance and servicing <strong>of</strong> equipment/system, and o<strong>th</strong>er<br />

operation-related problems.<br />

The financial/economic viability <strong>of</strong> energy conservation technologies is a major concern <strong>of</strong> every<br />

industry, and <strong>th</strong>e most common financial barriers include <strong>th</strong>e unavailability <strong>of</strong> funds for energy<br />

conservation projects and <strong>th</strong>e l<strong>ac</strong>k <strong>of</strong> skill, bo<strong>th</strong> <strong>of</strong> plant personnel and financial institution<br />

personnel, in <strong>th</strong>e p<strong>ac</strong>kaging and evaluation <strong>of</strong> energy conservation projects.<br />

There is also a need to enhance <strong>th</strong>e existing institutional framework <strong>th</strong>at promotes and encourages<br />

energy conservation. A more aggressive information/dissemination campaign should be<br />

emphasized to encourage <strong>th</strong>e industry to pr<strong>ac</strong>tice energy conservation.


114 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

6.3.7 Concluding remarks<br />

The pulp and paper industry in <strong>th</strong>e Philippines has been described as small, outmoded, and highly<br />

protected. It is generally inefficient and internationally non-competitive, wi<strong>th</strong> bleak long-term<br />

prospects. Most <strong>of</strong> <strong>th</strong>e m<strong>ac</strong>hines in <strong>th</strong>e pulp and paper sector are old and repl<strong>ac</strong>eable. It is<br />

believed <strong>th</strong>at 10 reasonably-sized paper m<strong>ac</strong>hines can easily produce 600,000 to 700,000 tons <strong>of</strong><br />

<strong>th</strong>e required one million tons projected for <strong>th</strong>e year 2000. Operating fewer but bigger units will<br />

take advantage <strong>of</strong> economies <strong>of</strong> scale and benefit from modern process technologies.<br />

In <strong>th</strong>e f<strong>ac</strong>e <strong>of</strong> existing conditions, expansion is not recommended for <strong>th</strong>e local industry. The<br />

increasing pressure to install environmental protection f<strong>ac</strong>ilities in all mills and <strong>th</strong>e required<br />

dislocation <strong>of</strong> plants outside <strong>th</strong>e densely populated metropolis likewise demand a major structural<br />

change. Millers are, <strong>th</strong>erefore, encouraged to relocate outside <strong>th</strong>e densely populated metropolis<br />

wi<strong>th</strong> <strong>th</strong>e high cost <strong>of</strong> environmental protection necessitating relocation in areas which are less<br />

populated.<br />

Since <strong>th</strong>e industry has not yet re<strong>ac</strong>hed <strong>th</strong>e ultimate limits <strong>of</strong> resource-use efficiency, reducing waste<br />

generation should be high on <strong>th</strong>e industry’s agenda, not only because <strong>of</strong> concern for <strong>th</strong>e<br />

environment, but for <strong>th</strong>e more fundamental reason <strong>of</strong> improving pr<strong>of</strong>itability. After all, whatever<br />

<strong>th</strong>e industry discharges as waste are essentially <strong>th</strong>e very resources it buys and pays for in <strong>th</strong>e first<br />

pl<strong>ac</strong>e. No<strong>th</strong>ing comes free. Yet in <strong>th</strong>e past, waste reduction never received <strong>th</strong>e priority it deserved.<br />

It is important, <strong>th</strong>erefore, to reflect and analyze why.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 115<br />

6.4 COUNTRY REPORT: SRI LANKA<br />

6.4.1 Introduction<br />

The current gross domestic product <strong>of</strong> Sri Lanka is estimated to be increasing at 6.9%. Manuf<strong>ac</strong>turing,<br />

wholesale and retail trade and agriculture are <strong>th</strong>e most important contributory sectors to <strong>th</strong>e grow<strong>th</strong>.<br />

In 1993, <strong>th</strong>e GDP at current market price was estimated to be Rs. 150.8 billion, wi<strong>th</strong> agriculture,<br />

forestry and fishing contributing 21.2% share <strong>of</strong> <strong>th</strong>e GNP, mining and quarrying 2.5%, manuf<strong>ac</strong>turing<br />

19.4%, wholesale and retail trade 21.8% and construction 7%.<br />

The population <strong>of</strong> Sri Lanka in 1993 has been estimated at 17.62 million. The per capita GNP at<br />

current f<strong>ac</strong>tor cost prices is estimated at US$ 526 in 93, an increase <strong>of</strong> 16.5% over previous year.<br />

Pulp and paper industry in Sri Lanka was introduced in <strong>th</strong>e 1950’s by <strong>th</strong>e state and was managed by<br />

<strong>th</strong>e state until very recently. The m<strong>ac</strong>hinery and <strong>th</strong>e technologies are generally old. Though it has been<br />

realised <strong>th</strong>at improvements in energy efficiency and environmental standards are very desirable, <strong>th</strong>e<br />

l<strong>ac</strong>k <strong>of</strong> finances has impeded <strong>th</strong>is development.<br />

6.4.2 Technological trajectory <strong>of</strong> <strong>th</strong>e Sri Lankan pulp and paper industry<br />

6.4.2.1 Cap<strong>ac</strong>ity, production, raw material and process mix<br />

There are two paper mills in Sri Lanka. The pulp manuf<strong>ac</strong>turing techniques <strong>of</strong> <strong>th</strong>ese mills are soda<br />

pulping and neutral sulfite semi-chemical processes. Bo<strong>th</strong> <strong>th</strong>ese plants are designed to use straw as <strong>th</strong>e<br />

raw material. Figure 6.4.1 shows <strong>th</strong>e pulp production and Figure 6.4.2 shows <strong>th</strong>e raw material mix for<br />

pulp production. The second plant was commissioned in <strong>th</strong>e late seventies <strong>th</strong>us increasing <strong>th</strong>e total<br />

installed cap<strong>ac</strong>ities. However, as sections <strong>of</strong> <strong>th</strong>e older plants become unavailable for production, <strong>th</strong>e<br />

total installed cap<strong>ac</strong>ity gradually decreased. This is reflected in Figure 6.4.1.<br />

The extent <strong>of</strong> production <strong>of</strong> pulp from rice straw gradually decreased due to <strong>th</strong>e environmental effect<br />

<strong>of</strong> discharges from <strong>th</strong>is process. To make up for <strong>th</strong>ese losses, <strong>th</strong>e production from waste paper<br />

increased proportionately. The productivity reported is shown in Table 6.4.1.<br />

Table 6.4.1 Reported productivity in Sri Lankan pulp and paper industry<br />

Year Productivity (ton/employee)<br />

1960 7.7<br />

1980 5.4<br />

1990 6.2<br />

1992 9.2<br />

The shortfall between <strong>th</strong>e demand for pulp and local production were met by gradual increase <strong>of</strong><br />

imported pulp from large pulp manuf<strong>ac</strong>turers, as <strong>th</strong>ese became economically attr<strong>ac</strong>tive.


116 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Pulp Production<br />

14000<br />

12000<br />

10000<br />

8000<br />

6000<br />

4000<br />

2000<br />

0<br />

1970 1980 1990 1992<br />

Year<br />

Installed Cap<strong>ac</strong>ity From Straw & Wood From Waste Paper<br />

Figure 6.4.1 Sri Lanka’s pulp production cap<strong>ac</strong>ity by source (tons)<br />

Raw material<br />

35000<br />

30000<br />

25000<br />

20000<br />

15000<br />

10000<br />

5000<br />

0<br />

1970 1980 1990 1992<br />

Year<br />

Wood Straw<br />

Figure 6.4.2 Raw material mix for pulp production (tons)<br />

6.4.2.2 Role <strong>of</strong> <strong>th</strong>e pulp and paper industry in <strong>th</strong>e national economy<br />

Paper is a direct input to o<strong>th</strong>er economic <strong>ac</strong>tivities like printing and service sectors and remains very<br />

important in Sri Lankan economy al<strong>th</strong>ough its relative importance in terms <strong>of</strong> production is not very<br />

significant. The contribution <strong>of</strong> <strong>th</strong>e pulp and paper industry to <strong>th</strong>e Sri Lankan national economy is


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 117<br />

demonstrated by its high value added and employment and pr<strong>of</strong>itability ratios. The percentage <strong>of</strong><br />

value added to GDP and <strong>th</strong>e value <strong>of</strong> output has been increasing over <strong>th</strong>e years. Table 6.4.2 shows<br />

some key economic indicators <strong>of</strong> <strong>th</strong>e sector.<br />

Table 6.4.2 Economic indicators <strong>of</strong> <strong>th</strong>e pulp and paper industry<br />

Year 1985 1993<br />

Value Added to GDP (Million<br />

Rs.)<br />

200.235 416.347<br />

No. <strong>of</strong> Direct Employees<br />

Sector employment as a ratio <strong>of</strong>:<br />

3953 3167<br />

Industrial Employment 1.26% 0.4%<br />

Total Employment 0.08% 0.06%<br />

Direct employment in <strong>th</strong>e pulp and paper sector declined by about 19% between <strong>th</strong>e years 1985 and<br />

1993. This was caused mainly by <strong>th</strong>e closure <strong>of</strong> <strong>th</strong>e Val<strong>ac</strong>hchenai plant owing to terrorism in <strong>th</strong>e<br />

Eastern part <strong>of</strong> Sri Lanka since 1985.<br />

6.4.3 Evolution <strong>of</strong> energy efficiency in <strong>th</strong>e pulp and paper industry <strong>of</strong> Sri Lanka<br />

Figure 6.4.3 shows <strong>th</strong>e specific energy consumption <strong>of</strong> <strong>th</strong>e two processes. These f<strong>ac</strong>tories have been<br />

operating on varying raw material and technological mixes over <strong>th</strong>e years. Whenever imported pulp or<br />

waste paper was cheaper, <strong>th</strong>e imported component increased substantially. Thus over <strong>th</strong>e years, <strong>th</strong>ese<br />

plants have been operating wi<strong>th</strong> varying degrees <strong>of</strong> integration, giving non-consistent values for<br />

specific energy consumption.<br />

6.4.4 Environmental externalities in <strong>th</strong>e pulp and paper industry <strong>of</strong> Sri Lanka<br />

The paper mill which was commissioned in <strong>th</strong>e 1950's, does not have a chemical recovery plant and<br />

<strong>th</strong>e bl<strong>ac</strong>k liquor was directly discharged into a natural water stream. This has caused a severe<br />

environmental problem in <strong>th</strong>e area. The stream became dead due to oxygen depletion and <strong>th</strong>e<br />

deposition <strong>of</strong> fibrous material along <strong>th</strong>e banks. The lagoon which receives <strong>th</strong>e water stream which was<br />

rich in prawns and o<strong>th</strong>er varieties <strong>of</strong> fish also became dead. This has led to some serious social<br />

problems in <strong>th</strong>e fishing villages <strong>of</strong> <strong>th</strong>e area.


118 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Specific Energy Consumption<br />

0.9<br />

0.8<br />

0.7<br />

0.6<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0<br />

1980 1990<br />

Year<br />

1992<br />

Soda Pulping Sulfite Process<br />

Figure 6.4.3 Specific energy consumption for soda and sulfite pulping processes<br />

(toe/t <strong>of</strong> pulp)<br />

In <strong>th</strong>e eighties <strong>th</strong>e use <strong>of</strong> straw as raw material was reduced and recycling <strong>of</strong> waste paper was increased<br />

in <strong>th</strong>is f<strong>ac</strong>tory. In <strong>th</strong>e early 90s, pulp production from straw was completely stopped. Since <strong>th</strong>en <strong>th</strong>e<br />

environmental issue <strong>of</strong> discharging effluent into <strong>th</strong>e lagoon has been satisf<strong>ac</strong>torily resolved.<br />

The second plant which was commissioned in <strong>th</strong>e 1970's was equipped wi<strong>th</strong> a chemical recovery<br />

plant. Unfortunately <strong>th</strong>is plant has never been commissioned due to <strong>th</strong>e high silica content in <strong>th</strong>e<br />

bl<strong>ac</strong>k liquor.<br />

Since <strong>th</strong>e inception <strong>of</strong> <strong>th</strong>e plant <strong>th</strong>e effluents from <strong>th</strong>e mill have been discharged into a main river. As<br />

<strong>th</strong>e effluents are discharged wi<strong>th</strong>out chemical recovery, <strong>th</strong>e pollution caused to <strong>th</strong>e river is appreciable.<br />

The users <strong>of</strong> <strong>th</strong>e river water are agitating for remedial <strong>ac</strong>tion.<br />

6.4.5 Potential for energy efficiency improvement and pollution abatement <strong>th</strong>rough<br />

technological changes<br />

The following options may be examined to resolve <strong>th</strong>e high energy cost and <strong>th</strong>e environmental<br />

problems caused:<br />

(a) Change Raw Material<br />

- By changing <strong>th</strong>e raw material from rice straw to bagasse, <strong>th</strong>e silica problem in <strong>th</strong>e bl<strong>ac</strong>k<br />

liquor could be overcome. Wi<strong>th</strong> minor modification to <strong>th</strong>e chemical recovery plant,<br />

chemicals in <strong>th</strong>e effluent could be recovered. Adequate bagasse is available in <strong>th</strong>e locality.


Pr<strong>of</strong>ile <strong>of</strong> <strong>th</strong>e Pulp and Paper Industry in Selected <strong>Asian</strong> Countries 119<br />

- The use <strong>of</strong> wood as raw material for <strong>th</strong>e manuf<strong>ac</strong>ture <strong>of</strong> pulp will have similar advantages as<br />

above. The resources needed for growing <strong>of</strong> trees for <strong>th</strong>is purpose are available.<br />

(b) Change <strong>of</strong> Chemical<br />

By <strong>th</strong>e use <strong>of</strong> potassium hydroxide instead <strong>of</strong> sodium hydroxide for cooking <strong>of</strong> rice straw, <strong>th</strong>e effluent<br />

could be collected and marketed as potassium based fertilizer.<br />

(c) Change <strong>of</strong> Fuel<br />

As <strong>th</strong>e paper f<strong>ac</strong>tories are located in <strong>th</strong>e rice growing and processing areas, adequate quantities <strong>of</strong> rice<br />

husk is available to be used as fuel for <strong>th</strong>e production <strong>of</strong> steam for heat and electricity.


120 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

7. BIBLIOGRAPHY<br />

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ATV, 1991. Guidelines for Pulp and Paper Industry in Germany”, Volume 38, page 1684.<br />

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Mora, J.C., K.J. Dileep, and P. Bouix, 1988. “Energy and Pollution Abatement in Pulp and<br />

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Section 5<br />

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Section 6.1<br />

A. References<br />

[1] Alman<strong>ac</strong> <strong>of</strong> China’s Paper Industry, 1993, Edited by China Technical Association <strong>of</strong> Paper<br />

Industry (CTAPI).<br />

[2] Alman<strong>ac</strong> <strong>of</strong> China's Paper Industry 1990, Edited by China Technical Association <strong>of</strong> Paper<br />

Industry (CTAPI).<br />

[3] Alman<strong>ac</strong> <strong>of</strong> China's Paper Industry 1986, Edited by China Technical Association <strong>of</strong> Paper<br />

Industry (CTAPI).<br />

[4] Chen Yonghong, Energy Issues and Counter-measures for <strong>th</strong>e Paper Industry <strong>of</strong> China,<br />

Proceedings <strong>of</strong> <strong>th</strong>e Annual Academic Conference <strong>of</strong> CTAPI, 1985.<br />

[5] Chen Zhongxing, Cogeneration in Pulp and Paper Mills <strong>of</strong> China, COPED core project<br />

1993/1994.<br />

[6] China Energy Statistical Book 1991, China Statistic Press.<br />

[7] Environmental Imp<strong>ac</strong>ts <strong>of</strong> <strong>th</strong>e Technological Transformation Project in Qiqihar Pulp &<br />

Paper Mill, Planning and Designing <strong>Institute</strong> <strong>of</strong> Light Industry, 1993.<br />

[8] Fen Shiao and Chai Yinian, Estimation <strong>of</strong> <strong>th</strong>e Potential <strong>of</strong> Cogeneration (CHP) in China's<br />

Pulp & Paper Industry, Energy <strong>of</strong> China, July, 1993.<br />

[9] Integrated exploitation <strong>of</strong> steamed & boiled wastewater and its pollution protection<br />

technologies, Edited by Zhang Ke et al., China Light Industry Press, 1992.


126 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

[10] Li Jiawan, Current Situation <strong>of</strong> World Paper Industry in 1990s and Its Perspective, World<br />

Pulp & Paper Mills Data Book, 1992.<br />

[11] Statistical Yearbook <strong>of</strong> China, China Statistical Press, 1994.<br />

[12] Studies on Unit Major Products Energy Consumption, Edited by Liu Xueyi, Guanminri<br />

Daily Press, 1989.<br />

[13] Yu Yiji, Speed, Efficiency and Environmental Protection — Some Considerations on<br />

Sustainable Development <strong>of</strong> China's Pulp & Paper Industry, China Pulp & Paper, Dec.,<br />

1994.<br />

[14] Zhang Shuyu and Meng Zhaoli, Final Report on Energy Audit <strong>of</strong> Qiqihar Paper Mill,<br />

Technological Support Project for Industrial Energy Conservation, sponsored by ADB,<br />

1990.<br />

B. Bibliography<br />

Cao Pia<strong>of</strong>ang and Jiang Manxia, General Situations <strong>of</strong> China Paper Industry Pollution<br />

Protection, China Pulp & Paper, No. 5, Oct. 1994.<br />

Huanqinan et al. (eds.), Development Strategy <strong>of</strong> China’s Paper Industry, China Light Industry<br />

Press, 1992.<br />

ITEESA, Evaluation <strong>of</strong> Energy Efficiency in Pulp & Paper Industry in P.R. China, Invited<br />

Report, ITEESA.<br />

Pan Peilei, Call for Efforts to Contribute to Environmental Protection in Pulp & Paper Industry,<br />

China Pulp & Paper, Aug., 1994.<br />

Yan Erpin, Study on Heat Pump Drying <strong>Technology</strong> in Paper M<strong>ac</strong>hine Parts, China Pulp &<br />

Paper, December 1994.<br />

Zhang Houmin, Bio-technology and Pulp & Paper Industry, China Pulp & Paper, Aug. 1994.<br />

Section 6.2<br />

[1] Comprehensive industry document for large pulp & paper industry, CBCP Publication.<br />

[2] Comprehensive industry document for small pulp & paper industry, CBCP Publication.<br />

[3] CPPRI Database.


Bibliography 127<br />

[4] Development Council for Paper Pulp & Allied Products.<br />

[5] Environmental preservation course in pulp & paper industry, Markyd, Sweden.<br />

[6] Evaluation <strong>of</strong> energy efficiency in connection wi<strong>th</strong> technology - Report prepared by<br />

Central Pulp & Paper Research <strong>Institute</strong> (CPRRI) for National Productivity Council, 1985.<br />

[7] Indian Pulp & Paper Technical Association (IPPTA), vol.1, no.4, Dec. 1989.<br />

[8] IPPTA convention issue on energy conservation, 1984.<br />

[9] Paper Asia, July 1993.<br />

[10] Proceedings <strong>of</strong> inter<strong>ac</strong>tion meet on high rate bio-me<strong>th</strong>anation <strong>of</strong> pulp & paper mill waste<br />

(UNDP/GEF project).<br />

[11] Proceedings <strong>of</strong> <strong>th</strong>e inter<strong>ac</strong>tion meet on waste management in <strong>th</strong>e pulp & paper industry<br />

towards sustainable development - Central Pollution Control Board (CPCB).<br />

[12] Report prepared by CPPRI for <strong>th</strong>e 8<strong>th</strong> five year <strong>ac</strong>tion plan.<br />

[13] UNEP report on environmental management in pulp & paper industry.<br />

Section 6.3<br />

Aragon, P.M., “The Philippines: Promising Outlook”, Country Focus.<br />

Hargb<strong>ac</strong>k, H., “Environmental Management Plan: Pulp and Paper Industry”, A Report to <strong>th</strong>e<br />

Development Bank <strong>of</strong> <strong>th</strong>e Philippines, June 25, 1992.<br />

Dalusong II, A.R., “Energy Development in <strong>th</strong>e Light <strong>of</strong> Current Environmental Issues: The<br />

Philippine Case”, Energy Policy Implications <strong>of</strong> <strong>th</strong>e Climatic Effects <strong>of</strong> Fossil Fuel Use in <strong>th</strong>e<br />

Asia-P<strong>ac</strong>ific Region, Bangkok, Thailand. November, 1991.<br />

Nyati, K.P., “Prospect, Barriers and Strategies - Cleaner Industrial Production in Developing<br />

Countries”, pp. 10-14, Asia P<strong>ac</strong>ific Tech. Monitor, Nov-Dec 1994, ESCAP APCTT, New Delhi,<br />

India.<br />

Oy, J.P., “Industrial Restructuring Studies: Pulp and Paper”, Development Bank <strong>of</strong> <strong>th</strong>e<br />

Philippines, 1992.


128 <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e Pulp and Paper Industry<br />

Schafer, A. et al., “Inventory <strong>of</strong> Greenhouse Gas Mitigation Measures - Examples from <strong>th</strong>e<br />

IIASA <strong>Technology</strong> Data Bank”.


The <strong>Asian</strong> <strong>Institute</strong> <strong>of</strong> <strong>Technology</strong> (AIT) is an autonomous international <strong>ac</strong>ademic institution<br />

located in Bangkok, Thailand. It’s main mission is <strong>th</strong>e promotion <strong>of</strong> technological changes<br />

and <strong>th</strong>eir management for sustainable development in <strong>th</strong>e Asia-P<strong>ac</strong>ific region <strong>th</strong>rough highlevel<br />

education, research and outre<strong>ac</strong>h <strong>ac</strong>tivities which integrate technology, planning and<br />

management.<br />

AIT carried out <strong>th</strong>is <strong>Asian</strong> Regional Research Programme in Energy, Environment and Climate<br />

(ARRPEEC), wi<strong>th</strong> <strong>th</strong>e support <strong>of</strong> <strong>th</strong>e Swedish International Development Cooperation Agency (Sida).<br />

One <strong>of</strong> <strong>th</strong>e projects under <strong>th</strong>is program concerns <strong>th</strong>e Development <strong>of</strong> Energy Efficient<br />

and Environmentally Sound Industrial Technologies in Asia.<br />

The objective <strong>of</strong> <strong>th</strong>is specific project is to enhance <strong>th</strong>e synergy among selected developing<br />

countries in <strong>th</strong>eir efforts to adopt and propagate energy efficient and environmentally sound<br />

technologies. The industrial sub-sectors identified for in-dep<strong>th</strong> analysis are iron & steel,<br />

cement, and pulp & paper. The project involves <strong>ac</strong>tive participation <strong>of</strong> experts from<br />

collaborating institutes from four <strong>Asian</strong> countries, namely China, India, <strong>th</strong>e Philippines, and<br />

Sri Lanka.<br />

The technological trajectories, energy efficiency and environmental externalities <strong>of</strong> <strong>th</strong>e pulp<br />

and paper industry in <strong>th</strong>e four <strong>Asian</strong> countries are presented in <strong>th</strong>is document (Volume III).<br />

O<strong>th</strong>er related publications based on <strong>th</strong>is research finding include:<br />

Volume I <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e<br />

Cement Industry<br />

Volume II <strong>Technology</strong>, Energy Efficiency and Environmental Externalities in <strong>th</strong>e<br />

Iron & Steel Industry<br />

Volume IV Regulatory Measures and Technological Changes in <strong>th</strong>e Cement, Iron<br />

& Steel, and Pulp & Paper Industries<br />

An assessment <strong>of</strong> <strong>th</strong>e implementation <strong>of</strong> energy efficient and environmentally sound<br />

industrial technologies among <strong>th</strong>e selected countries is presented in a separate “Cross-<br />

Country Comparison” Report.<br />

ASIAN INSTITUTE<br />

OF TEC HN OLOGY<br />

19 5 9

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