Preliminary Results - EURL | Residues of Pesticides
Preliminary Results - EURL | Residues of Pesticides
Preliminary Results - EURL | Residues of Pesticides
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EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Potato<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
ORGANISING GROUP<br />
DG SANCO<br />
Mrs. Almut Bitterh<strong>of</strong><br />
Dr. Amadeo R. Fernández-Alba<br />
Dr. Milagros Mezcua<br />
Mr. Octavio Malato<br />
Mrs. Carmen Ferrer<br />
STATISTICAL GROUP<br />
Dr. Carmelo Rodríguez<br />
QUALITY CONTROL GROUP<br />
Dr. Antonio Valverde<br />
Mr. Stewart Reynolds<br />
EUPT-Panel<br />
ADVISORY GROUP<br />
<strong>EURL</strong>-FV<br />
Dr. André de Kok<br />
Dr. Sonja Masselter<br />
Dr. Tuija Pihlström<br />
Dr. Mette Erecius Poulsen<br />
Dr. Michelangelo Anastassiades<br />
Dr. Miguel Gamón<br />
Mr. Ralf Lippold<br />
Dr. Magnus Jezussek<br />
Dr. Darinka Stajnbaher
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
No. Of Labs<br />
Participation<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV<br />
Country No. <strong>of</strong> Labs Country No. <strong>of</strong> Labs Country No. <strong>of</strong> Labs<br />
Austria 3 (-1) Greece 10 Portugal 3<br />
Belgium 8 (+4) Hungary 4 Romania 3<br />
Brazil 1 (-1) Iceland 1 Saudi Arabia 1 New<br />
Bulgaria 2 (+1) India 1 Serbia 1<br />
China 2 New Ireland 1 Slovakia 2<br />
Cyprus 1 Israel 1 Slovenia 3<br />
Croatia 3 Italy 24 Spain 28 (+3)<br />
Czech Republic 3 (+1) Latvia 1 Sweden 2<br />
Denmark 2 Lithuania 1 Switzerland 3 (-1)<br />
Estonia 2 Luxembourg 2 (+1) The Netherlands 2<br />
Finland 2 Malta 2 (-1) Turkey 1<br />
France 10 (+1)<br />
Morocco 1 New United Kingdom 4<br />
Norway 1 Uruguay 1<br />
Germany 25 (+2) Poland 11 (+2)<br />
Total No. <strong>of</strong> Labs = 175<br />
Total No. <strong>of</strong> Third countries Labs = 13<br />
Total No. <strong>of</strong> Countries = 40
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Participation<br />
Total No. <strong>of</strong> Labs = 175<br />
Total No. <strong>of</strong> Third countries Labs = 13<br />
Total No. <strong>of</strong> Countries = 40<br />
<strong>EURL</strong>-FV<br />
(27 EU + 3 EFTA + 1 acceding country + 2 Candidate countries + 7 3 rd countries)
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
175 pesticides<br />
3-hydroxy-carb<strong>of</strong>uran<br />
Acephate<br />
Acetamiprid<br />
Acrinathrin<br />
Aldicarb<br />
Aldicarb Sulfone<br />
Aldicarb Sulfoxide<br />
Amitraz<br />
Azinphos-methyl<br />
Azoxystrobin<br />
Benfuracarb<br />
Bifenthrin<br />
Bitertanol<br />
Boscalid<br />
Bromopropylate<br />
Bromuconazole<br />
Bupirimate<br />
Bupr<strong>of</strong>ezin<br />
Cadusafos*<br />
Captan<br />
Carbaryl<br />
Carbendazim<br />
Carb<strong>of</strong>uran<br />
Carbosulfan<br />
Chlorfenapyr<br />
Chlorfenvinphos<br />
Chlorobenzilate*<br />
Chlorothalonil<br />
Chlorpropham<br />
Chlorpyrifos<br />
Chlorpyrifos-methyl<br />
Cl<strong>of</strong>entezine<br />
Clothianidin<br />
Cyfluthrin<br />
Cypermethrin<br />
Cyproconazole<br />
Cyprodinil<br />
Deltamethrin<br />
Demeton-S-methylsulfone<br />
Desmethyl-pirimicarb<br />
Diazinon<br />
Dichl<strong>of</strong>luanid<br />
Dichlorvos<br />
Dicloran<br />
Dic<strong>of</strong>ol<br />
Difenoconazole<br />
Diflubenzuron<br />
Dimethoate<br />
Dimethomorph<br />
DMST<br />
Diphenylamine<br />
DMF<br />
DMPF<br />
Endosulfan alpha<br />
Endosulfan beta<br />
Endosulfan sulfate<br />
EPN<br />
Epoxiconazole<br />
Ethion<br />
Ethoprophos<br />
Et<strong>of</strong>enprox<br />
Fenamiphos<br />
Fenamiphos sulfone<br />
Fenamiphos sulfoxide<br />
Fenarimol<br />
Fenazaquin<br />
Fenbuconazole<br />
Fenhexamid<br />
Fenitrothion<br />
Fenoxycarb<br />
Fenpropathrin<br />
Fenpropimorph<br />
Fenthion<br />
Fenthion oxon<br />
Fenthion oxon sulfone<br />
Fenthion oxon sulfoxide<br />
Fenthion sulfone<br />
Fenthion sulfoxide<br />
Fipronil<br />
Fludioxonil<br />
Flufenoxuron<br />
Fluopicolide*<br />
Fluquinconazole<br />
Flusilazole<br />
Flutolanil*<br />
Flutriafol<br />
Folpet<br />
Fosthiazate<br />
Hexaconazole<br />
Hexythiazox<br />
Imazalil<br />
Imidacloprid<br />
Indoxacarb<br />
Iprodione<br />
Iprovalicarb<br />
Is<strong>of</strong>enphos-methyl<br />
Kresoxim-methyl<br />
Lambda-Cyhalothrin<br />
Linuron<br />
Lufenuron<br />
Malaoxon<br />
Malathion<br />
Mepanipyrim<br />
Metaflumizone*<br />
Metalaxyl and metalaxyl-M<br />
Metconazole<br />
Methamidophos<br />
Methidathion<br />
Methiocarb<br />
Methiocarb sulfone<br />
Methiocarb sulfoxide<br />
Methomyl<br />
Methoxyfenozide<br />
Monocrotophos<br />
Myclobutanil<br />
Omethoate<br />
Orthophenylphenol<br />
Oxadixyl<br />
Oxamyl<br />
Oxydemeton-methyl<br />
Paclobutrazole<br />
Paraoxon-methyl<br />
Parathion-ethyl<br />
Parathion-methyl<br />
Penconazole<br />
Pencycuron<br />
Pendimethalin<br />
Phenthoate<br />
Phosalone<br />
Phosmet<br />
Spinosad<br />
Spirodicl<strong>of</strong>en<br />
Spiroxamine<br />
Tau-Fluvalinate<br />
Tebuconazole<br />
Tebufenozide<br />
Tebufenpyrad<br />
Teflubenzuron<br />
Tefluthrin<br />
Tetraconazole<br />
Tetradifon<br />
Thiabendazole<br />
Thiacloprid<br />
Thiamethoxam<br />
Thiodicarb<br />
<strong>EURL</strong>-FV<br />
Phosmet oxon<br />
Phoxim<br />
Pirimicarb<br />
Pirimiphos-methyl<br />
Prochloraz<br />
Procymidone<br />
Pr<strong>of</strong>en<strong>of</strong>os<br />
Propargite<br />
Propiconazole<br />
Propyzamide<br />
Prothioconazole<br />
Prothi<strong>of</strong>os<br />
Pyraclostrobin<br />
Pyridaben<br />
Pyrimethanil<br />
Pyriproxyfen<br />
Quinoxyfen<br />
Thiophanate-me<br />
Tolcl<strong>of</strong>os-methyl<br />
Tolylfluanid<br />
Triadimefon<br />
Triadimenol<br />
Triazophos<br />
Trichlorfon<br />
Trifloxystrobin<br />
Triflumuron<br />
Trifluralin<br />
Triticonazole<br />
Vinclozolin<br />
Zoxamide<br />
*Not in the coordinated<br />
multiannual control programme
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>Pesticides</strong> used for the<br />
treatment<br />
Acephate Linuron<br />
Azoxystrobin Methiocarb<br />
Chlorpropham Pencycuron<br />
Chlorothalonil Prochloraz<br />
Cypermethrin Procymidone<br />
Diazinon Spirodicl<strong>of</strong>en<br />
Fluopicolide* Thiabendazxole<br />
Flutolanil* Thiacloprid<br />
Fosthiazate<br />
Iprovalicarb<br />
Total: 18<br />
<strong>EURL</strong>-FV<br />
* Not in the<br />
coordinated<br />
multiannual control<br />
programme<br />
New in the target list<br />
* COMMISSION IMPLEMENTING REGULATION (EU)<br />
No 788/2012 <strong>of</strong> 31 August 2012<br />
concerning a coordinated multiannual control<br />
programme <strong>of</strong> the Union for 2013, 2014 and 2015 to<br />
ensure compliance with maximum residue levels <strong>of</strong><br />
pesticides and to assess the consumer exposure<br />
to pesticide residues in and on food <strong>of</strong> plant and<br />
animal origin .
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
CALENDAR<br />
ACTIVITY DATE<br />
<strong>EURL</strong>-FV<br />
- Publishing the Target Pesticide List, Calendar on the Web page 22nd October 2012<br />
- Receiving Application Form from invited laboratories. 3rd Dec 2012 - 7th Jan 2013<br />
- Specific Protocol published on the Web site 7th Jan 2013 at the latest<br />
- Filling in the Laboratory Scope from the Participants: Form 0 8th-18th January 2013<br />
- Sample distribution. 21st January 2013<br />
- Deadline for receiving sample acceptance: Form 1 25th January 2013<br />
- Deadline for receiving results: Form 2, Form 3 and Form 4 13th February 2013<br />
- Filling in Form 5 20th-27th February 2013<br />
- <strong>Preliminary</strong> Report: provisional results, medians and z-scores. April 2013<br />
- Final Report to the Laboratories December 2013
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
WEB PAGE: Forms<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Forms<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Organic Potatoes were grown in Almería, Spain<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Post harvest treatment with commercial<br />
formulation and with standard solution<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Pesticide<br />
Commercial products used to treat the sample<br />
Concentration<br />
(mg/kg)<br />
MRRL Type Commercial Product<br />
Acephate 1 0.01 Standard Sigma-Aldrich<br />
Chlorothalonil 0.1-0.5 0.01 Commercial Bravo 50<br />
Cypermethrin
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Pesticide<br />
Commercial products used to treat the sample<br />
Concentration<br />
(mg/kg)<br />
MRRL Type Commercial Product<br />
Acephate 1 0.01 Standard Sigma-Aldrich<br />
Chlorthalonil 0.1-0.5 0.01 Commercial Bravo 50<br />
Cypermethrin
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV<br />
- The homogeneity in the treated sample was studied using<br />
the 2006 Harmonised Protocol.<br />
-The sampling standard deviation <strong>of</strong> all the pesticides must be<br />
lower than the critical value.<br />
Where,<br />
c = F 1σ 2 all + F 2s 2 analytical<br />
Homogeneity<br />
S sample 2 < c<br />
σ 2 all = 0.3 x FFP RSD(25%) x MEAN<br />
All the pesticides passed the homogeneity test
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Stability<br />
1 st Analysis - prior to the sample shipment<br />
<strong>EURL</strong>-FV<br />
2 nd Analysis - after the deadline to submit the results<br />
All the pesticides passed the stability test
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Stability<br />
<strong>EURL</strong>-FV<br />
Additionally:<br />
3 rd Analysis - keep the sample at room temperature for<br />
several days.
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
100ppb_Mix FV15_Potato<br />
400ppb_Spirodicl<strong>of</strong>en_Potato<br />
400ppb_Spirodicl<strong>of</strong>en_Solvent<br />
Sample_189_FV15<br />
100ppb_Mix<br />
FV15_Potato<br />
Sample_189_FV15<br />
Spirodicl<strong>of</strong>en<br />
[M+H] + : 411.1124<br />
C 21H 24Cl 2O 4<br />
<strong>EURL</strong>-FV<br />
Spirodicl<strong>of</strong>en<br />
“correct” storage conditions
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
3-OH-Spirodicl<strong>of</strong>en-enol<br />
C 15H 14Cl 2O 4<br />
[M+H]+: 329.0342<br />
Spirodicl<strong>of</strong>en-enol<br />
C 15H 14Cl 2O 3<br />
[M+H]+: 313.0393<br />
<strong>EURL</strong>-FV<br />
Spirodicl<strong>of</strong>en –potato matrix after<br />
4 days at room temperature<br />
Sample_189<br />
Spirodicl<strong>of</strong>en<br />
C 21H 24Cl 2O 4<br />
[M+H] + : 411.1124<br />
Spirodicl<strong>of</strong>en<br />
C 21H 24Cl 2O 4<br />
[M+H] + : 411.1124<br />
100ppb_MixFV15_Potato
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Spirodicl<strong>of</strong>en<br />
<strong>EURL</strong>-FV<br />
Spirodicl<strong>of</strong>en-enol<br />
3-hydroxy-spirodicl<strong>of</strong>en-enol
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Prochloraz metabolite<br />
C 11H 14NOCl 3<br />
[M+H]+: 282.0213<br />
PROCHLORAZ- Potato sample at room<br />
temperature during 4 days<br />
Prochloraz<br />
C 15H 17N 3O 2Cl 3<br />
[M+H]+: 376.0381<br />
Sample 189 Day 4 room temp.<br />
Sample 189 Day 1<br />
Sample 189 Day 1<br />
<strong>EURL</strong>-FV<br />
Sample 189 Day 4 room temp.
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
PRELIMINARY<br />
RESULTS<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Frequency<br />
Frequency<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
80<br />
60<br />
40<br />
20<br />
Acephate<br />
0 0,03 0,06 0,09 0,12 0,15<br />
Median: 0.083 mg/kg<br />
Chlorothalonil<br />
mg/Kg<br />
0<br />
-0,03 0,17 0,37 0,57 0,77<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
Median: 0.160 mg/kg<br />
mg/Kg<br />
Frequency<br />
Frequency<br />
100<br />
80<br />
60<br />
40<br />
20<br />
0<br />
80<br />
60<br />
40<br />
20<br />
0<br />
Azoxystrobin<br />
<strong>EURL</strong>-FV<br />
0 0,1 0,2 0,3 0,4 0,5<br />
Median: 0.203 mg/kg<br />
Chlorpropham<br />
mg/Kg<br />
0 1 2 3 4<br />
Median: 1.700 mg/kg<br />
mg/Kg
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Frequency<br />
Frequency<br />
80<br />
60<br />
40<br />
20<br />
Cypermethrin<br />
0<br />
-0,02 0,08 0,18 0,28 0,38<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
Median: 0.100 mg/kg<br />
Fluopicolide<br />
mg/kg<br />
0 0,03 0,06 0,09 0,12 0,15 0,18<br />
Median: 0.099 mg/kg<br />
mg/Kg<br />
Frequency<br />
Frequency<br />
100<br />
80<br />
60<br />
40<br />
20<br />
80<br />
60<br />
40<br />
20<br />
0<br />
Diazinon<br />
<strong>EURL</strong>-FV<br />
0 0,1 0,2 0,3 0,4 0,5<br />
Median: 0.195 mg/kg<br />
Flutolanil<br />
mg/Kg<br />
0<br />
-0,1 0,1 0,3 0,5 0,7 0,9 1,1 1,3<br />
Median: 0.410 mg/kg<br />
mg/Kg
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Frequency<br />
Frequency<br />
80<br />
60<br />
40<br />
20<br />
0<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
Fosthiazate<br />
0 0,03 0,06 0,09 0,12 0,15 0,18<br />
Median: 0.080 mg/kg<br />
Linuron<br />
mg/Kg<br />
0 0,03 0,06 0,09 0,12 0,15 0,18<br />
Median: 0.098 mg/kg<br />
mg/Kg<br />
Frequency<br />
Frequency<br />
80<br />
60<br />
40<br />
20<br />
0<br />
80<br />
60<br />
40<br />
20<br />
0<br />
Iprovalicarb<br />
<strong>EURL</strong>-FV<br />
0 0,04 0,08 0,12 0,16 0,2<br />
Median: 0.090 mg/kg<br />
Methiocarb<br />
mg/Kg<br />
0 0,2 0,4 0,6 0,8<br />
mg/Kg<br />
Median: 0.136 mg/kg
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Frequency<br />
Frequency<br />
80<br />
60<br />
40<br />
20<br />
0<br />
80<br />
60<br />
40<br />
20<br />
0<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
Pencycuron<br />
0 0,2 0,4 0,6 0,8<br />
Median: 0.269 mg/kg<br />
Procymidone<br />
mg/Kg<br />
0 0,04 0,08 0,12 0,16 0,2 0,24<br />
Median: 0.110 mg/kg<br />
mg/Kg<br />
Frequency<br />
Frequency<br />
40<br />
30<br />
20<br />
10<br />
0<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
Prochloraz<br />
<strong>EURL</strong>-FV<br />
0 0,02 0,04 0,06 0,08 0,1<br />
Median: 0.058 mg/kg<br />
Spirodicl<strong>of</strong>en<br />
mg/Kg<br />
0 0,3 0,6 0,9 1,2 1,5 1,8<br />
Median: 0.444 mg/kg<br />
mg/Kg
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Frequency<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
0<br />
Thiabendazole<br />
0 1 2 3 4<br />
Median: 1.710 mg/kg<br />
mg/Kg<br />
Frequency<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
Thiacloprid<br />
<strong>EURL</strong>-FV<br />
0 0,2 0,4 0,6 0,8<br />
Median: 0.338 mg/kg<br />
mg/Kg
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May <strong>Pesticides</strong><br />
No. <strong>of</strong><br />
Reported<br />
<strong>Results</strong><br />
No. <strong>of</strong> False<br />
Negative<br />
<strong>Results</strong><br />
No. <strong>of</strong> Not<br />
Analysed<br />
<strong>Results</strong><br />
<strong>EURL</strong>-FV<br />
Percentage <strong>of</strong> Reported<br />
<strong>Results</strong><br />
(out <strong>of</strong> 173)<br />
Acephate 132 8 33 76<br />
Azoxystrobin 162 1 10 94<br />
Chlorothalonil 144 6 23 83<br />
Chlorpropham 141 3 29 82<br />
Cypermethrin 157 6 10 91<br />
Diazinon 172 0 1 99<br />
Fluopicolide 101 1 71 58<br />
Flutolanil 106 1 66 61<br />
Fosthiazate 105 2 66 61<br />
Iprovalicarb 133 0 40 77<br />
Linuron 134 1 38 77<br />
Methiocarb 137 5 31 79<br />
Pencycuron 121 0 52 70<br />
Prochloraz 144 3 26 83<br />
Procymidone 161 2 10 93<br />
Spirodicl<strong>of</strong>en 113 2 58 65<br />
Thiabendazole 144 3 26 83<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
<strong>EURL</strong>-FV<br />
<strong>Pesticides</strong> MRRL (mg/kg) Median (mg/kg) FFP RSD (%) Qn RSD (%)<br />
Acephate 0.01 0.083 25 21.3<br />
Azoxystrobin 0.01 0.203 25 15.3<br />
Chlorothalonil 0.01 0.160 25 26.4<br />
Chlorpropham 0.01 1.700 25 19.9<br />
Cypermethrin 0.01 0.100 25 26.6<br />
Diazinon 0.01 0.195 25 20.4<br />
Fluopicolide 0.01 0.099 25 15.7<br />
Flutolanil 0.01 0.410 25 14.1<br />
Fosthiazate 0.01 0.080 25 19.4<br />
Iprovalicarb 0.01 0.090 25 17.3<br />
Linuron 0.01 0.098 25 20.4<br />
Methiocarb 0.01 0.136 25 21.2<br />
Pencycuron 0.01 0.269 25 16.5<br />
Prochloraz 0.01 0.058 25 26.8<br />
Procymidone 0.01 0.110 25 19.9<br />
Spirodicl<strong>of</strong>en 0.01 0.444 25 20.0<br />
Thiabendazole 0.01 1.710 25 22.1<br />
Thiacloprid 0.01 0.338 25 18.4
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
%<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
z-Scores<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>Pesticides</strong><br />
Median<br />
(mg/kg)<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
Acceptable<br />
(%)<br />
Questionable<br />
(%)<br />
<strong>EURL</strong>-FV<br />
Unacceptable<br />
Acephate 0.083 90.7 3.6 5.7<br />
Azoxystrobin 0.203 97.5 0.0 2.5<br />
Chlorothalonil 0.160 84.0 6.7 9.3<br />
Chlorpropham 1.700 93.8 2.8 3.5<br />
Cypermethrin 0.100 89.0 5.5 5.5<br />
Diazinon 0.195 95.3 2.9 1.7<br />
Fluopicolide 0.099 94.1 3.9 2.0<br />
Flutolanil 0.410 96.3 1.9 1.9<br />
Fosthiazate 0.080 95.3 1.9 2.8<br />
Iprovalicarb 0.090 97.0 2.3 0.8<br />
Linuron 0.098 95.6 3.7 0.7<br />
Methiocarb 0.136 93.0 2.1 4.9<br />
Pencycuron 0.269 97.5 1.6 0.8<br />
Prochloraz 0.058 89.8 8.2 2.0<br />
Procymidone 0.110 95.1 3.1 1.8<br />
Spirodicl<strong>of</strong>en 0.444 91.3 4.3 4.3<br />
Thiabendazole 1.710 93.2 4.1 2.7<br />
Thiacloprid 0.338 94.0 2.2 3.7<br />
(%)
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>Pesticides</strong><br />
Median<br />
(mg/kg)<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
Acceptable<br />
(%)<br />
Questionable<br />
(%)<br />
<strong>EURL</strong>-FV<br />
Unacceptable<br />
Acephate 0.083 90.7 3.6 5.7<br />
Azoxystrobin 0.203 97.5 0.0 2.5<br />
Chlorothalonil 0.160 84.0 6.7 9.3<br />
Chlorpropham 1.700 93.8 2.8 3.5<br />
Cypermethrin 0.100 89.0 5.5 5.5<br />
Diazinon 0.195 95.3 2.9 1.7<br />
Fluopicolide 0.099 94.1 3.9 2.0<br />
Flutolanil 0.410 96.3 1.9 1.9<br />
Fosthiazate 0.080 95.3 1.9 2.8<br />
Iprovalicarb 0.090 97.0 2.3 0.8<br />
Linuron 0.098 95.6 3.7 0.7<br />
Methiocarb 0.136 93.0 2.1 4.9<br />
Pencycuron 0.269 97.5 1.6 0.8<br />
Prochloraz 0.058 89.8 8.2 2.0<br />
Procymidone 0.110 95.1 3.1 1.8<br />
Spirodicl<strong>of</strong>en 0.444 91.3 4.3 4.3<br />
Thiabendazole 1.710 93.2 4.1 2.7<br />
Thiacloprid 0.338 94.0 2.2 3.7<br />
(%)
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
Lab019<br />
Lab010<br />
Lab086<br />
Lab049<br />
Lab006<br />
Lab079<br />
Lab128<br />
Lab095<br />
Lab045<br />
Lab037<br />
Lab022<br />
Lab085<br />
Lab154<br />
Lab116<br />
Lab099<br />
Lab080<br />
Lab005<br />
Lab131<br />
Lab002<br />
Lab138<br />
Lab126<br />
Lab119<br />
Lab094<br />
Lab092<br />
Lab164<br />
Lab120<br />
Lab104<br />
Lab040<br />
Lab144<br />
Lab018<br />
Lab163<br />
Lab112<br />
Lab075<br />
Lab046<br />
Lab030<br />
Lab161<br />
Lab107<br />
Lab083<br />
Lab121<br />
Lab158<br />
Lab033<br />
Lab156<br />
Lab118<br />
Lab111<br />
Lab068<br />
Lab039<br />
Lab052<br />
Lab044<br />
Lab078<br />
Lab054<br />
Lab043<br />
Lab004<br />
Lab135<br />
Lab132<br />
Lab093<br />
Lab047<br />
Lab041<br />
Lab014<br />
Lab136<br />
Lab026<br />
Lab130<br />
Lab103<br />
Lab038<br />
Lab029<br />
Lab165<br />
Lab091<br />
Lab100<br />
Lab073<br />
Lab062<br />
Lab124<br />
Lab082<br />
Lab059<br />
Lab057<br />
Lab067<br />
Lab123<br />
Lab097<br />
Lab076<br />
Lab008<br />
Lab159<br />
Lab108<br />
Lab110<br />
Lab105<br />
Lab081<br />
Lab117<br />
Lab051<br />
Lab024<br />
Lab140<br />
Lab101<br />
Lab066<br />
Lab007<br />
Lab114<br />
Lab015<br />
Lab148<br />
Lab069<br />
Lab061<br />
Lab053<br />
Lab137<br />
Lab109<br />
Lab162<br />
Lab122<br />
Lab072<br />
Lab173<br />
Lab125<br />
Lab032<br />
Lab027<br />
Lab013<br />
Lab011<br />
Lab166<br />
Lab050<br />
Lab171<br />
Lab143<br />
Lab134<br />
Lab017<br />
Lab065<br />
Lab058<br />
Lab028<br />
Lab012<br />
Lab090<br />
Lab055<br />
Lab172<br />
Lab034<br />
Lab025<br />
Lab106<br />
Lab129<br />
Lab020<br />
Lab035<br />
Lab074<br />
Lab102<br />
Lab021<br />
Lab160<br />
Lab001<br />
Lab150<br />
Lab147<br />
Lab145<br />
Lab089<br />
Lab087<br />
Lab084<br />
Lab077<br />
Lab064<br />
Lab003<br />
* * * * * * * *<br />
90.7 % Acceptable<br />
3.6 % Questionable<br />
5.7 % Unacceptable<br />
* False Negatives<br />
Acephate<br />
Acephate<br />
Median: 0.083 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Azoxystrobin<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab027<br />
Lab084<br />
Lab177<br />
Lab016<br />
Lab078<br />
Lab117<br />
Lab153<br />
Lab172<br />
Lab116<br />
Lab032<br />
Lab090<br />
Lab094<br />
Lab106<br />
Lab098<br />
Lab033<br />
Lab133<br />
Lab079<br />
Lab002<br />
Lab112<br />
Lab100<br />
Lab072<br />
Lab015<br />
Lab070<br />
Lab123<br />
Lab008<br />
Lab025<br />
Lab089<br />
Lab166<br />
Lab122<br />
Lab004<br />
Lab073<br />
Lab154<br />
Lab096<br />
Lab001<br />
Lab006<br />
Lab013<br />
Lab018<br />
Lab060<br />
Lab113<br />
Lab131<br />
Lab141<br />
Lab023<br />
Lab050<br />
Lab051<br />
Lab114<br />
Lab137<br />
Lab049<br />
Lab017<br />
Lab074<br />
Lab012<br />
Lab035<br />
Lab045<br />
Lab111<br />
Lab125<br />
Lab126<br />
Lab138<br />
Lab175<br />
Lab157<br />
Lab169<br />
Lab007<br />
Lab052<br />
Lab088<br />
Lab143<br />
Lab020<br />
Lab134<br />
Lab146<br />
Lab058<br />
Lab168<br />
Lab011<br />
Lab029<br />
Lab036<br />
Lab039<br />
Lab044<br />
Lab061<br />
Lab068<br />
Lab069<br />
Lab086<br />
Lab124<br />
Lab139<br />
Lab091<br />
Lab034<br />
Lab165<br />
Lab028<br />
Lab038<br />
Lab063<br />
Lab054<br />
Lab151<br />
Lab159<br />
Lab005<br />
Lab080<br />
Lab024<br />
Lab136<br />
Lab108<br />
Lab118<br />
Lab150<br />
Lab156<br />
Lab135<br />
Lab105<br />
Lab149<br />
Lab059<br />
Lab075<br />
Lab097<br />
Lab022<br />
Lab093<br />
Lab144<br />
Lab009<br />
Lab065<br />
Lab043<br />
Lab030<br />
Lab095<br />
Lab099<br />
Lab109<br />
Lab110<br />
Lab129<br />
Lab130<br />
Lab145<br />
Lab158<br />
Lab160<br />
Lab048<br />
Lab057<br />
Lab142<br />
Lab161<br />
Lab019<br />
Lab171<br />
Lab066<br />
Lab140<br />
Lab021<br />
Lab102<br />
Lab103<br />
Lab120<br />
Lab119<br />
Lab121<br />
Lab173<br />
Lab003<br />
Lab082<br />
Lab104<br />
Lab128<br />
Lab053<br />
Lab127<br />
Lab042<br />
Lab067<br />
Lab083<br />
Lab163<br />
Lab064<br />
Lab076<br />
Lab092<br />
Lab132<br />
Lab047<br />
Lab014<br />
Lab026<br />
Lab107<br />
Lab101<br />
Lab062<br />
Lab055<br />
Lab046<br />
Lab148<br />
Lab041<br />
Lab077<br />
Lab037<br />
Lab085<br />
Lab040<br />
Lab010<br />
Lab164<br />
97.5 % Acceptable<br />
0.0 % Questionable<br />
2.5 % Unacceptable<br />
Azoxystrobin<br />
Median: 0.203 mg/kg<br />
*<br />
* False Negatives<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
* * * * * *<br />
Lab129<br />
Lab075<br />
Lab043<br />
Lab004<br />
Lab108<br />
Lab102<br />
Lab158<br />
Lab026<br />
Lab088<br />
Lab135<br />
Lab031<br />
Lab019<br />
Lab052<br />
Lab171<br />
Lab029<br />
Lab098<br />
Lab073<br />
Lab140<br />
Lab161<br />
Lab175<br />
Lab033<br />
Lab173<br />
Lab142<br />
Lab028<br />
Lab144<br />
Lab109<br />
Lab049<br />
Lab038<br />
Lab024<br />
Lab139<br />
Lab092<br />
Lab087<br />
Lab074<br />
Lab103<br />
Lab067<br />
Lab041<br />
Lab105<br />
Lab030<br />
Lab020<br />
Lab048<br />
Lab003<br />
Lab143<br />
Lab095<br />
Lab061<br />
Lab040<br />
Lab021<br />
Lab166<br />
Lab096<br />
Lab146<br />
Lab104<br />
Lab101<br />
Lab131<br />
Lab080<br />
Lab066<br />
Lab046<br />
Lab055<br />
Lab017<br />
Lab156<br />
Lab154<br />
Lab151<br />
Lab113<br />
Lab111<br />
Lab110<br />
Lab086<br />
Lab037<br />
Lab058<br />
Lab042<br />
Lab059<br />
Lab163<br />
Lab082<br />
Lab022<br />
Lab145<br />
Lab107<br />
Lab093<br />
Lab079<br />
Lab070<br />
Lab018<br />
Lab065<br />
Lab063<br />
Lab164<br />
Lab152<br />
Lab150<br />
Lab138<br />
Lab119<br />
Lab069<br />
Lab064<br />
Lab060<br />
Lab035<br />
Lab011<br />
Lab132<br />
Lab039<br />
Lab120<br />
Lab034<br />
Lab160<br />
Lab133<br />
Lab124<br />
Lab094<br />
Lab077<br />
Lab115<br />
Lab099<br />
Lab009<br />
Lab012<br />
Lab078<br />
Lab117<br />
Lab005<br />
Lab123<br />
Lab121<br />
Lab044<br />
Lab016<br />
Lab097<br />
Lab054<br />
Lab050<br />
Lab147<br />
Lab112<br />
Lab007<br />
Lab008<br />
Lab002<br />
Lab062<br />
Lab032<br />
Lab116<br />
Lab091<br />
Lab172<br />
Lab085<br />
Lab118<br />
Lab114<br />
Lab148<br />
Lab025<br />
Lab090<br />
Lab015<br />
Lab165<br />
Lab137<br />
Lab122<br />
Lab125<br />
Lab068<br />
Lab177<br />
Lab106<br />
Lab051<br />
Lab013<br />
Lab053<br />
Lab136<br />
Lab159<br />
Lab149<br />
Lab084<br />
Lab169<br />
Lab153<br />
Lab134<br />
Lab083<br />
Lab056<br />
Lab027<br />
Lab006<br />
84.0 % Acceptable<br />
6.7 % Questionable<br />
9.3 % Unacceptable<br />
* False Negatives<br />
Chlorothalonil<br />
Chlorothalonil<br />
Median: 0.160 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Chlorpropham<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab083<br />
Lab085<br />
Lab160<br />
Lab010<br />
Lab153<br />
Lab056<br />
Lab148<br />
Lab003<br />
Lab057<br />
Lab114<br />
Lab142<br />
Lab105<br />
Lab123<br />
Lab145<br />
Lab088<br />
Lab002<br />
Lab100<br />
Lab131<br />
Lab044<br />
Lab038<br />
Lab063<br />
Lab055<br />
Lab165<br />
Lab166<br />
Lab106<br />
Lab091<br />
Lab039<br />
Lab108<br />
Lab025<br />
Lab015<br />
Lab090<br />
Lab053<br />
Lab143<br />
Lab013<br />
Lab073<br />
Lab032<br />
Lab168<br />
Lab074<br />
Lab118<br />
Lab001<br />
Lab018<br />
Lab109<br />
Lab141<br />
Lab134<br />
Lab137<br />
Lab034<br />
Lab020<br />
Lab078<br />
Lab112<br />
Lab092<br />
Lab082<br />
Lab022<br />
Lab050<br />
Lab146<br />
Lab041<br />
Lab028<br />
Lab036<br />
Lab051<br />
Lab061<br />
Lab150<br />
Lab171<br />
Lab017<br />
Lab136<br />
Lab046<br />
Lab030<br />
Lab040<br />
Lab135<br />
Lab149<br />
Lab094<br />
Lab029<br />
Lab102<br />
Lab110<br />
Lab111<br />
Lab121<br />
Lab129<br />
Lab139<br />
Lab120<br />
Lab138<br />
Lab147<br />
Lab127<br />
Lab163<br />
Lab097<br />
Lab173<br />
Lab054<br />
Lab103<br />
Lab066<br />
Lab019<br />
Lab049<br />
Lab172<br />
Lab042<br />
Lab077<br />
Lab119<br />
Lab007<br />
Lab005<br />
Lab062<br />
Lab161<br />
Lab011<br />
Lab004<br />
Lab048<br />
Lab125<br />
Lab024<br />
Lab093<br />
Lab132<br />
Lab154<br />
Lab067<br />
Lab047<br />
Lab130<br />
Lab043<br />
Lab027<br />
Lab033<br />
Lab068<br />
Lab156<br />
Lab065<br />
Lab035<br />
Lab021<br />
Lab058<br />
Lab059<br />
Lab076<br />
Lab080<br />
Lab124<br />
Lab158<br />
Lab079<br />
Lab099<br />
Lab026<br />
Lab140<br />
Lab164<br />
Lab006<br />
Lab075<br />
Lab116<br />
Lab101<br />
Lab014<br />
Lab070<br />
Lab037<br />
Lab107<br />
Lab052<br />
Lab151<br />
Lab016<br />
Lab064<br />
Lab012<br />
Lab089<br />
Lab072<br />
Lab104<br />
Lab008<br />
Lab095<br />
93.8 % Acceptable<br />
2.8 % Questionable<br />
3.5 % Unacceptable<br />
Chlorpropham<br />
Median: 1.700 mg/kg<br />
* * *<br />
* False Negatives<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
Lab122<br />
Lab027<br />
Lab177<br />
Lab026<br />
Lab138<br />
Lab089<br />
Lab059<br />
Lab070<br />
Lab037<br />
Lab144<br />
Lab101<br />
Lab049<br />
Lab004<br />
Lab140<br />
Lab109<br />
Lab055<br />
Lab169<br />
Lab066<br />
Lab080<br />
Lab150<br />
Lab130<br />
Lab086<br />
Lab076<br />
Lab054<br />
Lab052<br />
Lab098<br />
Lab042<br />
Lab135<br />
Lab093<br />
Lab043<br />
Lab020<br />
Lab132<br />
Lab164<br />
Lab148<br />
Lab141<br />
Lab139<br />
Lab129<br />
Lab126<br />
Lab124<br />
Lab119<br />
Lab112<br />
Lab061<br />
Lab029<br />
Lab102<br />
Lab067<br />
Lab039<br />
Lab104<br />
Lab088<br />
Lab017<br />
Lab105<br />
Lab097<br />
Lab058<br />
Lab035<br />
Lab021<br />
Lab168<br />
Lab128<br />
Lab121<br />
Lab111<br />
Lab110<br />
Lab118<br />
Lab025<br />
Lab173<br />
Lab127<br />
Lab143<br />
Lab024<br />
Lab005<br />
Lab142<br />
Lab063<br />
Lab171<br />
Lab081<br />
Lab062<br />
Lab048<br />
Lab159<br />
Lab120<br />
Lab099<br />
Lab008<br />
Lab152<br />
Lab125<br />
Lab113<br />
Lab074<br />
Lab044<br />
Lab028<br />
Lab018<br />
Lab108<br />
Lab096<br />
Lab019<br />
Lab078<br />
Lab073<br />
Lab069<br />
Lab047<br />
Lab036<br />
Lab166<br />
Lab041<br />
Lab030<br />
Lab034<br />
Lab161<br />
Lab116<br />
Lab065<br />
Lab158<br />
Lab154<br />
Lab115<br />
Lab103<br />
Lab068<br />
Lab060<br />
Lab015<br />
Lab051<br />
Lab149<br />
Lab147<br />
Lab022<br />
Lab095<br />
Lab079<br />
Lab038<br />
Lab123<br />
Lab075<br />
Lab007<br />
Lab114<br />
Lab012<br />
Lab040<br />
Lab146<br />
Lab085<br />
Lab175<br />
Lab156<br />
Lab106<br />
Lab087<br />
Lab172<br />
Lab151<br />
Lab107<br />
Lab160<br />
Lab090<br />
Lab050<br />
Lab046<br />
Lab001<br />
Lab134<br />
Lab091<br />
Lab117<br />
Lab100<br />
Lab092<br />
Lab157<br />
Lab133<br />
Lab145<br />
Lab013<br />
Lab165<br />
Lab009<br />
Lab163<br />
Lab011<br />
Lab033<br />
Lab053<br />
Lab137<br />
Lab084<br />
Lab071<br />
Lab094<br />
Lab057<br />
Lab136<br />
Lab032<br />
Lab170<br />
Lab010<br />
Lab153<br />
Lab083<br />
Lab077<br />
Lab072<br />
Lab064<br />
Lab006<br />
Lab002<br />
* * * * * *<br />
89.0 % Acceptable<br />
5.5 % Questionable<br />
5.5 % Unacceptable<br />
* False Negatives<br />
Cypermethrin<br />
Cypermethrin<br />
Median: 0.100 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Diazinon<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab114<br />
Lab056<br />
Lab170<br />
Lab153<br />
Lab077<br />
Lab003<br />
Lab053<br />
Lab057<br />
Lab013<br />
Lab087<br />
Lab136<br />
Lab157<br />
Lab133<br />
Lab090<br />
Lab122<br />
Lab100<br />
Lab032<br />
Lab061<br />
Lab084<br />
Lab159<br />
Lab025<br />
Lab165<br />
Lab050<br />
Lab112<br />
Lab123<br />
Lab175<br />
Lab046<br />
Lab151<br />
Lab137<br />
Lab072<br />
Lab049<br />
Lab039<br />
Lab009<br />
Lab134<br />
Lab177<br />
Lab001<br />
Lab015<br />
Lab044<br />
Lab070<br />
Lab073<br />
Lab126<br />
Lab145<br />
Lab152<br />
Lab008<br />
Lab034<br />
Lab012<br />
Lab131<br />
Lab172<br />
Lab028<br />
Lab085<br />
Lab146<br />
Lab017<br />
Lab166<br />
Lab011<br />
Lab018<br />
Lab027<br />
Lab094<br />
Lab150<br />
Lab160<br />
Lab091<br />
Lab019<br />
Lab048<br />
Lab036<br />
Lab005<br />
Lab079<br />
Lab148<br />
Lab118<br />
Lab002<br />
Lab149<br />
Lab033<br />
Lab060<br />
Lab064<br />
Lab069<br />
Lab138<br />
Lab141<br />
Lab171<br />
Lab047<br />
Lab062<br />
Lab092<br />
Lab007<br />
Lab051<br />
Lab169<br />
Lab030<br />
Lab054<br />
Lab117<br />
Lab143<br />
Lab067<br />
Lab042<br />
Lab082<br />
Lab055<br />
Lab074<br />
Lab111<br />
Lab113<br />
Lab121<br />
Lab124<br />
Lab139<br />
Lab144<br />
Lab156<br />
Lab158<br />
Lab081<br />
Lab058<br />
Lab106<br />
Lab041<br />
Lab063<br />
Lab168<br />
Lab040<br />
Lab097<br />
Lab089<br />
Lab115<br />
Lab023<br />
Lab135<br />
Lab029<br />
Lab068<br />
Lab110<br />
Lab125<br />
Lab129<br />
Lab142<br />
Lab164<br />
Lab078<br />
Lab088<br />
Lab093<br />
Lab147<br />
Lab173<br />
Lab022<br />
Lab116<br />
Lab128<br />
Lab065<br />
Lab086<br />
Lab108<br />
Lab119<br />
Lab038<br />
Lab099<br />
Lab120<br />
Lab059<br />
Lab066<br />
Lab105<br />
Lab080<br />
Lab075<br />
Lab083<br />
Lab102<br />
Lab107<br />
Lab127<br />
Lab130<br />
Lab101<br />
Lab103<br />
Lab020<br />
Lab104<br />
Lab024<br />
Lab076<br />
Lab162<br />
Lab163<br />
Lab132<br />
Lab010<br />
Lab154<br />
Lab035<br />
Lab004<br />
Lab026<br />
Lab140<br />
Lab096<br />
Lab043<br />
Lab014<br />
Lab161<br />
Lab016<br />
Lab031<br />
Lab037<br />
Lab052<br />
Lab021<br />
Lab045<br />
Lab006<br />
Lab095<br />
Lab109<br />
Lab098<br />
95.3 % Acceptable<br />
2.9 % Questionable<br />
1.7 % Unacceptable<br />
Diazinon<br />
Median: 0.195 mg/kg<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
Lab148<br />
Lab110<br />
Lab026<br />
Lab010<br />
Lab080<br />
Lab138<br />
Lab109<br />
Lab145<br />
Lab037<br />
Lab057<br />
Lab062<br />
Lab164<br />
Lab107<br />
Lab092<br />
Lab004<br />
Lab104<br />
Lab047<br />
Lab055<br />
Lab048<br />
Lab005<br />
Lab073<br />
Lab054<br />
Lab132<br />
Lab131<br />
Lab083<br />
Lab065<br />
Lab041<br />
Lab156<br />
Lab124<br />
Lab045<br />
Lab043<br />
Lab171<br />
Lab149<br />
Lab059<br />
Lab049<br />
Lab165<br />
Lab079<br />
Lab030<br />
Lab102<br />
Lab052<br />
Lab034<br />
Lab097<br />
Lab075<br />
Lab020<br />
Lab121<br />
Lab119<br />
Lab111<br />
Lab086<br />
Lab064<br />
Lab035<br />
Lab028<br />
Lab067<br />
Lab040<br />
Lab038<br />
Lab163<br />
Lab143<br />
Lab136<br />
Lab108<br />
Lab074<br />
Lab044<br />
Lab012<br />
Lab007<br />
Lab120<br />
Lab066<br />
Lab042<br />
Lab103<br />
Lab093<br />
Lab046<br />
Lab068<br />
Lab024<br />
Lab150<br />
Lab118<br />
Lab099<br />
Lab017<br />
Lab011<br />
Lab106<br />
Lab029<br />
Lab022<br />
Lab061<br />
Lab025<br />
Lab105<br />
Lab100<br />
Lab018<br />
Lab008<br />
Lab129<br />
Lab112<br />
Lab123<br />
Lab002<br />
Lab173<br />
Lab015<br />
Lab161<br />
Lab122<br />
Lab166<br />
Lab050<br />
Lab051<br />
Lab039<br />
Lab013<br />
Lab137<br />
Lab090<br />
Lab078<br />
Lab084<br />
Lab169<br />
*<br />
94.1 % Acceptable<br />
3.9 % Questionable<br />
2.0 % Unacceptable<br />
* False Negatives<br />
Fluopicolide<br />
Fluopicolide<br />
Median: 0.099 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
Lab010<br />
Lab045<br />
Lab037<br />
Lab080<br />
Lab026<br />
Lab163<br />
Lab124<br />
Lab033<br />
Lab136<br />
Lab055<br />
Lab073<br />
Lab092<br />
Lab038<br />
Lab079<br />
Lab143<br />
Lab156<br />
Lab095<br />
Lab006<br />
Lab049<br />
Lab046<br />
Lab043<br />
Lab057<br />
Lab065<br />
Lab110<br />
Lab005<br />
Lab107<br />
Lab132<br />
Lab171<br />
Lab119<br />
Lab064<br />
Lab149<br />
Lab075<br />
Lab097<br />
Lab034<br />
Lab021<br />
Lab020<br />
Lab145<br />
Lab138<br />
Lab109<br />
Lab059<br />
Lab058<br />
Lab007<br />
Lab102<br />
Lab120<br />
Lab148<br />
Lab042<br />
Lab121<br />
Lab111<br />
Lab044<br />
Lab091<br />
Lab129<br />
Lab066<br />
Lab061<br />
Lab029<br />
Lab104<br />
Lab093<br />
Lab078<br />
Lab103<br />
Lab035<br />
Lab004<br />
Lab173<br />
Lab067<br />
Lab164<br />
Lab068<br />
Lab017<br />
Lab100<br />
Lab030<br />
Lab106<br />
Lab002<br />
Lab040<br />
Lab013<br />
Lab028<br />
Lab024<br />
Lab118<br />
Lab052<br />
Lab011<br />
Lab099<br />
Lab094<br />
Lab062<br />
Lab105<br />
Lab022<br />
Lab018<br />
Lab054<br />
Lab112<br />
Lab050<br />
Lab108<br />
Lab086<br />
Lab074<br />
Lab001<br />
Lab012<br />
Lab166<br />
Lab096<br />
Lab051<br />
Lab137<br />
Lab025<br />
Lab015<br />
Lab041<br />
Lab008<br />
Lab072<br />
Lab165<br />
Lab161<br />
Lab039<br />
Lab090<br />
Lab123<br />
Lab122<br />
Lab084<br />
Lab083<br />
*<br />
96.3 % Acceptable<br />
1.9 % Questionable<br />
1.9 % Unacceptable<br />
* False Negatives<br />
Flutolanil<br />
Flutolanil<br />
Median: 0.410 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
* *<br />
Lab027<br />
Lab084<br />
Lab077<br />
Lab045<br />
Lab010<br />
Lab118<br />
Lab021<br />
Lab110<br />
Lab037<br />
Lab092<br />
Lab091<br />
Lab107<br />
Lab064<br />
Lab109<br />
Lab026<br />
Lab052<br />
Lab038<br />
Lab073<br />
Lab030<br />
Lab164<br />
Lab005<br />
Lab163<br />
Lab161<br />
Lab120<br />
Lab104<br />
Lab041<br />
Lab006<br />
Lab099<br />
Lab078<br />
Lab076<br />
Lab022<br />
Lab121<br />
Lab119<br />
Lab136<br />
Lab057<br />
Lab044<br />
Lab004<br />
Lab083<br />
Lab033<br />
Lab017<br />
Lab095<br />
Lab039<br />
Lab165<br />
Lab145<br />
Lab080<br />
Lab059<br />
Lab040<br />
Lab108<br />
Lab101<br />
Lab020<br />
Lab171<br />
Lab111<br />
Lab103<br />
Lab074<br />
Lab067<br />
Lab013<br />
Lab097<br />
Lab075<br />
Lab009<br />
Lab172<br />
Lab066<br />
Lab034<br />
Lab132<br />
Lab093<br />
Lab079<br />
Lab065<br />
Lab055<br />
Lab018<br />
Lab137<br />
Lab068<br />
Lab043<br />
Lab024<br />
Lab173<br />
Lab061<br />
Lab123<br />
Lab102<br />
Lab007<br />
Lab166<br />
Lab054<br />
Lab015<br />
Lab049<br />
Lab012<br />
Lab086<br />
Lab112<br />
Lab090<br />
Lab035<br />
Lab001<br />
Lab062<br />
Lab011<br />
Lab105<br />
Lab028<br />
Lab051<br />
Lab050<br />
Lab129<br />
Lab100<br />
Lab046<br />
Lab130<br />
Lab106<br />
Lab008<br />
Lab029<br />
Lab025<br />
Lab082<br />
Lab002<br />
Lab156<br />
Lab053<br />
Lab148<br />
Lab058<br />
95.3 % Acceptable<br />
1.9 % Questionable<br />
2.8 % Unacceptable<br />
* False Negatives<br />
Fosthiazate<br />
Fosthiazate<br />
Median: 0.080 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Iprovalicarb<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab084<br />
Lab008<br />
Lab095<br />
Lab072<br />
Lab162<br />
Lab025<br />
Lab135<br />
Lab023<br />
Lab112<br />
Lab078<br />
Lab010<br />
Lab051<br />
Lab123<br />
Lab028<br />
Lab001<br />
Lab090<br />
Lab122<br />
Lab166<br />
Lab114<br />
Lab015<br />
Lab029<br />
Lab054<br />
Lab129<br />
Lab161<br />
Lab177<br />
Lab017<br />
Lab035<br />
Lab131<br />
Lab039<br />
Lab073<br />
Lab124<br />
Lab024<br />
Lab074<br />
Lab105<br />
Lab106<br />
Lab145<br />
Lab171<br />
Lab173<br />
Lab011<br />
Lab018<br />
Lab137<br />
Lab004<br />
Lab013<br />
Lab007<br />
Lab050<br />
Lab143<br />
Lab034<br />
Lab043<br />
Lab044<br />
Lab049<br />
Lab102<br />
Lab108<br />
Lab165<br />
Lab040<br />
Lab093<br />
Lab111<br />
Lab150<br />
Lab002<br />
Lab066<br />
Lab069<br />
Lab100<br />
Lab062<br />
Lab151<br />
Lab006<br />
Lab020<br />
Lab032<br />
Lab068<br />
Lab075<br />
Lab097<br />
Lab146<br />
Lab041<br />
Lab061<br />
Lab065<br />
Lab099<br />
Lab120<br />
Lab160<br />
Lab058<br />
Lab157<br />
Lab138<br />
Lab012<br />
Lab045<br />
Lab059<br />
Lab103<br />
Lab067<br />
Lab127<br />
Lab019<br />
Lab080<br />
Lab132<br />
Lab046<br />
Lab064<br />
Lab101<br />
Lab110<br />
Lab119<br />
Lab126<br />
Lab130<br />
Lab156<br />
Lab158<br />
Lab164<br />
Lab052<br />
Lab092<br />
Lab048<br />
Lab082<br />
Lab083<br />
Lab104<br />
Lab163<br />
Lab030<br />
Lab159<br />
Lab063<br />
Lab091<br />
Lab038<br />
Lab079<br />
Lab055<br />
Lab057<br />
Lab033<br />
Lab076<br />
Lab107<br />
Lab121<br />
Lab022<br />
Lab047<br />
Lab136<br />
Lab005<br />
Lab021<br />
Lab118<br />
Lab109<br />
Lab140<br />
Lab053<br />
Lab096<br />
Lab026<br />
Lab037<br />
Lab085<br />
Lab148<br />
Lab086<br />
Lab027<br />
97.0 % Acceptable<br />
2.3 % Questionable<br />
0.8 % Unacceptable<br />
Iprovalicarb<br />
Median: 0.090 mg/kg<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Linuron<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab085<br />
Lab156<br />
Lab084<br />
Lab011<br />
Lab066<br />
Lab008<br />
Lab092<br />
Lab007<br />
Lab012<br />
Lab096<br />
Lab123<br />
Lab161<br />
Lab090<br />
Lab153<br />
Lab050<br />
Lab025<br />
Lab061<br />
Lab028<br />
Lab063<br />
Lab094<br />
Lab051<br />
Lab088<br />
Lab112<br />
Lab015<br />
Lab039<br />
Lab172<br />
Lab166<br />
Lab177<br />
Lab114<br />
Lab160<br />
Lab100<br />
Lab117<br />
Lab043<br />
Lab054<br />
Lab086<br />
Lab106<br />
Lab017<br />
Lab020<br />
Lab137<br />
Lab013<br />
Lab032<br />
Lab073<br />
Lab102<br />
Lab136<br />
Lab162<br />
Lab035<br />
Lab045<br />
Lab048<br />
Lab118<br />
Lab024<br />
Lab058<br />
Lab124<br />
Lab173<br />
Lab111<br />
Lab129<br />
Lab135<br />
Lab033<br />
Lab046<br />
Lab171<br />
Lab151<br />
Lab034<br />
Lab163<br />
Lab029<br />
Lab105<br />
Lab004<br />
Lab044<br />
Lab075<br />
Lab110<br />
Lab159<br />
Lab095<br />
Lab150<br />
Lab157<br />
Lab018<br />
Lab022<br />
Lab074<br />
Lab093<br />
Lab099<br />
Lab108<br />
Lab119<br />
Lab139<br />
Lab023<br />
Lab040<br />
Lab078<br />
Lab091<br />
Lab053<br />
Lab122<br />
Lab097<br />
Lab005<br />
Lab026<br />
Lab041<br />
Lab059<br />
Lab132<br />
Lab065<br />
Lab072<br />
Lab068<br />
Lab104<br />
Lab121<br />
Lab130<br />
Lab141<br />
Lab145<br />
Lab158<br />
Lab030<br />
Lab038<br />
Lab049<br />
Lab165<br />
Lab103<br />
Lab047<br />
Lab079<br />
Lab083<br />
Lab120<br />
Lab001<br />
Lab076<br />
Lab107<br />
Lab138<br />
Lab140<br />
Lab144<br />
Lab067<br />
Lab154<br />
Lab128<br />
Lab019<br />
Lab057<br />
Lab055<br />
Lab064<br />
Lab164<br />
Lab062<br />
Lab002<br />
Lab006<br />
Lab037<br />
Lab109<br />
Lab080<br />
Lab010<br />
Lab021<br />
Lab101<br />
Lab052<br />
Lab098<br />
95.6 % Acceptable<br />
3.7 % Questionable<br />
0.7 % Unacceptable<br />
Linuron<br />
Median: 0.098 mg/kg<br />
*<br />
* False Negatives<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
Lab077<br />
Lab013<br />
Lab098<br />
Lab140<br />
Lab085<br />
Lab062<br />
Lab156<br />
Lab064<br />
Lab033<br />
Lab057<br />
Lab105<br />
Lab096<br />
Lab080<br />
Lab163<br />
Lab048<br />
Lab030<br />
Lab052<br />
Lab103<br />
Lab072<br />
Lab136<br />
Lab130<br />
Lab104<br />
Lab037<br />
Lab021<br />
Lab128<br />
Lab097<br />
Lab047<br />
Lab002<br />
Lab107<br />
Lab101<br />
Lab076<br />
Lab014<br />
Lab006<br />
Lab065<br />
Lab083<br />
Lab046<br />
Lab026<br />
Lab035<br />
Lab038<br />
Lab119<br />
Lab110<br />
Lab061<br />
Lab165<br />
Lab132<br />
Lab059<br />
Lab058<br />
Lab041<br />
Lab082<br />
Lab004<br />
Lab055<br />
Lab099<br />
Lab079<br />
Lab148<br />
Lab040<br />
Lab129<br />
Lab121<br />
Lab109<br />
Lab108<br />
Lab070<br />
Lab045<br />
Lab044<br />
Lab043<br />
Lab005<br />
Lab001<br />
Lab091<br />
Lab073<br />
Lab039<br />
Lab034<br />
Lab137<br />
Lab075<br />
Lab120<br />
Lab022<br />
Lab154<br />
Lab020<br />
Lab050<br />
Lab173<br />
Lab158<br />
Lab145<br />
Lab126<br />
Lab124<br />
Lab111<br />
Lab095<br />
Lab068<br />
Lab066<br />
Lab029<br />
Lab028<br />
Lab018<br />
Lab118<br />
Lab012<br />
Lab017<br />
Lab172<br />
Lab149<br />
Lab019<br />
Lab171<br />
Lab049<br />
Lab159<br />
Lab074<br />
Lab024<br />
Lab093<br />
Lab106<br />
Lab112<br />
Lab092<br />
Lab175<br />
Lab164<br />
Lab150<br />
Lab123<br />
Lab032<br />
Lab114<br />
Lab054<br />
Lab100<br />
Lab102<br />
Lab025<br />
Lab166<br />
Lab069<br />
Lab015<br />
Lab011<br />
Lab135<br />
Lab051<br />
Lab161<br />
Lab146<br />
Lab122<br />
Lab131<br />
Lab086<br />
Lab134<br />
Lab151<br />
Lab090<br />
Lab027<br />
Lab053<br />
Lab007<br />
Lab031<br />
Lab067<br />
Lab169<br />
Lab078<br />
Lab008<br />
Lab153<br />
Lab160<br />
Lab084<br />
Lab177<br />
Lab138<br />
Lab094<br />
Lab060<br />
Lab010<br />
* * * * *<br />
93.0 % Acceptable<br />
2.1 % Questionable<br />
4.9 % Unacceptable<br />
* False Negatives<br />
Methiocarb<br />
Methiocarb<br />
Median: 0.136 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Pencycuron<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab172<br />
Lab039<br />
Lab084<br />
Lab053<br />
Lab007<br />
Lab032<br />
Lab157<br />
Lab177<br />
Lab090<br />
Lab100<br />
Lab079<br />
Lab161<br />
Lab122<br />
Lab051<br />
Lab106<br />
Lab050<br />
Lab015<br />
Lab018<br />
Lab078<br />
Lab123<br />
Lab008<br />
Lab058<br />
Lab094<br />
Lab112<br />
Lab049<br />
Lab028<br />
Lab091<br />
Lab011<br />
Lab014<br />
Lab025<br />
Lab166<br />
Lab002<br />
Lab165<br />
Lab137<br />
Lab045<br />
Lab066<br />
Lab109<br />
Lab102<br />
Lab017<br />
Lab105<br />
Lab022<br />
Lab005<br />
Lab140<br />
Lab149<br />
Lab041<br />
Lab114<br />
Lab082<br />
Lab143<br />
Lab092<br />
Lab001<br />
Lab013<br />
Lab024<br />
Lab074<br />
Lab110<br />
Lab145<br />
Lab136<br />
Lab040<br />
Lab088<br />
Lab063<br />
Lab019<br />
Lab020<br />
Lab068<br />
Lab086<br />
Lab095<br />
Lab103<br />
Lab108<br />
Lab111<br />
Lab138<br />
Lab156<br />
Lab173<br />
Lab065<br />
Lab093<br />
Lab097<br />
Lab135<br />
Lab012<br />
Lab124<br />
Lab034<br />
Lab075<br />
Lab148<br />
Lab054<br />
Lab163<br />
Lab038<br />
Lab035<br />
Lab044<br />
Lab107<br />
Lab129<br />
Lab073<br />
Lab099<br />
Lab026<br />
Lab059<br />
Lab064<br />
Lab067<br />
Lab164<br />
Lab046<br />
Lab057<br />
Lab083<br />
Lab006<br />
Lab029<br />
Lab076<br />
Lab132<br />
Lab004<br />
Lab043<br />
Lab085<br />
Lab119<br />
Lab120<br />
Lab033<br />
Lab121<br />
Lab130<br />
Lab030<br />
Lab055<br />
Lab037<br />
Lab080<br />
Lab104<br />
Lab052<br />
Lab062<br />
Lab101<br />
Lab118<br />
Lab061<br />
Lab021<br />
Lab158<br />
Lab010<br />
97.5 % Acceptable<br />
1.6 % Questionable<br />
0.8 % Unacceptable<br />
Pencycuron<br />
Median: 0.269 mg/kg<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Prochloraz<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab012<br />
Lab053<br />
Lab133<br />
Lab078<br />
Lab177<br />
Lab156<br />
Lab153<br />
Lab009<br />
Lab079<br />
Lab032<br />
Lab151<br />
Lab113<br />
Lab041<br />
Lab134<br />
Lab013<br />
Lab096<br />
Lab067<br />
Lab090<br />
Lab122<br />
Lab069<br />
Lab150<br />
Lab040<br />
Lab051<br />
Lab050<br />
Lab091<br />
Lab008<br />
Lab159<br />
Lab018<br />
Lab145<br />
Lab065<br />
Lab165<br />
Lab046<br />
Lab123<br />
Lab160<br />
Lab100<br />
Lab172<br />
Lab015<br />
Lab103<br />
Lab007<br />
Lab166<br />
Lab075<br />
Lab098<br />
Lab137<br />
Lab006<br />
Lab019<br />
Lab064<br />
Lab068<br />
Lab107<br />
Lab114<br />
Lab152<br />
Lab175<br />
Lab052<br />
Lab038<br />
Lab095<br />
Lab157<br />
Lab005<br />
Lab033<br />
Lab034<br />
Lab022<br />
Lab024<br />
Lab057<br />
Lab072<br />
Lab025<br />
Lab111<br />
Lab161<br />
Lab059<br />
Lab062<br />
Lab073<br />
Lab082<br />
Lab112<br />
Lab143<br />
Lab023<br />
Lab094<br />
Lab108<br />
Lab044<br />
Lab158<br />
Lab102<br />
Lab105<br />
Lab131<br />
Lab043<br />
Lab045<br />
Lab086<br />
Lab148<br />
Lab163<br />
Lab017<br />
Lab011<br />
Lab036<br />
Lab049<br />
Lab074<br />
Lab093<br />
Lab106<br />
Lab063<br />
Lab021<br />
Lab120<br />
Lab129<br />
Lab136<br />
Lab173<br />
Lab121<br />
Lab124<br />
Lab154<br />
Lab002<br />
Lab039<br />
Lab028<br />
Lab119<br />
Lab135<br />
Lab001<br />
Lab004<br />
Lab054<br />
Lab099<br />
Lab140<br />
Lab142<br />
Lab061<br />
Lab076<br />
Lab083<br />
Lab010<br />
Lab030<br />
Lab058<br />
Lab088<br />
Lab138<br />
Lab168<br />
Lab097<br />
Lab026<br />
Lab066<br />
Lab130<br />
Lab047<br />
Lab104<br />
Lab132<br />
Lab029<br />
Lab092<br />
Lab164<br />
Lab171<br />
Lab128<br />
Lab014<br />
Lab020<br />
Lab055<br />
Lab101<br />
Lab037<br />
Lab118<br />
Lab141<br />
Lab048<br />
Lab085<br />
Lab109<br />
Lab070<br />
Lab077<br />
Lab110<br />
Lab035<br />
Lab080<br />
89.8 % Acceptable<br />
8.2% Questionable<br />
2.0 % Unacceptable<br />
Prochloraz<br />
Median: 0.058 mg/kg<br />
* * *<br />
* False Negatives<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Procymidone<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab083<br />
Lab056<br />
Lab153<br />
Lab170<br />
Lab012<br />
Lab084<br />
Lab133<br />
Lab131<br />
Lab151<br />
Lab022<br />
Lab090<br />
Lab032<br />
Lab156<br />
Lab116<br />
Lab165<br />
Lab114<br />
Lab166<br />
Lab169<br />
Lab082<br />
Lab069<br />
Lab100<br />
Lab009<br />
Lab015<br />
Lab070<br />
Lab077<br />
Lab087<br />
Lab157<br />
Lab085<br />
Lab137<br />
Lab050<br />
Lab073<br />
Lab172<br />
Lab117<br />
Lab091<br />
Lab001<br />
Lab057<br />
Lab123<br />
Lab146<br />
Lab160<br />
Lab002<br />
Lab008<br />
Lab018<br />
Lab040<br />
Lab060<br />
Lab094<br />
Lab113<br />
Lab134<br />
Lab145<br />
Lab150<br />
Lab152<br />
Lab164<br />
Lab054<br />
Lab099<br />
Lab028<br />
Lab046<br />
Lab120<br />
Lab025<br />
Lab036<br />
Lab051<br />
Lab092<br />
Lab112<br />
Lab097<br />
Lab039<br />
Lab041<br />
Lab106<br />
Lab127<br />
Lab034<br />
Lab140<br />
Lab017<br />
Lab161<br />
Lab010<br />
Lab011<br />
Lab027<br />
Lab044<br />
Lab047<br />
Lab061<br />
Lab068<br />
Lab074<br />
Lab107<br />
Lab108<br />
Lab109<br />
Lab110<br />
Lab111<br />
Lab138<br />
Lab139<br />
Lab141<br />
Lab171<br />
Lab049<br />
Lab142<br />
Lab042<br />
Lab065<br />
Lab066<br />
Lab067<br />
Lab093<br />
Lab143<br />
Lab159<br />
Lab136<br />
Lab005<br />
Lab072<br />
Lab007<br />
Lab088<br />
Lab149<br />
Lab148<br />
Lab030<br />
Lab102<br />
Lab016<br />
Lab029<br />
Lab031<br />
Lab033<br />
Lab075<br />
Lab076<br />
Lab119<br />
Lab121<br />
Lab125<br />
Lab129<br />
Lab158<br />
Lab163<br />
Lab168<br />
Lab173<br />
Lab004<br />
Lab038<br />
Lab078<br />
Lab058<br />
Lab118<br />
Lab144<br />
Lab026<br />
Lab020<br />
Lab021<br />
Lab063<br />
Lab104<br />
Lab103<br />
Lab132<br />
Lab006<br />
Lab079<br />
Lab080<br />
Lab095<br />
Lab177<br />
Lab055<br />
Lab062<br />
Lab105<br />
Lab147<br />
Lab024<br />
Lab003<br />
Lab128<br />
Lab059<br />
Lab035<br />
Lab043<br />
Lab019<br />
Lab052<br />
Lab048<br />
Lab081<br />
Lab130<br />
Lab101<br />
Lab154<br />
Lab089<br />
Lab037<br />
Lab053<br />
Lab135<br />
Lab096<br />
Lab064<br />
Lab098<br />
Lab086<br />
Lab013<br />
95.1 % Acceptable<br />
3.1 % Questionable<br />
1.8 % Unacceptable<br />
Procymidone<br />
Median: 0.110 mg/kg<br />
* *<br />
* False Negatives<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
Lab105<br />
Lab088<br />
Lab098<br />
Lab062<br />
Lab057<br />
Lab104<br />
Lab004<br />
Lab043<br />
Lab010<br />
Lab037<br />
Lab130<br />
Lab052<br />
Lab029<br />
Lab026<br />
Lab136<br />
Lab030<br />
Lab164<br />
Lab024<br />
Lab080<br />
Lab076<br />
Lab163<br />
Lab132<br />
Lab137<br />
Lab109<br />
Lab143<br />
Lab021<br />
Lab092<br />
Lab129<br />
Lab033<br />
Lab073<br />
Lab049<br />
Lab064<br />
Lab048<br />
Lab171<br />
Lab138<br />
Lab103<br />
Lab059<br />
Lab124<br />
Lab075<br />
Lab112<br />
Lab093<br />
Lab158<br />
Lab097<br />
Lab061<br />
Lab018<br />
Lab102<br />
Lab099<br />
Lab011<br />
Lab107<br />
Lab045<br />
Lab034<br />
Lab150<br />
Lab119<br />
Lab067<br />
Lab007<br />
Lab055<br />
Lab173<br />
Lab111<br />
Lab028<br />
Lab100<br />
Lab002<br />
Lab054<br />
Lab022<br />
Lab095<br />
Lab017<br />
Lab065<br />
Lab005<br />
Lab110<br />
Lab108<br />
Lab068<br />
Lab166<br />
Lab145<br />
Lab121<br />
Lab074<br />
Lab044<br />
Lab012<br />
Lab066<br />
Lab114<br />
Lab008<br />
Lab025<br />
Lab120<br />
Lab082<br />
Lab165<br />
Lab051<br />
Lab079<br />
Lab006<br />
Lab035<br />
Lab123<br />
Lab086<br />
Lab046<br />
Lab020<br />
Lab015<br />
Lab106<br />
Lab148<br />
Lab013<br />
Lab161<br />
Lab090<br />
Lab118<br />
Lab096<br />
Lab078<br />
Lab085<br />
Lab039<br />
Lab122<br />
Lab050<br />
Lab040<br />
Lab041<br />
Lab038<br />
Lab149<br />
Lab156<br />
Lab023<br />
Lab084<br />
Lab091<br />
Lab053<br />
Lab083<br />
Lab058<br />
* *<br />
91.3 % Acceptable<br />
4.3 % Questionable<br />
4.3 % Unacceptable<br />
* False Negatives<br />
Spirodicl<strong>of</strong>en<br />
Spirodicl<strong>of</strong>en<br />
Median: 0.444 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
<strong>EURL</strong>-FV<br />
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Thiabendazole<br />
-5,0<br />
-4,0<br />
-3,0<br />
-2,0<br />
-1,0<br />
0,0<br />
1,0<br />
2,0<br />
3,0<br />
4,0<br />
5,0<br />
Lab169<br />
Lab172<br />
Lab177<br />
Lab023<br />
Lab048<br />
Lab073<br />
Lab132<br />
Lab020<br />
Lab022<br />
Lab106<br />
Lab004<br />
Lab094<br />
Lab154<br />
Lab069<br />
Lab160<br />
Lab096<br />
Lab134<br />
Lab011<br />
Lab074<br />
Lab035<br />
Lab108<br />
Lab028<br />
Lab001<br />
Lab084<br />
Lab032<br />
Lab175<br />
Lab050<br />
Lab085<br />
Lab002<br />
Lab171<br />
Lab125<br />
Lab131<br />
Lab112<br />
Lab161<br />
Lab025<br />
Lab063<br />
Lab143<br />
Lab052<br />
Lab015<br />
Lab107<br />
Lab122<br />
Lab066<br />
Lab091<br />
Lab092<br />
Lab043<br />
Lab166<br />
Lab057<br />
Lab051<br />
Lab053<br />
Lab118<br />
Lab044<br />
Lab078<br />
Lab034<br />
Lab114<br />
Lab137<br />
Lab039<br />
Lab041<br />
Lab049<br />
Lab012<br />
Lab047<br />
Lab102<br />
Lab159<br />
Lab054<br />
Lab018<br />
Lab061<br />
Lab077<br />
Lab086<br />
Lab090<br />
Lab111<br />
Lab119<br />
Lab129<br />
Lab138<br />
Lab146<br />
Lab150<br />
Lab024<br />
Lab072<br />
Lab120<br />
Lab040<br />
Lab017<br />
Lab013<br />
Lab128<br />
Lab097<br />
Lab135<br />
Lab082<br />
Lab029<br />
Lab045<br />
Lab121<br />
Lab158<br />
Lab164<br />
Lab153<br />
Lab010<br />
Lab058<br />
Lab060<br />
Lab008<br />
Lab065<br />
Lab093<br />
Lab007<br />
Lab104<br />
Lab142<br />
Lab124<br />
Lab145<br />
Lab062<br />
Lab005<br />
Lab056<br />
Lab157<br />
Lab019<br />
Lab130<br />
Lab059<br />
Lab030<br />
Lab075<br />
Lab038<br />
Lab026<br />
Lab064<br />
Lab109<br />
Lab110<br />
Lab123<br />
Lab156<br />
Lab165<br />
Lab067<br />
Lab100<br />
Lab036<br />
Lab148<br />
Lab151<br />
Lab144<br />
Lab099<br />
Lab014<br />
Lab033<br />
Lab055<br />
Lab163<br />
Lab101<br />
Lab080<br />
Lab140<br />
Lab068<br />
Lab076<br />
Lab083<br />
Lab079<br />
Lab173<br />
Lab027<br />
Lab098<br />
Lab021<br />
Lab037<br />
Lab103<br />
Lab006<br />
Lab046<br />
Lab136<br />
Lab105<br />
Lab095<br />
93.2 % Acceptable<br />
4.1 % Questionable<br />
2.7 % Unacceptable<br />
Thiabendazole<br />
Median: 1.710 mg/kg<br />
* *<br />
* False Negatives<br />
*<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
5,0<br />
4,0<br />
3,0<br />
2,0<br />
1,0<br />
0,0<br />
-1,0<br />
-2,0<br />
-3,0<br />
-4,0<br />
-5,0<br />
* * * *<br />
Lab039<br />
Lab052<br />
Lab148<br />
Lab037<br />
Lab010<br />
Lab140<br />
Lab107<br />
Lab030<br />
Lab156<br />
Lab128<br />
Lab064<br />
Lab055<br />
Lab083<br />
Lab038<br />
Lab104<br />
Lab080<br />
Lab026<br />
Lab002<br />
Lab047<br />
Lab079<br />
Lab143<br />
Lab005<br />
Lab145<br />
Lab007<br />
Lab006<br />
Lab163<br />
Lab101<br />
Lab046<br />
Lab059<br />
Lab043<br />
Lab058<br />
Lab040<br />
Lab121<br />
Lab119<br />
Lab109<br />
Lab108<br />
Lab086<br />
Lab076<br />
Lab018<br />
Lab014<br />
Lab099<br />
Lab068<br />
Lab057<br />
Lab021<br />
Lab164<br />
Lab130<br />
Lab075<br />
Lab041<br />
Lab072<br />
Lab157<br />
Lab022<br />
Lab132<br />
Lab120<br />
Lab067<br />
Lab008<br />
Lab094<br />
Lab065<br />
Lab153<br />
Lab033<br />
Lab073<br />
Lab097<br />
Lab093<br />
Lab110<br />
Lab045<br />
Lab136<br />
Lab103<br />
Lab165<br />
Lab138<br />
Lab111<br />
Lab044<br />
Lab013<br />
Lab085<br />
Lab066<br />
Lab062<br />
Lab054<br />
Lab004<br />
Lab122<br />
Lab082<br />
Lab020<br />
Lab024<br />
Lab017<br />
Lab134<br />
Lab091<br />
Lab061<br />
Lab051<br />
Lab112<br />
Lab124<br />
Lab090<br />
Lab060<br />
Lab035<br />
Lab102<br />
Lab118<br />
Lab034<br />
Lab137<br />
Lab015<br />
Lab173<br />
Lab114<br />
Lab166<br />
Lab012<br />
Lab028<br />
Lab105<br />
Lab092<br />
Lab100<br />
Lab158<br />
Lab129<br />
Lab032<br />
Lab029<br />
Lab001<br />
Lab151<br />
Lab135<br />
Lab123<br />
Lab161<br />
Lab049<br />
Lab154<br />
Lab175<br />
Lab074<br />
Lab025<br />
Lab172<br />
Lab011<br />
Lab106<br />
Lab095<br />
Lab050<br />
Lab069<br />
Lab027<br />
Lab078<br />
Lab023<br />
Lab053<br />
Lab150<br />
Lab019<br />
Lab162<br />
Lab177<br />
Lab169<br />
Lab160<br />
Lab063<br />
94.0 % Acceptable<br />
2.2 % Questionable<br />
3.7 % Unacceptable<br />
* False Negatives<br />
Thiacloprid<br />
Thiacloprid<br />
Median: 0.338 mg/kg<br />
<strong>EURL</strong>-FV<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Combined z-Scores<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV<br />
Average <strong>of</strong> Squared z-Scores<br />
2<br />
<<br />
AZ<br />
2<br />
AZ2 2 Good<br />
AZ2 AZ2 =<br />
<br />
><br />
n<br />
<br />
i<br />
=<br />
1<br />
Z<br />
i<br />
n<br />
Z<br />
3 Satisfactory<br />
i<br />
3 Unsatisfactory
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
AZ 2 Representation<br />
92 % Good 7 % Satisfactory 1 % Unsatisfactory<br />
Category A: 53 % <strong>of</strong> the EU Laboratories<br />
(86 Laboratories out <strong>of</strong> 162 EU Labs)<br />
<strong>EURL</strong>-FV<br />
EU Laboratories<br />
EUPT-FV14: 91 % Good 2 % Satisfactory 7 % Unsatisfactory<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
False Positives<br />
<strong>EURL</strong>-FV<br />
12 different laboratories reported 13<br />
pesticides as false positives<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Laboratory<br />
Code<br />
Pesticide<br />
Concentration<br />
(mg/kg)<br />
Determination<br />
Technique<br />
<strong>EURL</strong>-FV<br />
RL<br />
(mg/Kg)<br />
MRRL<br />
(mg/Kg)<br />
Lab038 Captan 0.131 GC-MSD (EI) 0.01 0,01<br />
Lab040 Endosulfan sulfate 0.013 GC-MSD (CI-) 0.001 0.01<br />
Lab041 Endosulfan sulfate 0.013 GC-MSD (CI-) 0.001 0.01<br />
Lab056 Fenitrothion 0.031 GC-NPD 0.01 0.01<br />
Lab056 Imazalil 0.028 GC-NPD 0.01 0.01<br />
Lab060 Dimethomorph 0.110 LC-MS/MS (QQQ) (ESI+) 0.01 0.01<br />
Lab073 Endosulfan sulfate 0.023 GC-MS/MS (QQQ) (EI+) 0.01 0.01<br />
Lab077<br />
Carbendazim (sum <strong>of</strong> benomyl<br />
and carbendazim expressed as<br />
carbendazim)<br />
False Positives<br />
0.040<br />
HPLC-FD<br />
Confirmation: GC-<br />
MS/MS (QQQ) (EI+)<br />
0.01 0.01<br />
Lab081 Omethoate 0.014 GC-MSD (EI) 0.02 0.003<br />
Lab114 Methiocarb sulfone 0.612 LC-MS/MS (QQQ) (ESI+) 0.01 0.01<br />
Lab128 Fludioxonil 0.123 LC-MS/MS (QQQ) 0.01 0.01<br />
Lab160 Tebuconazole 0.011<br />
LC-MS/MS (QQQ)<br />
(ESI+)<br />
0.01 0.01<br />
Lab175 Epoxiconazole 0.020 LC-MS/MS (QQQ) (ESI+) 0.01 0.01<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
GC-MS or GC-NPD<br />
Captan<br />
Carbendazim<br />
3 x Endosulfan sulfate<br />
Fenitrothion<br />
Imazalil<br />
Omethoate<br />
False Positives<br />
LC-MS/MS<br />
Carbendazim<br />
Dimethomorph<br />
Epoxiconazole<br />
Fludioxonil<br />
<strong>EURL</strong>-FV<br />
Methiocarb sulfone<br />
Tebuconazole<br />
<strong>Preliminary</strong> <strong>Results</strong>
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV<br />
Impurities <strong>of</strong> comercial formulations
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Diazinon Sulfotep<br />
0.195 ppm<br />
Spiked with diazinon<br />
<strong>EURL</strong>-FV<br />
Aprox. 0.040 ppm<br />
(NOT included in the<br />
target list)
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May GC-QQQ-MS/MS<br />
201.8>145.9<br />
237.8>145.9<br />
Blank Potato<br />
50ppb Sulfotep in Potato<br />
201.8>145.9 matrix<br />
237.8>145.9<br />
Ratio 55.1 %<br />
<strong>EURL</strong>-FV<br />
Sample EUPT-FV15_189<br />
201.8>145.9<br />
237.8>145.9<br />
Ratio 55.3 %
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
LC-QQQ-MS/MS<br />
50ppb Sulfotep in Potato matrix Sample<br />
EUPT-<br />
323.1>97.0<br />
FV15_189A<br />
323.1>115.0<br />
<strong>EURL</strong>-FV<br />
323.1>97.0<br />
Ratio: 62 % Ratio: 63 %<br />
323.1>115.0
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
100ppb sulfotep in potato matrix<br />
EUPT-FV15 sample<br />
C8H20O5P2S2<br />
GC-QTOF-MS<br />
Rt=14.198min<br />
<strong>EURL</strong>-FV<br />
Formula Exact Mass Exp.Mass Error(ppm)<br />
C8H20O5P2S2 322.0222 322.0248 -8.07<br />
C6H16O5P2S2<br />
C4H11O3P2S2<br />
293.9909 293.9908 0.34<br />
201.9882 201.9868 6.93
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
50ppb_Sulfotep_Solvent<br />
Sample_60_SM05<br />
Sample_189_FV15<br />
LC-QTOF-MS<br />
<strong>EURL</strong>-FV<br />
Sulfotep<br />
[M+H] + : 323.0300<br />
C 8H 20O 5P 2S 2
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV<br />
Contamination <strong>of</strong> comercial formulations
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
DIMETHOATE (Found<br />
in the sample at aprox. 3 ppb)<br />
<strong>EURL</strong>-FV<br />
POTATO BLANK 10 ppb POTATO SAMPLE 79A FV15 SOLVENT<br />
SRM1<br />
230>125.1<br />
SRM2<br />
230>199.1<br />
SRM1<br />
230>125.1<br />
SRM2<br />
230>199.1<br />
SRM1<br />
230>125.1<br />
SRM2<br />
230>199.1<br />
SRM1<br />
230>125.1<br />
SRM2<br />
230>199.1
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Endosulfan Alpha (concentration < 10ppb)<br />
238.8>204 5 ppb Potato FV15 189A<br />
241>206<br />
194.9>158<br />
194.9>160<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
Endosulfan Beta (concentration < 10ppb)<br />
241>206 5 ppb Potato FV15 189A<br />
238.8>204<br />
206.9>172<br />
194.9>158.9<br />
<strong>EURL</strong>-FV
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>Preliminary</strong> <strong>Results</strong><br />
<strong>EURL</strong>-FV
European Reference Laboratory - FV<br />
Standard solution exercise<br />
EUPT-FV15 pesticides standard solution in solvent<br />
Expected Delivery <strong>of</strong> the standard solutions<br />
September 2013
EUPT-T01<br />
Regulation (EU) No 1235/2012<br />
Samples coming from China<br />
European Reference Laboratory - FV<br />
Commercial tea with incurred pesticides<br />
Delivery <strong>of</strong> the test material<br />
10 th <strong>of</strong> June 2013
EUPT-FV15 <strong>Preliminary</strong> <strong>Results</strong><br />
7th May<br />
<strong>EURL</strong>-FV
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