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MODELING CHAR OXIDATION AS A FUNCTION OF PRESSURE ...

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varied between 1000 and 1500 K, with 5% to 21% oxygen in the bulk gas, resulting in<br />

average particle temperatures up to and 2100 K and burnout from 15% to 96% (daf).<br />

Approach<br />

Two injection probes, one cooled and the other uncooled, were used during the<br />

tests. Because of the large heat loss and the greater particle dispersion associated with the<br />

cooled probe, only the experiments using the uncooled probe were considered in this<br />

study. In addition, the majority of the experiments used a reaction length between 6.5 –<br />

12.5 cm while a few experiments used reaction length as short as 4 cm. Although the<br />

particles were pre-heated in the uncooled probe, there existed a short transient period in<br />

which ignition and momentum transfer (between the particle and the secondary gas)<br />

occurred. For experiments using a very short reaction length, this transition period may<br />

affect the accurate calculation of reaction rates. Therefore, the experiments with a<br />

reaction length shorter than 6 cm were not considered in this study. After the above<br />

screening, 45 experiments were modeled in this study (see Table 5).<br />

104

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