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MATERIAL SAFETY DATA SHEET

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Material Safety Data Sheet - Niobium<br />

THE REMBAR COMPANY, INC.<br />

67 Main Street, P.O. Box 67<br />

Dobbs Ferry, NY 10522<br />

<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />

Telephone: (914) 693-2620<br />

Fax: (914) 693-2247<br />

www.rembar.com<br />

Issue date: 01/20/92<br />

Supersedes: 05/23/89<br />

MSDS : | Molybdenum | Tungsten | Tantalum | Ta/W | Rhenium | Niobium |<br />

Chemical Name:<br />

Synonyms:<br />

Chemical Family:<br />

Formula:<br />

CAS #:<br />

PHYSICAL FORM:<br />

APPEARANCE & ODOR:<br />

pH:<br />

BOILING POINT:<br />

MELTING/FREEZING POINT:<br />

VAPOR PRESSURE:<br />

SOLUBILITY IN WATER:<br />

SPECIFIC GRAVITY:<br />

% VOLATILE BY WEIGHT:<br />

Niobium (Columbium)<br />

Sheet, rod, wire, tubing & other mill shapes<br />

Refractory Metal<br />

Nb (Cb)<br />

7440-03-1`<br />

PHYSICAL <strong>DATA</strong><br />

Solid<br />

Silver gray metal, Odorless<br />

Approx. 7 in aqueous suspension<br />

8900° F (4927° C)<br />

4474° F (2468° C)<br />

N/A<br />

Insoluble<br />

8.57<br />

N/A<br />

HAZARDOUS INGREDIENTS<br />

<strong>MATERIAL</strong> OSHA ACGIH<br />

Niobium (Columbium) Not established Not established<br />

http://www.rembar.com/MSDSni.htm<br />

Page 1 of 4<br />

28-Sep-06


Material Safety Data Sheet - Niobium<br />

STABILITY:<br />

HAZARDOUS<br />

POLYMERIZATION:<br />

Concentration: (%) Greater than 99%<br />

REACTIVITY <strong>DATA</strong><br />

Stable, however, powder or dust in fine size may ignite during<br />

intensive mechanical treatment.<br />

Will not occur.<br />

INCOMPATIBILITIES: Reacts violently with fluorine, chlorine and bromine trifluoride.<br />

Contact with strong oxidizers may cause fire/explosions.<br />

INSTABILITY CONDITIONS: Keep away from sparks or ignition sources.<br />

DECOMPOSITION<br />

Not established.<br />

TEMPERATURE:<br />

DECOMPOSITION<br />

Not known.<br />

PRODUCTS:<br />

FLASH POINT:<br />

AUTO-IGNITION<br />

TEMPERATURE:<br />

EXTINGUISHING<br />

MEDIA:<br />

SPECIAL FIRE<br />

FIGHTING<br />

PROCEDURES:<br />

UNUSUAL<br />

FIRE/EXPLOSION<br />

HAZARDS:<br />

ACGIH:<br />

NIOSH:<br />

OSHA:<br />

TWA:<br />

FIRE AND EXPLOSION <strong>DATA</strong><br />

Not Applicable<br />

Not established<br />

Dry powder type agents specifically designed for metal powder fires.<br />

Do not apply water to burning material. Full emergency equipment with<br />

self-contained breathing apparatus must be worn by firefighters. During a<br />

fire, irritating and toxic gases and aerosols may be generated by thermal<br />

decomposition and combustion.<br />

This product consists of pieces of metal. Dust and fumes generated from<br />

this product (through grinding, cutting, sawing, welding, sanding, etc.) may<br />

be a fire and explosion hazard when exposed to high temperatures or<br />

ignition sources. particle size and dispersion in air determine reactivity.<br />

American Conference of Governmental Industrial Hygienists<br />

National Institute for Occupational Safety and Health<br />

Occupational Safety and Health Administration<br />

Time Weighted Average<br />

HEALTH HAZARD <strong>DATA</strong><br />

ROUTES OF<br />

Inhalation, skin contact, eye contact.<br />

EXPOSURE:<br />

HUMAN EFFECTS & SYMPTOMS OF OVEREXPOSURE:<br />

ACUTE EFFECTS OF<br />

EXPOSURE:<br />

CHRONIC EFFECTS OF<br />

EXPOSURE:<br />

Material is a non-reactive solid. Mechanical irritation (i.e. abrasion) to<br />

the eyes, skin or respiratory tract may occur due to exposure to dusts<br />

formed in the mechanical treatment (i.e. cutting, sawing) of this material.<br />

None known.<br />

CARCINOGENICITY: This product is not listed by NTP, IARC or regulated as a carcinogen by<br />

OSHA.<br />

MEDICAL CONDITIONS: None known.<br />

EXPOSURE LIMITS: Although no exposure limit, in general, has been established for this<br />

product, the ACGIH-TLV for Particulates Not Otherwise Classified<br />

(PNOC) of 10 mg/m3 TWA is recommended.<br />

http://www.rembar.com/MSDSni.htm<br />

Page 2 of 4<br />

28-Sep-06


Material Safety Data Sheet - Niobium<br />

FIRST AID FOR<br />

EYES:<br />

EMERGENCY & FIRST AID PROCEDURES<br />

Flush eyes with plenty of clean water. Contact a physician if irritation is<br />

present and persists.<br />

FIRST AID FOR SKIN: Remove contaminated clothing. Wash affected areas with soap and water.<br />

Contact a Physician if irritation is present and persists..<br />

FIRST AID FOR<br />

INHALATION:<br />

FIRST AID FOR<br />

INGESTION:<br />

EYE PROTECTION<br />

REQUIREMENTS:<br />

SKIN PROTECTION<br />

REQUIREMENTS:<br />

RESPIRATOR<br />

REQUIREMENTS:<br />

VENTILATION<br />

REQUIREMENTS:<br />

ADDITIONAL<br />

PROTECTIVE<br />

MEASURES:<br />

SPILL OR LEAK<br />

PROCEDURES:<br />

WASTE DISPOSAL<br />

METHOD:<br />

TEMPERATURE (MIN/MAX):<br />

SHELF LIFE:<br />

SPECIAL SENSITIVITY:<br />

HANDLING/STORAGE<br />

PRECAUTIONS:<br />

TECHNICAL NAME:<br />

PRODUCT LABEL:<br />

Remove to fresh air.<br />

Dilute with large quantities of water and induce vomiting. Never give<br />

anything by mouth to an unconscious person. Contact a Physician.<br />

EMPLOYEE PROTECTION RECOMMENDATIONS<br />

HAZARD CLASS OR DIVISION:<br />

http://www.rembar.com/MSDSni.htm<br />

Safety glasses with side shields or goggles are recommended.<br />

Chemically resistant gloves and clothing are recommended to minimize<br />

skin contact. Employees should wash their hands and face before<br />

eating, drinking or using tobacco products.<br />

Work ambient concentrations should be monitored and if the<br />

recommended exposure limit is exceeded, a NIOSH/MSHA approved<br />

dust respirator should be worn.<br />

Use local exhaust ventilation adequate to keep exposure levels below<br />

the TLV for nuisance dust.<br />

Emergency showers and eye wash stations should be available.<br />

Educate and train employees in the safe use and handling of this<br />

product.<br />

SPILL & LEAK PROCEDURES<br />

Utilize recommended protective clothing and equipment. Spills should be<br />

swept up and placed in containers. Avoid generation of dust. If dust is<br />

generated, use appropriate respiratory protection. Spill area can be washed<br />

with water. Collect wash water for approved disposal. Keep from entering<br />

water or ground water.<br />

May be reclaimed or sold for scrap. Disposal must be in compliance with<br />

federal, state and local environmental control regulations.<br />

SPECIAL PRECAUTIONS & STORAGE <strong>DATA</strong><br />

Not established.<br />

Not established.<br />

None known.<br />

Solids require handling and storage appropriate for weight, size<br />

and shape of the material involved.<br />

SHIPPING INFORMATION<br />

Niobium metal.<br />

Niobium (Columbium) metal.<br />

DOT (HM-181) Domestic Surface: non-regulated.<br />

IMO/IMDG Ocean: non-regulated.<br />

Page 3 of 4<br />

28-Sep-06


Material Safety Data Sheet - Niobium<br />

HAZARD CLASS DIVISION NUMBER:<br />

HAZARD CLASS DIVISION NUMBER:<br />

No animal toxicity information available.<br />

OSHA STATUS:<br />

TSCA STATUS:<br />

CERCLA<br />

REPORTABLE<br />

QUANTITY:<br />

SARA TITLE III:<br />

RCRA STATUS:<br />

MSDS : | Molybdenum | Tungsten | Tantalum | Ta/W | Rhenium | Niobium |<br />

| Home | Fabrication | Technology | Contact Us | Quality | Calculator | Metal Specs |<br />

The REMBAR Company, Inc.<br />

P.O. Box 67<br />

67 Main Street<br />

Dobbs Ferry, NY 10522<br />

Tel.: (914) 693-2620<br />

FAX: (914) 693-2247<br />

ICAO/IATA Air: non-regulated.<br />

ANIMAL TOXICITY <strong>DATA</strong><br />

FEDERAL REGULATORY INFORMATION<br />

This product is hazardous under the criteria of the Federal OSHA Hazard<br />

Communication Standard 29 CFR 1910.1200.<br />

On TSCA Inventory<br />

None.<br />

SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: None.<br />

SECTION 311/312 HAZARD CATEGORIES: Fire Hazard.<br />

SECTION 313 TOXIC CHEMICALS: None.<br />

If discarded in its purchased form, this product would not be a hazardous waste<br />

either by listing or by characteristic. However, under RCRA, it is the<br />

responsibility of the product user to determine at the time of disposal, whether a<br />

material containing the product or derived from the product should be classified<br />

as a hazardous waste. (40 CFR 261.20-24).<br />

OTHER REGULATORY INFORMATION<br />

The following chemicals are specifically listed by individual states: other product specific health and<br />

safety data in other sections of the MSDS may also be applicable for state requirements. For details<br />

on your regulatory requirements you should contact the appropriate<br />

Although Rembar has attempted to provide current and accurate information herein, Rembar makes<br />

no representations regarding the accuracy or completeness of the information and assumes no<br />

liability for any loss, damage or injury of any kind which may result from or arise out of the use of or<br />

reliance on the information by any person.<br />

http://www.rembar.com/MSDSni.htm<br />

Page 4 of 4<br />

28-Sep-06

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