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GANESH BENZOPLAST LTD.

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<strong>GANESH</strong> <strong>BENZOPLAST</strong> <strong>LTD</strong>.<br />

MATERIAL SAFETY DATA SHEET<br />

PRODUCT TRADE NAME: GL 9334<br />

CAS NO: Confidential.<br />

SYNONYMS: None.<br />

GENERIC/CHEMICAL NAME: Zinc C1-C14 alkyldithiophosphate<br />

PRODUCT TYPE: Component sales.<br />

Preparation / Revision Date : March 2, 2002<br />

Transportation Emergency Phone no. : 91 22 2850 2096<br />

MSDS NO. : 02032002-ANOX-921<br />

Name and Address of Manufaturer: Ganesh Benzoplast Limited,<br />

Ganesh House, Gr floor. A-1/A-2 Gurudutt<br />

CHS. Near Jankalyan bank, J B Nagar, Andheri<br />

(E) Mumbai 400 059. INDIA<br />

NFPA CODE: Health: 3 Fire: 1 Reactivity: 1<br />

HMIS CODE: Health: 3 Fire: 1 Reactivity: 1<br />

PRINCIPAL HAZARDS: DANGER<br />

- CAUSES SEVERE EYE IRRITATION. RISK OF IRREVERSIBLE<br />

EYE DAMAGE.<br />

- MAY CAUSE SKIN IRRITATION.<br />

----------------------------------------------------------------------<br />

SECTION 1 - HAZARDOUS INGREDIENTS<br />

----------------------------------------------------------------------<br />

This material is not known to contain greater than 0.1% of any carcinogen<br />

required to be listed under the OSHA Hazard Communication Standard (29CFR<br />

1910.1200). - From 80 to 90 percent Zinc C1-C14 alkyldithiophosphate<br />

CAS#68649-42-3; - Please note that the chemical identity of some or all of<br />

the above hazardous ingredients is confidential business information and is<br />

being withheld as permitted by 29CFR 1910.1200 and various State Right to<br />

Know Laws.<br />

----------------------------------------------------------------------<br />

SECTION 2 - FIRE AND EXPLOSION HAZARDS<br />

----------------------------------------------------------------------<br />

FLASH POINT (Minimum): 101 Deg C 120 Deg F (PMCC)<br />

UPPER FLAMMABLE LIMIT: Not Determined.<br />

LOWER FLAMMABLE LIMIT: Not Determined.<br />

EXTINGUISHING MEDIA: CO2, dry chemical, alcohol foam. Water<br />

can be used to cool and protect exposed material.<br />

SPECIAL FIREFIGHTING PROCEDURES: Recommend wearing self-contained<br />

breathing apparatus. Water may cause splattering.<br />

UNUSUAL FIRE & EXPLOSION HAZARDS: Toxic fumes, gases or vapors may evolve<br />

on burning.<br />

----------------------------------------------------------------------<br />

SECTION 3 - HEALTH HAZARD DATA<br />

----------------------------------------------------------------------<br />

ORAL TOXICITY: The LD50 in rats is between 2000 mg/kg and 5000 mg/kg.<br />

Based on data from similar materials.<br />

EYE IRRITATION: Severe eye irritant. Risk of irreversible damage to<br />

eyes. Based on actual data.<br />

SKIN IRRITATION: May cause skin irritation. Based on actual data.<br />

Address: Ganesh House,A-1 / A-2, Gurudutt CHS Ltd., Om Nagar, J.B Nagar, Andheri (E), Mumbai - 400059.<br />

INDIA Direct Phone : +91 22 2839 0719 Fax : +91 22 2839 0715<br />

Email : export@ganeshgroup.com Website : www.ganeshgroup.com<br />

1


<strong>GANESH</strong> <strong>BENZOPLAST</strong> <strong>LTD</strong>.<br />

DERMAL TOXICITY: The LD50 in rabbits is > 2000 mg/Kg. Based on<br />

similar materials.<br />

INHALATION TOXICITY: No data available to indicate product or components<br />

may be a toxic inhalation hazard.<br />

RESPIRATORY IRRITATION: If material is misted or if vapors are<br />

generated from heating, exposure may cause irritation of mucous membranes<br />

and the upper respiratory tract similar to that observed with mineral<br />

oil. Based on data from components or similar materials. Under good<br />

industrial hygiene practices where all exposure limits are observed,<br />

respiratory irritation should not be a problem.<br />

DERMAL SENSITIZATION: No data available to indicate product or components<br />

may be a skin sensitizer.<br />

INHALATION SENSITIZATION: No data available to indicate product or<br />

components may be respiratory sensitizers.<br />

CHRONIC TOXICITY: No data available to indicate product or components<br />

present at greater than 1% are chronic health hazards.<br />

CARCINOGENICITY: No data available to indicate any components present at<br />

greater than 0.1% may present a carcinogenic hazard.<br />

MUTAGENICITY: No data available to indicate product or any components<br />

present at greater than 0.1% are mutagenic or genotoxic.<br />

REPRODUCTIVE TOXICITY: No data available to indicate either product<br />

or components present at greater than 0.1% that may cause reproductive<br />

toxicity.<br />

TERATOGENICITY: No data available to indicate product or any components<br />

contained at greater than 0.1% may cause birth defects. OTHER: No other<br />

health hazards known. EXPOSURE LIMITS: Contains mineral oil. Under<br />

conditions which may generate mists, observe the OSHA PEL of 5 mg per<br />

cubic meter, ACGIH STEL of 10 mg per cubic meter.<br />

SKIN: Wash with soap and water. Remove contaminated clothing. Get<br />

medical attention if irritation develops. Launder contaminated<br />

clothing before reuse.<br />

EYE: Flush immediately with water for at least 15 minutes.<br />

Get immediate medical attention.<br />

INHALATION: Remove exposed person to fresh air if adverse effects<br />

are observed.<br />

ORAL: DO NOT INDUCE VOMITING. If conscious, give 2 glasses of<br />

water. Get immediate medical attention.<br />

ADDITIONAL: Note to physician: Treat symptomatically.<br />

----------------------------------------------------------------------<br />

SECTION 4 - SPECIAL PROTECTION INFORMATION<br />

----------------------------------------------------------------------<br />

VENTILATION PROCEDURE: Use local exhaust ventilation to control mists<br />

or vapors.<br />

GLOVES PROTECTION: Neoprene.<br />

EYE PROTECTION: Faceshield.<br />

RESPIRATORY PROTECTION: Use NIOSH/MSHA approved full face respirator<br />

with a combination organic vapor and dust/mist cartridge if the<br />

recommended exposure limit is exceeded. Use self-contained breathing<br />

apparatus for entry into confined space, for other poorly ventilated areas<br />

and for large spill clean-up sites.<br />

CLOTHING RECOMMENDATION: Long sleeve shirt is recommended.<br />

Launder contaminated clothing before reuse.<br />

----------------------------------------------------------------------<br />

SECTION 5 - PHYSICAL DATA<br />

----------------------------------------------------------------------<br />

VAPOR PRESSURE: Not Determined.<br />

Address: Ganesh House,A-1 / A-2, Gurudutt CHS Ltd., Om Nagar, J.B Nagar, Andheri (E), Mumbai - 400059.<br />

INDIA Direct Phone : +91 22 2839 0719 Fax : +91 22 2839 0715<br />

Email : export@ganeshgroup.com Website : www.ganeshgroup.com<br />

2


<strong>GANESH</strong> <strong>BENZOPLAST</strong> <strong>LTD</strong>.<br />

PH: Not Determined.<br />

SPECIFIC GRAVITY: 1.12 at 15.6 Deg C<br />

WATER SOLUBILITY: Insoluble.<br />

PERCENT VOLATILE: Unknown.<br />

VAPOR DENSITY: Not Determined.<br />

EVAPORATION RATE: Not Determined.<br />

ODOR: Strong<br />

APPEARANCE: Medium dark liquid<br />

VISCOSITY: 270 Centistokes at 40 Deg C<br />

11.4 Centistokes at 100 Deg C<br />

ODOR THRESHOLD: Unknown.<br />

----------------------------------------------------------------------<br />

SECTION 6 - STABILITY<br />

----------------------------------------------------------------------<br />

STABILITY: Material can become unstable at elevated<br />

temperatures and pressures.<br />

INCOMPATIBILITY: Acids.<br />

POLYMERIZATION: Will not occur.<br />

THERMAL DECOMPOSITION: Smoke, carbon monoxide, aldehydes and other<br />

products of incomplete combustion. Hydrogen sulfide and alkyl<br />

mercaptans and sulfides may also be released. Under combustion<br />

conditions, oxides of the following elements will be formed: Phosphorus,<br />

Sulfur, Zinc.<br />

----------------------------------------------------------------------<br />

SECTION 7 - SPILL OR LEAK PROCEDURES<br />

----------------------------------------------------------------------<br />

SPILL PROCEDURES: Personal Protective Equipment must be worn, see<br />

Special Protection Information Section for PPE recommendations.<br />

Ventilate area if spilled in confined space or other poorly ventilated<br />

areas.Prevent entry into sewers and waterways. Pick up free liquid for<br />

recycle and/or disposal if can be accomplished safely with explosion proof<br />

equipment. Residual liquid can be absorbed on inert material.Check under<br />

Transportation and Labeling (DOT/CERCLA) and Other Regulatory<br />

Information Section (SARA) for hazardous substances to determine<br />

regulatory reporting requirements for spills.<br />

WASTE DISPOSAL: Material, if discarded, is not expected to be<br />

a characteristic hazardous waste under RCRA. Waste management should be<br />

in compliance with federal, state, and local laws.<br />

----------------------------------------------------------------------<br />

SECTION 8 - SPECIAL PRECAUTIONS<br />

----------------------------------------------------------------------<br />

SPECIAL PRECAUTIONS: Keep containers closed when not in use.<br />

Handling temperatures should not exceed 140 deg F (60 deg C). Odorous<br />

and toxic fumes may form from the decomposition of this product if stored<br />

at temperatures in excess of 113 deg F (45 deg C) for extended<br />

periods of time or if heat sources in excess of 250 deg F (121 deg C) are<br />

used. Wash thoroughly after handling. Launder contaminated clothing<br />

before reuse. Empty container contains product residue which may<br />

exhibit hazards of product.<br />

----------------------------------------------------------------------<br />

SECTION 9 - TRANSPORTATION AND LABELING<br />

----------------------------------------------------------------------<br />

U.S.DOT BULK SHIPPING DESCRIPTION: Not applicable.<br />

U.S.DOT NON-BULK SHIPPING DESCRIPTION: Not applicable.<br />

IMDG SHIPPING DESCRIPTION: Not applicable.<br />

ICAO SHIPPING DESCRIPTION: Not applicable.<br />

Address: Ganesh House,A-1 / A-2, Gurudutt CHS Ltd., Om Nagar, J.B Nagar, Andheri (E), Mumbai - 400059.<br />

INDIA Direct Phone : +91 22 2839 0719 Fax : +91 22 2839 0715<br />

Email : export@ganeshgroup.com Website : www.ganeshgroup.com<br />

3


<strong>GANESH</strong> <strong>BENZOPLAST</strong> <strong>LTD</strong>.<br />

ADR/RID HAZARD CLASS: Not applicable.<br />

CERCLA HAZARDOUS SUBSTANCES: None known.<br />

PRECAUTIONARY LABELS: DANGER<br />

- CAUSES SEVERE EYE IRRITATION. RISK OF<br />

IRREVERSIBLE EYE DAMAGE.<br />

- MAY CAUSE SKIN IRRITATION.<br />

----------------------------------------------------------------------<br />

SECTION 10 - OTHER REGULATORY INFORMATION<br />

----------------------------------------------------------------------<br />

U.S. TSCA INVENTORY: All components of this material are on the US<br />

TSCA Inventory.<br />

OTHER TSCA REG.: None known.<br />

EEC EINECS: All components are in compliance with the EEC<br />

Sixth Amendment Directive 79/ 831.<br />

JAPAN MITI: All components have MITI and MOL numbers in Japan.<br />

AUSTRALIA: All components are in compliance with<br />

chemical notification requirements in Australia.<br />

CANADA: All components are in compliance with the<br />

Canadian Environmental Protection Act.<br />

AUSTRIA: All components are in compliance with the<br />

Austrian Chemical Laws.<br />

SWITZERLAND: All components are in compliance with<br />

the Environmentally Hazardous Substances Ordinance in Switzerland.<br />

SARA EXT. HAZ. SUBST.: This product does not contain greater than 1.0%<br />

of any chemical substance on the SARA Extremely<br />

Hazardous Substances list.<br />

SARA SECTION 313: From 80 to 90 percent, Zinc compounds; contains<br />

11.2% as Zn.<br />

CAL. PROP. 65: Call for further information concerning the status of<br />

this product under California Proposition 65.<br />

----------------------------------------------------------------------<br />

THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED<br />

TO BE DEPENDABLE AND IS ACCURATE TO THE BEST OF THE <strong>GANESH</strong> <strong>BENZOPLAST</strong> <strong>LTD</strong><br />

KNOWLEDGE; HOWEVER, THE <strong>GANESH</strong> <strong>BENZOPLAST</strong> <strong>LTD</strong> MAKES NO WARRANTY WHATSOVER,<br />

EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR THE PARTICULAR<br />

PURPOSE, REGARDING THE ACCURACY OF SUCH DATA OR THE RESULTS TO BE OBTAINED<br />

FROM THE USE THEREOF. THE <strong>GANESH</strong> <strong>BENZOPLAST</strong> <strong>LTD</strong> ASSUMES NO RESPONSIBILITY<br />

FOR THE INJURY TO RECIPIENT OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY<br />

PROPERTY AND RECIPIENT ASSUMES ALL SUCH RISK.<br />

Address: Ganesh House,A-1 / A-2, Gurudutt CHS Ltd., Om Nagar, J.B Nagar, Andheri (E), Mumbai - 400059.<br />

INDIA Direct Phone : +91 22 2839 0719 Fax : +91 22 2839 0715<br />

Email : export@ganeshgroup.com Website : www.ganeshgroup.com<br />

4

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