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Proposed New Tesco Store<br />

Wallneuk Road<br />

Paisley, <strong>Renfrewshire</strong><br />

Revised Contaminated Land Generic<br />

Quantitative Risk Assessment


Goodson Associates<br />

53 Melville Street<br />

Edinburgh<br />

EH3 7HL<br />

Email: admin@goodsons.com<br />

Web: www.goodsons.com<br />

Tel: 0131 226 2044<br />

Fax: 0131 226 3107<br />

Proposed New Tesco Store<br />

Wallneuk Road<br />

Paisley, <strong>Renfrewshire</strong><br />

Revised Contaminated Land Generic<br />

Quantitative Risk Assessment<br />

Client: Tesco Stores Limited<br />

Date: June 2011<br />

Ref: 9692


Report<br />

Table of Contents<br />

1 Objective 1<br />

2 Preliminary Conceptual Site Model 1<br />

3 Generic Risk Assessment 3<br />

4 Final Risk Assessment/ Revised CSM 10<br />

5 Conclusions 15<br />

List of Tables<br />

Table 1 Preliminary Conceptual Site Model Summary<br />

Table 2 Total Soil Concentrations Human Health<br />

Table 3 Leachable Soil Concentrations<br />

Table 4 Total Soil Concentrations Phytotoxic Risk<br />

Table 5 Revised Conceptual Site Model Summary<br />

Appendices<br />

Appendix A CLEA v1.06 SGV/GAC Settings & Results<br />

Appendix B Laboratory Results Statistical Analysis<br />

Appendix C UKWIR 10/WM/03/21


Risk Assessment<br />

1.0 Objective<br />

Proposed New Tesco Store, Wallneuk Road, Paisley, <strong>Renfrewshire</strong>: 9692<br />

The objective of this report is to present the results of a revised updated generic<br />

(commercial/industrial) risk assessment undertaken on thirty four soil and leachate samples<br />

and: five groundwater samples obtained from a proposed new Tesco store at Wallneuk<br />

Road, Paisley <strong>Renfrewshire</strong>. This report provides an update to the previously compiled<br />

generic risk assessment report 1 in light of changes made to the CLEA modelling software<br />

and assessment of risk to water supply pipe placement since May 2009. The extent and<br />

nature of potential on site contamination and an evaluation of the potential risk(s) to<br />

development within the context of “suitability of use” is provided in this report.<br />

The history, current site setting, recent site investigation and development proposal details<br />

are contained within the Goodson Associates (Geotechnical and Environmental Assessment<br />

Report) of which this report is presented as (Appendix 8).<br />

2.0 Preliminary Conceptual Site Model<br />

The rationale, context and regulatory requirements for contamination assessment and<br />

methodology are provided in sections 2.0 and 8.0 of the geotechnical and environmental<br />

assessment report in conjunction with section 3.0 of this report. Summarised in Table 1<br />

below are the key components of the derived preliminary conceptual site model.<br />

2.1 Pollutant Linkage Assessment<br />

The key preliminary potential complete SPR linkages have been identified and rationalised in<br />

the context of the plausible risks upon redevelopment of the site. The full relationships<br />

between the identified plausible linkages and an assignment of categorised risk are provided<br />

in section 8.0 of the May 2009 geotechnical and environmental assessment report and<br />

graphically as (Appendix 9) of the September 2008 preliminary environmental assessment<br />

report.<br />

1 Proposed New Tesco Store at Wallneuk Road Paisley- Goodson Associates Contaminated Land Generic Quantitative Risk Assessment<br />

-1-


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

Table 1: Conceptual Site Model Summary<br />

Potential Risk<br />

Low Medium High<br />

Proposed Commercial Retail Development, Wallneuk Road, Paisley, <strong>Renfrewshire</strong><br />

Source(s)<br />

Pathways<br />

Receptors<br />

ON SITE:<br />

Historical Iron Foundry and<br />

engineering works, former<br />

industrial buildings and<br />

processes<br />

Made ground<br />

Generation and migration of<br />

ground gas- with made ground<br />

and potential underlying<br />

shallow coal workings<br />

Volatilisation and migration of<br />

organic compounds<br />

OFF SITE:<br />

Former Engineering works and<br />

mineral extraction activities<br />

Dermal contact/Dust Inhalation<br />

of exposed soils<br />

Dust dispersion during<br />

construction<br />

premises<br />

to adjacent<br />

Leaching of mobile phase<br />

aqueous phase contaminants<br />

to underlying perched<br />

groundwater and Surface run<br />

off to adjacent watercourse(s)<br />

Migration of gases and vapours<br />

into sub floor voids<br />

Surface run-off of impacted<br />

groundwater<br />

receptors<br />

to off site<br />

Construction workers<br />

End users<br />

Off site workers<br />

Buildings and services<br />

Water Environment<br />

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Comments<br />

The area within the site boundary has been<br />

utilised for numerous industrial processes, most<br />

prominent being Iron Foundry and steel works.<br />

Other processes warehousing and engineering<br />

works may also have impacted the site. There is<br />

the potential for viable pollutant linkages to exist<br />

at the site the current extent and nature of which<br />

are unknown, but may, if disturbed through<br />

construction work have a deleterious impact on<br />

(humans) the water environment and<br />

Buildings/structures .<br />

Potential for construction workers and end users<br />

to come in contact with exposed/disturbed soils<br />

during development.<br />

Good working practises should minimise dust<br />

generation and dispersion<br />

Potential of leaching of mobile phase<br />

contaminants into under lying groundwater<br />

resources or surface run-off. Surface tarmac and<br />

glacial soils reduce this risk.<br />

Potential of ground gas generation within made<br />

ground deposits and from underlying shallow<br />

mineral workings. Potential for vapour generation<br />

from potential hydrocarbon concentration within<br />

sub surface soils<br />

The existing drainage system mitigates to some<br />

extent uncontrolled surface run-off<br />

There is the potential for complete pollutant<br />

linkages to exist at this site, which could<br />

potentially have adverse impacts on sensitive<br />

receptors.<br />

Construction workers and buildings and services<br />

may be impacted by potentially contaminated<br />

soils.<br />

An evaluation is necessary to quantify and assign<br />

any risk(s) posed to the development considering<br />

the current site land use<br />

RISK CATEGORY RATING (CLR6)<br />

A MEDIUM Risk rating (Category 3) has been assigned to the site given the previous site land uses and the likely potential for<br />

contaminants to exist within the sub surface soils. There is likelihood for complete plausible pollutant linkages to exist at the<br />

site. These are likely to be prevalent during construction.<br />

The site is considered “suitable for use” in its current setting and context. However, during site preparation and construction<br />

works, there is a pathway to exposure to potentially deleterious levels of contaminants. Sensitive receptors may be impacted<br />

by movement (and/or) disturbance of contaminated soils. It is in this context that the site has been assigned a Medium risk<br />

rating. Due to the nature of the underlying soils and potential for contamination to exist, and the nature of the proposed<br />

development, the site requires further investigation to be deemed “Suitable for Use”.<br />

Upon completion of the development and the likely removal of exposure pathways and therefore incomplete pollutant<br />

linkage, the risks to the development and wider environment are likely to be Low.


3.0 Generic Risk Assessment<br />

Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

Following completion of the preliminary risk assessment (Tier 1 identification of pollutant<br />

linkages, summarised in (Section 8.0 of the May 2009 Geotechnical and Environmental<br />

Assessment Report), in order to assess the significance of the limited identified pollutant<br />

linkages, samples were obtained from the (November 2008) site investigation and a revised<br />

generic quantitative risk assessment conducted on data obtained from laboratory and field<br />

results (Tier II).<br />

This involves the screening of the reported concentrations of chemical contaminants in soil,<br />

groundwater and surface water (where applicable) against Generic Assessment Criteria<br />

(GAC). Separate GACs are available for assessing risks to human health, buildings and<br />

services, the water environment and gas generation risks. If any contaminants “fail” the<br />

assessment criteria then they are considered to potentially pose a risk to either (The Water<br />

Environment) or human health, or buildings and services via the relevant pollutant linkages<br />

identified and therefore either mitigation measures are required or more detailed risk<br />

assessment should be carried out.<br />

The GACs/SGV’s adopted for this Tier 2 assessment and the rationale behind their selection<br />

are detailed below.<br />

3.1 Soil- Human Health<br />

In the first instance, published (GACs) or published Soil Guideline Values (SGVs) which are<br />

currently under development in line with the release of the new CLEA v1.062’3 assessment<br />

model (which was released in December 2009) are adopted as the screening criteria. The<br />

new changes to the model (revisions made over CLEA v1.04 are presented on the EA<br />

website4 and the CLEA Model handbook (pp2-3). At the time of writing, new SGVs have<br />

been published (available to download as PDF from the EA website5) for arsenic, cadmium,<br />

mercury, nickel, selenium, phenols, dioxins, furans, dioxin like PCB’s and BTEX compounds<br />

in conjunction with updated Toxicological data. New values are due imminently for other<br />

key compounds during the coming months.6 SGVs/GACs are defined within <strong>documents</strong><br />

SC0500021/SR27 and SC0500021/SR38 (which replace CLR9 and CLR10) as concentrations<br />

of contaminants in soil that, if exceeded, may be indicative of unacceptable risks to human<br />

health. In this case, since the proposed land use for this site is a commercial retail<br />

development an appropriate application of the “model” is required), the CSM developed for<br />

this site matches the CSM derived using CLEA v1.06 site assessment criteria (SGVs/GACs)<br />

with a reasonable degree of conservativeness. SGVs/GACs have been selected on the basis<br />

of the proposed end use (with conservatism built-in) and additional site specific derived<br />

values (within the CLEA Model). These are considered to be sufficiently conservative to<br />

protect other sensitive receptors within and beyond a typical commercial/industrial<br />

development.<br />

As not all chemicals reported at the site have a published SGV/GAC, alternative sources of<br />

health based criteria have been used as the GAC.<br />

2 CLEA Software (v1.05) Science Report-(SC050021/SR4) September 2009<br />

3 http://www.environment-agency.gov.uk/research/planning/40397.aspx<br />

4 http://www.environment-agency.gov.uk/research/planning/33714.aspx<br />

5 http://www.environment-agency.gov.uk/research/planning/64015.aspx<br />

6 http://www.environment-agency.gov.uk/research/planning/33722.aspx<br />

7 Environment Agency-Human Health Toxicological Assessment of Contaminants in Soil (Science Report SC0500021/SR2) Final January 2009<br />

8 Environment Agency-Updated Technical Background to the CLEA Model (Science Report SC0500021/SR3) Final January 2009<br />

-3-


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

3.1 Soil- Human Health (continued)<br />

Given the limited number of available published SGV/GAC’s available, where an appropriate<br />

value is unavailable “derived values” have been generated following the approaches<br />

recommended in SC0500021/SR2 SC0500021/SR3 and associated material (CLEA v1.05<br />

Handbook and software “the Model”) and are therefore based on health criteria values<br />

selected following the hierarchy of preferred sources described in SC0500021/SR2.<br />

Physio-chemical input parameters for the CLEA model were selected from Environment<br />

Agency/Defra publications, where available, and additional authoritative data<br />

sources9’10’11’12.<br />

The newly derived screening criteria have been modelled by DAM using the new CLEA<br />

v1.06 assessment model (in Basic Mode-Generic Assessment Criteria-<br />

Commercial/Industrial) and the outputs (the settings and results) provided as supporting<br />

material in (Appendix A). The proposed development is a commercial retail store. In respect<br />

of this, the derived GAC’s have been modelled on a conservative approach with a<br />

commercial/industrial land use scenario applied (Warehouse post 1970) and the soil medium<br />

selected as SAND. This was selected as an appropriate conservative soil medium considering<br />

the insitu heterogeneous surface fill deposits (Made Ground) tarmac, ash, slag, and fused iron<br />

slag.<br />

A recent document13 published by The Environment Agency (EA) and based on the Total<br />

Petroleum Hydrocarbon Criteria Working Group (TPHCWG) provides the framework for<br />

evaluation of health risks from petroleum hydrocarbons in soil. The approach in the UK has<br />

been developed as part of the Environment Agency’s Contaminated Land Exposure<br />

Assessment model (CLEA). This model assesses the fate and transport dynamics of key<br />

aromatic and aliphatic petroleum fractions and through toxicological review, provides an<br />

appropriate Soil Guideline Value (SGV) conservative of Human Health. This framework is<br />

provided on pp9 and Figure 4.1 of the document. Assessment criteria for the evaluation of<br />

potential risk from petroleum hydrocarbons are derived and calculated by DAM using CLEA<br />

v1.06 and SC0500021/SR714.<br />

Assessment of polycyclic aromatic hydrocarbon (PAH) fractions are based on physiochemical<br />

parameters for selected principal risk driver compounds: naphthalene, benzo-apyrene,<br />

1,2:5,6 dibenzanthracene and fluorene. These are considered in terms of the most<br />

prevalent human health risk factors and have authoritative published data15 on chronic and<br />

acute exposure and interactions in the environment.<br />

At this stage, with ongoing new SGV development, there is limited value to be gained in<br />

determining Health Criteria Values (HCV’s) given that new SGVs and toxicological data are<br />

due to be published throughout 2011.<br />

9 CRC Handbook of Chemistry and Physics, IUPAC-NIST Solubility Series and US Environmental Protection Agency.<br />

10 ATSDR (1985 onwards) Toxicity Profiles – Various. US Department of Health and Human Services, Public Health Service, Agency for Toxic Substances and Disease Registry.<br />

11 Environment Agency (2003) Review of Fate and Transport of Selected Contaminants in the Soil Environment. Draft Technical Report P5-079/TR1, September 2003. Environment<br />

Agency, Bristol.<br />

12 USEPA (1996) Soil Screening Guidance: Technical Background Document – 2nd Edition. United States Environment Protection Agency – Office of Solid Waste and Emergency<br />

Response EPA/540/R95/128.<br />

13 The UK Approach for Evaluating Human Health Risks from Petroleum Hydrocarbons in Soils (Report P5-080/TR3) Environment Agency February 2005<br />

14 Compilation of Data for Priority Organic Pollutants for Derivation of Soil Guidelines Values<br />

15 Total Petroleum Hydrocarbons Working Group (TPHCWG) Vol 1-5 1997<br />

-4-


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

3.1 Soil- Human Health (continued)<br />

Following the withdrawal of CLR7 and adopting the accepted best authoritative guidance<br />

published by CL:AIRE16, a statistical representation of the likely contamination value of an<br />

individual contaminant can be calculated using the Mean Value Test. In assessing the<br />

significance of soil contamination a key assumption is that the receptor will tend towards an<br />

average exposure, which is related to both the contaminant profile at the site and receptor<br />

habits.<br />

In other words, at a typical site that has a spread of contaminant concentrations, over the<br />

lifetime of exposure, a receptor is expected to wander randomly over the site, thus being<br />

exposed at one moment to a higher concentration and the next moment to a lower<br />

concentration.<br />

Thus, the most appropriate Representative Contaminant Concentration (RCC) is the<br />

average. However, to account for uncertainties, CL:AIRE with caveats17recommends the<br />

use of the 95% upper confidence limit of the arithmetic mean (UCL) as the RCC.<br />

The RCC is then compared to the published or derived SGV/GAC and a pass or fail assigned<br />

to the particular contaminant. Should a small sample set be obtained from a site (normally<br />


Contaminant<br />

Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

Table 2: Total Soil Concentrations-Human Health-Commercial/Industrial<br />

Assessment<br />

Criteria mg/Kg<br />

pH 5-9<br />

Source<br />

BRE<br />

SD1(2005)<br />

-6-<br />

Max<br />

Conc<br />

mg/Kg<br />

Min<br />

Conc<br />

mg/Kg<br />

Location of<br />

Max Value<br />

UCL/RCC or<br />

MAX Value<br />

PASS/FAIL<br />

7.97 6.18 BH9 (1.0m) 6.16 LCL PASS<br />

Arsenic 640 SGV 2009 103.6


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

3.2 Leachable Soil Concentrations<br />

Fourteen samples from the November 2008 site investigation were scheduled for NRA<br />

(10:1) leachate analysis to determine the potential of total soil contaminants to enter the<br />

liquid phase, thus providing a pathway to contaminate ground water resources. Summarised<br />

in Table 3, are the leachable soil concentrations compared to applicable screening criteria19.<br />

Contaminant<br />

Assessment<br />

Criteria µg/l<br />

Table 3: Leachable Soil Concentrations<br />

Source<br />

19 A hierarchal approach is used to assess the significance of contamination and published UK Drinking Water standards and Environmental Quality Standards (EQS) are referenced.<br />

The more stringent of either the EQS or UK DWS is applied with consideration of the most sensitive receptor. In Scotland the Water Supply (Water Quality Scotland Regulations<br />

2001) has been used as the UK DWS for comparison. Other criteria including EQS, EU DWS and World Health were obtained from Appendix 8 of Hydrogeological Risk Assessment<br />

for Landfills (Environment Agency 2004)<br />

-7-<br />

Detected<br />

Above MDL Max<br />

Concentra<br />

tion µg/l<br />

Location of<br />

Max Value<br />

No Over<br />

Assessment<br />

Criteria<br />

Arsenic 10 UK DWS (Scotland) x N/A N/A 0<br />

Cadmium 5 UK DWS (Scotland) x N/A N/A 0<br />

Chromium 5-250 EQS Freshwater x N/A N/A 0<br />

Lead 25 UK DWS (Scotland) X N/A N/A 0<br />

Mercury 1 UK DWS (Scotland) X N/A N/A 0<br />

Selenium 10 UK DWS (Scotland) X N/A N/A 0<br />

Copper 1-28 EQS Freshwater X N/A N/A 0<br />

Nickel 20 UK DWS (Scotland) (1) 19 BH13 (1.0m) 0<br />

Zinc 8-500 EQS Freshwater (14) 91 BH6 (1.0m) 0<br />

Phenol 0.5 UK DWS (Scotland) X N/A N/A 0<br />

Free Cyanide 50 UK DWS (Scotland) N/S N/A N/A 0<br />

Sulphate 250 UK DWS (Scotland) (14) 64 BH9 (1.0m) 0<br />

Nitrate (NO3) 50 UK DWS (Scotland) (14) 19 BH8 (1.0m) 0<br />

Total TPH 10 UK DWS (Scotland) X N/A N/A 0<br />

Total PAH 0.1 (Total) UK DWS (Scotland) N/S N/S N/S N/S<br />

Pesticide Suite<br />

(OP-SP)<br />

Compounds<br />

0.5 (Total)<br />

0.1 individual<br />

species<br />

UK DWS (Scotland) N/S N/S N/S N/S


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

3.3 Total Soil Concentrations Phytotoxic Risk<br />

No specific guidelines values have been published when assessing the risks to plants,<br />

property or crops from contaminants in soils. A Soils Code 20 has been published in<br />

accordance with current legislation21on maximum permissible concentrations of potentially<br />

phytotoxic elements in sewage sludge applied to land for crop cultivation, which can be used<br />

in the context of assessing risk to plants from contaminants in soils.<br />

Presented in Table 4, are the maximum contaminant soil concentrations compared to the<br />

DEFRA guidelines.<br />

Contaminant<br />

Table 4: Total Soil Concentrations Phytotoxic Risk<br />

Assessment<br />

Criteria<br />

mg/Kg<br />

Arsenic 50<br />

Cadmium 3<br />

Chromium 400<br />

Lead 300<br />

Mercury 1<br />

Selenium 3<br />

Copper 135<br />

Nickel 75<br />

Zinc 200<br />

Source<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

DEFRA<br />

Guidance<br />

Observing the data from Table 4, it is noted that there are exceedances recorded for<br />

arsenic, mercury and nickel at locations distributed across the site. The values obtained are<br />

likely to be reflective of the typical heterogeneous nature of made ground deposits and the<br />

spatial variance often encountered at such sites. It should be noted that values for chromium,<br />

lead and copper include BH12 (an identified potential “hotspot”) given the elevated values<br />

significantly above the mean.<br />

In relation to the development proposal, (retail store with car parking, PFS and access<br />

roadways) which effectively creates a barrier to potential underlying contaminants and that<br />

soft landscaping is likely on (boundaries only) there are no further considerations deemed<br />

necessary with respect to phytotoxic risk(s).<br />

20 Ministry of Agriculture Fisheries (1998) Now DEFRA<br />

21 Sludge (Use in Agriculture) Regulations 1999 (as amended) which implement EC <strong>Council</strong> Directive 86/278<br />

-8-<br />

Maximum<br />

Concentration<br />

(UCL/RCC)<br />

mg/Kg<br />

Location of Max Value<br />

No Over<br />

Assessment<br />

Criteria<br />

103.6 MAX BH12 (1.0m) 1<br />

3.0 (RCC) Site Wide 0<br />

351.3 (RCC)<br />

Including BH12<br />

93.7 (RCC)<br />

Including BH12<br />

Site Wide<br />

Site Wide<br />

27.3 MAX BH11 (1.0m) 7<br />


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

3.4 Risks to Buildings/Services (Water Supply Pipes)<br />

When considering the specification/provision of construction materials relating to concrete<br />

and water supply pipes to be used in areas of contaminated land the following parameters<br />

should be considered:<br />

The pH/acidity of the soil and its potential aggressive behaviour.<br />

The concentration of toxic metals.<br />

Levels of sulphates and sulphides.<br />

Concentrations of organic compounds including hydrocarbons<br />

At the time of writing it is understood that the WRAS guidelines have been withdrawn 22 and<br />

are intended to be superseded by UKWIR document (Guidance for the selection of water<br />

pipes to be used in brownfield sites 23). This document provides a risk assessment based<br />

approach for the derivation of guideline parameters and applies updated procedures and<br />

technical background information which parallels CLEA v 1.06. As far as it is known, this<br />

document is currently under consultation and review by industry professionals with<br />

responses/comments due by mid end of May. We understand that Anglian Water have<br />

produced a document 24 that provides a review of the current UKWIR document and a<br />

discussion with regard to the implementation of the document recommendations.<br />

Correspondence with Scottish Water confirms that at the moment, all risk assessments for<br />

potentially contaminated sites are using the UKWIR published guidelines. In addition, WRAS<br />

may produce a new document later this year.<br />

Laboratory results indicate that site wide soil contaminant concentrations are generally well<br />

below the UKWIR guidelines for the provision of standard P.E supply pipe material. It is<br />

noted that whilst SVOC analysis has not been conducted on received soil samples, (the<br />

testing was conducted before the publication of the new document) total TPH and PAH soil<br />

concentrations are well below permissible guideline values. PAH soil concentrations are<br />

below the laboratory detection limit. Total phenol values are also below the 2.0 mg/kg<br />

detection limit for P.E water supply pipe specifications.<br />

Considering the historic land use, current site setting, recorded contaminant concentrations<br />

and the context of the development proposal, it is recommended that water supply pipes are<br />

upgraded to Aluminum wrapped polyethylene (A.I P.E) and laid in clean inert granular filled<br />

corridors and back filled with same. Alternatively, once the water supply pipe route has been<br />

finalised, additional samples could be obtained and analysed to determine whether the insitu<br />

soils present a risk to placement of standard PE water supply pipes.<br />

For clarity, the UKWIR document is included as (Appendix C).<br />

22 http://www.wras.co.uk/9-04-03_withdrawal.HTM<br />

23 Guidance for the Selection of Water Supply Pipes to be used in Brownfield Sites" (Ref 10/WM/03/21 January 2011<br />

24 http://www.anglianwater.co.uk/developers/installation/contaminated-land.aspx<br />

-9-


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

4.0 Final Risk Assessment/Revised CSM<br />

4.1 Ground Gas<br />

The results of on site gas monitoring have been compared with relevant guidance25,26,27,28,29,30.<br />

The Building Regulations set action levels for both methane and carbon dioxide from which<br />

an initial assessment can be made. The action threshold for methane is 1%v/v while for<br />

carbon dioxide an initial consideration should be undertaken if the concentration exceeds<br />

1.5%v/v. Action might be required if carbon dioxide concentrations exceed 5%. If these<br />

thresholds are exceeded, reference should be made to specific documentation to determine<br />

the nature and extent of the gas control measures required.<br />

Guidance within CIRIA C665 and BS8485 identifies a number of gas regimes based on gas<br />

concentrations and borehole flow rates. The results obtained during monitoring is<br />

summarised in the Factual Report. The results indicate that a maximum (steady state) carbon<br />

dioxide (CO2) concentration of 1.0% v/v was recorded at BH5 during the mointoirng<br />

period. Values were observed to remian static at all locations over the gas measuring period.<br />

No carbon monoxide, methane or hydrogen sulphide was detected over 5 monitoring<br />

rounds at any installation. No depleted oxygen values (< 16% v/v O2) were detected.<br />

CIRIA 665 provides guidance on calculating the gas flow rates by derivation of the Gas<br />

Screening Value (GSV). This is obtained by multiplying the gas concentration (as a percentage<br />

volume) by the borehole flow rate in litres per hour. Measured flow rates were low with a<br />

maximum flux of (+0.9l/hr) recorded at BH9, the average being +0.6 l/hr over the<br />

monitoring period. The low flow values indicating that the insitu made ground deposits have<br />

low evolution rates and are not providing a significant gassing risk.<br />

Barometric pressures over the monitoring period have generally favoured gas emissions<br />

(measurements being targeted to events of generally less than 1000mB and or falling); we<br />

are of the considered opinion that the very low flow rates and gas concentrations measured<br />

accurately reflect the insitu conditions within the sub surface soils.<br />

In accordance with the CIRIA, BS8485 gas regimes described above the site falls into<br />

Characteristic Situation 1 (low risk).<br />

Applying the guidance and methodology from CIRIA, BS8485 and NHBC, and using the<br />

maximum (worst case scenario) carbon dioxide concentration at (BH5) and flow rate<br />

recorded (+0.9 l/hr at BH9) a GSV of 0.009 can be applied to the site.<br />

This is within the criteria of gassing Characteristic Situation 1 (GSV


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

4.1 Ground Gas (continued)<br />

In accordance with CIRIA C665 pp59/60 Tables 5.5A and 5.5B, a suitable monitoring<br />

duration and frequency of recordings is required to suitably assess the gassing<br />

characteristion at a site and in the context of the development proposal. Six monitoring<br />

rounds have been completed over a period of twenty weeks.<br />

4.2 Water Environment-Ground Water Quality<br />

Five, shallow groundwater samples obtained at depths from (0.20m-3.70m bgl) were<br />

scheduled for laboratory analysis which included:<br />

CLEA Metals suite<br />

pH, cyanide, phenol , ammoniacal nitrogen, mercury<br />

Speciated US EPA (PAH 16)<br />

Speciated TPH (aliphatic/aromatic split)<br />

In the first instance, the most conservative generic screening criteria the (Drinking Water<br />

Scotland Regulations 2001) have been applied to the results (included in the Factual Report<br />

as Appendix E) from sampled groundwater. The UKDWS screening criteria are included in<br />

the SEPA document (Assigning groundwater assessment criteria for pollutant inputs) May<br />

2011.<br />

It is acknowledged that the nearest surface water receptor is the White Cart Water located<br />

some 300m to the southwest of the site boundary, in order to provide a degree of<br />

conservatism, the selected drinking water standard for assessment are the UKDWS<br />

(Scotland regulations 2001). These have been selected before the relevant EQS standards<br />

(surface water receptor). The values are considered suitable Resource Protection Values<br />

(RPV’s) as it is not considered that the site presents a significant source of potentially<br />

hazardous substances or List1/11 groundwater directive substances.<br />

Review of the laboratory results indicate that metalloid and inorganic compounds (cyanide,<br />

ammonia phenol) are below the UKDWS guidelines. All total petroleum hydrocarbon<br />

compounds (C5-C35) were below the UKDWS values and the majority below the laboratory<br />

detection limit.<br />

With regard to speciated PAH compounds, exceedances were recorded at all sampled<br />

boreholes on the first sampling round. A maximum total PAH concentration of 0.34µg/l was<br />

recorded at BH3 0.62m bgl. Results from the second round of sampling (only BH5 had a<br />

permissible sampling volume) were below the laboratory detection limit. It is possible that<br />

potential oil/fuel leakage from parked vehicles (buses park towards the warehouse buildings)<br />

may have entered the borehole during significant rainfall events. Considering the<br />

development proposal and the location of BH3, which will be covered by the new Tesco<br />

store, thus reducing infiltration, the potential risks to the water environmental are low.<br />

-11-


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

4.2 Water Environment-Ground Water Quality (continued)<br />

Overall risks to the water environment31’32 are low given consideration to the following:<br />

The development proposal (reducing infiltration)<br />

That sampled groundwater obtained was generally of good quality (no evidence of<br />

impaction by surface soil contaminants)<br />

The low propensity for contaminants to leach from the made ground and insitu<br />

natural deposits<br />

Provision of and integration with the existing storm and sewer drainage network<br />

should suitably mitigate any potential increased surface run-off.<br />

4.3 Buildings/Services<br />

Laboratory sulphate test results (Total Sulphate) indicate that the site conforms to BRE<br />

Special Digest (SD1) 33 ’ 34 Site Classification 1 criteria with regard to total sulphate<br />

concentrations. The measured soil pH values are generally slightly acidic (though not<br />

aggressive pH range 6.18-7.97) and, as a consequence, we would advise that foundation<br />

concrete of Aggressive Chemical Environment for Concrete (ACEC) AC-1 class is adopted.<br />

Water Supply pipes should be upgraded to Aluminum wrapped polyethylene (A.I.PE) and laid<br />

in clean granular corridors. Alternatively additional soil samples can be obtained and analysed<br />

once the water supply pipe route is finalised.<br />

No special gas protection measures are considered necessary on the basis of the recorded<br />

gas concentrations.<br />

4.4 Sensitive Receptors<br />

Having applied the procedures outlined in CLR1135, and developed a preliminary CSM the<br />

(first phase of a site risk assessment) a comparison of laboratory data against published and<br />

derived (GACs) indicate that the surface soils present a low risk to the identified receptors<br />

and the wider environmental setting. In the context of a commercial industrial end use, the<br />

site is suitable for use and no other considerations are deemed necessary in respect to the<br />

human identified receptors. The development proposal presents a barrier to underlying soils<br />

and thus effectively removes the source and subsequent pathway-receptor elements of the<br />

CSM. Laboratory soil contamination results and gas monitoring results indicate that the<br />

insitu soils present a low risk to the development in a commercial/industrial context. Overall<br />

metal and organic hydrocarbon (TPH and PAH) concentrations were below applicable<br />

criteria, and below laboratory detection limits (soil PAH). It is accepted that spatially isolated<br />

elevated metal concentrations (BH12) indicative of hotspot values were recorded. These are<br />

reflective of typical industrial soils which are often heterogeneous in nature.<br />

31 Water Framework Directive 2000/60 EC<br />

32 The Water Environment Water Services (WEWS) Scotland Act 2003<br />

33 BRE Special Digest 1, Concrete in Aggressive Ground (2005)<br />

34 Concrete Resistant to Chemical Attack (Specifying Concrete to BS EN 206-1/BS 8500)<br />

35 Model Procedures for the Management of Land Contamination, DEFRA September 2004<br />

-12-


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

4.4 Sensitive Receptors (continued)<br />

An important consideration is the nature and context of the development proposal. At this<br />

site, a new retail store and car parking will occupy the west and central portions of the site,<br />

with a PFS to the southwest. It is noted that the latest development boundary (included as<br />

Appendix 4), does not include the area around the indoor bowling club. BH12 and BH13<br />

were advanced in this area and at BH12, elevated metals were recorded. These results are<br />

no longer required or included in the risk assessment, as there are no risks to identified<br />

receptors during development.<br />

Analysis of the site soil concentrations with respect to organic hydrocarbons (TPH and<br />

PAH) indicate a low risk to the development and surroundings.<br />

Leachate results indicate a low propensity for contaminants to enter the liquid phase, thus<br />

limiting potential impacts on underlying groundwater resources.<br />

The risks to ecosystems, (plants and fauna) are low given the nature of the development<br />

proposal, the removal of pollutant linkages and the positioning of vegetated screening on the<br />

site boundaries.<br />

Shallow perched groundwater is unlikely to experience deleterious concentrations of<br />

contaminants given the underlying hydrogeology, distance of nearest surface water feature,<br />

low leaching potential of the overlying soils and the provision of suitable drainage network<br />

to minimise surface run-off and infiltration. The results from the first groundwater<br />

monitoring round indicate PAH concentrations above the applicable UKDWS criteria.<br />

However, given the previous historic land use it is possible that the standing water table may<br />

be marginally impacted. There were no PAH compounds detected in the retrieved sample<br />

from BH5 (second round).<br />

Considering that the new retail store will cover this portion of the site, and thus minimising<br />

infiltration it is not considered that groundwater resources are likely to be deleteriously<br />

impacted.<br />

Should any unusual odours or seepages be encountered on site during the construction<br />

stage, then these should immediately be brought to the attention of the Engineer who<br />

should then arrange for the relevant sampling and testing to be carried out.<br />

Overall, it is considered that in the context of the development proposal, effectively<br />

removing exposure the exposure pathway (removing a key link of the SPR model) the site is<br />

“suitable for use” for the development.<br />

Should any unusual odours or seepages be encountered on site during the construction<br />

stage, then these should immediately be brought to the attention of the Engineer who<br />

should then arrange for the relevant sampling and testing to be carried out.<br />

A revised conceptual site model is provided as Table 5.<br />

-13-


Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

Table 5: Revised Conceptual Site Model (Redevelopment)<br />

Potential Risk<br />

Low Medium High<br />

Proposed Commercial Retail Development, Wallneuk Road, Paisley, <strong>Renfrewshire</strong><br />

Source(s)<br />

Pathways<br />

Receptors<br />

ON SITE:<br />

Historical Iron Foundry and<br />

engineering works, former<br />

industrial buildings and<br />

processes<br />

Made ground<br />

Generation and migration of<br />

ground gas- with made ground<br />

and potential underlying<br />

shallow coal workings<br />

Volatilisation and migration of<br />

organic compounds<br />

OFF SITE:<br />

Former Engineering works and<br />

mineral extraction activities<br />

Dermal contact/Dust Inhalation<br />

of exposed soils<br />

Dust dispersion during<br />

construction<br />

premises<br />

to adjacent<br />

Leaching of mobile phase<br />

aqueous phase contaminants<br />

to underlying perched<br />

groundwater and Surface run<br />

off to adjacent watercourse(s)<br />

Migration of gases and vapours<br />

into sub floor voids<br />

Surface run-off of impacted<br />

groundwater<br />

receptors<br />

to off site<br />

Construction workers<br />

End users<br />

Off site workers<br />

Buildings and services<br />

Water Environment<br />

<br />

<br />

<br />

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<br />

Comments<br />

The area within the site boundary has been<br />

utilised for numerous industrial processes, most<br />

prominent being Iron Foundry and steel works.<br />

Other processes warehousing and engineering<br />

works may also have impacted the site. There is<br />

the potential for viable pollutant linkages to exist<br />

at the site the current extent and nature of which<br />

are unknown, but may, if disturbed through<br />

construction work have a deleterious impact on<br />

(humans) the water environment and<br />

Buildings/structures .<br />

Potential for construction workers and end users<br />

to come in contact with exposed/disturbed soils<br />

during development.<br />

Good working practises should minimise dust<br />

generation and dispersion<br />

Potential of leaching of mobile phase<br />

contaminants into under lying groundwater<br />

resources or surface run-off. Surface tarmac and<br />

glacial soils reduce this risk.<br />

Potential of ground gas generation within made<br />

ground deposits and from underlying shallow<br />

mineral workings. Potential for vapour generation<br />

from potential hydrocarbon concentration within<br />

sub surface soils<br />

The existing drainage system mitigates to some<br />

extent uncontrolled surface run-off<br />

There is the potential for complete pollutant<br />

linkages to exist at this site, which could<br />

potentially have adverse impacts on sensitive<br />

receptors.<br />

Construction workers and buildings and services<br />

may be impacted by potentially contaminated<br />

soils.<br />

An evaluation is necessary to quantify and assign<br />

any risk(s) posed to the development considering<br />

the current site land use<br />

RISK CATEGORY RATING (CLR6)<br />

A MEDIUM Risk rating (Category 3) has been assigned to the site given the previous site land uses and the likely potential for<br />

contaminants to exist within the sub surface soils. There is likelihood for complete plausible pollutant linkages to exist at the<br />

site. These are likely to be prevalent during construction.<br />

The site is considered “suitable for use” in its current setting and context. However, during site preparation and construction<br />

works, there is a pathway to exposure to potentially deleterious levels of contaminants. Sensitive receptors may be impacted<br />

by movement (and/or) disturbance of contaminated soils. It is in this context that the site has been assigned a Medium risk<br />

rating. Due to the nature of the underlying soils and potential for contamination to exist, and the nature of the proposed<br />

development, the site requires further investigation to be deemed “Suitable for Use”.


5.0 Conclusions<br />

Proposed New Tesco Store, Wallneuk Road, Paisley <strong>Renfrewshire</strong>: 9692<br />

The site in its current setting is suitable for use and for related activities.<br />

Risks from direct contact with soil/fill materials within the site present a Low risk to the<br />

proposed development in respect to overall recorded contaminant concentrations with<br />

regard to construction workers and buildings and services. A low risk is considered<br />

appropriate to end users, residents and off site adjacent premises upon completion of<br />

the development.<br />

Construction workers should employ good site practices, wear appropriate PPE and<br />

obtain specialist advice/assistance in removal/disposal of any unusual materials/odours<br />

should they be encountered.<br />

Ground gas concentrations recorded at the site do not indicate that a significant gas<br />

generation and migration source exists beneath the site. An overall Low Risk has been<br />

assigned and as such, basic protection measures (Visqueen® 1200g DPM or equivalent)<br />

with all joints and penetrations suitably lapped and sealed should be utilised under<br />

foundations.<br />

Potential risks to the water environment are low overall, given the low propensity for<br />

contaminants to leach from surface soils, the distance to the nearest water receptor,<br />

and overlying insitu glacial soils. Provision/incorporation into a suitable surface water<br />

drainage network and sewerage system will further mitigate potential surface run-off to<br />

off site receptors.<br />

Risks to the identified receptors are considered low overall in light of laboratory and<br />

field monitoring data in the context of the development proposal.<br />

With respect to water supply pipe placement, these be upgraded to aluminum wrapped<br />

polyethylene (A.I P.E) and routed in clean granular corridors. Alternatively, once the<br />

water supply pipe route is finalised, additional samples can be obtained to re-assesses<br />

any risk(s) to placement of standard “plastic” (P.E) water supply pipes.<br />

Having completed the intrusive investigation, laboratory analysis on soil and leachate<br />

potential: and ground gas evolution, the site presents limited risk to further development<br />

in a commercial/industrial context.<br />

-15-


APPENDIX A<br />

CLEA V 1.06 SGV/GAC SETTINGS & RESULTS


CLEA Software Version 1.06<br />

Report generated<br />

Report title<br />

Created by<br />

BASIC SETTINGS<br />

20/06/2011<br />

Land Use Commercial<br />

Proposed New Tesco Store at Wallneuk Paisley <strong>Renfrewshire</strong><br />

Stephen Milne at DAM Geotechnical Services<br />

090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

Building Warehouse (post 1970)<br />

Receptor Female (com) Start age class 17 End age class 17 Exposure Duration 49 years<br />

Soil Sand<br />

Exposure Pathways Direct soil and dust ingestion Dermal contact with indoor dust Inhalation of indoor dust <br />

Consumption of homegrown produce Dermal contact with soil Inhalation of soil dust <br />

Soil attached to homegrown produce Inhalation of indoor vapour <br />

Inhalation of outdoor vapour <br />

Page 1 of 5


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 2 of 5<br />

Age Class<br />

Land Use Commercial<br />

Direct soil ingestion<br />

Exposure Frequencies (days yr -1 ) Occupation Periods (hr day -1 )<br />

Consumption of<br />

homegrown produce<br />

Dermal contact with<br />

indoor dust<br />

Dermal contact with<br />

soil<br />

Inhalation of dust and<br />

vapour, indoor<br />

Inhalation of dust and<br />

vapour, outdoor<br />

1 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

2 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

3 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

4 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

5 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

6 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

7 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

8 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

9 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

10 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

11 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

12 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

13 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

14 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

15 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

16 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

17 230 0 230 170 230 170 8.3 0.7 0.14 0.14 0.05<br />

18 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

Indoors<br />

Outdoors<br />

Soil to skin adherence<br />

factors (mg cm 2 )<br />

Indoor<br />

Outdoor<br />

Direct soil ingestion rate<br />

(g day -1 )


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 3 of 5<br />

Age Class<br />

Receptor Female (com)<br />

Body weight (kg)<br />

Body height (m)<br />

Inhalation rate<br />

(m 3 day -1 )<br />

Max exposed skin factor Consumption rates (g FW kg -1 BW day -1 )<br />

Indoor (m 2 m -2 )<br />

Outdoor (m 2 m -2 )<br />

Total skin area<br />

(m 2 )<br />

1 5.60 0.7 8.5 0.00 0.00 3.43E-01 7.12 10.69 16.03 1.83 2.23 3.82<br />

2 9.80 0.8 13.3 0.00 0.00 4.84E-01 6.85 3.30 5.46 3.96 0.54 11.96<br />

3 12.70 0.9 12.7 0.00 0.00 5.82E-01 6.85 3.30 5.46 3.96 0.54 11.96<br />

4 15.10 0.9 12.2 0.00 0.00 6.36E-01 6.85 3.30 5.46 3.96 0.54 11.96<br />

5 16.90 1.0 12.2 0.00 0.00 7.04E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

6 19.70 1.1 12.2 0.00 0.00 7.94E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

7 22.10 1.2 12.4 0.00 0.00 8.73E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

8 25.30 1.2 12.4 0.00 0.00 9.36E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

9 27.50 1.3 12.4 0.00 0.00 1.01E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

10 31.40 1.3 12.4 0.00 0.00 1.08E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

11 35.70 1.4 12.4 0.00 0.00 1.19E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

12 41.30 1.4 13.4 0.00 0.00 1.29E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

13 47.20 1.5 13.4 0.00 0.00 1.42E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

14 51.20 1.6 13.4 0.00 0.00 1.52E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

15 56.70 1.6 13.4 0.00 0.00 1.60E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

16 59.00 1.6 13.4 0.00 0.00 1.63E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

17 70.00 1.6 14.8 0.08 0.08 1.78E+00 2.94 1.40 1.79 1.61 0.22 2.97<br />

18 70.90 1.6 12.0 0.00 0.00 1.80E+00 2.94 1.40 1.79 1.61 0.22 2.97<br />

Green vegetables<br />

Root vegetables<br />

Tuber vegetables<br />

Herbaceous fruit<br />

Shrub fruit<br />

Tree fruit


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 4 of 5<br />

Building Warehouse (post 1970) Soil Sand<br />

Building footprint (m 2 )<br />

Living space air exchange rate (hr -1 )<br />

Living space height (above ground, m)<br />

Living space height (below ground, m)<br />

Pressure difference (soil to enclosed space, Pa)<br />

Foundation thickness (m)<br />

Floor crack area (cm 2 )<br />

Dust loading factor (μg m -3 )<br />

1.91E+03 Porosity, Total (cm 5.40E-01<br />

1.00E+00 3.00E-01<br />

5.10E+00 2.40E-01<br />

3 cm -3 )<br />

Porosity, Air-Filled (cm 3 cm -3 )<br />

Porosity, Water-Filled (cm 3 cm -3 )<br />

0.00E+00 Residual soil water content (cm 7.00E-02<br />

3 cm -3 )<br />

3.40E+00 7.36E-03<br />

1.50E-01 3.51E-01<br />

Bulk density (g cm 1.18E+00<br />

-3 Saturated hydraulic conductivity (cm s<br />

)<br />

-1 )<br />

van Genuchten shape parameter m (dimensionless)<br />

3.50E+03<br />

1.00E+02 Threshold value of wind speed at 10m (m s -1 ) 7.20E+00<br />

Empirical function (Fx) for dust model (dimensionless) 1.22E+00<br />

Ambient soil temperature (K)<br />

2.83E+02<br />

Soil pH<br />

Soil Organic Matter content (%)<br />

Fraction of organic carbon (g g -1 )<br />

Effective air permeability (cm 2 Effective total fluid saturation (unitless)<br />

Intrinsic soil permeability (cm<br />

Relative soil air permeability (unitless)<br />

)<br />

2 )<br />

7.10E+00<br />

1.00E+00<br />

5.80E-03<br />

3.62E-01<br />

9.83E-08<br />

7.68E-01<br />

7.54E-08


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11 Page 5 of 5<br />

Soil - Vapour Model Air Dispersion Model<br />

Depth to top of source (no building) (cm)<br />

0 Mean annual windspeed at 10m (m s -1 ) 5.00<br />

Depth to top of source (beneath building) (cm) 65 Air dispersion factor at height of 0.8m *<br />

68.00<br />

Default soil gas ingress rate? Yes Air dispersion factor at height of 1.6m *<br />

120.00<br />

Soil gas ingress rate (cm 3 s -1 )<br />

Building ventilation rate (cm 2.71E+06<br />

Averaging time surface emissions (yr) 49<br />

Finite vapour source model? No<br />

Thickness of contaminated layer (cm) 200<br />

3 s -1 )<br />

Soil - Plant Model<br />

Green vegetables<br />

Root vegetables<br />

Tuber vegetables<br />

Herbaceous fruit<br />

Shrub fruit<br />

Tree fruit<br />

1.50E+02 Fraction of site cover (m 2 m -2 ) 0.8<br />

Dry weight conversion<br />

factor<br />

* Air dispersion factor in g m -2 s -1 per kg m -3<br />

Homegrown fraction<br />

Average High<br />

g DW g -1 FW dimensionless g g -1 DW dimensionless<br />

0.096 0.05 0.33 1.00E-03 2.00E-01<br />

0.103 0.06 0.40 1.00E-03 1.00E+00<br />

0.210 0.02 0.13 1.00E-03 1.00E+00<br />

0.058 0.06 0.40 1.00E-03 6.00E-01<br />

0.166 0.09 0.60 1.00E-03 6.00E-01<br />

0.157 0.04 0.27 1.00E-03 6.00E-01<br />

Gardener type None<br />

Soil loading<br />

factor<br />

Preparation<br />

correction factor


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Page 1 of 11<br />

Report generated<br />

Report title<br />

Created by<br />

RESULTS<br />

20-Jun-11<br />

Proposed New Tesco Store at Wallneuk Paisley <strong>Renfrewshire</strong><br />

Stephen Milne at DAM Geotechnical Services


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 2 of 11<br />

Assessment Criterion (mg kg -1 ) Ratio of ADE to HCV 50% rule?<br />

Saturation Limit (mg kg<br />

oral inhalation combined oral inhalation combined Oral Inhal<br />

-1 )<br />

1 Arsenic 6.35E+02 6.95E+02 NR 1.00 0.91 NR NR No No<br />

2 Cadmium 3.99E+02 3.87E+02 2.30E+02 0.41 0.59 1.00 NR Yes No<br />

3 Chromium 6.25E+03 NR 6.25E+03 1.00 0.00 1.00 NR No No<br />

4 Copper 1.62E+05 2.49E+05 1.28E+05 0.65 0.35 1.00 NR Yes Yes<br />

5 Lead NR NR NR NR NR NR NR No No<br />

6 Mercury 4.41E+03 9.22E+04 4.23E+03 0.96 0.04 1.00 NR No No<br />

7 Nickel 2.22E+04 1.79E+03 NR 0.07 1.00 NR NR No No<br />

8 Selenium 1.30E+04 NR NR 1.00 NR NR NR No No<br />

9 Zinc 6.07E+05 NR NR 1.00 NR NR NR Yes No<br />

10 Benzene 5.53E+02 3.15E+01 2.98E+01 0.05 0.95 1.00 1.11E+03 (sol) No No<br />

11 Toluene 4.25E+05 7.22E+04 6.17E+04 0.15 0.85 1.00 8.35E+02 (vap) No No<br />

12 Ethylbenzene 1.91E+05 1.88E+04 1.71E+04 0.09 0.91 1.00 5.08E+02 (vap) No No<br />

13 Xylene (Mixed Isomers) 4.00E+05 6.53E+02 6.52E+02 0.00 1.00 1.00 5.64E+02 (sol) No No<br />

14 Xylene m- 4.00E+05 6.79E+02 6.78E+02 0.00 1.00 1.00 6.13E+02 (vap) No No<br />

15 Xylene o- 4.00E+05 7.27E+02 7.26E+02 0.00 1.00 1.00 4.67E+02 (sol) No No<br />

16 Xylene p- 4.00E+05 6.53E+02 6.52E+02 0.00 1.00 1.00 5.64E+02 (sol) No No<br />

17 Aliphatic C5-6 1.21E+05 4.16E+01 4.16E+01 0.00 1.00 1.00 3.39E+02 (sol) No No<br />

18 Aliphatic C6-8 4.05E+06 2.76E+03 2.76E+03 0.00 1.00 1.00 1.58E+02 (sol) No No<br />

19 Aliphatic C8-10 2.02E+05 4.94E+02 4.93E+02 0.00 1.00 1.00 8.42E+01 (sol) No No<br />

20 Aliphatic C10-12 2.02E+05 4.81E+03 4.70E+03 0.02 0.98 1.00 4.99E+01 (sol) No No


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 3 of 11<br />

Assessment Criterion (mg kg -1 ) Ratio of ADE to HCV 50% rule?<br />

Saturation Limit (mg kg<br />

oral inhalation combined oral inhalation combined Oral Inhal<br />

-1 )<br />

21 Aliphatic C12-16 2.02E+05 2.85E+04 2.50E+04 0.12 0.88 1.00 2.21E+01 (sol) No No<br />

22 Aliphatic C16-21 4.05E+06 NR NR 1.00 NR NR 9.15E+00 (sol) No No<br />

23 Aliphatic C21-35 4.05E+06 NR NR 1.00 NR NR 9.15E+00 (sol) No No<br />

24 Aromatic C8-10 (Corrected) 2.02E+05 1.11E+03 1.11E+03 0.01 0.99 1.00 6.14E+02 (sol) No No<br />

25 Aromatic C10-12 6.07E+04 6.60E+03 5.95E+03 0.10 0.90 1.00 3.70E+02 (sol) No No<br />

26 Aromatic C12-16 6.05E+04 4.95E+04 2.72E+04 0.45 0.55 1.00 1.70E+02 (sol) No No<br />

27 Aromatic C16-21 6.06E+04 NR NR 1.00 NR NR 5.99E+01 (sol) No No<br />

28 Aromatic C21-35 6.06E+04 NR NR 1.00 NR NR 4.82E+00 (sol) No No<br />

29 Naphthalene 4.42E+04 2.09E+02 2.08E+02 0.00 1.00 1.00 7.50E+01 (sol) No No<br />

30 Fluorene 7.88E+04 4.48E+05 6.70E+04 0.85 0.15 1.00 1.53E+02 (sol) No No


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 4 of 11<br />

Sorbed<br />

Soil Distribution Media Concentrations<br />

Dissolved<br />

Vapour<br />

Total<br />

Soil<br />

% % % % mg kg -1<br />

Soil gas<br />

mg m -3<br />

Indoor Dust<br />

mg kg -1<br />

Outdoor dust<br />

at 0.8m<br />

mg m -3<br />

Outdoor dust<br />

at 1.6m<br />

mg m -3<br />

mg m -3<br />

mg m -3<br />

mg m -3<br />

mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW<br />

1 Arsenic 100.0 0.0 0.0 100.0 6.35E+02 NR 3.18E+02 7.63E-06 4.32E-06 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

2 Cadmium 99.8 0.2 0.0 100.0 2.30E+02 NR 1.15E+02 2.77E-06 1.57E-06 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

3 Chromium 100.0 0.0 0.0 100.0 6.25E+03 NR 0.00E+00 7.51E-05 4.26E-05 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

4 Copper 99.8 0.2 0.0 100.0 1.28E+05 NR 0.00E+00 1.54E-03 8.72E-04 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

5 Lead 0.0 0.0 0.0 0.0 0.00E+00 NR 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

6 Mercury 100.0 0.0 0.0 100.0 4.23E+03 NR 0.00E+00 5.08E-05 2.88E-05 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

7 Nickel 100.0 0.0 0.0 100.0 1.79E+03 NR 8.94E+02 2.15E-05 1.22E-05 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

8 Selenium 99.6 0.4 0.0 100.0 1.30E+04 NR 6.51E+03 1.56E-04 8.87E-05 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

9 Zinc 99.0 1.0 0.0 100.0 6.07E+05 NR 0.00E+00 7.29E-03 4.13E-03 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

10 Benzene 62.7 32.5 4.7 100.0 2.98E+01 5.54E+03 1.49E+01 3.59E-07 2.03E-07 2.86E-02 4.36E-03 2.47E-03 NA NA NA NA NA NA<br />

11 Toluene 83.6 14.4 2.1 100.0 6.17E+04 5.01E+06 3.09E+04 7.42E-04 4.20E-04 2.56E+01 5.61E+00 3.18E+00 NA NA NA NA NA NA<br />

12 Ethylbenzene 91.6 7.2 1.2 100.0 1.71E+04 8.40E+05 8.55E+03 2.06E-04 1.16E-04 4.27E+00 1.15E+00 6.52E-01 NA NA NA NA NA NA<br />

13 Xylene (Mixed Isomers) 91.8 7.2 1.0 100.0 6.52E+02 2.47E+04 0.00E+00 7.83E-06 4.44E-06 1.26E+00 3.85E-02 2.18E-02 NA NA NA NA NA NA<br />

14 Xylene m- 92.5 6.6 0.9 100.0 6.78E+02 2.47E+04 0.00E+00 8.15E-06 4.62E-06 1.26E+00 3.93E-02 2.23E-02 NA NA NA NA NA NA<br />

15 Xylene o- 91.6 7.5 0.9 100.0 7.26E+02 2.47E+04 0.00E+00 8.72E-06 4.94E-06 1.26E+00 4.06E-02 2.30E-02 NA NA NA NA NA NA<br />

16 Xylene p- 91.8 7.2 1.0 100.0 6.52E+02 2.47E+04 0.00E+00 7.83E-06 4.44E-06 1.26E+00 3.85E-02 2.18E-02 NA NA NA NA NA NA<br />

17 Aliphatic C5-6 48.9 2.2 48.9 100.0 4.16E+01 8.00E+04 0.00E+00 5.00E-07 2.83E-07 4.16E+00 2.09E-02 1.18E-02 NA NA NA NA NA NA<br />

18 Aliphatic C6-8 79.0 0.7 20.3 100.0 2.76E+03 2.20E+06 0.00E+00 3.32E-05 1.88E-05 1.15E+02 8.92E-01 5.06E-01 NA NA NA NA NA NA<br />

19 Aliphatic C8-10 93.7 0.1 6.2 100.0 4.93E+02 1.20E+05 0.00E+00 5.93E-06 3.36E-06 6.24E+00 8.80E-02 4.99E-02 NA NA NA NA NA NA<br />

20 Aliphatic C10-12 99.3 0.0 0.6 100.0 4.70E+03 1.18E+05 0.00E+00 5.65E-05 3.20E-05 6.12E+00 2.69E-01 1.52E-01 NA NA NA NA NA NA<br />

Indoor<br />

Vapour<br />

Outdoor<br />

vapour at<br />

0.8m<br />

Outdoor<br />

vapour at<br />

1.6m<br />

Green<br />

vegetables<br />

Root<br />

vegetables<br />

Tuber<br />

vegetables<br />

Herbaceous<br />

fruit<br />

Shrub fruit<br />

Tree fruit


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 5 of 11<br />

Sorbed<br />

Soil Distribution Media Concentrations<br />

Dissolved<br />

Vapour<br />

Total<br />

Soil<br />

% % % % mg kg -1<br />

Soil gas<br />

mg m -3<br />

Indoor Dust<br />

mg kg -1<br />

Outdoor dust<br />

at 0.8m<br />

mg m -3<br />

Outdoor dust<br />

at 1.6m<br />

mg m -3<br />

mg m -3<br />

mg m -3<br />

mg m -3<br />

mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW<br />

21 Aliphatic C12-16 99.9 0.0 0.1 100.0 2.50E+04 1.06E+05 0.00E+00 3.00E-04 1.70E-04 5.49E+00 5.87E-01 3.33E-01 NA NA NA NA NA NA<br />

22 Aliphatic C16-21 100.0 0.0 0.0 100.0 4.05E+06 8.92E+05 0.00E+00 4.86E-02 2.75E-02 4.64E+01 2.17E+01 1.23E+01 NA NA NA NA NA NA<br />

23 Aliphatic C21-35 100.0 0.0 0.0 100.0 4.05E+06 5.19E+05 0.00E+00 4.86E-02 2.75E-02 2.70E+01 1.66E+01 9.40E+00 NA NA NA NA NA NA<br />

24 Aromatic C8-10 (Corrected) 97.3 2.2 0.5 100.0 1.11E+03 2.36E+04 0.00E+00 1.33E-05 7.53E-06 1.23E+00 5.85E-02 3.31E-02 NA NA NA NA NA NA<br />

25 Aromatic C10-12 98.5 1.4 0.1 100.0 5.95E+03 1.93E+04 0.00E+00 7.15E-05 4.05E-05 1.00E+00 1.23E-01 6.95E-02 NA NA NA NA NA NA<br />

26 Aromatic C12-16 99.3 0.7 0.0 100.0 2.72E+04 1.29E+04 0.00E+00 3.27E-04 1.85E-04 6.73E-01 2.15E-01 1.22E-01 NA NA NA NA NA NA<br />

27 Aromatic C16-21 99.8 0.2 0.0 100.0 6.06E+04 1.95E+03 0.00E+00 7.28E-04 4.13E-04 1.01E-01 1.25E-01 7.10E-02 NA NA NA NA NA NA<br />

28 Aromatic C21-35 100.0 0.0 0.0 100.0 6.06E+04 9.05E+00 0.00E+00 7.29E-04 4.13E-04 4.80E-04 1.02E-02 5.76E-03 NA NA NA NA NA NA<br />

29 Naphthalene 94.8 5.1 0.0 100.0 2.08E+02 3.49E+02 0.00E+00 2.50E-06 1.42E-06 1.76E-02 2.50E-03 1.42E-03 NA NA NA NA NA NA<br />

30 Fluorene 99.7 0.3 0.0 100.0 6.70E+04 2.65E+03 0.00E+00 8.05E-04 4.56E-04 1.26E-01 9.34E-02 5.29E-02 NA NA NA NA NA NA<br />

Indoor<br />

Vapour<br />

Outdoor<br />

vapour at<br />

0.8m<br />

Outdoor<br />

vapour at<br />

1.6m<br />

Green<br />

vegetables<br />

Root<br />

vegetables<br />

Tuber<br />

vegetables<br />

Herbaceous<br />

fruit<br />

Shrub fruit<br />

Tree fruit


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 6 of 11<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

and attached soil<br />

Average Daily Exposure (mg kg -1 bw day -1 )<br />

Dermal contact with<br />

soil and dust<br />

Inhalation of dust<br />

Inhalation of vapour<br />

Distribution by Pathway (%)<br />

1 Arsenic 2.86E-04 0.00E+00 1.42E-05 1.83E-06 0.00E+00 0.00E+00 0.00E+00 94.70 0.00 4.69 0.61 0.00 0.00 0.00 0.00<br />

2 Cadmium 1.04E-04 0.00E+00 1.71E-07 6.63E-07 0.00E+00 1.91E-04 2.86E-07 49.69 0.00 0.08 0.32 0.00 0.00 49.77 0.14<br />

3 Chromium 2.81E-03 0.00E+00 0.00E+00 3.58E-06 0.00E+00 1.86E-04 0.00E+00 93.81 0.00 0.00 0.00 0.00 0.00 6.19 0.00<br />

4 Copper 5.76E-02 0.00E+00 5.68E-03 7.34E-05 0.00E+00 1.29E-01 2.29E-04 45.46 0.00 4.48 0.06 0.00 0.00 49.94 0.06<br />

5 Lead 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00<br />

6 Mercury 1.90E-03 0.00E+00 0.00E+00 2.42E-06 0.00E+00 1.43E-05 7.14E-06 99.00 0.00 0.00 0.13 0.00 0.00 0.74 0.13<br />

7 Nickel 8.05E-04 0.00E+00 6.64E-06 5.14E-06 0.00E+00 1.86E-03 8.57E-07 49.10 0.00 0.41 0.31 0.00 0.00 49.82 0.05<br />

8 Selenium 5.86E-03 0.00E+00 0.00E+00 3.75E-05 0.00E+00 5.00E-04 8.57E-07 91.59 0.00 0.00 0.59 0.00 0.00 7.83 0.00<br />

9 Zinc 2.73E-01 0.00E+00 2.69E-02 3.48E-04 0.00E+00 3.86E-01 0.00E+00 45.52 0.00 4.48 0.00 0.00 0.00 50.00 0.00<br />

10 Benzene 1.34E-05 0.00E+00 2.22E-06 8.59E-08 1.32E-03 0.00E+00 0.00E+00 1.00 0.00 0.17 0.01 98.30 0.53 0.00 0.00<br />

11 Toluene 2.78E-02 0.00E+00 4.59E-03 1.78E-04 1.19E+00 1.43E-04 7.43E-03 2.26 0.00 0.37 0.01 96.00 0.74 0.01 0.60<br />

12 Ethylbenzene 7.70E-03 0.00E+00 1.27E-03 4.92E-05 1.99E-01 7.14E-05 1.86E-03 3.68 0.00 0.61 0.02 93.88 0.89 0.03 0.89<br />

13 Xylene (Mixed Isomers) 2.93E-04 0.00E+00 2.89E-05 3.74E-07 5.79E-02 1.57E-04 2.00E-03 0.49 0.00 0.00 0.00 95.84 0.10 0.26 3.31<br />

14 Xylene m- 3.05E-04 0.00E+00 3.01E-05 3.89E-07 5.79E-02 1.57E-04 2.00E-03 0.51 0.00 0.00 0.00 95.81 0.11 0.26 3.31<br />

15 Xylene o- 3.27E-04 0.00E+00 3.22E-05 4.16E-07 5.79E-02 1.57E-04 2.00E-03 0.54 0.00 0.00 0.00 95.78 0.11 0.26 3.31<br />

16 Xylene p- 2.93E-04 0.00E+00 2.89E-05 3.74E-07 5.79E-02 1.57E-04 2.00E-03 0.49 0.00 0.00 0.00 95.84 0.10 0.26 3.31<br />

17 Aliphatic C5-6 1.87E-05 0.00E+00 1.84E-06 2.38E-08 1.92E-01 0.00E+00 8.06E-03 0.01 0.00 0.00 0.00 95.94 0.02 0.00 4.03<br />

18 Aliphatic C6-8 1.24E-03 0.00E+00 1.22E-04 1.58E-06 5.28E+00 0.00E+00 1.21E-02 0.02 0.00 0.00 0.00 99.72 0.03 0.00 0.23<br />

19 Aliphatic C8-10 2.22E-04 0.00E+00 2.19E-05 2.83E-07 2.88E-01 0.00E+00 1.49E-03 0.08 0.00 0.01 0.00 99.35 0.05 0.00 0.51<br />

20 Aliphatic C10-12 2.12E-03 0.00E+00 2.08E-04 2.69E-06 2.82E-01 0.00E+00 7.91E-04 0.74 0.00 0.07 0.00 98.76 0.15 0.00 0.28<br />

Background (oral)<br />

Background<br />

(inhalation)<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

and attached soil<br />

Dermal contact with<br />

soil and dust<br />

Inhalation of dust<br />

Inhalation of vapour<br />

(indoor)<br />

Inhalation of vapour<br />

(outdoor)<br />

Background (oral)<br />

Background<br />

(inhalation)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 7 of 11<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

and attached soil<br />

Average Daily Exposure (mg kg -1 bw day -1 )<br />

Dermal contact with<br />

soil and dust<br />

Inhalation of dust<br />

Inhalation of vapour<br />

Distribution by Pathway (%)<br />

21 Aliphatic C12-16 1.12E-02 0.00E+00 1.11E-03 1.43E-05 2.54E-01 0.00E+00 1.74E-04 4.22 0.00 0.42 0.01 94.94 0.36 0.00 0.07<br />

22 Aliphatic C16-21 1.82E+00 0.00E+00 1.79E-01 2.32E-03 2.17E+00 0.00E+00 0.00E+00 91.03 0.00 8.97 0.00 0.00 0.00 0.00 0.00<br />

23 Aliphatic C21-35 1.82E+00 0.00E+00 1.79E-01 2.32E-03 1.27E+00 0.00E+00 0.00E+00 91.03 0.00 8.97 0.00 0.00 0.00 0.00 0.00<br />

24 Aromatic C8-10 (Corrected) 4.98E-04 0.00E+00 4.90E-05 6.34E-07 5.68E-02 3.57E-04 5.91E-03 0.78 0.00 0.08 0.00 89.13 0.15 0.56 9.30<br />

25 Aromatic C10-12 2.68E-03 0.00E+00 2.64E-04 3.41E-06 4.64E-02 0.00E+00 5.50E-03 4.88 0.00 0.48 0.01 84.25 0.36 0.00 10.02<br />

26 Aromatic C12-16 1.22E-02 0.00E+00 1.21E-03 1.56E-05 3.13E-02 7.31E-05 2.29E-05 27.28 0.00 2.69 0.03 69.01 0.78 0.16 0.05<br />

27 Aromatic C16-21 2.73E-02 0.00E+00 2.69E-03 3.47E-05 4.88E-03 3.61E-05 9.29E-06 90.89 0.00 8.95 0.00 0.00 0.00 0.15 0.00<br />

28 Aromatic C21-35 2.73E-02 0.00E+00 2.69E-03 3.48E-05 3.86E-05 1.33E-05 2.86E-06 90.98 0.00 8.96 0.00 0.00 0.00 0.05 0.00<br />

29 Naphthalene 9.38E-05 0.00E+00 1.20E-05 1.19E-07 8.16E-04 1.00E-04 4.00E-05 8.98 0.00 0.00 0.01 77.80 0.39 8.98 3.83<br />

30 Fluorene 3.01E-02 0.00E+00 3.86E-03 3.84E-05 5.94E-03 8.40E-06 2.20E-06 75.37 0.00 9.65 0.10 14.48 0.38 0.02 0.01<br />

Background (oral)<br />

Background<br />

(inhalation)<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

Dermal contact with<br />

soil and dust<br />

Inhalation of dust<br />

Inhalation of vapour<br />

(indoor)<br />

Inhalation of vapour<br />

(outdoor)<br />

Background (oral)<br />

Background<br />

(inhalation)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 8 of 11<br />

Oral Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Inhalation Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Oral Mean Daily Intake<br />

(μg day -1 )<br />

Inhalation Mean Daily Intake<br />

(μg day -1 )<br />

1 Arsenic ID 0.3 ID 0.002 NR NR NR NR NR NR NR 0.03 0.5 1 1 1<br />

2 Cadmium TDI 0.36 TDI 0.0014 13.4 0.02 NR NR NR NR NR 0.001 0.5 1 1 1<br />

3 Chromium TDI 3 ID 0.001 13 NR NR NR NR NR NR 0 0 1 1 1<br />

4 Copper TDI 160 TDI 0.286 9000 16 NR NR NR NR NR 0.1 0 1 1 1<br />

5 Lead NR 0 NR 0 0 0 NR NR NR NR NR 0 0 1 1 1<br />

6 Mercury TDI 2 TDI 0.06 1 0.5 NR NR NR NR NR 0 0 1 1 1<br />

7 Nickel TDI 12 TDI 0.006 130 0.06 NR NR NR NR NR 0.005 0.5 1 1 1<br />

8 Selenium TDI 6.4 NR 0 35 0.06 NR NR NR NR NR 0 0.5 1 1 1<br />

9 Zinc TDI 600 NR 0 27000 NR NR NR NR NR NR 0.1 0 1 1 1<br />

10 Benzene ID 0.29 ID 1.4 NR NR 1.16E-01 8.77E-06 6.64E-10 1.83 2.13 0.1 0.5 10 1 1<br />

11 Toluene TDI 223 TDI 1400 10 520 1.15E-01 7.78E-06 5.88E-10 2.31 2.73 0.1 0.5 10 1 1<br />

12 Ethylbenzene TDI 100 TDI 220 5 130 1.39E-01 7.04E-06 5.31E-10 2.65 3.15 0.1 0.5 10 1 1<br />

13 Xylene (Mixed Isomers) TDI 180 TDI 60 11 140 1.07E-01 7.04E-06 5.31E-10 2.65 3.15 0.1 0 1 1 1<br />

14 Xylene m- TDI 180 TDI 60 11 140 1.12E-01 7.03E-06 5.31E-10 2.69 3.2 0.1 0 1 1 1<br />

15 Xylene o- TDI 180 TDI 60 11 140 9.20E-02 7.01E-06 5.31E-10 2.63 3.12 0.1 0 1 1 1<br />

16 Xylene p- TDI 180 TDI 60 11 140 1.07E-01 7.04E-06 5.31E-10 2.65 3.15 0.1 0 1 1 1<br />

17 Aliphatic C5-6 TDI 60 TDI 200 0 564 1.81E+01 1.00E-05 1.00E-09 2.9 3.3 0.1 0 1 1 1<br />

18 Aliphatic C6-8 TDI 2000 TDI 5300 0 850 2.33E+01 1.00E-05 1.00E-09 3.6 4.1 0.1 0 1 1 1<br />

19 Aliphatic C8-10 TDI 100 TDI 290 0 104 4.76E+01 1.00E-05 1.00E-09 4.5 5.2 0.1 0 1 1 1<br />

20 Aliphatic C10-12 TDI 100 TDI 290 0 55.4 3.67E+01 1.00E-05 1.00E-09 5.4 6.3 0.1 0 1 1 1<br />

Air-water partition coefficient<br />

(Kaw) (cm 3 cm -3 )<br />

Coefficient of Diffusion in Air<br />

(m 2 s -1 )<br />

Coefficient of Diffusion in Water<br />

(m 2 s -1 )<br />

log K oc (cm 3 g -1 )<br />

log K ow (dimensionless)<br />

Dermal Absorption Fraction<br />

(dimensionless)<br />

Soil-to-dust transport factor (g<br />

g -1 DW)<br />

Sub-surface soil to indoor air<br />

correction factor<br />

(dimensionless)<br />

Relative bioavailability via soil<br />

ingestion (unitless)<br />

Relative bioavailability via dust<br />

inhalation (unitless)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 9 of 11<br />

Oral Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Inhalation Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Oral Mean Daily Intake<br />

(μg day -1 )<br />

Inhalation Mean Daily Intake<br />

(μg day -1 )<br />

21 Aliphatic C12-16 TDI 100 TDI 290 0 12.2 1.23E+02 1.00E-05 1.00E-09 6.7 7.9 0.1 0 1 1 1<br />

22 Aliphatic C16-21 TDI 2000 NR 0 0 0 8.07E+02 1.00E-05 1.00E-09 8.8 10.4 0.1 0 1 1 1<br />

23 Aliphatic C21-35 TDI 2000 NR 0 0 0 4.70E+02 1.00E-05 1.00E-09 8.8 10.4 0.1 0 1 1 1<br />

24 Aromatic C8-10 (Corrected) TDI 100 TDI 63 25 414 2.02E-01 1.00E-05 1.00E-09 3.2 3.7 0.1 0 1 1 1<br />

25 Aromatic C10-12 TDI 30 TDI 57 0 385 4.79E-02 1.00E-05 1.00E-09 3.4 3.9 0.1 0 1 1 1<br />

26 Aromatic C12-16 TDI 30 TDI 57 5.12 1.6 1.39E-02 1.00E-05 1.00E-09 3.7 4.3 0.1 0 1 1 1<br />

27 Aromatic C16-21 TDI 30 NR 0 2.53 0.65 2.96E-03 1.00E-05 1.00E-09 4.2 4.9 0.1 0 1 1 1<br />

28 Aromatic C21-35 TDI 30 NR 0 0.93 0.2 1.09E-04 1.00E-05 1.00E-09 5.1 6 0.1 0 1 1 1<br />

29 Naphthalene TDI 20 TDI 0.86 7 2.8 6.62E-03 6.52E-06 5.16E-10 2.81 3.34 0.13 0 1 1 1<br />

30 Fluorene TDI 40 TDI 40 0.588 0.154 3.18E-03 3.63E-06 7.88E-10 4.14 4.18 0.13 0 1 1 1<br />

Air-water partition coefficient<br />

(Kaw) (cm 3 cm -3 )<br />

Coefficient of Diffusion in Air<br />

(m 2 s -1 )<br />

Coefficient of Diffusion in Water<br />

(m 2 s -1 )<br />

log K oc (cm 3 g -1 )<br />

log K ow (dimensionless)<br />

Dermal Absorption Fraction<br />

(dimensionless)<br />

Soil-to-dust transport factor (g<br />

g -1 DW)<br />

Sub-surface soil to indoor air<br />

correction factor<br />

(dimensionless)<br />

Relative bioavailability via soil<br />

ingestion (unitless)<br />

Relative bioavailability via dust<br />

inhalation (unitless)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 10 of 11<br />

Soil-to-water partition coefficient<br />

(cm 3 g -1 )<br />

Vapour pressure (Pa)<br />

Water solubility (mg L -1 )<br />

Soil-to-plant concentration factor<br />

for green vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for root vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for tuber vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for herbaceous fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

1 Arsenic 5.00E+02 NR 1.25E+06 0.00043 fw 0.0004 fw 0.00023 fw 0.00033 fw 0.0002 fw 0.0011 fw<br />

2 Cadmium 1.00E+02 NR 1.62E+06 0.052 fw 0.029 fw 0.031 fw 0.016 fw 0.0031 fw 0.0014 fw<br />

3 Chromium 6.31E+03 NR 6.29E+05 0.055 dw 0.02 dw model model model model<br />

4 Copper 1.27E+02 NR 7.06E+05 0.8 dw 0.8 dw model model model model<br />

5 Lead 5.01E+03 NR 1.70E+01 0 dw 0 dw model model model model<br />

6 Mercury 6.31E+03 NR 5.60E-02 0.35116 dw 0.05 dw model model model model<br />

7 Nickel 5.00E+02 NR 2.50E+06 0.0038 fw 0.0043 fw 0.0019 fw 0.0025 fw 0.0025 fw 0.0034 fw<br />

8 Selenium 5.00E+01 NR 2.17E+06 0.0108 fw 0.00364 fw 0.00083 fw 0.00271 fw 0.003 fw 0.003 fw<br />

9 Zinc 2.07E+01 NR 4.30E+06 0.99 dw 0.99 dw model model model model<br />

10 Benzene 3.92E-01 6.24E+03 1.78E+03 model model model 0.00E+00 0.00E+00 model<br />

11 Toluene 1.18E+00 1.73E+03 5.90E+02 model model model 0.00E+00 0.00E+00 model<br />

12 Ethylbenzene 2.59E+00 5.53E+02 1.80E+02 model model model 0.00E+00 0.00E+00 model<br />

13 Xylene (Mixed Isomers) 2.59E+00 4.95E+02 2.00E+02 model model model model model model<br />

14 Xylene m- 2.84E+00 4.95E+02 2.00E+02 model model model model model model<br />

15 Xylene o- 2.47E+00 3.86E+02 1.73E+02 model model model model model model<br />

16 Xylene p- 2.59E+00 4.75E+02 2.00E+02 model model model model model model<br />

17 Aliphatic C5-6 4.61E+00 3.54E+04 3.60E+01 model model model model model model<br />

18 Aliphatic C6-8 2.31E+01 6.38E+03 5.40E+00 model model model model model model<br />

19 Aliphatic C8-10 1.83E+02 6.38E+02 4.30E-01 0.0382 dw 0.0161 dw model model model model<br />

20 Aliphatic C10-12 1.46E+03 6.40E+01 3.40E-02 0.00883 dw 0.0143 dw model model model model<br />

Soil-to-plant concentration factor<br />

for shrub fruit<br />

(mg g -1 plant DW or FW basis<br />

over mg g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for tree fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (1)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 11 of 11<br />

Soil-to-water partition coefficient<br />

(cm 3 g -1 )<br />

Vapour pressure (Pa)<br />

Water solubility (mg L -1 )<br />

Soil-to-plant concentration factor<br />

for green vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for root vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for tuber vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for herbaceous fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

21 Aliphatic C12-16 2.91E+04 4.90E+00 7.60E-04 0.00105 dw 0.0122 dw model model model model<br />

22 Aliphatic C16-21 3.66E+06 1.00E-01 2.50E-06 0.00003 dw 0.00814 dw model model model model<br />

23 Aliphatic C21-35 3.66E+06 1.10E-01 2.50E-06 0.00003 dw 0.00814 dw model model model model<br />

24 Aromatic C8-10 (Corrected) 9.19E+00 6.38E+02 6.50E+01 model model model model model model<br />

25 Aromatic C10-12 1.46E+01 6.38E+01 2.50E+01 model model model model model model<br />

26 Aromatic C12-16 2.91E+01 4.90E+00 5.80E+00 model model model model model model<br />

27 Aromatic C16-21 9.19E+01 1.10E-01 6.50E-01 0.057 fw 0.019 dw model model model model<br />

28 Aromatic C21-35 7.30E+02 4.46E-05 6.60E-03 0.0132 fw 0.0167 dw model model model model<br />

Soil-to-plant concentration factor<br />

for tree fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

29 Naphthalene 3.74E+00 2.31E+00 1.90E+01 4.17 dw 12.7 dw model model model model<br />

30 Fluorene 8.01E+01 1.26E-01 1.90E+00 model model model model model model<br />

Soil-to-plant concentration factor<br />

for shrub fruit<br />

(mg g -1 plant DW or FW basis<br />

over mg g -1 DW soil)


CLEA Software Version 1.06<br />

Report generated<br />

Report title<br />

Created by<br />

BASIC SETTINGS<br />

20/06/2011<br />

Land Use Commercial<br />

Proposed New Tesco Store at Wallneuk Paisley <strong>Renfrewshire</strong><br />

Stephen Milne at DAM Geotechnical Services<br />

090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

Building Warehouse (post 1970)<br />

Receptor Female (com) Start age class 17 End age class 17 Exposure Duration 49 years<br />

Soil Sand<br />

Exposure Pathways Direct soil and dust ingestion Dermal contact with indoor dust Inhalation of indoor dust <br />

Consumption of homegrown produce Dermal contact with soil Inhalation of soil dust <br />

Soil attached to homegrown produce Inhalation of indoor vapour <br />

Inhalation of outdoor vapour <br />

Page 1 of 5


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 2 of 5<br />

Age Class<br />

Land Use Commercial<br />

Direct soil ingestion<br />

Exposure Frequencies (days yr -1 ) Occupation Periods (hr day -1 )<br />

Consumption of<br />

homegrown produce<br />

Dermal contact with<br />

indoor dust<br />

Dermal contact with<br />

soil<br />

Inhalation of dust and<br />

vapour, indoor<br />

Inhalation of dust and<br />

vapour, outdoor<br />

Soil to skin adherence<br />

factors (mg cm 2 )<br />

1 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

2 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

3 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

4 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

5 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

6 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

7 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

8 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

9 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

10 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

11 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

12 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

13 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

14 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

15 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

16 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

17 230 0 230 170 230 170 8.3 0.7 0.14 0.14 0.05<br />

18 0 0 0 0 0 0 0.0 0.0 0.00 0.00 0.00<br />

Indoors<br />

Outdoors<br />

Indoor<br />

Outdoor<br />

Direct soil ingestion rate<br />

(g day -1 )


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 3 of 5<br />

Age Class<br />

Receptor Female (com)<br />

Body weight (kg)<br />

Body height (m)<br />

Inhalation rate<br />

(m 3 day -1 )<br />

Max exposed skin factor Consumption rates (g FW kg -1 BW day -1 )<br />

Indoor (m 2 m -2 )<br />

Outdoor (m 2 m -2 )<br />

Total skin area<br />

(m 2 )<br />

1 5.60 0.7 8.5 0.00 0.00 3.43E-01 7.12 10.69 16.03 1.83 2.23 3.82<br />

2 9.80 0.8 13.3 0.00 0.00 4.84E-01 6.85 3.30 5.46 3.96 0.54 11.96<br />

3 12.70 0.9 12.7 0.00 0.00 5.82E-01 6.85 3.30 5.46 3.96 0.54 11.96<br />

4 15.10 0.9 12.2 0.00 0.00 6.36E-01 6.85 3.30 5.46 3.96 0.54 11.96<br />

5 16.90 1.0 12.2 0.00 0.00 7.04E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

6 19.70 1.1 12.2 0.00 0.00 7.94E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

7 22.10 1.2 12.4 0.00 0.00 8.73E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

8 25.30 1.2 12.4 0.00 0.00 9.36E-01 3.74 1.77 3.38 1.85 0.16 4.26<br />

9 27.50 1.3 12.4 0.00 0.00 1.01E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

10 31.40 1.3 12.4 0.00 0.00 1.08E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

11 35.70 1.4 12.4 0.00 0.00 1.19E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

12 41.30 1.4 13.4 0.00 0.00 1.29E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

13 47.20 1.5 13.4 0.00 0.00 1.42E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

14 51.20 1.6 13.4 0.00 0.00 1.52E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

15 56.70 1.6 13.4 0.00 0.00 1.60E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

16 59.00 1.6 13.4 0.00 0.00 1.63E+00 3.74 1.77 3.38 1.85 0.16 4.26<br />

17 70.00 1.6 14.8 0.08 0.08 1.78E+00 2.94 1.40 1.79 1.61 0.22 2.97<br />

18 70.90 1.6 12.0 0.00 0.00 1.80E+00 2.94 1.40 1.79 1.61 0.22 2.97<br />

Green vegetables<br />

Root vegetables<br />

Tuber vegetables<br />

Herbaceous fruit<br />

Shrub fruit<br />

Tree fruit


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 4 of 5<br />

Building Warehouse (post 1970) Soil Sand<br />

Building footprint (m 2 )<br />

Living space air exchange rate (hr -1 )<br />

Living space height (above ground, m)<br />

Living space height (below ground, m)<br />

Pressure difference (soil to enclosed space, Pa)<br />

Foundation thickness (m)<br />

Floor crack area (cm 2 )<br />

Dust loading factor (μg m -3 )<br />

1.91E+03 Porosity, Total (cm 5.40E-01<br />

1.00E+00 3.00E-01<br />

5.10E+00 2.40E-01<br />

3 cm -3 )<br />

Porosity, Air-Filled (cm 3 cm -3 )<br />

Porosity, Water-Filled (cm 3 cm -3 )<br />

0.00E+00 Residual soil water content (cm 7.00E-02<br />

3 cm -3 )<br />

3.40E+00 Saturated hydraulic conductivity (cm s 7.36E-03<br />

1.50E-01 3.51E-01<br />

3.50E+03<br />

1.18E+00<br />

-1 )<br />

van Genuchten shape parameter m (dimensionless)<br />

Bulk density (g cm -3 )<br />

1.00E+02 Threshold value of wind speed at 10m (m s -1 ) 7.20E+00<br />

Empirical function (Fx) for dust model (dimensionless) 1.22E+00<br />

Ambient soil temperature (K)<br />

2.83E+02<br />

Soil pH<br />

Soil Organic Matter content (%)<br />

Fraction of organic carbon (g g -1 )<br />

Effective total fluid saturation (unitless)<br />

Intrinsic soil permeability (cm 2 )<br />

Relative soil air permeability (unitless)<br />

Effective air permeability (cm 2 )<br />

7.10E+00<br />

1.00E+00<br />

5.80E-03<br />

3.62E-01<br />

9.83E-08<br />

7.68E-01<br />

7.54E-08


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11 Page 5 of 5<br />

Soil - Vapour Model Air Dispersion Model<br />

Depth to top of source (no building) (cm)<br />

0 Mean annual windspeed at 10m (m s -1 ) 5.00<br />

Depth to top of source (beneath building) (cm) 65 Air dispersion factor at height of 0.8m *<br />

68.00<br />

Default soil gas ingress rate? Yes Air dispersion factor at height of 1.6m *<br />

120.00<br />

Soil gas ingress rate (cm 3 s -1 )<br />

Building ventilation rate (cm 2.71E+06<br />

Averaging time surface emissions (yr) 49<br />

Finite vapour source model? No<br />

Thickness of contaminated layer (cm) 200<br />

3 s -1 )<br />

Soil - Plant Model<br />

Green vegetables<br />

Root vegetables<br />

Tuber vegetables<br />

Herbaceous fruit<br />

Shrub fruit<br />

Tree fruit<br />

1.50E+02 Fraction of site cover (m 2 m -2 ) 0.8<br />

Dry weight conversion<br />

factor<br />

* Air dispersion factor in g m -2 s -1 per kg m -3<br />

Homegrown fraction<br />

Average High<br />

g DW g -1 FW dimensionless g g -1 DW dimensionless<br />

0.096 0.05 0.33 1.00E-03 2.00E-01<br />

0.103 0.06 0.40 1.00E-03 1.00E+00<br />

0.210 0.02 0.13 1.00E-03 1.00E+00<br />

0.058 0.06 0.40 1.00E-03 6.00E-01<br />

0.166 0.09 0.60 1.00E-03 6.00E-01<br />

0.157 0.04 0.27 1.00E-03 6.00E-01<br />

Gardener type None<br />

Soil loading<br />

factor<br />

Preparation<br />

correction factor


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Page 1 of 11<br />

Report generated<br />

Report title<br />

Created by<br />

RESULTS<br />

20-Jun-11<br />

Proposed New Tesco Store at Wallneuk Paisley <strong>Renfrewshire</strong><br />

Stephen Milne at DAM Geotechnical Services


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 2 of 11<br />

Assessment Criterion (mg kg -1 ) Ratio of ADE to HCV 50% rule?<br />

Saturation Limit (mg kg<br />

oral inhalation combined oral inhalation combined Oral Inhal<br />

-1 )<br />

1 Benzo(a)pyrene 3.94E+01 1.04E+02 2.86E+01 0.73 0.27 1.00 9.11E-01 (vap) No No<br />

2 Dibenzo(ah)anthracene 3.94E+01 1.06E+02 2.87E+01 0.73 0.27 1.00 3.93E-03 (vap) No No<br />

3 Phenol 1.54E+06 3.62E+04 3.53E+04 0.02 0.98 1.00 3.78E+04 (vap) No No<br />

4 Cyanide (Free) 1.71E+04 1.57E+06 1.70E+04 0.99 0.01 1.00 NR No No<br />

5<br />

6<br />

7<br />

8<br />

9<br />

10<br />

11<br />

12<br />

13<br />

14<br />

15<br />

16<br />

17<br />

18<br />

19<br />

20


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 3 of 11<br />

21<br />

22<br />

23<br />

24<br />

25<br />

26<br />

27<br />

28<br />

29<br />

30<br />

Assessment Criterion (mg kg -1 ) Ratio of ADE to HCV 50% rule?<br />

Saturation Limit (mg kg<br />

oral inhalation combined oral inhalation combined Oral Inhal<br />

-1 )


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 4 of 11<br />

Soil Distribution Media Concentrations<br />

% % % % mg kg -1<br />

mg m -3<br />

mg kg -1<br />

mg m -3<br />

mg m -3<br />

mg m -3<br />

mg m -3<br />

mg m -3<br />

mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW<br />

1 Benzo(a)pyrene 100.0 0.0 0.0 100.0 2.86E+01 6.73E-05 0.00E+00 3.44E-07 1.95E-07 3.70E-09 1.62E-06 9.15E-07 NA NA NA NA NA NA<br />

2 Dibenzo(ah)anthracene 100.0 0.0 0.0 100.0 2.87E+01 1.43E-04 0.00E+00 3.45E-07 1.95E-07 7.79E-09 1.35E-06 7.67E-07 NA NA NA NA NA NA<br />

3 Phenol 70.3 29.7 0.0 100.0 3.53E+04 4.30E+02 1.77E+04 4.25E-04 2.41E-04 2.35E-02 9.37E-02 5.31E-02 NA NA NA NA NA NA<br />

4 Cyanide (Free) 100.0 0.0 0.0 100.0 1.70E+04 NR 0.00E+00 2.04E-04 1.15E-04 0.00E+00 0.00E+00 0.00E+00 NA NA NA NA NA NA<br />

5<br />

6<br />

7<br />

8<br />

9<br />

10<br />

11<br />

12<br />

13<br />

14<br />

15<br />

16<br />

17<br />

18<br />

19<br />

20<br />

Sorbed<br />

Dissolved<br />

Vapour<br />

Total<br />

Soil<br />

Soil gas<br />

Indoor Dust<br />

Outdoor dust<br />

at 0.8m<br />

Outdoor dust<br />

at 1.6m<br />

Indoor<br />

Vapour<br />

Outdoor<br />

vapour at<br />

0.8m<br />

Outdoor<br />

vapour at<br />

1.6m<br />

Green<br />

vegetables<br />

Root<br />

vegetables<br />

Tuber<br />

vegetables<br />

Herbaceous<br />

fruit<br />

Shrub fruit<br />

Tree fruit


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 5 of 11<br />

21<br />

22<br />

23<br />

24<br />

25<br />

26<br />

27<br />

28<br />

29<br />

30<br />

Sorbed<br />

Soil Distribution Media Concentrations<br />

Dissolved<br />

Vapour<br />

Total<br />

Soil<br />

% % % % mg kg -1<br />

Soil gas<br />

mg m -3<br />

Indoor Dust<br />

mg kg -1<br />

Outdoor dust<br />

at 0.8m<br />

mg m -3<br />

Outdoor dust<br />

at 1.6m<br />

mg m -3<br />

Indoor<br />

Vapour<br />

mg m -3<br />

Outdoor<br />

vapour at<br />

0.8m<br />

mg m -3<br />

Outdoor<br />

vapour at<br />

1.6m<br />

mg m -3<br />

Green<br />

vegetables<br />

Root<br />

vegetables<br />

Tuber<br />

vegetables<br />

Herbaceous<br />

fruit<br />

mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW mg kg -1 FW<br />

Shrub fruit<br />

Tree fruit


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 6 of 11<br />

Average Daily Exposure (mg kg -1 bw day -1 )<br />

Distribution by Pathway (%)<br />

1 Benzo(a)pyrene 1.29E-05 0.00E+00 1.65E-06 1.64E-08 2.80E-09 0.00E+00 0.00E+00 88.53 0.00 11.34 0.11 0.00 0.02 0.00 0.00<br />

2 Dibenzo(ah)anthracene 1.29E-05 0.00E+00 1.65E-06 1.64E-08 2.56E-09 0.00E+00 0.00E+00 88.53 0.00 11.34 0.11 0.00 0.02 0.00 0.00<br />

3 Phenol 1.59E-02 0.00E+00 7.88E-03 1.02E-04 1.23E-03 5.00E-03 5.71E-04 51.82 0.00 25.67 0.33 3.52 0.50 16.29 1.86<br />

4 Cyanide (Free) 7.63E-03 0.00E+00 0.00E+00 9.72E-06 0.00E+00 4.29E-03 8.57E-07 63.98 0.00 0.00 0.08 0.00 0.00 35.93 0.01<br />

5<br />

6<br />

7<br />

8<br />

9<br />

10<br />

11<br />

12<br />

13<br />

14<br />

15<br />

16<br />

17<br />

18<br />

19<br />

20<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

and attached soil<br />

Dermal contact with<br />

soil and dust<br />

Inhalation of dust<br />

Inhalation of vapour<br />

Background (oral)<br />

Background<br />

(inhalation)<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

and attached soil<br />

Dermal contact with<br />

soil and dust<br />

Inhalation of dust<br />

Inhalation of vapour<br />

(indoor)<br />

Inhalation of vapour<br />

(outdoor)<br />

Background (oral)<br />

Background<br />

(inhalation)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 7 of 11<br />

21<br />

22<br />

23<br />

24<br />

25<br />

26<br />

27<br />

28<br />

29<br />

30<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

and attached soil<br />

Average Daily Exposure (mg kg -1 bw day -1 )<br />

Dermal contact with<br />

soil and dust<br />

Inhalation of dust<br />

Inhalation of vapour<br />

Background (oral)<br />

Background<br />

(inhalation)<br />

Direct soil ingestion<br />

Consumption of<br />

homegrown produce<br />

Dermal contact with<br />

soil and dust<br />

Distribution by Pathway (%)<br />

Inhalation of dust<br />

Inhalation of vapour<br />

(indoor)<br />

Inhalation of vapour<br />

(outdoor)<br />

Background (oral)<br />

Background<br />

(inhalation)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 8 of 11<br />

1 Benzo(a)pyrene ID 0.02 ID 0.00007 NR NR 1.76E-06 4.38E-06 3.67E-10 5.11 6.18 0.13 0 1 1 1<br />

2 Dibenzo(ah)anthracene ID 0.02 ID 0.00007 NR NR 5.40E-06 4.08E-06 3.40E-10 5.27 6.38 0.13 0 1 1 1<br />

3 Phenol TDI 700 TDI 10 350 40 8.35E-06 7.90E-06 6.36E-10 1.92 1.48 0.3 0.5 1 1 1<br />

4 Cyanide (Free) TDI 12 TDI 0.9 300 0.06 NR NR NR NR NR 0 0 1 1 1<br />

5<br />

6<br />

7<br />

8<br />

9<br />

10<br />

11<br />

12<br />

13<br />

14<br />

15<br />

16<br />

17<br />

18<br />

19<br />

20<br />

Oral Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Inhalation Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Oral Mean Daily Intake<br />

(μg day -1 )<br />

Inhalation Mean Daily Intake<br />

(μg day -1 )<br />

Air-water partition coefficient<br />

(Kaw) (cm 3 cm -3 )<br />

Coefficient of Diffusion in Air<br />

(m 2 s -1 )<br />

Coefficient of Diffusion in Water<br />

(m 2 s -1 )<br />

log K oc (cm 3 g -1 )<br />

log K ow (dimensionless)<br />

Dermal Absorption Fraction<br />

(dimensionless)<br />

Soil-to-dust transport factor (g<br />

g -1 DW)<br />

Sub-surface soil to indoor air<br />

correction factor<br />

(dimensionless)<br />

Relative bioavailability via soil<br />

ingestion (unitless)<br />

Relative bioavailability via dust<br />

inhalation (unitless)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 9 of 11<br />

21<br />

22<br />

23<br />

24<br />

25<br />

26<br />

27<br />

28<br />

29<br />

30<br />

Oral Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Inhalation Health Criteria Value<br />

(μg kg -1 BW day -1 )<br />

Oral Mean Daily Intake<br />

(μg day -1 )<br />

Inhalation Mean Daily Intake<br />

(μg day -1 )<br />

Air-water partition coefficient<br />

(Kaw) (cm 3 cm -3 )<br />

Coefficient of Diffusion in Air<br />

(m 2 s -1 )<br />

Coefficient of Diffusion in Water<br />

(m 2 s -1 )<br />

log K oc (cm 3 g -1 )<br />

log K ow (dimensionless)<br />

Dermal Absorption Fraction<br />

(dimensionless)<br />

Soil-to-dust transport factor (g<br />

g -1 DW)<br />

Sub-surface soil to indoor air<br />

correction factor<br />

(dimensionless)<br />

Relative bioavailability via soil<br />

ingestion (unitless)<br />

Relative bioavailability via dust<br />

inhalation (unitless)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 10 of 11<br />

1 Benzo(a)pyrene 7.47E+02 2.00E-08 3.80E-03 0.0125 dw 0.00221 dw model model model model<br />

2 Dibenzo(ah)anthracene 1.08E+03 1.66E-10 6.00E-04 0.00486 dw 0.00209 dw model model model model<br />

3 Phenol 4.82E-01 1.15E+01 8.41E+04 model model model 0.00E+00 0.00E+00 model<br />

4 Cyanide (Free) 1.00E+03 NR 0.00E+00 model model model model model model<br />

5<br />

6<br />

7<br />

8<br />

9<br />

10<br />

11<br />

12<br />

13<br />

14<br />

15<br />

16<br />

17<br />

18<br />

19<br />

20<br />

Soil-to-water partition coefficient<br />

(cm 3 g -1 )<br />

Vapour pressure (Pa)<br />

Water solubility (mg L -1 )<br />

Soil-to-plant concentration factor<br />

for green vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for root vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for tuber vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for herbaceous fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for shrub fruit<br />

(mg g -1 plant DW or FW basis<br />

over mg g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for tree fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)


090930 CLEA v1.06 Software Wallneuk Rd Paisley (2)<br />

CLEA Software Version 1.06 Report generated 20-Jun-11<br />

Page 11 of 11<br />

21<br />

22<br />

23<br />

24<br />

25<br />

26<br />

27<br />

28<br />

29<br />

30<br />

Soil-to-water partition coefficient<br />

(cm 3 g -1 )<br />

Vapour pressure (Pa)<br />

Water solubility (mg L -1 )<br />

Soil-to-plant concentration factor<br />

for green vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for root vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for tuber vegetables (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for herbaceous fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for shrub fruit<br />

(mg g -1 plant DW or FW basis<br />

over mg g -1 DW soil)<br />

Soil-to-plant concentration factor<br />

for tree fruit (mg g -1<br />

plant DW or FW basis over mg<br />

g -1 DW soil)


- 20 -<br />

APPENDIX B<br />

LABORATORY RESULTS-REVISED STATISTICAL ANALYSIS


DAM Geotechnical Services Ltd<br />

SITE/JOB No<br />

GA 9692 Tesco Wallneuk Rd Paisley 95% (UCL) EPC/RCC<br />

MAXIMUM VALUE TEST<br />

Location Depth m bgl<br />

Assessment<br />

Criteria<br />

Commercial/<br />

Industrial pH As Cd Cr Pb Hg Se Cu Ni Zn As log TPH Total (Max Value Test<br />

CLEA UK v1.06* 6253 128041 606825<br />

SGV 2009** 640 230 410 13000 1800<br />

SGV 10 750<br />

BRE SD1 2001 5--9<br />

Laboratory Detection Limit mg/kg<br />

1.00 1.00 5.00 10.00 1.00 1.00 10.00 5.00 10.00 1.00 1.00<br />

BH1 1.20 6.39 1.0 1.6 71.4 10.0 1.0 1.0 10.0 58.1 71.2<br />

BH1 2.10 7.20 1.0 1.0 166.7 10.0 1.0 1.0 10.0 64.5 70.7<br />

BH2 1.20 6.97 1.0 1.0 165.2 10.0 1.0 1.0 10.0 61.5 69.1<br />

BH3 0.60 7.53 1.0 1.0 160.7 54.7 1.0 1.0 33.4 59.1 101.0<br />

BH3 1.65 6.89 1.0 1.0 185.5 10.0 1.0 1.0 10.0 62.0 71.5<br />

BH3 5.00 7.07 1.0 1.0 130.5 10.0 1.0 1.0 10.0 54.5 70.0<br />

BH4 0.80 6.69 1.0 1.0 137.6 68.1 9.0 1.0 19.7 71.5 101.0<br />

BH4 1.65 6.18 1.0 1.0 94.8 10.0 1.0 1.0 10.0 47.2 59.7<br />

BH5 0.80 7.75 1.0 1.0 76.5 10.0 1.0 1.0 23.7 35.7 77.9<br />

BH5 1.65 7.60 1.0 1.0 135.8 20.0 1.0 1.0 10.0 62.8 87.7<br />

BH5 5.00 7.12 1.0 1.0 139.3 10.0 1.0 1.0 10.0 56.8 67.6<br />

BH6 0.80 6.62 6.3 1.0 5.0 117.5 15.7 1.0 59.8 71.9 201.0<br />

BH6 2.10 6.94 1.0 1.0 161.1 10.0 1.0 1.0 10.0 54.1 68.5<br />

BH7 1.00 7.56 1.0 3.1 168.0 378.5 16.2 1.0 203.1 91.9 483.0<br />

BH7 4.00 6.49 1.0 2.1 102.3 88.3 3.4 1.0 26.9 76.2 112.0<br />

BH7 7.00 6.67 1.0 1.1 115.5 39.7 1.0 1.0 10.0 57.5 82.6<br />

BH8 1.00 7.51 1.0 1.0 300.0 51.3 1.0 1.0 67.7 166.9 167.5<br />

BH8 2.50 6.45 1.0 1.4 15.2 23.6 1.0 1.0 10.0 28.1 48.9<br />

BH9 1.00 7.97 2.5 6.7 107.9 187.6 1.0 1.0 124.5 48.8 121.0<br />

BH9 4.00 7.49 1.0 3.0 160.7 10.0 1.0 1.0 10.0 63.3 70.3<br />

BH10 1.00 6.83 1.0 1.2 5.0 10.0 1.4 1.0 10.0 22.3 36.7<br />

BH10 1.65 6.71 6.0 12.8 135.7 10.0 1.0 1.0 10.0 50.1 65.5<br />

BH10 3.00 6.76 1.0 1.0 192.6 10.0 1.0 1.0 10.0 58.1 73.0<br />

BH11 1.00 6.28 1.0 7.3 179.9 153.8 27.3 1.0 180.0 234.2 257.8<br />

BH11 2.10 7.41 1.0 3.4 98.7 10.0 1.0 1.0 10.0 65.9 74.6<br />

BH11 3.00 7.28 2.6 1.0 100.4 10.0 1.0 1.0 10.0 20.9 39.2<br />

BH11 4.50 6.97 1.0 6.6 58.4 10.0 1.0 1.0 10.0 13.1 24.4<br />

BH11 6.00 7.10 3.0 3.3 77.5 10.0 1.0 1.0 10.0 26.8 61.8<br />

BH12 1.00 7.60 103.6 1.0 2948.5 10.0 11.7 1.0 496.9 130.3 311.0<br />

BH12 7.00 7.26 1.0 1.0 128.8 10.0 1.0 1.0 10.0 41.9 57.8<br />

BH13 1.00 6.84 1.0 1.0 128.4 17.2 1.0 1.0 10.0 71.2 75.8<br />

BH13 4.00 7.45 10.2 3.6 95.7 10.0 1.0 1.0 10.0 53.3 65.4<br />

BH14 1.00 7.45 1.0 1.0 179.1 10.0 1.0 1.0 10.0 59.2 66.9<br />

BH14 1.65 7.19 1.0 1.0 189.9 10.0 3.1 1.0 10.0 55.4 70.0<br />

Min Value<br />

Max Value<br />

Location Depth (m)<br />

Assessment<br />

Criteria<br />

Commercial/<br />

Industrial<br />

As log TPH Total (Max Value Test<br />

6.18 1.00 1.00 5.00 10.00 1.00 1.00 10.00 13.10 24.40 0.00 0.00 0.00 0.00<br />

7.97 103.60 12.80 2948.50 378.50 27.30 1.00 496.90 234.20 483.00 0.00 0.00 0.00 0.00<br />

34.00 34.00 34.00 34.00 34.00 34.00 34.00 34.00 34.00 34.00 0.00 0.00 0.00 0.00<br />

33.00 33.00 33.00 33.00 33.00 33.00 33.00 33.00 33.00 33.00 -1.00 -1.00 -1.00 -1.00<br />

7.06 4.74 2.27 209.36 41.77 3.35 1.00 43.40 64.56 102.41 mean (log) #DIV/0! mean (log) #DIV/0!<br />

0.45 17.58 2.56 487.59 73.79 5.88 0.00 92.99 41.38 89.90 stdev (log) #DIV/0! stdev (log) #DIV/0!<br />

1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 Max Value Tes #DIV/0! Max Value Test #DIV/0!<br />

7.19 9.86 3.01 351.27 63.25 5.06 1.00 70.47 76.60 128.58 T Crit (10%) 2.38 T Crit (10%) 2.21<br />

LCL 6.16<br />

PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS Max Value Test #DIV/0! Max Value Test #DIV/0!<br />

* Values derived using CLEA v1.06 + December 2009 Guidance Documents: Science Reports (SC050021/SR2) and (SC050021/SR3) which Replaces CLR9 and CLR10 N/s Not scheduled N/d Not Detected<br />

** Values for Arsenic,Mercury, Selenium, Nickel and BTEX compounds have now been published (May 12th 2009) in conjunction with new TOX Reports (http://www.environment-agency.gov.uk/research/planning/64015.aspx)<br />

Guidance on Comparing Soil Contamination Data with a Critical Concentration: Chartered Institute of Environmental Health (CIEH) and (CL:AIRE) May 2008 (Supercedes CLR7<br />

The RCC Represents the 95th Percentile (UCL) Dection Limits are Based on 2009 values (see previous risk assessment)<br />

t derived from Table A1 (Appendix A pp46)<br />

Assessment<br />

T crit from Table B1 (Appendix A) pp50<br />

Location Depth<br />

Criteria<br />

Commercial/<br />

Industrial<br />

nC5-6 >nC6-nC8 >nC8-nC10<br />

Total TPH- Organic<br />

>nC10-nC12 >nC12-nC16 >nC16-nC21 >nC21-nC35<br />

(nC5-nC35) matter %<br />

TOC %<br />

Loss on<br />

Ignition@<br />

440 0 n<br />

n-1<br />

arithmetic mean<br />

stdev<br />

t<br />

Mean Value Test 95%ile (UCL/RCC)<br />

PASS/FAIL<br />

C %<br />

Asbestos<br />

Fibres<br />

Soluble<br />

Free Cyanide<br />

Sulphate 2:1<br />

CLEA UK v1.06*<br />

See speciated TPHCWG Banding for assessment criteria<br />

SNIFFER 50<br />

BS1377 1990 25<br />

BRE SD1 1.2<br />

Laboratory Reporting Limit mg/kg<br />

0.50 0.50 0.50 0.50 1.00 1.00 3.00 10.00 0.10 0.10 0.10 Visual Screen 2.50 0.001g/l<br />

BH1 1.20 N/A N/A N/A N/A N/A N/A N/A 28.48 N/S N/S 0.1 N/D 2.50 0.069<br />

BH1 2.10 N/A N/A N/A N/A N/A N/A N/A 36.42 N/S N/S 0.1 N/D 2.50 0.048<br />

BH2 1.20 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.051<br />

BH3 0.60 N/A N/A N/A N/A N/A N/A N/A 52.30 N/S N/S 0.1 N/D 2.50 0.048<br />

BH3 1.65 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.038<br />

BH3 5.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.226<br />

BH4 0.80 N/A N/A N/A N/A N/A N/A N/A 20.59 N/S N/S 0.1 N/D 2.50 0.062<br />

BH4 1.65 N/A N/A N/A N/A N/A N/A N/A 45.64 N/S N/S 0.1 N/D 2.50 0.065<br />

BH5 0.80 N/A N/A N/A N/A N/A N/A N/A 40.79 N/S N/S 0.1 N/D 2.50 0.075<br />

BH5 1.65 N/A N/A N/A N/A N/A N/A N/A 53.24 N/S N/S 0.1 N/D 2.50 0.075<br />

BH5 5.00 N/A N/A N/A N/A N/A N/A N/A 37.42 N/S N/S 0.1 N/D 2.50 0.172<br />

BH6 0.80 N/A N/A N/A N/A N/A N/A N/A 59.30 N/S N/S 0.1 N/D 2.50 0.065<br />

BH6 2.10 N/A N/A N/A N/A N/A N/A N/A 28.70 N/S N/S 0.1 N/D 2.50 0.069<br />

BH7 1.00 N/A N/A N/A N/A N/A N/A N/A 27.29 N/S N/S 0.1 N/D 2.50 0.045<br />

BH7 4.00 N/A N/A N/A N/A N/A N/A N/A 28.13 N/S N/S 0.1 N/D 2.50 0.034<br />

BH7 7.00 N/A N/A N/A N/A N/A N/A N/A 31.10 N/S N/S 0.1 N/D 2.50 0.055<br />

BH8 1.00 N/A N/A N/A N/A N/A N/A N/A 36.70 N/S N/S 0.1 N/D 2.50 0.240<br />

BH8 2.50 N/A N/A N/A N/A N/A N/A N/A 32.48 N/S N/S 0.1 N/D 2.50 0.072<br />

BH9 1.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.065<br />

BH9 4.00 N/A N/A N/A N/A N/A N/A N/A 15.60 N/S N/S 0.1 N/D 2.50 0.045<br />

BH10 1.00 N/A N/A N/A N/A N/A N/A N/A 40.19 N/S N/S 0.1 N/D 2.50 0.041<br />

BH10 1.65 N/A N/A N/A N/A N/A N/A N/A 43.58 N/S N/S 0.1 N/D 2.50 0.058<br />

BH10 3.00 N/A N/A N/A N/A N/A N/A N/A 48.00 N/S N/S 0.1 N/D 2.50 0.031<br />

BH11 1.00 N/A N/A N/A N/A N/A N/A N/A 45.30 N/S N/S 0.1 N/D 2.50 0.045<br />

BH11 2.10 N/A N/A N/A N/A N/A N/A N/A 45.16 N/S N/S 0.1 N/D 2.50 0.062<br />

BH11 3.00 N/A N/A N/A N/A N/A N/A N/A 52.91 N/S N/S 0.1 N/D 2.50 0.045<br />

BH11 4.50 N/A N/A N/A N/A N/A N/A N/A 49.35 N/S N/S 0.1 N/D 2.50 0.038<br />

BH11 6.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.051<br />

BH12 1.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.048<br />

BH12 7.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.2 N/D 2.50 0.041<br />

BH13 1.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.051<br />

BH13 4.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.051<br />

BH14 1.00 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.045<br />

BH14 1.65 N/A N/A N/A N/A N/A N/A N/A 10.00 N/S N/S 0.1 N/D 2.50 0.048<br />

Min Value<br />

0.00 0.00 0.00 0.00 0.00 0.00 0.00 10.00 0.00 0.00 0.05 2.50 0.031<br />

Max Value<br />

0.00 0.00 0.00 0.00 0.00 0.00 0.00 59.30 0.00 0.00 0.23 2.50 0.240<br />

n<br />

0.00 0.00 0.00 0.00 0.00 0.00 0.00 34.00 0.00 0.00 34.00 34.00 34.00<br />

n-1<br />

-1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 33.00 -1.00 -1.00 33.00 33.00 33.00<br />

arithmetic mean<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 29.67 #DIV/0! #DIV/0! 0.06 2.50 0.07<br />

stdev<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 16.59 #DIV/0! #DIV/0! 0.03 0.00 0.05<br />

t<br />

1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70<br />

Mean Value Test 95%ile (RCC)<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 34.50 #DIV/0! #DIV/0! 0.07 2.50 0.081<br />

PASS/FAIL<br />

N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A PASS PASS PASS<br />

TPH Analysis follows best practice- LQM and Science Report P5-080/TR3 The UK Approach for Evaluating Human Health Risks from Petroleum Hydrocarbons in Soils. TPH is banded in the first instance based upon TPH CWG groups and a Total Value<br />

Obtained. Should values be detcected above the laboratory reporting limit, then these values are "split" into aromatic/aliphatic bands in order to risk assess using derived (CLEA v 1.06 December 2009) values. An assessment as to the inhaltion vapour<br />

pathway can then be conducted in order to quantify any risk(s) posed by the presence in particluar of low range (nC6-nC12) aromatic compouds. Dectection limits based on 2009 values. (C5-C35 group banding not condcuted in 2009)<br />

phenol<br />

2-chlorophenol<br />

2-methylphenol<br />

4-methylphenol<br />

TOTAL/SPECIATED PHENOLS<br />

2-nitrophenol<br />

2,4-dimethylphenol<br />

SGV 2009**<br />

1% SOM mg/kg 38000<br />

2.5% SOM mg/kg Long Term<br />

5% SOM mg/kg Exposure<br />

Laboratory Detection Limit mg/kg<br />

0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.10<br />

BH1 1.20 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH1 2.10 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH2 1.20 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH3 0.60 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH3 1.65 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH3 5.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH4 0.80 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH4 1.65 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH5 0.80 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH5 1.65 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH5 5.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH6 0.80 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH6 2.10 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH7 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH7 4.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH7 7.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH8 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH8 2.50 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH9 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH9 4.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH10 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH10 1.65 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH10 3.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH11 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH11 2.10 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH11 3.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH11 4.50 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH11 6.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH12 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH12 7.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.2<br />

BH13 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH13 4.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH14 1.00 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

BH14 1.65 N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S N/S 0.1<br />

Min Value<br />

Max Value<br />

n<br />

n-1<br />

arithmetic mean<br />

stdev<br />

t<br />

Mean Value Test 95%ile (RCC)<br />

PASS/FAIL<br />

2,4-dichlorophenol<br />

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.05<br />

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.05 0.00 0.00 0.23<br />

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 34.00<br />

-1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 33.00<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.06<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.03<br />

1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68 1.68<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! 0.07<br />

N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A PASS<br />

Phenols are now specited using GC/MS. Total phenols (monohydritic) is assigned an Applicable value from Table 2 pp4 of the New 2009 SGV published in June 2009.<br />

2,6-dichlorophenol<br />

4-chloro-3-methyl-phenol<br />

2,4,6-trichlorophenol<br />

2,4,5-trichlorophenol<br />

4-nitrophenol<br />

2,3,4,6-tetrachlorophenol<br />

pentachlorophenol<br />

TOTAL Phenol (mg/kg)<br />

Proposed New Tesco Retail Store<br />

at Wallneuk Road Paisley<br />

GA 9692<br />

Z:\_Public\GA CONTRACTS\GA 9692\Phase II\Revised RA June 2011\GA 9692 UCL-MAX Value 2 1


DAM Geotechnical Services Ltd<br />

Location Depth (m)<br />

Assessment<br />

Criteria<br />

Commercial/<br />

Industrial<br />

Aromatic (C5-C6)<br />

Aromatic (C6-C8)<br />

Aromatic (C8-C10)<br />

Aromatic (C10-C12)<br />

TPHCWG (AROMATIC/ALIPHATIC SPLIT)<br />

Aromatic (C12-C16)<br />

Aromatic (C16-C21)<br />

CLEA UK v1.06*<br />

1% SOM mg/kg<br />

2.5% SOM mg/kg<br />

5% SOM mg/kg<br />

95.00 4440 1105 5952 27216 60583 60642 41.60 2763 493 4700 24970 4045004 4045004<br />

Laboratory Detection Limit mg/kg<br />

1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 10.00<br />

BH3 0.60 1.00 1.00 1.00 2.99 7.66 18.50 1.00 1.00 1.00 1.00 1.00 23.15 1.00 1.00 52.30<br />

BH4 1.65 1.00 1.00 1.00 8.90 12.20 1.00 1.00 1.00 1.00 1.00 13.77 1.00 10.77 1.00 45.64<br />

BH5 0.80 1.00 1.00 1.00 1.00 22.33 1.00 1.00 1.00 1.00 1.00 9.70 2.55 6.21 1.00 40.79<br />

BH5 1.65 1.00 1.00 1.00 5.61 12.22 8.95 1.00 1.00 1.00 1.00 13.23 10.74 2.49 1.00 53.24<br />

BH6 0.80 1.00 1.00 1.00 1.00 20.00 6.19 1.00 1.00 1.00 1.00 3.77 29.34 1.00 1.00 59.30<br />

BH10 1.00 1.00 1.00 1.00 1.00 1.00 11.15 1.00 1.00 1.00 1.00 6.55 12.37 10.12 1.00 40.19<br />

BH10 1.65 1.00 1.00 1.00 10.71 22.33 1.00 1.00 1.00 1.00 1.00 8.43 1.00 2.11 1.00 43.58<br />

BH10 3.00 1.00 1.00 1.00 1.00 11.91 10.53 1.00 1.00 1.00 1.00 6.12 1.00 19.44 1.00 48.00<br />

BH11 1.00 1.00 1.00 1.00 12.11 1.00 9.72 10.44 1.00 1.00 1.00 8.88 4.15 1.00 1.00 45.30<br />

BH11 2.10 1.00 1.00 1.00 16.14 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 29.02 1.00 45.16<br />

BH11 3.00 1.00 1.00 1.00 1.00 13.76 6.22 1.00 1.00 1.00 1.00 11.98 20.95 1.00 1.00 52.91<br />

BH11 4.50 1.00 1.00 1.00 1.00 1.00 24.89 1.00 1.00 1.00 1.00 8.13 16.38 1.00 1.00 49.35<br />

Min Value<br />

Max Value<br />

n<br />

n-1<br />

arithmetic mean<br />

stdev<br />

t<br />

Mean Value Test 95%ile (RCC)<br />

PASS/FAIL<br />

Aromatic (C21-C35)<br />

Aliphatic (C5-C6)<br />

1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 40.19<br />

1.00 1.00 1.00 16.14 22.33 24.89 10.44 1.00 1.00 1.00 13.77 0.05 29.02 1.00 59.30<br />

12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00 12.00<br />

11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00 11.00<br />

1.00 1.00 1.00 5.21 10.53 8.35 1.79 1.00 1.00 1.00 7.71 10.30 7.10 1.00 47.98<br />

0.00 0.00 0.00 5.41 8.30 7.49 2.73 0.00 0.00 0.00 4.27 10.12 8.99 0.00 5.66<br />

1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78 1.78<br />

1.00 1.00 1.00 7.99 14.80 12.20 3.19 1.00 1.00 1.00 9.91 15.51 11.72 1.00 50.89<br />

PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS N/A<br />

* Values derived using CLEA v1.06 + December 2009 Guidance Documents: Science Reports (SC050021/SR2)/(SC050021/SR3) and SC050021/SR7) which Replaces CLR9 and CLR10 and<br />

Additional guidance provide by LQM and Science Report P5-080/TR3 The UK Approach for Evaluating Human Health Risks from Petroleum Hydrocarbons in Soils<br />

See Accompanying (Risk Assessment Apendix A for CLEA v1.06 Inputs) Dection Limits based on 2009 values<br />

naphthalene<br />

acenaphthylene<br />

acenaphthene<br />

USEPA SPECIATED PAH 16 Results<br />

fluorene<br />

phenanthrene<br />

anthracene<br />

fluoranthene<br />

Location Depth<br />

Assessment<br />

Criteria<br />

Commercial/<br />

Industrial<br />

CLEA UK v1.06* 208 66985 28.59 28.69<br />

Laboratory Detection Limit mg/kg<br />

0.01 0.1 0.1 0.01 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.01 0.1 0.01 0.1 0.1<br />

See Bodycote Results in Factual Report 0.01 0.10 0.10 0.01 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.01 0.10 0.01 0.10 0.1<br />

Min Value<br />

#REF! #REF! #REF! 0.01 #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! 0.01 #REF! #REF! #REF!<br />

Max Value<br />

0.01 #REF! #REF! 0.01 #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! 0.01 #REF! #REF! #REF!<br />

n<br />

1.00 0.00 0.00 1.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.00 0.00 1.00 0.00<br />

n-1<br />

0.00 -1.00 -1.00 0.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 -1.00 0.00 -1.00 0.00 -1.00<br />

arithmetic mean<br />

0.01 #REF! #REF! 0.01 #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! 0.01 #REF! 0.01 #REF!<br />

stdev<br />

#DIV/0! #REF! #REF! #DIV/0! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #DIV/0! #REF! #DIV/0! #REF!<br />

t<br />

1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74 1.74<br />

Mean Value Test 95%ile (RCC)<br />

#DIV/0! #REF! #REF! #DIV/0! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #REF! #DIV/0! #REF! #DIV/0! #REF!<br />

PASS/FAIL<br />

#DIV/0! N/A N/A #DIV/0! N/A N/A N/A N/A N/A N/A N/A N/A #DIV/0! N/A #DIV/0! N/A<br />

** Values derived using CLEA v1.06 December 2009 (http://www.environment-agency.gov.uk/research/planning/40397.aspx) in conjunction with Guidance Documents: Science Reports (SC050021/SR2) (SC050021/SR3) and (SC050021/SR7) which Replaces CLR9 and CLR10<br />

Risk Driver Compounds have derived SGV applied highlighted in Red<br />

See Risk Assesment (Section 9.0) for current Rationale The Environment Agency are due to publish SGV values for PAH compounds throughout 2010<br />

Where laboratory results are less then the LDL (Laboratory Detection Limit) the laboratory detection limit is returned for statistical analysis (i.e a whole number)<br />

Assessment<br />

Criteria<br />

Commercial/ Benzene Toluene Ethyl-Benzene M- Xylene O-Xylene P- Xylene<br />

Location Depth m bgl Industrial<br />

SGV 2009**<br />

1% SOM<br />

2.5% SOM<br />

5% SOM<br />

95.00 4440 2800 3500 2600 3200<br />

Laboratory Detection Limit mg/kg<br />

0.05 0.05 0.05 0.10 0.05 0.05<br />

BH1 1.20 N/S N/S N/S N/S N/S N/S<br />

BH1 2.10 N/S N/S N/S N/S N/S N/S<br />

BH2 1.20 N/S N/S N/S N/S N/S N/S<br />

BH3 0.60 N/S N/S N/S N/S N/S N/S<br />

BH3 1.65 N/S N/S N/S N/S N/S N/S<br />

BH3 5.00 N/S N/S N/S N/S N/S N/S<br />

BH4 0.80 N/S N/S N/S N/S N/S N/S<br />

BH4 1.65 N/S N/S N/S N/S N/S N/S<br />

BH5 0.80 N/S N/S N/S N/S N/S N/S<br />

BH5 1.65 N/S N/S N/S N/S N/S N/S<br />

BH5 5.00 N/S N/S N/S N/S N/S N/S<br />

BH6 0.80 N/S N/S N/S N/S N/S N/S<br />

BH6 2.10 N/S N/S N/S N/S N/S N/S<br />

BH7 1.00 N/S N/S N/S N/S N/S N/S<br />

BH7 4.00 N/S N/S N/S N/S N/S N/S<br />

BH7 7.00 N/S N/S N/S N/S N/S N/S<br />

BH8 1.00 N/S N/S N/S N/S N/S N/S<br />

BH8 2.50 N/S N/S N/S N/S N/S N/S<br />

BH9 1.00 N/S N/S N/S N/S N/S N/S<br />

BH9 4.00 N/S N/S N/S N/S N/S N/S<br />

BH10 1.00 N/S N/S N/S N/S N/S N/S<br />

BH10 1.65 N/S N/S N/S N/S N/S N/S<br />

BH10 3.00 N/S N/S N/S N/S N/S N/S<br />

BH11 1.00 N/S N/S N/S N/S N/S N/S<br />

BH11 2.10 N/S N/S N/S N/S N/S N/S<br />

BH11 3.00 N/S N/S N/S N/S N/S N/S<br />

BH11 4.50 N/S N/S N/S N/S N/S N/S<br />

BH11 6.00 N/S N/S N/S N/S N/S N/S<br />

BH12 1.00 N/S N/S N/S N/S N/S N/S<br />

BH12 7.00 N/S N/S N/S N/S N/S N/S<br />

BH13 1.00 N/S N/S N/S N/S N/S N/S<br />

BH13 4.00 N/S N/S N/S N/S N/S N/S<br />

BH14 1.00 N/S N/S N/S N/S N/S N/S<br />

BH14 1.65 N/S N/S N/S N/S N/S N/S<br />

Min Value<br />

0.00 0.00 0.00 0.00 0.00 0.00<br />

Max Value<br />

0.00 0.00 0.00 0.00 0.00 0.00<br />

n<br />

0.00 0.00 0.00 0.00 0.00 0.00<br />

n-1<br />

-1.00 -1.00 -1.00 -1.00 -1.00 -1.00<br />

arithmetic mean<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!<br />

stdev<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!<br />

t<br />

1.70 1.70 1.70 1.70 1.70 1.70<br />

Mean Value Test 95%ile (RCC)<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!<br />

PASS/FAIL<br />

N/D not detected<br />

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!<br />

N/S-(Not scheduled) No GRO Compounds (C5-C6) Range detected Thus BTEX not scheduled<br />

pyrene<br />

Aliphatic (C6-C8)<br />

1,2 benzanthracene<br />

Aliphatic (C8-C10)<br />

chrysene<br />

Aliphatic (C10-C12)<br />

benzo(b)fluoranthene<br />

Aliphatic (C12-C16)<br />

benzo(k)fluoranthene<br />

Aliphatic (C16-C21)<br />

benzo-a-pyrene<br />

Aliphatic (C21-C35)<br />

indeno(1,2,3-CD) pyrene<br />

TOTAL TPH (mg/kg)<br />

1,2:5,6 dibenzanthracene<br />

1,12 benzo(g,h,i)perylene<br />

TOTAL PAH 16 components<br />

Proposed New Tesco Retail Store<br />

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- 21 -<br />

APPENDIX C<br />

UKWIR-10/WM/03/21 GUIDANCE FOR THE SELECTION OF WATER<br />

SUPPLY PIPES TO BE LAID IN CONTAMINATED LAND


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íç=ÄÉ=ìëÉÇ=áå=_êçïåÑáÉäÇ=ëáíÉëÛK==<br />

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máéÉ=ã~íÉêá~äë=ëÉäÉÅíáçå=<br />

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réçå=êÉÅÉáéí=çÑ=mo^=~åÇ=pfI=^åÖäá~å=t~íÉê=ïáää=<br />

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pÉäÉÅíáçå=q~ÄäÉ=çå=é~ÖÉ=RK=


Pipe Selection Table 2<br />

máéÉ=ã~íÉêá~ä=<br />

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^ää=íÜêÉëÜçäÇ=ÅçåÅÉåíê~íáçåë=~êÉ=áå=ãÖLâÖ=<br />

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tê~ééÉÇ=píÉÉä= tê~ééÉÇ=aìÅíáäÉ=<br />

fêçå=<br />

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EmbJ^fJmbF=<br />

MKR= MKNOR= m~ëë= m~ëë= m~ëë= m~ëë=<br />

N= bñíÉåÇÉÇ=sl`=ëìáíÉ=Äó=éìêÖÉ=~åÇ=íê~é=çê=ÜÉ~Ç=ëé~ÅÉ=<br />

~åÇ=d`Jjp=ïáíÜ=qf`=<br />

N~= H=_qbu=H=jq_b= MKN= MKMP= m~ëë= m~ëë= m~ëë= m~ëë=<br />

O= NKQ= m~ëë= m~ëë= m~ëë= m~ëë=<br />

O= psl`ë=qf`=Äó=éìêÖÉ=~åÇ=íê~é=çê=ÜÉ~Ç=ëé~ÅÉ=~åÇ=d`J<br />

jp=ïáíÜ=qf`=E~äáéÜ~íáÅ=~åÇ=~êçã~íáÅ=`RJ`NMF=<br />

OÉ= H=mÜÉåçäë= O= MKQ= m~ëë= m~ëë= m~ëë= m~ëë=<br />

OÑ= H=`êÉëçäë=~åÇ=ÅÜäçêáå~íÉÇ=éÜÉåçäë= O= MKMQ= m~ëë= m~ëë= m~ëë= m~ëë=<br />

P= jáåÉê~ä=çáä=`NNJ`OM= NM= m~ëë= m~ëë= m~ëë= m~ëë= m~ëë=<br />

J=R=J=<br />

Q= jáåÉê~ä=çáä=`ONJ`QM= RMM= m~ëë= m~ëë= m~ëë= m~ëë= m~ëë=<br />

`çêêçëáîÉ=áÑ=me=YR=<br />

çê=[U=~åÇ=bÜ=<br />

éçëáíáîÉ=<br />

`çêêçëáîÉ=áÑ=ée=YRI=<br />

bÜ=åçí=åÉìíê~ä=<br />

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~åÇ=ÅçåÇìÅíáîáíó=<br />

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= péÉÅáÑáÅ=ëìáíÉ=áÇÉåíáÑáÉÇ=~ë=êÉäÉî~åí=ÑçääçïáåÖ=ëáíÉ=áåîÉëíáÖ~íáçå=<br />

O~= bíÜÉêë= MKR= N= m~ëë= m~ëë= m~ëë= m~ëë=<br />

OÄ= káíêçÄÉåòÉåÉ= MKR= MKQ= m~ëë= m~ëë= m~ëë= m~ëë=<br />

OÅ= hÉíçåÉë= MKR= MKMO= m~ëë= m~ëë= m~ëë= m~ëë=<br />

OÇ= ^äÇÉÜóÇÉë= MKR= MKMO= m~ëë= m~ëë= m~ëë= m~ëë=<br />

S= ^ãáåÉë= c~áä= m~ëë= m~ëë= m~ëë= m~ëë= m~ëë=<br />

2 q~âÉå=Ñêçã=íÜÉ=rhtfo=éìÄäáÅ~íáçå=ÚOSedìáÇ~åÅÉ=Ñçê=íÜÉ=ëÉäÉÅíáçå=çÑ=ï~íÉê=ëìééäó=éáéÉë=íç=ÄÉ=ìëÉÇ=áå=_êçïåÑáÉäÇ=ëáíÉëÛ=<br />

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eÉ~äíÜ=~åÇ=p~ÑÉíó=<br />

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få=çêÇÉê=íç=ã~áåí~áå=íÜÉ=ë~ÑÉíó=çÑ=çìê=ëí~ÑÑI=<br />

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táíÜ=É~ÅÜ=ëáíÉ=~ééäáÅ~íáçå=éäÉ~ëÉ=áåÅäìÇÉ=íÜÉ=<br />

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t~íÉê=ÜÉ~äíÜ=~åÇ=ë~ÑÉíó=êÉèìáêÉãÉåíëK=<br />

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lå=ëáíÉ=êÉãÉÇá~íáçå=çÑ=Åçåí~ãáå~íÉÇ=ëçáä=ã~ó=<br />

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qóéÉ=^_=~áê=Ö~é=<br />

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