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Optoelectronics with Carbon Nanotubes

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The polarization dependence of light absorption and emission has been observed<br />

experimentally in CNTs. Lefebvre et al. has conducted spectral studies of PL and PLE for<br />

different polarizations 119, 134 and EL emission intensity as a function of polarization has also<br />

been measured experimentally 73, 87 . The results from the PL/PLE studies agree <strong>with</strong> the<br />

theoretical prediction that light in parallel polarization couples strongly <strong>with</strong> the E11 and E22<br />

transitions, while the E12 resonance is observed in transverse polarization, although it is much<br />

weaker than the E11 and E22 parallel resonances 119, 134 . A photocurrent study has also shown the<br />

maximum excitation when the light is polarized along the direction of the nanotube 27, 135, 136 .<br />

However, there has never been a spectral study of polarization dependence in EL, which we now<br />

discuss.<br />

Figure III-14. EL intensity as a function of the angle between the tube direction and a<br />

linear polarizer. The ratio of maximum (0 degrees) and minimum (90 degrees) is 3.4<br />

which is extracted from the fit. The large error is mostly due to the instability of the<br />

device.<br />

Figure III-14 shows the polarization of emitted light intensity from a CNTFET. Because<br />

the channel length is much smaller than the spatial resolution of the equipment, the light appears<br />

as a point source and the polarizer transmits the component of the emitted light that aligns <strong>with</strong><br />

the filter direction. The cosine squared fit gives a maximum (at 0 degrees) to minimum (at 90<br />

degrees) ratio of about 3.4, which is similar to the observation of polarization in EL first reported<br />

by Misewich et al. in 2003 73 . In terms of the degree of polarization (DOP), this translates to<br />

61

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