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Optoelectronics with Carbon Nanotubes

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tube has been subjected to much less chemical processing, and it does not rely on percolation for<br />

conduction. But we can never achieve significant total light output <strong>with</strong> the single device<br />

because we cannot pass more than about 1 μA of current <strong>with</strong>out destroying the tube itself.<br />

Ideally, parallel single-tube devices <strong>with</strong> good quality, long small-diameter CNTs that are almost<br />

exclusively semiconducting would be ideal for the maximum light output, but there is much<br />

technical challenge before such a device can be constructed. Our parallel-tube, percolation-<br />

driven devices are the best CNT electrical emitter to date in terms of total light intensity.<br />

(a) (b) (c)<br />

(d)<br />

Figure V-6. Spatial characteristics of EL from a 4-μm CNT light emitting diode<br />

taken at the same sample position. Note that the device dimensions are close to the<br />

resolution limit (~1 μm) of the optical measurement due to both the wavelength of the<br />

detected light and the pixel size. (a) Reflected image of a device showing the source<br />

91

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