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ORNL-4191 - the Molten Salt Energy Technologies Web Site

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The retrieval of <strong>the</strong> sample latch would have<br />

been facilitated had it been magnetic. Therefore,<br />

f.he replacement latch was made of magnetic typte<br />

430 stainless steel instead of type 304 stainless<br />

steel. Ano<strong>the</strong>r change in <strong>the</strong> replacement unit<br />

was <strong>the</strong> addition of a sleeve to bridge <strong>the</strong> 2-in.<br />

gap between <strong>the</strong> cable drive reel and <strong>the</strong> floor<br />

of <strong>the</strong> drive compartment. This wi11 prevent <strong>the</strong><br />

cable from escaping into this compartment if it<br />

meets resistance while being unreeled.<br />

As explajried on p. E, <strong>the</strong> detached capsule is<br />

positively confined by <strong>the</strong> baffle so that it cannot.<br />

escape. Swirl velocities observed in <strong>the</strong> bowl of<br />

<strong>the</strong> prototype salt pump were less than 0.1 fps,<br />

indicating that continual movement of <strong>the</strong> loose<br />

capsule is very unlikely. Nor should <strong>the</strong> capsule<br />

corrode. The body of <strong>the</strong> capsule is copper, and<br />

<strong>the</strong> cap is mild steel with a thin nickel plating<br />

that probably leaves some ferrous metal exposed.<br />

On exposure to t.he molten salt, <strong>the</strong> copper-ironnickel<br />

assemblage in contact with <strong>the</strong> chromiumcontaining<br />

Hastelloy of <strong>the</strong> baffle and lower head<br />

will temporaiily constitute an electrochemical<br />

cell, in which Cr0 from <strong>the</strong> Wastelloy surfaces<br />

will be oxidized to + Cr2 and reduced once again<br />

to Cro metal on <strong>the</strong> capsule surface. This reaction<br />

slows down as <strong>the</strong> chromium activity in <strong>the</strong><br />

capsule surface approaches that of <strong>the</strong> Hastelloy<br />

surfaces. Eventually <strong>the</strong> transfer diminishes to<br />

<strong>the</strong> rate at which <strong>the</strong> chromium can diffuse into<br />

<strong>the</strong> capsule metal. 'The amount of chromium that<br />

can be transferred in this way will have negligible<br />

effect on nearby Hastelloy surfaces. The conclusion<br />

is, <strong>the</strong>refore, that no ill effects will result<br />

from <strong>the</strong> presence of <strong>the</strong> capsule in <strong>the</strong> pump<br />

bowl.<br />

Coolant Sampler. - During this report period,<br />

seven 10-g samples were isolated from <strong>the</strong> coolant<br />

salt pump, bringing <strong>the</strong> total with this sampler to<br />

60. There were no operating difficulties and no<br />

maintenance was required.<br />

Fuel Processing Sampler. - The shielding<br />

around <strong>the</strong> fuel processing sampler was finished,<br />

complet-ing <strong>the</strong> installation of this sampler. The<br />

nylon guide in <strong>the</strong> removal area and <strong>the</strong> manipula-<br />

tor arm were subsequently removed for use in <strong>the</strong><br />

fuel sampler. O<strong>the</strong>r spares are now on hand but<br />

will not be installed until near time for use of <strong>the</strong><br />

processing facility.<br />

33<br />

Containment<br />

I?. 11. Harley R. c. Steffy<br />

Secondary Containment. -- During run 11, <strong>the</strong><br />

containment cell inleakage was measured to be<br />

cu 10 scf/day with <strong>the</strong> cell at .- 2 psig. This de-<br />

termination was made by monitoring <strong>the</strong> cell pres-<br />

sure with <strong>the</strong> Hook gage (a sophisticated water<br />

manometer) and by measuring ,711 known purges<br />

into and out of <strong>the</strong> containment cell. The cell<br />

ptessure arid system purges remained virtuaIly<br />

constant, with small pressure oscillations occur-<br />

ring as <strong>the</strong> outside temperature fluctuated. Thesc<br />

oscillations were particularly not iceable during<br />

<strong>the</strong> colder months.<br />

Between May 16 and June 13, an extensive<br />

contaitirrient check was made. Thirteen block<br />

valves out of a total of 160 were found to be<br />

leaking and were repaired. Five were instrument<br />

air block valves, three were in <strong>the</strong> cover-gas<br />

{helium) system, and five were in <strong>the</strong> treatedwater<br />

syst.em. The most common cause of leakage<br />

was aging elastomer O-rings; a few, however,<br />

had scale, metal filings, or dirt on <strong>the</strong> seating<br />

surfaces. None of <strong>the</strong> valves leaked excessively,<br />

and seven of <strong>the</strong>m are backed by a closed system.<br />

Two o<strong>the</strong>rs are in use .:0.1"/, of <strong>the</strong> time arid are<br />

normally backed by closed hand valves.<br />

At <strong>the</strong> beginning of run 12, <strong>the</strong> secondary con-<br />

tainment vessel leakage was checked with t.he<br />

containment cell at 20 psig. At this pressure <strong>the</strong><br />

cell leaked only "u 28 scf/day. The cell was <strong>the</strong>n<br />

evacuat.ed to - 2 psig, and reactor filling opera-<br />

tions were started.<br />

As during earlier runs, <strong>the</strong>re was a water leak<br />

in <strong>the</strong> cell during tun 12 (this leak is discussed<br />

later iri <strong>the</strong> section). As a result of <strong>the</strong> water<br />

leak <strong>the</strong> first determinations placed <strong>the</strong> cell<br />

leak rate at -270 scf/day. However, as soon as<br />

<strong>the</strong> cell air became saturated, <strong>the</strong> indicated leak<br />

rate dropped to t20 scf/day. This took only<br />

about seven days. For <strong>the</strong> major part of run 12,<br />

<strong>the</strong> indicated cell leak rate remained essentially<br />

constant at ^' 14 scf/day..<br />

For both runs 11 and 12, <strong>the</strong> (:ell leak rate<br />

values were well below <strong>the</strong> 85 scf/day permissible<br />

(extrapolated from accident conditions at a 39-<br />

psig cell pressure).

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