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ORNL-1816 - the Molten Salt Energy Technologies Web Site

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1<br />

I<br />

ANP QUARTERLY PROGRESS REPORT<br />

have developed a suitable composition by using<br />

Sic as <strong>the</strong> bonding material. However, specific<br />

details and samples of <strong>the</strong> material have yet to be<br />

received.<br />

Tubular Fuel Elements<br />

Twelve fuel plates have been prepared for forming<br />

into tubes, and eight more are being prepared.<br />

These tubes are to be drawn at Superior Tube Co.<br />

by <strong>the</strong> plug-drawing technique with low (10%)<br />

reductions. O<strong>the</strong>r techniques such as hot drawing<br />

or hot swaging may be used.<br />

Control Rods<br />

Thirty-five control ro eing prepared for<br />

<strong>the</strong> GE-ANP project. They were received as<br />

specially straightened tubes, 0.504 in. ID, 0.625<br />

in. OD, 35 in. long, with one end plugged. The<br />

being filled with a mixture of 50% alumi-<br />

er and 50% B,C, both supplied by <strong>the</strong><br />

General Electric Company. The B,C is a special<br />

grade containing 81% boron. The mixture is pre-<br />

pared with 2% paraffin as a binder and is being<br />

packed tightly into <strong>the</strong> tubes with a pneumatic<br />

hammer. Very small increments are used to obtain<br />

a high density. Twenty tubes have been filled<br />

with average boron concentrations of about 0.8<br />

g/cm3, that is, somewhat in excess of <strong>the</strong> 0.7<br />

g/cm3 required. After filling is completed, <strong>the</strong><br />

. tubes will be heated and evacuated to remove<br />

<strong>the</strong> paraffin and <strong>the</strong>n cold swaged to final size.<br />

AI-UO, Elements for Shielding Experiment<br />

Fuel plates 28 in. long and 23/4 or 2% in. wide<br />

are being prepared for an experiment to determine<br />

<strong>the</strong> shielding necessary for delayed neutrons.<br />

These plates are to be mounted on a belt and<br />

rotated at speeds up to 22 fps. The fuel concen-<br />

tration of 0.25 g/cm3 required for <strong>the</strong>se plates is<br />

quite high compared with that usually specified<br />

for fuel plates, and <strong>the</strong>refore new fabrication<br />

problems must be resolved.<br />

Several plates have been fabricated by using<br />

UO, and aluminum powder cores roll clad with<br />

aluminum. Three plates having 0.040-in. core<br />

ith 62 wt % UO, had <strong>the</strong> required fuel<br />

ation. Both high-fired and steam-oxidized<br />

UO, were used with good results. The edges of<br />

<strong>the</strong> core were quite clean and straight, and <strong>the</strong><br />

UO, was distributed fairly uniformly, as shown by<br />

radiograph examination. Because of <strong>the</strong> high<br />

1 08<br />

percentage of UO,, it was necessary to hot roll<br />

<strong>the</strong> plates with <strong>the</strong> covers on at all stages to<br />

prevent oxidation. Plates with lower percentages<br />

of UO, may be protected with thin aluminum foil<br />

pressed on <strong>the</strong> core compact during cold pressing.<br />

The finished plates, as-clad with 2s aluminum,<br />

were judged to be too weak for <strong>the</strong> high stresses<br />

involved in <strong>the</strong> rapid cycling. Several more ele-<br />

ments are being assembled by using 52s aluminum<br />

as frame and cladding in <strong>the</strong> hope that work harden-<br />

ing obtained in finish cold rolling will yield plates<br />

of sufficient strength.<br />

BRAZING ALLOY DEVELOPMENT<br />

P. Patriarca K. W. Reber<br />

R. E. Clausing G. M. Slaughter<br />

Meta I I urgy D iv i si on<br />

J. M. Cisar<br />

Aircraft Reactor Engineering Division<br />

R. L. Heestand<br />

Pratt & Whitney Aircraft<br />

The resistance to oxidation of a number of high-<br />

temperature brazing alloys when used in con-<br />

-<br />

junction with lnconel as a base material was , -<br />

described in a previous report., This study has<br />

been extended to include tests of several additional<br />

brazing alloys. These tests have been conducted<br />

in accordance with <strong>the</strong> experimental procedures 1<br />

used in <strong>the</strong> previous studies. The results of<br />

metallographic examination of inverted T-joint<br />

specimens after exposure to static air at 15OOOF<br />

for periods of 200 and 500 hr are summarized in<br />

Table 7.6. It appears that <strong>the</strong> majority of <strong>the</strong>se<br />

alloys are suitable for service within <strong>the</strong> limits of<br />

this investigation. The periods of exposure currently<br />

being studied extend to 1000 hr. Tests are.<br />

also being conducted at 170OOF in static air.<br />

It is recognized that <strong>the</strong> test results obtained to<br />

date may not be applicable except under iso<strong>the</strong>rmal<br />

conditions. Therefore a duplicate set of experiments<br />

will be conducted to determine <strong>the</strong> effect<br />

of <strong>the</strong>rmal cycling on <strong>the</strong> adherence of protective<br />

oxide films. Included in <strong>the</strong>se tests will be a<br />

determination of <strong>the</strong> effect of <strong>the</strong> presence of water<br />

*<br />

vapor on <strong>the</strong> nature of <strong>the</strong> scale formation and <strong>the</strong><br />

resistance of this scale to spalling under con- ..<br />

ditions characterized by temperature fluctuations.<br />

' * I<br />

5<br />

. *<br />

.

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