ORNL-1771 - Oak Ridge National Laboratory

ORNL-1771 - Oak Ridge National Laboratory ORNL-1771 - Oak Ridge National Laboratory

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ANP PROJECT ESS T PART 1. REACTOR THEORY, COMPONENT DESIGN AND TESTING, AND CONSTRUCTlQN Circulating-Fuel Aircraff Reactor Experiment The water tests of the fuel and the sodium cir- cuits of the ARE system at room temperature were completed (Sec. 1). The sodium circuit was pres- sure-filled with water from the sodium fill tanks, while the fuel system was vacuum-filled ‘io ensure the elimination of gas pockets in the fuel system. Both systems were found to function properly, and the fiiiing, circulating, and draining operations %ere effected with a minimum of difficulty. After the water was drained, the system was dried by heating it to approximately 600°F. The electrical heating system was found to be satisfactory in the check thus afforded. The final system completion work is now under way, that is, removal of the sodium system reactor bypass, completion of the fuel-enrichment system installation, completion of thermocouple and insu- lation installation, and other minor modifications. When this work is completed, sodium will Le charged to the system and the high-temperature checkout phase of the experiment will be initiated. The neutron source was put into the reactor, and the nuclear instrumentation was checked out. Also, mechanical checks were made of the per- formance of the safety and control rods. The building electric and helium systems were made ready to accommodate the loading facilities, and final arrangements were completed for attaching the fuel-sampling equipment. Radiation damage experiments indicated the de- sirability of providing gamma shielding at several points where elastomers were used (belts, dia- phragms, etc.). Where shielding was impractical, the composition diaphragms were replaced with metal diaphragms. The results of operation of the reactor system component test loop at K-25 are encouraging in that the loop has now been operated without major difficulties for more than 1800 hr. None of the minor difficulties encountered would indicate that serious problems might arise in operation of the ARE, $ ~ ~ ~ A ~ ~ Reflector-Moderated Reoctar The program for the development arid construc- tion of the Circulating-Fuel Reactor Experiment (CFRE) has been outlined, and many of the de- velopment psolects are under way. Tentative design data have been compiled and a flow sheet has been prepared (Sec. 2). The first priority development proiect, the test of beryllium in con- tact with sodium and lnconel under thermal stress, has been completed, The results of this test were needed in the determination of the amount of poison to Le expected in the reflector. The test indicated that. beryllium will not crock under the thermal stresses involved in the temperature range 1000 to 1300°F. Since corrosion and mass transfer, a5 well as thermal stress, will be important in the beryllium-lnconel-sodium system, many static and dynamic tests under various conditions have been made. There is considerable evidence to indicate satisfactory compatibility in the bery Ilium-lnconel- sodium system at temperatures up to 1200°F. The temperature coefficient of reactivity for the CFRE was computed on the UNIVAC and, for rapid temperature changes, was found to be -3.5 x lO-’/’F. The critical mass computed for the shomticuboctahedral critrcal assembly was rede- termined because of errors found in the original data. The redetermined value agreed closely with the experimental value, but, since the critical mass is not very sensitive to errors in detail, further evaluation of the agreement must await additional experimental results.. Experimental Reactor Engineering The emphasis in the engineering work is now on development of components for an in-pile loop for insertion in a horizontal beam hole of the MTR and the design and construction of forced-circu- lation corrosion testing loops (Sec, 3). The in-pile loop for insertion in the MTR is a joint ORNL and Pratt & Whitney Aircraft Division project. It is to circulote proposed fuel mixtures in the high-flux of the MTR so that the extent of radiation damage to materials of constructton and the effect of radi- ation on the fuel can be determined. Two types of pumps have been developed for in-pile use: a 1

ANP QUARTERLY PROGRE.S.5 REPORT vertical-shaft centrifugol sump pump for instal- lation external to the reactor shield and a hori- zontal-shaft sump pump for insertion inside a beam hole. A turbine-type impeller is being considered for the horizontal-shaft pump because it would have the advantage that both the inlet and dis- charge could be at the bottom. Hydraulic motors of suitably small dimensions have been found to be satisfactory drives for these pumps. Two series of lnconel forced-circulation cor- rosion loops for circulating fluoride mixtures ore being developed to meet the following require- ments: (1) a Reynolds number of 10,000 with temperature gradients of 100, 200, and 300°F and (2) a temperature gradient of 200°F with Reynolds numbers of 800, 3,000, and 15,000. The maximum fluid temperature is to be 1500°F. A study is under way of the cavitotion phe- nomenon associated with operating liquid metol systems at elevated temperatures, high flow rates, and high pump speeds. A correlation of fluid-flow- noise intensity with pressure data was noted. The number of stations available for convection- loop testing was increased from 18 to 31 and the basic design of the loops was simplified. Various means of heating the loops and of making operation of them more automatic are being studied. Critical Experiments The first step of the present critical experiment program was the construction of a small two-region reflector-moderated reactor to provide experimental data on a system of simple geometry and materials for use in checking the calculational methods being used (Sec. 4). The core consists of olter- nate sheets of enriched uranium metal and Teflon and is surrounded by a beryllium reflector. The uranium loading can be varied, within the specified dimensions, to make the system criticol. The assembly was loaded as prescribed by the inulti- group calculations but was not critical. However, when the calculations hod been corrected to take into account errors in the original data, a new attempt to achieve criticality with the prescribed loading was made. The corrected prescribed loading was 20.9 to 22.75 Ib of U2,' and the experimental loading was 24.35 Ib of U235. A larger critical assembly of the same shape is to be constructed that will consist of three regions, with the beryllium island ond the reflector sepa- rated by the fuel annulus. A further check on the calculational methods will be obtained. 2 PART II. MATERlALS RESEARCH Chemistry of Molten Materials Studies of the fluoride systems of interest as reactor fuels were continued, with particular em- phasis being given to systems in which the uranium-bearing component is the less corrosive UF, or a mixture of UF, and UF, rather than UF, alone (Sec. 5). Recent attempts to correlate the anticipated reduction of UF, in the UF3-bearing melts with wet chemical analysis for UF, and UF', and results of petrographic examination show some surprising Cinoriialies. When UF, dissolved in LiF, in NoF-ZrF,-UF, mixtures, or in NaF-LiF mixtures is treated under flowing hydrogen at 800°C with excess uranium metal, 90% or more of the UF, is reduced to UF,. However, when this technique is applied to UF, in NaF-KF-LiF mixtures, the reduction is only 50% complete at 800°C and, perhaps, 75% complete at 600°C. Petrographic examinations of the specimens reveal no complex compounds of tetravalent uranium; it is possible that the UF, is "hidden" in solid solutions or in complex UF,-UF, compounds in which it is not at present recognizable. Solid phase studies of the NaF-ZrF,-UF, system were initiated following completion of studies of the NaF-ZrF, system, and to date nu ternary com- pounds have been discovered. A tentative equi- librium diagram was prepared. A rnethod for large-scole purification of rubidium fluoride hos been developed thot can be used if muterial sufficiently free from cesium cannot be obtained from commercial sources. Fundamental studies of the reduction of NiF, and FeF, by H, in NaF-ZrF, systems were made as a means of determining possible i mprovements in purification techniques. Also, methods for preparing simple structural metal fluorides were studied. Large quantities of purified ZrF4-base fluorides were prepared for engineering tests at ORNL and elsewhere, and the demand for purified fluorides of other types is rapidly increasing. Therefore preparation and purification methods have been studied intensively in an effort to lower production time and costs. Developments indicate that the price of purified NnZrF, and NaF-ZrF,-UF, mix- tures may be halved in the next few months. Corrosion Research The static and seesaw corrosion testing fa- cilities were used for further studies of brazing

ANP PROJECT ESS T<br />

PART 1. REACTOR THEORY, COMPONENT<br />

DESIGN AND TESTING, AND CONSTRUCTlQN<br />

Circulating-Fuel Aircraff Reactor Experiment<br />

The water tests of the fuel and the sodium cir-<br />

cuits of the ARE system at room temperature were<br />

completed (Sec. 1). The sodium circuit was pres-<br />

sure-filled with water from the sodium fill tanks,<br />

while the fuel system was vacuum-filled ‘io ensure<br />

the elimination of gas pockets in the fuel system.<br />

Both systems were found to function properly, and<br />

the fiiiing, circulating, and draining operations<br />

%ere effected with a minimum of difficulty. After<br />

the water was drained, the system was dried by<br />

heating it to approximately 600°F. The electrical<br />

heating system was found to be satisfactory in<br />

the check thus afforded.<br />

The final system completion work is now under<br />

way, that is, removal of the sodium system reactor<br />

bypass, completion of the fuel-enrichment system<br />

installation, completion of thermocouple and insu-<br />

lation installation, and other minor modifications.<br />

When this work is completed, sodium will Le<br />

charged to the system and the high-temperature<br />

checkout phase of the experiment will be initiated.<br />

The neutron source was put into the reactor, and<br />

the nuclear instrumentation was checked out.<br />

Also, mechanical checks were made of the per-<br />

formance of the safety and control rods. The<br />

building electric and helium systems were made<br />

ready to accommodate the loading facilities, and<br />

final arrangements were completed for attaching<br />

the fuel-sampling equipment.<br />

Radiation damage experiments indicated the de-<br />

sirability of providing gamma shielding at several<br />

points where elastomers were used (belts, dia-<br />

phragms, etc.). Where shielding was impractical,<br />

the composition diaphragms were replaced with<br />

metal diaphragms.<br />

The results of operation of the reactor system<br />

component test loop at K-25 are encouraging in<br />

that the loop has now been operated without major<br />

difficulties for more than 1800 hr. None of the<br />

minor difficulties encountered would indicate that<br />

serious problems might arise in operation of the<br />

ARE,<br />

$ ~ ~ ~ A ~ ~<br />

Reflector-Moderated Reoctar<br />

The program for the development arid construc-<br />

tion of the Circulating-Fuel Reactor Experiment<br />

(CFRE) has been outlined, and many of the de-<br />

velopment psolects are under way. Tentative<br />

design data have been compiled and a flow sheet<br />

has been prepared (Sec. 2). The first priority<br />

development proiect, the test of beryllium in con-<br />

tact with sodium and lnconel under thermal stress,<br />

has been completed, The results of this test were<br />

needed in the determination of the amount of<br />

poison to Le expected in the reflector. The test<br />

indicated that. beryllium will not crock under the<br />

thermal stresses involved in the temperature range<br />

1000 to 1300°F. Since corrosion and mass transfer,<br />

a5 well as thermal stress, will be important in the<br />

beryllium-lnconel-sodium system, many static and<br />

dynamic tests under various conditions have been<br />

made. There is considerable evidence to indicate<br />

satisfactory compatibility in the bery Ilium-lnconel-<br />

sodium system at temperatures up to 1200°F.<br />

The temperature coefficient of reactivity for the<br />

CFRE was computed on the UNIVAC and, for rapid<br />

temperature changes, was found to be -3.5 x<br />

lO-’/’F. The critical mass computed for the<br />

shomticuboctahedral critrcal assembly was rede-<br />

termined because of errors found in the original<br />

data. The redetermined value agreed closely with<br />

the experimental value, but, since the critical<br />

mass is not very sensitive to errors in detail,<br />

further evaluation of the agreement must await<br />

additional experimental results..<br />

Experimental Reactor Engineering<br />

The emphasis in the engineering work is now<br />

on development of components for an in-pile loop<br />

for insertion in a horizontal beam hole of the MTR<br />

and the design and construction of forced-circu-<br />

lation corrosion testing loops (Sec, 3). The in-pile<br />

loop for insertion in the MTR is a joint <strong>ORNL</strong> and<br />

Pratt & Whitney Aircraft Division project. It is<br />

to circulote proposed fuel mixtures in the high-flux<br />

of the MTR so that the extent of radiation damage<br />

to materials of constructton and the effect of radi-<br />

ation on the fuel can be determined. Two types<br />

of pumps have been developed for in-pile use: a<br />

1

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