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ORNL-1771 - Oak Ridge National Laboratory

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was used with type-430 stainless-steel-clad copper,<br />

os shown in Fig. 7.8. In this case, the intergranular<br />

penetration was completely through the tube wall.<br />

The effect oaf the intergranular penetration on the<br />

physical properties of the tubing has not yet been<br />

determined, but it is believed that it would be ad-<br />

visable to use a brazing alloy that does not react<br />

with the iron-base cladding material.<br />

The tube-to-fin joints shown in Figs. 7,9 and<br />

7.10 are, respectively, type-310 stainless-steel -clad<br />

and type-430 stainless-steel-clad copper fins that<br />

were brazed ivith Coast Metals alloy 52 to lnconel<br />

and then exposed to static air for 400 hr at 1500°F.<br />

A negligible amount of dilution and a relatively<br />

minor amount of boron diffusion into the lnconel<br />

tubing occurred.<br />

Although low-melting-point Nicrobraz (LMNB) has<br />

been used successfully to braze all the proposed<br />

cladding materials to Inconel, its relatively high<br />

Fig. 7.7. Type-310 Stainless-Steel-Clad Copper<br />

fins Brazed to Inconel Tubing with 88% M1-12% P<br />

Alloy. Note dilution of fin and intergranular pene-<br />

tration into tube wall. As pofished. SOX. Re-<br />

duced 15%.<br />

PERIOD ENDING SEPTEMBER ?O, 1954<br />

flow point cf 1925°F is so close to the melting<br />

point of copper that it cannot be used with ease.<br />

Since the oxidation resistance of the Coast Metals<br />

alloy 52 is comparable to that of LMNB and the<br />

effect of boron diffusion is the same for both alloys,<br />

the Coast Metals alloy was selected for the fabri-<br />

cation of the first high-conductivity-fin sodium-to-air<br />

radiator.<br />

The problem of edge protection of the clad copper<br />

fins has been resolved. Aluminum is applied to the<br />

edges of fins by dip coating or spraying, or it is<br />

painted on as aluminum powder in (I Nicrobraa<br />

cement slurry. The fin is then heated at 80OoC for<br />

approximately '/2 hr. The diffusion of the aluminum<br />

into the copper core results in an aluminum bronze<br />

which exhibits excellent resistance to oxidation<br />

when exposed to static air for 500 hr at 1500°F.<br />

It appears that the depth of bronzing, which con-<br />

3<br />

tinues during oxidation testing, is about /32 to<br />

in. in 500 hr. The feasibility of simultaneously<br />

bronzing large numbws of fins is to be determined.<br />

Fig. 7.8. Type-430 Stainless-Steel-Clad Copper<br />

Fins Brazed to lnconel Tubing with 88% Ni-I2% P<br />

Alloy. Note dilution of the fin and severe inter-<br />

granular penetration into the tube wall. A5 pol-<br />

ished. 50X. Reduced 19%.<br />

119

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