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ORNL-1771 - Oak Ridge National Laboratory

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alloys for use in fabricating the radiator, ond the<br />

fabrication of radiators for service testing.<br />

Investigations of Fin Materials<br />

J. H. Coobs H. lnouye<br />

Meta I I urgy Division<br />

Stress-rupture and creep tests of type-310 stain-<br />

less-steel-clad copper fins that were 8 mils thick<br />

were made at 1500°F at stresses between 500 and<br />

2000 psi. The material was obtained from the<br />

General Plate Div. of Metals & Controls Corp. and<br />

had an average cladding thickness of 1.87 mils per<br />

side. The maximum cladding thickness was 2.3<br />

mils per side. The results of the several tests<br />

mode show that some alteration of the copper OC-<br />

curs even though the specimen does not fracture.<br />

This was indicated by the brittleness of the normally<br />

ductile composite. For long-time exposures (1000<br />

hours), stresses greater than 500 psi and less than<br />

1000 psi are tolerable and there is no indication of<br />

brittleness in the core or oxidation due to cladding<br />

failure. In all the specimens which ruptured, oxi-<br />

dation of the copper at the point ot fracture was<br />

complete, and the copper which did not appear to<br />

be oxidized was brittle. It was also noted that<br />

when the strain in 2.5 in. was lo%, the copper re-<br />

mained ductile, while strains above 20% (regardless<br />

of exposure time) produced brittleness. The data<br />

obtained are given in Table 7.1.<br />

The aluminum bronzes are among the materials<br />

being considered as cladding for copper fins. Al-<br />

though extensive diffusion occurs between these<br />

alloys and copper, increases in the thermal con-<br />

ductivity of the fin can be realized by cladding the<br />

copper with these alloys. The composition gradient<br />

existing in a diffused composite results in an in-<br />

crease in the conductivity of the cladding material<br />

(because of the outward diffusion of aluminum) and<br />

a decrease in the conductivity of the copper core.<br />

Thermal conductivity measurements of two alumi-<br />

num bronzes were made by the Solid State Division<br />

and are reported in Table 7.2. The values given<br />

for measurements at temperatures up to 392°F com-<br />

pare favorably with the datu of Smith and Palmer,2<br />

but for temperatures above 392°F they exceed the<br />

values extrapolated from their data. Also, the<br />

2C. S. Smith and E. W. Palmer, Am. Inst. Mining Met.<br />

Engrs., Metals Technol. Tech. Pub. No. 648, 1-21<br />

( 1935).<br />

PERIOD ENDING SEPTEMBER IO, 1954<br />

TABLE 7.1. STRESSRUPTURE PROPERTIES OF<br />

TYP E-310 STAINLESLSTE EL-CLAD<br />

COPPER FINS AT 15OO0F<br />

&mil cladding on each side of 4-mil copper sheet<br />

Rupture Elongation<br />

Stress<br />

Time in 2.5 in. Remarks<br />

(Psi) (hF)<br />

(%I<br />

2000<br />

1800<br />

1650<br />

1500<br />

1400<br />

1000<br />

1000<br />

5 00<br />

500<br />

96<br />

336<br />

52 8<br />

887<br />

1220<br />

39 Capper embrittled<br />

50 Copper embri ttled<br />

40 Copper embrittled<br />

Copper embrittled<br />

In progress<br />

27.5 Test terminated at 1000<br />

hr; specimen oxidized<br />

throughout<br />

20 Test terminated at 500 hr;<br />

oxide stringers on<br />

surface of specimen<br />

10 Test terminated at 1000<br />

hr; no indication of<br />

failure<br />

5 Test terminated at 500 hr;<br />

no indication of failure<br />

TABLE 7.2. THERMAL CONDUCTIVITY OF<br />

ALUMINUM f3RONZESATVARlOUS TEMPERATURES<br />

Temperature<br />

The rma I Conductivity<br />

[col/sec.cm2 ("C/C"S1<br />

.................................................<br />

(OF) For For<br />

6.2% A1-93.8% Cu 8.4% AI-91.6% Cu<br />

.......... ~<br />

212 0.178 0.176<br />

30 2 0.240 0.210<br />

3 92 0.280 0.250<br />

1156 0.55<br />

1562 0.77<br />

estimated value of six times the thermal conductivity<br />

of stainless steel at 1500°F was exce=ded by the<br />

experimental value for the &2% AI-93.8% Cu alloy,<br />

The values given in Table 7.2 were not corrected<br />

for the volume expansion of the alloy with temper-<br />

ature and are therefore accurate only to within<br />

*5%.<br />

117

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