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ORNL-2106 - the Molten Salt Energy Technologies Web Site

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I<br />

I 254<br />

1<br />

!<br />

A NP PROJECT PROGRESS REPORT<br />

runs was pentavalent. As a result of disprapor- These results indicate that, if a significant partionation<br />

of <strong>the</strong> pentavalent uranium in <strong>the</strong> analyti- tial pressure of UF, is retained in <strong>the</strong> NaF bed<br />

cal procedure, however, <strong>the</strong> tetravalent uranium because of a plugged line or cold trap during UF,<br />

content in each case was approximately equal to desorption, excessive UF, decomposition will oc<strong>the</strong><br />

hexavalent content. The decomposition reac- cur when <strong>the</strong> temperature reaches <strong>the</strong> 300 to 400OC<br />

tion is <strong>the</strong>refore believed to be range. Therefore precautions must be taken to<br />

UF6*3NaF + UFpNaF i '/Fz<br />

ensure that full sweep-gas flow through <strong>the</strong> NaF<br />

bed is maintained during UF, desorption.<br />

61<br />

.

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