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ORNL-2106 - the Molten Salt Energy Technologies Web Site

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ANP PROJECT PROGRESS REPORT<br />

IIOV -60-<br />

atom as it travels through <strong>the</strong> lattice result in <strong>the</strong><br />

formation of lattice vaccncies and interstitial<br />

atoms. Since <strong>the</strong> germanium lattice is fairly open,<br />

<strong>the</strong> interstitial atoms can diffuse readily through<br />

<strong>the</strong> crystal. Because of <strong>the</strong> high dielectric con-<br />

stant of germanium, <strong>the</strong> interstitial atom is ionized<br />

at room temperature, and hence its diffusion should<br />

be influenced by <strong>the</strong> presence of an electric field.<br />

Fields of <strong>the</strong> order of tenths of a volt per micron<br />

are available in <strong>the</strong> barrier region of a diode, and<br />

<strong>the</strong> conductivity of <strong>the</strong> diode is extremely sensitive<br />

to changes in carrier concentration in <strong>the</strong> region<br />

of <strong>the</strong> barrier.<br />

A 1N38A point-contact germanium rectifier was<br />

exposed for 5 min in hole 51-N of <strong>the</strong> <strong>ORNL</strong><br />

Graphite Reactor. After removal from <strong>the</strong> reactor<br />

<strong>the</strong> rectifier was biased in <strong>the</strong> forward direction<br />

246<br />

Fig. 4.2.16. Transistor Test Circuit.<br />

‘0<br />

at 0.7 v in order to remove <strong>the</strong> potential gradient<br />

in <strong>the</strong> barrier region. The measured current was<br />

low because of radiation damage. The unit was<br />

<strong>the</strong>n placed in an oil bath to maintain a constant<br />

temperature of about 250C for six days. At <strong>the</strong><br />

end of <strong>the</strong> six-day period <strong>the</strong>re had been no<br />

observable change in <strong>the</strong> current passing through<br />

<strong>the</strong> sample at 0.7-v bias. The bias was removed<br />

for 2 hr, <strong>the</strong>n restored. When <strong>the</strong> bias had been<br />

restored, it was noted that <strong>the</strong> current had in-<br />

creased by about an order of magnitude. After<br />

eight days in <strong>the</strong> biased condition, <strong>the</strong> current had<br />

not changed.<br />

When <strong>the</strong> bias was removed, an electric field<br />

was established at <strong>the</strong> barrier to cause <strong>the</strong> relative<br />

interstitial atoms to diffuse from <strong>the</strong> barrier region.<br />

This removal of interstitial atoms from <strong>the</strong> p-type<br />

.<br />

t

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