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Statistical Mechanics - Physics at Oregon State University

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8.1. INTRODUCTION. 159<br />

In a first approxim<strong>at</strong>ion the strength of the exchange interaction depends on<br />

the distance between l<strong>at</strong>tice sites only. We denote the l<strong>at</strong>tice sites by Ri and<br />

have<br />

H = − <br />

J(| Ri − Rj|) Si • Sj<br />

(8.3)<br />

i (8.4)<br />

Unfortun<strong>at</strong>ely, these are not eigenst<strong>at</strong>es of of the Hamiltonian, since the oper<strong>at</strong>ors<br />

Si are able to lower and raise the z quantum number. We have<br />

Si • Sj = S +<br />

i S− j + S− i S+ j + SizSjz (8.5)<br />

Because we do not know wh<strong>at</strong> to do with the first two terms, we ignore<br />

them. The Hamiltonian is now<br />

H = − <br />

J(| Ri − Rj|)SizSjz<br />

i. The original<br />

energy expression contains the product of spin-components perpendicular to the<br />

quantiz<strong>at</strong>ion axis, but leaving out these terms, like we did above, corresponds<br />

to assuming th<strong>at</strong> they average out to zero. Therefore, the energy eigenvalue of<br />

a given quantum st<strong>at</strong>e |σ1, · · · , σN > is<br />

E {σ1, · · · , σN} = − <br />

i

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