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Statistical Mechanics - Physics at Oregon State University

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156 CHAPTER 7. CLASSICAL STATISTICAL MECHANICS.<br />

The virial for a classical system is defined by V = <br />

thermal average of V is equal to −3NkBT .<br />

Problem 8.<br />

i<br />

dpi<br />

ri dt . Show th<strong>at</strong> the<br />

Consider the quantity L(t) = <br />

i ri(t)pi(t). Show th<strong>at</strong> the thermal average<br />

of L(t) is independent of time.

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