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Statistical Mechanics - Physics at Oregon State University

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5.4. PROBLEMS FOR CHAPTER 5 117<br />

(C) For T = ∞. (Note: this one you can get without any detailed calcul<strong>at</strong>ion).<br />

(D) For kBT ≫ ɛF , one more term beyond (C).<br />

Problem 5.<br />

The virial expansion is given by p<br />

kT = ∞ j=1 Bj(T ) <br />

N j<br />

V with B1(T ) = 1.<br />

Find B2(T ) for non-interacting Fermions in a box.<br />

Problem 6.<br />

The energy of rel<strong>at</strong>ivistic electrons is given by ɛp,s = p 2 c 2 + m 2 c 4 , which<br />

is independent of the spin s. These particles are contained in a cubical box,<br />

sides of length L, volume V .<br />

(1) Calcul<strong>at</strong>e the Fermi energy ɛF = µ(T = 0) as a function of N and V .<br />

(2) Calcul<strong>at</strong>e the internal energy U.<br />

(3) Expand the integral in (2) in a power series, assuming th<strong>at</strong> the density N<br />

V<br />

is very low.<br />

(4) Expand the integral in (2) in a power series, assuming th<strong>at</strong> the density N<br />

V<br />

is very high.<br />

Problem 7.<br />

Landau diamagnetism. The orbits of an electron in a magnetic field are also<br />

quantized. The energy levels of the electron are now given by<br />

ɛ(pz, j, α, s) = p2 z<br />

2m<br />

eB 1<br />

+ (j +<br />

mc 2 )<br />

with pz = 2π<br />

L l, l = 0, ±1, ±2, · · ·, and j = 0, 1, · · · . The quantum number<br />

α counts the degeneracy and α runs from 1 to g = eBL2<br />

2πc . The magnetic field<br />

is along the z direction. We have ignored the energy of interaction between the<br />

spin and the magnetic field.<br />

(1) Give an expression for the grand partition function ζ(T, µ, V ).<br />

(2) Calcul<strong>at</strong>e the magnetic susceptibility for T → ∞ ( no, zero is not an<br />

acceptable answer, one more term, please) in a weak magnetic field.

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