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Statistical Mechanics - Physics at Oregon State University

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98 CHAPTER 5. FERMIONS AND BOSONS<br />

Since this has to be identical to zero, all coefficients of all powers of t have to<br />

be zero, and we have cn+2(n + 2)(n + 1) + cn = 0. We get two sets of solutions.<br />

Either we set c0 = 1 and c1 = 0 or do the opposite. A general solution is a<br />

linear combin<strong>at</strong>ion of these two basic solutions. The basic solutions are<br />

and<br />

∞<br />

k=0<br />

∞<br />

k=0<br />

(−1) k<br />

(2k)! t2k<br />

(−1) k<br />

(2k + 1)! t2k+1<br />

(5.39)<br />

(5.40)<br />

which clearly converge for all values of time. Do these functions have special<br />

properties? Th<strong>at</strong> is very hard to tell from the power series solutions. We<br />

know however, th<strong>at</strong> they are equal to cos(t) and sin(t) and are periodic. Th<strong>at</strong><br />

inform<strong>at</strong>ion comes from a different source of knowledge. We can also solve the<br />

differential equ<strong>at</strong>ion on a computer and plot the solution. Most likely we will see<br />

the periodicity right away, but round-off errors will start to change the picture,<br />

and perhaps we can see only a certain number of periods. Therefore, can we<br />

conclude from the computer calcul<strong>at</strong>ions th<strong>at</strong> the solutions are periodic? Who<br />

knows.<br />

Another example is the differential equ<strong>at</strong>ion<br />

d3x + x = 0 (5.41)<br />

dt3 It is easy to construct power series solutions, they are of the form:<br />

∞<br />

k=0<br />

(−1) k<br />

(3k)! t3k<br />

and similar. Are they periodic? Wh<strong>at</strong> other properties do they have?<br />

Finding the chemical potential.<br />

Once we know the grand energy we are able to calcul<strong>at</strong>e N and find<br />

N(T, µ, V ) = −<br />

<br />

∂Ω<br />

∂µ T,V<br />

= −<br />

<br />

∂Ω<br />

∂λ T,V<br />

N = (2S + 1)V kBT λ −3<br />

<br />

∂<br />

T f 5<br />

∂λ 2 (λ)<br />

<br />

λ<br />

kBT<br />

<br />

∂λ<br />

∂µ T,V<br />

(5.42)<br />

(5.43)<br />

(5.44)<br />

The deriv<strong>at</strong>ive for our special function is easy to find for λ < 1 using the power<br />

series.

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