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Statistical Mechanics - Physics at Oregon State University

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96 CHAPTER 5. FERMIONS AND BOSONS<br />

The not<strong>at</strong>ion 5<br />

2 will become clear in a moment. This function was carefully<br />

analyzed, an important occup<strong>at</strong>ion before the days of computers when series<br />

expansions were badly needed to get numbers. Even now they are important<br />

since we can often use simple limit forms of these analytical functions in model<br />

calcul<strong>at</strong>ions. The grand energy is<br />

Ω(T, µ, V ) = − (2S + 1)<br />

<br />

spin<br />

degeneracy<br />

V<br />

<br />

simple<br />

volume<br />

dependence<br />

kBT<br />

<br />

energy<br />

scale<br />

λ −3<br />

T<br />

<br />

volume<br />

scale<br />

f 5<br />

2 (λ)<br />

<br />

density<br />

effects<br />

(5.29)<br />

The right hand side is independent of volume, depends on µ only via f 5 (λ) and<br />

2<br />

on T in three places.<br />

Density dependence.<br />

The function f 5 (λ) has some simple properties. For large values of x one<br />

2<br />

can expand the logarithm and the integrant is approxim<strong>at</strong>ely equal to x 2 λe −x2<br />

Therefore, the integral is well behaved <strong>at</strong> the upper limit of x → ∞ and we are<br />

allowed to play all kinds of games with the integrant. If λ < 1 (remember th<strong>at</strong><br />

λ > 0) the logarithm can be expanded in a Taylor series for all values of x and<br />

since the integral is well behaved it is allowed to interchange summ<strong>at</strong>ion and<br />

integr<strong>at</strong>ion. Using<br />

|z| < 1 ⇒ log(1 + z) =<br />

∞<br />

n=1<br />

1<br />

n zn (−1) n<br />

and generalizing λ to be able to take on complex values, we have<br />

|λ| < 1 ⇒ log(1 + λe −x2<br />

) =<br />

∞<br />

n=1<br />

1<br />

n (−1)n λ n e −nx2<br />

.<br />

(5.30)<br />

(5.31)<br />

and since the convergence of the series is uniform we can interchange summ<strong>at</strong>ion<br />

and integr<strong>at</strong>ion. This leads to<br />

4<br />

|λ| < 1 ⇒ f 5 (λ) = √<br />

2 π<br />

where we have used<br />

∞<br />

n=1<br />

∞<br />

0<br />

1<br />

n (−1)n λ n<br />

y 2 dye −ny2<br />

∞<br />

0<br />

x 2 dxe −nx2<br />

= 1√<br />

1<br />

π<br />

4 n √ n<br />

=<br />

∞ λn (−1) n+1<br />

n=1<br />

n 5<br />

2<br />

(5.32)<br />

(5.33)<br />

This defines why we used the not<strong>at</strong>ion 5<br />

2 . In general, one defines a family of<br />

functions fα(z) by

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