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ΕΘΝΙΚΟ ΜΕΤΣΟΒΙΟ ΠΟΛΥΤΕΧΝΕΙΟ

ΕΘΝΙΚΟ ΜΕΤΣΟΒΙΟ ΠΟΛΥΤΕΧΝΕΙΟ

ΕΘΝΙΚΟ ΜΕΤΣΟΒΙΟ ΠΟΛΥΤΕΧΝΕΙΟ

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Service time {days}<br />

C/C 0 %<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

80<br />

60<br />

40<br />

20<br />

0<br />

Bisphenol-A<br />

0 5 10 15 20 25<br />

Time {days}<br />

Figure 6 : Breakthrough curves of Bisphenol-A (left) and Ibuprofen (right)<br />

(column A is -○-, column B is -□-, column C is -∆- and column D is -×-).<br />

Bohart-Adams Bisphenol-A<br />

R² = 0,9391<br />

0 0,05 0,1 0,15 0,2<br />

GAC bed depth {m}<br />

Figure 7 : Bohart-Adams lines of Bisphenol-A (left) and Ibuprofen (right).<br />

Time-modified second batch experiment<br />

As mentioned above, during the second batch experiment there were several<br />

problems arisen with the pilot column system. Those problems are shown in every<br />

breakthrough curve of the second batch experiment as a “temporary stabilization” of<br />

the curve. In this section those “stabilizations” were counted as “dead times” and a<br />

proper time modification was applied for every curve to restore its continuity.<br />

~ x ~<br />

Service time {days}<br />

C/C 0 %<br />

100<br />

14<br />

12<br />

10<br />

80<br />

60<br />

40<br />

20<br />

8<br />

6<br />

4<br />

2<br />

0<br />

0<br />

Ibuprofen<br />

0 5 10 15 20 25<br />

Time {days}<br />

Bohart-Adams Ibuprofen<br />

R² = 0,9492<br />

0 0,05 0,1 0,15 0,2<br />

GAC bed depth {m}

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