tel-00770488, version 1 - 7 Jan 2013 Int. J. Mol. Sci. 2011, 12 6666 fabricated in the NANOFAB facility of the Néel Institute and we thank B. Fernandez, G. Julie, T. Crozes and T. Fournier for help in device fabrication. We thank M. Affronte, F. Balestro, N. Bendiab, L. Bogani, E. Bonet, V. Bouchiat, L. Calvet, A. Candini, D. Feinberg, J. Jarvinen, L. Marty, R. Maurand, T. Novotny, R. Piquerel, C. Thirion and R. Vincent for fruitful discussions and software development. We thank E. Eyraud, R. Haettel, C. Hoarau, D. Lepoittevin and V. Reita for technical support. References 1. Christou, G.; Gatteschi, D.; Hendrickson, D.N.; Sessoli, R. Single-molecule magnets. MRS Bull. 2000, 25, 66–71. 2. Wernsdorfer, W.; Sessoli, R. Quantum phase interference and parity effects in magnetic molecular clusters. Science 1999, 284, 133–135. 3. Xiong, Z.H.; Wu, D.; Vardeny, Z.V.; Shi, J. Giant magnetoresistance in organic spin-valves. Nature 2004, 427, 821–824. 4. Barraud, C.; Seneor, P.; Mattana, R.; Fusil, S.; Bouzehouane, K.; Deranlot, C.; Graziosi, P.; Hueso, L.; Bergenti, I.; Dediu, V.; Petroff, F.; Fert, A.. Unravelling the role of the interface for spin injection into organic semiconductors. Nat. Phys. 2010, 6, 615–620. 5. Bogani, L.; Wernsdorfer, W. Molecular spintronics using single-molecule magnets. Nat. Mater. 2008, 7, 179–184. 6. Urdampilleta, M.; Klyatskaya, S.; Cleuziou, J.-P.; Ruben, M.; Wernsdorfer, W. Supramolecular spin valves. Nat. Mater. 2011, 10, 502–506. 7. Sanvito, S. Filtering spins with molecules. Nat. Mater. 2011, 10, 484–485. 8. Hueso, L.E.; Pruneda, J.M.; Ferrari, V.; Burnell, G.; Valdés-Herrera, J.P.; Simons, B.D.; Littlewood, P.B.; Artacho, E.; Fert, A.; Mathur, N.D. Transformation of spin information into large electrical signals using carbon nanotubes. Nature 2007, 445, 410–413. 9. Aurich, H.; Baumgartner, A.; Freitag, F.; Eichler, A.; Trbovic, J.; Schönenberger, C. Permalloybased carbon nanotube spin-valve. Appl. Phys. Lett. 2010, 97, 153116. 10. Kim, W.Y.; Kim, K.S. Prediction of very large values of magnetoresistance in a graphene nanoribbon device. Nat. Nanotechnol. 2008, 3, 408–412. 11. Candini, A.; Klyatskaya, S.; Ruben, M.; Wernsdorfer, W.; Affronte, M. Graphene spintronic devices with molecular nanomagnets. Nano Lett. 2011, 11, 2634–2639. 12. Kong, J.; Soh, H.T.; Cassell, A.M.; Quate, C.F.; Dai, H. Synthesis of individual single-walled carbon nanotubes on patterned silicon wafers. Nature 1998, 395, 1–4. 13. Klyatskaya, S.; Galan-Mascarós, J.R.G.; Bogani, L.; Hennrich, F.; Kappes, M.; Wernsdorfer, W.; Ruben, M. Anchoring of rare-earth-based single-molecule magnets on single-walled carbon nanotubes. J. Am. Chem. Soc. 2009, 131, 15143–15151. 14. Ishikawa, N.; Sugita, M.; Wernsdorfer, W. Quantum tunnelling of magnetization in lanthanide single-molecule magnets: bis(phthalocyaninato)terbium and bis(phthalocyaninato)dysprosium anions. Angew. Chem. Int. Ed. 2005, 44, 2931–2935. 15. Ishikawa, N.; Sugita, M.; Okubo, T.; Tanaka, N.; Iino, T.; Kaizu, Y. Determination of ligand-field parameters and f-electronic structures of double-decker bis(phthalocyaninato)lanthanide complexes. Inorg. Chem. 2003, 42, 2440–2446.
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