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A solution and solid state study of niobium complexes University of ...

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Appendix A<br />

O(5)-Nb(1)-O(4) 99.36 (11)<br />

O(6)-Nb(1)-O(4) 96.53 (11)<br />

O(5)-Nb(1)-O(1) 97.12 (10)<br />

O(6)-Nb(1)-O(1) 87.70 (10)<br />

O(4)-Nb(1)-O(1) 161.84 (10)<br />

O(5)-Nb(1)-O(3) 92.16 (10)<br />

O(6)-Nb(1)-O(3) 163.66 (10)<br />

O(4)-Nb(1)-O(3) 90.66 (11)<br />

O(1)-Nb(1)-O(3) 81.12 (10)<br />

O(5)-Nb(1)-O(2) 171.85 (10)<br />

O(6)-Nb(1)-O(2) 86.28 (10)<br />

O(4)-Nb(1)-O(2) 83.14 (11)<br />

O(1)-Nb(1)-O(2) 79.50 (10)<br />

O(3)-Nb(1)-O(2) 80.03 (10)<br />

O(1)-Nb(2)-O(9) 102.79 (11)<br />

O(1)-Nb(2)-O(10) 98.99 (12)<br />

O(9)-Nb(2)-O(10) 97.89 (13)<br />

O(1)-Nb(2)-O(5) #1 93.53 (10)<br />

O(9)-Nb(2)-O(5) #1 90.30 (10)<br />

O(10)-Nb(2)-O(5) #1 163.11 (12)<br />

O(1)-Nb(2)-O(7) 93.04 (10)<br />

O(9)-Nb(2)-O(7) 162.89 (11)<br />

O(10)-Nb(2)-O(7) 85.84 (12)<br />

O(5)#1-Nb(2)-O(7) 82.19 (10)<br />

O(1)-Nb(2)-O(8) 169.62 (10)<br />

O(9)-Nb(2)-O(8) 84.44 (12)<br />

O(10)-Nb(2)-O(8) 87.22 (12)<br />

O(5)#1-Nb(2)-O(8) 78.86 (10)<br />

O(7)-Nb(2)-O(8) 79.04 (11)<br />

C(18A)-C(17A)-O(10) 145.8 (8)<br />

C(18A)-C(17A)-H(17A) 100.4<br />

O(10)-C(17A)-H(17A) 100.4<br />

C(18A)-C(17A)-H(17B) 100.4<br />

O(10)-C(17A)-H(17B) 100.4<br />

H(17A)-C(17A)-H(17B) 104.3<br />

C(18B)-C(17B)-O(10) 141.2 (10)<br />

C(18B)-C(17B)-H(17C) 101.7<br />

O(10)-C(17B)-H(17C) 101.7<br />

C(18B)-C(17B)-H(17D) 101.7<br />

O(10)-C(17B)-H(17D) 101.7<br />

H(17C)-C(17B)-H(17D) 104.7<br />

C(17B)-C(18B)-H(18D) 109.5<br />

C(17B)-C(18B)-H(18E) 109.5<br />

H(18D)-C(18B)-H(18E) 109.5<br />

C(17B)-C(18B)-H(18F) 109.5<br />

H(18D)-C(18B)-H(18F) 109.5<br />

105

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