A solution and solid state study of niobium complexes University of ...

Appendix A
Table 1.3: Bond angles (°) for [NbCl(acac)(OMe) 3].
Bond Angle (°)
O(1)-C(1)-C(2) 123.7 (2)
O(1)-C(1)-C(4) 116.3 (2)
C(2)-C(1)-C(4) 120.0 (2)
C(3)-C(2)-C(1) 123.7 (2)
O(2)-C(3)-C(2) 123.9 (2)
O(2)-C(3)-C(5) 116.1 (2)
C(2)-C(3)-C(5) 120.0 (2)
C(1)-O(1)-Nb(1) 133.52 (17)
C(3)-O(2)-Nb(1) 133.85 (17)
C(6)-O(3)-Nb(1) 141.75 (17)
C(7)-O(4)-Nb(1) 150.56 (17)
C(8)-O(5)-Nb(1) 144.13 (17)
O(5)-Nb(1)-O(4) 100.76 (9)
O(5)-Nb(1)-O(3) 100.03 (9)
O(4)-Nb(1)-O(3) 99.47 (8)
O(5)-Nb(1)-O(2) 163.65 (8)
O(4)-Nb(1)-O(2) 91.55 (8)
O(3)-Nb(1)-O(2) 88.37 (8)
O(5)-Nb(1)-O(1) 85.76 (8)
O(4)-Nb(1)-O(1) 170.14 (8)
O(3)-Nb(1)-O(1) 86.53 (8)
O(2)-Nb(1)-O(1) 80.74 (8)
O(5)-Nb(1)-Cl(1) 87.49 (7)
O(4)-Nb(1)-Cl(1) 88.75 (6)
O(3)-Nb(1)-Cl(1) 167.55 (6)
O(2)-Nb(1)-Cl(1) 82.03 (6)
O(1)-Nb(1)-Cl(1) 84.13 (6)
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