Tuning Reactivity of Platinum(II) Complexes

Table S5.9: Average observed rate constants, kobs(2 nd), at 298.15 K, for the reactions of
pmn with a series of nucleophiles at different concentrations.
[NU]/ M kobs(2 nd ), s -1
TU DMTU TMTU
0.002 2.462 x 10 -4 1.449 x 10 -4 9.097 x 10 -5
0.004 4.909 x 10 -4 3.197 x 10 -4 1.550 x 10 -4
0.006 7.333 x 10 -4 4.3479 x 10 -4 2.380 x 10 -4
0.008 9.149 x 10 -4 5.764 x 10 -4 3.220 x 10 -4
0.01 0.00122 7.244 x 10 -4 —
Table S5.10: Average observed rate constants, kobs(3 rd ), at 298.15 K, for the
displacement of the bridging ligand of pmn with a series of
nucleophiles at different concentrations.
[NU]/ M kobs(3 rd ), s -1
TU DMTU TMTU
0.002 5.634 x 10 -5 4.697 x 10 -5 6.858 x 10 -6
0.004 1.115 x 10 -4 9.291 x 10 -5 1.3745 x10 -5
0.006 1.645 x 10 -4 1.364 x 10 -4 2.065 x 10 -5
0.008 2.240 x 10 -4 1.869 x 10 -4 2.796 x 10 -5
0.010 — — 3.429 x 10 -5
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