Tuning Reactivity of Platinum(II) Complexes
Tuning Reactivity of Platinum(II) Complexes Tuning Reactivity of Platinum(II) Complexes
16 H. Ertürk, J. Maigut, R. Puchta and R. van Eldik, 2008, Dalton Trans., 2759. 17 H. Ertürk, R. Puchta and R. van Eldik, 2009, Eur. J. Inorg. Chem., 1334. 18 A. Mambanda, D. Jaganyi, S. Hochreuther and R. van Eldik, 2010, Dalton Trans., 39, 3595. 19 S. Bonnet, M. A. Siegler, J. H, van Lenthe, M. Lutz, A. L. Spek, G. van Koten and R. J. M. Klein Gebbink, 2010, Eur. J. Inorg. Chem. 4667-4674 and references therein. 20 J. E. Sutton and H. Taube, 1981, Inorg. Chem., 20, 3126. 21 R. Dembinski, T. Bartik, B. Bartik, M. Jaeger and J. Gladysz, 2000. J. Am. Chem. Soc., 122, 810. 22 R. Romeo, M. R. Plutino, M. L. Scolaro, S. Stoccoro and G. Minghetti, 2000, Inorg. Chem., 39, 4749. 23 J. W. Williams, Y. Qu, G. H. Bulluss, E. Alvorado and N. Farrell, 2007, Inorg. Chem., 46, 5821. 24 N. Summa, J. Maigut, R. Puchta and R. van Eldik, 2007. Inorg. Chem., 46, 2094. 25 V. Vacchina, L. Torte, C. Allievi and R. Lobeinski, 2003, J. Anal. Atomic Spectrom., 18, 884. 26 S. J. Hoseini, S. M. Nabavizadeh, S. Jamali, and M Rashidi, 2007, J.Organomet. Chem., 692, 1990. 27 S. Budagumpi, G. S. Kurdekar, N. V. Kulkarni and V. K. Revankar, 2010, J. Incl. Phenom. Macrocyl. Chem., 67, 271, and references cited therein. 28 N. Nédélec and F. D. Rochon, 2001, Inorg. Chem., 40, 5236. 29 (a) J. S. Gardner and D. P. Strommen, 2003, J. Phys. Chem., 107, 351; (b) F. D. Rochon and M. Fakhfakh, 2009, Inorg. Chim. Acta, 362. 1455. 34
30 D. Donghi, G. D`Alfonso, M. Mauro, M. Panigati, P. Mercandelli, A. Sironi, P. Mussini and L. D`Alfonso, 2008, Inorg. Chem., 47, 4243. 31 D. D. Perrin, W. L. F. Armarego, D. R. Perrin, 1980, Purification of Laboratory Chemicals, 2nd Ed., Pergamon, Oxford. 32 G. V. Kalayda, S. Komeda,K. Ikeda, T. Sato, M. Chikuma and J. Reedijk, 2003, Eur. J. Inorg. Chem., 4347. 33 A. D. Becke, 1993, J. Chem. Phys., 98, 5648. 34 P. J. Hay and W.R Wadt, 1985, J. Chem. Phys., 82, 299. 35 (a) Z. D. Bugarčić, G. Liehr and R. van Eldik, J. Chem. Soc., Dalton Trans., 2002, 951; (b) Z. D. Bugarčič, B. V. Petrović and R. Jelić, 2001, Transition Met. Chem., 26, 668. 36 T. G. Appleton, J. R. Hall, S. F. Ralph and C. S. M. Thompson, 1984, Inorg. Chem., 23, 3521. 37 MicrocalTM OriginTM Version 7.5, Microcal Software, Inc., One Roundhouse Plaza, Northampton, MA, 01060, USA, 1991-2003. 38 A. R. Katrityzky, C. A. Ramsden, J. A. Joule and V. V. Zhdankin, 2010, Handbook of Heterocyclic Chemistry, 3rd Ed., Elsevier Publishers, UK, pp. 17-20. 39 S. Komeda, G. V. Kalayda, M. Lutz, A. L. Spek, Y. Yamanaka, T. Sato, M. Chikuma and J. Reedijk, 2003, J. Med. Chem., 46, 1210. 40 M. Willermann, C. ulcahy, R. K. O. Sigel, M. M. Cerdià, E. Freisinger, P. J. Sanz Miguel, M. Roitzsch and B. Lippert, 2006, Inorg. Chem., 46, 2093. 41 S. Chatterjee, J. A. Krause, A. G. Oliver and W. B. Connick, 2010, Inorg. Chem., 49, 9798. 42 A. Hofmann, L. Dahlernburg and R. van Eldik, 2003, Inorg. Chem., 42, 6528. 35
- Page 200 and 201: Table S4.13: Average observed rate
- Page 202 and 203: Table S4.14: Average observed rate
- Page 204 and 205: Table S4.18: Average observed rate
- Page 206 and 207: k obs(1 st ) , s -1 0.06 0.04 0.02
- Page 208 and 209: Table S4.23: Average observed rate
- Page 210 and 211: ln(k 2(3 rd ) /T) -10.0 -10.5 -11.0
- Page 212 and 213: SpinWorks 2.5: 2,6 pznClO4 in D2O N
- Page 214 and 215: Table of Contents-5 Chapter 5 .....
- Page 216 and 217: List of Tables Table 5.1: A summary
- Page 218 and 219: 5.1 Introduction Multinuclear plati
- Page 220 and 221: onding. For this reason, pKa titrat
- Page 222 and 223: 400-300 cm -1): 3308, 3117, 3071 (N
- Page 224 and 225: 5.2.6 Spectrophotometric pKa Titrat
- Page 226 and 227: Table 5.1: A summary of DFT-calcula
- Page 228 and 229: However, because the highest occupi
- Page 230 and 231: Table 5.2: Acid dissociation consta
- Page 232 and 233: Table 5.3: A summary of DFT calcula
- Page 234 and 235: H3N 6 eq TU 0 eq TU Ha NH3 Ha Cl TU
- Page 236 and 237: third step due to the trans-effect
- Page 238 and 239: [H 2 O-Pt-(NN)-Pt-OH 2 ] +4 [NU-Pt-
- Page 240 and 241: k obs(1st) / s -1 0.20 TU DMTU TMTU
- Page 242 and 243: thiourea nucleophile is large enoug
- Page 244 and 245: ln(k st 2(1 ) /T) -3 -4 -5 -6 -7 -8
- Page 246 and 247: is the same as the electron-withdra
- Page 248 and 249: associative mode of substitution me
- Page 252 and 253: 43 (a) D. Jaganyi, A. Hofmann and R
- Page 254 and 255: 276 nm Absorbance 0 . 6 5 0 . 6 4 0
- Page 256 and 257: k obs(1 st ) , s -1 0.4 0.3 0.2 0.1
- Page 258 and 259: Table S5.5: Average observed rate c
- Page 260 and 261: ln(k 2(2 nd ) /T) -8.0 TU -8.5 -9.0
- Page 262 and 263: pzn PPM -1750.0 -1850.0 -1950.0 -20
- Page 264 and 265: Table S5.9: Average observed rate c
- Page 266 and 267: Figure S5.13: UV/Visible spectra fo
- Page 268 and 269: k obs(1 st ) in s -1 0.030 0.025 0.
- Page 270 and 271: Table S5.17: Average observed rate
- Page 272 and 273: ln(k 2(2 nd ) /T) -10 -11 -12 -13 -
- Page 274 and 275: 9.61 ppm Ha PPM 9.8 9.6 9.4 9.2 9.0
- Page 276 and 277: Table S5.22: Average observed rate
- Page 278 and 279: k obs(3rd) / s -1 -5 8 .00 x 10 T U
- Page 280 and 281: ln(k st 2(1 ) /T) -1.5 TU DMTU TMTU
- Page 282 and 283: ln(k rd 2(3 ) /T) -8.5 -9.0 -9.5 -1
- Page 284 and 285: SpinWorks 2.5: znPt(II)-OP4 in D2O
- Page 286 and 287: Figure S5.31: Mass spectrum for com
- Page 288 and 289: Table S5.28: Average observed rate
- Page 290 and 291: Table S5.29: Average observed rate
- Page 292 and 293: ln(k st 2(1 ) /T) -4 -5 -6 -7 -8 -9
- Page 294 and 295: SpinWorks 2.5: phtPt(II)-OP2 in D2O
- Page 296 and 297: Figure S5.41: Mass spectrum for com
- Page 298 and 299: List of Figures Figure 6.1: Spectro
30 D. Donghi, G. D`Alfonso, M. Mauro, M. Panigati, P. Mercandelli, A. Sironi, P.<br />
Mussini and L. D`Alfonso, 2008, Inorg. Chem., 47, 4243.<br />
31 D. D. Perrin, W. L. F. Armarego, D. R. Perrin, 1980, Purification <strong>of</strong> Laboratory<br />
Chemicals, 2nd Ed., Pergamon, Oxford.<br />
32 G. V. Kalayda, S. Komeda,K. Ikeda, T. Sato, M. Chikuma and J. Reedijk, 2003, Eur. J.<br />
Inorg. Chem., 4347.<br />
33 A. D. Becke, 1993, J. Chem. Phys., 98, 5648.<br />
34 P. J. Hay and W.R Wadt, 1985, J. Chem. Phys., 82, 299.<br />
35 (a) Z. D. Bugarčić, G. Liehr and R. van Eldik, J. Chem. Soc., Dalton Trans., 2002, 951;<br />
(b) Z. D. Bugarčič, B. V. Petrović and R. Jelić, 2001, Transition Met. Chem., 26, 668.<br />
36 T. G. Appleton, J. R. Hall, S. F. Ralph and C. S. M. Thompson, 1984, Inorg. Chem., 23,<br />
3521.<br />
37 MicrocalTM OriginTM Version 7.5, Microcal S<strong>of</strong>tware, Inc., One Roundhouse<br />
Plaza, Northampton, MA, 01060, USA, 1991-2003.<br />
38 A. R. Katrityzky, C. A. Ramsden, J. A. Joule and V. V. Zhdankin, 2010, Handbook <strong>of</strong><br />
Heterocyclic Chemistry, 3rd Ed., Elsevier Publishers, UK, pp. 17-20.<br />
39 S. Komeda, G. V. Kalayda, M. Lutz, A. L. Spek, Y. Yamanaka, T. Sato, M. Chikuma<br />
and J. Reedijk, 2003, J. Med. Chem., 46, 1210.<br />
40 M. Willermann, C. ulcahy, R. K. O. Sigel, M. M. Cerdià, E. Freisinger, P. J. Sanz<br />
Miguel, M. Roitzsch and B. Lippert, 2006, Inorg. Chem., 46, 2093.<br />
41 S. Chatterjee, J. A. Krause, A. G. Oliver and W. B. Connick, 2010, Inorg. Chem., 49,<br />
9798.<br />
42 A. H<strong>of</strong>mann, L. Dahlernburg and R. van Eldik, 2003, Inorg. Chem., 42, 6528.<br />
35