Tuning Reactivity of Platinum(II) Complexes

Table 4.4. Summary of Activation parameters for the substitution of
coordinated water ligands and the displacement of the linker by
thiourea nucleophiles in [cis-{PtOH2(NH3)2-μ-pzn] +4 complexes
……………………………………………………………………………………………..28
Table 4.5. DFT calculated (NBO) charges for Pt atoms of optimised
structures of monoaquaTU-substituted complexes ………………….32
Table 5.1. A summary of DFT-calculated parameters for the aqua complexes
pzn to pht. The table is ordered according to increasing values of
Natural Atomic charges (NBO) of Pt(II) centres ………………………10
Table 5.2 Acid dissociation constants of platinum(II) complexes determined
spectrophotometrically at 25 °C (Ionic strength, I = 0.1 M NaClO4/
HClO4) …………………………………………………………………………………...14
Table 5.3. A summary of DFT calculated Parameters for aqua/hydroxo
complex systems of benzodiazines and their monocyclic
analogues ………………………………………………………………………………16
Table 5.4 Summary of second order rate constants of diazine-bridged
dinuclear Pt(II) complexes; I = 0.1 M (NaClO4, adjusted with
HClO4), T = 298.15 K ………………………………………………………………23
Table 5.5 Summary of Activation parameters for the displacement of
coordinated water by a series of nucleophiles in complexes of the
Type [cis-{PtOH2(NH3)2-μ-pzn] +4 , I = 0.1 M NaClO4 …….….…………27
Table 6.1 Summary of the pKa values obtained for the deprotonation of
platinum-bound water of the different complexes …………………...11
Table 6.2 DFT-calculated parameters for platinum(II)complexes ……………13
Table 6.3 Summary of rate constants and activation parameters with the
corresponding standard deviations for the substitution of aqua
ligands by neutral (TU, DMTU, and TMTU) and ionic (I¯, Br¯ and
SCN¯) nucleophiles, I = 0.10 M (NaClO4) …………………………………..21
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