Tuning Reactivity of Platinum(II) Complexes
Tuning Reactivity of Platinum(II) Complexes Tuning Reactivity of Platinum(II) Complexes
3.6 References 1 D. Rosenberg, L. Van Camp, J. E. Trusko and V. H. Mansour, Nature, 1969, 222, 385. 2 V. X. Jin, S. I. Tan and J. N. Ranford, Inorg. Chim. Acta, 2005, 358, 677. 3 C. S. Peyratout, T. K. Aldridge, D. K. Crites and D.R. McMillin, Inorg. Chem., 1995, 34, 4484. 4 M. Casamento, G. E. Arena, C. Lo Passo,I. Pernice, A. Romeo and L. M. Scolaro, Inorg. Chim. Acta, 1998, 276, 242-249. 5 S. Bonse, J. M. Richards, S. A. Ross, G. Lowe and R. L. Krauth-Siegel, J. Med. Chem., 2000, 43, 4812. 6 (a) G. Lowe, A. S. Droz, T. Vilaivan, G. W. Weaver, L. Tweedale, J. M. Pratt, P. Rock, V. Yardley and S. L.Croft, J. Med. Chem., 1999, 42, 999; (b) G. Lowe, A. S. Droz, G. W. Weaver, J. J. Park, J. M. Pratt, L. Tweedale and L. R. J. Kelland, J. Med. Chem., 1999, 42, 3167. 7 Z. D.Bugarčić, G. Liehr and R. van Eldik, J. Chem. Soc., Dalton Trans., 2002, 2825. 8 B. Pitteri, G. Marangoni, L. Cattalini and T. J. Bobbo, J. Chem. Soc., Dalton Trans., 1995, 3853. 9 R. Romeo, M. R. Plutino, L. M. Scolaro, S. Stoccoro and G. Minghetti, Inorg. Chem., 2000, 39, 4749, and references therein. 10 J. Fazlur-Rahman and G. Verkade, Inorg. Chem., 1992, 31, 2064. 11 B. Pitteri, G. Marangoni, L. Cattalini, F. Visentin, V. Bertolasi and P. Gilli, Polyhedron, 2001, 20, 869. 12 R. J. Mureinik, M Bidani, Inorg. Chim. Acta, 1978, 29, 37. 13 D. Reddy and D. Jaganyi, Dalton Trans., 2008, 6724. 14 D. Jaganyi, D. Reddy, J-A. Gertenbach, A. Hofmann and R. van Eldik, Dalton Trans., 2004, 299. 25
15 D. Jaganyi, K-L, De Boer, J-A. Gertenbach and J. Perils, Int. J. Chem. Kinet., 2008, 807. 16 A. Hofmann, D. Jaganyi, O, Q. Munro, G. Liehr and R. van Eldik, Inorg. Chem., 2003, 42, 1688. 17 D. Jaganyi, A. Hofmann and R. van Eldik, Angew. Chem. Int. Ed. Engl. 2001, 40, 1680. 18 G. C. Summerton, Ph. D. Thesis, University of Natal, Pietermaritzburg, Republic of South Africa, 1997, pp. 51, 53, 71-77, 94, 107. 19 J. S. Field, R. J. Haines, D. R. McMillin, G. C. Summerton, J. Chem. Soc., Dalton Trans., 2002, 1369. 20 J. S. Field, J-A, Gertenbach, D. Jaganyi, D. R. McMillin, D. J. Stewart and A. Shaira, Z. Naturforsch., 2010, 65b, 1318. 21 J. J. Moore, J. J. Nash, P. E. Fanwick and D. R. McMillin, Inorg. Chem., 2002, 41, 6387. 22 A. Hofmann, L. Dahlenburg, and R. van Eldik, Inorg. Chem., 2003, 42, 6528-6538. 23 T. G. Appleton, J. R. Hall, S. F. Ralph and C. S M. Thompson, Inorg. Chem., 1984, 41, 3521. 24 J. S. Field, R. J. Haines, D. R. McMillin, G. C. Summerton, J. Chem. Soc., Dalton Trans., 2002, 1369. 25 J. X. McDermott, J. F. White and G. M. Whitesides, J. Am. Chem. Soc., 1976, 98, 6521. 26 A. Shaira, MSC Thesis, A Kinetic and Mechanistic study into the Substitution Behaviour of Platinum(II) Polypyridyl Complexes with a Series of Azole Ligands, University of KwaZulu-Natal, Pietermaritzburg, 2010. 27 E. Kröhnke, Synthesis, 1976, 1. 28 G. C. Summerton, PhD Thesis, Solid State Structures and Photophysical Properties of Polypyridyl Complexes of platinum(II), University of Natal, Pietermaritzburg, South Africa, 1997, pp. 23-25,32-33,70-75,153-154. 29 G. Annibale, M. Brandolisio and B. Pitteri, Polyhedron, 1995, 14, 451. 26
- Page 80 and 81: Figure 2.6: Schematic diagram of a
- Page 82 and 83: The light transmitted from the samp
- Page 84 and 85: c. Oxidizability: Ligands that are
- Page 86 and 87: Table 2.1: A selection of n o pt va
- Page 88 and 89: eaction with different nucleophiles
- Page 90 and 91: eaction site from direct attack by
- Page 92 and 93: PEt 3 PEt 3 R PEt 3 Pt Pt Y Y Cl R
- Page 94 and 95: direct displacement of the leaving
- Page 96 and 97: therefore, weaken the bond of the l
- Page 98 and 99: σ-Donation According to classical
- Page 100 and 101: References 1 (a) J. Reedijk, Chem.
- Page 102 and 103: 34 R. B. Jordan, Reaction Mechanism
- Page 104 and 105: Table of Contents-3 Chapter 3.The
- Page 106 and 107: Chapter 3 The π-Acceptor Effect in
- Page 108 and 109: In order to extend our understandin
- Page 110 and 111: after which water was added to quen
- Page 112 and 113: O CH 3 + I + N O oH - N O O 7 CH 3
- Page 114 and 115: 84% (34.7 mg, 0.0618 mmol). 1 H NMR
- Page 116 and 117: PhCN PhCN Pt Cl Cl + N N CH 3 N CH
- Page 118 and 119: Complex Structure HOMO LUMO PtCl CH
- Page 120 and 121: The geometry-optimised structures i
- Page 122 and 123: against the concentration of the in
- Page 124 and 125: Table 3.2: Summary of the second-or
- Page 126 and 127: constants of CH3PhisoqPtCl decrease
- Page 128 and 129: with π*-orbitals of the ligand. Th
- Page 132 and 133: 30 Microcal TM Origin TM Version 5.
- Page 134 and 135: Figure S3.1: Kinetic trace at 448 n
- Page 136 and 137: ln(k 2 /T) -6.0 -7.5 -9.0 -10.5 -12
- Page 138 and 139: Table S3.3b: Average observed rate
- Page 140 and 141: Table S3.5b: Temperature dependence
- Page 142 and 143: Table S3.8: DFT calculated electros
- Page 144 and 145: List of Figures Figure 4.1: Structu
- Page 146 and 147: Table 4.2: Summary of pKa values fo
- Page 148 and 149: 4.1 Introduction Platinum compounds
- Page 150 and 151: cis geometry, leading to dramatic c
- Page 152 and 153: ligand was added to the [{cis-PtCl(
- Page 154 and 155: spectra were measured in and refere
- Page 156 and 157: 4.3.1 DFT calculated Optimized Stru
- Page 158 and 159: Table 4.1: A summary of the DFT cal
- Page 160 and 161: H2O-Pt-L-Pt-OH2 H2O-Pt-L-Pt-OH2 H2O
- Page 162 and 163: electrophilicity and acidity of the
- Page 164 and 165: (A) 18 Absorbance 0.08 0.07 0.06 0.
- Page 166 and 167: k obs(3 rd ) , s -1 -5 6.00x10 TMTU
- Page 168 and 169: 4.3.4 Kinetics with NMR The substit
- Page 170 and 171: ln([ML] t ) 4.0 3.5 3.0 2.5 2.0 1.5
- Page 172 and 173: ln(k 2(1 st ) /T) -3.5 -4.0 -4.5 -5
- Page 174 and 175: Comple x Table 4.4: Summary of Acti
- Page 176 and 177: The decrease in reactivity of 2,6pz
- Page 178 and 179: Table 4.5: DFT calculated (NBO) cha
3.6 References<br />
1 D. Rosenberg, L. Van Camp, J. E. Trusko and V. H. Mansour, Nature, 1969, 222,<br />
385.<br />
2 V. X. Jin, S. I. Tan and J. N. Ranford, Inorg. Chim. Acta, 2005, 358, 677.<br />
3 C. S. Peyratout, T. K. Aldridge, D. K. Crites and D.R. McMillin, Inorg. Chem., 1995,<br />
34, 4484.<br />
4 M. Casamento, G. E. Arena, C. Lo Passo,I. Pernice, A. Romeo and L. M. Scolaro,<br />
Inorg. Chim. Acta, 1998, 276, 242-249.<br />
5 S. Bonse, J. M. Richards, S. A. Ross, G. Lowe and R. L. Krauth-Siegel, J. Med. Chem.,<br />
2000, 43, 4812.<br />
6 (a) G. Lowe, A. S. Droz, T. Vilaivan, G. W. Weaver, L. Tweedale, J. M. Pratt, P. Rock,<br />
V. Yardley and S. L.Cr<strong>of</strong>t, J. Med. Chem., 1999, 42, 999; (b) G. Lowe, A. S. Droz, G. W.<br />
Weaver, J. J. Park, J. M. Pratt, L. Tweedale and L. R. J. Kelland, J. Med. Chem., 1999,<br />
42, 3167.<br />
7 Z. D.Bugarčić, G. Liehr and R. van Eldik, J. Chem. Soc., Dalton Trans., 2002, 2825.<br />
8 B. Pitteri, G. Marangoni, L. Cattalini and T. J. Bobbo, J. Chem. Soc., Dalton Trans.,<br />
1995, 3853.<br />
9 R. Romeo, M. R. Plutino, L. M. Scolaro, S. Stoccoro and G. Minghetti, Inorg. Chem.,<br />
2000, 39, 4749, and references therein.<br />
10 J. Fazlur-Rahman and G. Verkade, Inorg. Chem., 1992, 31, 2064.<br />
11 B. Pitteri, G. Marangoni, L. Cattalini, F. Visentin, V. Bertolasi and P. Gilli,<br />
Polyhedron, 2001, 20, 869.<br />
12 R. J. Mureinik, M Bidani, Inorg. Chim. Acta, 1978, 29, 37.<br />
13 D. Reddy and D. Jaganyi, Dalton Trans., 2008, 6724.<br />
14 D. Jaganyi, D. Reddy, J-A. Gertenbach, A. H<strong>of</strong>mann and R. van Eldik, Dalton Trans.,<br />
2004, 299.<br />
25
Change language