Design og modellering af metanolanlæg til VEnzin-visionen Bilag

27.07.2013 Views
0 1 1 1 P 2 M type NOD* 12 2 type NOD* 1 1 1 Energy flow 2 Cost flow type NOD* 5 2 1 Exergy efficiency 2 Exergy destruction Water Steam 3T 13 2 3Exergy destruction cost flow - based on specific cost of input 3.4 -0 1.9 3.399 4H 14 2 4Exergy destruction cost flow - based on specific cost of output 1 0.11 kr/s Electrolyser 423 0.07 kr/s 8.55 412 2 5EX 6 EX_CH * Number of decimals 5 Component cost flow Electrolyser 2 0.107 - kr/MJ 0.03 kr/kg 56.3 MW SAND 201 56.34 2 0.07 0.02 kr/MJ 0.04 kr/kg 1.9 97.97 8.55 kr/s 0.09 kr/MJ NG 7 EX_PH SAND 301 Electrolyser NG_reformer 4.52 kr/kg 8X 9 EX*M 10 EX_CH*M Comp-O2-1 DH water 0.381 803 4 78.5 0.38 kr/s Electrolyser 18.62 2.4 0.26 0 802 2 78.5 0.00 kr/s DH water 0.29 Steam reformer 9.22 NG_reformer O2 11 EX_PH*M 0.0 MW 1 0.927 0.41 kr/MJ 3.0 0.393 0.4 44.05 0.643 0.00 kr/MJ 1.8 1.339 12 C 13 C/EX SAND 1E-05 0.00 kr/kg Electro-cool 3 4 0.16 kr/s 0.41 kr/MJ 2 18.08 kr/s 4 0.41 kr/MJ 0.00 kr/kg Electro-cool Comp-O2-2 0.6 MW 3 Reformat 5.6 95.09 403 2 0.31 kr/s 0.23 kr/MJ 0.0 0 Ash 0.3 0.252 83 0.00 kr/s 4 0.00 kr/MJ 14 C/M O2 0.066 7 4 0.066 0.00 1.2 0.07 kr/s 0.16 0.41 kr/MJ 0.05 kr/kg Comp-O2-1 0.066 5 2 1.2 0.07 kr/s 0.16 0.41 kr/MJ 0.05 kr/kg Comp-O2-1 DH water Gas 0.161 0.05 kr/kg Electrolyser 0.0 9E-36 6 0.00 kr/s 4 0.41 kr/MJ 18.08 48.11 kr/kg Electrolyser H2 O2 0.095 401 2 1.8 0.10 kr/s 0.233 0.41 kr/MJ 0.05 kr/kg SAND 0.604 0.309 402 4 0.01 0.309 1.8 0.31 kr/s 0.799 0.39 kr/MJ 0.18 kr/kg 431 9.22 kr/s 4 0.10 kr/MJ 9.22 1.66 kr/kg NG_reformer 0.31 0.18 kr/kg NG_reformer 0.6 10.73 441 1.04 kr/s 2 0.10 kr/MJ 1.041 1.66 kr/kg Heatex-O2 Gasifier 304 0.0 MW SAND 0 0.00 kr/kg Gasifier 0.0 0.009 1.3 33 2 0.01 kr/s Steam 32 8.4 10.81 0.06 kr/s 801 2 6.8 0.056 0.00 kr/s 0.00 kr/MJ 15 4 0.0 0.016 0.00 kr/s 0.00 kr/MJ Heatsink-H2 4E-36 0.05 kr/kg Split-O2-2 O2 0.00 Comp-H2 Comp-O2-2 Comp-O2-2 432 2 1.6 27.62 2.68 kr/s 0.10 kr/MJ 0.8 0.31 0.00 Heatex-O2 SAND 11 1.707 0.01 kr/MJ Heatex-GG-st 4 0.01 kr/MJ 0 0.00 kr/kg 0 0.00 kr/kg 0.0 MW 322 18.08 0.0 MW 9 Comp-CO2 2.678 1.66 kr/kg 0.01 kr/kg SAND 7 0.06 0.01 kr/kg Heatex-GG-DH Cleaner SAND 0.0 SAND 6E-05 0.0 MW 7 Heatex-NG 1.39 5 Gasifier 6.6 144.7 5 8.9 131.6 Gasifier 10 GG2 0.07 0.00 5.42 kr/s 0.9 0.04 kr/MJ 0.61 kr/kg 5 8.9 130.9 11 2 5.42 kr/s 0.04 kr/MJ 0.61 kr/kg Heatex-GG-st 0.06 0.01 5 10.8 8.9 124.8 12 2 0.00 0.00 5.42 kr/s 1.1 0.04 kr/MJ 0.61 kr/kg Heatex-GG-DH 5 8.9 124.6 13 2 5.42 kr/s 0.04 kr/MJ 0.61 kr/kg 0.00 Gas cleaner 5.4 8.9 124.5 14 5.42 kr/s 0.00 Heatsink 18.08 18.08 511 2 0.4 18.08 kr/s 44.05 0.41 kr/MJ 48.11 kr/kg Heatsink-H2 9.671 503 4 5.2 9.67 kr/s SAND 0.003 0.002 502 4 0.002 0.001 501 2 0.00 0.0 0.00 kr/s 0.0 0.00 kr/s CO2 8.545 411 2 NG1.9 8.55 kr/s 95.97 0.09 kr/MJ 4.51 kr/kg Heatex-NG 451 Heatex-NG SAND 3.3 56.74 5.50 kr/s 3.9 13 8.55 0.00 0 434 Water 2 0.1 0.00 kr/s 82 3.96 kr/s Heatex-GG-O2 Heatex-GG-st Heatex-GG-DH SAND 9 Cleaner 4 0.04 kr/MJ 88.77 0.11 kr/MJ 0.007 0.30 kr/MJ 0.005 0.25 kr/MJ 2 0.10 kr/MJ 0.007 0.00 kr/MJ 2 0.03 kr/MJ 0.07 9 2 Heatex-GG-O2 8.4 4.755 0 21 4 5.4 0.61 kr/kg 1.86 kr/kg 0.20 kr/kg 0.11 kr/kg 5.501 1.66 kr/kg 0.00 kr/kg 3.96 0.60 kr/kg 1.2 0.07 kr/s SAND 5 31 0.04 kr/s 0.0 0.00 kr/s Cleaner 18.08 512 2 26.82 524 4 14.4 264.3 Mixer-CO2-NG Comp-CO2 Comp-CO2 Heatex-H2O Pres-sep-3 Gasifier H2O [mass-%] = 0.05 Dry-wood 0.653 0.10 kr/MJ 0.05 kr/kg Gasifier 2 0.01 kr/MJ 0.043 0.01 kr/kg Heatex-GG-st -0 0.00 kr/MJ 9.2 168.4 0.00 kr/kg 521 23.50 kr/s Heatex-GG-DH 2 0.14 kr/MJ 0.4 18.08 kr/s 44.05 0.41 kr/MJ 48.11 kr/kg 9.2 26.82 kr/s 175.7 0.15 kr/MJ 2.91 kr/kg 531 36.49 kr/s 2 0.14 kr/MJ 36.49 2.53 kr/kg 0.061 422 2 Water 1.9 0.06 kr/s 0.006 10.14 kr/MJ 7.8 Heatex-H2O 0.07 0.01 SAND 15 0 453 Water 4 Steam 811 6.8 0.237 0.00 kr/s 23.50 2.55 kr/kg Comp-GG-H2-1 Comp-GG-H2-1 5.1 MW 11 Mixer-GG-H2 Comp-GG-H2-2 36.2 22.42 Syngas-cool1 0.03 kr/kg Heatex-H2O 0.2 0.013 0.00 kr/s 0.00 kr/MJ 4 0.01 kr/MJ 0.07 SAND 5.071 571 0.19 kr/s Syngas-cool1 Comp-NG_ref 0.00 kr/kg 0.00 0.00 kr/kg 25.3 22.7 12.89 6 0.01 kr/MJ SAND 21 1.3 MW 5 3.1 Heatex-H2O 1.5 25.38 0.6 7.1 9.101 Heatex-GG-DH 9.2 173.1 563 0.12 kr/s 0.19 0.01 kr/kg 5.8 SAND 1.267 3.1 52.16 1.5 25.38 0.6 10.17 Steam_dryer Biomass (dry) 34 0.05 kr/s 522 25.30 kr/s 2 0.01 kr/MJ Syngas-cool1 0.19 0.01 452 5.50 kr/s 433 2.68 kr/s 442 1.04 kr/s 0.31 62.1 35 4 0.31 kr/s SAND 1 0.07 16.9 Steam dryer 3.96 0.31 56.1 34 2 0.31 kr/s 4 0.01 kr/MJ 0.047 0.01 kr/kg Split-steam2 2 0.15 kr/MJ 0.12 0.01 kr/kg 25.3 2.74 kr/kg Cooler-GG-H2 Cooler-GG-H2 3.6 0.12 0.00 25.30 523 2 9.2 25.30 kr/s 0.06 26.82 561 2 0.186 36.2 20.51 0.19 kr/s 0.01 kr/MJ 0.01 kr/kg 0 541 4 0.0 0.00 kr/s -0 0.00 kr/MJ 0.00 kr/kg Water Reformat 9.669 462 2 9.669 5.2 9.67 kr/s 88.77 0.11 kr/MJ 9.22 461 2 0.02 5.2 9.22 kr/s 87.59 0.11 kr/MJ 2 0.11 kr/MJ 5.501 1.79 kr/kg Mixer-NG_ref 2 0.11 kr/MJ 2.678 1.82 kr/kg Mixer-NG_ref 2 0.10 kr/MJ 1.041 1.66 kr/kg Mixer-NG_ref 35.17 0.01 kr/MJ 38.2 0.01 kr/MJ Cooler-GG-H2 22.7 14.09 171.7 0.15 kr/MJ Syngas-cool1 14.4 262 Syngas-cool1 1.87 kr/kg 1.78 kr/kg 0.00 kr/kg 12.6 145.2 0.01 kr/kg SAND 19 571 0.12 kr/s 2.74 kr/kg Comp-GG-H2-2 532 36.49 kr/s Mixer-CO2-NG Comp-NG_ref Steam_dryer 81 3.89 kr/s Steam_dryer 4 0.01 kr/MJ Comp-GG-H2-2 2 0.14 kr/MJ 2 3.886 0.03 kr/MJ 0.31 kr/kg Steam 0.12 0.01 kr/kg Cooler-GG-H2 4.3 MW SAND 13 4.28 36.49 2.53 kr/kg Comp-syngas1 Comp-syngas1 Component information Technical lifetime = O&M = 15 years 0.02 of the componentprice per year Operating hours = 8000 Exergy Steam DH-condenser Steam_dryer Biomass (wet) 4.6 2.629 41 0.02 kr/s 2 0.01 kr/MJ Steam 0.08 38.57 14.4 267.5 533 38.57 kr/s 4 0.14 kr/MJ Syngas 38.57 2.67 kr/kg 5.9 MW SAND 15 5.869 Electrolyser Comp-H2 Comp-O2-1 Node before component 1 2 5 Component type Electrolyser Compressor Compressor DNA name ELECTROLYSER COMPRE_1 COMPRE_1 Specific price 1.52 mio. kr/MWe 4.50 mio. kr/MW 4.50 mio. kr/MW Price [mio. kr] 86 0 0 Total price [mio. kr] 111 0 0 C [kr/s] 0.26 0.00 0.00 Input: NG Biomass Power* Total power * for electrolyser 96 MW 145 MW 56 MW 79 MW Output: Methanol DH Oxygen Syngas 231 MW 12 MW 0 MW 13 MW SAND 79 0.024 0.01 kr/kg 53.5 33.11 set_temp-2 Gasifier 9 Gasifier GASIFI_3 3.80 mio. kr/MW-biomass 461 600 1.39 DH-condenser 0.01 10.8 0.42 811 12 DH condenser0.42 78.5 0.42 kr/s 581 2 0.28 0.28 kr/s 0.01 kr/MJ 0.01 kr/kg Steam 0.23 571 8 Heatex-GG-O2 Heatex-GG-st Heatex-GG-DH 10 11 12 Heat exchanger Heat exchanger Heat exchanger HEATEX_2 HEATEX_2 GASCOOL2 0.40 mio. kr/MW-transferred 0.40 mio. kr/MW-transferred 0.40 mio. kr/MW-transferred 0 4 0 0 6 1 0.00 0.01 0.00 Methanol-efficiency 1: Methanol-efficiency 2: Total efficiency: 78% (with power for electrolyser) 72% (with total power) 80% 4.6 0.183 2.743 0.15 kr/MJ DH-cooler DH-cooler 42.5 0.23 kr/s Cleaner 13 Gas cleaner GASCLE_2 0.00 mio. kr/(kg/s)-gas 0 0 0.00 42 0.00 kr/s 0.01 kr/kg SAND 25 26.35 0.01 kr/MJ Steam_dryer 34 Steam dryer DRYER_04 4.10 mio. kr/(kg/s)-evaporated 24 32 0.07 4 0.00 kr/MJ 0 0.00 kr/kg DH-condenser DH-condenser 430.0 15.02 811 0.49 kr/s 0.010 811 6 50.8 0.01 kr/s 1.776 0.01 kr/MJ 0.01 8.5 0 804 2 DH cooler DH water 0.01 50.8 0.00 kr/s 0.416 0.00 kr/MJ 1.0 0.639 0.219 562 2 42.5 0.22 kr/s 0.01 kr/kg Syngas-cool2 6.8 0.23 0.01 Syngas-cool2 SAND 23 DH-condenser Comp-O2-2 Heatex-O2 41 401 402 Heat exchanger Compressor Heat exchanger HEATEX_1 COMPRE_1 HEATEX_4 0.40 mio. kr/MW-transferred 4.50 mio. kr/MW 0.40 mio. kr/MW-transferred 4 3 0 6 4 0 0.01 0.01 0.00 Energy Water 2 0.03 kr/MJ 0.49 0.00 kr/kg DH DH water 0.00 kr/kg DH-cooler 35 6 53.5 30.28 0.28 kr/s 0.01 kr/MJ 0.00 kr/kg DH-cooler 571 0.01 kr/s 10 0.01 kr/MJ 0.01 0.01 kr/kg Cond-steam-1 24.1 0.01 kr/MJ 0.01 kr/kg Syngas-cool2 13.9 264.9 534 38.57 kr/s 2 0.15 kr/MJ 0 551 4 0.6 0.00 kr/s 0.049 0.00 kr/MJ 0.00 kr/kg NG_reformer Heatex-NG Water Heatex-H2O Comp-NG_ref Comp-CO2 403 411 422 461 501 NG reformer Heat exchanger Heat exchanger Compressor Compressor STEAM_REFORMER GASCOOL2 GASCOOL2 COMPRE_1 COMPRE_1 1.05 mio. kr/MW-NG 0.40 mio. kr/MW-transferred 0.40 mio. kr/MW-transferred 4.50 mio. kr/MW 4.50 mio. kr/MW 96 2 3 6 0 125 2 4 7 0 0.29 0.00 0.01 0.02 0.00 Input: NG Biomass Power* Total power 92 MW 121 MW 56 MW 79 MW Output: Methanol DH Oxygen Syngas 205 MW 72 MW 0 MW 11 MW Energy content in DH water = 72 MW 0.28 0.01 kr/kg DH-cooler Steam 38.57 2.78 kr/kg Comp-syngas2 Syngas-cool2 Heatsink-H2 Comp-GG-H2-1 511 521 Heat exchanger Compressor HEATSNK0 COMPRE_1 0.40 mio. kr/MW-transferred 4.50 mio. kr/MW 0 23 0 30 0.00 0.07 * for electrolyser Urenhed: 0.023 % Methanol loss in distillation [%] = 1.0 Methanol molar-% = 99.98 Water / 671 1.0 0.566 0.01 kr/s 0.06 Comp-syngas2 40.01 4.1 MW 17 SAND 4.068 13.9 268.6 Cooler-GG-H2 Comp-GG-H2-2 Syngas-cool1 Comp-syngas1 522 523 531 532 Heat exchanger Compressor Heat exchanger Compressor GASCOOL2 COMPRE_1 GASCOOL2 COMPRE_1 0.40 mio. kr/MW-transferred 4.50 mio. kr/MW 0.40 mio. kr/MW-transferred 4.50 mio. kr/MW 1 19 2 26 2 25 3 34 0.00 0.06 0.01 0.08 Methanol-efficiency 1: Methanol-efficiency 2: Total efficiency: 76% (with power for electrolyser) 70% (with total power) 99% Methanol 2 0.01 kr/MJ 535 40.01 kr/s Syngas-cool2 533 Heat exchanger GASCOOL2 0.40 mio. kr/MW-transferred 3 4 0.01 0.01 0.01 kr/kg 2 0.15 kr/MJ Comp-syngas2 534 Compressor COMPRE_1 4.50 mio. kr/MW 18 24 0.06 Cond-steam-1 40.01 2.88 kr/kg Meoh-convert 601 Meoh converter MEOH_CONVERTER ##### mio. kr/(kmol/s-syngas) 327 424 0.98 Gas composition at specific nodes (mol-%) 39.74 10.3 231.1 set-M Preheater-sy 602 Heat exchanger GASCOOL4 0.40 mio. kr/MW-transferred 4 5 0.01 793 794 39.74 kr/s 0.17 kr/MJ 601 59.3 519.3 81.56 kr/s Condenser-1 Syngas Condenser 640 643 Heat exchanger Heat exchanger GASCOOL4 GASCOOL4 0.40 mio. kr/MW-transferred 0.40 mio. kr/MW-transferred 3 4 3 5 0.01 0.01 Node 10 3 15 431 534 601 602 640 643 605 15 23 33 35 41 43 39 37 M-factor 1.67 4 3.86 kr/kg 2 0.16 kr/MJ Comp-recirc 605 Compressor COMPRE_1 4.50 mio. kr/MW 1 1 0.00 Species Split-meoh1 148 38.4 860.6 Steam 0 682 4 82 1.38 kr/kg Meoh-convert feed_Water Cond-steam-1 625 671 Distillation column Heat exchanger DISTILLATION_STAGE* HEATEX_1 23.52 mio. kr/(kg/s-feed) 0.40 mio. kr/MW-transferred 270 0 351 0 0.81 0.00 1 3 H2 N2 45.98 0.25 0.00 57.70 60.63 42.70 24.36 25.92 27.89 30.00 0.00 0.00 0.12 1.00 1.32 1.40 1.51 1.62 791 147.9 kr/s 17.1 0.00 kr/s Cond-steam-2 685 Heat exchanger HEATSNK0 0.40 mio. kr/MW-transferred 13 16 0.04 4 CO 42.73 0.00 22.49 29.16 14.45 3.27 3.47 3.74 4.02 792 0.17 kr/MJ 17.55 0.00 kr/MJ DH-cooler 804 Heat exchanger HEATEX_1 0.40 mio. kr/MW-transferred 3 4 0.01 6 CO2 5.24 0.00 5.09 4.47 35.29 46.38 49.35 53.11 57.12 Heatsourc-DH 4 3.86 kr/kg Cond-steam-1 0.00 kr/kg Heatsourc-DH 806 Heat exchanger HEATSRC0 0.40 mio. kr/MW-transferred 16 20 0.05 7 H2O-G 5.21 0.00 14.17 5.12 2.13 2.93 1.70 0.62 0.02 SAND 390 Cond-meoh SAND 35 Convert-cool * The distillation column is composed of 9 H2S 0.00 ##### 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.047 811 10 39.2 234.0 0.05 kr/s 0.047 0.05 0 806 2 DH water 234.0 0.00 kr/s 0 683 2 0.1 0.00 kr/s 0.2 0.01 0.00 0 684 4 0.1 0.00 kr/s Water 0 681 2 17.1 0.00 kr/s 31.8 Meoh-convert Methanol 0.98 SAND converter 83 311 Total several DISTILLATION_STAGE's 1423 1826 4.28 11 36 40 CH4 AR CH3OH 0.48 0.12 0.00 0.00 0.00 0.00 0.55 0.00 0.00 0.44 0.06 0.00 3.62 4.77 5.08 0.48 0.63 0.67 0.33 16.33 12.39 5.47 0.73 6.94 5.88 0.78 0.56 8.175 0.01 kr/MJ 0.00 kr/kg 1.916 0.00 kr/MJ 0.00 kr/kg 0.115 0.00 kr/MJ 0.00 kr/kg 0.025 0.00 kr/MJ 0.00 kr/kg 3.774 0.00 kr/MJ 0.00 kr/kg 602 59.3 503.9 82.55 kr/s 607 45.4 251 41.55 kr/s Input prices GG H2S NG_ref-cool Syngas-loop1 Syngas-meoh- Syngas-loop2 Syngas-3 Syngas-meoh Syngas-loop3 108.3 Heatsourc-DH 148 38.4 869.6 Heatsourc-DH 28.1 629.5 783 147.9 kr/s Cond-steam-1 Cond-steam-1 Convert-cool 2 83 0.16 kr/MJ 1.39 kr/kg 2 42 0.17 kr/MJ 0.92 kr/kg Input Electric power Price 324 kr/GJ Output cost Comparable fuel prices 781 108.2 kr/s 784 0.17 kr/MJ 17.0 17.43 Preheater-sy Mixer-syn_re Mechanical power 341 kr/GJ Output Cost flow Cost (exergy) Cost (energy) Cost (mass) Cost (volume) Fuel Price (exergy) Price (volume) 782 0.17 kr/MJ 4 3.86 kr/kg 685 0.00 kr/s 9.5 Preheater-sy NG 93 kr/GJ Methanol 39.7 kr/s 172 kr/GJ 194 kr/GJ 3.86 kr/kg 3.0 kr/l Methanol (commercial) 142 kr/GJ 2.5 kr/l 2 3.86 kr/kg Dis_stage_17 2 0.00 kr/MJ 42 606 2 42 0.01 SAND 29 Biomass 32 kr/GJ Oxygen 0.0 kr/s 410 kr/GJ - kr/GJ 0.05 kr/kg - kr/l Petrol 187 kr/GJ 6.6 kr/l Dis_stage_17 0 0.00 kr/kg Comp-recirc 42 45.4 41.54 kr/s 55.7 431 DH water 0 kr/ton Syngas 2.2 kr/s 167 kr/GJ - kr/GJ 0.91 kr/kg - kr/l Crude oil 58 kr/GJ 2.2 kr/l Cond-steam-2 0.2 MW 19 0.00 248.1 0.17 kr/MJ 640 71.13 kr/s 78 11.42 3.6 69.19 Water 32 kr/ton DH water 0.5 kr/s 32 kr/GJ 7 kr/GJ 0.00 kr/kg - kr/l Ethanol 100 kr/GJ 2.4 kr/l 0 681 4 SAND 0.176 0.92 kr/kg 2 0.17 kr/MJ 621 11.42 kr/s CO2 114 kr/ton Water 0 kr/s - kr/GJ - kr/GJ - kr/kg - kr/l Distillation column 155 0.81 Feed 17.0 3.749 0.00 kr/s 0.00 kr/MJ 0.00 kr/kg Preheater-sy 71.13 1.28 kr/kg Condenser-1 6.6 631 0.17 kr/MJ 4 3.21 kr/kg Preheater-sy Nomenclature: Cond-steam-2 1.21 0.01 If methanol and DH share the plant costs Condenser-1 84.1 13.67 621 631 4 (methanol and DH are the only products from the plant) - 7 705 706 19 6.96 kr/s 2 1.21 705 706 3 1.21 kr/s 6 SAND 31 51.6 346.2 643 57.46 kr/s 2 0.17 kr/MJ 4 13.67 kr/s 82 0.17 kr/MJ 3.38 kr/kg and the DH cost is fixed corresponding to the DH price: Output Cost flow Cost Methanol 31.6 kr/s 137 kr/Gjex Electrical power Node nr Cost flow Transferred heat [MW] 49 0.14 kr/MJ 9 0.14 kr/MJ Condenser 57.46 1.11 kr/kg Preheater-sy DH water 10.8 kr/s 150 kr/Gjen Specific exergy cost 0.37 kr/kg 0.37 kr/kg SAND 33 Condenser Specific mass cost Dis_stage_1 0.01 811 8 59.9 0.01 kr/s Reboil-meoh2 10.0 0.01 0.01 0 805 2 DH water 59.9 0.00 kr/s Mechanical power 10 6.915 19.8 40.63 2.091 0.01 kr/MJ 0.49 0.00 kr/MJ 1.2 3.2 6.628 707 6.92 kr/s Cond-steam-2 0.00 kr/kg 41.48 605 2 0.00 kr/kg 699 1.20 kr/s 0.25 708 0.17 kr/MJ SAND 393 Condenser 45.4 41.48 kr/s 2.4 13.05 Condenser 700 0.18 kr/MJ 4 0.35 kr/kg 247.9 0.17 kr/MJ 611 2.18 kr/s 91.4 13.8 3.9 82.48 2 0.37 kr/kg Water / Methanol Methanol molar-% = 5.16 0 693 694 1 0.00 kr/s 2 0.00 kr/MJ Dis_stage_1 4 5.716 695 696 15 5.72 kr/s 32 0.18 kr/MJ 2 31.6 5.754 0.04 5.754 705 706 15 5.75 kr/s 41 0.14 kr/MJ 4 38.88 625 635 11 38.88 kr/s 2 Methanol molar-% = 84.5 0.91 kr/kg Comp-recirc Methanol/ 4 0.17 kr/MJ 2.183 0.91 kr/kg Syngas Split-syngas 621 13.80 kr/s 631 0.17 kr/MJ 4 3.57 kr/kg Preheater-sy Reboil-meoh2 Heat Component cost flow [kr/s] 0.00 kr/kg set-x-2 0.37 kr/kg Reboil-meoh1 0.37 kr/kg Reboil-meoh1 234 0.17 kr/MJ 3.39 kr/kg meas_flow Methanol mass flow = 10.4 kg/s water

24. Flowsheets for metanolanlæg – for de 6 forskellige anlægskonfigurationer Flowsheets sorteret efter anlægsnummer - anlæg 1 først.

Page 1 and 2: Design og modellering af metanolanl

Page 3 and 4: 2 Resumé I forbindelse med DONG En

Page 5 and 6: 4 Indholdsfortegnelse 1 Abstract...

Page 7 and 8: 5 Indledning Baggrunden for dette p

Page 9 and 10: 7 Design og statisk modellering af

Page 11 and 12: Brint er specielt fordelagtig til m

Page 13 and 14: Ligning 7.1: Den specifikke varmeka

Page 15 and 16: DNA-navn: DRYER_04 Forgasser Forgas

Page 17 and 18: T Fordampning Pinch points Figur 7.

Page 19 and 20: Massestrøm af Metanol/vand-blandin

Page 21 and 22: Parameter Værdi Komponenter Evt. k

Page 23 and 24: 7.2 Anlægskonfigurationer Den opby

Page 25 and 26: 7.3 Økonomi For at kunne vurdere o

Page 27 and 28: Input-priser Kilde Elektricitet 18

Page 29 and 30: 7.4 Termoøkonomisk analyse Der er

Page 31 and 32: Komponent Produkt(er) Spild Elektro

Page 33 and 34: Tabet i fysisk exergi forekommer ho

Page 35 and 36: Anlæg 1 Total: 320 MWex (292 MW) 7

Page 37 and 38: antagelse, da naturgasnettet er try

Page 39 and 40: 246 562 112 Anlæg 1 Total: 1222 mi

Page 41 and 42: Brændsel Pris Kilde [kr/L] [kr/GJe

Page 43 and 44: Metanolomkostning [kr/GJex] 500 450

Page 45 and 46: 7.5.2 Parametervariation Nedenfor e

Page 47 and 48: Udkondenseret metanol [%] 100 95 90

Page 49 and 50: Metanolrenhed efter destillation [m

Page 51 and 52: vandkoncentrationen i syngassen fal

Page 53 and 54: Metanolexergivirkningsgrad [%] 73 7

Page 55 and 56: Metanolrenhed efter destillation [m

Page 57 and 58: Dette betyder at den metanolholdige

Page 59 and 60: Atmosfærisk forgasning (1 bar) Try

Page 61 and 62: 7.6 Diskussion I parametervariation

Page 63 and 64: 7.6.2 Alternative anlægsdesign Ned

Page 65 and 66: 8 Benyttelse af underjordiske gasla

Page 67 and 68: 8.2 Scenarier Der er undersøgt 2 s

Page 69 and 70: Ligning 8.5: Reference-el-omkostnin

Page 71 and 72: Ligning 8.13: Tidskonstant for lage

Page 73 and 74: Brintlagerbeholdning [MWh] 3000 250

Page 75 and 76: Brintlagerbeholdning [MWh] 400 350

Page 77 and 78: den time, hvor regulatorligningen b

Page 79 and 80: El-pris-funktionen [kr/MWh] 500 450

Page 81 and 82: Brintlagerbeholdning [MWh] 100 90 8

Page 83 and 84: Omkostninger [%] 100 90 80 70 60 50

Page 85 and 86: Sparede omkostninger [%] 30 25 20 1

Page 87 and 88: selvstændig investering og de omko

Page 89 and 90: Tilbagebetalingstid (beregnet ud fr

Page 91 and 92: Sparede omkostninger i nutidsværdi

Page 93 and 94: Tilbagebetalingstid [år] 15 10 5 0

Page 95 and 96: 8.4 Diskussion Resultaterne præsen

Page 97 and 98: El-pris [kr/Mwh] 400 350 300 250 20

Page 99 and 100: 9 Konklusion I den første del af r

Page 101 and 102: http://www.energyserver.net/ET1/Def

Page 103 and 104: 11 Nomenklaturliste c omkostning pe

Page 105 and 106: Design og modellering af metanolanl

Page 107 and 108: 25. Flowsheets for metanolanlæg -

Page 109 and 110: 2. Forgasserpris - Choren Choren In

Page 111 and 112: 4. El-afgifter og -tariffer GE-NET

Page 113 and 114: 6. Naturgasafgifter - DONG Energy N

Page 115 and 116: 8. Benzinforbrug til vejtransport E

Page 117 and 118: 10. Benzinafgift Benzinafgifter fra

Page 119 and 120: 12. Metanolpris Metanolpriser fra M

Page 121 and 122: Methanex Non-Discounted Reference P

Page 127 and 128: 14. Metanolproduktion, NZIC New Zea

Page 129 and 130: Maui Gas Supply Kapuni Gas Supply N

Page 131 and 132: Gas metering and letdown The proces

Page 133 and 134: Methanol Distillation Crude methano

Page 135 and 136: Product Gasoline Pipeline (250 mm N

Page 137 and 138: steam, preheat the reactants (steam

Page 139 and 140: As it is very difficult to separate

Page 141 and 142: Operational processes A schematic l

Page 143 and 144: The reaction of the synthesis gas c

Page 145 and 146: Figure 15 - Flowsheet of the MTG pr

Page 147 and 148: 15. Metanolproduktion, Nykomb Nykom

Page 149 and 150: NYKOMB SYNERGETICS 2. Methanol Plan

Page 151 and 152: NYKOMB SYNERGETICS 6. Investment Es

Page 153 and 154: NYKOMB SYNERGETICS 9. Logistics and

Page 155 and 156: 16. Metanolproduktion, Wikipedia Wi

Page 157 and 158: 18. Flowsheet for et metanolanlæg

Page 159 and 160: 20. Flowsheet for metanolanlæg - u

Page 161 and 162: 21. Flowsheet for metanolanlæg - t

Page 163 and 164: 22. Flowsheet for metanolanlæg - t

Page 165 and 166: 23. Flowsheets for metanolanlæg -

Page 167 and 168: 0 1 1 1 P 2 M type NOD* 2 1 type NO

Page 169: 0 1 1 1 P 2 M type NOD* 9 2 type NO







Page 185 and 186: 27. Flowsheet for metanolanlæg - f

Page 187 and 188: 28. Flowsheet for metanolanlæg - f

Page 189 and 190: 29. Matlab-kode til Scenarie 1

Page 191 and 192: 18-03-07 23:10 D:\DTU\Eksamensproje











Page 213 and 214: 32. DNA-kode for metanolanlæg

Page 215 and 216: metanolanlaeg.dna d:/DTU/Eksamenspr

Page 217 and 218: metanolanlaeg.dna d:/DTU/Eksamenspr

Page 219 and 220: 33. Dokumentation for tilføjede DN

Page 221 and 222: 17.121.4 Conditions ˙m1 > 0 ˙m2 <

Page 223 and 224: 9. - 10. - 11. - 12. - 13. - 14. -

Page 225 and 226: 17.123 GASIFI_3_VENZIN Gasifier wit

Page 227 and 228: 13. - 14. - 15. - 16. - 17. - 18. -

Page 229 and 230: 17.124 GASCLE_2 Syngas cleaning. Th

Page 231 and 232: 38. Compound number 39. Compound nu

Page 233 and 234: 43. - 44. - 45. - 46. - 47. - 48. -

Page 235 and 236: 17.124.5 Example struc Cleaner GASC

Page 237 and 238: 10. - 11. - 12. - 13. - 17.125.4 Co

Page 239 and 240: 7. - 8. - 9. - 10. - 11. - 12. - 13


Page 243 and 244: 11. - 12. - 13. - 14. - 15. - 16. -

Page 245 and 246: 17.128 SET_M Utility component for

Page 247 and 248: 4. - 5. - 6. - 7. - 8. - 9. - 10. -



Page 253 and 254: 17.131.2 Equations Number of equati

Page 255 and 256: 17.132 EL-MOTOR Motor with efficien

Page 257 and 258: 8. - 9. - 17.133.3 Conditions ˙m1

Page 259 and 260: 17.135 MIXER_03 Mixer for ideal gas

Page 261 and 262: 33. - 34. - 35. - 36. - 37. - 38. -

Page 263 and 264: 17.137 SET_X Utility component for


Page 267 and 268: 17.140 SET_FLOW Utillity component

Page 269 and 270: 17.142 SET_TEMP2 Utillity component

Page 271 and 272: 34. Tilføjede komponenter til DNA

Page 273 and 274: VEnzin.for c:/dna/source/ C C Param

Page 275 and 276: VEnzin.for c:/dna/source/ CA ANTED

Page 277 and 278: VEnzin.for c:/dna/source/ IF (MDOT(

Page 279 and 280: VEnzin.for c:/dna/source/ MMVAR(1)

Page 281 and 282: VEnzin.for c:/dna/source/ ENDDO DO

Page 283 and 284: VEnzin.for c:/dna/source/ $fluid O2

Page 285 and 286: VEnzin.for c:/dna/source/ C−−

Page 287 and 288: VEnzin.for c:/dna/source/ CA FKOMP

Page 289 and 290: VEnzin.for c:/dna/source/ ENDDO NIN

Page 291 and 292: VEnzin.for c:/dna/source/ C Subrout

Page 293 and 294: VEnzin.for c:/dna/source/ CALL STAT

Page 295 and 296: VEnzin.for c:/dna/source/ CA 3: Flu

Page 297 and 298: VEnzin.for c:/dna/source/ C C C M_B

Page 299 and 300: VEnzin.for c:/dna/source/ C C SETFL

Page 301 and 302: VEnzin.for c:/dna/source/ C C GASCO

Page 303 and 304: VEnzin.for c:/dna/source/ RES(5) =

Page 305 and 306: VEnzin.for c:/dna/source/ c c c E2=

Page 307 and 308: VEnzin.for c:/dna/source/ C C HEATE

Page 309 and 310: VEnzin.for c:/dna/source/ $ ’$\\d

Page 311 and 312: VEnzin.for c:/dna/source/ c 1 = Wat

Page 313 and 314: VEnzin.for c:/dna/source/ CA 4: Fin

Page 315 and 316: VEnzin.for c:/dna/source/ CL K_MED

Page 317 and 318: VEnzin.for c:/dna/source/ CA MEDIE

Page 319 and 320: VEnzin.for c:/dna/source/ CA −4 :

Page 321 and 322: VEnzin.for c:/dna/source/ C ENDDO E

Page 323 and 324: VEnzin.for c:/dna/source/ MEDIE(2)

Page 325 and 326: VEnzin.for c:/dna/source/ C C 400 C

Page 327 and 328: VEnzin.for c:/dna/source/ GOTO 9999

Page 329 and 330: VEnzin.for c:/dna/source/ MEDIE(1)


Page 333 and 334: VEnzin.for c:/dna/source/ RES(1) =



Page 339 and 340: 35. Metanol (fluid) til DNA - Fortr

Page 341 and 342: methanol.for d:/DTU/Eksamensprojekt









methanol

exchanger

output

goto

component

electrolyser

compressor

input

gasifier

syngas

modellering

bilag

etd.dtu.dk

Design og modellering af metanolanlæg til VEnzin-visionen Bilag

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