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V - Positron Annihilation in Halle

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Diffusion of Cu <strong>in</strong> GaAs<br />

280<br />

• <strong>Positron</strong> experiment:<br />

• 30 nm Cu-layer deposited by<br />

•<br />

evaporation evapo at o<br />

Anneal<strong>in</strong>g at 1100°C (under def<strong>in</strong>ed<br />

270<br />

•<br />

•<br />

As-pressure) for Cu <strong>in</strong>-diffusion<br />

Quench<strong>in</strong>g to RT<br />

then anneal<strong>in</strong>g with grow<strong>in</strong>g<br />

260<br />

•<br />

temperature<br />

<strong>Positron</strong> lifetime measurement<br />

250<br />

• Cu is completely solved at 1100°C<br />

• But it is oversaturated at RT<br />

• Precipitation starts very slowly (slow<br />

diffusion)<br />

• However: at elevated temperatures – diffusion<br />

240<br />

bbecomes faster: f out-diffusion diff i process<br />

• Result: formation of vacancy-type defects<br />

when out-diffusion starts<br />

• Not compatible with ith current c rrent diffusion diff sion models<br />

230<br />

Mart<strong>in</strong>-Luther-Universität <strong>Halle</strong><br />

averrage<br />

positrron<br />

lifetimee<br />

(ps)<br />

400 K<br />

500 K<br />

550 K<br />

600 K<br />

650 K<br />

700 K<br />

750 K<br />

800 K<br />

850 K<br />

900 K<br />

0 100 200 300 400 500<br />

measurement temperature (K)

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