V - Positron Annihilation in Halle

V - Positron Annihilation in Halle V - Positron Annihilation in Halle

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Height H [nm] ] 02 0.2 0.1 0.0 Identification of V VGa Ga-Si SiGa Ga-Complexes Complexes in GaAs:Si occupied empty states -2.0 V +1.4 V 1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9 lattice spacing in [110] direction • Scanning tunneling microscopy at GaAs (110)- cleavages l planes l (by (b Ph Ph. Ebert, Eb t Jülich) Jüli h) • Defect complex identified as VGa-SiGa Martin-Luther-Universität Halle cm -3 Defect conceentration (c ) 10 19 10 19 10 18 10 17 10 18 Positrons - c vac STM - [Si Ga -V Ga ] 10 19 Si concentration (cm -3 ) • Quantification → Agreement Mono-Vacancies in GaAs:Si are V Ga- Si Ga-complexes Gebauer et al., Phys. Rev. Lett. 78 (1997) 3334

Defects after high energy Si self self-implantation implantation -the the Rp/2 Effect on (cm -3 Cu conncentratio ) • After high-energy self-implantation of Si (3.5 MeV; 5 ×10 2 15 cm -2 ) and RTA (900°C, 30s): two new getter zones appear at Rp and Rp /2 (Rp = projected range of Si + ) • Zones become visible after Cu in-diffusion from rear side of sample (Cu implantation and diffusion annealing at 600°C) 10 17 10 16 TEM image by P. Werner, MPI Halle SIMS 10 0 1 2 3 4 15 Martin-Luther-Universität Halle R p/2 DDepth th( (μm) ) R p • at Rp : gettering by interstitial type dislocation loops • Formed due to interstial excess Si after iimplantation l t ti and dRTA RTA annealing li • Although gettering appears, no defects visible by TEM at Rp /2 • What is the nature of these defects?

Height H [nm] ]<br />

02 0.2<br />

0.1<br />

0.0<br />

Identification of V VGa Ga-Si SiGa Ga-Complexes Complexes <strong>in</strong> GaAs:Si<br />

occupied empty states<br />

-2.0 V +1.4 V<br />

1 2 3 4 5 6 7 8 9 1 2 3 4 5 6 7 8 9<br />

lattice spac<strong>in</strong>g <strong>in</strong> [110] direction<br />

• Scann<strong>in</strong>g tunnel<strong>in</strong>g microscopy at GaAs (110)-<br />

cleavages l planes l (by (b Ph Ph. Ebert, Eb t Jülich) Jüli h)<br />

• Defect complex identified as VGa-SiGa Mart<strong>in</strong>-Luther-Universität <strong>Halle</strong><br />

cm -3 Defect<br />

conceentration<br />

(c )<br />

10 19<br />

10 19<br />

10 18<br />

10 17<br />

10 18<br />

<strong>Positron</strong>s - c vac<br />

STM - [Si Ga -V Ga ]<br />

10 19<br />

Si concentration (cm -3 )<br />

• Quantification → Agreement<br />

Mono-Vacancies <strong>in</strong> GaAs:Si are V Ga- Si Ga-complexes<br />

Gebauer et al., Phys. Rev. Lett. 78 (1997) 3334

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