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Copyright by Kirsten Viering 2006 - Raizen Lab - The University of ...

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are therefore useful tools. A tweezer at the magic wavelength would allow to trap<br />

atoms in the ground state as well as in an excited state without heating them. Thus<br />

transitions between these two states can be induced and fluorescence imaging can<br />

be used to determine the atom number. Spatially resolved Raman transitions allow<br />

to measure spatial distributions where the achievable resolution is smaller than the<br />

wavelength.<br />

As this work deals with the manipulation <strong>of</strong> atomic states with light we will<br />

review the semi-classical description <strong>of</strong> atoms with non-resonant light (chapter 2) and<br />

apply it to calculations <strong>of</strong> the AC-Stark shift in Sodium and Rubidium. Knowing the<br />

respective energy shifts for the ground and the excited states we can determine the<br />

magic wavelength, where the relative shift between the ground and a specific excited<br />

state vanishes (chapter 3). Our efforts to determine the magic wavelength in Sodium<br />

are summarized in chapter 4, together with a brief discussion <strong>of</strong> the experimental<br />

environment.<br />

In chapter 5 we expand the theory <strong>of</strong> the interaction <strong>of</strong> electro-magnetic radiation<br />

with atoms to the case with two monochromatic light sources and introduce stimulated<br />

Raman transitions in the presence <strong>of</strong> an external magnetic field. Chapter 6 summarizes<br />

our calculations <strong>of</strong> stimulated Raman transitions for Sodium atoms, and outlines the<br />

spatial resolution that is prospectively achievable using a magnetic field gradient.<br />

A relevant parameter in all our calculations is the dipole matrix element between<br />

two states. A convenient way to determine these is the Wigner-Eckart <strong>The</strong>orem which<br />

is briefly discussed in appendix A. Appendix B summarizes some physical properties<br />

<strong>of</strong> Sodium atoms and describes the influence <strong>of</strong> an external magnetic field on the<br />

energy level structure. <strong>The</strong> Einstein-coefficients we calculated to determine the magic<br />

wavelength in Rubidium are tabulated in appendix C.<br />

2

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