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Ph.D. Thesis - Physics

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emission from the excited state |↓〉. This quantity is given by<br />

Γ = e2cω 3 0 |〈↓|r |↑〉|<br />

3πǫ0c3 . (4.19)<br />

For the types of atoms discussed in this thesis, Γ is on the order of 2π· 20 MHz. The<br />

operator ecr is the (vector) dipole operator.<br />

The principle of Doppler cooling is as follows: an atom (or ion) excited from |↑〉 to<br />

|↓〉 absorbs an amount of momentum from the laser equal to k, where k is the laser<br />

wavenumber. However, this energy is then spontaneously emitted in a random direction.<br />

Doppler cooling works by red-detuning the laser (δl < 0) so that the atom is more likely to<br />

absorb light when it is moving toward the laser than when it is moving away. This, combined<br />

with spontaneous emission, serves to cool the atom. When the atom is moving away from the<br />

laser, it is further off-resonance, and is not as affected by the beam. For Doppler cooling<br />

neutral atoms along a given direction, a total of six lasers are needed (three orthogonal<br />

pairs of counterpropagating beams). This is known as the optical molasses technique. For<br />

a trapped ion, the situation is better, because an ion is already bound in space by the trap.<br />

If the cooling laser has a component along ˆx, ˆy, and ˆz, then the back-and-forth motion of<br />

the ion allows it to be cooled in all three directions.<br />

Let us make the above description more quantitative. A result we shall need is the<br />

steady-state solution to the Optical Bloch equations that describes the average steady-state<br />

population p↓ of the excited atomic state. It reads as follows:<br />

p↓ =<br />

I/I0<br />

1 + I/I0 + 2δv<br />

Γ<br />

, (4.20)<br />

where I0 = ω 3 0 Γ/(6c2 ) is the saturation intensity of the transition. The quantity δv is the<br />

detuning, including the Doppler shift due to the atom’s velocity: δv = δl − k ·v. The cooling<br />

force on the atom due to the laser light is calculated in the following way: the force is equal<br />

to the momentum per photon times the rate of photon emission, which is the spontaneous<br />

emission rate times the probability that the atom is in state |↓〉. Altogether, the light force<br />

is<br />

F = k Γ<br />

2 p↓. (4.21)<br />

When the ion has been cooled to a sufficiently low velocity, one can approximate Eq. 4.21<br />

as being linear in v: this leads to an expression for the cooling rate:<br />

with the constant α given by<br />

<br />

˙Ecool = Fv = αv 2 , (4.22)<br />

91

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