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Ph.D. Thesis - Physics

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4.1 The ion trap system and Hamiltonian<br />

An ion trap is an electromagnetic device for confining a charged particle in space. The<br />

charged particle that concerns us is a singly-charged atomic ion, unless otherwise noted.<br />

A trapped ion, if left undisturbed, contains two separable quantum systems: a ladder<br />

of harmonic oscillator motional states, and an internal electronic state. The key insight of<br />

trapped ion quantum computation (and simulation) is that these internal and external states<br />

can be made to interact, and even become entangled, using a set of classical control pulses,<br />

which usually take the form of laser radiation (but can also be microwaves or magnetic<br />

fields). Comparing this situation to solution-state NMR, we note that the same basic<br />

ingredients are present, but in a different form. The spin states of nuclei are replaced<br />

by the electronic states of ions, while interaction between these states is mediated not by<br />

chemical bonds, but by the coupled motion of the ions.<br />

There are two main varieties of ion trap: Paul traps and Penning traps. Paul traps use<br />

oscillating radiofrequency (rf) electric fields, possibly in combination with dc electric fields,<br />

to confine ions. In these traps, one finds that time-averaging the oscillating field leads<br />

to an effective harmonic potential. Penning traps use static magnetic fields and electric<br />

fields to confine ions. The ions execute cyclotron motion around the B-field lines, and are<br />

simultaneously confined along the axis of the B-field by static voltages applied to endcap<br />

electrodes. Both have advantages and disadvantages. Penning traps necessarily have a very<br />

large Zeeman shift due to the confining magnetic fields, whereas in Paul traps the internal<br />

states are much less sensitive to the trapping fields. However, ions in Paul traps exhibit<br />

small oscillations at the rf frequency, called micromotion, that can only be removed if the<br />

ions are positioned where the confining fields vanish. Because of the independence of the<br />

internal states from the trapping fields, but for other reasons as well, Paul traps have been<br />

the trap of choice for most quantum information experiments. In this chapter, we shall<br />

focus on them exclusively.<br />

In this section we first discuss the ion trap potential and the motion of ions confined<br />

therein. We then turn to understanding laser-ion interactions to a sufficient extent that we<br />

can study the theory of quantum simulations with trapped ions, and also review the princi-<br />

ples of laser cooling of ions, a technique which will be used extensively in the experimental<br />

work of this thesis.<br />

4.1.1 Motional states of trapped ions<br />

All Paul traps obey the following basic principle. An electric quadrupole (or “saddle-<br />

shaped”) potential is formed in space by a set of electrodes, each of which is charged to a<br />

certain voltage. In the case of static voltages, the ion would follow the field lines out of the<br />

center of the potential. In fact, it is a well-known result, commonly known as Earnshaw’s<br />

theorem, that no static electric field configuration can trap a charged particle. However, if<br />

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