25.07.2013 Views

Ph.D. Thesis - Physics

Ph.D. Thesis - Physics

Ph.D. Thesis - Physics

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

µN the nuclear magneton, and B0 the magnitude of the magnetic field along ˆz. Zi is the<br />

Pauli Z matrix operating on qubit i. Here, and throughout, we use the most common phase<br />

convention for the Pauli matrices:<br />

X =<br />

<br />

0 1<br />

1 0<br />

<br />

; Y =<br />

<br />

0 −i<br />

i 0<br />

<br />

; Z =<br />

<br />

1 0<br />

0 −1<br />

<br />

. (2.2)<br />

where the spin states, unless otherwise noted, are written in the ˆz basis, with vector repre-<br />

sentations<br />

|↑〉 =<br />

<br />

1<br />

0<br />

<br />

and |↓〉 =<br />

<br />

0<br />

1<br />

<br />

. (2.3)<br />

The other important term in the static Hamiltonian arises from couplings between in-<br />

dividual nuclei that are mediated by the electron clouds surrounding them, which form the<br />

chemical bond in the molecule. Although, in general, there are also direct dipole-dipole<br />

couplings, in a dilute solution this interaction averages to zero. The through-bond cou-<br />

pling is called scalar coupling, or just J-coupling. This interaction takes the form of a ZZ<br />

interaction:<br />

HI = <br />

4<br />

N<br />

JijZiZj , (2.4)<br />

i,j

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!